cheminform abstract: the reaction of cyclohexyl isocyanide and dimethyl acetylenedicarboxylate with...

2000 furan derivatives furan derivatives R 0060 38 - 110 The Reaction of Cyclohexyl Isocyanide and Dimethyl Acetylenedi- carboxylate with Aldehydes: A Novel Synthesis of 2-Aminofuran Derivatives. — A one-pot reaction of isocyanides (III) and DMAD (II) with aldehydes (I) or (V) leads to a facile synthesis of the title compounds (IV) and (VI) in good yields. The mechanism is discussed. — (NAIR, VIJAY; VINOD, A. U.; Chem. Commun. (Cambridge) (2000) 12, 1019-1020; Org. Chem. Div., Reg. Res. Lab., CSIR, Trivandrum 695 019, Kerala, India; EN) 1

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Page 1: ChemInform Abstract: The Reaction of Cyclohexyl Isocyanide and Dimethyl Acetylenedicarboxylate with Aldehydes: A Novel Synthesis of 2-Aminofuran Derivatives

2000 furan derivatives

furan derivativesR 0060

38 - 110The Reaction of Cyclohexyl Isocyanide and Dimethyl Acetylenedi-carboxylate with Aldehydes: A Novel Synthesis of 2-AminofuranDerivatives. — A one-pot reaction of isocyanides (III) and DMAD (II)with aldehydes (I) or (V) leads to a facile synthesis of the title compounds (IV)and (VI) in good yields. The mechanism is discussed. — (NAIR, VIJAY;VINOD, A. U.; Chem. Commun. (Cambridge) (2000) 12, 1019-1020; Org.Chem. Div., Reg. Res. Lab., CSIR, Trivandrum 695 019, Kerala, India; EN)

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