detailed sedimentology and inorganic geochemistry of the

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Detailed Sedimentology and Inorganic Geochemistry of the Dolgeville Formation and Utica Group of the Central Mohawk Valley, NY Daniel Miserendino Jeffrey T. Pietras

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Page 1: Detailed Sedimentology and Inorganic Geochemistry of the

Detailed Sedimentology and Inorganic Geochemistry of the Dolgeville Formation and Utica

Group of the Central Mohawk Valley, NY

Daniel Miserendino

Jeffrey T. Pietras

Page 2: Detailed Sedimentology and Inorganic Geochemistry of the

Introduction and Purpose

• Drill cores present continuous, unweathered rock record ideal for detailed sedimentologic and geochemical studies

• Utica Group (Indian Castle Shale and Flat Creek Shale)

• Trenton Group (Dolgeville Fm.) • Study the evolution of Ordovician foreland basin

by investigating: • Source terrain • Seawater chemistry • Sea level changes • Depositional processes • Tectonic processes

Page 3: Detailed Sedimentology and Inorganic Geochemistry of the

Geologic Setting

http://www.mcz.harvard.edu/Departments/InvertPaleo/Trenton/

Early Ordovician: Passive margin off southwest Laurentia formed.

Mid-Late Ordovician: Carbonate platform developed. Onset of Taconic Orogeny.

Page 4: Detailed Sedimentology and Inorganic Geochemistry of the

Study Area N

150 km

Legend: Core Location Major city

N

30 km

75NY-5

75NY-7

74NY-5 75NY-2 Mohawk River

Page 5: Detailed Sedimentology and Inorganic Geochemistry of the

Stratigraphy

modified from Brett and Baird, 2002

Page 6: Detailed Sedimentology and Inorganic Geochemistry of the

Stratigraphy -This Study

-Spiegel, expected 2016

-Jones, 2013

-Saboda and Lash, 2014

modified from Brett and Baird, 2002

Page 7: Detailed Sedimentology and Inorganic Geochemistry of the

0

100

200

300

400

500

600

700

De

pth

(ft

)

Indian Castle Shale

Lower Indian Castle Shale

Upper Indian Castle Shale

Honey Hill Disconformity

Flat Creek Shale

Dolgeville Fm.

Dolgeville Fm.

Thruway Disconformity

75NY-7 74NY-5

Wintergreen Park Interval

75NY-7

Collected near Honey Hill Rd, Newport, NY

Trenton Group Limestone

25 km

E. Spiegel

74NY-5 0.5 mm

G. Baird

Page 8: Detailed Sedimentology and Inorganic Geochemistry of the

Dolgeville Formation Interbedded limestone and black mudstone

Interpretation: • Alternating

turbidites and low energy, pelagic mud deposition

Near County Home, NY Core 75NY-7

.5 f

t E. Spiegel E. Spiegel

Page 9: Detailed Sedimentology and Inorganic Geochemistry of the

Utica Group

Dino-Lite Edge Digital Microscope

Black mudstone

Interpretation: • Low energy • Pelagic • Organic matter accumulation and pyrite

Page 10: Detailed Sedimentology and Inorganic Geochemistry of the

Banded black mudstone

Interpretation: • Thin turbidites • Change in pelagic sediment

Page 11: Detailed Sedimentology and Inorganic Geochemistry of the

Graded gray calcareous silty mudstone

1 in

Fining upwards

5 mm

Interpretation: • Turbidites

Black mudstone

Fining upwards

Black mudstone

74NY-5 75NY-7

Page 12: Detailed Sedimentology and Inorganic Geochemistry of the

Cross-stratified calcareous silty mudstone

5 mm 5 mm

Interpretation: • Turbidites • Contourites

Page 13: Detailed Sedimentology and Inorganic Geochemistry of the

Dark gray silty mudstone

Interpretation: • Increased silt and sand input • More siliciclastic input, less carbonates

Page 14: Detailed Sedimentology and Inorganic Geochemistry of the

Matrix supported sandy mudstone

1 in

Stratigraphic up

75NY-7

Interpretation: • Debrite

Page 15: Detailed Sedimentology and Inorganic Geochemistry of the

Facies Summary:

Indian Castle Shale

Flat Creek Shale

Dolgeville Fm.

75NY-7

74NY-5

Wintergreen Park Interval

Lower Indian Castle Shale

Upper Indian Castle Shale

Dolgeville Fm.

Trenton Group Limestone

• Cross-stratified calcareous silty mudstone •Graded gray calcareous silty mudstone • Black mudstone

• Black mudstone •Banded black mudstone •Graded gray calcareous silty mudstone • Cross-stratified calcareous silty mudstone •Matrix supported sandy mudstone

•Black mudstone • Banded black mudstone •Graded gray calcareous silty mudstone •Dark gray silty mudstone •Matrix supported sandy mudstone

• Black mudstone • Banded black mudstone

15

0 f

t

Page 16: Detailed Sedimentology and Inorganic Geochemistry of the

Depositional Summary:

Indian Castle Shale

Flat Creek Shale

Dolgeville Fm.

75NY-7

74NY-5

Wintergreen Park Interval

Lower Indian Castle Shale

Upper Indian Castle Shale

Dolgeville Fm.

Trenton Group Limestone

• Turbidites • Pelagic

• Pelagic • Turbidites (calcareous) •Debrites

• Pelagic

• Pelagic • Turbidites (calcareous, siliciclastic) •Debrites

15

0 f

t

Page 17: Detailed Sedimentology and Inorganic Geochemistry of the

XRF and Rock Hardness Settings Mg to Mn Fe to Mo

kV 15 40

µA 25 30

Other Helium Yellow Filter

Measured elements: Mg, Al, Si, P, S, K, Ca, Ba, Ti, V, Cr, Mn, Fe, Co, Ni, Cu, Zn, Ga, As, Pb, Se, Th, Rb, U, Sr, Y, Zr, Nb, Mo

Leeb’s Hardness: Indentation hardness measures resistance to material deformation

Bruker Tracer III pXRF

Proceq Equotip Piccolo 2

3900 samples

2800 samples

Page 18: Detailed Sedimentology and Inorganic Geochemistry of the

200

300

400

500

600

700

800

0 1 2 3 4 5 6

Lee

b's

Har

dn

ess

Al (wt %)

Leeb’s Hardness Crossplots

0

100

200

300

400

500

600

700

800

0 10 20 30 40 50

Lee

b's

Har

dn

ess

Ca (wt%)

Similar trend for K, Th, and Si

Soft= Clay Hard= Carbonate

Page 19: Detailed Sedimentology and Inorganic Geochemistry of the

Honey Hill Disconformity (96 ft)

Page 20: Detailed Sedimentology and Inorganic Geochemistry of the
Page 21: Detailed Sedimentology and Inorganic Geochemistry of the
Page 22: Detailed Sedimentology and Inorganic Geochemistry of the

Summary and Future Work

• Sub-centimeter lithologic description of the entire Utica Group in NY has revealed a variety of unique facies

• Pelagic deposition, turbidity currents, debris flows and possible contour currents contributed to deposition of the Utica Group and Dolgeville Fm

• Chemostratigraphy at 3-inch intervals may help elucidate cryptic, chronostratigraphic horizons such as the lower and upper Indian Castle Shale contact

• Leeb’s Hardness values have a negative correlation with Al, K, Th, and Si (clay mineral rich softer), and a positive correlation with Ca (carbonate beds harder)

Future Work: • Build stratigraphic columns to compare to XRF and hardness data • Millimeter-scale XRF analysis with core scanning table • Correlate litho- and chemostratigraphy to other cores • Investigate patterns and cyclicity in XRF data (Fourier Analysis)

Page 23: Detailed Sedimentology and Inorganic Geochemistry of the

Thank You Special thanks to:

Sigma Alpha Mu Foundation, for funding part of this research

Brian Slater and the NYS Museum, for helping us move cores to Binghamton

Gordon C. Baird, for general discussions and donating hand samples

Proceq, for letting us borrow the Equotip Piccolo 2 for rock hardness testing