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Composition and structure of Earth’s Atmosphere
the atmosphere
composition of the atmosphere
400.0 0.040
0.00018 1.8
atmospheric CO2 concentrations at
Mauna Loa, Hawaii
Earth-Sun Relationships
• Energy received from the Sun drives weather and climate, so it is obvious to start with changes associated with the Sun and our orbit around the Sun
• The regular changes of Earth’s orbit around the Sun, and Earth’s rotation about its tilted axis, control seasonal and diurnal cycles and dominate the climatology of Earth
indirect rays
Earth’s surface, and lower atmosphere,
are unevenly heated
low latitudes receive more energy per unit
area than higher latitudes
distribution of incoming solar radiation
heat budget
caused by Earth’s orientation-inclination of the axis seasons
Length of day
length of day
daily variations in air temperature
heat (energy, W/m2) temperature (average energy, oC)
humidity (water vapor, g/kg) pressure (force/area, mb = 100 N/m2)
winds (circulation, m/s) cloud cover (liquid/solid water)
precipitation rate (mm/day)
Environmental Variables
Figure 1.1
temperature
Figure 1.2
seasonal temperature differences
Figure 1.3
structure of the atmosphere
temperature vs. height
in the troposphere temperature decreases with height
the average lapse rate is about 5-9 degrees C per kilometer depending on the humidity
in the stratosphere temperature increases with height
in the stratosphere ozone absorbs incoming ultraviolet radiation
80% of the mass of Earth’s atmosphere is in the troposphere,
we all live in the troposphere
ozone
ozone layer maximum at 20-25 km
tropopause height varies with latitude
Figure 1.6
atmospheric pressure pressure is a force per unit area exerted by the weight of air above
-- about 1 kg/cm2 or 14.7 lb/in2 at the surface of Earth (equivalent to a 10 meter column of water)
units of pressure are N/m2 where N = Newton = force required to accelerate a 1 kg mass 1 m/s2
The SI unit for pressure is the Pascal (Pa) 1 Pa = 1 N/m2
a standard atmosphere (and average typical of a mid latitude location) exerts a pressure of 101,325 Pa at sea level
the unit adopted by the National Weather Service is the millibar (mb) 1 mb = 100 Pa
--> standard sea level pressure = 1013.25 mb
factors affecting atmospheric pressure
1. gas molecules are able to fill space available
2. gas molecules bounce off one another when they collide (and off the wall if in a container)
3. the atmosphere is bounded above (gravity) and below (ground)
Air pressure is the force per unit area exerted against a surface by continuous collision of gas molecules
pressure is partly determined by temperature consider a change in temperature while holding density (volume) constant
temperature increase --> speed of molecules increases (force increases, higher pressure)
pressure is partly determined by density
Density (# molecules/volume) increase --> increase in # of collisions (higher pressure)
consider a change in density (volume) while holding temperature constant
ideal gas law Boyle's Law - at constant temperature, the volume of gas varies inversely with pressure
p1V1 = p2V2
Charles' Law - at constant pressure, the volume of a given mass is directly proportional to absolute temperature--> increase in temperature results in increase in volume
V1 / V2 = T1 / T2
Combine these two laws to obtain ideal gas law, or equation of state
p = ρ R T
where p = pressure, ρ = density, R = gas constant, and T = temperature
pressure changes with altitude
Figure 1.9
pressure and density vs. height
pressure at sea level is around 1000 millibars
pressure decreases with height exponentially
50% of the mass of Earth’s atmosphere is below an
altitude of 5-6 km (the 500 millibar height)
pressure is a force per unit area
Figure 1.7
reducing pressure to sea level
sea level pressure on Earth
seasonal pressure and wind patterns
Figure 1.15
pressure changes with temperature
pressure changes with temperature
hydrostatic equilibrium
concept: – the vertical pressure gradient force is equal and opposite to the gravitational force
hydrostatic equation
Where: Δp represents change in pressure, Δz, change in altitude, ρ, air density, and g, acceleration of gravity
(Δp / Δz) = - ρg
the rate at which pressure decreases with height equals the product of air density times the acceleration of gravity
hydrostatic equation examples
cold column: ρ = 1.3 kg/m3
(Δp / Δz) = - 1.3 (9.8) = -12.8 Pa/m
thus:
pressure declines more rapidly in a cold, dense air column than in a warm air column
water’s changes of state
Water’s Changes of State
amount of water vapor in air
1. absolute humidity = mass of water vapor per volume of air (g/m3)
2. mixing ratio = mass of water vapor in a unit mass of dry air (g/kg)
3. relative humidity = ratio of air's water vapor content to its capacity
4. dewpoint temperature is the temperature at which air is saturated
(100% relative humidity)
humidity
relative humidity
changes with added moisture
changes with temperature
relative humidity
saturation mixing-ratio
Figure 1.11
Which has more Moisture?
Which has higher Relative Humidity?
Higher Temperature Lower Relative Humidity with MORE Moisture!
Lower Temperature Higher Relative Humidity
with LESS moisture!
diurnal changes in relative humidity
cloud cover