cheminform abstract: rapid microwave induced palladium catalyzed amination of aryl bromides

2002 amines amines (benzene compounds) Q 0120 25 - 075 Rapid Microwave Induced Palladium Catalyzed Amination of Aryl Bromides. — Palladium-catalyzed coupling between aryl bromides (I), (IV), and (VI) and primary or secondary amines (II) readily occurs under microwave irradiation without employing inert conditions. Thus, the reaction time is shortened from hours to a few minutes. Some palladium catalysts are examined for the amination reaction. However, only PdCl 2 (P(o-tolyl) 3 ) 2 serves as an eﬀective palladium source. — (SHARIFI, ALI; HOSSEINZADEH, RAHMAN; MIRZAEI, MOJTABA; Monatsh. Chem. 133 (2002) 3, 329-332; Chem. Chem. Eng. Res. Cent., Tehran, Iran; EN) 1

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Page 1: ChemInform Abstract: Rapid Microwave Induced Palladium Catalyzed Amination of Aryl Bromides

2002 amines

amines (benzene compounds)Q 0120

25 - 075Rapid Microwave Induced Palladium Catalyzed Amination of ArylBromides. — Palladium-catalyzed coupling between aryl bromides (I),(IV), and (VI) and primary or secondary amines (II) readily occurs undermicrowave irradiation without employing inert conditions. Thus, the reactiontime is shortened from hours to a few minutes. Some palladium catalystsare examined for the amination reaction. However, only PdCl2(P(o-tolyl)3)2serves as an effective palladium source. — (SHARIFI, ALI; HOSSEINZADEH,RAHMAN; MIRZAEI, MOJTABA; Monatsh. Chem. 133 (2002) 3, 329-332;Chem. Chem. Eng. Res. Cent., Tehran, Iran; EN)

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