conductivity conductivity superconductivity electronic properties robert m rose, lawrence a...
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CONDUCTIVITY
Conductivity
Superconductivity
Electronic PropertiesRobert M Rose, Lawrence A Shepart, John Wulff
Wiley Eastern Limited, New Delhi (1987)
Resistivity range in Ohm m 25 orders of magnitude
10-9 10-7 10-5 10-3 10-1 10-1 103
Ag
Cu Al
Au
Ni
Pb
Sb Bi Graphite
Ge(doped)
Ge Si
105 107 109 1011 1013 1015 1017
WindowglassIonicconductivity
Bakelite
Porcelain
Diamond
Rubber
Polyethylene
Lucite
MicaPVC
SiO2
(pure)
Metallic materials
Insulators
Semi-conductors
A
LR
Classificationbased on
Conductivity
Semi-metals
Semi-conductors
Metals
Insulators
Free Electron Theory
Outermost electrons of the atoms take part in conduction
These electrons are assumed to be free to move through the whole solid Free electron cloud / gas, Fermi gas
Potential field due to ion-cores is assumed constant potential energy of electrons is not a function of the position(constant negative potential)
The kinetic energy of the electron is much lower than that of bound electrons in an isolated atom
Wave particle duality of electrons
mv
h
→ de Broglie wavelength v → velocity of the electrons h → Planck’s constant
mv
x
v kg x
s J x 4
31
34 1027.7
10109.9
1062.6
Wave number vector (k)
2
k
2
2
1mvE Non relativistic
m
khE
2
22
8
m
khE
2
22
8
↑ → k ↓ → E ↓
E →k →
Discrete energy levels(Pauli’s exclusion principle)
If the length of the box is L
Ln 2
n → integer (quantum number)
2
22
8mL
hnE
L
nk
Number of electrons moving from left to right equals the number in the opposite direction
Electron in an 1D boxL
Quantization of Energylevels
2222
2
8 zyx nnnmL
hE
In 3D
Each combination of the quantum numbers nx , ny , nz corresponds toto a distinct quantum state
Many such quantum states have the same energy and said to be degenerate The probability of finding an electron at any point in box is proportional
to the square of the amplitude there are peaks and valleys within L If the electron wave is considered as a travelling wave the amplitude will be
constant
Fermi level
At zero K the highest filled energy level (EF) is called the Fermi level
If EF is independent of temperature (valid for usual temperatures) ► Fermi level is that level which has 50% probability of occupation
by an electron
T > 0 K
kT
EEEP
Fexp1
1)(
P(E
) →
E →
1
FE
Incr
easin
g T
0K
0
Conduction by free electrons
If there are empty energy states above the Fermi level then in the presence of an electric field there is a redistribution of the electron occupationof the energy levels
E →
k → k →
Field
EF EFElectric
Field
eEmaF
Force experienced by an electron
m → mass of an electron E → applied electric field
Vel
ocit
y →
time →
vd
Collisions
In the presence of the field the electron velocity increases by an amount (above its usual velocity) by an amount called the drift velocity
The velocity is lost on collision with obstacles
eEv
mF d
vd → Drift velocity → Average collision time
m
eEvd
The flux due to flow of electrons → Current density (Je)
m
E e nv e nJ de
2
n → number of free electrons
(E) gradient potential unit
(J Flux)(ty Conductivi e ) E J e
m
e n 2
m
V
m Ohm
1
m
Amp2
IRV AmpOhm
V
2
1
mOhm
V
m
Amp2
~ Ohm’s law
Mean free path (MFP) (l) of an electron
l = vd The mean distance travelled by an electron between successive collisions For an ideal crystal with no imperfections (or impurities) the MFP
at 0 K is Ideal crystal there are no collisions and the conductivity is Scattering centres → MFP↓ , ↓ ↓ , ↑
Scattering centres
Sources ofElectron Scattering
Solute / impurity atoms
Defects
Thermal vibration → Phonons
Grain boundaries
Dislocations
Etc.
Thermal scattering
At T > 0K → atomic vibration scatters electrons → Phonon scattering T ↑ → ↓ → ↑ Low T
MFP 1 / T3
1 / T3
High T MFP 1 / T 1 / T
Impurity scattering
Resistivity of the alloy is higher than that of the pure metal at all T The increase in resistivity is the amount of alloying element added !
Res
isti
vity
()
[x
10-8 O
hm m
] →
T (K) →
Cu-Ni alloy
100 200 300
1
2
3
4
5
Cu-2%Ni
Cu-3%Ni
→ 0 as T→ 0K
With low density ofimperfections
Pure Cu
Increased phonon scattering
Impurity scattering (r)
Mattheissen rule
= T + r
Net resistivity = Thermal resistivity + Resistivity due to impurity scattering
Conductors
Power transmission lines → low I2R loss → large cross sectional area
Al used for long distance distribution lines(Elastic ModulusAl increased by steel reinforcement)
OFHC (Oxygen Free High Conductivity) Cu (more expensive) is used fordistribution lines and busbars. ► Fe, P, As in Cu degrade conductivity drastically
Electrical contacts
Electrical contacts in switches, brushes and relays
Properties:► High electrical conductivity ► High thermal conductivity → heat dissipation ►High melting point → accidental overheating ► Good oxidation resistance
Cu and Ag used
Ag strengthened by dispersion strengthening by CdO■ CdO
► Strengthens Ag► Improves wear resistance► If arcing occurs → decomposes (At MP of Ag) to
absorb the heat
Resistor
Properties: ► Uniform resistivity → homogenous alloy ► Stable resistance → Avoid aging / stress relaxation / phase change ► Small T coefficient of resistance (R) → minimizes error in
measurement ► Low thermoelectric potential wrt Cu ► Good corrosion resistance
Manganin (87% Cu, 13% Mn, R = 20 x 106 / K) and Constantan (60% Cu, 40% Ni) are good as resistor materials [R (Cu) = 4000 x 106 / K]
Low thermoelectric potential wrt to contact material (usually Cu) reduceserror due to temperature difference between junctions. For highprecision dissimilar junctions should be maintained at same temperature
Ballast resistors are used in maintaining constant current →I ↑ → T ↑ → R ↑ I ↓
Requriement: high R (71% Fe, 29% Ni → R = 4500 x 106 / K)
dT
dR
RR
1
Heating elements
Properties: ► High melting point ► High resistivity ► Good oxidation resistance ► Good creep strength ► Resistance to thermal fatigue
low elastic modulus low coefficient of thermal expansion
■ Upto 1300oC Nichrome (80% Ni, 20% Cr), Kanthal (69% Fe, 23% Cr, 6% Al, 2% Co) ■ Upto 1700oC: SiC & MoSi2 ■ Upto 1800oC: Graphite Mo and Ta need protective atmosphere at high T W (MP = 3410oC) is used is used as filament in light bulbs → creep resistance above 1500oC improved by dispersion hardening with ThO2
Resistance thermometers: ► High temperature coefficient of resistivity► Pure Pt
SUPERCONDUCTIVITY
Res
isti
vity
()
[x
10-1
1 Ohm
m]
→
T (K) →10 20
5
10 Ag Sn
Res
isti
vity
()
[x
10-1
1 Ohm
m]
→
T (K) →5 10
10
20
00 Tc
Superconducting transition temperature
Superconducting transition
?
Current carrying capacity
The maximum current a superconductor can carry is limited by the magnetic field that it produces at the surface of the superconductor
0 H
c [W
b / m
2 ] →
T (K) → Tc
Hc / Jc
Normal
Superconducting
J c [A
mp
/ m2 ]
→
Meissner effect
A superconductor is a perfect diamagnet (magnetic suceptibility = 1)
Flux lines of the magnetic field are excluded out of the superconductor Meissner effect
Normal Superconducting
Theory of low temperature superconductivity- Bardeen-Cooper-Schreiffer (BCS) theory
Three way interaction between an two electron and a phonon
Phonon scattering due to lattice vibrations felt by one electron in the Cooper pair is nullified by the other electron in the pair the electron pair moves through the lattice without
getting scattered by the lattice vibrations
The force of attraction between the electrons in the Cooper pair is stronger than the repulsive force between the electrons when T < Tc
Type I and Type II superconductors
M →
H → Hc
NormalSuperconducting
Type I
Type I (Ideal) superconductors
Type I SC placed in a magnetic field totally repels the flux lines till themagnetic field attains the critical value Hc
c
c
HH
HH HM
0
M →
H → Hc
Normal
Type I
Type II (Hard) superconductors
Type II SC has three regions
c2
c2c1
c1
HH 0
)H,(HHH
HHH
M
Vortex
VortexRegion
Gradual penetration of the magnetic flux lines
Superconducting
Hc1 Hc2
As type II SC can carry high current densities (Jc) they are of great practicalimportance
The penetration characteristics of the magnetic flux lines (between Hc1 and Hc2) is a function of the microstructure of the material presence of pinning centres in the material
Pinning centres: Cell walls of high dislocation density
(cold worked/recovery annealed) Grain boundaries
(Fine grained material) Precipitates
(Dispersion of very fine precipitates with interparticle spacing ~ 300 Å) Jc ↑ as Hc2 ↑
Nb – 40%Ti alloy, T = 4.2 K, Magnetic field strength = 0.9 Hc2
Microsctructure Jc (A / m2)
Recrystallized 105
Cold worked and recovery annealed 107
Cold worked and precipitation hardened 108
Potential Applications
Strong magnetic fields → 50 Tesla (without heating, without large power input)
Logic and storage functions in computersJosephson junction → fast switching times (~ 10 ps)
Magnetic levitation (arising from Meissner effect)
Power transmission
High Tc superconductivity
Compound Tc Comments
Nb3Ge 23 K Till 1986
La-Ba-Cu-O 34 K Bednorz and Mueller (1986)
YBa2Cu3O7-x 90 K > Boiling point of Liquid N2
Tl (Bi)-Ba(Sr)-Ca-Cu-O 125 K
Manufacture of YBa2Cu3O7-x
Please read from text book
Crystal structure of YBa2Cu3O7x
Y
Ba
Cu
O