distill_(alpha,heat).xlsx

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  • 8/14/2019 Distill_(alpha,heat).xlsx

    1/1

    Distillation using the Ponchon-Savarit method with alphaby Mark Burns and James Sung

    Department of Chemical Engineering at the University of Michigan

    D = 41.18 mol/hr

    Example from Geankoplis, Xd = 0.95

    1993, p. 674

    R = 1.755

    F = 100 mol/hr alpha = 2.5

    q = 1.195

    Xf = 0.45 E(ML) = 1

    W = 58.82 mol/hr

    Xw = 0.1

    = 11

    Qr = 4138403.7 J/hr Minimum Reflux = 1.16

    Saturated Qc = -3510493.9 J/hr

    Liquid Vapor

    5109 HB = 38439 J/mol Ponchon-Savarit Diagram >>>>>>>

    0 HA = 30820 J/mol

    Graphical Representation of Successive Substitution McCabe-Thiele Plot Ponchon-Savarit Plot

    Distillate41.18 mol/hr

    0.95 Desired Xd

    Tray x y

    Enriching Line Sat. Liquid line

    1 0.88372 0.95 y = 0.637 0.345 h = -5109 x +5109.000

    2 0.79762 0.90786

    3 0.69951 0.85337 Sat. Vapor line

    4 0.60308 0.79160 Stripping Line H = -7619 x +38439.000

    5 0.52114 0.73124 y = 1.442 -0.044

    6 0.45970 0.68021 Point D'

    7 0.39707 0.62213 x = 0.95

    Feed 8 0.31272 0.53216 q line H' = 85510.3

    100 mol/hr 9 0.21777 0.41038 y = 6.128 -2.308

    0.45 Xf 10 0 .13026 0.27242

    x = Point W'hF 11 0 .06326 0.14444 x = 0.1

    -3469.1475 12 - done Intersection (q,enriching) h' = -65754.8

    13 - - x = 0.483

    14 - - y = 0.653 Switching point

    15 - - x = 0.484299

    R = 1.755 16 - - Intersection (q,equilibrium)

    alpha = 2.5 17 - - x = 0.492

    q = 1.195 18 - - y = 0.708

    E(ML) = 1 19 - -

    # of Stages 11 20 - -

    Min. reflux 1.16 Bottoms

    Qc -3510493.926 58.82 mol/hr

    Qr 4138403.676 0.1 Desired Xw

    Points for use on McCabe-Thiele (X-Y) plot - Only one decimal place used for the sake of clarity

    x 45 Degree line Equilibrium line Stripping line Enriching line q line Distillation(MT) op equil

    0.0 0.0 0.0 0.0 0.0

    0.1 0.1 0.2 0.0 0.0

    0.2 0.2 0.4 0.0 0.0

    0.3 0.3 0.5 0.0 0.0

    0.4 0.4 0.6 0.0 0.0

    0.5 0.5 0.7 0.0 0.0

    0.6 0.6 0.8 0.0 0.0

    0.7 0.7 0.9 0.0 0.0

    0.8 0.8 0.9 0.0 0.0

    0.9 0.9 1.0 0.0 0.0

    1.0 1.0 1.0 0.0 0.0

    0.5 0.7 0.0 0.0

    0.1 0.1 0.0 0.0

    0.5 0.7 0.0 0.0

    1.0 1.0 0.0 0.0

    0.5 0.5 0.0 0.0

    0.5 0.7 0.0 0.0

    0.0 0.0

    0.1 0.1

    0.1 0.1

    0.1 0.1

    0.1 0.3

    0.2 0.3

    0.2 0.4

    0.3 0.4

    0.3 0.5

    0.4 0.5

    0.4 0.6

    0.5 0.6

    0.5 0.7

    0.5 0.7

    0.5 0.7

    0.6 0.7

    0.6 0.8

    0.7 0.8

    0.7 0.9

    0.8 0.9

    0.8 0.9

    0.9 0.9

    0.9 1.0

    1.0 1.0

    0.0

    0.2

    0.4

    0.6

    0.8

    1.0

    1.2

    0.0 2.0

    AxisTitle

    Axis Title

    -80000.0

    -60000.0

    -40000.0

    -20000.0

    0.0

    20000.0

    40000.0

    60000.0

    80000.0

    100000.0

    0.0 0.5 1.0 1.5

    Horh

    Y or X