dowex optipore v503

2
Product Information Page 1 of 2 * Trademark of The Dow Chemical Company Form No. 177-01885-603 DOWEX Ion Exchange Resins and Adsorbents DOWEX OPTIPORE V503 Polymeric Adsorbent for Removal of Organics from Humid Air Streams Features Dow has commercialized a new product for capturing volatile organic compounds (VOC) from air. Designated as DOWEX* OPTIPORE* V503 polymeric adsorbent, this product replaces DOWEX OPTIPORE V502. The new adsorbent is a 1.0 mm diameter, spherical bead material, designed to give lower pressure drop in vapor phase applications while retaining all the other attributes of the smaller particle size adsorbent, DOWEX OPTIPORE V493. DOWEX OPTIPORE V503 polymeric adsorbent is available in dry form, ready to use for most applications. Since DOWEX OPTIPORE V503 is a powerful adsorbent, it may adsorb odors and solvents during transportation and storage. The adsorbent can be precycled through a regeneration cycle prior to use to remove these materials. Table 1 lists typical properties for the adsorbent. Table 1. Typical physical and chemical properties of DOWEX OPTIPORE V503 adsorbent DOWEX OPTIPORE V503 Matrix structure Macroporous styrenic polymer Physical form Orange to brown spheres Particle size (mm) 1.0 Moisture content <5% BET surface area (m 2 /g) >1,100 Total porosity (cc/g) 0.94 Average pore diameter (Å) 34 Apparent density (g/cc) (lbs/cf) 0.34 21.3 Ash content (%) <0.01 Crush strength (g/bead) >1,000 These properties are typical of the product and should not be confused with nor regarded as specifications. Figure 1 shows a pressure drop curve for DOWEX OPTIPORE V503 adsorbent as a function of air velocity downflow through a packed bed. For upflow applications, DOWEX OPTIPORE V503 adsorbent will begin to fluidize at an air velocity of 30 to 40 ft/min, depending on the bed depth. Low Moisture Uptake Figure 2 shows a typical moisture uptake for DOWEX OPTIPORE V503. This product is produced with a patented chemistry to make it very hydrophobic. Low moisture uptake means that water does not compete for adsorption sites and reduce capacity, energy is not wasted to desorb the water and less water is subsequently recovered with the product solvent.

Upload: imranul-islam

Post on 19-Dec-2015

48 views

Category:

Documents


6 download

TRANSCRIPT

Page 1: Dowex Optipore V503

Product Information

Page 1 of 2 * Trademark of The Dow Chemical Company Form No. 177-01885-603DOWEX Ion Exchange Resins and Adsorbents

DOWEX OPTIPORE V503Polymeric Adsorbent for Removal of Organics from Humid Air Streams

Features Dow has commercialized a new product for capturing volatile organic compounds (VOC) fromair. Designated as DOWEX* OPTIPORE* V503 polymeric adsorbent, this product replacesDOWEX OPTIPORE V502. The new adsorbent is a 1.0 mm diameter, spherical beadmaterial, designed to give lower pressure drop in vapor phase applications while retaining allthe other attributes of the smaller particle size adsorbent, DOWEX OPTIPORE V493.

DOWEX OPTIPORE V503 polymeric adsorbent is available in dry form, ready to use for mostapplications. Since DOWEX OPTIPORE V503 is a powerful adsorbent, it may adsorb odorsand solvents during transportation and storage. The adsorbent can be precycled through aregeneration cycle prior to use to remove these materials. Table 1 lists typical properties forthe adsorbent.

Table 1. Typical physical and chemical properties of DOWEX OPTIPORE V503adsorbent

DOWEX OPTIPORE V503Matrix structure Macroporous styrenic polymerPhysical form Orange to brown spheresParticle size (mm) 1.0Moisture content <5%BET surface area (m2/g) >1,100Total porosity (cc/g) 0.94Average pore diameter (Å) 34Apparent density (g/cc)

(lbs/cf)0.3421.3

Ash content (%) <0.01Crush strength (g/bead) >1,000These properties are typical of the product and should not be confused with nor regarded as specifications.

Figure 1 shows a pressure drop curve for DOWEX OPTIPORE V503 adsorbent as a functionof air velocity downflow through a packed bed. For upflow applications, DOWEX OPTIPOREV503 adsorbent will begin to fluidize at an air velocity of 30 to 40 ft/min, depending on the beddepth.

Low MoistureUptake

Figure 2 shows a typical moisture uptake for DOWEX OPTIPORE V503. This product isproduced with a patented chemistry to make it very hydrophobic. Low moisture uptake meansthat water does not compete for adsorption sites and reduce capacity, energy is not wasted todesorb the water and less water is subsequently recovered with the product solvent.

Page 2: Dowex Optipore V503

Page 2 of 2 *Trademark of The Dow Chemical Company Form No. 177-01885-603

Catalytic Activity In contrast to activated carbon, DOWEX OPTIPORE V503 adsorbent can be used to adsorbreactive solvents without catalyzing their decomposition. Reactive solvents such as acetone,methylethyl ketone, cyclohexanone and styrene have been adsorbed desorbed withoutmeasurable change in composition. With most activated carbons however, measurablesolvent degradation occurs. In extreme cases, solvent degradation on carbon beds can leadto an uncontrollable exotherm and subsequent bed fire. The lack of catalytic decompositionwhen using DOWEX OPTIPORE V503 adsorbent may be attributed to its extremely lowmineral ash content.

Vapor Phase Adsorption Isotherms for DOWEX OPTIPORE V503 Adsorbent

DOWEX Ion Exchange ResinsFor more information about DOWEXresins, call the Dow Liquid Separationsbusiness:North America: 1-800-447-4369Latin America: (+55) 11-5188-9277Europe: (+32) 3-450-2240Japan: (+81) 3-5460-2100Australia: (+61) 3-9226-3545http://www.dowex.com

Warning: Oxidizing agents such as nitric acid attack organic ion exchange resins under certain conditions. This could lead toanything from slight resin degradation to a violent exothermic reaction (explosion). Before using strong oxidizing agents, consultsources knowledgeable in handling such materials.

Notice: No freedom from any patent owned by Seller or others is to be inferred. Because use conditions and applicable lawsmay differ from one location to another and may change with time, Customer is responsible for determining whether productsand the information in this document are appropriate for Customer’s use and for ensuring that Customer’s workplace anddisposal practices are in compliance with applicable laws and other governmental enactments. Seller assumes no obligation orliability for the information in this document. NO WARRANTIES ARE GIVEN; ALL IMPLIED WARRANTIES OFMERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE ARE EXPRESSLY EXCLUDED.

ACTIVATEDCARBON

V503

0 20 40 60 80 100

50

40

30

20

10

0

Wat

er A

dso

rpti

on

Cap

acit

y(p

erce

nt

of

dry

wei

gh

t)

Relative Humidity (%)

PERCHLOROETHYLENE

TRICHLOROETHYLENE

1,1,1-TRICHLOROETHANE

METHYLENE CHLORIDE

0 5000 10000 15000 20000 25000

1.2

1.0

0.8

0.6

0.4

0.2

0.0

.

.

.

.

.

CONC (vppm)

AD

SO

RP

TIO

N C

AP

AC

ITY

(g/

g)

XYLENE

BUTYL ACETATE

ISOPROPYL ALCOHOL

METHANOL

1.2

1.0

0.8

0.6

0.4

0.2

0.0

CONC (vppm)

AD

SO

RP

TIO

N C

AP

AC

ITY

(g/

g)

METHYL ETHYL KETONE

ACETONE

1.2

1.0

0.8

0.6

0.4

0.2

0.0

CONC (vppm)

AD

SO

RP

TIO

N C

AP

AC

ITY

(g/

g)

TOLUENE

1.2

1.0

0.8

0.6

0.4

0.2

0.0

CONC (vppm)

AD

SO

RP

TIO

N C

AP

AC

ITY

(g/

g)

0 5000 10000 15000 20000 25000

0 5000 10000 15000 20000 250000 5000 10000 15000 20000 25000

0 20 40 60 80 100

Air Velocity (ft/min)

Pre

ssur

e D

rop

(in

H2O

/ft B

ed D

epth

)

24

18

12

6

0

Figure 1. Air pressure drop Figure 2. Moisture uptake for V503and activated carbon