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Page 1: Copyright by Lei Lin 2004

Copyright

by

Lei Lin

2004

Page 2: Copyright by Lei Lin 2004

The Dissertation Committee for Lei Lin certifies

that this is the approved version of the following dissertation:

Integration of Thin Film GaAs MSM Photodetector in

Fully Embedded Board-level Optoelectronic

Interconnects

Committee:

__________________________________ Ray T. Chen, Supervisor __________________________________ Michael F. Becker __________________________________ Dean P. Neikirk __________________________________ Archie Holmes, Jr __________________________________ Bipin Bihari

Page 3: Copyright by Lei Lin 2004

Integration of Thin Film GaAs MSM Photodetector in

Fully Embedded Board-level Optoelectronic

Interconnects

by

Lei Lin, B.S.; M.S.

Dissertation

Presented to the Faculty of the Graduate School of

the University of Texas at Austin

in Partial Fulfillment

of the Requirements

for the Degree of

Doctor of Philosophy

The University of Texas at Austin

May 2004

Page 4: Copyright by Lei Lin 2004

DEDICATE TO

My parents, wife and daughter,

For their love and support

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Acknowledgements

My biggest thank goes to Professor Ray T. Chen, for his academic guidance,

personal patience and financial support. I am appreciative and thankful for Professor

Michael F. Becker, Professor Aechie Holmes Jr., Professor Dean P. Neikirk, and Dr.

Bipin Bihari to serve as my committee. Without their supports, this dissertation would

no have been written.

My thanks also go to my fellow students Chul Chae Choi and YuJie Liu for

their five years helps and collaboration. It is my deep pleasure to work with them as a

team. I thank the present fellow students in Professor Ray T. Chen’s group, Yihong

Chen, XuLiang Han, Brie Howley, Chiou-Hung Jang, Yongqiang Jang, Wei Jiang,

Jin-Ha Kim, Zhong, Shi. I am very obliged to Dr. DengChang An, Dr. LinHui Wu,

Dr. XueGong Deng, Dr. XueJun Lu and Dr. Jie Qiao for their companionship in UT

Austin.

Finally and not least I wish express my thanks go to my wife Wei Yu and my

daughter Denise Lin for their love, patience and emotional support. My thanks also

go to my parents XuGuo Lin and PeiYing Zhu, for their thirty years of love and

guidance. My final appreciation goes to my brother Bo Lin for his encouragement.

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Integration of Thin Film GaAs MSM Photodetector in

Fully Embedded Board-level Optoelectronic

Interconnects

Publication No. __________

Lei Lin, Ph.D.

The University of Texas at Austin, 2003

Supervisor: Ray T. Chen

Technology in 21 century has developed in an accelerated rate. As a

technology indicator of modern era, computer has developed from its early age to

ubiquitous equipment in every day life. The driven force for faster computer has

become even stronger. Together with the fast-evolved high-speed Internet, faster

computes are processing huge amount of data. Electrical interconnect between CPU

and memory has become the bottleneck of data processing in computer. The

foreseeable solution to address this bottleneck is to use optical interconnect replacing

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electrical interconnect. However, before this substation becomes reality, many

difficulties to integrate optics into VLSI system have to be addressed.

In this dissertation, a fully embedded optical interconnect system is proposed.

The main attribute of optical interconnect system with fully embedded form is the

high degree of reliability. Together with the high bandwidth, low power consumption,

the optical interconnect system is fully compatible with VLSI circuit and fully fulfill

the request of bandwidth between CPU and memory. The fully embedded optical

interconnect system includes three main components: thin film VCSEL (vertical

cavity surface emitting laser) as optical transmitter, thin film GaAs MSM (metal-

semiconductor-metal) photodetector as optical receiver and flexible polymer

waveguide as optical transmitting media. Thin film MSM photodetector array is

fabricated and integrated with channel waveguide array. The whole system

integration among thin film array of photodetector and VCSEL and thin film flexible

waveguide is presented.

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Contents Chapter 1 Introduction of Optical Data Links…………………………………..1

1.1 Overview of telecommunication…………………………………….....1

1.2 Timeline overview of computer………………………………………..3

1.2.1 Timeline of early age computer………………………………...3

1.2.2 Time line of modern computer……………………………........6

1.3 Historic evolution of internet and WWW (world-wide-web)……. …...10

1.4 Challenges faced by board level electrical interconnect……………….13

Chapter 2 Theoretical analysis of photodetector………………………………..20

2.1 Electrons in periodic structure……………………………………….20

2.2.1 Bandstructure of semiconductor……………………..………22

2.2.2 Conduction and valence band in semiconductors……...…….23

2.2.3 Density of States…………..…………………………………26

2.2.4 Band structures of Silicon and GaAs…………..…………….27

2.2.5 Electron transport property in semiconductor………………..32

2.2.6 Optical absorption of semiconductors………………….…….34

2.3 Semiconductor photodetectors……………………………………….35

2.4 PIN photodiode………………………………………………………37

2.5 APD (avalanche photoddetector)…………………………………….39

2.6 Metal-Semiconductor-Metal photedetector………………………….40

Chapter 3 Silicon and GaAs MSM photodetector………………………………47

3.1 Introduction………………………………………………………......47

3.2.1 Thin film silicon based MSM photodetector………………...48

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3.2.2 Fabrication of 1×12 thin film silicon MSM photodetector array..52

3.2.3 Testing of 1×12 thin film silicon MSM photodetector array….....59

3.3.1 GaAs MSM phodetector………………………………………....68

3.3.2 Testing of GaAs MSM photodetector array…………………......78

Chapter 4 Epitaxial liftoff GaAs MSM photodetector array and integration with

waveguide……………………………………………………………83

4.1 Introduction………………………………………………..................83

4.2 Thin film MSM phodetector array by epitaxial liftoff technique…....85

4.3 Design and fabrication of thin film GaAs MSM photodetector……..89

4.4 Characterization of thin film GaAs photodetector…………………..95

Chapter 5 Integration of board level optical interconnection system………….101

5.1 Introduction…………………………………………………………101

5.2 Integration of GaAs MSM photodetector array and polymer waveguide

array with 450 TIR micro couplers………………………………….104

5.3 Measurement of integrated GaAs MSM photodetector array and

polymer channel waveguide array………………………………….109

5.4 Integration of thin film GaAs MSM photodetector, channel waveguide

with micro-mirror coupler and thin film VCSEL…………………..112

5.5 Summary……………………………………………………………117

References…………………………………………………………………………..120

Vita………………………………………………………………………………….132

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List of Figures:

Fig. 1.1 Diagram of free space optical interconnect…………………………………15

Fig. 1.2 Diagram of fully embedded optical interconnect…………………………...17

Fig. 2.1 Electron energy levels in single atom and band structure in semiconductor..22

Fig. 2.2 band structure of direct and indirect band gap semiconductor……………...24

Fig 2.3 Band structure of silicon……………………………………………………..28

Fig 2.4 Band structure of GaAs……………………………………………………...29

Fig 2.5 Fermi distribution curve……………………………………………………..31

Fig 2.7 Schematic of PIN photdiode ………………………………………………...39

Fig 2.8 Schematic of basic APD structure …………………………………………..40

Fig 2.9 Intedigitated contacts pattern of MSM photodetector……………………….41

Fig. 2.10 Optical absorption coefficient of different semiconductor………………...43

Fig. 3.1 Cross section structure of Si MSM photodetectro…………………………..49 Fig. 3.2 Absorption coefficient of silicon……………………………………………50 Fig. 3.3 Band structure of Silicon…………………………………………………...50 Fig3.4, The energy-band diagram of MSM junction……………………………...…52 Fig. 3.5 Etched contact finger pattern of MSM thin film photo-detector……………55 Fig. 3.6. Active area of MSM silicon photdetector and finished MSM photodetector57 Fig. 3.7 The fabrication process of thin film Si MSM photdetector…………………58 Fig. 3.8 Formation of Schottkey barrier between metal and semiconductor………...60 Fig 3.9 I-V of thin film silicon MSM photodetector………………………………...61

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Fig. 3.10 Measurement setup for test of thin film silicon MSM photodetector…….65 Fig. 3.11 Measurement setup and test of thin film silicon MSM photodetector……66 Fig 3.12 3dB bandwidth of thin film silicon MSM photodetector…………….……68

Fig. 3.13 Band structure of GaAs……………………………………………………70

Fig 3.14 Design of GaAs MSM photodetector………………………………………71

Fig 3.15 Contacting finger pattern of GaAs MSM photodetector…………………...75

Fig. 3.16 Interdigitate finger pattern of GaAs MSM photdetector…………………..77

Fig. 3.17. Array of GaAs MSM photodetector………………………………………77

Fig 3.18 2.648 GHz 3dB bandwidth of GaAs MSM photodetector…………………82

Fig 4.1 Step one of epitaxial liftoff thin film GaAs device………………………….86

Fig 4.2 Step two of epitaxial liftoff thin film GaAs device………………………….87

Fig. 4.3 Design of thin film GaAs MSM photodetector……………………………..90

Fig. 4.4 Design of epitaxial liftoff thin film GaAs MSM photodetector……………91

Fig 4.5 finished thin film MSM GaAs photodetector……………………………….94

Fig 4.6 Process of epitaxial liftoff thin film GaAs MSM photodetector……………96

Fig. 4.7 4.9 GHz 3dB bandwidth of epitaxial liftoff GaAs MSM photodetecter…..100 Fig. 5 1. System architecture of fully embedded optical interconnect……………...103 Fig. 5.2 Schematic integration of GaAs MSM photodetector and waveguide with

micro coupler……………………………………………………………………….106

Fig. 5.3 Channel waveguide array with fully embedded 45o TIR micro coupler…..108

Fig5.4 polymer channel waveguide array integrated with MSM GaAs photo detector

array……………………………………………………………………………….109

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Fig. 5.5 Cross talk measurement of channel array waveguide…………………….111

Fig. 5.6 450 mirror surface of soft molding waveguide……………………………113

Fig.5.7. 10 µm thick thin film VCSEL array………………………………………114

Fig. 5.8 10 µm thin film VCSEL with electro-deposited Cu heat sink…………….115

Fig. 5.9.Integrated GaAs MSM photodetector and VCSEL array with flexible

waveguide…………………………………………………………………………..117

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Chapter 1

Introduction of Optical Data Links

1.1 Overview of telecommunication

Optical communication dates back four thousand years ago when ancient

people used fire to signal to each other. As recorded in human history, people in

ancient Egypt used fire to transfer military messages. Even though humans had

realized that messages can be transferred through open space, there were many

limitations of this communication method. The most severe disadvantage was that the

signal was not visible over a very long distance so that there had to be many relay

stations to sustain the signals. The starting point of real implementation of long haul

communication began on Friday, 13 July 1866 when the largest ship at that time with

2730 nautical miles of copper cable in her hold, left Valentia, Ireland and bound the

destination Trinity Bay, Newfoundland. The mission of the ship was to lay down a

line of copper cable through Atlantic Ocean. The copper cable was laid down through

Atlantic Ocean and telegraph message started to be sent between the two continents

through this copper cable. This event opened up one hundred years of

telecommunication using copper cable.

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The idea of using optical light to transmit message was conceived even before

the telecommunication using copper cable took place. Around 1790, a French

engineer, Claude Chappe originated “optical telegraph”. The method was to build a

series of towers 10-15 km apart, equipped with telescope. The wooden beam on the

tower could stand out different positions that were assigned to numeric symbols in

connection with a codebook. While a message took days to transmit with this set up,

individual symbol may reach transmission speed up to 500 km per hour. This was a

novelty try-out without much impact on telecommunication because of the

complexity, high cost, slow transmission speed and lack of security.

Late eighteen century witnessed the rapid development of telecommunication

using copper cable. However, the scene of telecommunication was totally changed by

the invention of laser around 1960.1-3 Research of telecommunication using laser as

the source of signal was renewed, but the main focus was on transmitting laser

through open space4-6. This direction of research did not capitalized because of its

fundamental shortcomings. Even though laser light kept its focusing power very well

through long distance; the heavy absorption of atmosphere to laser beam causes so

high loss of its intensity that it could not travel long distance.

The real breakthrough emerged, almost one hundreds years after the first

trans-Atlantic cable was laid down on the bottom of Ocean. Optical fiber, the real

player of transmitting media in telecommunication industry came to light around

1970’s when three Corning scientists, Dr. Donald Keck, Dr. Bob Maurer and Dr.

Peter Schultz invented low loss optical fiber7-9. The revolution of replacing copper

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cable with optical fiber took place after Corning announced their low-loss fibers,

which showed loss below 20dB/km at the 633nm helium-neon wavelength. The

development of optical interconnect technology using fiber optics in the 1970s was a

milestone of the modern telecommunication industry. Replacing copper cables with

optical fiber provided superior performance in term of the wide data bandwidth, low

loss, and reduced noise level. It also significantly reduced the cost of communication

system. Even in the early stage of developed optical fibers, they were able to transmit

65,000 times more information as copper wire10.

1.2 Timeline overview of computer

1.2.1 Timeline of early age computer

The first computing device as we know today is abacus that appeared circa

1200 AD in China. The abacus was man’s first attempt to automat the counting

process. Strictly speaking, the abacus is more a device to remember the current state

of computing than a device to really compute numbers. For over a thousand years

after the invention of abacus, automatic computing remained in same way. The

automatic computing machine came to light when a British mathematician and

inventor, Charles Babbage, designed and built it around 1820s. The machine was

called difference engine and it could perform simple mathematical calculations. The

difference engine consisted entirely of mechanical components and numbers were

represented in the decimal system. The device Babbage built was far from real

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computing machine by modern standard, but it did demonstrate that machine could

automatically perform mathematical calculations.

The calculating principle of modern computer was invented by another British

mathematician; Alan Turing. Turing conceived the computing machine with limitless

memory and digital inputs and outputs11-12. The machine read a series of zeroes and

ones through a magnetic tape. These zeroes and ones were the instructions and data

on which the machine need to process. Even though this is a well accepted idea today,

this was a revolutionary concept at that time since all other design of calculate

machine only performed a particular task on a limited range of purposes. Turing’s

idea was brilliant for the time. To modern standard, however, the machine he built

was very slow in speed. With the ongoing World War II, British were in a critical

moment to defend their air space in order to stop German amphibious invasion. It

would put British Military in a great advantage if the enemy’s encoding message

could be deciphered. It was at that time when Dr. Turing designed British Colossus13,

a completely electronic computer capable of deciphering encoded messages of

German military. It used paper tape reader to input data and 2400 vacuum tubes to

make up the electrical calculating system. The Colossus deciphered German military

code quickly and efficiently. It was considered as the first step towards modern

computer.

Different steps were taken in US to build military computer. J. Presper Eckert

and John William Mauchly of the University of Pennsylvania built Electronic

Numerical Integrator and Computer (ENIAC) 14-16. It took three years for J. Presper

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Eckert and John William Mauchly to build the machine. Physically ENIAC was

gigantic, it contained more than 18,000 vacuums, 70,000 resistors, 10,000 capacitors

and it weighted 30 tons. It used 160kW electricity when it fully operated. Because the

bulkiness and huge power consumption, it was one time design and it would never be

redesigned nor upgraded.

The real computing machine for normal people was yet to come with other

technology breakthrough. The technology breakthrough did come in 1947 when three

Bell Lab scientists, John Bardeen, Walter Brittan and William Shockley invented first

transistor17,18. The invention led them to share Nobel Prize in physics in 1956. The

invention of transistor sparkled people to produce computer by transistors. Even

though transistors are remarkably smaller than vacuum tubes and they consume far

less power, computers made by transistors were still very bulky, inefficient and slow.

The tide to make computer by using transistors did not last long because of all the

disadvantages of transistor. In early days, electronic circuit were composed of many

individual components such as resistors, capacitors, inductors, diodes, vacuum tubes

etc.. With the invention of the transistors, vacuum tubes were obsolete and replaced

by transistors. As a result, electronic circuits could be made more complex, much

faster because transistors are much smaller and switch much more rapidly. But the

construction techniques of those circuits reached their limit quickly. It was still very

hard to assemble too many transistors on the circuit board. These transistors could not

be arranged closed enough to keep signal, among those transistors, to travel at decent

delay time.

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Another brilliant invention came to the light around 1958 when scientist Jack

Kilby19-20 of Texas Instrument conceived a way to fabricate many electronic

components on a piece of semiconductor and as a result, integrated circuit was

developed. Not only could many transistors be made at once on a piece of

semiconductor, but also other electrical components such as resistors, inductors,

capacitors could be made by the same process as well. By fabricating all the

electronic components on a piece of semiconductor, IC (integrated circuit) was

invented. IC leads to the building of the microchip, which is the heart of today’s

computer. As a matter of fact, ENIAC, the first electronic computer made from

vacuum tube that weighted 30 tons and consume 150 kW power, could be redesigned

and be made by IC and it could be as small as a hand held calculator. Only after the

maturation of IC could make today’s computer a reality, and the bulky, expensive and

huge power consuming computer made from vacuum tubes quickly became history.

With the invention of IC, much of the computer’s computing abilities, addition,

subtraction, multiplication, division and logic operation could be located on a single

small chip.

1.2.2 Time line of modern computer

In 1971 Intel released the world’s first commercial microprocessor21,22, the

4004. This processor could only process 60,000 instructions per second. It used 2300

transistors and had 108 kHz clocking speed. A year later Intel introduced

microprocessor 8008, which was twice as powerful as microprocessor 4004. It used

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3500 transistors and had 200 kHz clocking speed. The continue line of processor from

Intel constituted 8080 processor in the late 70’s which was developed into 8086 and

8088 in 1979. The processor 8086/8088 was a central processing unit of computer; it

acquired data and instruction form and wrote result back to Random Accessed

Memory (RAM) upon its finishing computing. The maximum clocking of 8086 and

8088 were 8 MHz and 10 MHz respectively and the transistor usage was 29,000. The

maximum physical memory of 8086 and 8088 was one megabyte.

In 1982 Intel introduced processor 80286, which was an enhanced version of

processor 8086; its main enhancement lied on the ability to access 16 megabytes of

memory. With the increased ability to access memory, processor 80286 was the first

to run all of the software written for its predecessor. Its clocking speed was between

6MHz to 12.5 MHz and the transistor usage was 134,000.

In 1985, Intel introduced 386-processor, which was the first to use 32-bit

addressing and it could utilize up to 4 Gigabytes of memory. This was the first time

when concern of interconnects came to the light because of CPU’s capability to

address the large quantity of memory. Its clocking speed ran through 16 MHz to 40

MHz and transistor usage was 275,000. There were foreseeable instances that there

existed discrepancy between the processing speed of CPU and the slow fetching rate

of data and instructions from main memory. There was no imminent call for the

increasing of bus speed because CPU processing speed was still under 100 MHz and

it took several CPU clocking cycles to fetch a single instruction or datum from main

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memory. At the time of Intel 386 was used, the CPU, memory and bus were all

clocking at the same speed.

In 1989 Intel introduced processor 486 which could run even higher clocking

speed than its predecessor. The transistor usage was 1.2 million and clocking speed of

486 ran through 25 MHz to 33 MHz and later up to 100 MHz. It was at that time

when the different running speed between processor and memory emerged. A

computer's memory is the repository for all the information used by and produced

from the computer's CPU. At processing speed of 100 MHz, the processor met the

problem of waiting data and instructions coming out of the memory.

From time on, cache memory started to appear on same die with CPU. Cache

memory typically exploits the principle of spatial locality of references by pre-

fetching a fixed amount of data and instructions that are contiguous to the referenced

data and instructions. The caches are generally made up of static random access

memory (SRAM) and faster than random access memory (RAM) although more

power is used and more chip area is occupied. The widening gap of speed between

the processor and memory has lead to employment of cache memory. In the next

design of processor 486, Intel included eight kilobyte Level 1 cache memory on CPU

chip. On that chip, there was some flexibility on data handling; CPU could use some

data and instructions on the L1 cache to compensate the waiting period of the data

and instructions being fetched from main memory.

In 1993, Intel debuted its first Pentium processor that used 3.1 million

transistors and had the clocking speed either 60 or 66 MHz. Not only did the usage of

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transistors and the clocking speed was increased, but the L1 cache memory was

increased from 8 kilobytes to 16 kilobytes as well. The processor Pentium Pro was

unveiled in 1995 and the transistor usage and the clocking speed were increased to

5.5 million and 200 MHz, respectively. Besides the 16 kilobytes L1 cache memory

that located close to main processing unit of CPU, a 256 kilobytes or 512 kilobytes

L2 cache memory was also included in Pentium Pro processor as well.

After the clocking speed exceeds 100 MHz, there is a growing discrepancy

between the operation speed and the speed of feeding data and instructions from main

memory. There were several main reasons to include cache memory. The general rule

of super fast computing relies not only on how fast the CPU runs, but also sufficient

data and instructions have to be fetched out from memory at high speed. Since the

reality of slow bus speed of the motherboard, the cache memory was introduced.

Cache memory permits CPU fetching data and instructions in a batch instead

of fetching them one by one. This certainly speeded up CPU’s processing speed

dramatically as long as the program to be run by CPU was in a good series order. If

the program was in an odd series order and CPU could not predict well of adjacent

data and instructions then there would be a high probability that following data and

instruction would not be fetched on time in the cache memory. In this case a delay

penalty would occur; CPU would wait the right data and instruction be fetched out

from main memory, as the result a miss penalty would occur and the processing speed

would dramatically reduced.

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There are many algorithms to address this issue and different tradeoffs had to

be made. However, miss penalty always exists as long as the data and instruction sets

are not fetched from main memory directly. In order to fully utilize the 512 kilobytes

L2 cache memory, Pentium Pro CPU used three instruction-decode-units to work in

parallel to decode object code into smaller operations called “micro-ops”. The break

down instructions went into an instruction pool and could be executed out of order by

execution units. Suppose there were optical interconnects exist at that time to

substitute electrical interconnect, and ran at speed faster than CPU, the whole history

of computer architecture would be rewritten and there would be a big waste to include

any cache memory on the same die with CPU.

In 1999 Intel unveiled Pentium III processor. It employed 9.5 million

transistors and the clocking speed ran between 650 MHz to 1.2 GHz. The cache

memory sizes were either 256 kilobytes or 512 kilobytes. The minimum line width of

transistor had shrunk from 0.25 to 0.18 micron meters. It was the new minimum line

width of transistor to make this high processing speed possible. Even though the bus

speed had also increased from precious 66 MHz to 100 MHz, the speed mismatch

between CPU and memory still existed. Higher bus speed and large on-chip cache

memory helps the situation of this speed mismatch, it sacrificed the performance

dramatically if miss hit in the cache memory happened; CPU would suffered long

waiting time for data and instruction sets to be fetched from main memory.

1.3 Historic evolution of internet and World-Wide-Web (WWW)

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The fast evolution of computer’s processing speed was partially intrigued by

the fast development of internet, also called world-wide-web. Usually high

technology instruments and apparatus were driven by either military requests or

simply by government funding to explore unknown boundaries of mankind. In the

early years of computer development around the time of World War II, it was the

imminent request to break German military code to motivate British Scientist Alan

Turing to construct Colossus, the first electronic computer to efficiently break

German code in time. However, the computer industry would have little chance to

boom without big consumer market. At early stage of the computer development, the

highest processing speed at that time was needed. However this need only came from

scientific research field and cost of that high speed processing could somehow

overlooked, if noticed at all. The sole motivation from scientific field could not

sustain the continuous development of the processing speeds of chips if the broad

consumer market was not created. That consumer market was finally generated with

emerge of array of software that could be run on computers. The need of faster

computer processing speed was intensified by the advent of internet and later the fast

communication speed of the internet. Information now could be transferred up to 155

Mega bytes per second and the data transfer speed up to 10-20 Giga bytes per second

is being under test23. Instead of word processing ability of the computer in the early

days, now computers send and receive large amount of information from internet and

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accordingly process those information. It is already a reality that computers handle

from low speed word processing to high speed graphic processing.

The world-wide-web was originated from the era of Cold War. The

hypothesis was that if the nuclear war happened, would military units and different

government agencies communicate? A centralized communication system would be

easily destroyed; a whole new way of communication had to be developed. In 1972,

Defense Advanced Research Projects Agency (DARPA) funded a project to develop

a way for computers to communicate with each other. It was hoped that safe

communication among computers from military and different government agencies

would be in a secure command and control over information during the wartime. The

project first brought online computers from four US universities. The universities

were University of California at Los Angeles, University of California at Santa

Barbara, University of Utah and Stanford University. The initial prospective of the

project assured that the internet was designed to be functional even in case some

nodes were destroyed. If the most direct route was impassable, then information could

still be directed through alternate routes. Soon after the establishment of internet, first

email was sent in 1972. A year later, File Transfer Protocol (FTP), enabling file

transfer between different internet sites, was established. It would allow anyone who

had the privilege to access the site to get file either download from or upload to the

serve site. In 1986, a cross-country 56 Kbps backbone of internet was accomplished

from support of National Science Foundation. As the protocol of internet became

standard, it reached everyone who had the access of the online computer.

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There are two driven forces for higher processing speed of computer, one from consumer market and

the other from military. From consumer market, the rapid proliferation of affordable computers and

fast connection to the world-wide-web enable computers to process huge amount information at short

period of time. This force requires that even higher processing speed to be pursued. And the disparity

of speed between BUS and CPU become even more prominent. Another driven force for higher

computing speed comes from military. Military needs highest computing speed for the application

from simulated nuclear explosion to guided missile recognition system. Many times the highest

processing speed is sought after with emphasis on reliability and little attention is paid on cost.

1.4 Challenges faced by board level electrical interconnect

The development of optical interconnect technology using fiber optics in the

1970s was a milestone of the modern telecommunication industry. Replacing copper

cables with optical fiber provides superior performance in term of the wide data

bandwidth, reduced noise, and low loss. It also significantly reduces the cost of

communication system. But the early success of optics in telecommunication industry

did not inspire the electronic designer to adopt optical components into the computer

system design. In particular, progress in inserting optical components and

interconnects into digital system has been hindered by the relative high cost of the

discrete optical components, by the lack of a flexible transmission medium that can

be planar processed for the board level application, and by the lack of a packaging

platform that can be used for both optical and electronic devices24. For practical

purposes, the cost/performance benefit does not justify the use of optical technology

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within a computer system at a clock frequency much lower below 1GHz. The

situation has drastically changed in recent years because:

(1) The rapid advancement of the microelectronics technology has significantly

increased the chip speed, interconnected complexity, I/O pins, and processing

power, with clock speed now reaching 3GHz commercially and still increasing.

(2) The use of parallel processors as the prevailing supercomputing architecture has significantly

increased the number of the processors in high-performance computing.

(3) The exponential growth of network computing and global communication

networks such as the Internet has created significant traffic that demands

computer to process much larger quantity of information.

The increased complexity required for high-speed, high-density cross-

platform interconnects has made electrical wiring interconnect system more costly. In

today's applications, data transfer rates exceeding gigabits per second are common in

distributed computing systems, interactive multimedia, high-speed ATM switching,

and network communication. A cost effective, wideband interconnect solution for

high-speed data communication between chips, modules, boards, and backplanes is

critically needed in all these systems.

Recently, significant advances in optical materials, devices, and packaging

technologies have made optical interconnects the viable wideband interconnects

technology of choice. These enable technologies are Vertical Cavity Surface Emitting

Laser (VCSEL) array25, polymer based optical waveguide26 and high-speed photo-

detector array27. All of these opto-electronics can be handled, processed, and

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packaged much like IC devices using planar fabrication and batch processing. These

characteristics of optical materials are key requirements for low-cost, large-volume

manufacturing.

There are two ways to optically connect different destinations, the free

space28,29 optical interconnect and the guided wave optical interconnect.30,31 When

using the free space optical interconnect approach, the optical signal is generated

from a emitter (VCSEL), focused by lenses and transmitted through open space

before it reaches the receiver (photodetector). This architecture is illustrated in Fig.1.

The advantage of the free space optical interconnect is low loss in optical energy. The

disadvantage of this method is the issue of reliability. Because free space optical

interconnect rely on lenses to focus laser beam both form VCSEL and to the

photodetector, this approach places a heavy burden on packaging to ensure reliability

issue. Also using optical lenses results bulkiness in the system. For these

disadvantages, the free space optical interconnect system should not be implemented

if the reliability of connection is emphasized.

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source detectorlens lenssource detectorlens lens

Fig. 1.1 Diagram of free space optical interconnect

Another optical interconnect approach is the guided wave optical interconnect.

In this method, optical receiver and emitter are connected by polymer waveguide.

Compared with the free space optical interconnect approach, this technique provides

structure stability and easiness of implementation. The best way to realize the guided

wave optical interconnect is to embedded the whole layer of optical interconnect

between PCB (printed circuit board). The diagram of the fully embedded optical

interconnect is presented in figure 2. In order to implement the fully embedded

optical interconnect; the characteristics of three main components have to be

investigated. The three components of fully embedded optical interconnect are thin

film detector as the receiver, thin film VCSEL as the emitter and thin film polymer

waveguide and micro-coupler mirror as the transmitting media.

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Fig. 1.2 Diagram of fully embedded optical interconnect

There are five chapters in this dissertation. In the following chapter, the

theoretical analysis of the photodetector is presented. First, the basic concepts of

electrons and holes in a semiconductor are discussed, followed by the introduction of

density-of-states and band structures of silicon and GaAs. Then the electron and hole

transport properties in semiconductors are analyzed, followed by a discussion of

optical absorption in semiconductors. The light absorption in a semiconductor and

photo-detection rely on the excitation of electrons from the valence band into the

Waveguide

Thin-film VCSEL

Polymer Waveguide

Interlayer Dielectric

Electrical Interconnects

VCSEL

Polymer Waveguide Index Buffer Layers

To receiving IC

Electrical interconnect Layers Photodetector

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conduction band. The operating mechanism of semiconductor photodetectors is then

introduced, followed by the description of different types of semiconductor

photodetectors. The photodetectors discussed are PIN photodiodes, Avalanche Photo-

Detectors (APD), and Metal-Semiconductor-Metal (MSM) photedetectors.

In Chapter 3, MSM photodetectors are discussed. The main focuses are on the

thin film silicon based MSM photodetector array and GaAs based MSM

photodetector array. The detailed fabrication processes and characterization of these

two types of MSM phtodetectors are followed.

In Chapter 4, the thin film GaAs based MSM photodetector is first introduced.

Then the epitaxial lift off technique is presented. The epitaxial lift off technique is

used to acquire thr thin film GaAs MSM photodetector array. This technique enables

the hetero-integration of the thin film GaAs photodetector array with the thin film

VCSEL array and the polymer waveguide array. Upon the successful fabrication of

the thin film GaAs MSM photodetector array, its DC and temporal responses are then

measured.

In chapter 5, the integrated system is first proposed. Then the crosstalk of

1×12 polymer waveguide array was first measured before the integration. It is

followed by the integration of the GaAs MSM photodetector array and the 1×12

polymer waveguide array with 450 TIR micro-mirror coupler. The properties of the

integrated system are then investigated. Finally the whole system integration is

presented. The integrated system is composed of the thin film GaAs MSM

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photodetctor array, the thin film VCSEL array and the 1×12 polymer waveguide array

with total internal reflection (TIR) micro-mirror coupler.

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Chapter 2

Theoretical analysis of photdetectors

2.1 Electrons in periodic structure

Every semiconductor device involves electrons and holes in a bulk

semiconductor material. According to the different band structure, semiconductors

are divided into the direct band semiconductor and the indirect band semiconductor.

The mostly used direct band semiconductor and indirect band semiconductor are

GaAs and Silicon, respectively. In order to investigate different electrical and

photonic process in semiconductors, the transport property of electrons and holes has

to be investigated. To examine electrons inside a solid material we need to use

quantum mechanics, i.e., the Schrödinger equation.

)()()(2

2

0

2

rErrVm

Ψ=Ψ

+∇

− h 2.1

ψ(r): electronic state or wavefunction.

E: electronic allowed energy or eigenvalue.

V(r): background potential that is periodic in crystals.

The above equation is impossible to solve if an accurate solution is requested.

Because there are nearly 1023 atoms in a 1 cm3 volume, if there is only one free

electron in one atom then there are 1023 electrons. Those electrons interact with each

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other. Normally the above equation is not solvable because there are many

interactions between nuclei and electrons. Fortunately many solid materials, include

semiconductors, are periodic in structure and in potential. So there are two

assumptions have to be made before equation 2.1 is to be solved. First assumption is

that V(r), the potential seen by electrons has periodicity as the lattice

V(r) = V(r+R) 2.2

where R is the lattice constant.

Second assumption is that even though every electron belongs to a specific nucleus,

the electron finds itself in the field of all nuclei and all other electrons.32 Based on

these two assumptions, the probability of finding electron is to be the same in all unit

cells of the solid because every cell is identical. The Bloch theorem gives the form of

the electron wavefunction in a periodic structure and states that the eigenfunction of

electron wave is the product of a plane wave eik•r times a function which has the

same periodicity as the periodic potential. Thus

(ψ)k(r) = V k(r)eik•r 2.3

is the form of electronic function. The wavefunction has the property

(ψ)k(r+R) = V k(r+R) eik•(r+R) = V k(r)eik •r eik•R = (ψ)k(r) eik•R 2.4

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Atomic levels ofIsolated atoms

E

1s

2s,2p

3s, 3p, 3d

4s

4p

Allowed bands of crystal

Fig. 2.1 Electron energy levels in single atom and band structure in semiconductor

2.2.1 Bandstructure of semiconductor

The Bloch theorem states that the electron wavefunction in a crystal has a

particularly simple form; it is the product of a plane wave and periodic part of a cell.

As shown in Fig. 2.1 there are different energy levels in discrete atoms, as atoms are

brought closer and closer to each other to form crystal; the electron on a given atom

starts to see the neighboring nuclei and other electrons, the discrete atomic levels start

to broaden to form bands of allowed energies to be separated by gap. The allowed

energy levels are called the conduction band and the valence band; the gap between

energy bands is called the forbidden band. In the bound state, the electron energy is

negative with respect to the vacuum lever.

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2.2.2 Conduction and valence band in semiconductors

The solution of Schrödinger equation in a crystal gives E vs k relationship that

has regions of allowed bands separated by forbidden bandgaps. If the temperature is 0

K, the valence band of a semiconductor is totally filled and the conduction band is

totally empty. When a band is empty, it cannot conduct current; when a band is

totally filled, it cannot conduct current either. When solving Schrödinger equation,

the top of valence bands of most semiconductors occurs at effect momentum k=0, the

bottom of the conduction bands in some semiconductors occurs at k=0. These

semiconductors are called direct band gap semiconductor, such as GaAs, InP,

InGaAs. In other semiconductors, the bottom of the conduction band shift from k=0

to some degree, these semiconductors are called indirect band gap semiconductor,

such as Si, Ge, AlAs. The bandstructure of direct band gap and indirect band gap

semiconductor is shown in Fig. 2.2. The relationship between the energy and

wavevector k is

∑=

−+=

zyxi i

iic m

kkEkE,,

02

2)()( h 2.5

if the band structure is isotropic as in the case of direct band gap semiconductor

materials, then the relationship simplifies as

∗+=mkEkE c 2

)(22h

2.6

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Fig. 2.2 band structure of direct and indirect band gap semiconductor

Near the band edges, the electrons in semiconductor behave as if they have a

mass m* which is called as effective mass. For direct band gap semiconductors, the

relationship is

y

cv

Emp

mm 20

2

0

211+≅∗ 2.7

where eVEm

p

y

cv 202

20

2

≅ and m0 is the free electron mass.

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Semiconductors are defined as materials in which the valence band is full of

electrons and the conduction band is totally empty at 0 K. As the temperature arises,

some of the electrons in valence band leave valence band and enter into conduction

band. When all the valence band states are occupied, the sum over all wavevector

state is zero.

2.8

this formula simply shows that there are as many as positive k states occupied as

negative k states. When an electron at wavevector ke is missing, it is called a hole in

valence band and the wavevector of the system –ke is attributed to it. The relationship

between wavevector of hole and electron is

ekk

ii kkkei

+== ∑∑≠

0

eh kk −= 2.9

Even it is called a hole in valence band; it is the representation of a missing electron

in valence band. If the electron is not missing and valence band is full then electrons

cannot carry any current in valence band. However, if an electron is exited into the

conduction band, not only the electron in conduction band can carry current, but the

missing state, the hole in valence band can carry current also if the electric field is

applied. The hole in valence band acts as if it has a positive charge.

)( BvEedt

dkh

h ×+=h 2.10

where and are the momentum and velocity of the hole. hk hv

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2.2.3 Density of States

The electronic states in a semiconductor have a plane wave form modulated

by the central cell part. Near the band edge, the relationship of momentum and energy

is in the simple parabolic form

∗=mkE

2

22h 2.11

where is the effective mass. ∗m

Density of state is the number of available electronic states per unit volum per

unit energy around an energy E. If the energy of discussion is near the band edge and

parabolic relationship between momentum and energy is assumed then the density of

state is expressed as

32

2/12/3)(2)(

hπEm

EN dos∗

= 2.12

In semiconductor hetero-structures the electron can be confined in a two-dimension

stricture, quantum well, the density of state is expressed as

2)(hπ

= dosmEN 2.13

If a one-dimension structure is produced in a quantum wire, the density of states is

expressed as:

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2/12/1)(2)(

−∗

=Em

EN dos 2.14

for direct bandgap semiconductors, the density of state mass for the conduction band

is the same as the effective mass

∗∗ = mmdos 2.15

for indirect bandgap material in which the effective mass is different in various

directions, density of state mass is

3/1321 )( mmmmdos =∗

2.16

where m1,m2,m3 are the effective mass in the three principle directions.

2.2.4 Band structures of Silicon and GaAs

Silicon is the most important semiconductor material used in chip fabrication.

The semiconductor industry claims world wide sell $140 billion back in 1996 and

silicon consist of more than half of the big market.34 Up to date silicon is still the

unchallenged material in semiconductor industry. Silicon is an indirect band material,

means that the minimum of band gap dose not occur at k=0. The k position at

minimum of the conduction band and k position at maximum of the valence band

does not coincide, as shown in Fig. 2.3.

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Fig 2.3 Band structure of silicon

The band gap of silicon is

)(6361037.417.1

24

eVT

TEg −×

−=−

2.17

The other properties of silicon are as follow; density of state mass = 1.08 m0, heavy

hole mass = 0.49 m0 and light hole mass is 0.16m0. Intrinsic carrier concentration at

300K is 1.5x1010cm-3. As an indirect band material, silicon has poor optical properties

because light cannot be absorbed efficiently to generate electrons in the conduction

band and holes in the valence band. However silicon is still the backbone material in

chip industry as the results of long time highly reliable processing technology

developed by semiconductor industry.

GaAs is the main material in opto-electronic industry. Its usage extends from

light emitting diode (LED) to different semiconductor lasers.

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Fig 2.4 Band structure of GaAs

The band gap of GaAs is direct and shown in Fig. 2.4. This is the main reason that

GaAs is widely used in opto-electronic industry. Also the fast electronic transport

property makes GaAs the material of fast transistor manufacture. The band gap of

GaAs is

eVT

TEg 204104.5519.1

24

−=−

2.18

The other properties of GaAs are as follow: Electron mass is m*=0.067m0 in the

conduction band. In the valence band, light hole mass is 0.08m0 and heavy hole mass

is 0.45m0. Intrinsic carrier concentration at 300K is 1.84x106cm-3. Because the band

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edge E vs k relation is quite isotropic, the relationship of energy and wavevector k can

be expressed as

∗=mkE

2

22h 2.19

where =0.067m∗m 0.

Previous the semiconductor material was treated at 0K temperature where the

valence band is totally filled and the conduction band is totally empty. At this

circumstance current cannot flow through semiconductor even an electrical field is

applied. Thus at low temperatures the pure semiconductor exhibits very high

resistance to current transport. Electrons obey Pauli exclusion principle; which states

that one state at the same time can only accommodate a single electron. At finite

temperatures, the occupation of electrons and holes is governed by Fermi distribution

formula as in Fig. 2.5

TkEEEf

B

F−+

=exp1

1)( 2.20

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Fig 2.5 Fermi distribution curve

As temperature is raised, the shape of Fermi distribution function changes and

some electrons are exited from the valence band to the conduction band. Now there

are electrons in the conduction band and holes in the valence band and current can be

carried through semiconductor. Besides the excitation from temperature, electrons

can be exited from valence band to conduction band by optical energy. This is the

basic ideal behind every photo detective sensors. The concentration of electrons in the

conduction band is

dEEfENncE

e )()(∫∞

= 2.21

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where Ne(E) is the electron density of states near the conduction bandedge and is

the Fermi function. For a three dimension system and the expression of N

)(Ef

e(E)

and , the concentration of electrons in conduction band is expressed as )(Ef

∫∞∗

−+

−=

Ec

B

F

ce

TkEEdEEEmn

exp1

)()2(21 2/1

2/32hπ 2.22

The hole distribution function fh is

][exp1TkEEff

B

Feh

−−≅−= 2.23

the approximation of hole distribution is based on the TkEE BF >>− .

2.2.5 Electron transport property in semiconductor

The electron wavefunction is in the form:

)exp()exp(),( , tirikutk kn ω•=Ψ 2.24

where )(kE=ωh . If an electron occupies a certain energy level and has a momentum

k at time t0, it remains at the same state throughout its lifetime provide its

environment is the perfect crystal. When the external electrical field is applied, the

electron obeys free Newton’s law that is expressed as

extFdtdk

=h 2.25

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If the above-mentioned scenario is totally true, then the electrons can be

accelerated indefinitely. In reality though, there are numerous defects in even

“perfect” crystal, electrons will be scattered before reaching the edge of Brillion zone.

Furthermore, there are vibrations of the lattice atoms and electron sees the vibration

of lattice as scattering facter too. If a group of electrons move initially with the same

momentum, because of the scattering either from the imperfection of lattice or the

vibrations of lattice the momentum and energy of electrons will gradually lose

coherence with the initial states. The time it takes to lose initial coherence is called

relaxation time.

When an electron is under an electrical field, the electron tends to move in the

opposite direction of the field and gain velocity from the field. The velocity an

electron gained through electrical field is called drift velocity. The average drift

velocity is the velocity gained by electron form the electrical field during the time

when the electron is moving without scattering.

∗−=m

eEv scd

ι 2.26

where v is the drift velocity, d scι is the scattering time. The current density is

expressed as

EEm

nenevJ scd σι

==−= ∗

2

2.27

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where σ is the conductivity.

2.2.6 Optical absorption of semiconductors

Basically light is represented by electromagnetic waves and expressed as

Maxwell’s equation.

)2

exp()](exp[0zt

cniEE r αω −−= 2.28

where z is the propagation direction; ω is the frequency; is the refractive index and

α is the absorption coefficient of the medium. For non-zero α, there is absorption in

the medium and the outcome of the light flux is

rn

]exp[)0()( zIzI α= 2.29

Though absorption can happen due to a variety of causes, such as absorption of

impurities and intraband absorption, the main focus is the band-to-band absorption. In

a band-to-band absorption, a photon scatters an electron in the valence band and

causes it going into the conduction band. In the absorption process, the conservation

of energy is maintained.

ωh+= if EE 2.30

where Ef and Ei are the final and initial energy and ωh is the photon energy. Because

the minimum energy difference between the valence band and the conduction band is

the bandgap, the photon energy must greater than the bnadgap for the absorption to

occur. Beside the conservation of energy, the conservation of momentum is also

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maintained. Since the k value of normal photon is essentially zero compared to the k

value of the electron, the conservation of momentum guarantees that the initial and

final electron state has the same k value. In other words, only vertical k transition is

allowed. Because of the constraint of momentum conservation, the optical absorption

is strong for direct bnadgap material, like GaAs. The optical absorption is weak for

indirect bnadgap material, like Si. The reason of the weak optical absorption is that

the lattice vibration is also required in the process of electron exitation in order to

satisfy the law of momentum conservation.

2.3 Semiconductor photodetectors

In an optical interconnect system, the photodetector acts as the receiver at the

end of system. It converts optical signals into the electrical form. The semiconductor

photodetector takes irreplaceable role in optical interconnection system. The basic

operation process of a semiconductor photodetector is the generation of electron-hole

pairs from external optical excitation and the collection of the electrons and holes to

generate electrical signals. Usually the laser beam illuminates on semiconductor

surface and electron-hole pairs are generated because the excitation of electrons from

the valance band to the conduction band. In order to excite the electron from the

valence band into the conduction band, the photon energy must be equal to or greater

than the bandgap energy of semiconductor. Also the photon absorption is strongest

when photons can directly excite electrons from the valence band into the conduction

band. Since the photon momentum is extremly small compare with the electron

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momentum, the conservation of momentum requires that electron-hole transition is

vertical in k space. Such transitions are only possible near the bandedge for direct

bandgap material. The absorption coefficient can be written as

32

2/12/32

020

2 )()(22

)(h

h

h

hh

πω

ωεπωα grcv

r

Empcmne −

=∗

2.31

∗∗∗ +=her mmm

111 2.32

where nr is the refractive index; ωh is the photon energy; Eg is the bandgap and

is the momentum matrix element which allows the transition to take place. For

GaAs material the absorption coefficient is calculated as

cvp

12/1

4 )(106.5)( −−

×≅ cmEg

ωω

ωαh

hh

2.33

There is a cut off wavelength above which the absorption coefficient is zero. The cut

off wavelength is expressed as

)()(

24.1 meVEg

c µλ = 2.34

For detection of an optical signal, the light should be absorbed in certain

distance. For a strong absorption of light, the condition )/(1 ωh>L must be satisfied.

When the light beam impinges upon a semiconductor and generates electron-hole

pairs, the detector performance depends on how the electrons and holes are collected.

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If no electrical field is applied, then electrons and holes will be recombined and no

detection signal is generated. However, when an electrical field is applied to the

semiconductor, the electron-hole pairs are separated and electrons flow to the anode

and holes flow to the cathode. The resulting current flow is proportional to the

incident optical power. A characteristic property of photodetector is responsivity and

it is defined as the generated current divided by impinging optical power.

op

Lph P

JR = 2.35

where JL is the photocurrent density and Pop is the impinging optical intensity.

Another property of photodetector is quantum efficiency and is defined as how many

carriers are collected for each photon impinging on the photodetector.

eRphQ

ωη h= 2.36

There are three types of semiconductor photodetectors; PIN diode, metal-

semiconductor-metal (MSM) photodetector and avalanche photoddetector (APD).

2.4 PIN photodiode

PIN photodiodes are widely used in optical interconnect system.34-36 The

essence of the PIN diode is to generate electron-hole pairs in depleted semiconductor

region and collect carriers to outside circuit. When light impinges upon a

semiconductor to create electron-hole pairs, some of the carriers are collected at the

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contact and lead to the photocurrent. The basic structure of a PIN is shown in Fig.

2.7; it is consist of a depleted region in the middle of the device, p and n region on

either side. The PIN is under reverse biasing and the dark current of the device is

independent from applied biasing voltage. The electrical field in this region sweeps

the electron hole pairs rapidly. The electrons are swept into n region and holes are

swept into p region. The photon current caused by the photons absorbed in the

depletion region is expressed as

ωαh

opnpL

PLLWeAI )( ++⋅= 2.37

where is the optical intensity of impinging light; A is the diode area; W is the

width of the depletion length and L

opP

p, Ln are the diffusion length of holes and electrons

respectively. Because electrons and holes are generated in depletion area and under

high electrical field, they move very fast thus give a very fast response time of the

diode. Beside the carriers generated in depletion area, some holes and electrons are

also generated in p and n region. If they are under the diffusion length of the

depletion region, the slow moving holes and fast moving electrons are able to enter

depletion region and contribute to photocurrent as well.

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Fig 2.7 Schematic of PIN photdiode

2.5 avalanche photoddetector (APD)

APD attracts many interests in recent years.37,38 The new interests change the

coupling mechanism of APD from top illumination to side illumination for boasting

sensibility without sacrifice resposivity.39 The basic idea behind APD is the usage of

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high energy carrier to generate electron-hole pairs. The avalanche process requires the

initial electron to have energy greater than the bandgap energy.

Fig 2.8 Schematic of basic APD structure

The APD usually has a very high gain because of the carrier multiplication. On the

other hand, the noise level of APD is also higher because the random process of

carrier multiplication. The basic APD structure is shown in Fig 2.8. The

multiplication rate of the APD is expressed as

WM

impe α−

=1

1 2.38

where impα is the ionization coefficient and W is the width of multiplication region.

2.6 Metal-Semiconductor-Metal photodetector

Another important class photodetector is metal-semiconductor-metal

photodetector(MSM). In recent years, MSM photodetectors have attracted many

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interests in the field of optical interconnect. Speed and responsivity of MSM

photdetector can be improved by resonant cavity.40 If only speed response is

concerned, then ion implantation is a good choice.41 The traveling wave MSM

photodetector exhibits both high speed and high quantum efficiency.11

b

d

Fig 2.9 Intedigitated contacts pattern of MSM photodetector

In Fig. 2.9, the active area of a MSM photodetector is shown. In MSM

photodetector active area, two Schottky barriers are placed in a planar geometry close

to each other. The electrical contacts are placed as interdigitated manor. The active

material is GaAs. The eleteode fingers are Au thin films. The structure of the

electrode is interdigital, and the length b of the electrode is much larger than their

width d. The thickness of the electrode fingers is much smaller than either their width

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or their length, thus the fingers are theoretically considered infinitely thin. The

number of the electrode fingers is large enough to allow neglecting the absence of

symmetry at the electrode edges. Schottky barriers are formed at the interface

between metal and semiconductor. Biasing voltage variations due to phodetector

response are very small, so bias voltage is considered to be constant. The

concentration of generated carriers depends on the optical signal intensity, the

absorption coefficient α and the wavelength λ. As the optical coefficient curve in Fig.

2.10, low intensity optical signal is considered to avoid the carrier saturation in active

area. The electrical field is not homogeneous and decrease shapely from the surface

towards the bulk of the substrate. Drift mechanism dominates in the transport of

photo-generated carriers in the part of the GaAs active area at the incident surface. At

deeper region inside GaAs active area, the transport mechanism is governed by

diffusion. Carrier recombination is neglected because the recombination time is much

larger than the response time. Another assumption is the transport equation for two

valley semiconductor.43 Carriers transport in each separated valley can be described

by the drift-diffusion relation and the continuity equation, where the inter-valley

transfer is described by transfer times, according to hydrodynamic model.44 The

transport equation is

12

2

1

11

1

)(1

nn GnE

nJdivqt

n++−=−

∂∂ →

ττ 2.39

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21

1

2

22

2

)(1

nn GE

nnJdivqt

n++−=−

∂∂ →

ττ 2.40

Fig. 2.10 Optical absorption coefficient of different semiconductor

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pp GJdivqt

p=+

∂∂ →1

2.41

→→

= EqnJ n 111 µ Evs 11 µ≤ 2.42

→→

= 111 sn vqnJ Evs 11 µ≥ 2.43

→→

= EqnJ n 222 µ Evs 22 µ≤ 2.44

→→

= 222 sn vqnJ Evs 22 µ≥ 2.45

→→

= EqpJ pp µ Ev psp µ≤ 2.46

→→

= EqpJ spp µ Ev psp µ≥ 2.47

2.48 pnn JJJJ→→→→

++= 21

where n1 is the electron concentration in the Γ valley, n2 is the electron concentration

in the Χ and L valley, p is the hole concentration, Jn1, Jn2 Jp are current densities, µ is

the carrier mobility of the material. Gn1, Gn2, Gp are the generation for electrons and

holes in different valley of conduction band and valence band. E is the electrical field,

and τ1, τ2 are the relaxation time in different valley of conduction band.

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Bias variation caused by the impedance in the photodetector circuit can be

neglected in comparison to the DC component of voltage, and it is possible to neglect

the time variations of the electric field as well. The collected current by contacting

finger is defined as the surface integral of the current density over an electrode.

dlnt

tyxDtyxJth o

s

→→

∂∂

+= ∫ ]),,(),,([)( 2.49

where is the electric induction vector and is the unit vector perpendicular to the

electrode surface.

D on→

The generation term is given by

])(exp[)( yhI λαν

λα −=G 2.50

where )(λα is the absorption coefficient, and I is the incident photon flux density.

The response characterization from the physical processe point of the view is

realized via carrier transit time, usually expressed as 3dB bandwidth. The carrier

transit time is the parameter to characterize the mean time for generated carries to

leave the detector.

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∫ ∫

∫ ∫∞ →→

∞ →→

=

00

00

][

][

s

n

s

n

n

dtdlnJ

dtdlnJtT 2.51

∫ ∫

∫ ∫∞ →→

∞ →→

=

00

00

][

][

s

p

s

p

p

dtdlnJ

dtdlnJtT

2.52

where integral constant s denotes the electrode area through which electrons and

holes leave the detector.

The 3 dB bandwidth frequency is used in practice to measure the response

speed. The bandwidth frequency is obtained from the frequency response H(jω)

which itself is the Fourier transform of h(t)in equation 2.46:

2)(max)( ωω jHjH B = 2.53

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Chapter 3

Silicon and GaAs MSM photodetectrors

3.1 Introduction

MSM photodetectors are the receivers of optical interconnect system. MSM

photodetectors have been investigated extensively in recent years in close connections

with optical interconnects. From fabrication point of view, there are MSM

photodetectors having nanometer scale electrical finger contact.45-47 These MSM

photodetectors exhibits 3-dB bandwidth in Terahertz range. The drawback of this

approach is the difficulty in fabrication. Form view of detecting wavelength, there are

MSM photodetectors which are sensitive in 1.3µm and 1.5 µm range.48,49 At shorter

distance data communication, the light source with wavelength of 850 µm is usually

utilized and many researches of MSM photodetector have been conducted at this

wavelength. One of the material choices for MSM photodetector is poly-silicon.50

The advantage of this material is the simple fabrication process that is compatible

with standard VLSI processes. The drawbacks of this approach is that 3 dB bandwidt

is in megahertz range and quantum efficiency tends to be low, only 0.19A/W.

Another material choice of MSM photodetector is GaAs.51 Though GaAs MSM

photodetecctor has Gigahertz range of 3-dB bandwidth and responsivity is high, the

challenge exists in the integration of GaAs MSM photodetector with VLSI

electronics.

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3.2.1 Thin film silicon based MSM photodetector

Traditional electrical interconnections are approaching fundamental speed and

density limitations. The integrated optoelectronic system would be the most realistic

solution for these limitations. One of the preferred materials for individual

components of integrated optoelectronics system is silicon for VLSI circuitry and

optoelectronics, polymers for optical wave-guides. Using the polymeric optical

material for a particular application often can reduce the system cost and increases

system performance. The fabrication challenge in integrated optoelectronics is to take

the cost and performance advantages of these materials in a manufacturability

manner.

One promising method for integrating semiconductor devices, both electronic

and optoelectronic, with certain host substrates is thin film device integration. Single

crystal, thin film semiconductor devices can be separated from the growth substrate

and bonded to host substrate using standard microelectronic processes. It is an

attractive option for multi-material integrated optoelectronics. Multi-material

integrated systems, both electronic and optoelectronic, enable the system to perform

at higher speed, consume less power, require less area for interconnects, and dissipate

less heat. Optoelectronics has an opportunity not to compete with silicon, but to

complement and augment the capabilities of silicon electronics. Recently, attention

has been given to use optical technology to improve connection of devices on a single

chip or wafer and between multi-chip-modules(MCM).52 Considering the widespread

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proliferation of fiber networks into homes and businesses, low-cost and high

reliability components will be required. Optoelectronics together with silicon circuitry

meet this challenge by offering the potential advantages of large bandwidth,

immunity from EMI and capacitive loading, and inherent parallelism.53-55

The design of the thin film silicon detector is presented in Fig.3.1. The

absorption coefficient of silicon is shown on Fig. 3.2. Silicon is an indirect band gap

semiconductor material, as illustrated in fig. 3.3. When the optical absorption

happens, the lattice vibrations are needed to assist the electron-hole pair generation.

Fig. 3.1 Cross section structure of Si MSM photodetectro

Metal contact

AuAu 1000 Å SiO2

1000 Å SiO2

1000 Å SiO2

30-50 µm Silicon

Fig. 3.1 Cross section structure of Si MSM photodetectro

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Fig. 3.2 Absorption coefficient of silicon

Fig. 3.3 Band structure of Silicon

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The band gap of silicon is

)(636

1037.417.124

eVT

TEg −×

−=−

3.1

At room temperature the band gap = 1.07 eV. Since the absorption length

of 850 nm wavelength laser light in silicon is around 9 µm, the total depth of

the active silicon guarantees the total absorption of 850nm laser light. The

distance between the contacting interdigitate fingers is 2 µm. By the one-

dimensional approximation, the energy-band structure of MSM photodetector

under different bias voltages can be illustrated as in Fig.3.4. Obviously, when

the external bias voltage equals to zero, the photo-generated carriers will be

restricted within the potential well formed by the two Schottky junctions. So,

the detector has no response to the optical signal. As V

gE

bias increasing, the

depletion region on left side (the electron potential is higher) will expand and

finally occupies the whole semiconductor area. This is the case (b) in Fig.3.4,

however, the potential well still exist. The photon-current will not be

produced until the lowest point of the electron potential curve moves to the

right metal/semiconductor interface through increasing Vbias further. That is

the case shown in Fig.3.4 (c). This electron potential function in the depletion

region can be solved from the Poisson equation. The following threshold bias

voltage for photon-current generation can be obtained:

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Vbias

qe Nd. d2.

2 ε 3.2

where, Nd is the donor impurity density in N-type semiconductor area, d is the

width of the depletion region, qe is the electron charge.

Metal Semiconductor Metal

hνVbias

Vbias

X0 d

Ve x( ) qe

(a) (b) (c)

Fig3.4, The energy-band diagram of MSM junction, (a) Vbias=0; (b) Vbias just enough

to deplete all the semiconductor area; (c) Vbias equals to flat band voltage VFB.

3.2.2 Fabrication of 1×12 thin film silicon MSM photodetector array

In order to eliminate foreign particles and contamination, all fabrication

procedures were performed in class 100 clean-room. The fabrication of 1x12 thin film

MSM silicon photodetector array device started with <100> n-type silicon wafers of

6-12 Ω/cm sheet resistance. The silicon wafer was first mechanically polished from

its original thickness of 500 µm to around 50 µm thick. Then the backside of the

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wafer was glued on the transferring substrate that used as a mechanical support. The

wafer surface was cleaned with HF in a supersonic bath for 30 seconds. Then the

wafer was rinsed in DI water for five minutes. The wafer later was in a supersonic

bath with acetone for 10 minutes, followed by a supersonic bath with Isopropanol for

five minutes. Finally the wafer was rinsed in DI water for five minutes and then

baked at a 150°C oven for 10 minutes to get rid of water residue on surface. This

cleaning procedure was to ensure that the thin layer of SiO2 was etched away and the

wafer surface was clean. Immediately after the cleaning procedure, the wafer was

deposited with 1000 Å SiO2 using physical enhanced chemical vapor deposition

(PECVD). The photo-resist, AZ 5209, was spin coated on the wafer at 4000

revolution-per-minute (RPM) for 40 seconds. The wafer then underwent soft

bake(900C, 20 minutes). The sample was then illuminated under Karl-Suess mask

aligner for 40 seconds with mask pattern. As a result the inter-digitated finger pattern

was fabricated on top of the silicon dioxide layer. The electrode pattern was revealed

after the wafer was being developed for 35 seconds using AZ 425 developer. This is

followed by a 1200C 20 minutes hard backing.

The inter-digitate finger pattern has to be opened all the way down to the

silicon surface. In order to etch away SiO2 on the silicon surface, reactive ion etching

(RIE) was used. Not only the dry etching method provides good surface condition,

but also the vertical profile of the inter-digitate finger pattern is guaranteed. The

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interdigitate finger pattern was etched on a Lam 760 RIE system and the following is

the receipt.

• Pressure: ~20 mτ

• Oxygen: 25 sccm

• CF4: 10sccm

• RF Power: 75W

• Etching rate: 500 Å /min

• Mask: PR

After etching away rest area of SiO2, finger pattern was formed. The 1500 Å Au was

then deposited on the pattern of the device using CHA e-beam evaporation machine.

The interdigitate finger pattern was preserved and the rest of the gold was removed by

lift off procedure, which composed of emerging sample in acetone and ultrasonic bath

for 30 seconds and then rinsed with DI water. Figure 3.5 shows an interdigitate finger

pattern after the lift off process.

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Fig. 3.5 Etched contact finger pattern of MSM thin film photo-detector

After the deposition of interdigitate finger electrode contact, the wafer was

again spin coated with photo resist, AZ 5209 at 4000 rpm for 40 seconds. The sample

was again undergone soft-baked at 90°C for ten minute. The sample was aligned with

contacting pad pattern mask and illuminated under Karl-Suess mask aligner for 40

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seconds. The sample was hard baked in the oven under 1200C for 20 minutes. The

electrode pattern was revealed after being developed for 35 seconds using AZ 425

developer. A layer of 1500Å thick Au was deposited by CHA electron beam

evaporator. The final contacting pad was revealed when the unnecessary gold was

removed by emerging sample in acetone and ultrasonic bath for 30 seconds and then

rinsed with DI water. The active area of MSM thin film photodetector and finished

MSM photodetector with contact pad are shown in figure 3.6. The 1x12 thin film

array MSM silicon photodetector was finally thinned down to around 10 µm by RIE

etching process. The etching receipt is as below:

• Pressure: ~20 mτ

• Oxygen: 50 sccm

• CF4: 20 sccm

• RF Power: 90W

• Etching rate: 0.2 µm /min

The final thickness of the thin film MSM silicon photodetector array was around 30

µm. The whole process of fabrication of thin film silicon MSM photodetector is

illustrate in figure 3.7

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Fig. 3.6. Active area of MSM silicon photdetector and finished MSM photodetector

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Fig. 3.7 The fabrication process of thin film Si MSM photdetector

Au finger deposition

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3.2.3 Testing of 1×12 thin film silicon MSM photodetector array.

When metal is deposited on the surface of semiconductor, interface between

metal and semiconductor emerges. The Schottkey barrier arises when current flows

from the metal into the semiconductor in order to come to equilibrium.56,57 The

electrons flow only around nanometer range into semiconductor and leave space

charges that forms physical barrier to electrons, therefore prevent any current flow in

between the two materials. The formation of Schottkey barrier is illustrated in figure

3.7. The height of the Schottkey barrier is express as

smb κφφ −= 3.3

where φb is defined as the Schottkey barrier height, φm is the work function of metal

and κs electron affinity of the semiconductor. The work function of Au is 4.58 eV and

the electron affinity of silicon is 4.01eV, as in figure 3.7. So the theoretical Schottkey

barrier height is 0.57eV. The formation of the Schottkey barrier is demonstrated by

the I-V curve of the silicon MSM photodetector. The I-V of the device was measured

using I-V curve tracer. The result is shown on figure 3.8 and the breaking voltage is

10 volts.

When apply voltage between the anode and the cathode of MSM

photodetector, there is a very small electrical current even without the lamination of

light. This small electrical current is defined as dark current. The origin which

contributes to the dark current is due to thermionic emission.58-59 from the theory of

thermionic emission, the hot electrons with energy equal to or larger than the

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conduction band energy at the metal-semiconductor interface cross the metal

semiconductor interface and induce the dark current.

Fig. 3.8 Formation of Schottkey barrier between metal and semiconductor

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Fig 3.9 I-V of thin film silicon MSM photodetector

Current flow between metal and semiconductor is defined in equation 3.4.

dEdEdnqvJ

cEx∫

= 3.4

For non-degenerately doped material, the density of electrons between E and E + dE

is given by

)](exp[)2(43

2/3

kTEE

EEhm

dEdn f

c

−−−=

∗π 3.5

if the bottom of the conduction band is parabolic, E-Ec=(m*v2)/2 is the equation

relates electron energy and electron speed. The velocity of the electrons is deducted

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from the statement that its kinetic energy is equal to the potential height of the

Schottkey barrier.

bqvm φ=∗ 2

21

3.6

which yields the final expression of the dark current density crossing the Schottkey

barrier.

)1(4 //3

22

−= −∗

kTqVkTqdark

ab eeh

TkqmJ φπ 3.7

where Va is the applied voltage cross the Schottkey barrier and φb is the potential of

Schottkey barrier.

In order to measure the dark current of the thin film MSM photodetector, HP-

4641 semiconductor analyzer was used. The HP-4641 semiconductor analyzer has a

testing chamber, which can be closed to prevent light going into the chamber, and the

chamber was kept totally darkness while the test was made. The dark current of thin

film silicon MSM photo-detector at 5 volts bias voltage was 82.9 nA.

The responsivity of thin film MSM photodetector is defined as ratio between

the current generated by the light absorption over the total power of the light that

applied to the detector. The responsivity of the thin film MSM photodetector was

measure through the photocurrent and the total power applied to the photodetector.

The responsivity value of the thin film MSM photodetector was 0.25A/W at

wavelength 850nm.

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Another important characteristic of thin film MSM photodetector is its 3dB

bandwidth. The 3dB bandwidth can be calculated by solving dependent continuity

equation and is expressed as following:

kt

pk

tn

daph Ceee

wLLLRqAVtI kpnk ][]1[

)()1()( ξξα µµ −−− +−

+−

= ∑ 3.8

where A is the area of the active area, Va is the effective applied voltage, R is the

surface reflectivity, α is the light absorption coefficient, d is the thickness of

absorption length, L is the length of the finger space, W is the finger width, nµ is the

electron mobility, pµ is the hole mobility, Ck is given as

222

2

])()[(])1(1][)1(1[)(2

παπ αα

kdeek

ALEE

Cdkdk

ph

pulsek +

−−−−=

3.9

and

τπαξ 1])([ 22 ++=d

kDnkn τπαξ 1])([ 22 ++=d

kDpk p

in which Dn and Dp are the diffusion constants of electrons and holes respectively.

Theoretically, the 3dB bandwidth is hard to calculate because of the effective voltage

applied between electrodes is difficult to calculate. To clarify this matter, the effective

voltage applied on the active area of thin film photodetector is the voltage underneath

the surface of the silicon. The distribution of electrical field inside silicon does not

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linearly decrease form the top to the boundary of absorption length. The electrical

field was strong near the surface of the thin film of silicon and decrease exponentially

with the increase of the thickness of the silicon. The best way to decide 3dB

bandwidth is to measure it experimentally.

The impulse measurement of thin film silicon MSM photodetector was

performed in the lab. The setup included Ti:sapphire mode-locked femto-second laser

operates at the wavelength 850nm with a pulse width of about 150fs and a repetition

rate of 76MHz. The optical attenuator was used to attenuate the laser power from its

original 200mW to 10mW. The pulse of the mode-lock is very unstable if optical

isolator is not used. The reason for that instability of the laser pulse is when the laser

pulse is coupled into multi-mode fiber end, the

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DUT(Thin film Si MSMPhoto-detector)

Cascade Microwave Multi Mode

Femto-second Laser

Biasing Optical

HP Spectrum

DC Voltage

Fig. 3.10 Measurement setup for test of thin film silicon MSM photodetector

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DC Voltage

Cascade Microwave

Multi Mode

DUT(Thin film Si MSM Photo-detector) HP Spectrum

Fig. 3.11 Measurement setup and test of thin film silicon MSM photodetector

collimating lens of the multi-mode fiber reflects large mount of the laser energy back

into the cavity of the laser system. The reflected energy of the original laser pulse

greatly disturbed the mode locking mechanism of the Ti:sapphire laser. For that

reason, a 30dB optical isolator was also used in the measurement setup. It was

discovered later that the optical isolator could be could if the pulse laser light is

coupled off center into the multi mode fiber deliberately. In that way the collimating

lens reflects most energy of the laser light back into space and only very small

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amount of the energy reflects back into laser system and dose not incur big

disturbance of the mode-locking mechanism. After passing through optical attenuator

and optical isolator, the pulse laser light was butt coupled into one end of the multi

mode optical fiber. The multi mode optical fiber was then routed through a

mechanical holder onto the top of the thin film MSM silicon photodetector. The fiber

tip was directed vertically on the very surface of active area of the thin film MSM

silicon photodetector. A 40 GHz ground-signal-ground (GSG) microwave probe was

used for electrical signal extraction. A 100k-18GHz biasing tee was connected to the

microwave probe and biasing voltage was provided by the DC power supply.

Between the power supply and biasing tee, an ampere meter was serially connected in

the circuit. The tip of the multi mode fiber was first brought to the vicinity area of the

active part of the photodetector, then the tip of the fiber was moved slowly and at the

same time, the readout of the ampere meter was carefully monitored, validation of the

pulse laser’s vertical illuminating on the active area of the MSM photo-detector was

confirmed by the existence of the photocurrent, usually around 30-50 µA. Finally a

9k-26GHz spectra-analyzer was connected through high frequency cable to the GSG

microwave probe. The 3dB bandwidth was read out from spectra-analyzer. The whole

measurement setup diagram and test are shown in figure 3.10 and 3.11. The biasing

voltage of the thin film MSM silicon photodetector was 5V. The 3dB bandwidth was

350 MHz, as shown in figure 3.12.

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0.00E+000 1.00E+008 2.00E+008 3.00E+008 4.00E+008-71.0-70.5-70.0-69.5-69.0-68.5-68.0-67.5-67.0-66.5-66.0-65.5-65.0-64.5-64.0-63.5

B B

Am

plitu

de(d

B)

Frequency(Hz)0.00E+000 1.00E+008 2.00E+008 3.00E+008 4.00E+008

-71.0-70.5-70.0-69.5-69.0-68.5-68.0-67.5-67.0-66.5-66.0-65.5-65.0-64.5-64.0-63.5

B B

Am

plitu

de(d

B)

Frequency(Hz)

Fig 3.12 3dB bandwidth of thin film silicon MSM photodetector

3.3.1 GaAs MSM phodetector

Silicon MSM photdetector has the advantage of being able to integrate with

VLSI circuit without extra fabrication steps to accommodate since most VLSI circuits

is fabricated on silicon wafer. One big drawback of silicon MSM thin film

photodetector is the slow response in speed. The 3dB bandwidth only reached 350

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MHz in above-mentioned thin film MSM silicon photodetector. Even consider the 12-

detector array, the aggregated bandwidth was 4.25GHz. The slow response time of

silicon MSM photodetector results from the inherent absorption length of silicon at

850 nm wavelength. That absorption length is around 9 µm. When biasing voltage is

applied on the surface of the silicon, it drops very quickly inside silicon with the

increase of thedepth. So the electron-hole pairs generated at the end of the absorption

length acquire very weak electrical field and therefore the drifting velocity is slow.

This effect contributes to the slow 3dB bandwidth of thin film MSM silicon

photdetector. If the active depth of the silicon is dramatically reduced to less than

one-micron meter the speed response would be considerably increased. However

silicon is an indirect band gap semiconductor; it does not absorb light efficiently

through short length. Also when silicon material absorbs light, in order to fulfill the

requirement of the conservation of momentum, the lattice vibration and phonon

absorption have to be added with the momentum of the electron.

GaAs is an ideal material for the optoelectronic device. At 850 nm

wavelength, the absorption coefficient of GaAs is much larger than that of silicon

material. As a result, the absorption length of GaAs is an order less than that of

silicon. The band structure of GaAs is shown on figure 3.13. The band gap energy of

GaAs is

)(204

104.5519.124

eVT

TEg +×

−=−

3.10

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the electron mass in GaAs is me*=0.067m0 and light hole mass is mh*=0.08 m0.

Fig. 3.13 Band structure of GaAs

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At 300 K, intrinsic carrier concentration of GaAs is 1.84x10-6 cm-3. At room

temperature the band gap energy of GaAs is = 1.423 eV. The design of MSM

GaAs photodetector is illustrated in figure 3.14. This design is not much different

from the schematic design of thin film silicon MSM photodetector. The deference

gE

500 µm GaAs

1000 Å SiO2 1000 Å SiO2 1000 Å SiO2Au Au

3000Å Metal contact

500 µm GaAs

1000 Å SiO2 1000 Å SiO2 1000 Å SiO2Au Au

3000Å Metal contact

Fig 3.14 Design of GaAs MSM photodetector

lies on the fact that the absorption length at given wavelength 850 nm of GaAs is

much shorter than that of silicon MSM photodetector. The interdigitate finger width

and the width of finger are all 2 µm. The MSM GaAs photodetectors are designed to

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be 1x12 array. The center-to-center distances between individual detectors are 250

µm. Each detector in the array has an active area of 50x50µm. The contacting metal

used to form Schottkey barrier is Au. When there is no biasing voltage applied to the

MSM GaAs photodetector, the detector acts as two back-to-back diodes. If the 850

nm pulse laser light is illuminated on the active area of MSM photodetector, the

electron-hole pairs will be generated and restricted between the potentials formed by

two Schottkey barriers. When small biasing voltage is applied to both ends of

Schottkey barrier, the conduction band and the valence band will tilt according to the

voltage applied. When applied voltage is large enough to totally bend the conduction

and the valence band, the Schottkey barrier will disappear on anode side and electrons

can flow from conduction band to anode terminal, and Schottkey barrier will also

disappear on cathod side and holes can flow from the valence band to cathode

terminal. Since the absorption length of GaAs is much smaller than silicon, a better

3dB bandwidth is anticipated because the electron-hole pairs are generated much

nearer to GaAs surface as compared with those electron-hole pairs generated under

the silicon surface. Another factor of better 3-dB bandwidth is the faster electron and

hole mobility in GaAs material. The electron and hole mobility in GaAs material are

8500 cm 2 /V-s and 400 cm 2 /V-s respectively, compared with 1400 cm2 V-1s-1 and

450 cm2 V-1s-1 electron and hole mobility in silicon material. The electronic

properties of GaAs is listed in table 3.1

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Fabrication of GaAs MSM photodetector array was much alike the fabrication

of thin film silicon MSM photodetector array. The wafer is Liquid Encapsulation

Czochralski (LEC) grow <100> semi-insulating GaAs that has bulk resistivity of

108Ωm. The fabrication procedures were taken in class 100 clean-room. The surface

of GaAs wafer was first cleaned with DI water. Then the wafer was

Table 3.1 Room temperature properties of GaAs

Property Parameter

Crystal structure Zinc blende

Lattice constant 5.65 Å

Density 5.32 g/cm 3

Atomic density 4.5 × 10 22 atoms/cm 3

Molecular weight 144.64

Bulk modulus 7.55 × 10 11 dyn/cm 2

Sheer modulus 3.26 × 10 11 dyn/cm 2

Coefficient of thermal expansion 5.8 × 10 –6 K –1

Specific heat 0.327 J/g-K

Lattice thermal conductivity 0.55 W/cm-°C

Dielectric constant 12.85

Band gap 1.42 eV

Threshold field 3.3 kV/cm

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Peak drift velocity 2.1 × 10 7 cm/s

Electron mobility (undoped) 8500 cm 2 /V-s

Hole mobility (undoped) 400 cm 2 /V-s

Melting point 1238°C

cleaned in a supersonic bath of acetone for 10 minutes, followed by a supersonic bath

of Isopropanol for five minutes. The wafer was rinsed by DI water for 5 minutes and

then baked at a 150°C oven for 10 minutes to get rid of water residue. After cleaning

process, 1000 Å SiO2 was deposited on the GaAs surface by PECVD. This layer of

SiO2 was used as the insulation layer between pad and active area of GaAs. The

photoresist, AZ 5209 was spin coated on the top of SiO2 layer. The RPM of the spin

was 4000 and the time of spine coating was 40 seconds. The wafer then went through

900C 20 minutes soft bake curing. The finger pattern was formed on the GaAs wafer

though photolithography process, which was shined UV light for 40 seconds through

Karl-Suess mask aligner. The interdigitate finger pattern appeared after 20 seconds

develop time using AZ 425 developer. The wafer went on 1200C, 20 minutes hard

backing.

In order for the electrode finger pattern touch the surface of the active area of

GaAs wafer, finger part of SiO2 has to be etched away. SiO2 was wet etched by 1:6

oxide etchant. This was followed by Au metal deposition that was performed through

CHA e-beam evaporation machine. After depositing Au on the wafer, the Au finger

pattern was preserved and the rest of gold was taken off by liftoff process. The liftoff

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process involved emerging sample in acetone and ultrasonic bath for 30 seconds, then

rinsed with DI water. Because the photo-resist was highly resolvable in acetone, the

area of the Au, which was on top of photoresist and had no contact with the surface of

GaAs, became loosen from the wafer and later was moved away by ultrasonic bath.

Figure 3.15 shows an interdigitate finger pattern of Au after the lift off process. The

space between two interdigitated fingers is 2 µm.

Fig 3.15 Contacting finger pattern of GaAs MSM photodetector

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The fabrication of contacting pad of MSM GaAs photdetector array was

followed after the formation of interdigitate fingers. The wafer was first spin coated

with photo resist, AZ 5209 at 4000 rpm for 40 seconds. Then it was put into oven and

soft-baked at 90°C for ten minute. The sample was aligned with contacting pad

pattern mask under Karl-Suess mask aligner and was shined with UV light for 40

seconds. The sample was hard baked in the oven under 1200C for 20 minutes. The

pattern was developed using AZ 425 developer. After the pattern formation, 1500 Å

Au pad material was deposited by CHA electron beam evaporator. The final

contacting pad was revealed when the unnecessary gold was removed by emerging

sample in acetone and underwent ultrasonic bath for 30 seconds and then rinsed with

DI water. The whole process of fabricating 1×12 GaAs MSM photodetector array is

similar to that of silicon MSM photodetector array except that in GaAs photodetector

fabrication, the wet etching of SiO2 was used instead of RIE etching. The whole

fabrication process of GaAs MSM photodetector array can be referenced through

figure 3.7. The interdigitate finger pattern of GaAs MSM photodetector and array of

photodetector are shown in figure 3.16 and figure 3.17 respectively.

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Fig. 3.16 Interdigitate finger pattern of GaAs MSM photdetector

Fig. 3.17. Array of GaAs MSM photodetector

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3.3.2 Testing of GaAs MSM photodetector array

When Au is deposit on the surface of GaAs surface, interface arises between

metal and semiconductor. Because of the difference between the work function of

metal and electron affinity of semiconductor, Schottkey barrier forms at the interface

of metal and semiconductor. The schottkey barrier height is defined as the difference

between the metal work function and the semiconductor’s electron affinity. The value

of work function of Au is 4.58 eV. The value of electron affinity of GaAs is 4.07eV.

The theoretical value of Schottkey barrier is 0.51eV. The formation of the Schottkey

barrier at the interface of GaAs and Au is demonstrated by the I-V curve of the GaAs

MSM photodetector. The I-V curve characteristic was measured using I-V curve

tracer. The I-V curve clearly demonstrates rectifying characteristic and the

breakdown voltage was 15 volts.

Another important characteristic of GaAs MSM photodetector is dark current.

Even without the illumination of light, there is small current flow between cathode

and anode of GaAs photodetector when the biasing voltage is applied. The dark

current is due to thermionic emission of electrons in GaAs. The hot electrons with

energy equal to or larger than the conduction band energy at the metal-semiconductor

interface cross the metal semiconductor interface and induce the dark current. The

formula to express dark current is shown in equation 3.7. To measure dark current of

GaAs photodetector, HP-4641 semiconductor analyzer was used. In the process of

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measuring dark measurement, the device under test was kept in total darkness. The

dark current of GaAs MSM photo-detector at 5 volts bias voltage was 4.6 pA.

The responsivity of GaAs MSM photodetector is defined as ratio between the

current generated by the light absorption over the total power of the light that applied

to the GaAs MSM photodetector. The responsivity of the GaAs MSM photodetector

was measured through the photocurrent and the total power applied to the

photodetector. The responsivity value of the GaAs MSM photodetector was 0.32A/W

at wavelength 850nm.

Another important characteristic of thin film MSM photodetector is its 3dB

bandwidth. The 3dB bandwidth can be calculated by solving dependent continuity

equation and is expressed in equation 3.8. The limitation of the 3dB bandwidth is the

electrons and holes transit time needed from the location they are generated to the

contacting fingers. Since the absorption length in GaAs is much shorter than that in

silicon, the electrons and holes can be generated in location much near to electron

contacting fingers and they experience much stronger electrical field. Also taken into

account of electron and hole mobility in GaAs are higher than those in silicon. The

3dB bandwidth of GaAs photodetector is to be higher than that of silicon

photodetector. The 3dB bandwidth is also related closely with applied voltage

between interdigitate fingers, because the transit time of electrons and hole decreases

with the increase of the applied voltage. However, there is an upper limit when the

applied voltage is so large that the saturation speeds of hole and electron are reached.

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The impulse measurement of GaAs MSM photodetector was performed in the

lab. The instruments of the setup include Ti:sapphire mode-locked femto-second laser

operates at the wavelength 850nm with a pulse width of about 150fs and a repetition

rate of 76MHz. Other instruments are optical isolator, optical attenuator, and multi

mode optical fiber. The fiber tip was directed vertically on the very surface of active

area of the MSM GaAs photodetector. The electrical signal was extracted through a

40 GHz ground-signal-ground (GSG) microwave probe. The 100k-18GHz biasing tee

was connected to the microwave probe and the biasing voltage was provided by the

DC power supply. Between biasing tee and DC power supply, an ampere meter was

serially connected in the circuit. Another end of biasing tee was connected to the HP

spectra-analyzer. The tip of multi mode fiber was moved back and forth slowly

around the vicinity and at the same time, the readout of the ampere meter was

carefully monitored. Validation of the pulse laser light vertical illumination on the

active area of GaAs MSM photo-detector was confirmed by the existence of the

photocurrent, usually around 50-100 µA.

In the measurement of 3dB bandwidth, the coupling of laser light to multi

mode fiber was deliberately distorted to decrease the coupling efficiency of the pulse

laser light. There were two reasons for the deliberately distort the coupling of laser

and multi mode fiber. One reason was that by tilt fiber on purpose, the collimate lens

of multi mode fiber did not reflect pulse laser light directly back into Ti:sapphire laser

system and therefore the mode locking mechanism was not disturbed. Another reason

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was that by distort the coupling between pulsed laser and multi mode fiber, great

amount of laser energy was diverted and only small portion was fed into the active

area of GaAs MSM photodetector, therefore the detector did not get saturated upon

measuring.

The whole set up diagram and experiment apparatus lay out can be referenced

in Fig. 3.10 and Fig. 3.11. The 3dB bandwidth of GaAs MSM photodetector was

measured under 5V biasing voltage and the read out of the spectra-analyzer was 2.6

GHz. For the 1×12 GaAs MSM photodetector array, the aggregated 3dB bandwidth

was 32 GHz

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1G 2G 3G 4G 5G

-11

-10

-9

-8

-7

-6

-5

-4

2.648GHz

Am

plitu

de

Frequency

Fig 3.18 2.6 GHz 3dB bandwidth of GaAs MSM photodetector

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Chapter 4

Epitaxial liftoff GaAs MSM photodetector array

4.1 Introduction.

Optical waveguide has an enormous capability for transmitting digital

information. One channel waveguide is able to transmit several Gagabits/sec light

pulse signal.60,61 In today’s fast moving computation speed in computer industry,

there is an accelerated trend to increase CPU’s speed to match up with Moor’s Law.

The intrinsic limitation of the present generation of computer has encouraged

researcher to seriously consider other computer architecture that uses optical

interconnects as main component. The basic limitations of electrical interconnects

include interconnection time, clock skew, resistance and capacitance time constants

and electromagnetic-interference (EMI) radiation.62,63 Optical interconnect has been

vigorously pursued as a better choice for the interconnecting different processors and

memories whenever the conventional electrical interconnect can not meet the system

requirements.

Other components in an optical interconnect system are optical sources and

optical receivers. Since CPU and other digital components are fabricated on the

silicon wafer, the first initiative would be to fabricate optical source and optical

receiver from silicon. Usually 850 nm light is used in short distance optical

interconnection.64,65 At 850 nm wavelength, silicon is not efficient in absorbing light

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and the absorption length is extremely long. Also because the silicon material is an

indirect band gap semiconductor, when 850 nm light illuminates silicon, electron hole

pairs are not efficiently generated. In order to keep momentum conservation, phonons

assistance are required if electron hole pairs are to be generated. For the optical

source, silicon is not a suitable material either. There is no laser source fabricated by

silicon up to date. The reason is the characteristics of the indirect band gap

semiconductor. There is near impossible to generate stimulated emission from silicon.

The suitable material for semiconductor lasers and photodetectors is GaAs. GaAs is a

direct bandgap semiconductor and stimulated emission is easy to be obtained.66,67 For

photodetector’s perspective, the light absorption length with 850nm wavelength in

GaAs material is short, and the direct bandgap characteristics of GaAs ensure an

efficient excitation for photon to generate electron hole pairs. The difficulty to utilize

GaAs into VLSI system lies in the different fabrication process between GaAs and

silicon. Also GaAs and silicon are dopants of each other, which means that Ga and As

atoms are considered to be contaminants of silicon material and vice versa. The only

way to cooperate GaAs device with VLSI silicon circuit is by afterwards integration.

The GaAs device has to be fabricated before it is integrated into VLSI system.

Because the fully embedded optical interconnect system has to have the

ability to be inserted among the layers of Printed Circuit Board (PCB), the

photodetector and semiconductor laser have to be fabricated in thin film formation.

Most microelectronic devices utilize only a thin layer near the surface of a

semiconductor wafer, in Metal-Oxide-Semiconductor (MOS) devices; for example,

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the first few hundred nanometers from the top of the wafer are used for electron

transport.68,69 The remainder of the several hundred micrometers in wafer thickness,

almost exclusively, serves as mechanical support for the devices. Electrical

interaction between devices and substrate may lead to a number of detrimental

parasitic effects. In addition, the conductive bulk substrate makes the full dielectric

insulation of independent neighboring components difficult; as a consequence

parasitic devices may become active. Fabricating devices in a thin layer offers a

variety of advantages, many of which result from the reduction or elimination of

unwanted parasitic interaction among the devices and the bulk substrate.70 A direct

approach to integrate silicon with GaAs is hetero-epitaxy growth using MOCVD or

MBE. In reality, this approach is very expensive and time consuming since a silicon

foundry has to be developed to allow such growth in conjunction with process of

silicon VLSI circuit. As mentioned above, silicon and GaAs are dopants to each

other. In another words they are mutual contamination for each other. Another

difficulty lies in the different lattice structure of these two semiconductors, and when

one kind material is grown on the other material as the substrate, large amounts of

defects, including dislocations exist and degrade greatly the device performance and

yield.

4.2 Thin film MSM phodector arry by epitaxial liftoff technique

In order to obtain thin film GaAs photodetector, epitaxial liftoff technique was

used. The technique relies on the separation of a thin film of epi-GaAs from its

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substrate, followed by direct bonding of the thin film to a host substrate. The first

successful epitaxial liftoff GaAs thin film was reported by Yablonovitch.71 Since

then, this technique has been used widely by different research group to demonstrate

novel devices.72-75 The mechanism of epitaxially liftoff thin film is to use the 1;1000

HF etching rate between GaAs and AlAs. Usually a thin layer of AlAs is grown

Black wax

GaAs device

AlAs sacrificial layer

Dilute HF

GaAs substrate

Fig 4.1 Step one of epitaxial liftoff thin film GaAs device

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Pressure

Black

Thin film GaAs device

H2O Host substrate

Fig 4.2 Step two of epitaxial liftoff thin film GaAs device

between substrate GaAs and epi layer of GaAs. There are two steps in the process as

illustrated in Fig. 4.1 and fig.4.2. A thick layer of black wax was melted on top of the

thin film device to give the device mechanical strength and handling capability after

the thin film was detached from its substrate. The layer of black wax also protects the

top surface of the thin film device. The whole sample was then emerged in 10% HF

for a period of time until sacrificial layer was totally etched away. At this point thin

film device would be separated from its substrate. The thin film device covered with

black wax at the top was then picked up from the solution of HF. It was first rinsed

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thoroughly with DI water and left to naturally dry for a period of time. Because the

mechanical support of the black wax, the thin film device was not difficult to handle.

The second step is to bond the GaAs thin film device to the host substrate. There is

the more critical step as the quality of adhesion affects yield directly. In the ideal

condition, strong adhesion is necessary to achieve good bonding. Glue less bonding

process is used to bond the thin film GaAs device to the host material. After bonding

to the host substrate, thin film device has to withstand later fabrication steps that are

needed to make electrical contact to other components on the PCB. It also has to have

good thermal conductivity. In the glue less bonding method, the mechanism of

bonding depends on the type of substrate surface on which the thin film device was

later transferred. The bonding force was Van der Waals forces between thin film

device and host substrate. In this case, both surfaces of substrate and thin film device

had to be as flat as possible.

The thin film GaAs device can be processed before epitaxial liftoff as well as after

epitaxial liftoff. In the procedure of fabricating device before epitaxial liftoff, the thin

film device has to be aligned with other features on the substrate and components

which it will later be integrated with. In the procedure of fabricating device after the

epitaxial liftoff, the thin film bonded to the substrate requires no precise alignment

when it is fabricated. Howeveer, after fabricating the thin film device and integrating

with other components of the system, the thin film device on the substrate still

requires precise alignment with other components. For this reason, all thin film device

fabrications are done before epitaxial liftoff and bonding.

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4.3 Design and fabrication of thin film GaAs MSM photodetector

All VLSI circuitry and optoelectronic devices are fabricated on either silicon

or III-V semiconductor amterial. Usually the thickness of silicon wafer and III-V

semiconductor wafer is 500-700 µm, but only a thin layer from top of the substrate

surface is utilized for electron transport. The rest several hundred micron-meters in

thickness of the wafer serve as the mechanical support. The design of thin film MSM

GaAs photodetector is based on the fact that the absorption length of 850 nm

wavelength light is around 2 µm in GaAs material. Also the lattice constant of AlAs

and GaAs are comparable and these two materials can be grown epitaxially on each

other. Another fact concerning epitaxial liftoff is that the HF etching rate of GaAs and

AlAs approaches 1000:1. The design of original device and finished thin film GaAs

MSM photodetector are shown in Fig. 4.3 and Fig. 4.4. GaAs is a direct band gap

semiconductor material, the light absorption could be more efficient to generate

electron-hole pairs. The 850 nm wavelength light is totally absorbed in 2 µm distance

from the top surface. The thin film GaAs MSM photodetector is designed to be 1 µm

thick of its active layer. The lost efficiency is compensated by reflection of light from

the silver layer at the bottom of thin film device. The reflectivity of silver at 850 nm

wavelength is 94%. So this 1µm thick thin film GaAs MSM photdetector has an

effective light absorbing layer equal to 2 µm. The thinner active layer also increase

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3000Å Metal contact

Au Au1000 Å

SiO2

1000 Å SiO2

1000 Å SiO2

1 µm GaAs

2000 Å AlAs GaAs Substrate

Fig. 4.3 Design of thin film GaAs MSM photodetector

the effective electrical field inside GaAs active area without sacrificing the efficiency

of detector. The increased electrical field facilitates the electron and hole transit time,

which result in higher 3dB bandwidth compared with the conventional GaAs MSM

photodetector having the normal 2 µm absorption length.

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3000Å Metal contact

Au Au1000 Å SiO2 1000 Å

SiO2 1000 Å SiO2

1 µm GaAs

1000 Å Ag

Fig. 4.4 Design of epitaxial liftoff thin film GaAs MSM photodetector

The top 1 µm active area of GaAs and 1000 Å AlAs are epitaxially grown on

(100) GaAs wafer. Array of GaAs MSM photodetector was first fabricated before the

epitaxial liftoff. The fabrication of GaAs MSM photodetector is very similar with

fabrication of thin film silicon MSM photodetector and conventional GaAs MSM

photodetector. The fabrication processes were performed in class-100 clean room.

The surface of GaAs wafer was first cleaned with DI water. It was followed by 10

minutes supersonic bath with acetone and 5 minutes supersonic bath with

Isopropanol. The wafer was rinsed by DI water for 5 minutes and then baked at a

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120°C oven for 10 minutes to evaporate excessive water residue. Following the

cleaning process, 1000 Å SiO2 was deposited on the GaAs surface by PECVD. The

photoresist, AZ 5209 was spin coated on the top of SiO2 layer. The RPM of the spin

was 4000 and the time of spine coating was 40 seconds. The wafer then went through

900C, 20 minutes soft bake curing.

Photolithography step was followed to form the pattern of interdigitate finger

contacts. This was followed by 1200C 20 minutes hard backing. In order for the

electrode finger pattern touch the surface of the active area of GaAs wafer, finger part

of SiO2 has to be etched away. SiO2 was wet etched by 1:6 oxide etchant. The 1500Å

Au was then deposited on the surface of epi-GaAs wafer using CHA e-beam

evaporator. The Au interdigitate finger pattern was defined by liftoff unwanted Au

from other place of GaAs surface. The finished interdigitate finger pattern has finger

spacing 2 µm.

After the deposition of interdigitate finger, the formation of contacting pad

was followed. The wafer was first spin coated with photo resist, AZ 5209 at 4000 rpm

for 40 seconds. Then it was put into oven and soft-baked at 90°C for ten minute. Then

the pattern of contacting pad was aligned with interdigitate finger through Karl-Suess

mask aligner. After the successful alignment of contacting pad with interdigitate

finger, 40 seconds UV light was shined on the sample and the pattern of pad was

defined. The pattern was formed after the sample was developed in AZ 425 developer

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for 20 seconds and followed by 1500Å Au deposition through CHA electron beam

evaporator. Final step was to liftoff unnecessary gold pad material by emerging

sample in acetone and ultrasonic bath for 30 seconds and then rinsed off with DI

water.

After the fabrication of GaAs MSM photodetector on the epi-wafer, the

epitaxial liftoff process was followed to obtain thin film device. The surface of the

device was first covered with molten black wax. Black wax was chosen because it

was easy to be handled and later to be cleaned away. It acted as the mechanical

support of the thin film device and the protection of the device surface. The black

wax at the edge of the device was carefully cleaned away by trichloroethylene. The

sample was then dipped into 10% HF for a period of time while it was carefully

monitored. Because the large different HF etching ratio between AlAs and GaAs, the

1000 Å thick AlAs sacrificial layer was gradually etch away while at the same time

the integrity of thin film GaAs was preserved. When the sacrificial layer was totally

etched away, the thin film device will separated from the rest of the substrate. The

thin film device was transferred out of the HF solution and was rinsed with DI water.

The thin film device was preserved in a container to let it dry naturally.

After the thin film was dry completely, a layer of 1500 Å thick silver was

deposited on the back end of the device through electron beam evaporator. The

function of this silver layer was to reflect 850 nm light back to GaAs. Because the

thickness of thin film GaAs MSM photodetector is 1 µm and 2 µm is the effective

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absorption length of 850 nm wavelength light in GaAs, the light is reflected back into

GaAs to make the 1 µm real thickness to be effectively 2 µm thick. Upon finishing

the deposition of thin layer of silver, the surface of the silver was intentionally

Fig 4.5 finished thin film MSM GaAs photodetector

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moistened with water vapor. The surface of the silver was pressed to the surface of

glass and moderate pressure was applied for a period of time. Finally the black wax

was removed by trichloroethylene. The finished thin film GaAs MSM photodetector

is presented in figure 4.5. The whole process of fabricating and wpitaxial liftoff thin

film GaAs MSM photodetector is shown in figure 4.6.

4.4 Characterization of thin film GaAs photodetector

The first measurement of thin film GaAs photodetedtor was its I-V

characteristic. The I-V characteristic was used to demonstrate its schottkey barrier

and rectify feature. Schottkey barrier forms at the interface of metal and GaAs and its

value is the difference between the value of work function of Au and the value of

electron affinity of GaAs. The I-V curve characteristic was measured using I-V curve

tracer. The I-V curve clearly demonstrates rectifying characteristic and the

breakdown voltage was 13 volts. The slightly decrease of the breakdown voltage of

thin film GaAs pdotodetector compared with normal GaAs photodetector might due

to the thickness decrease of the photdetector active area. This decrease of thickness

increases the effective electrical field in active area and as a consequence it generates

more hot electrons in the process.

Another I-V characteristic of GaAs MSM photodetector is its dark current.

The dark current was also measured by HP-4641 semiconductor analyzer. In GaAs

photodetector, majority of electron and hole pairs are generated by the energy

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Fig 4.6 Process of fabrication and epitaxial liftoff thin film GaAs MSM

photodetector

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absorbed from 850 nm laser light. Beside the electron and hole pairs resulted in form

absorbing energy of laser light, there are small amount of electron hole pairs

generated form thermionic emission of electrons from the valence band into the

conduction band. The formula to describe thermionic emission is equation 3.7.

The demonstration of thermionic emission is the existence of dark current.

The dark current was measured when the device was in total darkness. The dark

current of thin film GaAs MSM photodetector was 5.7 pA under 5V biasing voltage.

Compare with the dark current value of conventional GaAs MSM photodetector

under the same basing voltage, there was a 1.1 pA increase. The reason of that

increase was due to the dramatically thickness decrease of photodetector’s active

region. Because the decrease of the active region thickness, the applied effective

voltage was increased and that increase contributes higher value of dark current.

The responsivity of thin film GaAs MSM photodetector was measured in the

lab. The resposivity of photodector is defined as the ratio of the current produced by

the absorbing energy of 850 nm laser light, to the amount of light energy falling on

the detector. The resposivity of thin film GaAs MSM photodetector was measured as

0.25 A/W. The slight drop of the detector resposivity to the value of conventional

GaAs MSM photodetector was due to the 1 µm effective length of thin film device.

The total absorption length of 850 nm wavelength light in GaAs is 2µm. The

design of thin film GaAs MSM photodetector results in a thickness of active region to

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be 1µm. In order to compensate the 50% decrease of the total absorption length, one

layer of silver was deposited on the back of the thin film GaAs MSM photodetector.

The reflectivity of silver to 850 nm laser light is 94% which compensates the

thickness of active region to be a light less than 2 µm. Another reason for the drop of

resposivity might due to the much higher effective electrical field in the active region

of the photdetector, the higher effective electrical field might cause the detector to be

saturated.

The temporal response of thin thin film GaAs MSM photdetector was

measured through its 3dB bandwidth. The formula to express 3dB bandwidth is in

equation 3.8. The limitation of 3dB bandwidth is the electrons and holes transit time

needed from the location they are generated to the contacting electrode. The

instruments for 3dB bandwidth measurement include Ti:sapphire mode-locked femto-

second laser operating at the wavelength 850nm with a pulse width of about 150fs

and a repetition rate of 76MHz.The energy of laser was attenuated before it was fed

into a multi mode fiber. An optical isolator was also used between the fiber and laser

to block the back reflection of laser energy from the collimating lens of the fiber. The

fiber tip was directed vertically on the vicinity surface of active area of thin film

MSM GaAs photodetector.

The contacting pad was probed by a 40 GHz ground-signal-ground (GSG)

microwave probe. A 100k-18GHz biasing tee was connected to the probe and it

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provided biasing voltage through a DC voltage supply. An ampere meter was

connected between biasing tee and the probe to monitor the photocurrent. A 40G

high-speed cable was connected between biasing tee and HP spectra-analyzer. The

diagram of whole measurement setup can be referenced in Fig. 3.10. A microscope

was used to observe the probe when it was guided to the detector’s metal pad. After

the tip of the fiber was moved to the vicinity of active area of the detector, the read

out of ampere meter was closely watched and the fiber was move slowly to guarantee

maximum photocurrent, usually around 70-90 µA. The 3dB bandwidth of thin film

GaAs MSM photodetector was measured as 4.9 GHz under 5V biasing. The result is

expressed in Fig. 4.7. For the 1×12 GaAs MSM photodetector array, the aggregated

3dB bandwidth was 58.8 GHz. The increase of 3dB bandwidth is due to the decrease

of effective thickness of the detector, therefore increase effective voltage through the

region and decrease the transit time of electron hole pairs.

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4.9GHz

Fig. 4.7 4.9 GHz 3dB bandwidth of epitaxial liftoff GaAs MSM photodetecter

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Chapter 5

Integration of board level optical interconnection system

5.1 Introduction

The speed and complexity of integrated circuits have increased rapidly in

recent years, and this trend continues. With the increase of components per chip,

chips per board, the clock speed and the degree of integration, electrical

interconnects, which rely primarily on metallic (aluminum/copper) or poly-silicon

lines, are approaching fundamental limitations such as speed, packaging density, fan-

outs, and power dissipation.76,77 The CPU speed has been increased faster than

previous predicted. In 1997, The Semiconductor Industry Association (SIA) issued

the road map for CMOS technology and predicted that by the year 2009 more than

5000 I/O’s (pads) on the chip will be required and off-chip (chip-to-board) clock rate

will reach 2-3 GHz.78. The up-to-date commercial CPU speed has already exceeded

3GHz and the design of a 10 GHz CPU is underway. Conventional electrical

interconnects are unable to offer these high speed connection and wide-band

performance due to poor isolation at frequencies greater than a few giga-hertz.79,80

Furthermore, it is extremely difficult for a multiprocessor computing system, which

involves a large number of fan-outs and long interconnection lengths (>15cm), to

obtain synchronous high-speed (>500MHz) clock distribution using electrical

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interconnections.81 Recently, emphasis has been given to employing optical

technology for improving connection of devices on a signal chip as well as between

chips on a multi-chip-module.82,83

Just as fiber optics offers advantages in long-haul communication systems,

optical interconnection promises benefits for the future in computer system

communication. Its potential advantages include large bandwidth, no capacitive

loading, immunity from electromagnetic interference (EMI) and inherent parallelism.

Therefore, it can facilitate communication within computers by means of its high

speed, high capacity and high component-packaging density.84,85 In contrast to

electrical interconnections, the optical interconnection transmits information at higher

data rate, consumes less power. For circuits requiring complex interconnections, it

occupies less real estate on the board. Because of the dominance of the silicon CMOS

technology, however, the optical interconnect system under investigation should have

the possibility to integrate with today’s silicon technology.86,87.

There are several research directions in optical interconnect. One trend of

research is the implementing free-space optical interconnect system. 88,89 Although it

supports high speed connection between the CPU and memory, the main concern of

this system is the reliability issue. Because the beam of light in the system is routed to

some distance away, the system has to be rigid and stable at all times in order to keep

the beam stay aligned. If small uncertainty occurs, it is easy for the optical system to

go out of alignments. For example, when the system is moved to another location,

due to the vibrations from the process of relocation, the alignment of the system

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might be disturbed. Another research trend is fully embedded guided wave board-

level optical interconnect system. Compared to the free-space optical interconnect,

the system in fully embedded approach has the ability to withstand different

disturbances from outside world. A design diagram of the fully embedded guided-

wave board-level optical interconnection is presented in Fig.5 1. The three main

components of the system are the thin film GaAS MSM photo-detector array, the thin

film vertical cavity surface emitting laser (VCSEL) array and the multi-mode

polymer waveguide array.

µ -via WG mirror

Detector arrayPWB layers

WG layer

VCSEL array

Fig. 5 2 System architecture of fully embedded guided-wave board-level optical

interconnection.

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In the system of fully embedded guided-wave board-level optical

interconnect, all components are buried inside printed circuit board (PCB). The

pulsed laser lights emitting from the VCSEL array are first coupled into the multi-

mode waveguide array through 45o TIR micro-mirror couplers. They propagate

through the channels of waveguide array. At the other end of the waveguide array,

they are reflected again by 45o TIR micro-mirror couplers. Finally they illuminate

vertically on the active areas of the photo-detector array. The driving circuits of the

VCSEL array and the amplifying circuits of the photo-detector array are located on

the surface of the PCB. These circuits connect the VCSEL array and photo-detector

array through electrical vias. In this arrangement, the buried opto-electronic

components provide the performance improvement without occupying the surface of

PCB.

5.2 Integration of GaAs MSM photodetector array and polymer waveguide

array with 450 TIR micro-mirror couplers

The feasibility of fully embedded guided wave board-level optical

interconnect system was first demonstrated through integrating 1x12 GaAs MSM

photodector array and the polymer waveguide array with 450 TIR micro-mirror

coupler. Fig.5.2 illustrates the schematic of the integration. The two components of

this integration are the 1x12 GaAs MSM photo-detector array and the polymer

waveguide array with 45o TIR micro-mirror couplers. The center-to-center distance

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between adjacent detectors of 1x12 photo-detector array is 250 µm. This distance

maches the channel spacing of waveguide array. Each detector in the array has an

active area of 50x50µm.

The 45o TIR micro-mirror coupler was selected as the surface-normal coupler

because of its palnar nature and insensibility to the wavelength change in case of

wavelength shifting of laser. Compared with other conventional ways of coupling

laser beam surface-normally into waveguide, coupling through 45o TIR micro-mirror

coupler has certain advantages. One conventional way to attain surface normal

coupling is prism-lense coupling. Though it is a convenient way to change the

direction of light beam in most optical system, its bulkiness prevents it from being

used in fully embedded optical interconnect system. Another reason to reject prism-

lense coupling in the system is the issue of later planarization of the

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Photo-detector

substrate

Multi-mode waveguide

9020D

9120D

450 micro-coupler

Fig. 5.2 Schematic integration of GaAs MSM photodetector and waveguide with

micro coupler

system. Because of the inherited feature of prisms and lenses, there is no foreseeable

future to implement prism-lens coupling in fully embedded optical interconnect

system. Another method to couple laser beam surface-normally into waveguide is

grating coupling. Grating coupling needs precise control of grating parameters. It

normally has small tolerance to the shifting wavelength of laser. For the above-

mentioned reasons, TIR micro-mirror coupler was selected as the surface-nomal

coupler.

There are three steps to integrate the 1×12 GaAs MSM photodetector array

and the 1×12 polymer waveguide array with 450 micro-mirror couplers. First the

photodetector array was fabricated. Then the polymer waveguide was formed and

aligned on the top of the photodetector array. The final step was to open windows on

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the location of the photedetector array and form TIR micro-mirror couplers by RIE.

The fabrication process of the GaAs MSM photodector array is already described in

chapter 3. To fabricate the 1×12 polymer waveguide array and 450 micro-mirror

coupler, polymer Ultradel 9020D and Ultradel 9120D were used as materials for

buffer and core layer of the waveguide. These polymers are negatively photosensitive

therefore they can be patterned by conventional photolithography method. At 850nm

wavelength the refractive indexes of Ultradel 9020D and Ultradel 9120D are 1.54 and

1.56, respectively. The GaAs wafer with fabrocated photodetector array was first

cleaned and then spin coated with a thin layer of A600, the adhesion promoter that

helps the 9020D layer to stick better on the surface of GaAs. Then the bottom

cladding layer 9020D was spin coated on the wafer and the thickness of 9020D was

between 6-7 µm. 900C 2-minute soft back process was followed to remove residue

solvent. After forming the cladding layer, 6-7 µm thick 9120D polymer was spin

coated on the top of the 9020D polymer. Then the sample went through

photolithographic process to form 1×12 array of channel waveguide with dimension

of 50 µm in width, 12-13 µm in thickness and 250 µm separation spacing between

adjacent channel waveguides. During the fabrication of channel waveguides, the

active area of the MSM GaAs photodetector array was precisely aligned under the

channel waveguide array. RIE technique was utilized to form the 450 TIR micro-

mirror couplers. First, a layer of 3000Å thick aluminum was deposited on the surface

of the polymer by the electron-beam evaporator. Through photolithographic process

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and wet etching, an array of 50µm × 50µm square window was opened on the

aluminum layer at the top of the active area of GaAs MSM photodetector. During

RIE process the sample was placed at a 450 angle with respect to the bottom surface

of the chamber. As a result, an array of slanted surface with 450-angle was formed as

TIR micro-mirror couplers. Figure 5.3 shows the channel waveguide with 450 TIR

micro-mirror couplers. Figure 5.4 shows the integration between the GaAs MSM

photodetector array and polymer channel waveguide array with micro-mirror

couplers.

Fig. 5.3 Polymer channel waveguide array with 45o TIR micro-mirror coupler

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Fig5.4 GaAs MSM photodetector array integrated with polymer channel waveguide

array and 45o TIR micro-mirror couplers

5.3 Measurement of integrated GaAs MSM photedetector array and polymer

` channel waveguide array with 45o TIR micro-mirror couplers

When the MSM GaAs photodetector array was integrated with the polymer

channel waveguide array and micro-mirror couplers, it underwent 2000C temperature

for 30 minutes while the RIE procedure was being performed. The first concern with

MSM GaAs photodetector was the characteristic of Schottkey barrier of the detector.

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Certain duration of high temperature process acts as annealing process and it might

detrimentally affect Shottkey barrier. I-V characteristic of the system was first

measured though I-V curve tracer. I-V characteristic shows clearly the rectify

characteristics and the breakdown voltage of the detector remained same as 15 volts.

The measurement of I-V characteristic implies that Shottkey barrier exists and high

temperature process dose not affect rectify nature of the detector.

After the confirmation of unchanged Schottkey barrier and breakdown

voltage, the 3dB bandwidth the photodetector was tested. The experiment set up was

very similar to the setup of measuring individual MSM photdetector, except the

pulsed laser beam was coupled into one end of channel waveguide instead of on the

top surface of the GaAs MSM photodetector. One experiment detail need to be

pointed out was the use of ampere meter in the test setup to confirm the effective

coupling of pulse laser beam into the channel waveguide and the GaAs MSM

photodetector. The 3dB bandwidth of a single GaAs MSM photodetector was 2.6

GHz, remain same as that of the photodetector before the integration. The aggregated

3dB bandwidth of 12-channel waveguide was 32 GHz. The unchanged 3dB

bandwidth indicates that 30 minutes, 2000C RIE in the process of the integration does

not detrimentally affect the performance of the detector.

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Fig. 5.5 Cross talk measurement of channel array waveguide

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Before the integration of channel waveguide and the array MSM

photodetector, the cross talk between adjacent channels was measure. The definition

of cross talk is the electrical and magnetic field in one waveguide channel manifests

itself in an adjacent waveguide channel. The phenomenon that causes cross talk is

electromagnetic interference. The cross talk measurement setup is shown on figure

5.5. The 633 nm HeNe laser light was coupled into one channel of waveguide array

and the light signal was measured through an adjacent channel. The cross talk was

measured to be –32dB. This shows that optical channel waveguide has extremely

small electromagnetic interference among adjacent channels.

5.4 The integration of thin film GaAs MSM photodetector, channel

waveguide with micro-mirror coupler and thin film VCSEL

The complete fully embedded optical interconnect system is composed of

integration of the thin film GaAs MSM photodetector array, the thin film VCSEL

array and the channel waveguide array with TIR micro-mirror coupler. In order to be

consistent with the thin film photodetector and the thin film VCSEL, a flexible thin

film waveguide was fabricated. Soft molding technique was used to fabricate the

flexible thin film waveguide array with end 450 mirror. The commercial available

Topas film was used as the mechanical support of the channel waveguide array. The

core material of channel waveguide is SU8, which is a negative, epoxy-type, near-UV

photoresist based on EPON SU-8 epoxy resin. The value of refractive index of SU8 is

1.8. The fist step of fabricating thin film waveguide was to spin coat SU8 on Topas

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thin film. Then the mode with end 450-slant surface was pressed on the SU8 and

Topas film. They went into 2 hours baking in the oven. Upon finishing baking, the

Topas film could be simply peeled off from the mode and the flexible channel

waveguide was preserved. Soft molding procedure is a fast convenient method to

fabricating channel waveguide. Figure 5.6 shows a mirror end of the soft molding

waveguide.

Mirror surface

Fig. 5.6 450 mirror surface of soft molding waveguide

The VCSEL was designed to be emitting 850 nm laser and has a modulation

speed 2.5 GHz. The epitaxial structure of the VCSEL array was grown on a GaAs

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substrate. An etch stop layer of 100 nm thick Al0.98Ga0.02As was grown and then a

GaAs buffer layer, which includes 40.5 pairs of n-DBR (Distributed Brag Reflector),

10µm10µm

Effective aperture 12 µm

Fig.5.7. 10 µm thick thin film VCSEL array

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three GaAs quantum wells, and 23 pairs of p-DBR were grown. The total thickness

of the epitaxial structure is 10 µm. VCSEL array was first mechanically polished

down to 250 µm, and then it was back etched down to 10 µm thick. Figure 5.6 shows

a 10 µm thick VCSEL array and its detail structure.

Because in the fully embedded optical interconnect system, VCSEL takes the

role as emitter and the output power of thin film VCSEL is 2 mW, proper heat sink

structure has to be provided to VCSEL. The thermal behavior of VCSEL is described

in thermal diffusion equation.

pp CqT

Ck

tT

ρρ12

+∇=∂∂

where T is temperature, ρ is the material density of GaAs, is the specific heat and

k is the thermal conductivity. The boundary condition of VCSEL is no heat flow

pC

T0.3µm thick

thick 250

µm25

0, 2

00, 1

50,1

00,

10

Contact to H eat Sink (25 oC)

op contact PadTop contact pad

µm10 µm

VCSEL (GaAs)

18µm aperture activeregion

250 µm

Electroplated Cu, 30µm30µm Electroplated Cu

Contact to 250Heat sink

Fig. 5.8 10 µm thin film VCSEL with electro-deposited Cu heat sink

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through top and side boundary and the bottom keeps at constant room temperature.

The proposed structure is shown in figure 5.7. The structure requires that a 30 µm

layer Cu be deposited on the back of the VCSEL and the heat sink is connected to the

out side through 250 µm Cu vias. The simulated temperature in the active area of

VCSEL is 320C.7,8

The preliminary integration of the fully embedded optical interconnect system

was fabricated in the lab. The thin film 1×12 850 nm array VCSEL and the thin film

1×12 array GaAs MSM photodetector were used as transmitter and receiver of the

system. An array of flexible channel waveguide with 450 micro-mirror coupler was

used as transmitting media. The VCSEL array and the GaAs MSM photodetector

array were first fabricated. The thin film VCSEL array and thin film GaAs MSM

photodetector array were produced by epitaxially lift off. The flexible channel

waveguide array with 450 micro-mirror coupler was fabricated by soft molding

method. The integration was performed on Karl-Suess mask aligner. The flexible

waveguide was first bonded on a piece of clear glass mask using molten black wax.

The photodetector array and VDSEL array were placed on the sample holder on the

mask aligner. Very small amount of UV glue was applied on the top surface of the

photodetector array and the VCSEL array. The VCSEL array was aligned with the

flexible waveguide first and after UV expose the VCSEL array was fixed on the

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surface of waveguide. Same aligning procedure was performed on the GaAs

photdetector array. The finished system integration is shown on figure 5.8.

Flex Substrate

1X12 Waveguide

1X12 PD Array1X12 VCSEL Array

Fig. 5.9.Integrated GaAs MSM photodetector and VCSEL array with flexible

waveguide

5.5 Summary

This research work proposes a fully embedded optical interconnect system in

computer’s board level domain. The finished system includes three main components;

the thin film GaAs MSM photodetector array, the thin film 850 nm VCSEL array and

the polymer channel waveguide array with 450 total internal reflection micro-mirror

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couplers. As one of the components of integrated system, the MSM photodetector

array is investigated in details. Other issues investigated are different integration

methods.

There are several types of photodetectors exist. The motivation to utilize the

MSM type photodetector as the receiver of integrated system is its easiness to fabricat

and epitaxial lift off. The photodetctor array in semi-insulating GaAs wafer was

investigated at first. The DC and temporal characteristics were studied. The 3dB

bandwidth of single GaAs MSM photodetector was measured as 2.6 GHz. As a result,

the total aggregated bandwidth of the 1x12 photodetector array is 32 GHz. This result

is five times faster than the speed of today’s fastest system BUS. In order to achieve

the fully embedded optical interconnect system; the optical receiver, in this case

MSM photodetector array, has to be in the form of thin film type. To obtain the thin

film MSM GaAs photodetector array, the expitaxial liftoff procedure was investigated

in this research work. The thin film GaAs MSM photodetector was successfully

fabricated. The thickness of thin film GaAs MSM photodetector array was 1mm. The

DC and temporal responses of thin film GaAs MSM photodetector array were

measured. The 3dB bandwidth of the thin film detector was 4.6 GHz. The 3dB

bandwidth was almost two times better than that of detector made directly on the

semi-insulating GaAs wafer. It is the much thinner vertical distance of active GaAs

wafer causes the 3dB bandwidth improvement.

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The first step of integrating the system was accomplished. The integrated

system includes an MSM photodetector array and an array of polymer channel

waveguides with TIR micro-mirror couplers. The success of the integration was

confirmed by measuring photocurrent from the photodetector when the laser light was

launched into one end of polymer waveguide. The measured 3dB bandwidth of the

system’s single channel was 2.6 GHz. The total system integration was also

attempted. Three components, the thin film GaAs MSM photodetector, the thin film

850 nm VCSEL and the flexible polymer channel waveguide with 450 TIR micro-

mirror coupler have been physically integrated. Integration confirmation of the

system is being underway. Future works may include sending modulated signal from

VCSEL, and measure the DC, temporal response of the photodetector. The expected

3dB bandwidth of this fully embedded board-level optical interconnection is an order

higher when compared with the BUS bandwidth of state of art computer. Also the

fully embedded architecture will dramatically increase in BUS speed that constrained

by all electrical interconnect system and has no interference of today’s PCB

fabrication process.

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VITA

Lei Lin was born in LanZhou, GanSu, China on April 26, 1967, the son of XuGuo

Lin and PeiYing Zhu. After completing his work at No.33 High School, Lanzhou,

GanSu, China, in 1985, he entered LanZhou University in LanZhou, China. He

received the Bachelor of Science in Ceramic Material from Lanzhou University in

1989. After completing his undergraduate degree, he was employed by Institute of

Chemical Engineering of GanSu province from 1989 to 1994. In August 1994, he

entered Norfolk State University and received Master degree in Chemical Physics in

1996. In 1996, he entered University of North Carolina at Charlotte and received

Master degree in Electrical & Computer Engineering in 1998. In August 1998, he

entered the Graduate School of The University of Texas at Austin.

Permenent Address: Science Academy of GanSu Province

DingXi South Road, 730000

LanZhou, GanSu Province

P. R. China

This dissertation was typed by the author.