chemistry 125: lecture 71 april 21, 2010 -h reactivity (ch. 19) a few topics in carbohydrate...
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Chemistry 125: Lecture 71April 21, 2010
-H Reactivity(Ch. 19)
A Few Topics in Carbohydrate Chemistry(Ch. 22)
Preliminary This
For copyright notice see final page of this file
-Alkylation Iketones/aldehydes (19.5a)
-143
-170
HOMO favors C
electrostatic potential favors O
-Alkylation Iketones/aldehydes (19.5a)
~ Random
Preform Kinetic Enolate
Controlled
-Alkylation Icarboxylic acids (19.5b)
-Alkylation II-dicarbonyls (19.5c)
-Alkylation IIDecarboxylation (19.5d)
malonic/acetoacetic ester syntheses of acids/ketones
Arndt-Eistert added one C to chain, malonic ester adds two.
The Aldol Condensation (sec 19.6)
The Aldol Condensation
(sec 19.6)
The Aldol Condensation
(sec 19.6)
Conjugate Addition (sec 19.6c)
Carbohydrates before Fischer (Ch. 22)
Heinrich Kiliani 22.3a
A.S. Couper (last semester)
Ring-Chain Tautomers (sec 22.2)
End of Lecture 71April 21, 2010
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