cover me - daeraappsd.daera-ni.gov.uk/ipri/docs/p0052-04a lafarge ireland limited … · 4" bsp ea...

ISO/IEC 17025 Accredited Legal Entity, UKAS Accredited Testing Laboratory No. 4279Exova (UK) Ltd trading as Exova Catalyst & Exova Catalyst Ireland

Unit C5, Emery Court, The Embankment Business Park, Stockport, SK4 3GL

PPC Permit: P0052/04A/V6

Stack Reference

Lafarge Ireland LtdCookstown Works29 Sandholes Road

CookstownBT80 9AR

Primary Site Contact: Jim Buchanan

Installation Name & Address

EN 14181 AST Report Commissioned by

A8 - Kiln Exhaust Main Stack (Duty Analyser)

Lafarge Ireland Ltd

Exova Catalyst, 70 Montrose Avenue, Hillington Park, Glasgow, G52 4LAYour Exova Catalyst Contact: John Healey (07826 916 681)

E: [email protected]

Report Approved by

15th - 16th May 2018

Job Reference NumberCEK-2909

Report Written by

COVER ME

Signature of Report Approver

Version 1Report Version

John Healey

29th May 2018Report Date

TE1 TE2 TE3 TE4MM 03 476

MCERTS Level 2

Dates of the Monitoring Campaign

Regional Manager

Deputy Regional Manager

TE1 TE2 TE3 TE4MM 04 492

MCERTS Level 2

Iain Wilkie

CAT-14181 (Version X)CEK-2909 Lafarge Ireland Ltd (Cookstown) - A8 Kiln Exhaust Main Stack - AST (Duty Analyser)

SECTION 1A: TITLE PAGE

CONTENTS 2

SECTIONS 1B & 1C: EXECUTIVE SUMMARY

Overall Aim of the Monitoring Campaign & Special Requirements 3

AST Calibration Check Summary 3

Summary of Standard Reference Method & EN 14181 Deviations 4

Conclusions, Discussions and Actions arising from the Sampling 5

SECTION 2: INFORMATION ABOUT THE REGULATED INSTALLATION

Regulatory Information 5

Operational Information and Site Monitoring Provisions 6

Monitoring Provisions at the Installation - Periodic Monitoring 7

Continuous Emissions Monitors (CEM) at the Installation 9

SECTION 3: INFORMATION ABOUT THE MONITORING CAMPAIGN

Test Laboratory Staff 10

Standard Reference Methods (SRMs) 10

SECTION 4B: Data and Calculations - AST

SECTION 5: Results of the Functional Tests

CONTENTS

SECTION 5: Results of the Functional Tests

This test report has been written to fully comply with the requirements in EN 14181:2014 and the Environment Agency's Technical Guidance Note TGN M20, Version 3 (incorporating MID 14181 as Annex A) which was published in June 2015.

Opinions and interpretations expressed herein are outside the scope of Exova Catalyst's UKAS accreditation.

This test report shall not be reproduced, except in full, without the written approval of Exova Catalyst.

CAT-14181 (Version X)2 of 37

Lafarge Ireland LtdCookstown WorksA8 - Kiln Exhaust Main Stack (Duty Analyser)

Job Number: CEK-2909, Version 1Sample Date/s: 15th - 16th May 2018


Overall Aim of the Monitoring Campaign

Special Requirements

AST CALIBRATION CHECK SUMMARY

Parameter Calibration Function as Derived from the

Previous QAL2

Result of Calibration

Test

SECTION 1B

Lafarge Ireland Ltd, Cookstown WorksA8 - Kiln Exhaust Main Stack (Duty Analyser)

15th - 16th May 2018

Exova Catalyst were commissioned by Lafarge Ireland Ltd to carry out stack emissions testing on the A8 - Kiln Exhaust Main Stack (Duty Analyser) Stack at Cookstown Works.

There were no special requirements.

The aim of the monitoring campaign was to perform an AST Calibration Check Exercise on the Continuous Emissions Monitor (CEM), which is installed on the Plant, following the requirements of EN 14181.

Executive Summary (Page 1 of 2)

Calibration Function derived

from QAL2?

Range after AST Extension

@ REF Conditions

Calibration Function that the AST was

performed against (See Conclusion)

Result of Variability

Test

Calibration Range from

Previous QAL2 @ REF

Conditions

All calibration functions relate to mg/m³, unless otherwise stated.

Ammonia Yes y = 0.9675x + 1.3417

Carbon Monoxide y = 1.0626x -3.1462Hydrogen Chloride y = 1.0802x + 0.1374

Total Particulate Matter y = 0.7784x + 0.1406Total VOCs y = 0.8666x -0.3319

Pass Passy = 0.9769x -0.0657

0 to 21.80 to 16.6 Pass Pass

Oxygen (% v/v) Yes y = 0.9897x + 0.0939

YesYes

y = 0.9897x + 0.0939

Pass

PassPass

PassPassPass

PassOxides of Nitrogen (as NO₂) Yes y = 0.986x + 6.582 Pass Pass

Water Vapour (% v/v) Yes y = 0.9769x -0.0657

Sulphur Dioxide Yes

YesYes

y = 0.9826x + 23.5667

0 to 55.50 to 11.3

y = 0.7784x + 0.1406y = 0.8666x -0.3319y = 0.986x + 6.582

y = 0.9826x + 23.5667y = 1.0626x -3.1462

Pass Passy = 1.0802x + 0.1374y = 0.9675x + 1.3417

Pass

PassPass0 to 554.5

0 to 679.30 to 1005.2

0 to 19.70 to 28.5

Existing Range Still Valid









The calibration functions, once applied, only remain valid as long as the QAL3 data remains within control limits, and that there are no manual adjustments made to the CEMs other than those allowed to bring the settings back within the QAL3 control limit.





Total Particulate Matter, Total VOCs, Oxides of Nitrogen, Sulphur Dioxide, Carbon Monoxide, Hydrogen Chloride, Ammonia, Water Vapour & Oxygen

15th - 16th May 2018A8 - Kiln Exhaust Main Stack (Duty Analyser)

CONCLUSIONS, DISCUSSIONS & ACTIONS FROM THE SAMPLING EXERCISE

SECTION 1C

Executive Summary (Page 2 of 2)

Lafarge Ireland Ltd, Cookstown Works

The CEM data was corrected using the calibration function derived during the most recent QAL2 campaign. The corrected values passed both the variability and calibration tests as required by EN 14181 and therefore the calibration function is deemed to be valid within the given tolerances. The calibration range derived in the previous QAL2 is still valid.

SUMMARY OF STANDARD REFERENCE METHOD & EN 14181 DEVIATIONS

Parameter Run Deviation

All Parameters All There are no deviations associated with the sampling employed





Regulated Determinands and Emission Limit Values (ELVs)

¹ TGN M20, Version 3

Section 2: Information about the Regulated Installation

Date CEMs Data Obtained by Exova Catalyst 25th May 2018

20 ¹

Name of the Installation

20

Value

600

--

30


15th - 16th May 2018

Short-Term ELV (mg/m³)

Daily or 48hr Average ELV (mg/m³)

Date of the Last QAL2 / AST Campaign

Cookstown Works

1st - 6th November 2017 (Gaseous AST / TPM QAL2)

Oxides of Nitrogen (as NO₂) -

--

3035

600

Ammonia 40Hydrogen ChlorideCarbon Monoxide

10

30

-

-

REGULATORY INFORMATION

Parameter

800 20

Cement & LimePermit Number P0052/04A/V6

Address of the Installation See Title PageSector of the Installation

5040

Uncertainty Requirement (%)

Sulphur Dioxide

Total VOCsTotal Particulate Matter

Determinand

¹ TGN M20, Version 3





Process Type and Variations in Emissions

Type of Fuel

Continuous

Yes

NoWill these variations affect the representative nature of the collected data?

OPERATIONAL INFORMATION AND SITE MONITORING PROVISIONS

A8 - Kiln Exhaust Main Stack (Duty Analyser)15th - 16th May 2018

Are multiple calibration functions required if the emissions vary

Value

Pulverised Coal & Recyled Liquid Fuel Oil

No

Are there any factors that may affect the collected data(e.g. auto-calibrations, plant start up and shut down)

Fuel type used during the EN 14181 test(include proportions for co-incineration)

Was the CEM reading zero for any determinands, if so, was this investigated to ensure it was working?


No

Were there any variations in emissions during the EN 14181 test (e.g. Load changes)

Reviewing historical Plant data, were low emissions expected for any determinands?

What product was being processed during the tests? Cement


Parameter Value

Continuous or batch process

No

Parameter

No

Abatement

due to different fuel types being used?

ESP

Parameter Value

Running Status On

Type of Abatement System





Duct Characteristics Location of Sampling Platform

Platform Details

Number of Ports

Safe access available

- 4.0

YesPlatform has vertical base boards (approx. 0.25m high) Yes

No

cm 9.0Orientation of Duct

YesPlatform has 2 levels of handrails (approx. 0.5m & 1.0m high)

Platform has chains / self closing gates at top of ladders

- Vertical

Sufficient working area to manipulate probe and operate the measuring instruments

4" BSP

EA Technical Guidance Note M1 / EN 15259 Platform Requirements

YesYes

Value

Units Value General Platform Information Value

Type - Circular Permanent / Temporary Platform PermanentDepth m 4.82 Inside / Outside OutsideWidth m -Area m² 18.25Port Depth

Sample Port Size

Access to sample ports unhindered by obstructions

15th - 16th May 2018

Parameter

-


MONITORING PROVISIONS AT THE INSTALLATION - PERIODIC MONITORING


(Page 1 of 2)

Sampling Location / Platform Improvement Recommendations

EN 15259 Homogeneity Test Requirements

Sampling Plane Validation Criteria (EN 15259)

m/s 5.22 - -

6.0

Highest Gas Velocity

< 15° Yes

- > 5 Pa Yes

-

Safe access available

-

Required Compliant

Lowest Differential Pressure Pa 13.5

No

The sampling location meets all the requirements specified in EA Guidance Note M1 and EN 15259, and therefore there are no improvement recommendations.

According to EN 15259, a Homogeneity Test is required on this stack, however, as far as we are aware, it has not yet been undertaken. Unless agreed otherwise with the respective regulator, we would recommend that the Homogeneity Test be undertaken prior to the next set of emissions testing on this stack, and would be happy to carry out the work. Please contact Exova Catalyst for further details.

Criteria in M1 Units

Maximum Angle of Swirl °Yes

---

-Ratio of Above : 1 1.20

4.34 - -

-

- -

Yes

- -

Yes - -No Local Negative Flow - -

Lowest Gas Velocity m/s

- -

Traverse 1 - - - -

Easy access available Yes

- -< 3 : 1

Mean Velocity m/s - - - --

- - -4.85





Pro-forma for Site Provisions for Monitoring

Plant Photos

Yes

Compliance with MID 15259


Requirement Notes

Photo 1 Photo 2

A safe and clean working environment with sufficient space and weather protection.

Yes

Easy and safe access to the CEM. Yes

Adequate supplies of reference materials, tools and spare parts.

Yes

Compliant

15th - 16th May 2018

MONITORING PROVISIONS AT THE INSTALLATION - PERIODIC MONITORING


Facilities to introduce the reference materials for gaseous-monitoring systems, both at the inlet of the sampling line (where present), and at the inlet of the CEM.

Yes

(Page 2 of 2)

See the Sampling Plane Validation Criteria table on the previous page.

Sample Points

where = isokinetic point sampled at

= isokinetic point not sampled at

= combustion gases sample point

= non-isokinetic sample point

Line A

Line B

B1

B4

B3

B2

B6

B9

B8

B7

A8A7 A9 A10

A1 A2 A3 A4

B10

B5

A5

A6





Type

ABB CEMAS FTIR-NT

Yes DURAG D-R-230

3.340487.6

3.340487.6

3.340487.6

Extractive

MC 030016MC 030016Oxygen (Wet)

3.340487.6

MC 030016Ammonia 0 - 15

Cross-Duct

ABB CEMAS FTIR-NT

FTIR

0 - 40%

MC 030016MC 030016

15th - 16th May 2018

Yes

ExtractiveExtractive

Water Vapour0 - 25%

3.340487.6

Measurement Principle

Total Particulate Matter DURAG D-R-230

Instrument Name

A0 2000 Multi FIDABB CEMAS FTIR-NT


Extractive 3.340487.6

Nitrogen MonoxideNitrogen DioxideSulphur Dioxide

FID

Peripheral Determinand Recorded Instrument Name

Temperature

3.340487.63.340487.6

Optical Light Scattering

Total VOCs

MC 030016

Certified Range (mg/m³)

0 - 7.5 MC 140253

FTIRFTIR

Zirconia

MC 030016

Pressure Yes DURAG D-R-230

ABB CEMAS FTIR-NTABB CEMAS FTIR-NT

ExtractiveExtractive

YesExtractiveExtractiveExtractive

ABB CEMAS FTIR-NT

Main Determinand

Carbon MonoxideHydrogen Chloride

QAL1 Compliant

MC 030015

MC 030016

0 - 200

Instrument Serial Number

01239225


0 - 15

MCERTS Number

FTIRFTIR

FTIRFTIR


CONTINUOUS EMISSION MONITORs (CEMs) AT THE INSTALLATION

-0 - 750 - 750 - 15

YesYesYesYes

ABB CEMAS FTIR-NTABB CEMAS FTIR-NT

3.340487.6YesYes

YesYes





NOTE 1: Exova Catalyst hold UKAS and MCERTS Accreditation for all Standard Reference Method Tests performed.

NOTE 2: The MU specified in this column is reported as the MU at the Daily ELV (not the MU percentage of concentration measured.)

where: MST stands for Manual Sampling Train

Technician Anthony Lovell

MC 130223 EN 14792

Position

Gasmet DX4000Water Vapour 0 -30%

Total VOCs0 - 75

MCERTS Level 1 MM 16 1397, Expiry: 30/09/2021 None

Horiba PG-350E Chemiluminescence 0 - 205

EN 14789TGN M22FTIR

Paramagnetic CellHoriba PG-350E

0 - 15

Team Leader

MCERTS Number & Expiry Date

MM 10 1061, Expiry :30/04/2020

Operational (mg/m³)

N/A - SRM0 - 161

Instrumental Ranges

Sulphur Dioxide

EN 12619Oxides of Nitrogen (as NO₂)

0 - 75.9 MC 030014 TGN M22 8.1

MU ²(%)

MC 030014Gasmet DX4000

MST

FTIR

STANDARD REFERENCE METHODS (SRMs)

Total Particulate Matter

Determinand

FTIRCarbon Monoxide 0 - 75

EN 13284-10 - 15

Ammonia Gasmet DX4000 FTIR N/A

8.02.2

1.5

Sick Maihak 3006

Exova Catalyst hold UKAS and MCERTS Accreditation for performing QAL2 and ASTs, to EN 14181.

MCERTS Number

FTIR

MC 040036MC 030014

2.28.9

0 - 20%0 - 25%

0 - 936.9 2.4

Technical EndorsementsMCERTS AccreditationName

Stephen Dick MCERTS Level 2 TE1 TE2 TE3 TE4

Certified (mg/m³)

Section 3 - Information about the Monitoring Campaign

TEST LABORATORY STAFF

MC 130223MC 030014 5.4

3.4

Reference Method

0 - 1159.2TGN M22

Measurement Principle

GravimetricFID

TGN M22

Instrument Name

0 - 75

Hydrogen Chloride

TGN M22Gasmet DX4000Gasmet DX4000 MC 030014

MC 0300140 - 624.60 - 16.3

Oxygen (Dry) 0 - 25%

Servomex 4900

Oven Box (1)

Mass View (2)

CAT 13.24Umbilical (2)

Control Box DGM (1)

Stack Thermocouple (1)

CAT 25.4

Heated Probe (3) CAT 5.11 Ankersmid APP100

Box Thermocouples (2)Umbilical (1) CAT 3.57

Servomex 5200MP -Barometer

--

Digital Temperature Meter CAT 3.34 / 3.54

Heated Probe (2) CAT 5.162 CAT 20.131

5m Heated Line (1)

Equipment Type

-

Oven Box (2)CAT 12.963 CAT 4.934

Stopwatch

CAT 4.206

CAT 12.721m Heated Line (2)

L-Pitot -

Mass Flow Controller (1)Mass Flow Controller (2) CAT 6.12

CAT 6.111m Heated Line (3) -

CAT 21S.28

-

1m Heated Line (1) CAT 20.130Gasmet Sampling System-

CAT 10.4Stack Thermocouple (3) CAT 4.995 / 4.0048

Heated Probe (1) CAT 5.4Bernath 3006 FID

CAT 14.53

Equipment Type Equipment I.D. Equipment Type Equipment I.D. Equipment I.D.

Gasmet DX4000 CAT 19.12Stack Thermocouple (2)

CAT 4.597

Extractive Sampling Instrumental Analysers

CAT 7.38 Horiba PG-350E CAT 39.7 Digital Manometer (1) CAT 3.34Control Box DGM (2)

LIST OF EQUIPMENT

JCT JCC P1 Cooler

CAT 8.4

- Eco Physics CLD 822Mh

- Horiba PG-250 SRM CAT 9.13 Digital Manometer (2) CAT 3.54

Single Channel Heater Controller

500g Check WeightMass View (1) -

Miscellaneous Items

CAT 17.420m Heated Line (1) CAT 20.133

Box Thermocouples (1) CAT 3.57

-ABB AO2020-URAS26

S-Pitot (1)

-Laboratory Balance CAT 1.18 / 1.18aTape Measure CAT 16.3

S-Pitot (2) 15m Heated Line (1) -CAT 21P.95 / 105

20m Heated Line (2) -Dual Channel Heater Controller1Kg Check Weight

Last Impinger ArmCallipersTubes Kit Thermocouple

CAT 17.4CAT 4.22 / 4.24 / 4.9993

CAT 23.22CAT 4.217

Easylogger EN-EL-12 Bit -Hioki 5043 (V) CAT 11.94

CAT 3.161





Calibration Data

Outliers Data

Reason for Data Pair Removal

SELECT or TYPE INSELECT or TYPE INSELECT or TYPE INSELECT or TYPE INSELECT or TYPE INSELECT or TYPE IN

INPUT

INPUT INPUT

Time

8

(Page 1 of 3)

12.8712.11

x - xav(A)

y - yav(B)

13.80

12:00 - 12:45

Section 4B - Data and Calculations - AST

TOTAL PARTICULATE MATTER: AST CALCULATIONS

0.00 0.00

5 15/05/2018 14:20 - 15:06 12.61 8.469.34

INPUT

10.00 INPUT

INPUT INPUT 0.00 0.00 INPUT

2.65

MAX SRM - MIN SRM

x, CEM (STP, ACTUAL) mg/m³

-0.39

6

43

INPUT INPUT 0.00 0.00

0.00

0.005INPUTINPUT INPUT 0.00

-3.97 21.39(DAILY) DELV (mg/m³)

30

INPUT2 INPUT INPUT

INPUT 0.00 0.00

9.45

9.01 14.15

11.96

0.60 0.81 10.107 16/05/2018 09:00 - 09:46

10:48 - 11:34

y, SRM (STP, ACTUAL) mg/m³

(A) x (B) (x - xav)² CAL CEM (STP,

ACTUAL) mg/m³

1 15/05/2018 09:35 - 10:20 12.74 9.50 15.27 -0.97 0.64 -0.62 0.9315/05/2018

SRM (STP, DRY,

10% O₂) mg/m³

9.73-1.38

SUM

-3.30 7.01

5.2530

95% CI MU (%)

Pair Date Time

10.05

11.702

15.46

6 15/05/2018 15:25 - 16:11 12.80 8.19 13.19

3 15/05/201812.32

17.36 1.15 2.08 2.40 1.330.16 -0.21 1.91

14.85 10.93


Pair Date

x, CEM (ACTUAL)

mg/m³

y, SRM (ACTUAL)

mg/m³

Filter ID Number

(47-XXXX)

15.98

0.43 1.20 9.95-0.90

2.28 -1.06 -2.41 5.19 12.58

INPUT

7.80 12.71-1.2516.35 7.61-0.66

-1.09-1.74 0.49 -0.85 3.024 15/05/2018 13:15 - 14:02

16/05/2018 10:00 - 10:45


SELECT or TYPE INSELECT or TYPE INSELECT or TYPE INSELECT or TYPE INSELECT or TYPE IN

INPUT

INPUT8 INPUT INPUT 0.00 0.000.00 INPUT9 INPUT

6

10



Existing Calibration Functiony = 0.7784x + 0.1406

INPUT 0.00

0.00 0.00 INPUT7

Source of Existing Calibration FunctionCEK-2705 Exova Catalyst QAL2

Existing Calibration Range (@ REF Conditions)0 to 28.5 mg/m³

INPUT INPUT





PLOT 1: BAR CHART FOR REFERENCE SRM vs REFERENCE CEM (STANDARDISED)

Variability Test Data where CAL = Calibrated using AST calibration functions



Date

TOTAL PARTICULATE MATTER: AST CALCULATIONS (Page 2 of 3)


SRMPressure

COPY CORRECT PLOT 1 BAR CHART

Time CEMTemp

SRMWater

CEMOxygen

CEMOxygen

SRMTemp

CEMPressure

Pair SRMOxygen

CAL CALCEM

Water CEM

Water

0.0

5.0

10.0

15.0

20.0

25.0

30.0

1 2 3 4 5 6 7 8

mg/

m³ (

REF)

Pair

CEM SRM

0.0

00/01/1900

0 00/01/1900 00:00 0.0 0.0 0.0

101.7 101.78 16/05/2018 101.7 101.7

0.0 0.0

0 00/01/1900

101.7

0

00:000

0.00 0.000

PressurekPa

0.0

0

91.9

0.0

0 00/01/1900

10:00 - 10:45

9.9810.11 10.10 10.02

95.3

0.00

101.7 101.796.1 101.7

94.3 95.3

00/01/1900

0

10.15 10.13 10.2616.14 15.71 14.59 10.13 10.12

00/01/1900

13.80 -2.226 15/05/2018 15:25 - 16:11

67 16/05/2018 90.1

96.0 101.7 101.7

0

101.7

15/05/2018 10:48 - 11:34 94.3

Temp°C

00/01/1900

5

2

0 0.000:00 0.0

15/05/2018 10:48 - 11:34

0.00 0.00 0.00 0.00

2

-8.328

Filter ID Number

(47-XXXX)

47-4896847-51049

00:00MAX

0.00 0.000.0000.00 0.00

0.00

0.00

0

09:35 - 10:20 93.8

00:00 0.0

12:00 - 12:45

1 15/05/2018

Water Vapour% v/v

Oxygen (DRY)% v/v

Oxygen (DRY)% v/v

16.02

0.00

15/05/2018

Date

14:20 - 15:06

12.11

0.00

15.46 0.33

10:00 - 10:45 12.58 20.29

0.0 0.0

Sd 3.17

0.000 000/01/1900 00:00

Time CAL CEM (ACTUAL)

mg/m³

CAL CEM (STP, DRY,

10% O₂) mg/m³

000:00 0.00

09:35 - 10:20

0.00 0.00 0.00

9.95 16.02

17.36 -1.43

10.10

SRM (STP, DRY,

10% O₂) mg/m³

ys, SRM - CAL CEM

0

Pair

0

7

00:0016/05/2018

10.05 16.14 15.27 -0.88

0.00

16/05/2018

00/01/1900

0 00/01/1900 00:00 0.00 0.00 0.00 0.00 0

20.43

4

0 00/01/19000 00/01/1900 00:00

0.000.00

15/05/2018

15/05/2018 15:25 - 16:11 94.3 96.4 101.7

Temp°C

PressurekPa

13:15 - 14:0215/05/2018 101.7 101.7

4 94.3

Oxygen (DRY)% v/v

15.59 14.19

0.0

96.6 101.7 101.7

90.4 93.7

94.3

00/01/1900

09:00 - 09:46

00:00 0.0 0.0

16.13 15.69 15.18

47-5121547-5096347-5044447-5121647-50449

1

0.00 0.00 0.00

3

12.87

5

9.73 15.65 14.15

0.0 0.0

15/05/2018 14:20 - 15:06

0.00.0 0.0

16.09

3 15/05/2018 12:00 - 12:45 11.70 18.79

47-5044309:00 - 09:46 20.43

15/05/2018

0.0 0.0 0.000:00

0.0 0.010.40

0.00 0.00 0.00 0.00 0.00 0.00

0.000.00

0.00 0.00 0.00

13.19 -2.90

00:00 0.0

0.0

Water Vapour% v/v

Water Vapour% v/v

0.000.00 0.00 0.00 0.00 0.00 0.000.00 0.00 0.00 0.00 0.00

00/01/1900 00:00

0.00 0.00 0.00 0.00 0.000.00 0.00 0.00 0.00 0.00 0.00

-1.50

12.71 -7.57

13:15 - 14:02 9.45 15.1315/05/2018

10.2216.05 15.62 15.28 10.15 10.14 10.2615.89 15.46 16.14 10.06 10.05 10.0215.60 15.17 15.93 10.19 10.18 10.06

16.09 15.66 16.98 10.08 10.07

15.48 15.06 14.80 10.36 10.35

0.00 0.00 0.00 0.00 0.00





Test of Variability Test of Calibration (Acceptance of Calibration Function)

where N (number of samples) = 8

The variability is accepted if Sd ≤1.5 x Q₀ x Kv The calibration is accepted if D < t0.95 (N-1) x Sd / SQRT (N) + Q₀

PLOT 2: X-Y Plot - REF CAL CEM vs REF SRM Values

Standard Deviation (Sd)


4.59



TOTAL PARTICULATE MATTER: AST CALCULATIONS


3.061.5 x Q₀ x Kv 6.56

Kv for 8 Pairs of Data

t0.95 (N-1)

a) Calibrated Range (10% extension) (mg/m³)

3.17 Mean Difference (D)t0.95 (N-1) x Sd / SQRT (N) + Q₀

Outcome of Variability Test Pass

Q₀ = ELV x (MU / 100) / 1.96

(Page 3 of 3)

Outcome of Calibration Test

Value

0 to 22.5b) Calibrated Range (50% of Daily ELV) (mg/m³) 0 to 15

New range up to a maximum of 50% of the Daily ELV 0 to 15

1.895

6.71Pass

0.9521

Parameter Value Parameter

New Calibration Range (REF)

20.0

25.0

30.0 DATE/S: 15/05/2018 to 16/05/2018

COPY APPROPRIATE PLOT 2: X-Y PLOT OF REF CAL CEM vs REF SRM VALUES (choose the graph with or without the AST extension)

-5.0

0.0

5.0

10.0

15.0

20.0

0.0 5.0 10.0 15.0 20.0 25.0 30.0

SRM

mg/

m³ (

REF)

CAL CEM mg/m³ (REF)

TPMCalibration Range





Calibration Data

15/05/2018 -1.72 -2.01

0.00

-0.84 0.39 0.22 8.3319 15/05/2018 -1.07 -1.38 1.47 1.14

(Page 1 of 3)

8.58

15/05/2018 08:32 - 09:02

0.00 0.00 0.00 0.00 0.00

15/05/2018

0.35

11.26

9.50

11.58 13.78 0.89

8.71

7.81

4 15/05/2018 03:32 - 04:02 11.55 12.105

9.50

6 15/05/2018 05:32 - 06:02 11.48 9.62


8.543 15/05/2018 02:32 - 03:02 10.28 10.95

6.77

9.90 11.86 -0.47

9.68

18:32 - 19:02

21:32 - 22:02

0.00 0.00

9.4115/05/2018 10:32 - 11:02 11.35


VOLATILE ORGANIC COMPOUNDS: AST CALCULATIONS

SRM (STP, DRY,

10% O₂) mg/m³

15 15/05/2018

CAL CEM (STP, WET)

mg/m³

915/05/2018 09:32 - 10:02 11.25 12.15 14.47

1.18 0.83 0.49 9.34

10.88 13.13

8.91

1.71 2.61 2.32

10.48 12.85

11.16 11.91 14.05 0.70

10.49 12.60

0.77 0.34

8.53

(A) x (B)

14

5.10

7.81

11.96 14.13

18 15/05/2018 17:32 - 18:02

10.058

0.35 0.05

-0.02 -0.25

1.30 1.04

0.05

0.19 9.11

2

0.00 0.00

17 15/05/2018

0.00 0.00

22:32 - 23:02

7.84

15/05/201815/05/2018 20:32 - 21:02 9.12

0.15

0.62

0.89

16 15/05/2018 15:32 - 16:02 10.60 11.08

13:32 - 14:02

13.29

130.01 0.00

1.42 1.12

0

0.00

-1.3419:32 - 20:02 9.43 9.32

0.14

10.48 -0.24 -0.01

10.66 10.70

8.94 10.84

0.00

0.00 0.000.00 0.00

0 00/01/1900 00:00 0.00

00/01/1900 00:00

0 00/01/1900 00:00 0.00

11

16:32 - 17:02

-1.7920 15/05/2018

23

9.39 9.35

10.23

15/05/2018 1.091.52

7.5722 8.20

0.7906:32 - 07:02 11.98

10.718.73

1

1.1910.90

11.05 10.85 13.35 0.59 0.12 0.07

x - xav(A)

y - yav(B)

Pair Date

0.76

21

8.920.02

7 15/05/2018

Time (30-minute Average)

01:32 - 02:02 10.24 10.83

0.00

1.49

12.00


0.44

x, CEM (STP, WET)

mg/m³

y, SRM (STP, WET)

mg/m³

14.27 1.02 1.27

11.23 -1.03

14.83 1.09

12.92 -0.22 0.10 -0.02 0.05

10

-0.03

2.40 1.80

0.00 0.00 0.000.00 0.00

00:00 0.00

9.61 -2.26 -2.92 6.60

15/05/2018 04:32 - 05:02

-1.41 1.45 1.06

(x - xav)²

07:32 - 08:02 11.35

1.37

0.00 0.00

8.72

-0.2315/05/2018

13.26 -0.18 0.22 -0.04 0.03

0.05

0 00/01/1900

15/05/2018 12:32 - 13:02 10.68

15/05/2018 00:32 - 01:02

12 15/05/2018 11:32 - 12:02

0.00 0.00

0.04

1.23

14:32 - 15:02

0.85

9.99

10.43

8.75

3.47 2.97 7.24

9.240.02

11.50 13.74

0.80

10.85 12.90 0.22 0.12 0.03

12.44 14.76

0.79

8.85

0.000.00

13.29 0.20 -0.03 -0.01

Outliers Data


SELECT or TYPE INSELECT or TYPE INSELECT or TYPE INSELECT or TYPE INSELECT or TYPE INSELECT or TYPE INSELECT or TYPE INSELECT or TYPE INSELECT or TYPE IN

CEK-2320 Exova Catalyst QAL2 Report (Duty Analyser)

0.00 0.00 0.00 0.00 0.00

8


SELECT or TYPE IN

Existing Calibration Functiony = 0.8666x -0.3319

Source of Existing Calibration Function

0.00 0.00

0.00 0.003 INPUT INPUT

0.00 0.00

0.00

INPUT 0.00

00/01/1900 00:00

0


x, CEM (WET) mg/m³

00:00 0.00

0.00


0.00

1 INPUT2 INPUT INPUT

0.00 0.00

Pair Date

0

00/01/1900 00:00

0.00 0.00 0.000.00

5 INPUT INPUT 0.00 0.006 INPUT INPUT 0.00 0.007 INPUT

3595% CI MU (%) 30

0 00/01/1900

y, SRM (WET) mg/m³

0.00

INPUT 0.00 0.00

4 INPUT INPUT 0.00 0.00

0 00/01/1900 00:00 0.00 0.00 0.00 0.00 0.00

0.00 0.00 0.00 0.00 0.00

0.0010 INPUT INPUT 0.00 0.00

0.00

0.000.00

INPUT 0.00

0.00 0.00

MAX SRM - MIN SRM 5.21 SUM 25.37 20.32(DAILY) DELV (mg/m³)





PLOT 1a: GRAPH FOR STP SRM vs STP CEM (NON-STANDARDISED) (1 minute readings)

PLOT 1: GRAPH FOR REFERENCE SRM vs REFERENCE CEM (STANDARDISED) (30 minute rolling averages)

(Page 2 of 3)


COPY PLOT 1: 30/60-MINUTE ROLLING AVERAGE TREND GRAPH INTO HERE

COPY PLOT 1a: 1 MINUTE TREND GRAPH INTO HERE


VOLATILE ORGANIC COMPOUNDS: AST CALCULATIONS

0.0

5.0

10.0

15.0

20.0

25.0

30.0

35.0

00:0

0

01:0

0

02:0

0

03:0

0

04:0

0

05:0

0

06:0

0

07:0

0

08:0

0

09:0

0

10:0

0

11:0

0

12:0

0

13:0

0

14:0

0

15:0

0

16:0

0

17:0

0

18:0

0

19:0

0

20:0

0

21:0

0

22:0

0

23:0

0

mg/

m³ (

STP)

Time

VOCs (CEM - 1 min)VOCs (SRM - 1 min)

0.0

5.0

10.0

15.0

20.0

25.0

30.0

35.0

00:0

0

01:0

0

02:0

0

03:0

0

04:0

0

05:0

0

06:0

0

07:0

0

08:0

0

09:0

0

10:0

0

11:0

0

12:0

0

13:0

0

14:0

0

15:0

0

16:0

0

17:0

0

18:0

0

19:0

0

20:0

0

21:0

0

22:0

0

23:0

0

mg/

m³

Time

VOCs (CEM - 30 min)VOCs (SRM - 30 min)

Variability Test Datawhere CAL = Calibrated using AST calibration functions

MAX0.00 0.00 0.000 00/01/1900

8.85

0.47

9.44 11.23 1.80

00:00 0.00 0.00 0.00 0.00

00/01/1900 00:00 0.00

00:00 0.00

1 15/05/2018 00:32 - 01:02 8.53

0

14 13:32 - 14:02 8.71

15/05/2018 04:32 - 05:02

08:32 - 09:02 9.34

15/05/2018 10.05

11.24 14.47 3.24

19 15/05/2018 18:32 - 19:02 7.81

4 15/05/2018 03:32 - 04:02 9.685

15/05/2018

06:32 - 07:02

8.33

15/05/2018 8.91

2.3310.47 13.29 2.82

17:32 - 18:02

2

11:32 - 12:02 8.75

9.91

2.62

16.23 15.7902:32 - 03:02 8.58

19:32 - 20:02 7.84

16.15 15.71 15.77 10.15 10.14 10.1216.02 15.59 15.75

15/05/2018 01:32 - 02:02 8.54 10.31

12.15 14.76

10.18

15/05/2018

13.26 2.73

Sd

CAL CALCEM

Water Vapour% v/v

CEMWater Vapour% v/v

1.7622 15/05/2018 21:32 - 22:02 6.77 8.20 9.61 1.42

10.27

SRM (STP, DRY,

10% O₂) mg/m³

ys, SRM - CAL CEM

14:32 - 15:02

13.78

15.85

16 15/05/2018

10.55

18

12.15

17

21 15/05/2018 20:32 - 21:02 7.57 9.08 10.84

Pair SRMWater Vapour% v/v

CEMOxygen (DRY)% v/v


SRMOxygen (DRY)% v/v

Date Time (30-minute Average)

CAL CEM (STP, WET)

mg/m³

15:32 - 16:02

10.54

11.02

10.51 12.60

15/05/2018 16:32 - 17:02 13.35

15.81

13 15/05/2018

2.618 15/05/2018 07:32 - 08:02 9.50 11.49 14.13 2.64

23 15/05/2018

10.67 13.29

15.93 10.26

9.116 15/05/2018 05:32 - 06:02 9.62

10.42 12.85 2.43

9 15/05/2018

0 00/01/1900

7

1.89

2.68

20 15/05/2018

13.74 2.78

12 15/05/201811 15/05/2018 10:32 - 11:02 9.50 11.32

9.24 11.01

12:32 - 13:02 8.92

15

2.09

CAL CEM (STP, DRY,

10% O₂) mg/m³

11.81 14.83 3.01

15.96 15.52 15.67 10.24 10.23 10.00

10.38 13.13 2.7512.92 2.61

2.35

10.9611.60 14.27

10.37 10.2116.43 15.98 16.02 10.29

16.25

15.42 15.54 10.23

10.16

12.90

10.28 10.31

15.83 10.05 10.04 10.02

16.06 15.63 15.72 10.23 10.22 9.9516.12 15.69 15.76 9.95 9.94 9.9316.03 15.59 15.65

9.99 9.98

10.09

22:32 - 23:02 7.24

14.05 3.0310 15/05/2018 09:32 - 10:02 9.41

15.95 15.52

15.97 15.54 15.63 10.08 10.07

10.0416.20 15.76 15.83 10.38

10.40

00/01/1900 00:00 0.00 0.00 0.00 0.00

0 00/01/1900 00:00 0.00 0.00 0.00 0.0000/01/1900 00:00

10.13

0.00 0.00 0.00

15.60 10.16 10.14 9.36 11.26

10.0116.13 15.69 15.75 10.10 10.09 10.3416.03 15.59 15.74 10.13 10.12 10.49

10.31 10.29 10.47

0

3 15/05/2018

0.00 0.00 0.000 00/01/1900 00:00 0.00 0.00 0.00 0.00

0.00 0.00 0.00 0.000

15.90 15.47 15.65 10.19 10.18 10.0810.21 10.05

10.08 10.0516.17 15.73

15.91 10.19

2.46

15.71 15.28 15.37 10.38 10.37 10.420.00 0.00 0.00

1.88

0.00 0.00 0.00 0.00 0.00 0.000.00 0.00 0.00

0.00

11.8610.17

15.92 15.49 15.57 10.20 10.19 10.1915.77 15.34 15.52 10.18 10.17 10.2615.55 15.12 15.20

8.84 10.71

15.99 15.55 15.61 10.07 10.06 10.13

15.88 15.45 15.62 10.00 10.00

0.00 0.00 0.00 0.00 0.00 0.000.00 0.00 0.00 0.00 0.00 0.000.00 0.00 0.00 0.00 0.00 0.00

0.00 0.00 0.000.00 0.00 0.00 0.00 0.00

1.95

00:0

0

01:0

0

02:0

0

03:0

0

04:0

0

05:0

0

06:0

0

07:0

0

08:0

0

09:0

0

10:0

0

11:0

0

12:0

0

13:0

0

14:0

0

15:0

0

16:0

0

17:0

0

18:0

0

19:0

0

20:0

0

21:0

0

22:0

0

23:0

0

Time










Standard Deviation (Sd) 0.471.5 x Q₀ x Kv 7.89

1.711

Outcome of Calibration Test Pass

Mean Difference (D)t0.95 (N-1) x Sd / SQRT (N) + Q₀

Outcome of Variability Test Pass

2.435.53

0.9824

Parameter

Q₀ = ELV x (MU / 100) / 1.96 t0.95 (N-1)

Parameter ValueValue

5.36Kv for 23 Pairs of Data


VOLATILE ORGANIC COMPOUNDS: AST CALCULATIONS(Page 3 of 3)



a) Calibrated Range (10% extension) (mg/m³) 0 to 13.4b) Calibrated Range (50% of Daily ELV) (mg/m³) 0 to 17.5

New range up to a maximum of 50% of the Daily ELV 0 to 13.4

25.0

30.0

35.0

40.0 DATE/S: 15/05/2018 to 15/05/2018


-10.0

-5.0

0.0

5.0

10.0

15.0

20.0

25.0

0.0 5.0 10.0 15.0 20.0 25.0 30.0 35.0

SRM

mg/

m³ (

REF)


VOCsCalibration Range





Calibration Data

595.17 583.53

10 15/05/2018

46.71


Pair

103.078.38

SRM (STP, DRY,

10% O₂) mg/m³

874.51

-31.71 -31.1415/05/2018

(A) x (B) (x - xav)² CAL CEM (STP, WET)

mg/m³

00:32 - 01:02

6 15/05/2018 3663.95

685.45 39.88 32.64 586.68

653.21 3.95 8.88 35.11 15.62 551.26

559.4954 15/05/2018

57.4915/05/2018 04:32 - 05:02 637.81 622.85 744.05 89.35 81.08 7244.61

3 15/05/2018 02:32 - 03:02

1 15/05/2018

706.8701:32 - 02:02

518.89 506.31

151.19635.46

518.21

641.52 529.22 524.68

7305.96

563.31

2181.40 593.421950.15

Date Time (30-minute Average)

x - xav(A)

y - yav(B)

4062.28 610.217

550.15 674.08 12.30

2 15/05/2018

15/05/2018 10:32 - 11:02 525.46

694.28 11.89 17.19

13 15/05/2018 12:32 - 13:0212

463.09

11:32 - 12:02 516.75 510.63 613.12

05:32 - 06:02 612.20 599.26 712.44

22 15/05/2018 21:32 - 22:02 641.29

15 15/05/2018 14:32 - 15:02 560.35 558.96

578.41

638.89

63.74

204.36 141.36 559.0916

538.68 534.15 634.57 -9.78 -7.62 74.51 95.64 537.72

09:32 - 10:02 472.98 473.61 564.00 -75.48 -68.17 5145.47 5697.759

23

20:32 - 21:02 462.99 462.66

0.00

03:32 - 04:02 560.767983.18

0.00 0.00

07:32 - 08:02 564.63 550.73 650.51

-85.47 -79.11 6762.23

0.000 00/01/1900 00:00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00

0.00

15/05/2018 15:32 - 16:02 506.65 527.72 -41.81-2.98 7.11 549.99

0.00 0.00

512.83 628.40 -28.88 -28.95 836.05 834.19 518.89

2102.07 1841.99 505.05472.94

11

-14.05

15/05/2018 08:32 - 09:02 505.54 492.79 581.24 -42.92 -48.98

987.59

632.65

939.72 991.55

22:32 - 23:02 435.44 440.26

00/01/1900

611.16

17 15/05/2018 16:32 - 17:02 551.13

8354.25 8617.04540.63 -113.02 -101.51 11472.30 12773.12 435.93

0 00/01/1900 00:00 0.0015/05/2018

0.00

0.00 0.00

18 15/05/2018 17:32 - 18:02 667.76 654.46 784.57 119.30 112.6919 15/05/2018 18:32 - 19:02 579.95 571.61 687.99 31.49 29.84

00:00 0.00 0.00 0.000 0.00

13443.11 14231.88 664.99

0.00

20 15/05/2018 19:32 - 20:02 499.86 496.87 598.69 -48.60 -44.90 2182.36 2362.13 499.44

x, CEM (STP, WET)

mg/m³

y, SRM (STP, WET)

mg/m³

16.17 8.95 144.82 261.56

0 00/01/1900 00:00 0.00 0.00 0.00 0.00

560.8621 15/05/2018

0.00 0.00 0.000.00

-35.46

631.77 777.97 92.83 90.00

513.89 611.43 -23.00 -27.89

8

540.65 664.83 2.67 -1.12

15/05/2018

-29.57 1048.65

41.75


OXIDES OF NITROGEN (as NO₂): AST CALCULATIONS(Page 1 of 3)


588.34 574.41 1301.44 1590.23

587.51 1748.11 506.14

15/05/2018 06:32 - 07:02 552.41 550.66

1005.73 516.10

14 15/05/2018 13:32 - 14:02 519.58

Outliers Data

SELECT or TYPE IN

INPUT 0.00


Existing Calibration Function

0.006

0.00 0.00


SELECT or TYPE INSELECT or TYPE IN

INPUT

00/01/1900 00:00 0.00 0.00 0.00 0.00 0.00

20

0.00 0.00 0.00 0.00 0.00 0.00

Source of Existing Calibration Function

00/01/1900

0

0.004 INPUT INPUT

2 INPUT INPUT 0.00 0.003 INPUT INPUT 0.00

5 INPUT INPUT 0.00

x, CEM (WET) mg/m³

SELECT or TYPE IN

0.00 0.00MAX SRM - MIN SRM(DAILY) DELV (mg/m³) 80095% CI MU (%)

0.00

INPUT INPUT 0.00 0.00INPUT INPUT 0.00 0.00

00/01/1900 00:00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00

INPUT

00:00 0.00 0.00 0.00

0

0

0.00

0.000 00/01/1900 00:00 0.00 0.00

0.00

243.94 SUM 69221.87 75302.75

Pair Date Time (30-minute Average)

0.00

y, SRM (WET) mg/m³

1 INPUT INPUT

0.00 0.00 0.00

0.00

0.007 INPUT

9

0.008 INPUT

INPUT 0.00

CEK-2320 Exova Catalyst QAL2 Report (Duty Analyser)y = 0.986x + 6.582

0.00

SELECT or TYPE INSELECT or TYPE INSELECT or TYPE INSELECT or TYPE INSELECT or TYPE INSELECT or TYPE IN10










ys, SRM -


CAL CEM SRM Time CAL CEM CAL CAL

CEM CEM SRM CEM CEM SRMPair Date

0

100

200

300

400

500

600

700

800

900

00:0

0

01:0

0

02:0

0

03:0

0

04:0

0

05:0

0

06:0

0

07:0

0

08:0

0

09:0

0

10:0

0

11:0

0

12:0

0

13:0

0

14:0

0

15:0

0

16:0

0

17:0

0

18:0

0

19:0

0

20:0

0

21:0

0

22:0

0

23:0

0

mg/

m³

Time

NOx (CEM - 30 min)NOx (SRM - 30 min)

0.000.00 0.000.00

-5.80

023

0.000.00

0.00 0.00 0.00 0.00 0.00 0.00

693.80

0.00 0.00 0.00

15.28 15.37 10.38 10.420.00 0.00 0.00 0.00 0.00

735.81 712.44 -23.36

0.00

0.00 0.00

15.59 15.65 10.09 10.08 10.0516.17 15.73 15.83

15.76 15.83

9.9316.03

728.90 706.87

8 15/05/2018 07:32 - 08:027 15/05/2018 06:32 - 07:02

9.94

559.49 683.10 674.08

595.79 581.24

15/05/2018 04:32 - 05:02 635.46

708.14

05:32 - 06:02764.22 744.05 -20.17

2 15/05/2018 01:32 - 02:02 586.68

ys, SRM - CAL CEM

-9.02

0

10.37

15.52 10.18

4

14

03:32 - 04:02

15/05/2018

681.28 650.51

6 15/05/2018

10.05 10.04 10.02

13 15/05/2018 12:32 - 13:02 537.72

-22.03

-30.77

15.85 15.42 15.54

685.45 -22.693 10.38 10.37 10.21

563.31

16.43 15.98 16.02 10.29 10.28 10.3115.90

10.12635.82 634.57

-14.55

10.23 10.21 10.0515.96

9

5

34.25

1 15/05/2018 00:32 - 01:02 518.21 630.28 611.16

15/05/2018

19 15/05/2018 18:32 - 19:02 578.41

15/05/2018 10:32 - 11:02 524.68 624.73 611.43 -13.30

9.95

16.15 15.71 15.77

15.63

532.29 540.63 8.3422:32 - 23:02 435.930.00

0.00

0.00 0.00 0.000 00/01/1900 00:000 00/01/1900 00:00 0.00 0.00 0.00 0.000

20

16

0.00

15.12

564.55 564.00 -0.5511

15.47 15.65 10.19 10.18 10.08

15.52

791.77 784.57 -7.21

666.45 653.21 -13.24

518.8915.59 15.75

00/01/1900 00:00

15/05/2018 13:32 - 14:02

15.67 10.24 10.23 10.0016.06

551.26

15/05/2018 08:32 - 09:02 505.05

CAL CEM (STP, DRY,

10% O₂) mg/m³

SRM (STP, DRY,

10% O₂) mg/m³

12 15/05/2018 11:32 - 12:02 516.10

15/05/2018 02:32 - 03:02 593.42

10 15/05/201816.12 15.69 15.76 9.95

15.79 15.91 10.19 10.18 10.0416.20

15.72 10.23 10.22


CAL CEM (STP, WET)

mg/m³

16.02 9.99 9.98

15 15/05/2018 14:32 - 15:02 559.09 669.75 694.28 24.53

10.15 10.1410.01

16.13-1.25

619.89 613.12 -6.76

16.25 15.81 15.93 10.27 10.26 10.1616.23

09:32 - 10:02 472.94

610.21

549.99 655.26 664.83 9.57



SRMWater Vapour% v/v




10.07 10.40

-19.12

Pair Date

15/05/2018

687.9915.92 15.49 15.57 10.20 10.19 10.19

0.00 0.00

10.17 10.2615.55

00/01/1900 00:00 0.00

0.00 0.00 0.00

0.0015.71

15.20 10.31 10.29 10.4715.77

0.00

0.00 0.00 0.0000/01/1900 00:00

21 15/05/2018 20:32 - 21:02 463.09 555.48 560.86 5.3822 15/05/2018 21:32 - 22:02 638.89 773.36 777.97 4.61

17 15/05/2018 16:32 - 17:0218 15/05/2018 17:32 - 18:02 664.99 15.99 15.55 15.61 10.07 10.06 10.13

15.95 15.52 15.60 10.16 10.14 10.17

15.34

620.68 628.40

15:32 - 16:02 506.14 598.41

19:32 - 20:02 499.44 601.36 598.69 -2.67

15.69 15.75 10.10 10.09 10.3416.03 15.59

00:00 0.00 0.00 0.00 0.000 00/01/1900 00:00

0.00 0.00 0.00 0.00 0.00 0.00 0.000.00 0.00 0.00 0.00

0.00 0.000.00 0.00

0.00 0.00 0.00 0.0015.800.000.00

MAX 791.77 Sd

15.74 10.13 10.12 10.4915.88 15.45 15.62 10.00 10.00 10.1315.97 15.54 15.63 10.08

15/05/2018

0.00

0 00/01/1900

632.65

7.72









Kv for 23 Pairs of Data1.711

0.9824

Parameter Value Parameter Value




81.63


Standard Deviation (Sd) 15.80 Mean Difference (D) 5.131.5 x Q₀ x Kv 120.29 t0.95 (N-1) x Sd / SQRT (N) + Q₀ 87.27Outcome of Variability Test Pass



t0.95 (N-1)



Q₀ = ELV x (MU / 100) / 1.96

a) Calibrated Range (10% extension) (mg/m³) 0 to 871b) Calibrated Range (50% of Daily ELV) (mg/m³) 0 to 400

1000

1200 DATE/S: 15/05/2018 to 15/05/2018


-200

0

200

400

600

800

0 200 400 600 800 1000 1200

SRM

mg/

m³ (

REF)


NOxCalibration Range





Calibration Data

0.00 0.000 00/01/1900 00:00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00

19 15/05/2018 18:32 - 19:02 215.99 220.75 265.70 -64.71 -71.27 4611.98 4187.14 235.79

0.00 0.00 0.000 00/01/1900 00:00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00

17 15/05/2018 16:32 - 17:02 342.02 354.10 435.43 61.32 62.07 3806.63 3760.69 359.6318 15/05/2018 17:32 - 18:02 282.03 289.18 346.67 1.34 -2.85 -3.80 1.79 300.69

14:32 - 15:02 301.05 310.41 385.55 20.36 18.38 374.27 414.53 319.3816 15/05/2018 15:32 - 16:02 317.89 329.59 395.13 37.20 37.56 1397.33 1383.73 335.93

23 15/05/2018 22:32 - 23:02 171.33 177.45 217.91 -109.36 -114.58 12530.13 11959.99 191.920 00/01/1900 00:00 0.00 0.00 0.00 0.00 0.00

0 00/01/1900 00:00 0.00 0.00 0.00 0.00 0.00 0.00

13 15/05/2018 12:32 - 13:02 294.76 308.52 366.52 14.06 16.49 231.91 197.81 313.20

174.09 181.52 220.05 -106.61 -110.50 11780.42 11365.03 194.62

14 15/05/2018 13:32 - 14:02 276.77 289.35 354.56 -3.93 -2.68 10.51 15.42 295.5215 15/05/2018

11 15/05/2018 10:32 - 11:02 317.34 325.72 387.55 36.65 33.69 1234.75 1342.98 335.3912 15/05/2018 11:32 - 12:02 291.64 303.05 363.88 10.95 11.03 120.68 119.80 310.13

9 15/05/2018 08:32 - 09:02 316.45 329.89 389.10 35.76 37.87 1354.20 1278.86 334.5210 15/05/2018 09:32 - 10:02 323.51 338.84 403.51 42.81 46.81 2004.11 1833.11 341.45

7 15/05/2018 06:32 - 07:02 319.10 333.82 395.99 38.41 41.79 1605.23 1475.27 337.128 15/05/2018 07:32 - 08:02 323.39 335.34 396.10 42.69 43.31 1849.16 1822.61 341.33

1173.00 1095.16 331.895 15/05/2018 04:32 - 05:02 313.13 330.35 394.63 32.44 38.32 1243.17 1052.43 331.256 15/05/2018 05:32 - 06:02 300.13 317.72 377.73 19.44 25.69 499.36 377.82 318.48


mg/m³

1 15/05/2018 00:32 - 01:02 295.64 307.12 370.72 14.95 15.09 225.59 223.46 314.06

y, SRM (STP, WET)

mg/m³

SRM (STP, DRY,

10% O₂) mg/m³

x - xav(A)

y - yav(B)

21 15/05/2018 20:32 - 21:0222 15/05/2018 21:32 - 22:02 158.87 164.66 202.76 -121.83 -127.37 15517.30 14841.77 179.67

2 15/05/2018 01:32 - 02:02 305.32 319.36 381.09 24.63 27.33 673.08 606.60 323.583 15/05/2018 02:32 - 03:02 309.18 324.41 392.99 28.48


SULPHUR DIOXIDE: AST CALCULATIONS(Page 1 of 3)



x, CEM (STP, WET)

mg/m³

20 15/05/2018 19:32 - 20:02 192.54 198.00 238.58 -88.15 -94.03 8288.97 7771.19 212.76

32.39 922.45 811.20 327.364 15/05/2018 03:32 - 04:02 313.79 327.47 401.24 33.09 35.45

Outliers Data


SELECT or TYPE INSELECT or TYPE INSELECT or TYPE INSELECT or TYPE INSELECT or TYPE INSELECT or TYPE IN

0.00 0.00

0 00/01/1900 00:00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00


x, CEM (WET) mg/m³

y, SRM (WET) mg/m³

1 INPUT INPUT 0.00

0 00/01/1900 00:00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00

0.00 0.003 INPUT

SUM 71450.42 67938.40(DAILY) DELV (mg/m³) 60095% CI MU (%) 20

2 INPUT INPUTINPUT 0.00 0.00


0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.000 00/01/1900 00:00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00

MAX SRM - MIN SRM 232.67

4 INPUT INPUT

0.00

0 00/01/1900 00:00

SELECT or TYPE IN


SELECT or TYPE INSELECT or TYPE INSELECT or TYPE IN10 INPUT INPUT 0.00 0.00

Existing Calibration Function Source of Existing Calibration Functiony = 0.9826x + 23.5667 CEK-2320 Exova Catalyst QAL2 Report (Duty Analyser)

5 INPUT INPUT 0.00 0.006 INPUT INPUT 0.00 0.007 INPUT INPUT 0.00 0.008







Variability Test Datawhere CAL = Calibrated using AST calibration functionsCAL

CEM CEM SRM CEM CEM SRM


Pair Date Time CAL CEM CAL CEM SRM CAL

ys, SRM -




0

50

100

150

200

250

300

350

400

450

500

00:0

0

01:0

0

02:0

0

03:0

0

04:0

0

05:0

0

06:0

0

07:0

0

08:0

0

09:0

0

10:0

0

11:0

0

12:0

0

13:0

0

14:0

0

15:0

0

16:0

0

17:0

0

18:0

0

19:0

0

20:0

0

21:0

0

22:0

0

23:0

0

mg/

m³

Time

SO₂ (CEM - 30 min)SO₂ (SRM - 30 min)

0.00

22 15/05/2018 21:32 - 22:02 179.67234.34 217.91 -16.43

0 00/01/1900 00:00 0.00

10.29 10.4715.71 15.28 15.37 10.38 10.37 10.42

0.00 0.00 0.000.00 0.00 0.00 0.00 0.00 0.000.00 0.00 0.00 0.00

20 15/05/2018 19:32 - 20:02 212.76 256.17 238.58 -17.6021 15/05/2018 20:32 - 21:02

00/01/1900 00:00 0.00

15.92 15.49

0 00/01/1900 00:00 0.00 0.00 0.00 0.000.00 0.00

0.00 0.00 0.00 0.00

194.62 233.46 220.05 -13.40

00/01/1900 00:00 0.00 0.00 0.00 0.00

23 15/05/2018 22:32 - 23:02 191.92

0 00/01/1900

358.02 346.67 -11.3419 15/05/2018 18:32 - 19:02 235.79 282.83 265.70 -17.13

15.99 15.55 15.61 10.07 10.06 10.1317 15/05/2018 16:32 - 17:02 359.63 428.47 435.43 6.9718 15/05/2018 17:32 - 18:02 300.69

15.55 15.12 15.20 10.31

15.97 15.54 15.63 10.08 10.07 10.40

15.95 15.52 15.60 10.16 10.14 10.17

0 00/01/1900

-2.04

16.13 15.69 15.75 10.10 10.09 10.3416.03 15.59 15.74 10.13 10.12 10.4915.88 15.45 15.62 10.00 10.00 10.13

372.50 363.88 -8.6213 15/05/2018 12:32 - 13:02 313.20 370.33 366.52 -3.82

16.15 15.71 15.77 10.15 10.14 10.1216.02 15.59 15.75 9.99 9.98 10.01

10.38 10.37 10.2116.43 15.98 16.02 10.29 10.28 10.3115.90 15.47 15.65 10.19 10.18 10.0815.85 15.42 15.54 10.23 10.21 10.05

398.37 394.63 -3.746 15/05/2018 05:32 - 06:02 318.48 384.03 377.73 -6.30







16.25 15.81 15.93 10.27 10.26 10.1616.23 15.79 15.91 10.19 10.18 10.0416.20 15.76 15.83

2 15/05/2018 01:32 - 02:02 323.58 390.57 381.09 -9.47


CAL CEM (STP, WET)

mg/m³

CAL CEM (STP, DRY,

10% O₂) mg/m³

SRM (STP, DRY,

10% O₂) mg/m³

ys, SRM - CAL CEM

381.99 370.72 -11.271 15/05/2018 00:32 - 01:02 314.06

412.81 396.10 -16.719 15/05/2018 08:32 - 09:02 334.52 394.62 389.10 -5.52

10

7 15/05/2018 06:32 - 07:02 337.12 407.56 395.99 -11.5715.96 15.52 15.67 10.24 10.23 10.00

09:32 - 10:02 341.45 407.59 403.51 -4.0815/05/2018

14 15/05/2018 13:32 - 14:02 295.52 353.49 354.56 1.0715 15/05/2018 14:32 - 15:02 319.38 382.60 385.55 2.9616 15/05/2018 15:32 - 16:02 335.93 397.16 395.13

11 15/05/2018 10:32 - 11:02 335.39 399.34 387.55 -11.7912 15/05/2018 11:32 - 12:02 310.13

3 15/05/2018 02:32 - 03:02 327.36 402.11 392.99 -9.114 15/05/2018 03:32 - 04:02 331.89 405.22 401.24 -3.985 15/05/2018 04:32 - 05:02 331.25

217.48 202.76 -14.73

8 15/05/2018 07:32 - 08:02 341.33

0.000

0.000.00 0.00 0.00

000:00 0.00 0.00 0.00 0.00

0.00 0.00 0.00MAX 428.47 Sd 6.70

0 00/01/1900 00:00 0.00

0.000.00 0.000.00 0.00 0.00

0.00 0.000.00 0.00 0.00 0.00 0.00 0.00

00:00 0.00 0.00 0.00

16.17 15.73 15.83 10.05 10.04 10.02

15.57 10.20 10.19 10.1915.77 15.34 15.52 10.18 10.17 10.26

0.00 0.00 0.00 0.00 0.00 0.000.00 0.00 0.00 0.00

16.06 15.63 15.72 10.23 10.22 9.9516.12 15.69 15.76 9.95 9.94 9.9316.03 15.59 15.65 10.09 10.08 10.05












Outcome of Variability Test Pass Outcome of Calibration Test Pass


Value Parameter Value

Q₀ = ELV x (MU / 100) / 1.96 61.22 t0.95 (N-1) 1.711Kv for 23 Pairs of Data 0.9824

ParameterStandard Deviation (Sd) 6.70 Mean Difference (D) 8.161.5 x Q₀ x Kv 90.22 t0.95 (N-1) x Sd / SQRT (N) + Q₀ 63.61

a) Calibrated Range (10% extension) (mg/m³) 0 to 471.3b) Calibrated Range (50% of Daily ELV) (mg/m³) 0 to 300



700

800 DATE/S: 15/05/2018 to 15/05/2018


-100

0

100

200

300

400

500

600

0 100 200 300 400 500 600 700 800

SRM

mg/

m³ (

REF)


SO₂Calibration Range





Calibration Data

329.4615 15/05/2018 14:32 - 15:02 319.88 333.23 413.90 8.57 6.48 55.51 73.42

21 15/05/2018 20:32 - 21:02 258.93 280.60 340.16 -52.38 -46.15 2417.65 2744.1115/05/2018 21:32 - 22:02 254.40 274.96 338.59 -56.91 -51.79 2947.46

0.00 0.00 0.00

0 00/01/1900 00:00 0.00 0.00 0.00 0.00 0.00 0.00

288.02

17 15/05/2018 16:32 - 17:02 326.33 343.61

0.00 0.00 0.00 0.00

0.00277.35

00:00 0.0023 15/05/2018 22:32 - 23:02 2056.15 2240.78

3239.25 267.18271.99

22

238.82 344.07

286.04 344.66 -44.22 -40.71 1800.14 1955.35 280.67

18 15/05/2018 17:32 - 18:02 289.15 305.36 366.06 -22.16 -21.39 474.05 490.93 304.1119 15/05/2018 18:32 - 19:02 274.01 292.09 351.56 -37.30 -34.6620 15/05/2018 19:32 - 20:02 267.09

0.00 0.000.00 0.00 0.00 0.00

0 00/01/1900

0 00/01/1900 00:00 0.00 0.00

15/05/2018 13:32 - 14:02 313.02 328.31 402.30 1.70 1.55 2.65 2.90336.76

16 15/05/2018 15:32 - 16:02 326.77 339.65 407.19 15.45 12.90 199.42

391.67 1.20 -0.55 -0.67 1.45 328.9313 15/05/2018 12:32 - 13:02 319.39 331.99 394.41 8.08 5.24 42.35 65.25 336.24

0.00 0.00 0.000

0.00 0.00

15/05/2018 10:32 - 11:02 324.72 338.40 402.63 13.41 11.65 156.15 179.79 341.9012 15/05/2018 11:32 - 12:02 312.52 326.2011

17.40 32.50 333.71

589.91 353.462 15/05/2018 01:32 - 02:02 333.08 345.99 412.88 21.76 19.24 418.74 473.64 350.78


CARBON MONOXIDE: AST CALCULATIONS

0.00

1292.68 1391.20


x, CEM (STP, WET)

mg/m³

y, SRM (STP, WET)

mg/m³

SRM (STP, DRY,

10% O₂) mg/m³

x - xav(A)

y - yav(B)


mg/m³

330.99 346.76 420.06 19.67 20.01 393.62 387.06 348.56

1 15/05/2018 00:32 - 01:02 335.60 348.94 421.20 24.29 22.19 538.90

228.47 254.22 344.609 15/05/2018 08:32 - 09:02 322.72 336.45 396.84 11.41 9.70 110.70 130.16 339.78

10

14

15/05/2018 09:32 - 10:02 317.01 329.80 392.75 5.70 3.05

338.91 416.75 15.02 12.16 182.66 225.58

00/01/1900 0.00

15/05/2018 06:32 - 07:02 326.40 339.76 403.04 15.09 13.01 196.32 227.68 343.698 15/05/2018 07:32 - 08:02 327.26 341.08 402.88 15.94 14.33

3 15/05/2018 02:32 - 03:02

(Page 1 of 3)


359.16349.81 417.87 24.97 23.06 575.75

4 15/05/2018 03:32 - 04:02 350.01 372.29 456.15 38.70 45.54 1762.37 1497.37 368.775 15/05/2018 04:32 - 05:026 15/05/2018 05:32 - 06:02 330.65 345.32 410.54 19.34 374.14 348.21

336.28 623.46 354.19

0.00 0.00

263.98 283.31 347.90 -47.34 -43.44

7

00:00

18.57

Outliers Data

y, SRM (WET) mg/m³


0.00 0.00


0.00 0.00 0.00 0.00


x, CEM (WET) mg/m³

17438.96(DAILY) DELV (mg/m³)

0.00 0.000.00 0.00



0.00

60095% CI MU (%) 20


Existing Calibration Function Source of Existing Calibration Functiony = 1.0626x -3.1462 CEK-2320 Exova Catalyst QAL2 Report (Duty Analyser)

7 INPUT INPUT6 INPUT INPUT 0.00

SELECT or TYPE INSELECT or TYPE INSELECT or TYPE INSELECT or TYPE INSELECT or TYPE INSELECT or TYPE INSELECT or TYPE IN

3

00:00

MAX SRM - MIN SRM 117.56 SUM 16227.62


0.00

0 00/01/1900 00:00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00

0.00 0.008 INPUT INPUT 0.00 0.00

SELECT or TYPE ININPUT INPUT 0.00 0.009

0.00 0.00 0.00 0.000 00/01/1900 0.00 0.00 0.000 00/01/1900 00:00

0 00/01/1900 00:00 0.00 0.00 0.00 0.000.00 0.00 0.00

0 to 554.5 mg/m³

4 INPUT INPUT 0.00 0.005 INPUT INPUT 0.00

Existing Calibration Range (@ REF Conditions)





PLOT 1a: GRAPH FOR STP SRM vs STP CEM (NON-STANDARDISED) (1 minute readings)


COPY PLOT 1a: 1 MINUTE TREND GRAPH INTO HERE



CARBON MONOXIDE: AST CALCULATIONS(Page 2 of 3)


0

100

200

300

400

500

600

00:0

0

01:0

0

02:0

0

03:0

0

04:0

0

05:0

0

06:0

0

07:0

0

08:0

0

09:0

0

10:0

0

11:0

0

12:0

0

13:0

0

14:0

0

15:0

0

16:0

0

17:0

0

18:0

0

19:0

0

20:0

0

21:0

0

22:0

0

23:0

0

mg/

m³ (

STP)

Time

CO (CEM - 30 min)CO (SRM - 30 min)

0

100

200

300

400

500

00:0

0

01:0

0

02:0

0

03:0

0

04:0

0

05:0

0

06:0

0

07:0

0

08:0

0

09:0

0

10:0

0

11:0

0

12:0

0

13:0

0

14:0

0

15:0

0

16:0

0

17:0

0

18:0

0

19:0

0

20:0

0

21:0

0

22:0

0

23:0

0

mg/

m³

Time

CO (CEM - 30 min)CO (SRM - 30 min)


0.00

20 15/05/2018 19:32 - 20:02 280.67 337.94

15.1823 15/05/2018 22:32 - 23:02 277.35 338.66

0.00 0.00 0.00

15.55 15.61 10.07 10.06 10.1315.95 15.52 15.60 10.16 10.14 10.1715.92 15.49 15.57 10.20 10.19 10.19 6.72

00:00

Sd 8.830 00/01/1900 00:00 0.00

362.09 366.06 3.9719 15/05/2018

0.00 0.00

0.000 00/01/1900 00:00 0.00 0.00 0.00

15.71

0.000 00/01/1900 00:00 0.00 0.00 0.00 0.00

22 15/05/2018 21:32 - 22:02 267.18 323.41 338.59

17:32 - 18:02 304.11

14

10.23

10.4916

343.69 415.50 403.04 -12.46

17 15/05/2018 16:32 - 17:02

21 15/05/2018 20:32 - 21:02 271.99 326.26 340.16 13.90

16.03 15.59 15.74 10.13 10.12 10.4915.88 15.45 15.62 10.00 10.00 10.13

5.91

15.91 10.19 10.18 10.04

15/05/2018 15:32 - 16:02 344.07 406.80 407.19 0.39

397.58 394.41 -3.17

10 15/05/2018 09:32 - 10:02

10.29 10.28 10.3115.90 15.47

2 15/05/2018348.56 428.14 420.06 -8.09

4 15/05/2018 03:32 - 04:02

15/05/2018 05:32 - 06:02

18:32 - 19:02 288.02 345.48 351.56 6.09

333.71 398.35 392.75 -5.6111 15/05/2018 10:32 - 11:02 341.90 407.10 402.63 -4.4712 15/05/2018 11:32 - 12:02 328.93

16.20 15.7615.98 16.02

15.83 10.38 10.37 10.2116.43






CAL CEM (STP, WET)

mg/m³

CAL CEM (STP, DRY,

10% O₂) mg/m³

SRM (STP, DRY,

10% O₂) mg/m³

ys, SRM - CAL CEM

CAL CALCEM

Water Vapour% v/v


01:32 - 02:02 350.78 423.40 412.88 -10.5210.16

16.23 15.79

10.08368.77 450.24 456.15

425.95 417.87 -8.076

10.26

3 15/05/2018 02:32 - 03:02

15.65 10.19 10.18

15/05/2018 00:32 - 01:02 353.46 429.91 421.20 -8.71

13:32 - 14:02 329.46 394.10 402.30 8.20

10.22 9.9516.12 15.69 15.76 9.95 9.94 9.9316.03 15.59 15.65 10.09 10.08 10.0516.17 15.73 15.83 10.05 10.04 10.0216.15

8

15/05/2018

15/05/2018 07:32 - 08:02 344.60 416.76 402.88 -13.889 15/05/2018 08:32 - 09:02 339.78 400.83 396.84 -3.99

15.71 15.77 10.15 10.14 10.12 395.08 391.67 -3.4113 15/05/2018 12:32 - 13:02 336.24

7.3718 15/05/2018

347.90 9.240 00/01/1900 00:00 0.00

0.00 0.00 0.00 0.00 0.00 0.000.00 0.00 0.00 0.00 0.00 0.000.00 0.00 0.00

348.21 419.88 410.54 -9.347 15/05/2018 06:32 - 07:02

16.02 15.59 15.75 9.99 9.98 10.01

1

0.00 0.00 0.00

344.66

403.41 413.90

15.85 15.42 15.54 10.23 10.21 10.0515.96 15.52 15.67 10.24 10.23 10.0016.06 15.63 15.72

5 15/05/2018 04:32 - 05:02 354.19

16.25 15.81 15.93 10.27

15 15/05/2018 14:32 - 15:02 336.76

343.61 409.38 416.75

0.000.000.00 0.00 0.00 0.00 0.00 0.00

MAX 450.24

0.00 0.00 0.00

0.00

00/01/1900

15.28 15.37 10.38 10.37 10.420.00

0.00

0 00/01/1900

0.00 0.00 0.00 0.00 0.00 0.000.00 0.000.00 0.00

0.00 0.00 0.00

0.00 0.00

0.000 00/01/1900 00:00 0.000

00:000.00 0.00

16.13 15.69 15.75 10.10 10.09 10.34

15.77 15.34 15.52 10.18 10.17 10.2615.55 15.12 15.20 10.31 10.29 10.47

15.97 15.54 15.63 10.08 10.07 10.4015.99

0.00 0.00

Time









a) Calibrated Range (10% extension) (mg/m³)

Parameter Value Parameter Value

Kv for 23 Pairs of Data 0.9824

90.22 t0.95 (N-1) x Sd / SQRT (N) + Q₀ 64.37Outcome of Variability Test Pass


Pass Outcome of Calibration Test

0 to 495.3b) Calibrated Range (50% of Daily ELV) (mg/m³) 0 to 300



Standard Deviation (Sd) 8.83 Mean Difference (D) 0.181.5 x Q₀ x Kv


t0.95 (N-1)

CARBON MONOXIDE: AST CALCULATIONS(Page 3 of 3)


Q₀ = ELV x (MU / 100) / 1.96 61.22 1.711

700

800 DATE/S: 15/05/2018 to 15/05/2018


-100

0

100

200

300

400

500

600

0 100 200 300 400 500 600 700

SRM

mg/

m³ (

REF)


COCalibration Range





Calibration Data

0.00

(x - xav)² CAL CEM (STP, WET)

mg/m³

9.54

0

00/01/1900 00:00 0.00 0.00

00/01/1900 00:00 0.00 0.00 0.00 0.00 0.00 0.00 0.00

0.00 0.00 0.000.00

0.00 0.00

0.00 0.00

0.00 0.00 0.00 0.00 0.00 0.00

0.00

0.00 0.00 0.000.00

0 00/01/1900 00:00

0.00 0.00

0 00/01/1900 00:00 0.00 0.00

0.000.00

0.00

0

0.00 0.00 0.00

0.88

-0.30

0.78

0.000 00/01/1900

0.00

00/01/1900 00:00 0.00 0.00 0.00

0 00/01/1900 00:00 0.00 0.00

00:00 0.00 0.00 0.00 0.00

0.00

00:32 - 01:02 7.62 6.13 7.40 -0.19 -0.70 0.14

0.00 0.00 0.00

0.04

0.00

0.00 0.00 0.00 0.0000/01/1900 00:00 0.00 0.00 0.00

0.00 0.00

03:32 - 04:02 7.22 7.33

8.19 -0.67 0.06 -0.045 15/05/2018 04:32 - 05:02

0.56 9.39

0.45 7.86

0.000 00/01/1900 00:00

0 0.00 0.00 0.00 0.00 0.00

0.00

0.000

0 00/01/1900

0 00/01/1900 00:00 0.00 0.00 0.00

0.36 7.9302:32 - 03:02 8.57 7.37 8.93 0.75 0.54 0.40

0.00 0.00 0.00

0.00

0 00/01/1900 00:00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00

0.00 0.00

0.00 0.000 00/01/1900 00:00 0.00

0 00/01/1900 00:00 0.00 0.00 0.00 0.00

0 00/01/1900 00:00 0.00 0.00 0.00 0.00

0.00 0.00 0.00

0.00

0 00/01/1900 00:00 0.00 0.00 0.00 0.00 0.00

0.00 0.00 0.00 0.00

00/01/1900 00:00 0.00

0.00 0.00 0.00

0.00 0.00 0.000.00

2 15/05/2018

0.00

1 15/05/2018

4 15/05/2018

0.00 0.00 0.000

15/05/2018 05:32 - 06:02 7.15 6.89

8.98


HYDROGEN CHLORIDE: AST CALCULATIONS(Page 1 of 3)


3 15/05/2018



x, CEM (STP, WET)

mg/m³

y, SRM (STP, WET)

mg/m³

SRM (STP, DRY,

10% O₂) mg/m³

x - xav(A)

y - yav(B)

(A) x (B)

-0.60 0.49

01:32 - 02:02 8.70 5.96 7.118.37

0.00 0.00 0.000.00 0.00

0.00 0.00 0.00 0.00

7.65 7.32 8.74 -0.17 0.48 -0.08 0.036

0 00/01/1900 00:00 0.00 0.00 0.00 0.00 0.00 0.00

0.00 0.00 0.00 0.00 0.00 0.00 0.00

0.000 00/01/1900 00:00 0.00 0.00 0.00

0.00

0.00 0.00 0.00 0.00 0.00 0.00 0.000 00/01/1900 00:00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00

00:00

-0.87 -0.77

0.00

0 00/01/1900 00:00

8.40

Outliers Data

40

Date

00:00 0.00 0.00 0.00


0.00 0.00 0.00 0.00 0.00

2 INPUT

0.00

INPUT

0.00 0.00 0.00 0.00

0.00

INPUT

INPUT

INPUT 0.00


0.00 0.00INPUT

SELECT or TYPE INSELECT or TYPE INSELECT or TYPE IN


0.00 0.003 INPUT INPUT 0.00

0.00 0.0010 INPUT INPUT 0.00 0.00

SELECT or TYPE INSELECT or TYPE INSELECT or TYPE IN

6 INPUT INPUT


Pair

0.00

0.000 00/01/1900 00:00 0.00 0.00 0.00


0.00 0.00 0.00


5

00/01/1900


SELECT or TYPE IN

MAX SRM - MIN SRM 1.86 SUM -0.65 2.22(DAILY) DELV (mg/m³) 1095% CI MU (%)

0.00

0 00/01/1900

0.004 INPUT INPUT 0.00 0.00

0.00 0.00 0.00 0.00 0.00 0.00 0.000.00

0 0.00 0.000

00/01/190000:00


x, CEM (WET) mg/m³

y, SRM (WET) mg/m³

1 SELECT or TYPE IN

00:00








CAL CALCAL CEM SRM ys, SRM - Pair Date Time



CAL CEM


CEM CEM SRM CEM CEM SRM

0.0

2.0

4.0

6.0

8.0

10.0

12.0

14.0

16.0

18.0

20.0

00:0

0

00:3

0

01:0

0

01:3

0

02:0

0

02:3

0

03:0

0

03:3

0

04:0

0

04:3

0

05:0

0

05:3

0

mg/

m³

Time

HCl (CEM - 30 min)HCl (SRM - 30 min)

0.00 0.00 0.00

0.00

11.54 8.93

00:00

00:00 0.00

00:00 0.000.00 0.000.00 0.00

15/05/2018 00:32 - 01:02

0.00

0.000.00

0.00

8.37

16.43

0.00

00/01/19000.00

0 00/01/1900

0.00

00/01/1900

00/01/1900 00:00 0.00

0.00 0.00 0.000 00/01/1900

00/01/1900 00:00

0.00

0.00 0.00

0.00

0

0.00 0.0000/01/1900 00:00 0.00

0

0 00/01/1900

0.00

0.00 0.00 0.00

15.98

0.00

0.00

0.00 0.00 0.00 0.00

-2.614 15/05/2018 03:32 - 04:02 7.93 9.69 8.98

15.85

0.00

00:00

00:00

0.000 00/01/1900 00:00 0.00

0

00:00 0.00

00:00 0.00 0.00 0.00 0.00

00/01/1900

CAL CEM (STP, DRY,

10% O₂) mg/m³

SRM (STP, DRY,

10% O₂) mg/m³

ys, SRM - CAL CEM


0.00

0.00 0.00 0.00 0.00 0.00 0.000.00

11.51 7.11 -4.4016.23 15.79 15.91 10.19

0.00 0.00 0.00 0.00 0.00 0.00

3

0

0

15/05/2018 02:32 - 03:02 9.39

15.90 15.47 15.65 10.19 10.18 10.08

10.16

MAX 11.54 Sd 1.35

00:00 0.00

0.00 0.00 0.00

15.81

0.00 0.00 0.00

1 15.93 10.27 10.26

0 00/01/1900

0.00 0.00

15.42 15.54 10.23

CAL CEM (STP, WET)

mg/m³

10.18

6 15/05/2018 05:32 - 06:02 7.86 9.48

7.40 -2.782 15/05/2018 01:32 - 02:02 9.54

00:00 0.00

0.00 0.00 0.00 0.00 0.00 0.00

0.00

10.0416.20 15.76 15.83 10.38 10.37 10.21

16.02 10.29 10.28 10.31

0

5

00/01/1900 00:00 0.00 0.00 0.00 0.00

15/05/2018 04:32 - 05:02 8.40 10.10 8.74 -1.36

0 00/01/1900 0.0000:00 0.00 0.00 0.00

0

0 00/01/1900 0.00

0.00 0.00 0.00 0.00 0.00 0.00

8.19 -1.29

-0.71

0

00/01/1900 00:00 0.00

0.000 00/01/1900

00:00 0.00 0.00

0.000 00/01/1900 00:00 0.00 0.00 0.00

0.00 0.00

0 00/01/1900

10.18

0.00 0.0000/01/1900 00:00

0 00/01/1900 00:00 0.00

0 00/01/1900 00:00 0.00 0.00 0.00 0.00

0 00/01/1900 00:00 0.00 0.00 0.00 0.000 00/01/1900 00:00 0.00 0.00 0.00

0.00

10.21 10.05

0.00 0.000

0.00 0.00 0.00

0.00 0.00 0.00 0.00

0.00

0.00 0.00

0.000 00:0000/01/1900 0.00 0.00 0.00 0.00

0.00 0.00 0.00 0.00 0.00 0.00







16.25

0.00 0.00 0.00 0.00 0.00 0.00

0.00 0.00 0.00 0.00 0.00 0.000.00 0.00 0.00 0.00 0.00 0.000.00 0.00 0.00 0.00 0.00 0.000.00 0.00 0.00 0.00 0.00 0.00

0.00 0.00

0.00 0.00 0.00 0.00 0.00 0.000.00 0.00 0.00 0.00 0.00 0.000.00 0.00 0.00 0.00 0.00 0.000.00 0.00 0.00 0.00 0.00 0.00

0.00 0.00 0.00 0.000.00 0.00 0.00 0.00 0.00 0.000.00 0.00 0.00 0.00 0.00 0.000.00 0.00 0.00 0.00 0.00 0.00

0.00

0.00 0.00 0.00 0.00 0.00 0.000.00 0.00 0.00 0.00 0.00 0.00

0.00 0.00 0.00 0.00 0.00 0.00

0.00

0.00 0.00









Value Parameter ValueStandard Deviation (Sd) 1.35 Mean Difference (D)

2.86 t0.95 (N-1) x Sd / SQRT (N) + Q₀

2.015Kv for 6 Pairs of Data 0.9329

Parameter

Q₀ = ELV x (MU / 100) / 1.96 2.04 t0.95 (N-1)



2.191.5 x Q₀ x Kv 3.15Outcome of Variability Test Pass




a) Calibrated Range (10% extension) (mg/m³) 0 to 12.7b) Calibrated Range (50% of Daily ELV) (mg/m³) 0 to 5



14.0

16.0

18.0 DATE/S: 15/05/2018 to 15/05/2018


-4.0

-2.0

0.0

2.0

4.0

6.0

8.0

10.0

12.0

14.0

0.0 2.0 4.0 6.0 8.0 10.0 12.0 14.0 16.0 18.0

SRM

mg/

m³ (

REF)


HClCalibration Range





Calibration Data

28.11 33.70 2.18 -1.96 -4.28 4.75 33.70

-5.1629.39

0.000.00 0.00 0.00

28.06 30.31 36.04 -3.21 0.24 -0.77 10.30 28.49

00/01/1900 00:00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.000 00/01/1900

15:32 - 16:02 33.45

5.26

15/05/2018 07:32 - 08:02 34.51

00/01/1900 00:00

34.49

0.00 0.00

15/05/2018 03:32 - 04:02 28.99 31.16 38.18 -2.28 1.09 5.19

31.69

33.8113 15/05/2018 12:32 - 13:02 34.26 30.72 36.50

6 15/05/2018 05:32 - 06:028.47 7.52 34.25

09:32 - 10:02 33.6734.66 32.86 39.10 3.40 2.79 9.47 11.53 34.88

12 15/05/2018

31.90

0.10 -1.03 0.01

36.46 -3.08 -0.38 1.1615/05/2018 22:32 - 23:02 28.18 29.70

0.0000/01/1900 00:00 0.00

00:00 0.00

0.00 0.00 0.00 0.00

9.52 28.610

36.13

01:32 - 02:02 25.84

(Page 1 of 3)


Pair Date

15/05/2018 00:32 - 01:02 26.72 28.24 34.0925.17 35.37

y, SRM (STP, WET)

mg/m³

SRM (STP, DRY,

10% O₂) mg/m³

15/05/2018

0.000.00

15/05/2018 13:32 - 14:02 35.47

2.41 0.08 0.20 5.79

15/05/2018

3.24 1.83 5.94 10.51

6.15 17.69

22 15/05/2018 21:32 - 22:02 25.16

1.82 8.55 22.00

0.00

39.62 4.69

0 0.00

25.90

1415

15/05/2018 18:32 - 19:02

7 15/05/2018 06:32 - 07:02 34.01

0

18 15/05/2018 17:32 - 18:02 32.74 29.37

31.89 -6.11

0.00 0.000.00

33.5821 15/05/2018 20:32 - 21:02 29.78 31.36 38.02 -1.49 1.29 -1.92 2.21 30.15

33.16

1.94

34.739 15/05/2018 08:32 - 09:02 32.58

16 15/05/2018

31.37 29.05 34.96 -0.10

-4.18 25.51 37.32 25.6823

17

38.04 2.06 1.50 3.09 4.23

10 15/05/201810:32 - 11:02

31.91

11:32 - 12:02 33.56

14:32 - 15:02 35.96

30.43 36.54 2.29

33.0219

31.53

8 37.69

5

11 15/05/2018


AMMONIA: AST CALCULATIONS

26.50 26.6115/05/2018

8.31

3 15/05/2018 02:32 - 03:02 26.1125.84

x - xav(A)

y - yav(B)


mg/m³

130.84 -5.95 -4.232 15/05/2018


x, CEM (STP, WET)

mg/m³

10.90 26.62 26.60

9.58

25.3220.64 27.20

4 -2.4933.70 -5.15 -1.86

20 15/05/2018 19:32 - 20:02 33.32

16:32 - 17:02 35.14 30.92 38.02 3.88 0.84 3.27 15.04

31.57

27.96 33.87

28.21

-4.54 -1.83

31.31 36.93 1.31 1.24

35.21 1.47 -0.71

30.15 35.91

4.21 1.46

-2.11

35.66

35.34

39.34 2.74 3.09

38.64

0.83

0.00

0.36

-1.04 2.16

0.00

04:32 - 05:02 26.12

2.99 0.65

33.92

8.97

1.62 1.72

0.00 0.00

32.86

Daily

Outliers Data

INPUT INPUT 0.00


INPUT 0.00 0.00

0.003 INPUT

0.00 0.0000:00 0.00

119.57

00/01/1900 00:0000/01/1900

INPUT

0.0000:00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00

0 00/01/1900

0.00 0.00 0.00 0.00


0.008 INPUTINPUTINPUT 0.00

00

00/01/1900

0.00 0.000.00

0.00 0.00


0 0.00 0.00


4 INPUT INPUT

00:00 0.00

7 INPUT

INPUT 0.00 0.00

290.86ELV (mg/m³) 5095% CI MU (%) 40



SELECT or TYPE IN

1

SELECT or TYPE IN

0.00

x, CEM (WET) mg/m³

y, SRM (WET) mg/

cover me - daeraappsd.daera-ni.gov.uk/ipri/docs/p0052-04a lafarge ireland limited … · 4" bsp ea...

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