cheminform abstract: planar-chiral cyclopalladated ferrocenyl amines and imines as enantioselective...
TRANSCRIPT
1999 carboxylic amides
carboxylic amides (benzene compounds)Q 0490
10 - 096Planar-Chiral Cyclopalladated Ferrocenyl Amines and Imines asEnantioselective Catalysts for Allylic Imidate Rearrangements. —Enantiopure cyclopalladated amines and imines are synthesized from chiral ferro-cenyl aldehydes. They are investigated as catalysts for the [3,3]-rearrangementsof allylic benzimidates (II) to allylic benzamides. Enantioselectivities up to73% can be obtained. — (COHEN, FREDERICK; OVERMAN, LARRY E.;Tetrahedron: Asymmetry 9 (1998) 18, 3213-3222; Dep. Chem., Univ. Calif.,Irvine, CA 92717, USA; EN)
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