chem 2411 review what did you learn in organic chemistry i?
TRANSCRIPT
CHEM 2411 Review
What did you learn in What did you learn in Organic Chemistry I?Organic Chemistry I?
Chapter/sections from Klein (2nd edition) you should already know:
• 1, 2, 3, 4, 5, 6, 7, 8, 10.2, 11.1-11.6, 13.1, 14.2, 14.11, 15.16, 18.2, 20.2, 21.2, 21.3, 21.6, 23.2
CHEM 2411 Review
Drawing structures• Lewis
• Condensed
• Line-angle
Functional groups• Alkane, alkene, alkyne, aromatic, alkyl halide, alcohol, ether, carbonyl,
aldehyde, ketone, carboxylic acid, acid chloride, ester, amide, acid anhydride, amine, nitrile, thiol
Nomenclature• For all functional groups listed above
Isomerism• Constitutional
• Stereoisomers
CHEM 2411 Review Topics
Structure• an bonds
• Bond strength
• Primary, secondary, tertiary carbons
• Bond and molecular polarity
Physical properties• Intermolecular forces
• BP
• Solubility
Hybridization• Atomic orbitals
• Hybrid orbitals
• Which orbitals are used in sigma bonds? Pi bonds?
CHEM 2411 Review Topics
Resonance• Resonance structures
• Which structures contribute to hybrid structure?
• Electron movement
Acids and bases • Brønsted-Lowry
• How to predict acid strength?
• Lewis
Alkane conformations• Staggered vs. eclipsed
• Torsional strain
• Steric strain
CHEM 2411 Review Topics
Cycloalkane conformations• Angle strain
• Cyclohexane chair vs. boat
Alkene stability• Cis or trans?
• More substituted or less substituted?
Stereochemistry• R and S
• Chiral center (stereocenter), enantiomers, diastereomers
• Meso compounds
• Racemic mixture
• Cis and trans
• E and Z
CHEM 2411 Review Topics
Mechanisms• Symmetrical/homolytic/radical
• Unsymmetrical/heterolytic/polar
• Nucleophile and electrophile
• Electron motion
• Energy diagrams
Reaction types• Addition
• Elimination
• Substitution
• Rearrangement
• Oxidation
• Reduction
CHEM 2411 Review Topics