clean coal technologies for sustainability

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    Dr. V. K. SETHI

    Prof. & Head

    RGPV

    Bhopal

    CLEAN COAL TECHNOLOGIES FOR

    SUSTAINABLE POWER DEVELOPMENT

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    PRIORITIES ON ENERGY GENERATION SECTOR:

    Increased use of Advanced Fossil Fuel Technology.

    Promote CCT in countries where coal is main stayfuel for Power Generation.

    Reduce Atmospheric Pollution from EnergyGenerating Systems.

    Enhance productivity through Advanced Fossil FuelTechnology.

    WORLD SUMMIT ON SUSTAINABLE DEVELOPMENT

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    POWER SCENARIO IN INDIA

    Installed capacity in utilities (March 31, 2002)

    Thermal 73,274 mw

    Hydro 25,574 mw

    Nuclear 2,860 mw

    Wind 1,427 mw

    Total 1,03,135 mw

    Total energy generation - 383 billion kwh Per Capita Energy Consumption -400 kwh

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    DEMAND PROJECTION

    YEAR 2012 CAPACITY ADDITION BY SECTORS

    Central 46,500 MW

    State & IPP 41,800 MW

    NCES 10,700 MW

    Nuclear 6,400 MW

    Total 105,400 MW

    YEAR 2020 MIX OF GENERATION

    Thermal 326,000MW Renewable & Hydro 104,000 MW

    Nuclear 20,000 MW

    Total 450,000 MW

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    CLEAN COAL TECHNOLOGIES

    Mining Management & Practices(Reduction of Extraneousmaterial)

    Coal Preparation Process after mining to improve

    inherent & Extraneous material(washing & beneficiation)

    Conversion Technologies Supercritical, PFBC and IGCC

    Post combustion cleaning Particulate and gaseouspollutants removal(Environmental requirement)

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    VISION 2020

    PROGRAM

    Post combustion Clean-up-Desulfurization

    (FGC systems) Supercritical

    In-combustion Clean-upFluidized bed

    combustion (CFBC,PFBC, AFBC)

    Gasification using +fluidized bed, moving bedor Entrained bed Gasifiers

    Pre combustion Clean-up beneficiation/washing

    Technologies for utilization of Coal for Power Generation with minimalpollutants discharged to the atmosphere (Reduced CO2, Sox, Nox,

    SPM) at high conversion efficiency

    .World Coal Institute.

    CLEAN COALTECHNOLOGIES

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    TECHNOLOGIES

    Clean Coal Technologies (CCTs)are defined as technologies designed

    to enhance:

    Efficiency of conversion

    Environmental acceptability of coal

    extraction, preparation and use.

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    COAL FOR POWER

    GENERATIONChina and India are projected to account for30%

    of the worlds increase in energy consumption

    between 2000-2020 and 92% of increase in coal use.

    The key environmental challenges facing the coalindustry are related to :

    Coal Mining

    Particulate emission

    Disturbance land me

    Acid rain

    Ozone and Waste disposal

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    INDIA AMONGST TOP SIX

    EMITTERS OF CO2Country Total emission Percentage

    of

    (Million Tonnes of CO2) world emission

    USA 5470 24%

    China 3121 14%

    Russian Federation 1456 6% Japan 1173

    Germany 884 4%

    India 881 4%

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    Note : Green House inventory

    for India for Energy Sector(Million Tonnes of CO2)Energy Sector CO2 CO2 equivalent

    (CO2+CH4+NOx)

    Total Emission 508 565

    (58% of total) (64% of total)

    Source : IAE : 1999

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    PER CAPITA EMISSIONS OF CO2

    Top 6 Polluters

    World Developed countries

    Parties

    (Tonnes of CO2 per

    capita)

    Developing Countries

    (Tonnes of CO2 per

    capita)

    Qatar 44.08

    Bahrain 35.23

    UAE 30.11

    Kuwait 25.01

    Singapore 23.47U.S.A 20.50

    USA 20.50

    Luxemboury 20.42

    Australia 16.52

    Canada 15.76

    Finland 12.47Estonia 12.47

    Qatar 44.08

    Bahrain 35.23

    U.A.E. 30.11

    Kuwait 25.01

    Singapore 23.47Saudi Arabia 13.27

    Note : Per capita CO2 equivalent emissions for India in 1990 are estimated to be

    1.194 tonnes or 325 kg of Carbon per capita. This contribution 58% of National

    Emissions and 4% of global emission.

    Source : IEA 1999 & UNDP 1998.

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    COSTOF VARIOUSCO2 MITIGATIONOPTIONS FOR INDIAN POWER SECTOR

    Potential

    Technologies

    1. Co-generation

    2. Combined Cycle

    3. PFBC

    4. IGCC

    5. Supercritical

    6. Coal Washing

    Green house

    gas emission

    reduction (kg/kWh)

    1.50

    0.960.18

    0.23

    0.18

    0.125

    COST (Rs/Tonnes CO2).

    480

    260024000

    16000

    16000

    8500Source: ADP 1998

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    Zero Emission Technology

    (ZET)This technology combines and forms a part of :

    Clean Coal Technologies

    Solid to liquid fuel technology

    GHG mitigation technology Clean Development Mechanism for power sector

    Non-CFC Refrigerant and Non-CFC Aerosol PropellantTechnology

    Clean Aviation Fuel or ATF for aircraft Substitute LPG for domestic use.

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    Measures to achieve Sustainable

    Development

    Promoting CCTs, including carbon

    sequestration is essential to a balanced cost

    effective climate change response

    Developing countries where coal combustion

    efficiencies are low CCT promotion a need ofthe day.

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    EFFICIENCY IMPROVEMENT FORECAST

    CONVENTIONAL Vs IGCC( Courtesy BHEL)

    60555045

    403530

    1990 1995 2000 2005 2010Year of commercial use

    NetThermalEfficiency(%)

    Ceramic gasturbine

    566 Co 600 Co623 Co 1300 C

    o 1500 Co

    540 Co650 Co1184 Co

    IGCC (15 C Amb)IGCC (Indian Condition)

    Super Critical PC Power Plant (15 C Amb.)oSuper Critical PC Power Plant (Indian Condition)

    o

    Sub Critical PC Power Plant (Indian Condition)

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    570

    256

    384380

    0

    100

    200

    300

    400

    500

    600

    CO2

    MMT

    2.84.3

    10

    6.6

    0

    5

    10

    15

    SO2

    M

    MT

    85

    128

    13.3

    20

    0

    50

    100

    150

    ASH

    M

    MT No Change Scenario

    Specific Coal Consumption

    =0.75 KG/KWH

    Coal

    Ash : 43%

    Sulphur : 0.6%

    Ideal Scenario

    Specific Coal Consumption=0.35 KG/KWH

    Coal

    Ash : 15%

    Sulphur : 3%

    POLLUTANT GENERATION FROM PC PLANTS

    1997

    1997

    1997

    1997

    1997

    1997

    2002

    2002

    2002

    2002

    2002

    2002

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    SOx NOx Particulates

    0

    10

    20

    30

    40

    50

    60

    70

    80

    90

    100

    110

    120

    PERCEN

    TAGE

    OFPC

    PLANTS

    PC

    IGCC

    PFBC

    PC+FGD

    RELATIVE EMMISSION

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    SUPER CRITICAL UNITS

    Standardized Unit Size 660 MW, 246 ata, 537 oC

    Station Size 2x660 MW (Minimum) Common Off site facility

    FW Temperature 270 oC 275 oC with 6 Heaters.

    Total Capacity Planned 14,560 MW *

    Number of Units 22 Units

    *Includes 6x720 MW and 2x500 MW Imported sets.

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    Main advantages of

    Super-Critical Steam Cycle

    Reduced fuel cost due to improved thermal efficiency

    Reduction of CO2 emissions by 15% per unit of Powergenerated compared to sub-critical

    Very good part load efficiencies

    Plant costs are comparable with sub-critical units

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    Current State-of-Art

    Super-critical Steam Power Generation Plants

    Pressure - 300 bar

    Temperature - 600o

    CEfficiency - 45% (LHV Basis)

    Nickel based alloys allows up 650oC

    By the year 2005 - 620 oCBy the year 2020 - 650-700 oC

    Cycle Efficiency - 50-55%

    & I PE I I

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    & I PE I ITECHNOLOGY

    Main Thrust Areas : Materials & Metallurgy for components of boiler &

    turbine subjected to high temperature and high

    pressure. Supercritical cycle optimization -incremental heat rate

    improvement

    Retrofit of supercritical boiler to subcritical PC boiler

    Fluidized bed supercritical steam cycles

    Once through HRSGs with supercritical parameters

    Multi-reheat supercritical boilers with double/triple

    reheater.

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    EXPECTED BENEFITS:

    Coal Saving 1,565,200 Tonnes

    Co2 Emission Reduction 1,909,544

    SO2 Emission Reduction 11,648

    Ash Reduction 661,752

    SUPER CRITICAL SCENARIO

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    COAL BASED COMBINED CYCLE PLANT

    Routes

    Combustion Gasification

    Hot Flue gas under pressure

    drives the G.T.

    Pressurized gasification

    process produces fuel forG.T.

    Pressurized

    Fluidized BED

    Combustor (PFBC)

    Options Available

    Moving BED

    Fluidized BED

    Entrained BED

    COAL BASED

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    COAL BASEDCOMBINED CYCLE POWER GENERATION

    Offers Plant efficiency over 44% with advanced GT

    Has Lower emission of gaseous and solid pollutants

    Accept Inferior and varying quality of coals

    Lower water requirement

    Capability of phased construction and retrofitting

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    IGCC TECHNOLOGY ...

    Gasification of coal is the cleanest way of utilization of coal,while combined cycle power generation gives the highestefficiency.

    Integration of these two technologies in IGCC powergeneration offers the benefits of very low emissions andefficiencies of the order of 44-48%.

    The comparative indices show that in case of IGCC,emission of particulate, NOx and SOx are:

    7.1%, 20% and 16%, respectively, of thecorresponding emissions from PC plant.

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    IGCC ... Environmental performance of IGCC plants far exceeds that

    of conventional and even supercritical plants.

    Three major areas of technology that will contribute toimprovements in IGCC are :

    hot gas de-sulfurisation

    hot gas particulate removal

    advanced turbine systems

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    DEVELOPMENTAL GOALS FOR IGCC

    To utilize Indias low grade coal for power generationwith improved plant efficiency.

    To introduce coal gas in Natural Gas based Combined

    Cycle Plants in a phased manner.

    To increase power generation capacity at the level ofpresent emission.

    To develop state of Art Technology for Indigenous andExport Markets.

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    Gasifier

    Raw GasCooler

    CombustionChamber

    Comp. Turb.

    Alternator

    Air

    COAL

    Ash

    Exhaust

    Gases

    Condenser

    WHB

    Alternator

    ST

    Air

    Fuel

    Steam

    GasClean Up

    Booster

    Steam

    IGCC

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    IGCC DEVELOPMENT PROGRAM IN INDIA

    MAJOR MILE STONES:

    Choice of gasification for high ash coals by BHEL 6.2 MW IGCC demonstration plant established by BHEL both with

    Moving Bed and Fluidized Bed.

    Coal Characterization by BHEL & IICT for gasification application.

    Intensive data generated by IICT on oxygen-steam gasification in their

    Moving Bed gasifier.

    Task force CEA, CSIR, NTPC & BHEL constituted to assess

    technological maturity & Financial requirement for a green field IGCC

    plant of 100 MW capacity at Dadri (NTPC).

    BHEL, CSIR & NTPC prepared proposal for setting up of this 100 MW

    IGCC demonstration plant.

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    Circulating Fluidized Bed Combustion(CFBC) technology has selectively beenapplied in India for firing high sulphur

    refinery residues, lignite, etc.

    CFBC Technology is superior to PC PowerPlant Technology:

    Lower NOx formation and the ability tocapture SO2 with limestone injection thefurnace.

    Circulating fluidized Bed Combustion

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    Good combustion efficiencies comparable to PCPower Plants.

    The heat transfer coefficient of the CFB furnace isnearly double that of PC which makes the furnacecompact.

    Fuel Flexibility: The CFB can handle a wide range offuels such as inferior coal, washery rejects, lignite,anthracite, petroleum coke and agricultural wastewith lower heating.

    Circulating fluidized Bed Combustion

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    Steam to Super Heater

    Cyclone

    FurnaceCoal FeedHopper

    Ash Cooler

    Back-Pass

    ESP

    ExternalHeat-Exchanger

    HP Air

    Circulating Fluidised Bed Boiler

    CFBC Vs Other Clean Coal

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    CFBC Vs Other Clean CoalTechnologies

    At present pulverized fuel firing with FGD are less costly

    than prevailing IGCC technology. However, firing in CFB

    Boiler is still more economical when using high sulfur lignite

    and low-grade coals and rejects.

    0.8-0.981.491.0Relative O&M

    Cost/kW

    1.15-1.421.03-1.191.0Relative CapitalCost/kW

    41-4236.734.8Cycle Eff. %

    IGCCPF+FGD/SCRCFBCITEM

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    Renovation & Modernization (R&M) and LifeExtension (LE) of old power plants is a cost-effective option as compared to adding up greenfield plant capacities.

    Growing environmental regulations would force

    many utilities within the country to go forrevamping these polluting old power plants usingenvironmentally benign CFBC technology.

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    Sustainable Power Development calls foradoption of Clean Coal Technologies like

    Supercritical cycles, IGCC and FBCtechnologies

    Supercritical Power technologies mayselectively be used for Pit Head powergeneration using washed coal

    SUMMERY

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    IGCC can revolutionize the power generationscenario in India, once the commercial viability oftechnology with high ash coals is established at the

    proposed 100 MW plant.

    The success of the project will largely depend onmaturity of Fluidized bed gasification technology for

    high ash Indian Coals.

    CFBC technologies are particularly useful for BoilerEmission reduction through revamping of old

    polluting plants.

    SUMMERY

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