confidential report air emissions survey(elv), while uncertainty of measurement results are...

CONFIDENTIAL REPORT

AIR EMISSIONS SURVEY

AT

THE RECYCLING VILLAGE

FOR

IVAN CALLAGHAN

Licence Reg. W0286-01

TMS Environment Ref. 26030

Commencement Date: 14 February 2019 Completion Date: 18 April 2019

Reporting Site Personnel Analysts

Graham Adams

Graham Adams

Approved by:

Date: 18 April 2019

Dr Imelda Shanahan

Technical Manager

Phone: +353-1-4626710

Fax: +353-1-4626714

Web: www.tmsenv.ie

TMS Environment Ltd

53 Broomhill Drive

Tallaght

Dublin 24

t m s environment ltd

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The Recycling Village (WO386-01) Emissions Survey

Revision 1.0 Quarter 1 & Biannual #1, 2019

TMS Environment Ref. 26030, of 37

EXECUTIVE SUMMARY

This Air Emissions report presents results of emissions monitoring from Vent A1 at The

Recycling Village Duleek, Co Meath to satisfy the requirements of Waste Licence Register

WO286-01. Monitoring has been conducted to satisfy the customer’s requirements in respect

of the following parameters:

Particulate Matter

Total Heavy Metals including Mercury (Including Al, As, Cd, Cr, Cu, Pb, Ni, Zn & Hg)

Velocity and Temperature

Measurements were completed by Air Scientific on the 14 February 2019. Details of the

monitoring methods employed, Standard Reference Methods used and Guidance Notes

consulted are presented in Section 4.0 of this report together with information on the

equipment used and the monitoring personnel.

The results for all of the measurement parameters reported are compared with the licence

Limit Values specified in the customer’s Waste Licence.

From the results presented in Section 3.0 it is clear that the results for particulate monitoring

comply with Waste Licence Reg. No: WO286-01. There are no emission limits specified for

Metals.

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1.0 Scope....................................................................................................................... 4

2.0 Survey protocol ..................................................................................................... 4

2.1 Protocol .................................................................................................................. 4

3.0 Monitoring Results................................................................................................ 5

3.1 Results for Vent A1 14 February 2019, 12:30-13:00 Particulates .................... 5

3.2 Results for Vent A1 14 February 2019, 11:17-12:17 Heavy Metals ................. 5

3.3 Reference Conditions for Vent A1....................................................................... 5

4.0 Supporting Information ....................................................................................... 6

4.1 Monitoring team information .............................................................................. 6

4.2 Substance(s) monitored, SOP’s and Standard Methods ................................... 6

4.3 Reporting results ................................................................................................... 6

4.3.1 Expression of test results ...................................................................................... 6

4.3.2 Reporting results less than the detection limit ................................................... 6

4.3.3 Uncertainty calculation ........................................................................................ 7

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1.0 Scope

This report deals with a survey of emissions to atmosphere from Vent A1 at The

Recycling Village Duleek, Co Meath to satisfy the requirements of Waste Licence

Register No. W0386-01. The licence requirements satisfied are summarized as

follows:

Reporting period Quarter 1 & Bi-annual #1 - 2019

EMISSION

POINT PARAMETER

SAMPLING METHOD AND

MEDIUM & ANALYSIS

METHODOLOGY

STANDARD REFERENCE

METHOD

Vent A1

Temperature, Pressure,

Velocity, Flow

Pitot tube coupled with pressure

measurement device or

anemometer, and temperature

measurement device

EN/ISO 16911-1:2013

Particulate Matter

Isokinetic,

Filter & rinse /

Gravimetric analysis

EN 13284-1:2002

Metals & Mercury

Metals - Isokinetic

Nitric peroxide solution /

Analysis by ICP-MS, ICP-OES or

ICP-AAS

Mercury – Isokinetic/

Potassium dichromate or potassium

permanganate solution /Analysis by

CV-AAS, ICP-MS or CV-AFS

MID 14385:2013 Ver. 4

2.0 Survey protocol

2.1 Protocol

The monitoring survey was completed on the 14 February 2019. Emissions to

atmosphere from Vent A1 were monitored during the visit. The survey was completed

in order to meet the requirements of the company’s Waste Licence (Reg. No. W0386-

01)

Relevant Process conditions during the survey are summarized below.

Operational information during testing

Emission

monitoring

point

Date Time Details

A1

14 Feb

2019

12:30 – 13:00

11:17 – 12:17

Continuous Process, normal loading variable

loads. Fan extraction volts checked daily to

determine if filters are functional. If not filters

are changed to ensure the maximum amount of

dust and heavy metals are extracted.

Abatement System SARF Carbon filters and Pleated Panel filters

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A Site Specific Protocol was prepared in accordance with EPA Air Guidance Note

AG1 and CEN/TS 15675:2007 after a site review has been conducted with site

personnel. A site risk assessment was completed prior to commencement of any

monitoring to confirm that the monitoring could be carried out in a safe manner. All

necessary PPE was worn at all times on site.

3.0 Monitoring Results

The results of the air emission monitoring reported in this document are presented in

tables below.

3.1 Results for Vent A1 14 February 2019, 12:30-13:00 Particulates

Note: Air Scientific conducted monitoring

3.2 Results for Vent A1 14 February 2019, 11:17-12:17 Heavy Metals

Note: Air Scientific conducted monitoring

3.3 Reference Conditions for Vent A1

Reference Conditions for concentrations and volume flow as expressed as:

Parameter Emission

limit value

Emission

results Uncertainty Units

Mass

emission

kg/hr

Compliance

Particulates 10 7.28

± 0.77 mg/m3 N/S

Yes

Blank 10 < 0.79

± 0.79 mg/m3 N/S

Yes

Volume

Flow Rate 10,000 9,587 ±681 Nm

3/hr - Yes

Parameter Emission limit

value

Emission

results Uncertainty Units

Mass

emission

Total Heavy

Metals NS < 0.31 ± 0.01 mg/m

3 N/S

Blank NS < 0.01

± 0.01 mg/m3 N/S

Volume Flow

Rate 10,000 9,506 ±589 Nm

3/hr -

Temperature, K Pressure, kPa Oxygen % Moisture %

273 101.3 N/A N/A

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4.0 Supporting Information

4.1 Monitoring team information

Name Function Qualification

Graham Adams Environmental Engineer

Team Leader

Bachelor of Engineering (Hons.) in

Manufacturing Engineering.(2006) ITT Dublin

National Diploma in Mechanical Engineering

(2004), ITT Dublin

4.2 Substance(s) monitored, SOP’s and Standard Methods

Substance

Monitored SOP Standard Method Analysis by

Accreditation

Range mg/m3

ISO 17025 Accreditation

Status

Analysis

Date

Total

Particulate N/S

EN 13248-1 ISO 9096:2003

CLS 0.1-50

20-1,000 I

22 Feb -

07 Mar

2019 Total

Particulate

(Rinse) N/S

EN 13248-1 ISO 9096:2003

CLS 0.1-50

20-1,000 I

22 Feb -

07 Mar

2019

Heavy

Metals

QP-

SITE-

2017

EN 14358: 2014

CSL 0.005-50 I 22 Feb -

07 Mar

2019

Mercury QP-

SITE-

2023 EN 13211: 2001 CSL 0.001-50 I

22 Feb -

07 Mar

2019

Moisture N/S EN 14790:2005 Air

Scientific 2-40% J

14 Feb

2019

Velocity

& Temp N/S

EN 13284-1:2002/

EN/ISO 16911-

1:2013

Air

Scientific

2.8-25m/s 0.13-40m/s

0-1,200

oC

J 14 Feb

2019

Note 1: ISO 17025 Accreditation Status: I – Air Scientific accredited for Monitoring and Subcontract Lab accredited for

Analysis, J – Air Scientific accredited for Monitoring and Analysis.

4.3 Reporting results

4.3.1 Expression of test results

All test results are expressed to one decimal place lower than the Emission Limit Value

(ELV), while uncertainty of measurement results are expressed to two decimal places lower

than the ELV, e.g. where an ELV of 50mg/m3 applies, the reported result shall be reported to

the first decimal place e.g. 6.6mg/m3

with the uncertainty of measurement reported to two

decimal places, e.g. ±0.12mg/m3.

4.3.2 Reporting results less than the detection limit

If a single result is reported as being less than the limit of detection, the measurement result is

expressed using a less than “<” sign, e.g. <0.005 mg/Nm3. Where a number of parameter

results, found to be less than the limit of detection, are expressed as an overall parameter,

these results are calculated as per Section 3.3, Method 3 (Half the Limit of Detection) of the

EPA BREF Guidance on the General Principles of Monitoring. This percentage method

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provides an estimation of the value of the measurement. It is reported without the less than

“<” sign, e.g. 0.05 mg/Nm3.

4.3.3 Uncertainty calculation

An estimation of the uncertainty of measurement is attached to all measurements.

Measurement uncertainties are based on calibration data and laboratory repeatability

experiments. All uncertainties are given at a 95% confidence, based on applying a coverage

factor of k=2 to the combined uncertainties for each measurement. The uncertainty of

measurement associated with emissions monitoring are provided in Air Scientific report in

Appendix II.

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TMS Environment Ref. 26030, Appendix I, of 37



QUARTER 1 PARTICULATES &

BI-ANNUAL 1 HEAVY METALS

APPENDIX I

EMISSION POINT DETAILS

Licence Reg. WO 386-01


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Appendix1:1 – Stack Diagram A1

Appendix1:2 - Stack Information

Emission Point A1 (Vent)

Stack Length [m] 0.9

Stack Length [m] 0.6

Stack Cross Sectional Area [m2] 0.54

Number of Ports 2

Number of sampling planes 2

Number of Sampling points per

line 4

Power supply available Yes

Shelter at platform Yes

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Appendix1:3 – Particulate Matter Stack Measurements Vent A1

Reference method EN 13284

Sampling date 14 February 2019

Sampling time 12:30-13:00

Sampling technique

Flue gas sampling system Isokinetic in stack filtration system

Oxygen measurement technique N/A

Material

Sampling probe material Titanium

Filter material GFF

Sampling conditions

Probe temperature [oC] 26.2

Average sampling flow rate [l/min] 14.8

Total sampling time [min] 30

Sampled volume of the dry gas at STP [m3] 0.44

Average flue gas velocity [m/s] 5.2

Nozzle diameter [mm] 8

Ratio of highest to lowest velocity < 1:3

Swirl test result Pass

Initial leak test result [% of expected sampling flow

rate] < 2

Final leak test result [% of average sampling flow

rate] <2

Average flue gas temp temperature [oC] 17.5

Reference conditions Actual conditions

Moisture [%] 0 Moisture [%] 0.0

Temperature [K] 273 Temperature [K] 290

Pressure [kPa] 101.3 Pressure [kPa] 102.2

Oxygen [%] N/A Oxygen [%] N/A

Deviation from isokinetic conditions [%] 0.2

Deviation from reference method

Monitoring Point does not conform to AG2

requirement of being at least 5 hydraulic stack

diameters upstream of the sampling plane and

2 hydraulic diameters downstream.

Appendix1:4 – Manual method results A1

Parameter Result mg/m3 Normalised Result mg/Nm

3

Particulates N/S 7.28

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Appendix1:5 –Heavy Metal Stack Measurements Vent A1

Reference method EN 14358 & EN 13211

Sampling date 14 February 2019

Sampling time 11:17-12:17

Sampling technique

Flue gas sampling system Isokinetic in stack filtration system

Oxygen measurement technique N/A

Material

Sampling probe material Titanium

Filter material Quartz

Trapping solution for metals 3.3%HNO3 @ 1.5%H2O2 @ DI H2O

Trapping solution for Mercury KMnO4@H2SO4@H2O

Sampling conditions

Probe temperature [oC] 181.8

Filtration temperature [oC] 181.3

Average sampling flow rate [l/min] 14.7

Total sampling time [min] 60

Sampled volume of the dry gas at STP [m3] 0.87

Average flue gas velocity [m/s] 5.28

Nozzle diameter [mm] 8

Ratio of highest to lowest velocity < 1:3

Swirl test result Pass

Initial leak test result [% of expected sampling flow

rate] < 2

Final leak test result [% of average sampling flow

rate] <2

Average flue gas temp temperature [oC] 24.6

Reference conditions Actual conditions

Moisture [%] 0 Moisture [%] 0

Temperature [K] 273 Temperature [K] 298

Pressure [kPa] 101.3 Pressure [kPa] 102.3

Oxygen [%] N/A Oxygen [%] N/A

Deviation from isokinetic conditions [%] -0.3

Deviation from reference method

Monitoring Point does not conform to AG2

requirement of being at least 5 hydraulic stack

diameters upstream of the sampling plane and 2

hydraulic diameters downstream.

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The Recycling Village (WO386-01) Emissions Survey Emissions Survey, Quarter 3, 2018

Revision 1.0 Quarter 1 & Biannual #1, 2019 Ref. 25672

TMS Environment Ref. 26030, Appendix II, of 37 Appendix II, Page 12 of 31



QUARTER 1 PARTICULATES &

BI-ANNUAL 1 HEAVY METALS

APPENDIX II

AIR SCIENTIFIC REPORT

Licence Reg. WO 386-01


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Document No: REVITL8140219B Licence Number: W0286-01 Visit No: 1 Licence Holder: The Recycling Village Year: 2019 Facility Location: Duleek, County Meath Office: Limerick Version No: 2

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Report Title Air Emissions Compliance Monitoring Emissions Report

Company address Air Scientific Ltd., Unit 5, Caherdavin Business Centre, Caherdavin,

Park, Ennis Road, Limerick V94 NT63.

Stack Emissions Testing Report Commissioned by TMS Environment Limited

Facility Name The Recycling Village

Contact Person Graham Adams

EPA Licence Number W0286-01

Licence Holder The Recycling Village

Stack Reference Number A1

Dates of the Monitoring Campaign 14-02-2019

Job Reference Number REVITL814022919B

Report Written By Mr Jer Moore

Report Approved by Mark McGarry

Stack Testing Team Mr Jer Moore & Mr Mike Flood

Report Date 17-04-2019

Report Type Test Report Compliance Monitoring

Version 2

Signature of Approver

Operations Manager

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Contents

1.0 Executive Summary ................................................................................................................................................................................ 3 1.1 Overall aim of the monitoring campaign ................................................................................................................................................ 3 1.2 Summary of substances to be monitored at each emission point .......................................................................................................... 3 1.3 Special Requirements ............................................................................................................................................................................. 3 1.4 Summary of Results ................................................................................................................................................................................ 4 Emission Point Number: A1 ............................................................................................................................................................................... 4 1.5 Operating Information ........................................................................................................................................................................... 5 Please reference Process Details as per Appendix III attached. ........................................................................................................................ 5 1.6 Monitoring Deviations ............................................................................................................................................................................ 5 1.7 Reference Documents ............................................................................................................................................................................ 5 1.8 Revision History ...................................................................................................................................................................................... 5 Part 2: Supporting Information ........................................................................................................................................................................ 6 Appendix I ......................................................................................................................................................................................................... 7 1.1 Monitoring Personnel ............................................................................................................................................................................. 7 1.2 Equipment Inventory .............................................................................................................................................................................. 8 Appendix II ........................................................................................................................................................................................................ 9 2.1 Stack Emission Point Reference: A1 ....................................................................................................................................................... 9 2.1.1 Suitability of Sample Location: .......................................................................................................................................................... 9 2.1.2 Stack Diagram ................................................................................................................................................................................. 10 2.1.3 Stack Raw Data ............................................................................................................................................................................... 11 Appendix III: Certificates and Process Detail Form .................................................................................................................................... 19

Opinions and interpretations expressed herein will be outside the scope of Air Scientific Limited INAB accreditation. This test report shall not be reproduced, without the written approval of Air Scientific Limited.

All sampling and reporting is completed in accordance with Environmental Protection Agency Air Guidance Note 2 requirements.

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1.0 Executive Summary

1.1 Overall aim of the monitoring campaign

The aim of the monitoring campaign was to demonstrate compliance with a set of emission limit values as specified

in the site licence.

1.2 Summary of substances to be monitored at each emission point

Stack Name: A1

Total Particulate Matter

Metals (Al, As, Cd, Cr, Cu, Ni, Pb & Zn)

Mercury (Hg)

Volumetric Flow Rate (Ref)

1.3 Special Requirements

There were no special requirements

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1.4 Summary of Results

Emission Point Number: A1

Parameter Method Units Result MU +/- Limit O2 Ref.

(%)

Moisture

Ref.(%) Compliant Blanks Date Time on Time off

Accreditation

Sampling Analysis

Particulate Matter EN 13284-1 mg.m-3 7.28 0.77 10 N/a N/a Yes 0.79 14/02/2019 12:30 13:01 Yes Yes

Volumetric Flow Rate (Ref) EN 16911 m3.h-1 9587 681 10,000 N/a N/a Yes N/a 14/02/2019 12:30 13:01 Yes N/a

Total Metals EN 14385 mg.m-3 <0.3083 0.01115 N/a N/a N/a N/a 0.0111 14/02/2019 11:17 12:18 No Note 3 No

Aluminium EN 14385 mg.m-3 <0.2040 0.00738 N/a N/a N/a N/a 0.1882 14/02/2019 11:17 12:18 No Note 3 No

Arsenic EN 14385 mg.m-3 <0.0007 0.00002 N/a N/a N/a N/a 0.0006 14/02/2019 11:17 12:18 Yes Yes

Cadmium EN 14385 mg.m-3 <0.0015 0.00006 N/a N/a N/a N/a 0.0007 14/02/2019 11:17 12:18 Yes Yes

Chromium EN 14385 mg.m-3 <0.0175 0.00063 N/a N/a N/a N/a 0.0024 14/02/2019 11:17 12:18 Yes Yes

Copper EN 14385 mg.m-3 <0.0014 0.00005 N/a N/a N/a N/a 0.0008 14/02/2019 11:17 12:18 Yes Yes

Lead EN 14385 mg.m-3 0.0491 0.00177 N/a N/a N/a N/a 0.0022 14/02/2019 11:17 12:18 Yes Yes

Nickel EN 14385 mg.m-3 <0.0032 0.00011 N/a N/a N/a N/a 0.0028 14/02/2019 11:17 12:18 Yes Yes

Zinc EN 14385 mg.m-3 <0.0302 0.00109 N/a N/a N/a N/a 0.0241 14/02/2019 11:17 12:18 No Note 3 No

Mercury EN 13211 mg.m-3 <0.0008 0.00003 N/a N/a N/a N/a 0.0001 14/02/2019 11:17 12:18 Yes Yes

Note 1: All results are normalised to standard temperature and pressure (0OC and 101.3kPa)

Note 2: All results are reported in the format as defined by the EPA in guidance note AG2:2018.

Note 3: EN 14385 only covers As, Cd, Cr, Co, Cu, Mn, Ni, Pb, Sb, Tl and V. There is no standard method for Al & Zn

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1.5 Operating Information

Please reference Process Details as per Appendix III attached.

1.6 Monitoring Deviations

Stack Name:A1

Parameter Deviation

Total Particulate Matter Port position Incorrect – 2 side divisions required for stacks with an area >0.1m2

Mercury and Metals Port position Incorrect – 2 side divisions required for stacks with an area >0.1m2

Volumetric Flow Rate (Ref) Port position not in agreement with EN 15259 EN 16911 - in accordance with MID 16911-1

1.7 Reference Documents

Risk Assessment (RA) SOP 1011

Site Review (SR) SOP 1015

Site Specific Protocol (SSP) SOP 1015

1.8 Revision History

Revision Number Changes to the report

1 Original version of the report

2 Incorrect area used in calculations amended

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Part 2: Supporting Information

Report Title Air Emissions Compliance Monitoring Emissions Report

Company address Air Scientific Ltd., Unit 5, Caherdavin Business Centre, Caherdavin,

Park, Ennis Road, Limerick V94 NT63.

Stack Emissions Testing Report Commissioned by TMS Environment Limited

Facility Name The Recycling Village

Contact Person Graham Adams

EPA Licence Number W0286-01

Licence Holder The Recycling Village

Stack Reference Number A1

Dates of the Monitoring Campaign 14-02-2019

Job Reference Number REVITL814022919B

Report Written By Mr Jer Moore

Report Approved by Mark McGarry

Stack Testing Team Mr Jer Moore & Mr Mike Flood

Report Date 17-04-2019

Report Type Test Report Compliance Monitoring

Version 2

Signature of Approver

Operations Manager

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Appendix I

1.1 Monitoring Personnel

Team Leader Name Jer Moore

System approval ASL Team Leader Approved

Technician Name Mike Flood

System approval ASL Technician Approved

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1.2 Equipment Inventory

ID Item of Equipment Used ID Item of Equipment Used ID Item of Equipment Used

ASLLK12EQ500 Pump ASLLK12EQ525 Horiba (PG-250) X ASLLK13EQ501 Vernier Calipers

ASLLK12EQ531 Pump ASLLK14EQ501 Horiba-PG 350 ASLLK14EQ503 Vernier Calipers

ASLLK12EQ532 Pump ASLLK14EQ512 Horiba PG250Y ASLLK14EQ507 Vernier Calipers

ASLLK12EQ533 Pump ASLLK16EQ508 Horiba- PG250z ASLLK17EQ533 Vernier Calipers

ASLLK12EQ534 Pump ASLLK17EQ515 Horiba 350 ASLLK18EQ506 Vernier Calipers

ASLLK12EQ535 Pump

ASLLK12EQ536 Pump

ASLLK12EQ537 Pump ASLLK12EQ526 Chiller ASLLK13EQ503 1kg weight

ASLLK12EQ538 Pump ASLLK14EQ513 Chiller ASLLK13EQ508 500g Hafner weight

ASLLK12EQ539 Pump ASLLK16EQ509 Chiller ASLLK13EQ509 500g Hafner weight

ASLLK12EQ540 Pump ASLLK18EQ505 Chiller ASLLK15EQ512 1kg weight

ASLLK12EQ541 Pump ASLLK16EQ511 1kg weight

ASLLK12EQ542 Pump ASLLK16EQ512 500g weight

ASLLK12EQ543 Pump ASLLK14EQ518 Velocity Meter ASLLK17EQ529 500g weight

ASLLK13EQ513 Pump ASLLK16EQ501 Velocity Meter ASLLK17EQ530 1kg weight

ASLLK13EQ514 Pump ASLLK17EQ508 Velocity Meter

ASLLK16EQ518 Pump ASLLK17EQ514 Velocity Meter

ASLLK16EQ519 Pump ASLLK18EQ504 Velocity Meter ASLLK13EQ504 G4

ASLLK17EQ509 Pump ASLLK13EQ515 G4

ASLLK17EQ510 Pump ASLLK15EQ501 G4

ASLLK17EQ525 Pump ASLLK14EQ500 FID ASLLK17EQ534 ST5

ASLLK17EQ526 Pump ASLLK16EQ502 FID ASLLK18EQ503 ST5

ASLLK17EQ522 Pump ASLLK17EQ517 FID

ASLLK17EQ523 Pump ASLLK17EQ535 Signal Cutter

ASLLK17EQ524 Pump ASLLK14EQ510 Digital Protractor

ASLLK14EQ511 Digital Protractor

ASLLK13EQ512 PCDD thermometer ASLLK15EQ505 Digital Protractor

ASLLK12EQ529 Calibrator ASLLK16EQ507 Digital Protractor

ASLLK14EQ502 Calibrator ASLLK17EQ528 Digital Protractor

ASLLK17EQ532 MF Meter ASLLK16EQ510 Measuring Tape ASLLK18EQ507 Digital Protractor

ASLLK17EQ540 MF Meter ASLLK16EQ513 Measuring Tape

ASLLK17EQ541 MF Meter ASLLK16EQ514 Measuring Tape

ASLLK17EQ542 MF Meter ASLLK17EQ527 Measuring tape ASLLK12EQ522 Balance

ASLLK18EQ511 MF Meter ASLLK18EQ508 Measuring tape ASLLK12EQ544 Balance

ASLLK15EQ509 Balance

ASLLK12EQ507 Heated Line ASLLK15EQ510 Balance

ASLLK12EQ527 Heated Line ASLLK16EQ515 Thermocouple K type ASLLK17EQ537 Balance

ASLLK14EQ509 Heated Line ASLLK16EQ516 Thermocouple K type ASLLK17EQ538 Balance

ASLLK14EQ514 Heated Line ASLLK17EQ531 K type Thermocouple




ASLLK18EQ510 K type Thermocouple

ASLLK12EQ518 S type Pitot Tube ASLLK17EQ518 Stopwatch

ASLLK12EQ520 L Type Pitot tube ASLLK17EQ519 Stopwatch


ASLLK14EQ506 Pitot + thermocouple ASLLK17EQ521 Stopwatch


ASLLK16EQ517 S type Pitot Tube

ASLLK17EQ536 S type Pitot

ASLLK17EQ507 1 m S type & K type

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Appendix II

2.1 Stack Emission Point Reference: A1

2.1.1 Suitability of Sample Location:

General Information A1

Permanent/Temporary Permanent

Inside/ Outside Inside

Platform Details

Irish EPA Technical Guidance Note AG1 / BS EN 15259 Platform Requirements

Value Comment

Sufficient Working area to manipulate probe and measuring instruments

Yes -

Platform has 2 handrails (approx. 0.5m & 1.0 m high) Yes

-

Platform has vertical base boards (approx. 0.25 m high) Yes

-

Platform has chains / self-closing gates at top of ladders Yes

-

There are no obstructions present which hamper insertion of sampling equipment

Yes -

Safe Access Available Yes

-

Easy Access Available Yes

-

Sampling Location / Platform Improvement Recommendations

None

EN 15259 Homogeneity Test Requirements

1.

Select Option: 1: There is no requirement to perform a BSEN15259 Homogeneity Test on this stack 2: Test results were obtained from previous Homogeneity test carried out by ASL 3: Test results were obtained from previous Homogeneity test carried out by Alternative contractor 4: Homogeneity Test is required on this stack and the client has been informed of this requirement

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2.1.2 Stack Diagram

Figure 1: A1

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2.1.3 Stack Raw Data

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Title: Determination of Total Particulates

Method: EN 13284-1

Client: Recycling Village

Test Date: 14/02/2019 Temperature at Pump 19.17 Deg C

Test Time 12:30 Pressure at Pump 92.94 kPa

Laboratory Used: CLS Air Volume at Pump 0.5141 m3

Stack Name A1 Humidity at Pumps 0 %

Run I.D. 1 Filter Weight 0.61 mg

Filter I.D. T42 Front End Weight 2.6 mg

Moisture Content 0 %

Stack Flow Rate 9587 Nm3/hr Flow Uncertainty 681 m3/hr

Volume of Air Sampled 0.4407 Nm3 Flow Uncertainty 7.1 %

Leak Check Results Result % Leak

Before Sample 1 0.2 l/min 1.4

Average Flow Rate 14.8 l/min 1.4

Standard Maximum 0.296 l/min 2%

Back Pressure 69 kPa

Standard Criteria to be Met Result Std. Requirement

Angle of Flow Pass <15 Degrees Probe material Stainless Steel

Negative Flow in the Stack Pass None Filter housing Stainless Steel

Pitot Pressure Difference Pass >5Pa Positioning of filter In Stack

Ratio of Flow Measurement Pass <3:1 Filter Size & Material 47mm Quartz

Stagnation Test Pass <10Pa

Pitot Tube Leak Check Result

Positive Pressure Pass -

Negative Pressure Pass -

Number of Ports 2 2

Straight length before sample point No > 5 Hydraulic Diameters

Straight length after sample point No > 5 Hydraulic Diameters to Stack Outlet or 2HD to Fan/ Bend

Sample Calculations

Blank (Filter and Front Wash Combined) 0.35 mg

Sample 1 (Filter and Front Combined) 3.21 mg

Volume of Air Sampled 0.4407 Nm3

Blank Result 0.79 mg/Nm3

Sample Result 7.28 mg/Nm3

Uncertainty of Measurement 0.77 mg/Nm3 Requirement <20% ELV

Emission Limit Value 10 mg/Nm3

Blank as Percentage of ELV 7.9 % Requirement <10% ELV or <0.5 mg/m3

Isokinetic Criterion Compliance

Isokinetic Variation 0.2 %

Allowable Isokinetic Range -5 to + 15% %

Isokinetic Acceptable Yes -

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Uncertainty calculation for EN 13284 Determination of low range mass concentration of dust, Manual Gravimetric Method Version 14

Stack Name: A1

Measurement Equation

Limit value (ELV) 10 mg.m -3Reference oxygen % by volume

Measured concentration 7.28 mg.m -3 (at reference conditions)

Measured Quantities Symbol Value Standard uncertainty Units Uncertainty as percentage Uncertainty at lv Requirement of std

Sampled Volume Vm 0.5141 uVm 0.001 m 30.19 <=5%

Sampled gas Temperature T m 292.17 uTm 2 k 0.68 <=2%

Sampled gas Pressure ρm 92.94 uρm 1 kPa 1.08 <=2%

Sampled gas Humidity Hm 0 uHm 1 % by volume 1.00 <=1%

Oxygen content O2,m uO2,m 0.1 % by volume #DIV/0! <=5%

Mass particulate m 3.21 um 0.16 mg 4.94 3.60 <5% of limit value

Note - Sampled gas humidity, temperature and pressure are values at the gas meter

Leak L 1.35 % 1.35 <=2%

Uncollected Mass UCM 0 mg 0 <=10%

(Instack filter - no rinse)

Intermediate calculations

Factor for std conds fs 0.86

uncertainty components symbol sensitivity coeff u (in units of fs)

ρm 0.009 0.009

Hm 0.009 0.009

T m 0.003 0.006

ufs 0.014 1.62

Corrected volume V 0.44 uV 0.007 m 31.64

Factor for O2 correction fc 1.00

uncertainty components symbol sensitivity coeff u

O2,m 0.05 0.005

Factor for O2 Correction ufc 1.00 0.005 0.48

Parameter Value Units Sensitivity coeff Uncertainty contribution Uncertainty as %

Corrected Volume (standard conditions) V 0.44 m3 16.53 0.12 mg.m-3 1.64 %

Mass m 3.21 mg 2.27 0.36 mg.m-3 4.94 %

Factor for O2 Correction fc 1.00 7.28 0.03 mg.m-3 0.48 %

Leak L 0.06 mg.m-3 1.00 0.06 mg.m-3 0.78 %

Uncollected mass UCM 0.00 mg 2.27 0.00 mg.m-30.00 %

Combined measurement uncertainty 0.38 mg.m-3

Expanded uncertainty as percentage of measured value 10.56 % measured of value expressed with a level of confidence of 95%

(Using a coverage factor k=2)

Expanded uncertainty in units of measurement 0.77 mg.m -3

Expanded uncertainty as percentage of limit value 7.69 % ELV

sm fVV

m

ref

cO

Of

,2

,2

21

21

cfV

mc

3.101

273

100

)100( m

m

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sT

Hf

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DUCT AND GAS SPECIFICATION

Name a2-1

Section Rectangular

Size [m]x[m] 0.60 x 0.90

Area [m2] 0.54

Ports B [#] 2

Points P [#] 2

Density ρn [kg/Nm3] 1.286

Carbon Dioxide CO2 [%] 0

Oxygen O2 [%] 21

Water Vapor Ratio rw [0;1] 0

Nozzle nz [mm] 8

Turbolence factor ft [sec] 1

Wall Adjustment Factor waf 1

PITOT DATA SPECIFICATION

Name p0.830

Velocity [m/sec] 5 0.83





NORMALIZATION FACTOR

Tnorm [K] 273

Pnorm [kPa] 101.3

DUCT FLOW RATE

Dry actual QVa [m3/h] 10109

Moist actual Q'Va [m3/h] 10109

Moist standard [Tnorm Pnorm] Q'Vn [Nm3/h] 9587

Dry standard [Tnorm Pnorm] QVn [Nm3/h] 9587

AVERAGE VALUES

Total Points [#] 2

Velocity v'a [m/sec] 5.2

Stack temperature tstack [°C] 17.49

Stack Pressure Pa [kPa] 102.23

Isokinetic Rate DI [%] 0.2

Velocity at nozzle v'N [m/sec] 5.211

Probe temperature tprobe [°C] 26.2

Filter temperature tfilter [°C] 28.3

Outlet temperature toutlet [°C] 25.4

Aux temperature taux [°C] 26.7

Ambient Pressure Pamb [kPa] 102.15

GAS METER SAMPLED VOLUMES

Elapsed time et [hh:mm:ss] 00:30:00

Standard Volume [Tnorm Pnorm] Vgn [Nm3] 0.4407

Moist Volume at stack conditions V'ga [m3] 0.4647

Volume at dgm conditions Vdgm [m3] 0.5141

Gas meter temperature tdgm [°C] 19.17

Gas Meter Pressure Pdgm [kPa] 92.94

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Velocity Profile 14/02/2019 09:31:47

POINT LIST

start ts port point Probe pos

Swirl angle

Swirl axis avg Elapsed

Time tstack avg Pa avg

dP pitot avg

velocity avg

[timestamp] [###] [###] [cm] [°] [°] [hh:mm:ss] [°C] [kPa] [Pa] [m/sec] 14/02/2019

1 1 15.3 0 0 00:01:00 12.55 102.16 25.4 5.31 09:32:33

00:01:00 12.54 102.16 25.47 5.32 14/02/2019

1 2 45.8 0 0 00:01:00 12.85 102.17 25.6 5.34 09:33:35

00:01:00 12.84 102.17 25.6 5.34 14/02/2019

2 1 15.3 0 0 00:01:00 13.18 102.17 25.98 5.38 09:34:38

00:01:00 13.17 102.17 25.94 5.37 14/02/2019

2 2 45.8 0 0 00:01:00 13.51 102.17 26 5.38 09:35:45

00:01:00 13.5 102.17 26.02 5.39

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Title: Determination of Total Metals and Mercury

Method: EN 14385 & EN 13211

Client: Recycling Village

Test Date: 14/02/2019 Temperature at Pump 18.62 Deg C

Test Time On: 11:17:52 Pressure at Pump 88.02 kPa

Test Time Off: 12:18 Air Volume at Pump 1.071 m3

Laboratory Used: CLS Humidity at Pumps 0 %

Stack Name a2-1

Filter I.D. T89 Flow Uncertainty 589 m3/hr

Stack Flow Rate 9506 m3.hr-1 Flow Uncertainty 6.2 %

Dry Volume of Air Sampled Metals 0.8711 Nm3

Dry Volume of Air Sampled Mercury 0.8711

Moisture Content 0 %

Wet Volume of Air Sampled Metals 0.8711 m3

Wet Volume of Air Sampled Mercury 0.8711 m3

Emission Limit Value N/a mg.m-3

Leak Check Results Result % Leak

Before Blank 0.132 cc/min 0.9

After Blank 0.132 cc/min 0.9

Before Sample 1 0.132 cc/min 0.9

After Sample 1 0.132 cc/min 0.9

Average Flow Rate 14.709 cc/min 0.9

Standard Maximum 0.29418 cc/min 2%

Back Pressure 69 bar or kPa

Standard Criteria to be Met Result Standard Requirement

Angle of Flow Pass <15 Degrees Probe material Titanium

Negative Flow in the Stack Pass None Filter housing Titanium

Pitot Pressure Difference Pass >5Pa Positioning of filter Out Stack

Ratio of Flow Measurement Pass <3:1 Filter Size & Material 47mm Quartz

Stagnation Check Pass <10 Pa

Pitot Tube Leak Check Result

Positive Pressure Pass -

Negative Pressure Pass -

Number of Ports 2 2

Straight length before sample point No > 5 Hydraulic Diameters

Straight length after sample point No > 5 HD from fan or bend / >2 from stack exit

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Sample Calculations

Filter Imp 1 & 2 Imp 3 Total Metal

ug / filter ug/L ug/L ug

Aluminium 140 100 100 177.7

Arsenic 0.5 0.2 0.2 0.6

Cadmium 0.5 3.2 0.5 1.3

Chromium 2 55 0.5 15.2

Copper 0.6 2 1 1.2

Lead 14 120 0.5 42.7

Nickel 2 2 2 2.8

Zinc 15 33 25 26.3

Mercury 0.01 2.7 0.5 0.7

Run 1 Run 2

Impinger 1 & 2 Total Volume (Incl Rinse) 239 220 mls

Impinger 3 Total Volume (Incl Rinse) 138 148 mls

Concentration Calculation

mg.m-3 Uncertainty

Aluminium 0.20399 0.007377

Arsenic 0.00066 0.000024

Cadmium 0.00153 0.000055

Chromium 0.01747 0.000632

Copper 0.00140 0.000050

Lead 0.04907 0.001775

Nickel 0.00316 0.000114

Zinc 0.03023 0.001093

Mercury 0.00078 0.000028

Blank Calculations

Filter Impingers Total Metals Concentration

ug / filter ug/L ug mg.m-3

Aluminium 140 100 163.900 0.18815

Arsenic 0.5 0.2 0.548 0.00063

Cadmium 0.5 0.5 0.620 0.00071

Chromium 2 0.5 2.120 0.00243

Copper 0.5 1 0.739 0.00085

Lead 1.8 0.3 1.872 0.00215

Nickel 2 2 2.478 0.00284

Zinc 15 25 20.975 0.02408

Mercury 0.01 0.5 0.120 0.00014

% of ELV

Total Metals 0.2220

Blank < 10% of the Emission Limit Values N/a Yes / No

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DUCT AND GAS SPECIFICATION Name a2-1

Section Rectangular

Size [m]x[m] 0.60 x 0.90

Area [m2] 0.54

Ports B [#] 2

Points P [#] 2

Density ρn [kg/Nm3] 1.286

Carbon Dioxide CO2 [%] 0

Oxygen O2 [%] 21

Water Vapor Ratio rw [0;1] 0

Nozzle nz [mm] 8

Turbolence factor ft [sec] 1

Wall Adjustment Factor waf 1

PITOT DATA SPECIFICATION Name p0.830






NORMALIZATION FACTOR Tnorm [K] 273

Pnorm [kPa] 101.3

DUCT FLOW RATE Dry actual QVa [m3/h] 10264

Moist actual Q'Va [m3/h] 10264

Moist standard [Tnorm Pnorm] Q'Vn [Nm3/h] 9506

Dry standard [Tnorm Pnorm] QVn [Nm3/h] 9506

AVERAGE VALUES Total Points [#] 2

Velocity v'a [m/sec] 5.28

Stack temperature tstack [°C] 24.55

Stack Pressure Pa [kPa] 102.25

Isokinetic Rate DI [%] -0.3

Velocity at nozzle v'N [m/sec] 5.265

Probe temperature tprobe [°C] 181.8

Filter temperature tfilter [°C] 181.3

Outlet temperature toutlet [°C] 25.6

Aux temperature taux [°C] 26

Ambient Pressure Pamb [kPa] 102.15

GAS METER SAMPLED VOLUMES Elapsed time et [hh:mm:ss] 01:00:00

Standard Volume [Tnorm Pnorm] Vgn [Nm3] 0.8711

Moist Volume at stack conditions V'ga [m3] 0.9406

Volume at dgm conditions Vdgm [m3] 1.071

Gas meter temperature tdgm [°C] 18.62

Gas Meter Pressure Pdgm [kPa] 88.02

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Uncertainty calculation

Stack Name: A1

Measurement Equation

Limit value (ELV) N/a mg.m -3Reference oxygen % by volume

Measured concentration 0.31 mg.m -3 (at reference conditions)

Measured Quantities Symbol Value Standard uncertainty Units Uncertainty as percentage Uncertainty at lv Requirement of std

Sampled Volume Vm 1.0710 uVm 0.001 m 30.09 <=2%

Sampled gas Temperature T m 291.62 uTm 2 k 0.69 <=1%

Sampled gas Pressure ρm 88.02 uρm 1 kPa 1.14 <=1%

Sampled gas Humidity Hm 0 uHm 1 % by volume 1.00 <=1%

Oxygen content O2,m uO2,m 0.1 % by volume <=5%

Note - Sampled gas humidity, temperature and pressure are values at the gas meter

Leak L 0.90 % 0.90 <=2%

Intermediate calculations

Factor for std conds fs 0.81

uncertainty components symbol sensitivity coeff u (in units of fs)

ρm 0.009 0.009

Hm 0.008 0.008

T m 0.003 0.006

ufs 0.01352 1.66

Corrected volume V 0.87 uV 0.015 m 31.67

Factor for O2 correction fc 1.00

uncertainty components symbol sensitivity coeff u

O2,m 0.05 0.005

Factor for O2 Correction ufc 1.00 0.005 0.48

Parameter Value Units Sensitivity coeff Uncertainty contribution Uncertainty as %

Corrected Volume (standard conditions) V 0.87 m3 0.35 0.01 mg.m-3 1.67 %

Factor for O2 Correction fc 1.00 0.31 0.00 mg.m-3 0.48 %

Leak L 0.00 mg.m-31.00 0.00 mg.m-3

0.52 %

Combined measurement uncertainty 0.01 mg.m-3

Expanded uncertainty as percentage of measured value 3.62 % measured of value expressed with a level of confidence of 95%

(Using a coverage factor k=2)

Expanded uncertainty in units of measurement 0.01115 mg.m -3

sm fVV

m

ref

cO

Of

,2

,2

21

21

cfV

mc

3.101

273

100

)100( m

m

m

sT

Hf

V1.4 Oct-16Enter data in orange cells only <---- Complete (Don’t Touch)

ConstantsGas constant 8.314 J/(K.mol)

2500 Pa

10 Pa

Enter Data in yellow cells only (They should pull correctly) 0.01 % of value0.32 % of range between calibrations

0.25 % of range2.5 Pa

Water vapour measurement 2 % relative

Pitot coefficient, K 0.83 1 °C CO content measurement 2 % relativeExpanded uncertainty (95%, k=2) 0.03 160.5 Pa CO2 content measurement 2 % relative

1.0 % O2 content measurement 2 % relative

Duct dimensions Circular Rectangular

Diameter 0.90 m a 0.6 m

Area 0.6 m2 b 0.6 mArea 0.4 m2

All Pressures should be entered in Pascals, PaMeasurement Point Atmospheric Pressure, Pa Stack Pressure, Pa Static Pressure, Pa meas1, Pa meas2, Pa meas3, Pa meas4, Pa meas5, Pa Delta P, Pa Stack Temperature, C Water Vapour Content, % CO, ppm CO2, % N2, % O2, % dry molecular wt, g/mol stack molecular wt, g/mol

1 102150 204400 102250 29.47 29.47 24.55 0 0 0.1 79.0 20.9 28.85 28.85

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

Mean 102150 204400 102250.0 29.5 #DIV/0! #DIV/0! #DIV/0! #DIV/0! 29.5 24.6 0.0 0.0 0.1 79.0 20.9 28.85 28.85

Mean density 2.384 kg/m3

Mean velocity 4.13 m/sec

Standard uncertainty of velocity 0.11 m/sec 2.8 % of value

Expanded uncertainty in velocity 0.23 m/sec 5.5 % of value

Circular duct Rectangular ductFlow rate 9506 m3/hour 9506 m3/hour

Volume flow rate expanded uncertainty 568 m3/hour 589 m3/hour

Volume flow rate expanded uncertainty 6.0 % of value 6.2 % of value

Repeatability of Delta P transducerDrift of Delta P transducer

Lack of fit of measurement system

Uncertainty calculation for Velocity and Volume Flow Rate Measurement by Pitot tube EN ISO 16911-1

Characteristics of pressure sensor used for Delta PEnter uncertainties as (95%,k=2) where relevant

Range of Delta P transducer

Resolution of Delta P transducer

Uncertainty in duct area measurement

Dry gas basis

Uncertainty in stack gas compositionUncertainty in Delta P transducer Enter uncertainties as (95%,k=2) where relevant

Uncertainty in temperature readout system

Uncertainty in atmospheric pressure transducer

Enter uncertainties as (95%,k=2) where relevant

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Appendix III: Certificates and Process Detail Form

Attach Process Details.

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Concept Life Sciences

Certificate of Analysis

Hadfield HouseHadfield Street

CornbrookManchester

M16 9FETel : 0161 874 2400Fax : 0161 874 2404

Report Number: Supplement to 804180-1

Date of Report: 01-Apr-2019

Customer: Air ScientificUnit 5Cahirdavin Shopping CentreEnnis RoadLimerick

Customer Contact: Project Management

Customer Job Reference: REVITL8140219BDate Job Received at Concept: 20-Feb-2019

Date Analysis Started: 22-Feb-2019Date Analysis Completed: 07-Mar-2019

The results reported relate to samples received in the laboratory and may not be representative of a wholebatch.Opinions and interpretations expressed herein are outside the scope of UKAS accreditationThis report should not be reproduced except in full without the written approval of the laboratoryTests covered by this certificate were conducted in accordance with Concept Life Sciences SOPsAll results have been reviewed in accordance with Section 25 of the Concept Life Sciences, AnalyticalServices Quality Manual

This document has been printed from a digitally signed master copy

Concept Life Sciences is a trading name of

Concept Life Sciences Analytical & Development

Services Limited registered in England and

Wales (No 2514788)

1549

Report checkedand authorised by :Howard HandleySite Director

Issued by :Kathryn GleavesCustomer Service Advisor

Page 1 of 3

Supplement to804180-1

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Concept Reference: 804180

Customer Reference: REVITL8140219B

Combined (filter/rinse) Analysed as Combined (filter/rinse)

(Al, As, Cd, Cr, Cu, Hg, Ni, Pb, Zn)

Concept Reference 804180 001 804180 006

Customer Sample Reference 1. A1 Metals &Mercury

Filter+Rinse

6. Blank Metals &Mercury

Filter+Rinse

Test Sample AR AR

Date Sampled 14-FEB-2019 14-FEB-2019

Determinand Method LOD Units Symbol

Aluminium ICPMS (HF BS EN 14385) 5 µg N 140 140

Arsenic ICPMS (HF BS EN 14385) 0.5 µg U <0.5 <0.5

Cadmium ICPMS (HF BS EN 14385) 0.5 µg U <0.5 <0.5

Chromium ICPMS (HF BS EN 14385) 2 µg U <2 <2

Copper ICPMS (HF BS EN 14385) 0.5 µg U 0.6 <0.5

Lead ICPMS (HF BS EN 14385) 0.5 µg U 14 1.8

Mercury CVAFS (BS EN 13211) 0.01 µg U <0.01 <0.01

Nickel ICPMS (HF BS EN 14385) 2 µg U <2 <2

Zinc ICPMS (HF BS EN 14385) 15 µg N <15 <15



Impinger(5%HNO3/5%H2O2)

Analysed as Impinger (3.3%HNO3/1.5%H2O2)

(Al, As, Cd, Cr, Cu, Ni, Pb, Zn)

Concept Reference 804180 002 804180 003 804180 007

Customer Sample Reference 2. A1 Metals Imp1+2

3. A1 Metals Imp 3 7. Blank Metals

Test Sample AR AR AR

Date Sampled 14-FEB-2019 14-FEB-2019 14-FEB-2019


Aluminium ICPMS (BS EN 14385) 100 µg/l N <100 <100 <100

Arsenic ICPMS (BS EN 14385) 0.2 µg/l U <0.2 <0.2 <0.2

Cadmium ICPMS (BS EN 14385) 0.5 µg/l U 3.2 <0.5 <0.5

Chromium ICPMS (BS EN 14385) 0.5 µg/l U 55 <0.5 <0.5

Copper ICPMS (BS EN 14385) 1 µg/l U 2 <1 <1

Lead ICPMS (BS EN 14385) 0.3 µg/l U 120 0.5 0.3

Nickel ICPMS (BS EN 14385) 2 µg/l U <2 <2 <2

Zinc ICPMS (BS EN 14385) 25 µg/l N 33 <25 <25



Impinger(4%K2Cr2O7/20%HNO3)

Analysed as Impinger (4%K2Cr2O7/20%HNO3)

Mercury

Concept Reference 804180 004 804180 005 804180 008

Customer Sample Reference 4. A1 Mercury Imp1+2

5. A1 Mercury Imp3

8. Blank Mercury

Test Sample AR AR AR

Date Sampled 14-FEB-2019 14-FEB-2019 14-FEB-2019


Mercury CVAFS (BS EN 13211) 0.5 µg/l U 2.7 <0.5 <0.5



Filter Quartz 47mm Analysed as Filter Quartz 47mm

Particulates (Total)


Customer Sample Reference 9. A1 Dust Filter T-42

11. Blank Dust FilterT-82

Test Sample AR AR



Particulates (Total) Grav (5 Dec) 0.05 mg U 0.61 <0.05


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s only

.

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r req

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EPA Export 25-06-2019:04:12:42

Index to symbols used in Supplement to 804180-1

Notes



Wash(Acetone) Analysed as Wash(Acetone)

Particulates (Total)


Customer Sample Reference 10. A1 Dust Rinse 12. Blank DustRinse

Test Sample AR AR



Particulates (Total) Grav 0.3 mg U 2.6 <0.3

Value Description

AR As Received

U Analysis is UKAS accredited

N Analysis is not UKAS accredited

Supplement to 804180: report issued to amend the Copper results for samples 001 & 006, as they were incorrectly reported on the final report without blank correction.


Produced by Concept Life Sciences, Hadfield House, Hadfield Street, Cornbrook, Manchester, M16 9FE Page 3 of 3


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ectio

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pose

s only

.

Conse

nt of

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right

owne

r req

uired

for a

ny ot

her u

se.

EPA Export 25-06-2019:04:12:42

For

insp

ectio

n pur

pose

s only

.

Conse

nt of

copy

right

owne

r req

uired

for a

ny ot

her u

se.

EPA Export 25-06-2019:04:12:42