chapter 11 atoms molecules and ions teacher s copy

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What is an atom? All matter is made up of atoms. An atom is defined as the smallest particle of an element that can exist.

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Chemistry Notes On Atoms, Molecules and Ions

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Page 1: Chapter 11 Atoms Molecules and Ions Teacher s Copy

What is an atom?What is an atom?

• All matter is made up of atoms.

• An atom is defined as the smallest particle of an element that can exist.

• All matter is made up of atoms.

• An atom is defined as the smallest particle of an element that can exist.

Page 2: Chapter 11 Atoms Molecules and Ions Teacher s Copy

How big is an atom?How big is an atom?

..

Contains about 1016 atoms!!!Contains about 1016 atoms!!!

2 million times more than humans in the world.

2 million times more than humans in the world.

Page 3: Chapter 11 Atoms Molecules and Ions Teacher s Copy

Why do we change models?Why do we change models?

• Old models are discarded or revised when they are found to be unsatisfactory in explaining certain phenomena.

• Models are continuously being revised as new evidence is gathered.

• Old models are discarded or revised when they are found to be unsatisfactory in explaining certain phenomena.

• Models are continuously being revised as new evidence is gathered.

Page 4: Chapter 11 Atoms Molecules and Ions Teacher s Copy

How big is an atom?How big is an atom?

• A scanning tunnelling microscope (STM) is used to observe atoms.

• Atoms have an average diameter of about 0.1nm.

• A scanning tunnelling microscope (STM) is used to observe atoms.

• Atoms have an average diameter of about 0.1nm.

Page 5: Chapter 11 Atoms Molecules and Ions Teacher s Copy

Use your imagination!Use your imagination!

1803, John Dalton1803, John Dalton In 1897, JJ ThomsonIn 1897, JJ Thomson

Page 6: Chapter 11 Atoms Molecules and Ions Teacher s Copy

Use your imagination!Use your imagination!

1911, Ernest Rutherford1911, Ernest Rutherford 1915, Niel Bohr1915, Niel Bohr

Page 7: Chapter 11 Atoms Molecules and Ions Teacher s Copy

Present your drawingPresent your drawing

Page 8: Chapter 11 Atoms Molecules and Ions Teacher s Copy

Development of the atomic modelDevelopment of the atomic model

2500 years ago,

Democritus:

“Matter is made up of

tiny individual

particles called atoms.”

2500 years ago,

Democritus:

“Matter is made up of

tiny individual

particles called atoms.”

Page 9: Chapter 11 Atoms Molecules and Ions Teacher s Copy

Development of the atomic modelDevelopment of the atomic modelIn 1803, John Dalton:

“ - All matter is made up of small indivisible particles called atoms” - Atoms of the same elements are alike - Different elements have different types of atoms - Atoms cannot be created, destroyed or changed - Compounds are formed when two or more elements combine”

In 1803, John Dalton:

“ - All matter is made up of small indivisible particles called atoms” - Atoms of the same elements are alike - Different elements have different types of atoms - Atoms cannot be created, destroyed or changed - Compounds are formed when two or more elements combine”

Page 10: Chapter 11 Atoms Molecules and Ions Teacher s Copy

Development of the atomic modelDevelopment of the atomic modelIn 1897, JJ Thomson:

“ - An atom is a continuous mass of positive charges containing negative charges called electrons. - The electrons are like the plums in a pudding of positive charges or raisins in a cake.”

In 1897, JJ Thomson:

“ - An atom is a continuous mass of positive charges containing negative charges called electrons. - The electrons are like the plums in a pudding of positive charges or raisins in a cake.”

Page 11: Chapter 11 Atoms Molecules and Ions Teacher s Copy

Development of the atomic modelDevelopment of the atomic modelIn 1911, Ernest Rutherford:

“ - An atom has a small, dense and positively charged nucleus in the centre, surrounded by negatively charged electrons circling around it, just like planets orbiting around the Sun. - Most of the atom is empty space.”

In 1911, Ernest Rutherford:

“ - An atom has a small, dense and positively charged nucleus in the centre, surrounded by negatively charged electrons circling around it, just like planets orbiting around the Sun. - Most of the atom is empty space.”

Page 12: Chapter 11 Atoms Molecules and Ions Teacher s Copy

Development of the atomic modelDevelopment of the atomic model

In 1915, Niel Bohr:“ - An atom has a small, dense nucleus made up of positively charged protons and electrically neutral neutrons. - The negatively charged electrons move around the nucleus in fixed orbits. - Only a certain number of electrons can be found in each orbit.”

In 1915, Niel Bohr:“ - An atom has a small, dense nucleus made up of positively charged protons and electrically neutral neutrons. - The negatively charged electrons move around the nucleus in fixed orbits. - Only a certain number of electrons can be found in each orbit.”

Page 13: Chapter 11 Atoms Molecules and Ions Teacher s Copy

Development of the atomic modelDevelopment of the atomic model

In 1926, Quantum Model of Atom:“ - Electrons do not move in fixed orbits. - They move around the nucleus in random paths. - Scientists can only predict the chance of finding the electrons in a particular region. - The regions where an electron is most likely to be found is called an orbital or electron density cloud.”

In 1926, Quantum Model of Atom:“ - Electrons do not move in fixed orbits. - They move around the nucleus in random paths. - Scientists can only predict the chance of finding the electrons in a particular region. - The regions where an electron is most likely to be found is called an orbital or electron density cloud.”

Page 15: Chapter 11 Atoms Molecules and Ions Teacher s Copy

Thomson’s modelThomson’s model

• Electrons distributed among a continuous mass of positive charges

• Electrons distributed among a continuous mass of positive charges

Page 16: Chapter 11 Atoms Molecules and Ions Teacher s Copy

Ernest Rutherford’s modelErnest Rutherford’s model

• Electrons orbiting around a small, dense positively charged nucleus

• Electrons orbiting around a small, dense positively charged nucleus

Page 17: Chapter 11 Atoms Molecules and Ions Teacher s Copy

Niel BohrNiel Bohr

• Electrons move round the nucleus in fixed orbits

• Electrons move round the nucleus in fixed orbits

Page 18: Chapter 11 Atoms Molecules and Ions Teacher s Copy

Quantum ModelQuantum Model

• Electrons move randomly and not in fixed orbits

• They are most likely to be found in the orbitals

• Electrons move randomly and not in fixed orbits

• They are most likely to be found in the orbitals

Page 19: Chapter 11 Atoms Molecules and Ions Teacher s Copy

What makes up an atom?What makes up an atom?

• An atom is the smallest particle of an element that can exist.

• The atom is made up of smaller particles called sub-atomic particles.

• An atom is the smallest particle of an element that can exist.

• The atom is made up of smaller particles called sub-atomic particles.

Page 20: Chapter 11 Atoms Molecules and Ions Teacher s Copy

Subatomic particlesSubatomic particles

Proton (+1) mass =1

Electron ( -1) mass = 1/1840

Neutron ( 0 ) mass= 1

Proton (+1) mass =1

Electron ( -1) mass = 1/1840

Neutron ( 0 ) mass= 1

Page 21: Chapter 11 Atoms Molecules and Ions Teacher s Copy

Is an atom charged?Is an atom charged?

• There are equal numbers of protons and electrons in an atom.

• An atom is an electrically neutral entity made up of a positively charged nucleus (protons and neutrons) with negatively charged electrons moving round the nucleus.

• There are equal numbers of protons and electrons in an atom.

• An atom is an electrically neutral entity made up of a positively charged nucleus (protons and neutrons) with negatively charged electrons moving round the nucleus.

Page 22: Chapter 11 Atoms Molecules and Ions Teacher s Copy

Different types of atomsDifferent types of atoms

• Atoms are different because they have different number of protons and electrons.

• Atoms of the same element contain the same number of protons and those of different elements contain different number of protons.

• Atoms are different because they have different number of protons and electrons.

• Atoms of the same element contain the same number of protons and those of different elements contain different number of protons.

79Au79Au

12Mg12Mg

Page 23: Chapter 11 Atoms Molecules and Ions Teacher s Copy

What is the atomic number?What is the atomic number?

• The atomic number is the number of protons that an element has in each atom.

• The atomic number is like the identification card number – each element has a unique atomic number.

• The atomic number is the number of protons that an element has in each atom.

• The atomic number is like the identification card number – each element has a unique atomic number.

12Mg12Mg

Atomic number

Page 24: Chapter 11 Atoms Molecules and Ions Teacher s Copy

The periodic tableThe periodic table• The elements in the periodic table are

arranged in order of increasing atomic number.

• The elements in the periodic table are arranged in order of increasing atomic number.

Page 25: Chapter 11 Atoms Molecules and Ions Teacher s Copy
Page 26: Chapter 11 Atoms Molecules and Ions Teacher s Copy

Are there other ways of representing atoms?

Are there other ways of representing atoms?

• Atoms can be represented by circles, spheres or balls of different colours and sizes.

• Atoms can be represented by circles, spheres or balls of different colours and sizes.

Page 27: Chapter 11 Atoms Molecules and Ions Teacher s Copy

JournalJournalCarbon Oxygen Boron Sodium

Nucleon =mass Number 12 16 11 23

Proton Number 6 8 5 11

Number of protons 6 8 5 11

Number of electrons 6 8 5 11

Number of neutrons 12-6=6 16-8=8 11-5=6 23-

11=12

Practice

27

Page 28: Chapter 11 Atoms Molecules and Ions Teacher s Copy

ClassworkClasswork

• Workbk Pg 111-115a• Workbk Pg 111-115a

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Page 30: Chapter 11 Atoms Molecules and Ions Teacher s Copy
Page 31: Chapter 11 Atoms Molecules and Ions Teacher s Copy

What are ions?What are ions?• Ions are charged particles• An ion is formed when an atom loses or

gains electrons.

• Ions are charged particles• An ion is formed when an atom loses or

gains electrons.

Positive ion Negative ion

Page 32: Chapter 11 Atoms Molecules and Ions Teacher s Copy

Why do they gain or lose electrons?Why do they gain or lose electrons?

• To be like Group VIII elements• To be like Group VIII elements

Page 33: Chapter 11 Atoms Molecules and Ions Teacher s Copy

How are positive ions formed?How are positive ions formed?

• When an atom loses an electron,

It will have more positive charges than negative charges;

• It becomes a positive ion.

• [insert diagram of formation of Na+ from Pg 176]

• When an atom loses an electron,

It will have more positive charges than negative charges;

• It becomes a positive ion.

• [insert diagram of formation of Na+ from Pg 176]

Page 34: Chapter 11 Atoms Molecules and Ions Teacher s Copy

How are negative ions formed?How are negative ions formed?

• When an atom gains an electron,

It will have more negative charges than positive charges;

• It becomes a negative ion.

• [insert diagram of formation of Cl- from Pg 176]

• When an atom gains an electron,

It will have more negative charges than positive charges;

• It becomes a negative ion.

• [insert diagram of formation of Cl- from Pg 176]

Page 35: Chapter 11 Atoms Molecules and Ions Teacher s Copy

Bonding Bonding • And they live happily ever after• And they live happily ever after

Page 36: Chapter 11 Atoms Molecules and Ions Teacher s Copy

Overall process…Overall process…

Page 37: Chapter 11 Atoms Molecules and Ions Teacher s Copy

Formation of ionsFormation of ions• When atoms undergo ionic bonding, ions

are formed.• When atoms undergo ionic bonding, ions

are formed.

Atoms Ions

Ionic

Bonding

Page 38: Chapter 11 Atoms Molecules and Ions Teacher s Copy

Some common ionsSome common ions

• [Insert table of ions from Pg 177]• [Insert table of ions from Pg 177]

Valency Positively charged ions Negatively charged ions1 sodium

potassiumsilvercopper(I)hydrogen*ammonium

Na+ K+ Ag+ Cu+ H+ NH4

+

 

chloridebromideiodidehydroxidenitrate 

Cl -

Br -

I -

OH -

NO3-

2 lead(II)copper(II)magnesiumcalciumzincbariumiron(II)

Pb2+

Cu2+

Mg2+

Ca2+

Zn2+

Ba2+

Fe2+

*sulfatesulfite*carbonateoxideSulfide

SO4 2-

SO32-

CO32-

O2-

S2-

3 iron(III)aluminium

Fe3+

Al3+

*phosphate PO4 3-

* Complex ions-important in upper secondary

Page 39: Chapter 11 Atoms Molecules and Ions Teacher s Copy

What are molecules?What are molecules?

• A molecule is made up of two or more atoms combined together.

• A molecule is made up of two or more atoms combined together.

Page 40: Chapter 11 Atoms Molecules and Ions Teacher s Copy

Molecules of elementsMolecules of elements

• Molecules of elements consist of a fixed number of the same type of atoms combined together.

• Molecules of elements consist of a fixed number of the same type of atoms combined together.

Page 41: Chapter 11 Atoms Molecules and Ions Teacher s Copy

Molecules of compoundsMolecules of compounds

• Molecules of compounds consist of a fixed number of two or more different types of atoms combined together.

• Molecules of compounds consist of a fixed number of two or more different types of atoms combined together.

Page 42: Chapter 11 Atoms Molecules and Ions Teacher s Copy

Metals tend to form positive ionsMetals tend to form positive ions

• Non-metals tend to form negative ions• Non-metals tend to form negative ions

Page 43: Chapter 11 Atoms Molecules and Ions Teacher s Copy

Do all compounds exist as molecules?Do all compounds exist as molecules?• No, not all compounds

exist as molecules

• Some compounds, such as sodium chloride, are formed by the attraction of ions.

• No, not all compounds exist as molecules

• Some compounds, such as sodium chloride, are formed by the attraction of ions.

Sodium chloride lattice

Ions

Page 44: Chapter 11 Atoms Molecules and Ions Teacher s Copy

Chemical formulaeChemical formulae

• The chemical formulae of a molecule shows the number and types of atoms it contains.

Examples• Oxygen is O2 and methane is CH4

• The chemical formulae of a molecule shows the number and types of atoms it contains.

Examples• Oxygen is O2 and methane is CH4

Page 45: Chapter 11 Atoms Molecules and Ions Teacher s Copy

Which of the following are elements and which are compounds?

Which of the following are elements and which are compounds?

• Name of molecule and Chemical formula].

• Name of molecule and Chemical formula].

Page 46: Chapter 11 Atoms Molecules and Ions Teacher s Copy

Picture referencesPicture references

• Democritus• http://www.stenudd.com/myth/greek/images/democritus_1628_Brugghen.jpg • John Dalton• http://cache.eb.com/eb/image?id=8421&rendTypeId=4 • J J Thomson• http://www.aip.org/history/electron/images/jj-equip.jpg • Niels Bohr• http://web.gc.cuny.edu/sciart/copenhagen/nyc/index.htm • Quantum Model• http://static.howstuffworks.com/gif/atom-quantum.jpg • Plum pudding• http://upload.wikimedia.org/wikipedia/commons/thumb/f/ff/Plum_pudding_atom.svg/348px-Plum_pudding_atom.svg.png • Rutherfod’s model• http://www.faqs.org/docs/qp/images/rfmodel.gif • Bohr’s model• http://csep10.phys.utk.edu/astr162/lect/light/bohrframe/bohr2.gif

• Democritus• http://www.stenudd.com/myth/greek/images/democritus_1628_Brugghen.jpg • John Dalton• http://cache.eb.com/eb/image?id=8421&rendTypeId=4 • J J Thomson• http://www.aip.org/history/electron/images/jj-equip.jpg • Niels Bohr• http://web.gc.cuny.edu/sciart/copenhagen/nyc/index.htm • Quantum Model• http://static.howstuffworks.com/gif/atom-quantum.jpg • Plum pudding• http://upload.wikimedia.org/wikipedia/commons/thumb/f/ff/Plum_pudding_atom.svg/348px-Plum_pudding_atom.svg.png • Rutherfod’s model• http://www.faqs.org/docs/qp/images/rfmodel.gif • Bohr’s model• http://csep10.phys.utk.edu/astr162/lect/light/bohrframe/bohr2.gif

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Picture referencesPicture references

• Atom• http://content.answers.com/main/content/wp/en/d/d8/Atom_diagram.png • STM• http://www.phys.unt.edu/stm/images/STM-side_view.JPG • Molecule – spheres of different colours • http://www.nrao.edu/pr/2004/GBTMolecules/molecules.JPG • Ball and stick model• http://www.lsbu.ac.uk/water/images/so4clust.jpg • Ions• http://www.chem.purdue.edu/gchelp/liquids/ions.gif • Air molecules• http://www.chemistryland.com/CHM107/AirWeBreathe/Comp/AirAtomsMolecules.jpg• Molecules of elements and compounds• http://www.eoearth.org/upload/thumb/2/24/Compounds_molecules.jpg/300px-Compounds_molecules.jpg • Sodium chloride lattice• http://www.rkm.com.au/imagelibrary/thumbnails/SALT-NaCl-2-150.jpg

• Atom• http://content.answers.com/main/content/wp/en/d/d8/Atom_diagram.png • STM• http://www.phys.unt.edu/stm/images/STM-side_view.JPG • Molecule – spheres of different colours • http://www.nrao.edu/pr/2004/GBTMolecules/molecules.JPG • Ball and stick model• http://www.lsbu.ac.uk/water/images/so4clust.jpg • Ions• http://www.chem.purdue.edu/gchelp/liquids/ions.gif • Air molecules• http://www.chemistryland.com/CHM107/AirWeBreathe/Comp/AirAtomsMolecules.jpg• Molecules of elements and compounds• http://www.eoearth.org/upload/thumb/2/24/Compounds_molecules.jpg/300px-Compounds_molecules.jpg • Sodium chloride lattice• http://www.rkm.com.au/imagelibrary/thumbnails/SALT-NaCl-2-150.jpg