double displacement (or replacement) reactions also referred to as metathesis reaction the two...
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Double Displacement (or Replacement) Reactions
• Also referred to as metathesis reaction The two compounds exchange ions to produce two
new compounds. It is easier to simply remember that the cations (+ ions) exchange anions (- ions).
AB + CD CB + ADNOTE: always write the cation first then the anion.• Many reactions including precipitation and
neutralization use the double displacement mechanism.
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pp. 220, 223
Double Displacement (or Replacement)
Reactions
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Fig. 8-18, p. 221
NaCl(aq) + AgNO3(aq) → NaNO3(aq) + AgCl(s)
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Double Displacement (or Replacement) Reactions
• PREDICT THE PRODUCT & BALANCE
1. MgSO4 + LiOH ___________
2. Pb(NO3)2 + Na2CO3 ____________
3. HNO3 + Ba(OH)2 ___________
Answers are on the next slide.
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Double Displacement (or Replacement) Reactions
• ANSWERS
1. MgSO4 + 2 LiOH Mg(OH)2 + Li2SO4
2. Pb(NO3)2 + Na2CO3 PbCO3 + 2 NaNO3
3. 2 HNO3 + Ba(OH)2 Ba(NO3)2 + 2 H2O
Exchange cations
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PRECIPITATION REACTIONPRECIPITATION REACTIONA reaction where an insoluble solid is formed during a
reaction between two aqueous solutions.
(aq) (aq) + + (aq)(aq) (aq)(aq) + + (s)(s)
2KI(aq) + Pb(NO3)2(aq) 2KNO3(aq) + PbI2(s)
NEUTRALIZATION REACTIONNEUTRALIZATION REACTIONA reaction between an acid and a base which results in the
production of a salt and water.
HA + BOH (metal/nonmetal) + H2O
HNO3(aq) + KOH(aq) KNO3(aq) + H2O(l)
Exchange cationsExchange cations
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Table 9-3, p. 252
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Fig. 9-13, p. 253
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Single Displacement (or Replacement) Reactions
One element reacts with a compound to produce a different element and a new compound.
A + BC AC + B• NOTE: if the element is a metal, it will replace the cation.
A + BC C + BA• NOTE: if the element is a nonmetal, it will replace the anion.
Many reduction-oxidation reactions use the single displacement mechanism.
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pp. 218, 220
Single Displacement (or Replacement)
Reactions
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Fig. 8-15, p. 218
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Single Displacement (or Replacement) Reactions
PREDICT THE PRODUCT
1. Ca + HCl
2. ZnBr2 + I2
3. Cu + AgNO3
Answers are on the next slide.
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Single Displacement (or Replacement) Reactions
ANSWERS:
1. Ca + 2 HCl CaCl2 + H2
2. ZnBr2 + I2 ZnI2 + Br2
3. Cu + 2AgNO3 2Ag + Cu(NO3)2
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Fig. 9-9, p. 245
A reaction occurs when a piece of zinc is dipped into a solution of copper (II) nitrate. Write the conventional (molecular), ionic and net ionic equations.
Single-Replacement Redox Reactions
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• Conventional (Molecular) Equation
Zn(s) + Cu(NO3)2 (aq) → Zn(NO3)2(aq) + Cu(s)
• Ionic EquationZn(s) + Cu+2
(aq) + NO3- (aq) → Zn+2
(aq) + NO3- (aq) + Cu(s)
• Net Ionic EquationZn(s) + Cu+2
(aq) → Zn+2(aq) + Cu(s)
Single-Replacement Redox Reactions
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Table 9-2, p. 245
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• What happens if we place a piece of copper metal into a solution of zinc nitrate?
• Evidence shows that copper is below zinc on the Activity Series, therefore copper will not replace zinc and no reaction occurs.
• Cu(s) + Zn(NO3)2(aq) → NR
Single-Replacement Redox Reactions
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ReductionReduction--OxidationOxidation Reactions ReactionsA reaction in which electrons are transferred from one A reaction in which electrons are transferred from one
species to anotherspecies to another..
• Oxidation means the loss of electrons
• Reduction means the gain of electrons
Rusting is a redox reaction:
4Fe (s) + 3O2 (g) 2Fe2O3 (s)
As a reactant Fe has a zero oxidation state but as a product (in Fe2O3) iron has a 3+ oxidation state. Three electrons per atom had to be transferred (lost) in order for this to happen. Note that oxygen also changed from a zero oxidation state to a 2- oxidation state. Oxygen needed to gain 2 electrons per atom.
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ReductionReduction--OxidationOxidation Reactions Reactions• Oxidation means the loss of electrons
• Reduction means the gain of electrons
Electrochemistry involves redox Rx.Cu(s) + 2AgNO3(aq) 2Ag(s) + Cu(NO3)2(aq)
The reactant Cu has a zero oxidation state (all elements have a zero oxidation state) but as a product, in Cu(NO3)2,the copper atom loses two electrons and has a 2+ oxidation state. The other atom which acquired the electrons donated by copper is silver. As a reactant silver has a 1+ oxidation state then by gaining electrons from copper, the ions are turned into elemental silver with a zero oxidation state.
The net effect of this reaction has metallic copper being The net effect of this reaction has metallic copper being oxidizedoxidized to to copper ions and silver ions being copper ions and silver ions being reduced reduced to silver metalto silver metal.
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Fig. 16-2, p. 459
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COMBINATION REACTIONCOMBINATION REACTIONA reaction in which two or more substances
combine to form a single product.
A +B + CA +B + C ABC ABC
CaO(s) + SOCaO(s) + SO22(g) (g) CaSO CaSO33(s)(s)
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Fig. 8-11, p. 214
C (s) + O2 (g) → CO2 (g)
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DECOMPOSITION REACTIONDECOMPOSITION REACTIONA reaction in which a single compound reacts to
give two or more substances, usually requiring a raise in temperature.
ABCABC A + B + C A + B + C
2KClO2KClO33(s) (s) 2KCl(s) + 3O 2KCl(s) + 3O22(g)(g)
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Fig. 8-13, p. 215
2H2O(l) → 2H2(g) + O2(g)
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COMBUSTION REACTIONCOMBUSTION REACTIONA reaction of a substance with oxygen, usually the rapid
release of heat produces a flame.
CH + OCH + O22 CO CO22 + H + H22OO
2C4H10(g) + 13O2(g) 8CO2(g) + 10H2O(g)
(hint: balance the C’s first, followed by the H then the O’s)
Many times in a combustion reaction, heat energy is given off. In chemical terms this is called an exothermic reaction. Thermochemistry is field of chemistry which studies the transfer of heat in a reaction.
The thermodynamic equation representing this exothermic reaction is:
2C4H10(g) + 13O2(g) 8CO2(g) + 10H2O(g) + heat (in Joules)
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GAS FORMATION REACTIONSGAS FORMATION REACTIONS• A reaction that produces a gas from reactants
not in the gaseous state. 2 HCl (aq) + ZnS (s) ZnCl2 (aq) + H2S (g)
Zn (s) + 2 HCl (aq) ZnCl2 (aq) + H2 (g)
• Many gas formation reactions involve two steps, first the double displacement reaction then the decomposition reaction of an unstable substance.
NaNa22COCO33 + 2HCl + 2HCl 2 NaCl + H 2 NaCl + H22COCO33
HH22COCO3 3 CO CO22 + H + H22OO
• Besides carbonic acid (H2CO3), sulfurous acid (H2SO3) also decomposes into SO2 and water.
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COMMON GAS FORMATION COMMON GAS FORMATION REACTIONS YOU SHOULD REMEMBERREACTIONS YOU SHOULD REMEMBER
• NH4OH → NH3 (g) + H2O (l)
• H2CO3 → CO2 (g) + H2O (l)
• H2SO3 → SO2 (g) + H2O (l)
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Table 8-3, p. 223
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GROUP STUDY PROBLEM # 17aGROUP STUDY PROBLEM # 17aWrite the following as balanced chemical equations then classify each reactionWrite the following as balanced chemical equations then classify each reaction ..
1. Solid mercuric oxide decomposes at high temperatures to form metallic mercury and oxygen.
2. Aqueous lead(II) nitrate reacts with aqueous magnesium bromide to produce the insoluble salt lead(II)bromide and soluble magnesium nitrate.
3. At room temperature, aqueous ammonium carbonate is added to hydrochloric acid to produce aqueous ammonium chloride, water and carbon dioxide.
4. Hydrochloric acid is poured over tin metal producing hydrogen gas and tin (IV) chloride.
5. The combustion of ethanol, C2H5OH, results in the production of carbon dioxide and water.
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PRACTICE PROBLEMS # 17aPRACTICE PROBLEMS # 17aWrite the following as balanced chemical equations then classify each reactionWrite the following as balanced chemical equations then classify each reaction ..
1. Magnesium metal is combined with nitrogen at elevated temperatures to form magnesium nitride powder.
2. An aqueous solution of soluble aluminum nitrate is mixed with aqueous sodium hydroxide to produce insoluble aluminum hydroxide and a sodium nitrate solution.
3. Solid potassium sulfite is added to hydrochloric acid to produce sulfur dioxide, water, and potassium chloride.
4. Acetic acid reacts with calcium hydroxide to produce calcium acetate and water.
5. Lithium metal is dropped in water to produce lithium hydroxide and hydrogen gas.
3 Mg (s) + N2 (g) Mg3N2 (s); combination, redox
Al(NO3)3 (aq) + 3NaOH (aq) Al(OH)3(s) + 3NaNO3(aq) ; ppt, DD
K2SO3 (s) + 2HCl (aq) H2SO3 (aq) + 2KCl (aq) ; DD then
H2SO3 (aq) H2O (l) + SO2 (g) ; decomposition
overall Rx : K2SO3 (s) + 2HCl (aq) H2O (l) + SO2 (g) + 2KCl (aq)
2 HC2H3O2 (aq) + Ca(OH)2 (aq) Ca(C2H3O2)2 (aq) + 2H2O (l) ; DD, neutralization
2Li (s) + 2H2O(l) 2LiOH (aq) + H2 (g); SD, redox
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GROUP STUDY PROBLEM # 17bGROUP STUDY PROBLEM # 17bPREDICT THE PRODUCT THEN WRITE A BALANCED EQUATION FOR EACH REACTIONSPREDICT THE PRODUCT THEN WRITE A BALANCED EQUATION FOR EACH REACTIONS ..
1. The reaction between lead (II) acetate and ammonium carbonate solutions results in the formation of a white solid.
2. An zinc metal wire is dipped in hydrobromic acid.
3. The decomposition of sulfurous acid.
4. Sodium hydroxide solution is added to sulfuric acid.
5. Solid tin(II) sulfide is added to hydroiodic acid.
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PRACTICE PROBLEMS # 17bPRACTICE PROBLEMS # 17bPREDICT THE PRODUCT THEN WRITE A BALANCED EQUATION FOR EACH REACTIONSPREDICT THE PRODUCT THEN WRITE A BALANCED EQUATION FOR EACH REACTIONS ..
1. Cadmium (II) iodide solution is added to aqueous potassium phosphate.
2. Magnesium hydroxide solution is mixed with phosphoric acid.
3. The decomposition of carbonic acid.
4. The combustion of methanol, CH3OH.
5. Solid cadmium reacts with a copper(II) sulfate solution.
3 CdI2 (aq) + 2 K3PO4 (aq) Cd3(PO4)2 (s) + 6 KI (aq)
3 Mg(OH)2 (aq) + 2 H3PO4 (aq) Mg3(PO4)2 (aq) + 6 H2O (l)
H2CO3 (aq) CO2 (g) + H2O (l)
2 CH3OH (l) + 3 O2 (g) 2 CO2 (g) + 4 H2O (l)
Cd (s) + CuSO4 (aq) Cu (s) + CdSO4 (aq)