chockfast red hardener msds

8/17/2019 Chockfast Red Hardener MSDS

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ITW POLYMERS AND FLUIDS

Chockfast Red Hardener

Chemwatch: 5141-60

Version No: 8.1.1.1

Safety Data Sheet according to WHS and ADG requirements

Issue Date: 26/05/2014

Print Date: 03/06/2014

Initial Date: Not Available

S.GHS.AUS.EN

SECTION 1 IDENTIFICATION OF THE SUBSTANCE / MIXTURE AND OF THE COMPANY / UNDERTAKING

Product Identifier

Product name Chockfast Red Hardener

Chemical Name Not Applicable

Proper shipping name CORROSIVE LIQUID, N.O.S. (contains diethylenetriamine and tetraethylenepentamine)

Chemical formula Not Applicable

Other means of identification Not Available

CAS number Not Applicable

Relevant identified uses of the substance or mixture and uses advised against

Relevant identified uses

Hardener or Part B of a 2 pack

epoxy systemRequires that the two parts be mixed by hand or mixer before use, in accordance with manufacturers directions. Mix only as much as is

required. Do not return the mixed material to the original containers

Use according to manufacturer's directions.

The use of a quantity of material in an unventilated or confined space may result in increased exposure and an irritating atmosphere developing.

Details of the supplier of the safety data sheet

Registered company name ITW POLYMERS AND FLUIDS

Address100 Hassall Street Wetherill Park NSW 2164

Australia

Telephone +61 2 9757 8800

Fax +61 2 9757 3855

Website www.itwpf.com.au

Email Not Available

Emergency telephone number

Association / Organisation Not Available

Emergency telephone numbers 1800 039 008

Other emergency telephone numbers +61 3 9573 3112

CHEMWATCH EMERGENCY RESPONSE

Primary Number Alternative Number 1 Alternative Number 2

1800 039 008 +612 9186 1132 Not Available

Once connected and if the message is not in your prefered language then please dial 01

SECTION 2 HAZARDS IDENTIFICATION

Classification of the substance or mixture

HAZARDOUS CHEMICAL. DANGEROUS GOODS. According to the Model WHS Regulations and the ADG Code.

Poisons Schedule S5

GHS Classification[1] Metal Corrosion Category 1, Skin Corrosion/Irritation Category 2, Eye Irrit. 2, Skin Sensitizer Category 1, Chronic Aquatic Hazard Category 3

Legend: 1. Classified by Chemwatch; 2. Classification drawn from HSIS ; 3. Classification drawn from EC Directive 1272/2008 - Annex VI

Label elements

GHS label elements

SIGNAL WORD WARNING

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Hazard statement(s)

H290 May be corrosive to metals

H315 Causes skin irritation

H319 Causes serious eye irritation

H317 May cause an allergic skin reaction

H412 Harmful to aquatic life with long lasting effects

Precautionary statement(s): Prevention

P280 Wear protective gloves/protective clothing/eye protection/face protection.

P234 Keep only in original container.

P261 Avoid breathing dust/fume/gas/mist/vapours/spray.

P273 Avoid release to the environment.

Precautionary statement(s): Response

P321 Specific treatment (see advice on this label).

P302+P352 IF ON SKIN: Wash with plenty of water and soap

P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

P333+P313 If skin irritation or rash occurs: Get medical advice/attention.

Precautionary statement(s): Storage

Not Applicable

Precautionary statement(s): Disposal

P501 Dispose of contents/container to authorised chemical landfill or if organic to high temperature incineration

SECTION 3 COMPOSITION / INFORMATION ON INGREDIENTS

Substances

See section below for composition of Mixtures

Mixtures

CAS No %[weight] Name

68513-05-3 >50 tall oil/ tetraethylenepentamine polyamides

112-57-2


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The presence of shock suggests perforation and mandates an intravenous line and fluid administration.

Damage due to alkaline corrosives occurs by liquefaction necrosis whereby the saponification of fats and solubilisation of proteins allow

deep penetration into the tissue.

Alkalis continue to cause damage after exposure.

INGESTION:

Milk and water are the preferred diluents

No more than 2 glasses of water should be given to an adult.

Neutralising agents should never be given since exothermic heat reaction may compound injury.

* Catharsis and emesis are absolutely contra-indicated.* Activated charcoal does not absorb alkali.

* Gastric lavage should not be used.

Supportive care involves the following:

Withhold oral feedings initially.

If endoscopy confirms transmucosal injury start steroids only within the first 48 hours.

Carefully evaluate the amount of tissue necrosis before assessing the need for surgical intervention.

Patients should be instructed to seek medical attention whenever they develop difficulty in swallowing (dysphagia).

SKIN AND EYE:

Injury should be irrigated for 20-30 minutes.

Eye injuries require saline. [Ellenhorn & Barceloux: Medical Toxicology]

SECTION 5 FIREFIGHTING MEASURES

Extinguishing media

Water spray or fog.

Foam.

Dry chemical powder.

BCF (where regulations permit).

Special hazards arising from the substrate or mixture

Fire IncompatibilityReacts with aluminium / zinc producing flammable, explosive hydrogen gas

Avoid contamination with oxidising agents i.e. nitrates, oxidising acids, chlorine bleaches, pool chlorine etc. as ignition may result

Advice for firefighters

Fire Fighting

Alert Fire Brigade and tell them location and nature of hazard.

Wear full body protective clothing with breathing apparatus.

Prevent, by any means available, spillage from entering drains or water course.

Use fire fighting procedures suitable for surrounding area.

Fire/Explosion Hazard

Combustible.

Slight fire hazard when exposed to heat or flame.Heating may cause expansion or decomposition leading to violent rupture of containers.

On combustion, may emit toxic fumes of carbon monoxide (CO).

SECTION 6 ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment and emergency procedures

Minor Spills

Remove all ignition sources.

Clean up all spills immediately.

Avoid breathing vapours and contact with skin and eyes.

Control personal contact with the substance, by using protective equipment.

Major Spills

Clear area of personnel and move upwind.




Personal Protective Equipment advice is contained in Section 8 of the MSDS.

SECTION 7 HANDLING AND STORAGE

Precautions for safe handling

Safe handling

DO NOT allow clothing wet with material to stay in contact with skin

DO NOT use aluminium, galvanised or tin-plated containers

DO NOT USE brass or copper containers / stirrers

Avoid all personal contact, including inhalation.

Wear protective clothing when risk of exposure occurs.

Use in a well-ventilated area.

Prevent concentration in hollows and sumps.

Other information

Store in original containers.

Keep containers securely sealed.No smoking, naked lights or ignition sources.

Store in a cool, dry, well-ventilated area.

Conditions for safe storage, including any incompatibilities

Suitable container

Lined metal can, lined metal pail/ can.

Plastic pail.

Polyliner drum.

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Packing as recommended by manufacturer.

Storage incompatibility

Avoid contact with copper, aluminium and their alloys.

Avoid strong acids, acid chlorides, acid anhydrides and chloroformates.

Avoid reaction with oxidising agents

PACKAGE MATERIAL INCOMPATIBILITIES

Not Available

SECTION 8 EXPOSURE CONTROLS / PERSONAL PROTECTION

Control parameters

OCCUPATIONAL EXPOSURE LIMITS (OEL)

INGREDIENT DATA

Source Ingredient Material name TWA STEL Peak Notes

Australia Exposure Standards diethylenetriamine Diethylene triamine 4.2 mg/m3 / 1 ppm Not Available Not Available Not Available

EMERGENCY LIMITS

Ingredient TEEL-0 TEEL-1 TEEL-2 TEEL-3

tetraethylenepentamine 5 ppm 15 ppm 350 ppm 500 ppm

diethylenetriamine 1 ppm 1 ppm 1.25 ppm 100 ppm

Ingredient Original IDLH Revised IDLH

tall oil/ tetraethylenepentamine polyamides Not Available Not Available

tetraethylenepentamine Not Available Not Available

diethylenetriamine Not Available Not Available

Exposure controls

Appropriate engineering controls

Use in a well-ventilated area

General exhaust is adequate under normal operating conditions.

Refer also to protective measures for the other component used with the product. Read both MSDS before using; store and attach MSDS

together.

Personal protection

Eye and face protection

· Chemical goggles.

· Full face shield may be required for supplementary but never for primary protection of eyes.

· Contact lenses may pose a special hazard; soft contact lenses may absorb and concentrate irritants. A written policy document, describing the

wearing of lenses or restrictions on use, should be created for each workplace or task.

Skin protection See Hand protection below

Hands/feet protection

Wear chemical protective gloves, e.g. PVC.

Wear safety footwear or safety gumboots, e.g. Rubber

NOTE:

The material may produce skin sensitisation in predisposed individuals. Care must be taken, when removing gloves and other protective

equipment, to avoid all possible skin contact.

Contaminated leather items, such as shoes, belts and watch-bands should be removed and destroyed.

Body protection See Other protection below

Other protection

Overalls.

P.V.C. apron.

Barrier cream.

Thermal hazards Not Available

Recommended material(s)

GLOVE SELECTION INDEX

Glove selection is based on a modified presentation of the:

" Forsberg Clothing Performance Index".

The effect(s) of the following substance(s) are taken into account in the computer-

generated selection:


Material CPI

BUTYL A

NEOPRENE A

VITON A

* CPI - Chemwatch Performance Index

A: Best Selection

Respiratory protection

Type AK-P Filter of sufficient capacity. (AS/NZS 1716 & 1715, EN 143:2000 & 149:2001, ANSI

Z88 or national equivalent)

Where the concentration of gas/particulates in the breathing zone,

approaches or exceeds the "Exposure Standard" (or ES), respiratory

protection is required.

Degree of protection varies with both face-piece and Class of filter;

the nature of protection varies with Type of filter.

Required

Minimum

Protection

Factor

Half-Face

Respirator

Full-Face

Respirator

Powered Air

Respirator

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B: Satisfactory; may degrade after 4 hours continuous immersion

C: Poor to Dangerous Choice for other than short term immersion

NOTE: As a series of factors will influence the actual performance of the glove, a final

selection must be based on detailed observation. -

* Where the glove is to be used on a short term, casual or infrequent basis, factors such as

"feel" or convenience (e.g. disposability), may dictate a choice of gloves which might otherwise

be unsuitable following long-term or frequent use. A qualified practitioner should be consulted.

up to 10 x ES AK-AUS P2 - AK-PAPR-AUS /

Class 1 P2

up to 50 x ES - AK-AUS /

Class 1 P2-

up to 100 x ES - AK-2 P2 AK-PAPR-2 P2 ̂

^ - Full-face A(All classes) = Organic vapours, B AUS or B1 = Acid gasses, B2 =

Acid gas or hydrogen cyanide(HCN), B3 = Acid gas or hydrogen

cyanide(HCN), E = Sulfur dioxide(SO2), G = Agricultural chemicals,

K = Ammonia(NH3), Hg = Mercury, NO = Oxides of nitrogen, MB =

Methyl bromide, AX = Low boiling point organic compounds(below

65 degC)

SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES

Information on basic physical and chemical properties

Appearance Amber liquid with an ammoniacal odour; mixes with water.

Physical state Liquid Relative density (Water = 1) 1.24

Odour Not Available Partition coefficient n-octanol / water Not Available

Odour threshold Not Available Auto-ignition temperature (°C) Not Available

pH (as supplied) >7 Decomposition temperature Not Available

Melting point / freezing point (°C) Not Available Viscosity (cSt) Not Available

Initial boiling point and boiling range

(°C)>204 Molecular weight (g/mol) Not Applicable

Flash point (°C) >94 Taste Not Available

Evaporation rate Not Available Explosive properties Not Available

Flammability Not Available Oxidising properties Not Available

Upper Explosive Limit (%) Not Available Surface Tension (dyn/cm or mN/m) Not Available

Lower Explosive Limit (%) Not Available Volatile Component (%vol) Not Available

Vapour pressure (kPa) Not Available Gas group Not Available

Solubility in water (g/L) Miscible pH as a solution(1%) Not Available

Vapour density (Air = 1) Not Available VOC g/L Not Available

SECTION 10 STABILITY AND REACTIVITY

Reactivity See section 7

Chemical stability

· Unstable in the presence of incompatible materials.

· Product is considered stable.

· Hazardous polymerisation will not occur.

Possibility of hazardous reactions See section 7

Conditions to avoid See section 7

Incompatible materials See section 7

Hazardous decomposition products See section 5

SECTION 11 TOXICOLOGICAL INFORMATION

Information on toxicological effects

Inhaled

Inhalation of aerosols (mists, fumes), generated by the material during the course of normal handling, may be damaging to the health of the

individual.

511hardamine

Inhalation of amine vapours may cause irritation of the mucous membranes of the nose and throat and lung irritation with respiratory distress and

cough. Single exposures to near lethal concentrations and repeated exposures to sublethal concentrations produces tracheitis, bronchitis,

pneumonitis and pulmonary oedema. Aliphatic and alicyclic amines are generally well absorbed from the respiratory tract.

Ingestion

The material can produce chemical burns within the oral cavity and gastrointestinal tract following ingestion.

Ingestion of amine epoxy-curing agents (hardeners) may cause severe abdominal pain, nausea, vomiting or diarrhoea. The vomitus may contain

blood and mucous. If death does not occur within 24 hours there may be an improvement in the patients condition for 2-4 days only to be followed

by the sudden onset of abdominal pain, board-like abdominal rigidity or hypo-tension; this indicates that delayed gastric or oesophageal corrosive

damage has occurred.

Skin Contact

Skin contact with the material may damage the health of the individual; systemic effects may result following absorption.

511r38

Entry into the blood-stream through, for example, cuts, abrasions, puncture wounds or lesions, may produce systemic injury with harmful effects.

Examine the skin prior to the use of the material and ensure that any external damage is suitably protected.

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Amine epoxy-curing agents (hardeners) may produce primary skin irritation and sensitisation dermatitis in predisposed individuals.

Eye

510r36

Vapours of volatile amines cause eye irritation with lachrymation, conjunctivitis and minor transient corneal oedema which results in "halos"

around lights (glaucopsia, "blue haze", or "blue-grey haze"). Vision may become misty and halos may appear several hours after workers are

exposed to the substance

This effect generally disappears spontaneously within a few hours of the end of exposure, and does not produce physiological after-effects.

However oedema of the corneal epithelium, which is primarily responsible for vision disturbances, may take more than one or more days to clear,

depending on the severity of exposure. Photophobia and discomfort from the roughness of the corneal surface also may occur after greater

exposures.

ChronicPractical experience shows that skin contact with the material is capable either of inducing a sensitisation reaction in a substantial number of

individuals, and/or of producing a positive response in experimental animals.

Chockfast Red Hardener TOXICITY IRRITATION

Not Available Not Available

tall oil/ tetraethylenepentamine

polyamides

TOXICITY IRRITATION

Oral (rat) LD50: >5000 mg/kg Eyes (rabbit) (-) moderate

Skin (rabbit) (-) moderate


tetraethylenepentamine

TOXICITY IRRITATION

Dermal (rabbit) LD50: 660 mg/kg Eye (rabbit): 100 mg/24h moderate

Oral (rat) LD50: 3990 mg/kg Eye (rabbit): 5 mg moderate

Skin (rabbit): 495 mg SEVERE

Skin (rabbit): 5 mg/24h SEVERE


diethylenetriamine

TOXICITY IRRITATION

Dermal (rabbit) LD50: 1090 mg/kg Skin (rabbit): 10 mg/24h - SEVERE

Intraperitoneal (Mouse) LD50: 71 mg/kg Skin (rabbit):500 mg open moderate

Intraperitoneal (Rat) LD50: 74 mg/kg

Oral (rat) LD50: 1080 mg/kg


Not available. Refer to individual constituents.

TALL OIL/

TETRAETHYLENEPENTAMINE

POLYAMIDES,

TETRAETHYLENEPENTAMINE,

DIETHYLENETRIAMINE

The following information refers to contact allergens as a group and may not be specific to this product.

Contact allergies quickly manifest themselves as contact eczema, more rarely as urticaria or Quincke's oedema. The pathogenesis of

contact eczema involves a cell-mediated (T lymphocytes) immune reaction of the delayed type. Other allergic skin reactions, e.g. contact

urticaria, involve antibody-mediated immune reactions.

Acute Toxicity Carcinogenicity

Skin Irritation/Corrosion Reproductivity

Serious Eye Damage/Irritation STOT - Single Exposure

Respiratory or Skin sensitisation STOT - Repeated Exposure

Mutagenicity Aspiration Hazard

CMR STATUS

SKIN diethylenetriamine Australia Exposure Standards - Skin Sk

SECTION 12 ECOLOGICAL INFORMATION

Toxicity

Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.

DO NOT discharge into sewer or waterways.

Persistence and degradability

Ingredient Persistence: Water/Soil Persistence: Air

Not Available Not Available Not Available

Bioaccumulative potential

Ingredient Bioaccumulation

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Mobility in soil

Ingredient Mobility


SECTION 13 DISPOSAL CONSIDERATIONS

Waste treatment methods

Product / Packaging disposal

Recycle wherever possible or consult manufacturer for recycling options.

Consult State Land Waste Authority for disposal.

Bury or incinerate residue at an approved site.

Recycle containers if possible, or dispose of in an authorised landfill.

SECTION 14 TRANSPORT INFORMATION

Labels Required

Marine PollutantNO

HAZCHEM 2X

Land transport (ADG)

UN number 1760

Packing group III

UN proper shipping name CORROSIVE LIQUID, N.O.S. (contains diethylenetriamine and tetraethylenepentamine)

Environmental hazard No relevant data

Transport hazard class(es)Class 8

Subrisk

Special precautions for user Special provisions 223 274

Limited quantity 5 L

Air transport (ICAO-IATA / DGR)

UN number 1760

Packing group III

UN proper shipping name Corrosive liquid, n.o.s. * (contains diethylenetriamine and tetraethylenepentamine)


Transport hazard class(es)

ICAO/IATA Class 8

ICAO / IATA Subrisk

ERG Code 8L

Special precautions for user

Special provisions A3A803

Cargo Only Packing Instructions 856

Cargo Only Maximum Qty / Pack 60 L

Passenger and Cargo Packing Instructions 852

Passenger and Cargo Maximum Qty / Pack 5 L

Passenger and Cargo Limited Quantity Packing Instructions Y841

Passenger and Cargo Limited Maximum Qty / Pack 1 L

Sea transport (IMDG-Code / GGVSee)

UN number 1760

Packing group III

UN proper shipping name CORROSIVE LIQUID, N.O.S. (contains diethylenetriamine and tetraethylenepentamine)

Environmental hazard

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Transport hazard class(es)IMDG Class 8

IMDG Subrisk


EMS Number F-A,S-B

Special provisions 223 274

Limited Quantities 5 L

SECTION 15 REGULATORY INFORMATION

Safety, health and environmental regulations / legislation specific for the substance or mixture

tall oil/ tetraethylenepentamine

polyamides(68513-05-3) is found on the

following regulatory lists

"International Maritime Dangerous Goods Requirements (IMDG Code)","International Maritime Dangerous Goods Requirements (IMDG

Code) - Substance Index","United Nations Recommendations on the Transport of Dangerous Goods Model Regulations (English)","Australia

Dangerous Goods Code (ADG Code) - List of Emergency Action Codes","Australia Inventory of Chemical Substances (AICS)","OECD List of

High Production Volume (HPV) Chemicals","Belgium Federal Public Service Mobility and Transport, Regulations concerning the International

Carriage of Dangerous Goods by Rail - Table A: Dangerous Goods List - RID 2013 (Dutch)","OSPAR National List of Candidates for

Substitution – United Kingdom","United Nations Recommendations on the Transport of Dangerous Goods Model Regulations

(Spanish)","Australia Dangerous Goods Code (ADG Code) - Dangerous Goods List","International Air Transport Association (IATA)

Dangerous Goods Regulations"

tetraethylenepentamine(112-57-2) is

found on the following regulatory lists

"Australia Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP) - Appendix F (Part 3)","International Maritime Dangerous

Goods Requirements (IMDG Code)","International Council of Chemical Associations (ICCA) - High Production Volume List","Australia

Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP) - Schedule 5","International Maritime Dangerous Goods

Requirements (IMDG Code) - Substance Index","FisherTransport Information","Australia FAISD Handbook - First Aid Instructions, Warning

Statements, and General Safety Precautions","United Nations Recommendations on the Transport of Dangerous Goods Model Regulations

(English)","Australia Dangerous Goods Code (ADG Code) - List of Emergency Action Codes","OECD List of High Production Volume (HPV)

Chemicals","Australia Inventory of Chemical Substances (AICS)","OSPAR National List of Candidates for Substitution – Norway","Belgium

Federal Public Service Mobility and Transport, Regulations concerning the International Carriage of Dangerous Goods by Rail - Table A:

Dangerous Goods List - RID 2013 (Dutch)","Australia National Pollutant Inventory","OSPAR National List of Candidates for Substitution –

United Kingdom","Sigma-AldrichTransport Information","United Nations Recommendations on the Transport of Dangerous Goods Model

Regulations (Spanish)","OECD Existing Chemicals Database","GESAMP/EHS Composite List - GESAMP Hazard Profiles","Australia

Dangerous Goods Code (ADG Code) - Dangerous Goods List","Australia Hazardous Substances Information System - Consolidated

Lists","Australia Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP) - Appendix E (Part 2)","International Air Transport

Association (IATA) Dangerous Goods Regulations","IMO IBC Code Chapter 17: Summary of minimum requirements"

diethylenetriamine(111-40-0) is found on

the following regulatory lists


Goods Requirements (IMDG Code)","Australia Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP) - Schedule

5","Australia Exposure Standards","International Maritime Dangerous Goods Requirements (IMDG Code) - Substance Index","Australia FAISD

Handbook - First Aid Instructions, Warning Statements, and General Safety Precautions","United Nations Recommendations on the Transport of

Dangerous Goods Model Regulations (English)","Australia Dangerous Goods Code (ADG Code) - List of Emergency ActionCodes","Australia Inventory of Chemical Substances (AICS)","OECD List of High Production Volume (HPV) Chemicals","OSPAR National List

of Candidates for Substitution – Norway","Belgium Federal Public Service Mobility and Transport, Regulations concerning the International

Carriage of Dangerous Goods by Rail - Table A: Dangerous Goods List - RID 2013 (Dutch)","Australia National Pollutant Inventory","OSPAR

National List of Candidates for Substitution – United Kingdom","Sigma-AldrichTransport Information","United Nations Recommendations on the

Transport of Dangerous Goods Model Regulations (Spanish)","OECD Existing Chemicals Database","GESAMP/EHS Composite List -

GESAMP Hazard Profiles","Australia Dangerous Goods Code (ADG Code) - Dangerous Goods List","Australia Hazardous Substances

Information System - Consolidated Lists","International Air Transport Association (IATA) Dangerous Goods Regulations","Australia Standard

for the Uniform Scheduling of Medicines and Poisons (SUSMP) - Appendix E (Part 2)","IMO IBC Code Chapter 17: Summary of minimum

requirements"

SECTION 16 OTHER INFORMATION

Other information

Classification of the preparation and its individual components has drawn on official and authoritative sources as well as independent review by the Chemwatch Classification committee using

available literature references.

A list of reference resources used to assist the committee may be found at:

www.chemwatch.net/references

The (M)SDS is a Hazard Communication tool and should be used to assist in the Risk Assessment. Many factors determine whether the reported Hazards are Risks in the workplace or other

settings. Risks may be determined by reference to Exposures Scenarios. Scale of use, frequency of use and current or available engineering controls must be considered.

This document is copyright. Apart from any fair dealing for the purposes of private study, research, review or criticism, as permitted under the Copyright Act, no part may be reproduced by any

process without written permission from CHEMWATCH. TEL (+61 3) 9572 4700.

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Chockfast Red Resin

Chemwatch: 5141-59

Version No: 8.1.1.1





S.GHS.AUS.EN


Product Identifier

Product name Chockfast Red Resin


Proper shipping name ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (contains epoxy resin)





Relevant identified uses

Use according to manufacturer's directions.

Requires that the two parts be mixed by hand or mixer before use, in accordance with manufacturers directions. Mix only as much as isrequired. Do not return the mixed material to the original containers

The use of a quantity of material in an unventilated or confined space may result in increased exposure and an irritating atmosphere developing.




Australia

Telephone +61 2 9757 8800

Fax +61 2 9757 3855


Email Not Available



Emergency telephone numbers 1800 039 008

Other emergency telephone numbers +61 3 9573 3112



1800 039 008 +612 9186 1132 Not Available




HAZARDOUS CHEMICAL. DANGEROUS GOODS. According to the Model WHS Regulations and the ADG Code.

COMBUSTIBLE LIQUID, regulated for storage purposes only

Poisons Schedule S5

GHS Classification[1] Flammable Liquid Category 4, Skin Corrosion/Irritation Category 2, Eye Irrit. 2, Skin Sensitizer Category 1, STOT - SE (Narcosis) Category 3,

Acute Aquatic Hazard Category 2, Chronic Aquatic Hazard Category 2


Label elements

GHS label elements

SIGNAL WORD WARNING

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Hazard statement(s)

H227 Combustible liquid

H315 Causes skin irritation

H319 Causes serious eye irritation

H317 May cause an allergic skin reaction

H336 May cause drowsiness or dizziness

H401 Toxic to aquatic life

H411 Toxic to aquatic life with long lasting effects


P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.

P271 Use only outdoors or in a well-ventilated area.

P280 Wear protective gloves/protective clothing/eye protection/face protection.

P261 Avoid breathing dust/fume/gas/mist/vapours/spray.


P321 Specific treatment (see advice on this label).

P370+P378 In case of fire: Use… to extinguish.

P302+P352 IF ON SKIN: Wash with plenty of water and soap

P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.


P403+P235 Store in a well-ventilated place. Keep cool.

P405 Store locked up.

P403+P233 Store in a well-ventilated place. Keep container tightly closed.




Substances


Mixtures


25068-38-6 >60 bisphenol A/ epichlorohydrin resin

1330-20-7 1-10 xylene

SECTION 4 FIRST AID MEASURES

Description of first aid measures

Eye Contact

If this product comes in contact with the eyes:

Wash out immediately with fresh running water.Ensure complete irrigation of the eye by keeping eyelids apart and away from eye and moving the eyelids by occasionally lifting the upper

and lower lids.

Seek medical attention without delay; if pain persists or recurs seek medical attention.

Removal of contact lenses after an eye injury should only be undertaken by skilled personnel.

Skin Contact

If skin contact occurs:

Immediately remove all contaminated clothing, including footwear.

Flush skin and hair with running water (and soap if available).

Seek medical attention in event of irritation.

Inhalation

If fumes or combustion products are inhaled remove from contaminated area.

Lay patient down. Keep warm and rested.

Prostheses such as false teeth, which may block airway, should be removed, where possible, prior to initiating first aid procedures.

Apply artificial respiration if not breathing, preferably with a demand valve resuscitator, bag-valve mask device, or pocket mask as trained.

Perform CPR if necessary.

Transport to hospital, or doctor.

Ingestion

If swallowed do NOT induce vomiting.

If vomiting occurs, lean patient forward or place on left side (head-down position, if possible) to maintain open airway and preventaspiration.

Observe the patient carefully.

Never give liquid to a person showing signs of being sleepy or with reduced awareness; i.e. becoming unconscious.

Give water to rinse out mouth, then provide liquid slowly and as much as casualty can comfortably drink.

Seek medical advice.

Indication of any immediate medical attention and special treatment needed

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Treat symptomatically.

SECTION 5 FIREFIGHTING MEASURES

Extinguishing media

Water spray or fog.

Alcohol stable foam.Dry chemical powder.

Carbon dioxide.

Special hazards arising from the substrate or mixture

Fire Incompatibility Avoid contamination with oxidising agents i.e. nitrates, oxidising acids, chlorine bleaches, pool chlorine etc. as ignition may result

Advice for firefighters

Fire Fighting




Use water delivered as a fine spray to control fire and cool adjacent area.

Fire/Explosion Hazard

Combustible.

Slight fire hazard when exposed to heat or flame.

Heating may cause expansion or decomposition leading to violent rupture of containers.

On combustion, may emit toxic fumes of carbon monoxide (CO).

SECTION 6 ACCIDENTAL RELEASE MEASURES


Minor Spills

Environmental hazard - contain spillage.


Avoid breathing vapours and contact with skin and eyes.

Control personal contact with the substance, by using protective equipment.

Major Spills

Environmental hazard - contain spillage.

Moderate hazard.






Safe handling

DO NOT allow clothing wet with material to stay in contact with skin

Avoid all personal contact, including inhalation.



Prevent concentration in hollows and sumps.

Other information


Keep containers securely sealed.


Store away from incompatible materials and foodstuff containers.


Suitable container

Metal can or drum

Packaging as recommended by manufacturer.

Check all containers are clearly labelled and free from leaks.

Storage incompatibility Avoid reaction with oxidising agents


Not Available


Control parameters


INGREDIENT DATA


Australia Exposure Standards xylene Xylene (o-, m-, p- isomers) 350 mg/m3 / 80 ppm 655 mg/m3 / 150 ppm Not Available Not Available

EMERGENCY LIMITS


Chemwatch:5141-59

Version No: 8.1.1.1

Page 3 of8

Chockfast Red Resin



Continued...


12/23

bisphenol A/ epichlorohydrin resin 125 / 4 / 50 ppm 150 / 350 / 12.5 ppm 500 / 100 ppm 500 ppm

xylene 100 ppm 130 ppm 920 ppm 2500 ppm


bisphenol A/ epichlorohydrin resin Not Available Not Available

xylene 1,000 ppm 900 ppm

Exposure controls


Engineering controls are used to remove a hazard or place a barrier between the worker and the hazard. Well-designed engineering controls

can be highly effective in protecting workers and will typically be independent of worker interactions to provide this high level of protection.

The basic types of engineering controls are:

Process controls which involve changing the way a job activity or process is done to reduce the risk.

Enclosure and/or isolation of emission source which keeps a selected hazard "physically" away from the worker and ventilation that strategically

"adds" and "removes" air in the work environment.

Personal protection


· Safety glasses with side shields.



wearing of lenses or restrictions on use, should be created for each workplace or task.



The selection of suitable gloves does not only depend on the material, but also on further marks of quality which vary from manufacturer to

manufacturer. Where the chemical is a preparation of several substances, the resistance of the glove material can not be calculated in advance

and has therefore to be checked prior to the application.

The exact break through time for substances has to be obtained from the manufacturer of the protective gloves and.has to be observed when

making a final choice.

Suitability and durability of glove type is dependent on usage.


Other protection

Overalls.

P.V.C. apron.

Barrier cream.






The effect(s) of the following substance(s) are taken into account in the computer-

generated selection:

Chockfast Red Resin

Material CPI

PE/EVAL/PE A

PVA A

TEFLON A

VITON A


A: Best Selection









Type A Filter of sufficient capacity. (AS/NZS 1716 & 1715, EN 143:2000 & 149:2001, ANSI Z88

or national equivalent)

Where the concentration of gas/particulates in the breathing zone,

approaches or exceeds the "Exposure Standard" (or ES), respiratory

protection is required.

Degree of protection varies with both face-piece and Class of filter;

the nature of protection varies with Type of filter.

Required

Minimum

Protection

Factor

Half-Face

Respirator

Full-Face

Respirator

Powered Air

Respirator

up to 10 x ES A-AUS / Class

1-

A-PAPR-AUS /

Class 1

up to 50 x ES Air-line* - -

up to 100 x ES - A-3 -

100+ x ES - Air-line** -

* - Continuous-flow; ** - Continuous-flow or positive pressure

demand

A(All classes) = Organic vapours, B AUS or B1 = Acid gasses, B2 =

Acid gas or hydrogen cyanide(HCN), B3 = Acid gas or hydrogen

cyanide(HCN), E = Sulfur dioxide(SO2), G = Agricultural chemicals,



65 degC)



Chemwatch:5141-59

Version No: 8.1.1.1

Page 4 of8

Chockfast Red Resin



Continued...


13/23

Appearance Clear to yellow liquid with a very slight odour; not miscible with water.

Physical state Liquid Relative density (Water = 1) 1.15

Odour Not Available Partition coefficient n-octanol / water Not Available

Odour threshold Not Available Auto-ignition temperature (°C) Not Available

pH (as supplied) Not Available Decomposition temperature Not Available

Melting point / freezing point (°C) Not Available Viscosity (cSt) Not Available


(°C)>120 Molecular weight (g/mol) Not Applicable

Flash point (°C) 65 Taste Not Available

Evaporation rate Not Available Explosive properties Not Available

Flammability Combustible. Oxidising properties Not Available

Upper Explosive Limit (%) Not Available Surface Tension (dyn/cm or mN/m) Not Available

Lower Explosive Limit (%) Not Available Volatile Component (%vol) Not Available

Vapour pressure (kPa) Not Available Gas group Not Available

Solubility in water (g/L) Immiscible pH as a solution(1%) Not Available

Vapour density (Air = 1) Not Available VOC g/L Not Available



Chemical stability

· Unstable in the presence of incompatible materials.

· Product is considered stable.

· Hazardous polymerisation will not occur.







Inhaled

Inhalation of vapours may cause drowsiness and dizziness. This may be accompanied by narcosis, reduced alertness, loss of reflexes, lack of

coordination and vertigo.

If exposure to highly concentrated solvent atmosphere is prolonged this may lead to narcosis, unconsciousness, even coma and possible death.

Inhalation of aerosols (mists, fumes), generated by the material during the course of normal handling, may be harmful.

Ingestion

Accidental ingestion of the material may be damaging to the health of the individual.

Considered an unlikely route of entry in commercial/industrial environments. The liquid may produce gastrointestinal discomfort and may be

harmful if swallowed. Ingestion may result in nausea, pain and vomiting.

Skin Contact

Skin contact with the material may damage the health of the individual; systemic effects may result following absorption.

The material produces moderate skin irritation; evidence exists, or practical experience predicts, that the material either

produces moderate inflammation of the skin in a substantial number of individuals following direct contact, and/or

produces significant, but moderate, inflammation when applied to the healthy intact skin of animals (for up to four hours), such inflammation

being present twenty-four hours or more after the end of the exposure period.

Skin irritation may also be present after prolonged or repeated exposure; this may result in a form of contact dermatitis (nonallergic). The

dermatitis is often characterised by skin redness (erythema) and swelling (oedema) which may progress to blistering (vesiculation), scaling and

thickening of the epidermis.

Eye

Evidence exists, or practical experience predicts, that the material may cause severe eye irritation in a substantial number of individuals and/or

may produce significant ocular lesions which are present twenty-four hours or more after instillation into the eye(s) of experimental animals. Eye

contact may cause significant inflammation with pain. Corneal injury may occur; permanent impairment of vision may result unless treatment is

prompt and adequate. Repeated or prolonged exposure to irritants may cause inflammation characterised by a temporary redness (similar to

windburn) of the conjunctiva (conjunctivitis); temporary impairment of vision and/or other transient eye damage/ulceration may occur.

Chronic

On the basis, primarily, of animal experiments, concern has been expressed that the material may produce carcinogenic or mutagenic effects; in

respect of the available information, however, there presently exists inadequate data for making a satisfactory assessment.

Limited evidence suggests that repeated or long-term occupational exposure may produce cumulative health effects involving organs or

biochemical systems.

Limited evidence shows that inhalation of the material is capable of inducing a sensitisation reaction in a significant number of individuals at a

greater frequency than would be expected from the response of a normal population.

Pulmonary sensitisation, resulting in hyperactive airway dysfunction and pulmonary allergy may be accompanied by fatigue, malaise and aching.

Chockfast Red Resin

TOXICITY IRRITATION


bisphenol A/ epichlorohydrin resin

TOXICITY IRRITATION

Intraperitoneal (mouse) LD50: 4000 mg/kg Eye (rabbit): 100 mg - mild

Intraperitoneal (rat) LD50: 2400 mg/kg Nil reported

Oral (mouse) LD50: 15600 mg/kg

Chemwatch:5141-59

Version No: 8.1.1.1

Page 5 of8

Chockfast Red Resin



Continued...


14/23




xylene

TOXICITY IRRITATION

Inhalation (rat) LC50: 5000 ppm/4h Eye (human): 200 ppm irritant

Intraperitoneal (Mouse) LD50: 1548 mg/kg Eye (rabbit): 5 mg/24h SEVERE

Intraperitoneal (Rat) LD50: 2459 mg/kg Eye (rabbit): 87 mg mild

Oral (Mouse) LD50: 2119 mg/kg Skin (rabbit):500 mg/24h moderate


Subcutaneous (Rat) LD50: 1700 mg/kg


* Value obtained from manufacturer's msds

unless otherwise specified data extracted from RTECS - Register of Toxic Effects of Chemical Substances

BISPHENOL A/ EPICHLOROHYDRIN

RESINfor RTECS No: SL 6475000: (liquid grade) Equivocal tumourigen by RTECS criteria Somnolence, dyspnea, peritonitis

XYLENE

The material may produce severe irritation to the eye causing pronounced inflammation. Repeated or prolonged exposure to irritants may

produce conjunctivitis.

The material may cause skin irritation after prolonged or repeated exposure and may produce a contact dermatitis (nonallergic). This form of

dermatitis is often characterised by skin redness (erythema) and swelling the epidermis.

Reproductive effector in rats

Chockfast Red Resin, BISPHENOL A/

EPICHLOROHYDRIN RESIN

The following information refers to contact allergens as a group and may not be specific to this product.

Contact allergies quickly manifest themselves as contact eczema, more rarely as urticaria or Quincke's oedema. The pathogenesis of

contact eczema involves a cell-mediated (T lymphocytes) immune reaction of the delayed type. Other allergic skin reactions, e.g. contact

urticaria, involve antibody-mediated immune reactions.






CMR STATUS

Not Applicable


Toxicity

Toxic to aquatic organisms.

Do NOT allow product to come in contact with surface waters or to intertidal areas below the mean high water mark. Do not contaminate water when cleaning equipment or disposing of equipment

wash-waters.

Wastes resulting from use of the product must be disposed of on site or at approved waste sites.







Mobility in soil

Ingredient Mobility






Consult State Land Waste Authority for disposal.

Bury or incinerate residue at an approved site.

Chemwatch:5141-59

Version No: 8.1.1.1

Page 6 of8

Chockfast Red Resin



Continued...


15/23



Labels Required

Marine Pollutant

HAZCHEM •3Z

Land transport (ADG)

UN number 3082

Packing group III

UN proper shipping name ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (contains epoxy resin)


Transport hazard class(es)Class 9

Subrisk

Special precautions for user Special provisions 179 274 331 335 AU01

Limited quantity 5 L

Environmentally Hazardous Substances meeting the descriptions of UN 3077 or UN 3082

are not subject to this Code when transported by road or rail in;

(a) packagings;

(b) IBCs; or

(c) any other receptacle not exceeding 500 kg(L).- Australian Special Provisions (SP AU01) - ADG Code 7th Ed.

Air transport (ICAO-IATA / DGR)

UN number 3082

Packing group III

UN proper shipping name Environmentally hazardous substance, liquid, n.o.s. * (contains epoxy resin)


Transport hazard class(es)

ICAO/IATA Class 9

ICAO / IATA Subrisk

ERG Code 9L


Special provisions A97A158

Cargo Only Packing Instructions 964

Cargo Only Maximum Qty / Pack 450 L

Passenger and Cargo Packing Instructions 964

Passenger and Cargo Maximum Qty / Pack 450 L

Passenger and Cargo Limited Quantity Packing Instructions Y964

Passenger and Cargo Limited Maximum Qty / Pack 30 kg G

Sea transport (IMDG-Code / GGVSee)

UN number 3082

Packing group III

UN proper shipping name ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (contains epoxy resin)

Environmental hazard

Transport hazard class(es)IMDG Class 9

IMDG Subrisk

Special precautions for user EMS Number F-A,S-F

Special provisions 274 335

Chemwatch:5141-59

Version No: 8.1.1.1

Page 7 of8

Chockfast Red Resin



Continued...


16/23

Limited Quantities 5 L



bisphenol A/ epichlorohydrin

resin(25068-38-6) is found on the



Goods Requirements (IMDG Code)","Australia - Victoria Occupational Health and Safety Regulations - Schedule 9: Materials at Major Hazard

Facilities (And Their Threshold Quantity) Table 2","Australia Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP) -

Schedule 5","WHO Model List of Essential Medicines - Adults","International Maritime Dangerous Goods Requirements (IMDG Code) -

Substance Index","Australia FAISD Handbook - First Aid Instructions, Warning Statements, and General Safety Precautions","United Nations

Recommendations on the Transport of Dangerous Goods Model Regulations (English)","Australia Dangerous Goods Code (ADG Code) - List

of Emergency Action Codes","OECD List of High Production Volume (HPV) Chemicals","Australia Inventory of Chemical Substances

(AICS)","Belgium Federal Public Service Mobility and Transport, Regulations concerning the International Carriage of Dangerous Goods by

Rail - Table A: Dangerous Goods List - RID 2013 (Dutch)","Australia National Pollutant Inventory","Sigma-AldrichTransport

Information","Australia High Volume Industrial Chemical List (HVICL)","United Nations Recommendations on the Transport of Dangerous

Goods Model Regulations (Spanish)","OECD Existing Chemicals Database","Australia Dangerous Goods Code (ADG Code) - Dangerous

Goods List","Australia Hazardous Substances Information System - Consolidated Lists","International Air Transport Association (IATA)

Dangerous Goods Regulations","Australia Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP) - Appendix E (Part

2)","Australia - New South Wales Protection of the Environment Operations (Waste) Regulation 2005 - Characteristics of trackable wastes"

xylene(1330-20-7) is found on the



Goods Requirements (IMDG Code)","International Council of Chemical Associations (ICCA) - High Production Volume List","Australia

Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP) - Schedule 5","OSPAR List of Chemicals for Priority

Action","Australia Exposure Standards","International Maritime Dangerous Goods Requirements (IMDG Code) - SubstanceIndex","FisherTransport Information","IMO Provisional Categorization of Liquid Substances - List 3: (Trade-named) mixtures containing at least

99% by weight of components already assessed by IMO, presenting safety hazards","Australia FAISD Handbook - First Aid Instructions,

Warning Statements, and General Safety Precautions","United Nations Recommendations on the Transport of Dangerous Goods Model

Regulations (English)","Australia Dangerous Goods Code (ADG Code) - List of Emergency Action Codes","OECD List of High Production

Volume (HPV) Chemicals","Australia Inventory of Chemical Substances (AICS)","Australia Drinking Water Guideline Values For Physical and

Chemical Characteristics","International Agency for Research on Cancer (IARC) - Agents Classified by the IARC Monographs","Australia

Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP) - Appendix I","Belgium Federal Public Service Mobility and Transport,

Regulations concerning the International Carriage of Dangerous Goods by Rail - Table A: Dangerous Goods List - RID 2013

(Dutch)","UNECE - Kiev Protocol on Pollutant Release and Transfer Registers - Annex II","Australia National Pollutant Inventory","Australia -

Australian Capital Territory - Environment Protection Regulation: Pollutants entering waterways taken to cause environmental harm - Domestic

water supply quality","Australia High Volume Industrial Chemical List (HVICL)","WHO Guidelines for Drinking-water Quality - Guideline values

for chemicals that are of health significance in drinking-water","United Nations Recommendations on the Transport of Dangerous Goods Model

Regulations (Spanish)","OECD Existing Chemicals Database","GESAMP/EHS Composite List - GESAMP Hazard Profiles","Australia

Dangerous Goods Code (ADG Code) - Dangerous Goods List","International Air Transport Association (IATA) Dangerous Goods

Regulations","Australia Hazardous Substances Information System - Consolidated Lists","Australia Standard for the Uniform Scheduling of

Medicines and Poisons (SUSMP) - Appendix E (Part 2)","Australia - Australian Capital Territory - Environment Protection Regulation: Ambient

environmental standards (Domestic water supply - organic compounds)","IMO IBC Code Chapter 17: Summary of minimumrequirements","Australia Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP) - Schedule 7","International Fragrance

Association (IFRA) Survey: Transparency List","Australia Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP) - Schedule

6"


Other information







This document is copyright. Apart from any fair dealing for the purposes of private study, research, review or criticism, as permitted under the Copyright Act, no part may be reproduced by anyprocess without written permission from CHEMWATCH. TEL (+61 3) 9572 4700.

Chemwatch:5141-59

Version No: 8.1.1.1

Page 8 of8

Chockfast Red Resin



end of SDS


17/23


Chockfast Red Aggregate

Chemwatch: 5141-61

Version No: 8.1.1.1





S.GHS.AUS.EN


Product Identifier

Product name Chockfast Red Aggregate


Proper shipping name Not Applicable





Relevant identified uses Mixed with Chockfast resin and hardener to form epoxy grouting compound..




Australia

Telephone +61 2 9757 8800

Fax +61 2 9757 3855


Email Not Available



Emergency telephone numbers 1800 039 008Other emergency telephone numbers +61 3 9573 3112



1800 039 008 +612 9186 1132 Not Available




HAZARDOUS CHEMICAL. NON-DANGEROUS GOODS. According to the Model WHS Regulations and the ADG Code.

Poisons Schedule Not Applicable

GHS Classification[1] STOT - RE Category 2


Label elements

GHS label elements

SIGNAL WORD WARNING

Hazard statement(s)

H373 May cause damage to organs through prolonged or repeated exposure

Continued...


18/23


P260 Do not breathe dust/fume/gas/mist/vapours/spray.


P314 Get medical advice/attention if you feel unwell.


Not Applicable




Substances


Mixtures


14808-60-7 60-90 silica crystalline - quartz

65997-17-3 1-20 glass, oxide

70657-70-4


19/23


Minor Spills


Avoid contact with skin and eyes.

Wear impervious gloves and safety glasses.

Use dry clean up procedures and avoid generating dust.

Major Spills



Control personal contact with the substance, by using protective equipment and dust respirator.

Prevent spillage from entering drains, sewers or water courses.




Safe handling

Limit all unnecessary personal contact.



Avoid contact with incompatible materials.

Other information


Keep containers securely sealed.


Store away from incompatible materials and foodstuff containers.


Suitable container Polyethylene or polypropylene container.

Check all containers are clearly labelled and free from leaks.

Storage incompatibility No known incompatibility with normal range of industrial materials


Not Available


Control parameters


INGREDIENT DATA


Australia Exposure Standardssilica crystalline -

quartz

Quartz (respirable dust) / Silica -

Crystalline Quartz (respirable dust)

0.1

mg/m3

Not

Available

Not

Available

(see Silica - Crystalline) /

(see Chapter 14)

EMERGENCY LIMITS


silica crystalline - quartz 0.3 ppm 0.3 ppm 0.3 ppm 50 ppm

glass, oxide 5 ppm 15 ppm 60 ppm 500 ppm


silica crystalline - quartz N.E. mg/m3N.E. ppm 50 mg/m3

glass, oxide Not Available Not Available

propylene glycol monomethyl ether acetate,

beta-isomer Not Available Not Available

hydrotreated distillate, light Not Available Not Available

polyether modified methalkyl polysiloxane

copolymer Not Available Not Available

Exposure controls


Engineering controls are used to remove a hazard or place a barrier between the worker and the hazard. Well-designed engineering controls

can be highly effective in protecting workers and will typically be independent of worker interactions to provide this high level of protection.

The basic types of engineering controls are:

Process controls which involve changing the way a job activity or process is done to reduce the risk.

Enclosure and/or isolation of emission source which keeps a selected hazard "physically" away from the worker and ventilation that strategically"adds" and "removes" air in the work environment.

Personal protection

Chemwatch:5141-61

Version No: 8.1.1.1

Page 3 of7




Continued...


20/23


· Safety glasses with side shields; or as required,



wearing of lenses or restrictions on use, should be created for each workplace or task. This should include a review of lens absorption and

adsorption for the class of chemicals in use and an account of injury experience.



Experience indicates that the following polymers are suitable as glove materials for protection against undissolved, dry solids, where abrasive

particles are not present.polychloroprene.

nitrile rubber.

butyl rubber.


Other protection

Overalls.

P.V.C. apron.

Barrier cream.






The effect(s) of the following substance(s) are taken into account in the computer- generated selection:

Chockfast Red Aggregate Not Available

Material CPI


A: Best Selection









Type AX-P Filter of sufficient capacity. (AS/NZS 1716 & 1715, EN 143:2000 & 149:2001, ANSI

Z88 or national equivalent)

Required

Minimum

Protection Factor

Half-Face

Respirator

Full-Face

Respirator

Powered Air

Respirator

up to 10 x ES AX P1

Air-line*

-

-

AX PAPR-P1

-

up to 50 x ES Air-line** AX P2 AX PAPR-P2

up to 100 x ES - AX P3 -

Air- line* -

100+ x ES - Air-line** AX PAPR-P3

* - Negative pressure demand ** - Continuous flow

A(All classes) = Organic vapours, B AUS or B1 = Acid gasses, B2 =

Acid gas or hydrogen cyanide(HCN), B3 = Acid gas or hydrogencyanide(HCN), E = Sulfur dioxide(SO2), G = Agricultural chemicals,



65 degC)



Appearance Red coloured sand granules with no odour; insoluble in water. Slightly wetted to inhibit dusting.

Physical state Divided Solid Relative density (Water = 1) 2.57

Odour Not Available Partition coefficient n-octanol / water Not AvailableOdour threshold Not Available Auto-ignition temperature (°C) Not Applicable

pH (as supplied) Not Applicable Decomposition temperature Not Available

Melting point / freezing point (°C) 1710 Viscosity (cSt) Not Applicable


(°C)2330 Molecular weight (g/mol) Not Applicable

Flash point (°C) Not Available Taste Not Available

Evaporation rate Not Applicable Explosive properties Not Available

Flammability Not Available Oxidising properties Not Available

Upper Explosive Limit (%) Not Applicable Surface Tension (dyn/cm or mN/m) Not Available

Lower Explosive Limit (%) Not Applicable Volatile Component (%vol) Not Applicable

Vapour pressure (kPa) Not Applicable Gas group Not Available

Solubility in water (g/L) Immiscible pH as a solution(1%) 7 (5% slurry)

Vapour density (Air = 1) Not Applicable VOC g/L Not Available



Chemical stability Product is considered stable and hazardous polymerisation will not occur.

Chemwatch:5141-61

Version No: 8.1.1.1

Page 4 of7




Continued...


21/23







Inhaled

Limited evidence or practical experience suggests that the material may produce irritation of the respiratory system, in a significant number of

individuals, following inhalation. In contrast to most organs, the lung is able to respond to a chemical insult by first removing or neutralising the

irritant and then repairing the damage. The repair process, which initially evolved to protect mammalian lungs from foreign matter and antigens,

may however, produce further lung damage resulting in the impairment of gas exchange, the primary function of the lungs. Respiratory tract

irritation often results in an inflammatory response involving the recruitment and activation of many cell types, mainly derived from the vascular

system.

Ingestion

The material has NOT been classified by EC Directives or other classification systems as "harmful by ingestion". This is because of the lack of

corroborating animal or human evidence. The material may still be damaging to the health of the individual, following ingestion, especially where

pre-existing organ (e.g liver, kidney) damage is evident. Present definitions of harmful or toxic substances are generally based on doses

producing mortality rather than those producing morbidity (disease, ill-health).

Skin Contact

Limited evidence exists, or practical experience predicts, that the material either produces inflammation of the skin in a substantial number of

individuals following direct contact, and/or produces significant inflammation when applied to the healthy intact skin of animals, for up to four

hours, such inflammation being present twenty-four hours or more after the end of the exposure period. Skin irritation may also be present after prolonged or repeated exposure; this may result in a form of contact dermatitis (nonallergic). The dermatitis is often characterised by skin

redness (erythema) and swelling (oedema) which may progress to blistering (vesiculation), scaling and thickening of the epidermis. At the

microscopic level there may be intercellular oedema of the spongy layer of the skin (spongiosis) and intracellular oedema of the epidermis.

Eye

Limited evidence exists, or practical experience suggests, that the material may cause eye irritation in a substantial number of individuals and/or

is expected to produce significant ocular lesions which are present twenty-four hours or more after instillation into the eye(s) of experimental

animals. Repeated or prolonged eye contact may cause inflammation characterised by temporary redness (similar to windburn) of the conjunctiva

(conjunctivitis); temporary impairment of vision and/or other transient eye damage/ulceration may occur.

Chronic

Harmful: danger of serious damage to health by prolonged exposure through inhalation.

Serious damage (clear functional disturbance or morphological change which may have toxicological significance) is likely to be caused by

repeated or prolonged exposure. As a rule the material produces, or contains a substance which produces severe lesions. Such damage may

become apparent following direct application in subchronic (90 day) toxicity studies or following sub-acute (28 day) or chronic (two-year) toxicity

tests.


TOXICITY IRRITATION


silica crystalline - quartz

TOXICITY IRRITATION

Y


glass, oxideTOXICITY IRRITATION


propylene glycol monomethyl ether

acetate, beta-isomer

TOXICITY IRRITATION

Dermal (rabbit) LD50: >5000 mg/kg* [CCINFO]*

Inhalation (rat) LC50: 4345 ppm/6h



Not available. Refer to individual constituents.

SILICA CRYSTALLINE - QUARTZ

WARNING: For inhalation exposure ONLY: This substance has been classified by the IARC as Group 1: CARCINOGENIC TO HUMANS

The International Agency for Research on Cancer (IARC) has classified occupational exposures to respirable (


22/23

PROPYLENE GLYCOL MONOMETHYL

ETHER ACETATE, BETA-ISOMER

Asthma-like symptoms may continue for months or even years after exposure to the material ceases. This may be due to a non-allergenic

condition known as reactive airways dysfunction syndrome (RADS) which can occur following exposure to high levels of highly irritating

compound. Key criteria for the diagnosis of RADS include the absence of preceding respiratory disease, in a non-atopic individual, with

abrupt onset of persistent asthma-like symptoms within minutes to hours of a documented exposure to the irritant. A reversible airflow pattern,

on spirometry, with the presence of moderate to severe bronchial hyperreactivity on methacholine challenge testing and the lack of minimal

lymphocytic inflammation, without eosinophilia, have also been included in the criteria for diagnosis of RADS.

No data for material. Data for isomer only as its alpha isomer; propylene glycol monomethyl ether acetate:






CMR STATUS

Not Applicable


Toxicity

DO NOT discharge into sewer or waterways.







Mobility in soil

Ingredient Mobility






Consult State Land Waste Management Authority for disposal.

Bury residue in an authorised landfill.



Labels Required

Marine Pollutant NO

HAZCHEM Not Applicable

Land transport (ADG): NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS

Air transport (ICAO-IATA / DGR): NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS

Sea transport (IMDG-Code / GGVSee): NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS



silica crystalline - quartz(14808-60-7) is


"Australia Hazardous Substances Requiring Health Surveillance","Australia - Tasmania - Work Health and Safety Regulations 2012 -

Restricted hazardous chemicals","Australia Exposure Standards","Australia - Western Australia Hazardous Substances Requiring Health

Surveillance","Australia - Northern Territories Work Health and Safety National Uniform Legislation Regulations- Requirements for health

monitoring - Hazardous chemicals (other than lead) requiring health monitoring","FisherTransport Information","Australia - Tasmania

Hazardous Substances Requiring Health Surveillance","United Nations Consolidated List of Products Whose Consumption and/or Sale Have

Been Banned, Withdrawn, Severely Restricted or Not Approved by Governments","Australia - Northern Territories Work Health and Safety

National Uniform Legislation Regulat ions- Restricted hazardous chemicals","Australia - Tasmania Hazardous Substances Prohibited for

Chemwatch:5141-61

Version No: 8.1.1.1

Page 6 of7




Continued...


23/23

Specified Uses","OECD List of High Production Volume (HPV) Chemicals","Australia Inventory of Chemical Substances (AICS)","Australia -

Queensland Work Health and Safety Regulation - Restricted hazardous chemicals","Australia - South Australia - Work Health and Safety

Regulations 2012 - Restricted hazardous chemicals","Australia - Western Australia Hazardous Substances Prohibited for Specified Uses or

Methods of Handling","International Agency for Research on Cancer (IARC) - Agents Classified by the IARC Monographs","Australia

Occupational Health and Safety (Commonwealth Employment) (National Standards) Regulations 1994 - Hazardous Substances Requiring

Health Surveillance","Australia - South Australia - Work Health and Safety Regulations 2012 - Requirements for health monitoring - Hazardous

chemicals (other than lead) requiring health monitoring","Australia - Queensland Work Health and Safety Regulation - Hazardous chemicals

(other than lead) requiring health monitoring","Sigma-AldrichTransport Information","Australia - New South Wales - Work Health and Safety

Regulation 2011 - Requirements for health monitoring -Hazardous chemicals (other than lead) requiring health monitoring","Australia HighVolume Industrial Chemical List (HVICL)","Australia Work Health and Safety Regulations 2011 - Hazardous chemicals (other than lead)

requiring health monitoring","OECD Existing Chemicals Database","Australia - New South Wales - Work Health and Safety Regulation 2011

Restricted hazardous chemicals","Australia Hazardous Substances Information System - Consolidated Lists","Australia - New South Wales

Hazardous Substances Requiring Health Surveillance","Australia Work Health and Safety Regulations 2011 - Restricted hazardous

chemicals","Australia - Tasmania - Work Health and Safety Regulations 2012 - Requirements for Health Monitoring - Hazardous chemicals

(other than lead) requiring health monitoring","Australia - South Australia - Hazardous Substances Requiring Health Surveillance","Australia -

New South Wales Hazardous Substances Prohibited for Specific Uses"

glass, oxide(65997-17-3) is found on the


"FisherTransport Information","Australia Inventory of Chemical Substances (AICS)","OECD List of High Production Volume (HPV)

Chemicals","International Agency for Research on Cancer (IARC) - Agents Classified by the IARC Monographs","Sigma-AldrichTransport

Information","Australia Hazardous Substances Information System - Consolidated Lists"

propylene glycol monomethyl ether

acetate, beta-isomer(70657-70-4) is


"International Maritime Dangerous Goods Requirements (IMDG Code)","International Maritime Dangerous Goods Requirements (IMDG

Code) - Substance Index","United Nations Recommendations on the Transport of Dangerous Goods Model Regulations (English)","Australia

Dangerous Goods Code (ADG Code) - List of Emergency Action Codes","OECD List of High Production Volume (HPV) Chemicals","Australia

Inventory of Chemical Substances (AICS)","OSPAR National List of Candidates for Substitution – Norway","Belgium Federal Public Service

Mobility and Transport, Regulations concerning the International Carriage of Dangerous Goods by Rail - Table A: Dangerous Goods List - RID

2013 (Dutch)","International Chemical Secretariat (ChemSec) SIN List (*Substitute It Now!)","Australia National Pollutant Inventory","UnitedNations Recommendations on the Transport of Dangerous Goods Model Regulations (Spanish)","Australia Dangerous Goods Code (ADG

Code) - Dangerous Goods List","Australia Hazardous Substances Information System - Consolidated Lists","International Air Transport

Association (IATA) Dangerous Goods Regulations"


Other information







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Chemwatch:5141-61

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