department of experimental physics, comenius university bratislava, slovakia formation of positive...
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![Page 1: Department of Experimental Physics, Comenius University Bratislava, Slovakia Formation of positive ions by electron impact: Temperature effects Š. Matejčík](https://reader038.vdocuments.us/reader038/viewer/2022110101/56649edd5503460f94bee0f5/html5/thumbnails/1.jpg)
Department of Experimental Physics, Department of Experimental Physics, Comenius University BratislavaComenius University Bratislava, , SlovakiaSlovakia
Formation of positive ions by electron impact:Formation of positive ions by electron impact:Temperature effectsTemperature effects
Š. MatejčíkŠ. Matejčík
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Department of Experimental PhysicsDepartment of Experimental Physics
Division of plasma physicsDivision of plasma physics • llow temperature plasma ow temperature plasma technological plasmas, glow discharges ...
• high pressure discharges high pressure discharges corona discharge, barrier discharge ...
• reactions in the plasma reactions in the plasma electron impact ionization, electron attachment to the molecules ...
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• Electron Electron interinteractionactionss
• Photon induced reactionsPhoton induced reactions
• Ion –Ion – molecule reactions molecule reactions
• Neutral reaction Neutral reaction
• Reactions on the surfacesReactions on the surfaces
Reactions in plasmaReactions in plasma
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• Electron impact ionization Electron impact ionization
• Electron attachmentElectron attachment
• Excitation Excitation
• DissociationDissociation
• Electron reaction on the surfaces Electron reaction on the surfaces
Electron interactionsElectron interactions in plasma in plasma
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Comenius universityComenius university
• Electron attachment Electron attachment
• Electron impact ionizationElectron impact ionization
• Electron Electron inducedinduced reactions on surfaces reactions on surfaces
PreparationPreparation
• Electron impact excitationElectron impact excitation
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Electron impact ionization:Electron impact ionization:e + AB → AB+ + 2e
Dissociative electron impact ionization:Dissociative electron impact ionization:e + AB → A+ + B + 2e
Ion pair formation:Ion pair formation:e + AB → A+ + B- + e
Fusion related researchFusion related research
Molecules:Molecules:CHCH44, CH, CH33D, CDD, CD44, C, C22HH66, C, C33HH88
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We have studiedWe have studied
- appearance energies (AE) of the positive ionsappearance energies (AE) of the positive ions
- gas temperature effects on the AEgas temperature effects on the AE
- isotopic effects on AEisotopic effects on AE
Theory:Theory:
Ionization energies (OVGF, CCSD(T))Ionization energies (OVGF, CCSD(T))
Appearance energies (G3, G3B3 and CBS-APNO, CBS-Q)Appearance energies (G3, G3B3 and CBS-APNO, CBS-Q)
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Experimental setup:Experimental setup:
E = 0 – 150 eVE = 0 – 150 eVFWHM ~FWHM ~50-50-140 meV140 meVIe~Ie~20-20-100nA100nA
T = 293KT = 293K 693K693K
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low Tghigh Tg
Electron impact ionizationElectron impact ionization
E
σ
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low Tg
Rate coefficientRate coefficient
E
σ
dETEfTEETT ewe ),(),(),(0
f(E,Te)high Tg
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A
A+
IE
En
erg
y
Q
M+
M
VIE
AIEAE
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En
erg
y
Q
M+
M
AE1
AE2
E
f
ΔAE = AE2-AE1=
= Ei(T2)-Ei(T1)
Ei(T)=Ev(T)+Er(T)
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σ
E
Sensitivity in present experiment:
σ ~10-26 - 10-25 m2
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23,5 24,0 24,5 25,0 25,5
0
100
200
300
400
500
He+/Hed=1.127±0.005
Ion
yiel
d (a
rb.
units
)
E (eV)
Problem of thresholdProblem of threshold energy energy estimation estimation
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Atoms:
Wannier theory:
w(E,AE,A,d) = 0 E<AE A(E-IE)d E>AEd=1.127
Threshold behaviour of the cross sections for EIIThreshold behaviour of the cross sections for EII
dEUEfAdAEEAdAEEI w ),(),,,(),,,(0
f(E,U) - EEDF
Fitting function:
w(E,AE,A,d)
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23,5 24,0 24,5 25,0 25,5
0
100
200
300
400
500
He+/He
Ion
yiel
d (a
rb.
units
)
E (eV)
d=1.127±0.01
Threshold behaviour of the cross sectionsThreshold behaviour of the cross sections
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Molecules - empirical formula:
w(E,AE1,AE2,d1,d2A) = 0 E<AE1
A(E-AE1)d1 E>AE1
Threshold behaviour of the cross sections for EIIThreshold behaviour of the cross sections for EII
dEUEfAddAEAEEAddAEAEEI w ),(),2,1,,,(),2,1,,,(0
2121
A(E-AE2)d2 + A(E-AE1)d1 E>AE2
...
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Temperature effects on Appearance energies of Temperature effects on Appearance energies of the ionsthe ions
P. Plessis et al., Can. J. Chem. 65 (1987) 1424, J. Phys. B, 16 (1983) 1770
H. M. Rosenstock, Int. J. Mass Spectr. Ion Phys., 20 (1976)139
Predicted by:Predicted by:
Rosenstock – review article Rosenstock – review article
PlessisPlessis && Marmet – in CHMarmet – in CH44 and C and C22HH66 papers papers
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CHCH44
e + CHe + CH44 → CH→ CH44++ + 2e + 2e
CHCH33++ + H + 2e + H + 2e
CHCH33++ + H + H-- + 2e + 2e
CHCH22++ + H + H22 + 2e + 2e
CHCH++ + H + H22 + + H H + + 2e2e
CC++ + + 22HH22 + 2e + 2e......
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12,0 12,2 12,4 12,6 12,8 13,0 13,2 13,4
0
20
40
60
80
100Io
n y
ield
(a
rb. u
nits
)
Electron energy (eV)
293K
12,0 12,2 12,4 12,6 12,8 13,0 13,2 13,4
0
20
40
60
80
100Io
n y
ield
(a
rb. u
nits
)
Electron energy (eV)
CHCH44++/CH/CH44
693K
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Experiment AE (eV)
T=293 K
AE (eV)
T=693 K
ΔAE
(eV)
Plessis et al. AE(eV)
T=293 K
CH4+/CH4 12.650.04 12.510.04 0.14 12.62 0.02
CH3+/CH4 13.580.1
14.340.1
13.450.1
14.200.1
0.14 - - -
14.01 0.08
EEii(T) - rotational and vibrational energy of the molecule at T(T) - rotational and vibrational energy of the molecule at T
EEii =E =Eii(693) – E(693) – Eii(293 K) ~ (293 K) ~ 0.12 eV0.12 eV
Stano et al., J. Phys. B: At. Mol. Opt. Phys. , 36 (2003) 261
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CHCH33++/CH/CH44
13,0 13,5 14,0 14,5 15,0
0
20
40
60
80
100
120
140
Ion
yie
ld (
arb
. un
its)
Electron energy (eV)
13,0 13,5 14,0 14,5 15,0
0
20
40
60
80
100
120
140
Ion
yie
ld (
arb
. un
its)
Electron energy (eV)
693K
293K
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CHCH33DD++/CH/CH33DD
12,0 12,5 13,0
0,0
0,6
1,2
1,8Io
n si
gnal
(ar
b. u
nits
)
Electron energy (eV)
AE1=12.75 eVAE1=12.62 eV
293K
693K
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e+CH3D→ AE(293K) AE(693K) D(AE(693K)-AE(293K))
(CH3D)+ 12.75 ± 0.03 12.58 ± 0.05 0.17 ± 0.07
(CH2D)+ + H–
(CH2D)+ + H
13.66 ± 0.0714.42 ± 0.05
13.49 ± 0.0714.25 ± 0.05
0.17 ± 0.10.17 ± 0.06
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CC22HH66++/C/C22HH66
11,0 11,5 12,0 12,5-0,2
0,0
0,2
0,4
0,6
0,8
1,0
1,2
1,4
1,6
1,8
2,0Io
n y
ield
(a
rb. u
nits
)
Electron energies (eV)
11,0 11,5 12,0 12,5-0,2
0,0
0,2
0,4
0,6
0,8
1,0
1,2
1,4
1,6
1,8
2,0Io
n y
ield
(a
rb. u
nits
)
Electron energies (eV)
693K
293K
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e + C2H6 Experiment Theory
AE [eV]293 K
Thermochemistry[eV]
G3B3AIE [eV]
C2H6+ 11.46±0.04 11.55
C2H5+ + H-
C2H5+ + H
12.06±0.0612.7±0.1
11.7212.47±0.03
12.0312.79
C2H4+ + H2 11.90±0.04 11.92±0.0006 11.93
C2H3+ + H + H2 15.02±0.1 14.47±0.46 14.83
C2H2++2H2 15.02±0.1 14.61±0.01 14.61
C2H++2H2+H
C2H++H2+3H 25.7±0.3
20.5±0.1525.1±0.15
21.6526.12
C2+ + 3H2 22.6±0.3 20.95±0.3 21.73
CC22HH66
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9,5 10,0 10,5 11,0 11,5
0,0
0,2
0,4
0,6
0,8
1,0
Ion
yie
ld (
arb
. un
its)
Electron energy (eV)
9,5 10,0 10,5 11,0 11,5
0,0
0,2
0,4
0,6
0,8
1,0
Ion
yie
ld (
arb
. un
its)
Electron energy (eV)
CC33HH88++/C/C33HH88
693K
293K
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Molecule ΔAE (eV)
Exp.
ΔAE (eV)
Theory
CH4 0.12-0.14 0.12
CH3D 0.12-0.17 0.13
CD4 0.16-0.20 0.15
C2H6 0.19-0.3 0.31
C3H8 0.21-0.42 0.46
SummarySummary
Temperatures 293 and 693 K
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En
erg
y
Q
M+
M
Isotopic effect on AEIsotopic effect on AE
Changes in vibrational energies in Changes in vibrational energies in isotopomers isotopomers
Heavy isotopomer – lower zero point Heavy isotopomer – lower zero point eenergy nergy ==> larger AE> larger AE
Comparison:Comparison:CHCH44, CD, CD44, CH, CH33DD
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CH3D
AE (eV)293 K
CD4
AE (eV)293 K
CH4
AE (eV)293 K
CH3D+ 12.75 ± 0.03 12.89 ± 0.03 12.65 ± 0.04 CH4
+
CH2D+ + H–
CH2D+ + H
13.66 ± 0.07 14.42 ± 0.05
- 14.54 ± 0.05
13.58 ± 0.1 14.34 ± 0.1
CH3+ + H–
CH3+ + H
IIssotopic effect on AEotopic effect on AE
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PresentmeV
a)meV
b)meV
(CH3D)+/CH3D 100 50
(CH2D)+/CH3D 80
(CH3)+/CH3D 200
(CHD)+/CH3D 110
(CD4)+/CD4 190 170 160
(CD3)+/CD4 200 130
(CD2)+/CD4 310 90
a) F. P. Lossing, A. W. Tickner, W. A. Bryce, J. Chem. Phys. 19, 1254 (1951).b) V. H. Dibeler, M. Krauss, R. M. Reese, F. N. Harlee J. Chem. Phys. 42, 3791 (1965).
Isotopic shiftIsotopic shift
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ConclusionsConclusions
experimentally observed dependence of AE´s on the experimentally observed dependence of AE´s on the temperaturetemperature
magnitude of the shift magnitude of the shift ~~ vibrational and rotational vibrational and rotational excitation of the moleculeexcitation of the molecule
confirmed isotopic shift in the appearance energies of confirmed isotopic shift in the appearance energies of the moleculesthe molecules
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Contribution to new CRPContribution to new CRP
Experiment:Experiment:The temperature effects:-estimation of the partial cross sections in C3H8 for particular
fragment ions- evaluation of the rate coefficients
Theory - QM:Theory - QM:- BenHm - electronic structure, binding energies, volatility, ionization
potentials and electron affinities - H2 reactions with Ben
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CoworkersCoworkers Comenius University BratislavaComenius University BratislavaM. Stano, E. Vašeková, J.D. Skalný, D. Kubala,M. Stano, E. Vašeková, J.D. Skalný, D. Kubala, J. Kočíšek J. Kočíšek
TheoristTheorists:s: I. Hubac, I. Hubac, J. Urban, P. MachJ. Urban, P. Mach
S. Denifl, T.D. MärkS. Denifl, T.D. MärkUniversity InnsbruckUniversity Innsbruck
SupportSupportVW StiftungVW Stiftung, , EU (Euroatom-FUSION)EU (Euroatom-FUSION),, IAEA IAEA, APVT, APVT