chemical stratification and differentiation

46
fluid, 90% iron solidified iron 2000 4000 km 6000 8000 10,000 12,000 Mg(Fe) silicates phase changes basaltic-granitic crust chemical stratification and differentiation

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chemical stratification and differentiation. basaltic-granitic crust. phase changes. Mg(Fe) silicates. fluid, 90% iron. solidified iron. 2000. 4000 km. 6000. 8000. 10,000. 12,000. Structure of Earth as imaged by seismic waves. crust. upper mantle. transition zone. lower mantle. - PowerPoint PPT Presentation

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Page 1: chemical stratification and differentiation

fluid, 90% iron

solidified iron

2000 4000 km 6000 8000 10,000 12,000

Mg(Fe) silicates

phase changes

basaltic-granitic crust

chemical stratification and differentiation

Page 2: chemical stratification and differentiation

upper mantle

outer core

inner core

D”, core-mantle boundary layer

2000 4000 km 6000 8000 10,000 12,000

lower mantle

core-mantle boundary

transition zone

crust

Structure of Earth as imaged by seismic waves

radius of earth = 6371 km

Page 3: chemical stratification and differentiation

Seismic waves involve stress, strain, and density

Two important types of stresses and strains:

Pressure, P and volume change per unit volume, V/V

Shear stress and shear strain

Page 4: chemical stratification and differentiation

For linear elasticity, Hooke’s law applies:

stress = elastic_constant x strain

Page 5: chemical stratification and differentiation

For elastic waves, two elastic constants are key:

And density of the material,

= mass/volume

Page 6: chemical stratification and differentiation

Two types of elastic waves

Compressional or P waves involve volume change and shear

Shear or S waves involve only shear

P wave particle motions

S wave particle motions

Click on these links to see particle motions:

Page 7: chemical stratification and differentiation

Elastic wave velocities determined by material properties

43

p

s

V

V

P wave velocity

S wave velocity

Page 8: chemical stratification and differentiation

epicenter

expanding wavefront at some instant of time after earthquake occurrence

ray perpendicular to wavefront

seismograph station

Earth surface

Earthcenter

Page 9: chemical stratification and differentiation

epicenter

ray

seismograph station

= epicentral distance in degrees

Earth surface

Earthcenter

tt() = total travel time along ray from earthquake to station

Page 10: chemical stratification and differentiation

Globally recorded earthquakes during the past 40 years

earthquake depth 0-33 km 33-70 70-300 300-700

Page 11: chemical stratification and differentiation

Partial map of modern global seismograph network

Page 12: chemical stratification and differentiation

2,538,185 travel time observations from International Seismological Centre (ISC), for earthquakes with depths between “0” and 60 km.

These are the commonly reported phases as reported to the ISC from seismograph stations from around the world; see phase types on next page

distance, degrees

tim

e, m

inu

tes

Page 13: chemical stratification and differentiation

These lines represent plus or minus one minute errors in reading arrival times

P

diffracted P

PKIKP

PKP

PcP

PP

PPP

ScS

SKS

S

PcS

SS

SSS

PS

PPSPKPPKP

PKKP

PKS

SKKS

PPP

surf

ace w

aves

wat

er w

aves

click on link to P and S phases in the earth

Page 14: chemical stratification and differentiation

Nomenclature for seismic body phases

c = reflection at core mantle boundary

K

P or S

I or Ji = reflection at inner core-outer core boundary

P wave segments in blueS wave segments in red

inner core

outer core

mantle

Page 15: chemical stratification and differentiation

PS

Mantle

Inner core

Outer core

Single path refracted through mantle

seismic wave source

Page 16: chemical stratification and differentiation

2,538,185 travel time observations from International Seismological Centre (ISC), for earthquakes with depths between “0” and 60 km.

These are the commonly reported phases as reported to the ISC from seismograph stations from around the world; see phase types on next page

distance, degrees

tim

e, m

inu

tes

P

S

P diffracted around core

Page 17: chemical stratification and differentiation

PP

SS

Mantle

Outer core

Single reflection at surface

Inner core

Page 18: chemical stratification and differentiation

2,538,185 travel time observations from International Seismological Centre (ISC), for earthquakes with depths between “0” and 60 km.

These are the commonly reported phases as reported to the ISC from seismograph stations from around the world; see phase types on next page

distance, degrees

tim

e, m

inu

tes

PP

SS

Page 19: chemical stratification and differentiation

PcP

Single reflection at core-mantle boundary

reflection

Page 20: chemical stratification and differentiation

ScS

Single reflection at core-mantle boundary

Page 21: chemical stratification and differentiation

PcS

Single reflection with conversion of P to S

Page 22: chemical stratification and differentiation

2,538,185 travel time observations from International Seismological Centre (ISC), for earthquakes with depths between “0” and 60 km.

These are the commonly reported phases as reported to the ISC from seismograph stations from around the world; see phase types on next page

distance, degrees

tim

e, m

inu

tes

PcP

ScS

PcS

Page 23: chemical stratification and differentiation

PKP

P in mantle, refracting to P in the outer core (K) and out through the mantle as P

PK

P

Page 24: chemical stratification and differentiation

PKIKP

P segments in mantle, P segments in outer core (K), and P segment in inner core (I)

P

KPK

I

Page 25: chemical stratification and differentiation

2,538,185 travel time observations from International Seismological Centre (ISC), for earthquakes with depths between “0” and 60 km.

These are the commonly reported phases as reported to the ISC from seismograph stations from around the world; see phase types on next page

distance, degrees

tim

e, m

inu

tes

PKIKP

PKP

Page 26: chemical stratification and differentiation

SKSS in mantle, refracting and converting to P in outer core,

then refracting back out and

converting back to S in the

mantle

S

KS

Page 27: chemical stratification and differentiation

SKKS

S in mantle, refracting and converting to P in outer core, P reflects once at

inner side of core-mantle

boundary, then refracting back out back with

conversion to S in the mantle

S

KS

Kreflection

Page 28: chemical stratification and differentiation

2,538,185 travel time observations from International Seismological Centre (ISC), for earthquakes with depths between “0” and 60 km.

These are the commonly reported phases as reported to the ISC from seismograph stations from around the world; see phase types on next page

distance, degrees

tim

e, m

inu

tes

SKS

S

SKKS

Page 29: chemical stratification and differentiation

outer core

inner core

lower mantle

upper mantlekm/sec

km

transition zone

D’’ layer

0

1000

2000

3000

4000

5000

6000

7000

0 1 2 3 4 5 6 7 8 9 10 11 12 13 14

dep

th

seismic wave velocity

Compressional (P) and Shear (S) wave velocities, Vp and Vs

Page 30: chemical stratification and differentiation

outer core

inner core

lower mantle

upper mantlekm/sec

km

transition zone

D’’ layer

0

1000

2000

3000

4000

5000

6000

7000

0 1 2 3 4 5 6 7 8 9 10 11 12 13 14

dep

th

seismic wave velocity

Compressional (P) and Shear (S) wave velocities, Vp and Vs

No Shear waves in outer core!

Page 31: chemical stratification and differentiation

43

p

s

V

V

modulus of incompressibility/

shear stressmodulus of rigidity

shear straindensity

(R) = "seismic parameter" derived from Vp(R) and Vs(R)

P

V V

2 24( )

3p sV V R

From Vp and Vs to seismic parameter

Page 32: chemical stratification and differentiation

For self compression of homogeneous material

(R) = /

= - dP/(dV/V) = dP/(d/)

dP = - g dR

where R = radius to a point in the earth, andg = gravitational acceleration at that radiusg = GMR/R2

where MR = mass within sphere of radius R

d/dR = -/g

Page 33: chemical stratification and differentiation

For self compression of homogeneous material

d/dR = -/g

This is the gradient in density determined by the seismic wave velocities. To obtain density, one must integrate by fixing the density, , and gravity, g, at the top of the layer and calculating both and g as one proceeds downwards.

The calculation assumes

a simple compression of material that does not change chemistry or phase.

the compression as one goes deeper produces an adiabatic temperature increase.

Page 34: chemical stratification and differentiation

For self compression of homogeneous material

d/dR = -/g

The method is applied to the following layers:upper mantlelower mantleouter coreinner core

To determine the jumps in density between these layers, the following constraints are used:

Mass of earthMoment of Inertia of EarthPeriods of free oscillations of Earth

Page 35: chemical stratification and differentiation

Density,

0

1000

2000

3000

4000

5000

6000

0 2000 4000 6000 8000 10000 12000 14000

core-mantle boundary

kg/m3

km

dep

th, k

m

Page 36: chemical stratification and differentiation

Gravitational acceleration, g

0

1000

2000

3000

4000

5000

6000

0 2 4 6 8 10 12

core-mantle boundary

km

m/s2

dep

th, k

m

Page 37: chemical stratification and differentiation

Pressure, P

core-mantle boundary

GPa.

km

0

1000

2000

3000

4000

5000

6000

0 50 100 150 200 250 300 350 400

dep

th, k

m

Page 38: chemical stratification and differentiation

Density vrs pressure

0

2000

4000

6000

8000

10000

12000

14000

0 50 100 150 200 250 300 350 400GPa.

kg/m3

Page 39: chemical stratification and differentiation

Density vrs pressure

0

2000

4000

6000

8000

10000

12000

14000

0 50 100 150 200 250 300 350 400GPa.

kg/m3

compression

compression

com

pos

itio

n

chan

ge

ph

ase

chan

ges liq

uid

to

solid

mantle density

crustal density

core-mantle boundary

Inner core/outer core boundary

1 mbar

Page 40: chemical stratification and differentiation

fluid, 90% iron

solidified iron

2000 4000 km 6000 8000 10,000 12,000

Mg(Fe) silicates

phase changes

basaltic-granitic crust

Chemical stratification

Page 41: chemical stratification and differentiation

upper mantle “Peridotite”:

65% olivine: (Mg,Fe)2SiO4

25% orthopyroxene (Mg,Fe)2Si2O6

10% clinopyroxene (Ca,Mg,Fe)2Si2O6

+ garnet (Mg,Fe)3AL2Si3O12

phase changes through transition zonelower mantle

85% Perovskite: (Mg0.9Fe0.1)SiO3

15% magnesiowustite (Mg0.9Fe0.1)O

+ Ca Perovskite ( Ca, Mg, Fe )SiO3

+ Corundum Al2O3outer core

90% Fe (Ni)

10% lighter alloy (FeO, S, Si, ?)

inner core

solid Fe + ?

oceanic crust continental crustMOHO

CMB

Page 42: chemical stratification and differentiation

upper mantle

lower mantle

transition zone

outer coreCMB

D”

0 2000 4000 500030001000Temperature, degrees C

iron melting

Ad

iabatic g

radien

t

near surface thermal boundary layer = lithosphere

D” = Lower mantle thermo-chemical boundary layer

mantle convectionadvective heat flow

conductive heat flow

conductive heat flow

Temperature in mantle

?

man

tle meltin

g

Page 43: chemical stratification and differentiation

Temperature profile through

entire earth

Page 44: chemical stratification and differentiation

cool, strong lithospheric boundary layer

slowly convecting mantle:plate tectonic engine

rapidly convectingouter core:

geomagnetic dynamo

solid inner core

subd

uctio

n

seafloor spreading

core-mantle thermo-chemical boundary layer

2000 4000 km 6000 8000 10,000 12,000

crust

Earth’s convective systems

Page 45: chemical stratification and differentiation

inner core

mantle

The geomagnetic dynamo:• turbulent fluid convection• electrically conducting fluid• fluid flow-electromagnetic interactions• effects of rotation of earth

Generation of Earth’s magnetic field in the outer core

outer core

Page 46: chemical stratification and differentiation

Geomagnetic field