cheminform abstract: albumin-controlled stereoselective reduction of 1,3-diketones to anti-diols
TRANSCRIPT
2002 alcohols
alcohols (benzene compounds)Q 0230
29 - 113Albumin-Controlled Stereoselective Reduction of 1,3-Diketones toanti-Diols. — An unprecedented combination of high chemo- and stere-oselectivity in the NaBH4 reduction of 1:1 complexes between albumin andaromatic 1,3-diketones (I) results in the formation of anti-1,3-diols with up to96% d.e.. — (BENEDETTI, FABIO; BERTI, FEDERICO; DONATI, IVAN;FREGONESE, MASSSIMO; Chem. Commun. (Cambridge) (2002) 8, 828-829;Dip. Sci. Chim., Univ. Trieste, I-34127 Trieste, Italy; EN)
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