discussion on boltzmann constant
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7/25/2019 Discussion on Boltzmann Constant
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Discussion on Boltzmann Constant
Boltzmann constant denoted by KBis a physical constant relating energy at the individual
particle level with temperature. Its proportionality constant in between energy of particle and
temperature. It is sometimes referred as a bridge between macroscopic and microscopic
physics.
Macroscopically, the ideal gas law states that, for an ideal gas, the product of pressure p and
volume V is proportional to the product of amount of substance n in moles! and absolute
temperature " by
pV=nRT
#here $ is gas constant %.&'(()*'+! -K'mol'!.
Introducing the Boltzmann constant transforms the ideal gas law into an alternative form
pV=NKT
#here / is the number of molecules of gas. 0or n 1 ' mol, / is e2ual to the number of
particles in one mole i.e. 3vogadros number
4ince KBis proportionality constant its value depend on unit system opted. 0or MK4 system
KBis1.38 E23 -K5'