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© 2014 Chevron U.S.A. Inc. All rights reserved. Consequence Modeling and PSM Wilbert Lee Senior Staff Process Risk Engineer Chevron Energy Technology Company

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Page 1: Consequence Modeling and PSM - SAChEsache.org/workshop/2014Faculty/files/Consequence Modeling and PSM... · Consequence Modeling and PSM ... Pressure Vessel Burst ... © 2014 Chevron

© 2014 Chevron U.S.A. Inc. All rights reserved.

Consequence Modeling and PSM

Wilbert Lee Senior Staff Process Risk Engineer Chevron Energy Technology Company

Page 2: Consequence Modeling and PSM - SAChEsache.org/workshop/2014Faculty/files/Consequence Modeling and PSM... · Consequence Modeling and PSM ... Pressure Vessel Burst ... © 2014 Chevron

© 2014 Chevron U.S.A. Inc. All rights reserved.

Consequence Modeling

The use of models to assess the potential for

injury to persons and damage to buildings and

equipment that could result from a Loss of

Containment.

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Page 3: Consequence Modeling and PSM - SAChEsache.org/workshop/2014Faculty/files/Consequence Modeling and PSM... · Consequence Modeling and PSM ... Pressure Vessel Burst ... © 2014 Chevron

© 2014 Chevron U.S.A. Inc. All rights reserved.

Potential Hazards from Loss of Containment

Explosions

Fire

Flammable Cloud

Toxic Cloud

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Page 4: Consequence Modeling and PSM - SAChEsache.org/workshop/2014Faculty/files/Consequence Modeling and PSM... · Consequence Modeling and PSM ... Pressure Vessel Burst ... © 2014 Chevron

© 2014 Chevron U.S.A. Inc. All rights reserved.

Potential Hazards from Loss of Containment

Explosions

Vapor Cloud Explosion

Pressure Vessel Burst

Dust

Confined Explosion

Chemical

Fire

Jet Fire

Pool Fire

Flash Fire

Flares

BLEVE , (Boiling Liquid Expanding Vapor Explosion)

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© 2014 Chevron U.S.A. Inc. All rights reserved.

Potential Hazards from Loss of Containment

Toxic Release

Hydrogen Sulfide

Ammonia

Chlorine

Combustion Byproducts

Particulate Matter

Air Quality – SOx, NOx

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© 2014 Chevron U.S.A. Inc. All rights reserved.

Consequence Models & Methodology

Equations and calculations

Graphical

Computer Programs

Excel Based

Integrated Program, with Subroutines

Single Hazard Program

Dispersion

Accidental Release

Air Quality, (Gaussian)

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© 2014 Chevron U.S.A. Inc. All rights reserved.

Use & Purpose of Consequence Modeling

Project Design

Risk management and reduction

Plant Layout:

Vents and PSV’s

Flares

Building Siting

Risk Assessments

Qualitative

Quantitative, (QRA’s)

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© 2014 Chevron U.S.A. Inc. All rights reserved.

Use & Purpose of Consequence Modeling

Regulatory:

EPA Risk Management Plan, (RMP)

OSHA PSM – Facility Siting

UK, Europe, & Australia Safety Case

Inherently Safer Design

Emergency Response Procedures

Operating Procedures

Maintenance Procedures

Company Policy

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© 2014 Chevron U.S.A. Inc. All rights reserved.

Use & Purpose of Consequence Modeling: Facility Siting Assessments

API RP-752 & RP-753, (Permanent & Portable

Buildings)

Refineries, Gas Plants, and Chemical Plants

Methodology for managing potential risks to

personnel in occupied buildings that could result

from releases in process units

Possible Hazards Include:

Explosion

Fire

Toxic Releases

Consequence or Risk Based Analysis

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© 2014 Chevron U.S.A. Inc. All rights reserved.

Potential Sources of Releases

Rupture, puncture, leak or hole in:

Pressure Vessels

Equipment:

Pipes

Pumps

Compressors

Flares, Vents, PSVs

Valves, Gaskets, Seals, Flanges, Bleeders

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© 2014 Chevron U.S.A. Inc. All rights reserved.

Potential Sources of Releases

Transportation Vehicles:

Trucks

Railcars

Ships

Pipelines:

Above ground

Below ground

Subsea

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© 2014 Chevron U.S.A. Inc. All rights reserved.

Model Capabilities & Considerations

Thermodynamics

Multi-Component

Release Rate

Aerosol Effects

Weather Conditions

Pool Evaporation

Surface Roughness

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© 2014 Chevron U.S.A. Inc. All rights reserved.

Model Capabilities & Considerations

Possible Hazards:

Explosion

Fire

Dispersion – Toxics & Flammables

Flares: Radiant Heat

Model Validation

Accidental versus Air Quality Model

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© 2014 Chevron U.S.A. Inc. All rights reserved.

Explosion Modeling: Factors

Energy Term

Congestion

Confinement

Fuel Reactivity

Ignition Strength

Shielding and Channeling Effects

Venting of Overpressure Buildup

Deflagration versus Detonation

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© 2014 Chevron U.S.A. Inc. All rights reserved.

Explosion Models

Baker Strehlow

TNO Multi-Energy

TNT

CAM

SCOPE

Computation Fluid Dynamics, (CFD)

FLACS

EXSIM

AutoReaGas

(Note: Some models are proprietary)

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© 2014 Chevron U.S.A. Inc. All rights reserved.

Dispersion Models

Accidental Releases:

Canary, (Quest Consultants)

PHAST, (DNV)

SAFER TRACE, (SAFER Systems)

Air Quality:

AERMOD

Screen3

ISCST3

Many Others

First Responders:

ALOHA

CAMEO 16

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© 2014 Chevron U.S.A. Inc. All rights reserved.

Endpoint or Concentration Criteria

Flammable Gas Dispersion

Lower Flammable Limit, (LFL)

Upper Flammable Limit, (UFL)

Criteria to Keep From Potential Ignition Sources:

20-50% LFL

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Substance LFL UFL

Methane 5% 15%

Propane 2.1% 9.5%

Hydrogen 4% 75%

Page 18: Consequence Modeling and PSM - SAChEsache.org/workshop/2014Faculty/files/Consequence Modeling and PSM... · Consequence Modeling and PSM ... Pressure Vessel Burst ... © 2014 Chevron

© 2014 Chevron U.S.A. Inc. All rights reserved.

Toxic Endpoint Criteria

ERPG: Emergency Response Planning

Guidelines

ERPG-1, 2, 3: (1) Hour Exposure

Minor Health Effects, (max) Serious Health Effects, (max limit, without

experiencing) Life-Threatening Effects, (max limit, without

experiencing)

AEGL: Acute Exposure Guideline Levels

AEGL 1, 2, 3

(10) min to (8) hr Exposure Duration

Similar to ERPG Health Effects Definitions

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© 2014 Chevron U.S.A. Inc. All rights reserved.

Toxic Endpoint Criteria

IDLH: Immediate Dangerous Limit or Health

TLV & STEL: Worker Exposure

Threshold Limit Value, Short-Term Exposure Limit

8 hour and 15 min

Dosage & Probits

Exposure Time & Concentration

Potential Fatality rates

Can be used in QRA’s

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© 2014 Chevron U.S.A. Inc. All rights reserved.

Hydrogen Sulfide Endpoint Criteria, (ppm)

ERPG-1: 0.1ppm

ERPG-2: 30 ppm

ERPG-3: 100 ppm

AEGL-1: 0.51ppm, (1 hour)

AEGL-2: 27 , (1 hour)

AEGL-3: 50 , (1 hour)

IDLH:100 ppm

TLV:1 ppm

STEL:5 ppm

1% Fatality for (1) Hour Exposure:160 ppm* * - Perry and Articola – CCPS 1980

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© 2014 Chevron U.S.A. Inc. All rights reserved.

Radiant Heat Endpoint Criteria

Jet, Pool Fires, & Flares

API 521 Flare Design Criteria: (max)

500 Btu/hr-ft2: Continuous exposure for personnel

1500 Btu/hr-ft2: Personnel Exposure only for several minutes

2000 Btu/hr-ft2: Personnel Exposure only for 1 minute

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Page 22: Consequence Modeling and PSM - SAChEsache.org/workshop/2014Faculty/files/Consequence Modeling and PSM... · Consequence Modeling and PSM ... Pressure Vessel Burst ... © 2014 Chevron

© 2014 Chevron U.S.A. Inc. All rights reserved.

Example of Dispersion Modeling, (Canary 4.4)

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Scenario Weather

Conditions

Distance to LFL, (ft)

Distance to 20% LFL,

(ft)

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© 2014 Chevron U.S.A. Inc. All rights reserved.

Example of Dispersion Modeling, (Canary 4.4)

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Scenario Weather

Conditions

Distance to LFL, (ft)

Distance to 20% LFL,

(ft)

1/2” Hole, Methane at 50 psig Sunny Day

10 mph wind 3 7

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© 2014 Chevron U.S.A. Inc. All rights reserved.

Example of Dispersion Modeling, (Canary 4.4)

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Scenario Weather

Conditions

Distance to LFL, (ft)

Distance to 20% LFL,

(ft)

1/2” Hole, Methane at 50 psig Sunny Day

10 mph wind 3 7

1/2” Hole, Methane at 200 psig

Sunny Day 10 mph wind 5.6 13

Page 25: Consequence Modeling and PSM - SAChEsache.org/workshop/2014Faculty/files/Consequence Modeling and PSM... · Consequence Modeling and PSM ... Pressure Vessel Burst ... © 2014 Chevron

© 2014 Chevron U.S.A. Inc. All rights reserved.

Example of Dispersion Modeling, (Canary 4.4)

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Scenario Weather

Conditions

Distance to LFL, (ft)

Distance to 20% LFL,

(ft)

1/2” Hole, Methane at 50 psig Sunny Day

10 mph wind 3 7

1/2” Hole, Methane at 200 psig Sunny Day

10 mph wind 5.6 13

1/2” Hole, Propane at 200 psig

Sunny Day 10 mph wind 20 130

Page 26: Consequence Modeling and PSM - SAChEsache.org/workshop/2014Faculty/files/Consequence Modeling and PSM... · Consequence Modeling and PSM ... Pressure Vessel Burst ... © 2014 Chevron

© 2014 Chevron U.S.A. Inc. All rights reserved.

Example of Dispersion Modeling, (Canary 4.4)

26

Scenario Weather

Conditions

Distance to LFL, (ft)

Distance to 20% LFL,

(ft)

1/2” Hole, Methane at 50 psig Sunny Day

10 mph wind 3 7

1/2” Hole, Methane at 200 psig Sunny Day

10 mph wind 5.6 13

1/2” Hole, Propane at 200 psig Sunny Day

10 mph wind 20 130

2” Hole, Propane at 200 psig Sunny Day

10 mph wind 500 1100

Page 27: Consequence Modeling and PSM - SAChEsache.org/workshop/2014Faculty/files/Consequence Modeling and PSM... · Consequence Modeling and PSM ... Pressure Vessel Burst ... © 2014 Chevron

© 2014 Chevron U.S.A. Inc. All rights reserved.

Example of Dispersion Modeling, (Canary 4.4)

27

Scenario Weather

Conditions

Distance to LFL, (ft)

Distance to 20% LFL,

(ft)

1/2” Hole, Methane at 50 psig Sunny Day

10 mph wind 3 7

1/2” Hole, Methane at 200 psig Sunny Day

10 mph wind 5.6 13

1/2” Hole, Propane at 200 psig Sunny Day

10 mph wind 20 130

2” Hole, Propane at 200 psig Sunny Day

10 mph wind 500 1100

2” Hole, Propane at 200 psig Night

5 mph wind 900 2000

Page 28: Consequence Modeling and PSM - SAChEsache.org/workshop/2014Faculty/files/Consequence Modeling and PSM... · Consequence Modeling and PSM ... Pressure Vessel Burst ... © 2014 Chevron

© 2014 Chevron U.S.A. Inc. All rights reserved.

Example of Dispersion Model Output

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0.0

10.0

20.0

30.0

40.0

50.0

60.0

70.0

0.0 20.0 40.0 60.0

Momentum Jet CloudCONCENTRATION CONTOURS: SIDE VIEW

LPG Release

CANARY by Quest Thu Jul 17 14:25:28 2014D stability

windspeed = 10.0 mphcasename=1LPGtst

9.50 mole percent Propane 2.10 mole percent Propane 1.05 mole percent Propane

He

igh

t (f

ee

t)

Downwind Distance (feet)

Page 29: Consequence Modeling and PSM - SAChEsache.org/workshop/2014Faculty/files/Consequence Modeling and PSM... · Consequence Modeling and PSM ... Pressure Vessel Burst ... © 2014 Chevron

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Example of Explosion Model Output

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References for Information

CCPS: “Guidelines for Consequence Analysis of Chemical

Releases”

CCPS: “Guidelines for Vapor Cloud Explosions, Pressure

Vessel Burst, BLEVE and Flash Fire Hazards”

CCPS: “Guidelines for Chemical Process Quantitative Risk

Analysis”

API 752: “Management of Hazards Associated with Location

of Process Plant Permanent Buildings”

API 521: “Guide for Pressure-relieving and Depressuring

Systems”

Lee’s Loss Prevention in the Process Industry

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CCPS: “Guidelines for Consequence Analysis of Chemical Releases” - Equations, Graphs & Excel Spreadsheets

Liquid Discharge through a Piping System

Gas Discharge through a Hole

Pool Evaporation

Vapor Cloud Explosion Model

Overpressure from a Ruptured Vessel

Range of a Fragment in Air

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CCPS: “Guidelines for Consequence Analysis of Chemical Releases” - Equations, Graphs & Excel Spreadsheets

BLEVE Thermal Flux

BLEVE Blast Fragments

Overpressure from a Combustion in a Vessel

Radiation from a Burning Pool

Radiant Flux from a Jet Fire

Thermal Flux Dosage Fatality Estimate

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Use of Consequence Modeling in PSM: Summary

Identify Potential Hazards:

PHA’s

Review of plant & drawings

Estimate Potential Impact & Hazard

Understand why modeling is needed

Use to improve/determine design basis

Mitigation Options

Procedures and Emergency Response

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Use of Consequence Modeling in PSM: Other Issues

Know what models and methods are available

Understand limits & boundaries of models

Understand accuracy and sensitivities of model

Understand what data is needed to run analysis

Determine most appropriate model to use

Understand that models only provide estimates

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Questions ?

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