cheminform abstract: silyl-substituted carbocations

1

1999 organic chemistry, review organic chemistry, review Z 0200 17 - 339 Silyl-Substituted Carbocations — [170 refs.]. — (SIEHL, HANS- ULLRICH; MULLER, THOMAS; Chem. Org. Silicon Compd. 2 (1998) PT.1, 595-701; Abt. Org. Chem., Univ. Ulm, D-89081 Ulm, Germany; EN) 1

Upload: hans-ullrich-siehl

Post on 06-Jun-2016

217 views

Category:

Documents

1 download

Report

Download

Embed Size (px):

TRANSCRIPT

Page 1: ChemInform Abstract: Silyl-Substituted Carbocations

1999 organic chemistry, review

organic chemistry, reviewZ 0200

17 - 339Silyl-Substituted Carbocations — [170 refs.]. — (SIEHL, HANS-ULLRICH; MULLER, THOMAS; Chem. Org. Silicon Compd. 2 (1998) PT.1,595-701; Abt. Org. Chem., Univ. Ulm, D-89081 Ulm, Germany; EN)

1

MY SEARCH FOR CARBOCATIONS AND THEIR ROLE IN … · MY SEARCH FOR CARBOCATIONS AND THEIR ROLE IN CHEMISTRY Nobel Lecture, December 8, 1994 by GEORGE A. OL A H Loker Hydrocarbon Research

Fluoride ion induced stereoselective functionalization of ... · Fluoride ion induced stereoselective functionalization of heterosubstituted silyl derivatives Dipartimento di Chimica

Non Classical Carbocations

A Highly Diastereoselective ‘Super Silyl’ Governed …...A Highly Diastereoselective ‘Super Silyl’ Governed Aldol Reaction: Synthesis of α,β-Dioxyaldehydes and 1,2,3-Triols

RESEARCHARTICLE LargescalecomparisonofQSAR … · 2020. 3. 19. · Boscet al. J Cheminform Page3of16 Dta preparation Compoundstructureswereextractedfromthedatabase inSMILESformatandusingRDKit(version2017_09_01)

I3C-'H Coupling Constants in Carbocations. 4.' Conformations of

Aryldisilane Photochemistry. The Role of Silyl Free ...wjl/leigh/publications/om_13_1005_1994.pdfOrganometallics 1994,13, 1005-1013 1005 Aryldisilane Photochemistry. The Role of Silyl

Alkyl-4-silyl-phenols and esters thereof as antiatherosclerotic agents

Lanthanide alkyl and silyl compounds: synthesis

Silyl effusion from plasma-produced silicon nanocrystals · Silyl effusion from plasma-produced silicon nanocrystals ... corresponding to changes in the Si-Hx bonds at ... passivation

Electrophilic oligodeoxynucleotide synthesis using dM-Dmoc ...chem.sites.mtu.edu/.../uploads/...Oligo-synthesis.pdfScheme 3: Synthesis of ester-containing phosphoramidite 26a. silyl

THE ALLYLIC AMINATION OF SILYL ENOL ETHERS USING N, N …

ElEctrochEmistry 2014 - WittstockSolid State Electrochemistry – From the macro- to the Nanoscale Seji Suga, okayama/JP Electrochemically Generated Carbocations for Stereoselective

RESEARCHARTICLE OpAccess ......Jiangiet al. J Cheminform Pagej2jofj26 playerindrugabsorption,distribution,metabolism, excretion,andtoxicity(ADMET)[5, 6],andhasalsobeen

Reaction of the Si O (SnMe Building Block with Silyl ......Reaction of the Si8O20(SnMe3)8 Building Block with Silyl Chlorides: A New Synthetic Methodology for Preparing Nanostructured

Silyl Radical Activation of Alkyl Halides in ...chemlabs.princeton.edu/macmillan/wp-content/... · Silyl Radical Activation of Alkyl Halides in Metallaphotoredox Catalysis: A Unique

Hydrogenation of Silyl Formate: Sustainable Production of ... · Hydrogenation of Silyl Formate: Sustainable Production of Silanol and Methanol from Silane and Carbon Dioxide Jangwoo

ChemInform Sheet A4 · 2013. 9. 13. · The ChemInform Reaction Library (CIRX) helps to deal with the enormous number of published reactions as it does not cover all information available

Science of Synthesis KnowledgeUpdates 2020/3...4.4.28.17.9 Synthesis of a-Silyl Amines from Silylmethyl Azides ..... 37 4.4.28.17.9.1 Method 1: a -Silyl Amines by Ruthenium-Catalyzed

Enantioselective,SilylProtectionof, Dioldonohoe.chem.ox.ac.uk/resources/051113LitXuezheng.pdfBackground How to achieve enantioselective silyl protection？ • Modified guanidines

3 Factors That Stabilize Carbocations

ChemInform RxnFinder

7 Structure, Liaisons et Stabilité des Carbocations 1 Copyright© 2005, Dominique BLONDEAU All rights reserved

NHC Cu(I) Catalyzed Asymmetric Conjugate Silyl transfer … · S1 NHC–Cu(I) Catalyzed Asymmetric Conjugate Silyl transfer to Unsaturated Lactones: Application in Kinetic Resolution

MECHANISTIC STUDIES OF THE SILYL-HECK REACTION

Catalytic asymmetric addition of thiols to silyl

Synthesis of 2-Alkyl Chromane-4-ones Using Hydrogen Bond ......Silyl Ketene Acetals Silyl ketene acetals are attractive nucleophiles for reaction with benzopyryliuim triflates in the

Lecture 7. Rearrangement Involving Carbocations Qn: Why is rearrangement quite common to carbocations, and not in case of radicals or anions? Formation

SILYL KETONE CHEMISTRY ...949... · SILYL KETONE CHEMISTRY ... NH and CH groups; (2) as activating and ... and Roman.‘3b Compound 18 was prepared from 2-

Selected Ion Infrared Spectroscopy of Carbocations

RESEARCHARTICLE Assessingtheinformationcontent ......Rodríguez‑Pérezet al. J Cheminform Page6of14 whichyieldedmedianMCCvaluesof0.67(IFP_85) and0.63(EFCP_folded).us,inhibitorswithbinding

Silyl Ketone Chemistry. Preparation and Reactions of Silyl ...€¦ · J. Am. Chem. SOC. 1986, 108, 7791-7800 7791 pyrany1oxy)dodecanoic acid, 1.38 1 g (3.15 mmol) of GPC-CdCIz, 0.854

Alcohols. Tetrahydropyranyl Ethers to Silyl-protected One ... · One-step Chemoselective Conversion of Tetrahydropyranyl Ethers to Silyl-protected Alcohols. Julian Bergueiro, Javier

Chiral Carbocations as Lewis Acid Catalysts in Diels-Alder

Coordination-Induced Stereocontrol over Carbocations