chemistry of life 25-27feb2014
TRANSCRIPT
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the divine smell of theblack t ruf fle comesfrom this compound
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damascenone - the smell of roses
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F , C4H10, CH3(CH2)2CH3,
CH3CH2CH2CH3
C4H10
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3D
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F , :
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CH3
CH2
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G
1) D 120
2) M C
3) M H , CH
4) D ,
5) I ,
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(CH3CH2CN) (CH3CH2CH2NH2)
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I , 2
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(R)-(+)-limonenesmells of oranges
(S)-(-)-limonenesmells of lemons
(R)-(-)-carvonesmells of caraway seeds
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(S)-(+)-carvonesmells of spearmint
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A ()
A ( ) C=C ()
A CC ()
A (OH) (OH) ()
E (1O2) (O) ()
A (NH2) (NH2) ()
A (CHO) (1CO2)
(C=O) (/)
C (CO2H) (CO2H) ( )
A (CONH2, 1CONH2, 1CON23) ()
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N :
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MeO
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MeO
OMeHO
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MeO
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MeO
OMeO
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1. N-iodosuccinamide2. nBu3SnH
(71% yield)
16 17
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P 1971 H (
H)
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