cheminform abstract: asymmetric synthesis of allylic sulfides via palladium-mediated allylation of...

1999 stereochemistry stereochemistry (general, optical resolution) O 0030 12 - 031 Asymmetric Synthesis of Allylic Sulfides via Palladium-Mediated Allylation of Thiols. — An asymmetric synthesis of allylic sulfides mediated by a complex generated in situ from Pd 2 (dba) 3 ·CHCl 3 and the Trost ligand (BPC) is presented. It continues recently published studies on palladium- mediated enantioselective sulfide formations. — (FRANK, MICHAEL; GAIS, HANS-JOACHIM; Tetrahedron: Asymmetry 9 (1998) 19, 3353-3357; Inst. Org. Chem., RWTH Aachen, D-52074 Aachen, Germany; EN) 1

Upload: michael-frank

Post on 06-Jun-2016

214 views

Category:

Documents

0 download

Report

Download

Embed Size (px):

TRANSCRIPT

Page 1: ChemInform Abstract: Asymmetric Synthesis of Allylic Sulfides via Palladium-Mediated Allylation of Thiols

1999 stereochemistry

stereochemistry (general, optical resolution)O 0030

12 - 031Asymmetric Synthesis of Allylic Sulfides via Palladium-MediatedAllylation of Thiols. — An asymmetric synthesis of allylic sulfidesmediated by a complex generated in situ from Pd2(dba)3·CHCl3 and the Trostligand (BPC) is presented. It continues recently published studies on palladium-mediated enantioselective sulfide formations. — (FRANK, MICHAEL; GAIS,HANS-JOACHIM; Tetrahedron: Asymmetry 9 (1998) 19, 3353-3357; Inst. Org.Chem., RWTH Aachen, D-52074 Aachen, Germany; EN)

Conjugated Unsaturated Systems 46 Chapter 13 allylic substitution & allylic radicals allylic bromination sabitility of allylic radicals allylic cations

Stereoselective Allylation of Imines

Synthesis of functionalized allylic, propargylic and allenylic

Radical C(sp3)-H Alkenylation, Alkynylation and Allylation of … · 2017-04-19 · Radical C(sp3)-H Alkenylation, Alkynylation and Allylation of Ethers and Amides Enabled by Photocatalysis

Rhodium(III)-Catalyzed Direct C-H Allylation of Electron ... Rhodium(III)-Catalyzed Direct C-H Allylation of Electron-Deficient Alkenes with Allyl Acetates Chao Feng, Daming Feng and

Stereospecific Allylic Functionalization: The Reactions of

Conjugation in Alkadienes and Allylic Systems

Conjugate Additions and Transposition of the Allylic

New Approaches towards the Asymmetric Allylation of the ... · Figure 1-4: The Hosomi-Sakurai Reaction 13 Chapter 2 Figure 2-1: ... Scheme 1-17: Asymmetric Allylation of Chiral Aldehydes

Asymmetric Transition Metal-Catalyzed Allylic Alkylations...Asymmetric Transition Metal-Catalyzed Allylic Alkylations Barry M. Trost* Department of Chemistry, Stanford University,

The allylic chalcogen effect in olefin metathesis

ChemInform RxnFinder