chapter 6 – an introduction to spectrometric methodscoryw.people.cofc.edu/f10ch6.pdf · ·...
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Chapter 6 – An Introduction to Spectrometric Methods What makes a method Spectrometric? Brief review of Properties of Light Transmission: Diffraction: Coherent radiation: Incoherent radiation:
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Interference: Polychromatic interference: Refraction: Reflection: Scattering: Behavior of light waves:
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The Photoelectric Effect How Light Interacts with Matter:
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Energy States
Atomic: Molecular:
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In what ways can the interaction of light with matter be measured? Radiation
Frequency (Hz)
Wavelength
Transition
Non-Chemical Uses
Radio
< 3x1011
nuclear spin flips
Signal Transmission
MW
3x1011-1013
molecular rotations,
electron spin flips
Cooking
IR
1013-1014
molecular vibrations
Heating
VIS
4-7.5x1014
valence electron
Illumination
UV
1015-1017
valence electron
"Black" Lights
X-Ray
1017-1020
inner electron
Imaging
Gamma
1020-1024
nuclear
Cancer treatment
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Type
Radiant Power Measured
Concentration Relationship
Method
Emission
Emitted, Pe
Atomic Emission
Luminescence
Luminescent, PL
Atomic and molecular fluorescence, phosphorescence, chemiluminescence
Scattering
Scattered, Psc
Raman scattering, turbidimetry, and nephelometry
Absorption
Incident, Po & transmitted P
Atomic and molecular absorption
Homework: 6th edition, Chapter 6 #2-12, 14-19