ch2 sec 3and4
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THE PHOTOELECTRIC EFFECT
The phenomena of the emission of electrons from a metallic surface when
exposed to EM radiation.
Electrons ejected from the surface in this way are called Photoelectrons .
The experimental setup that exhibits the photoelectric effect is as follows:
An evacuated tube contains two electrodes connected to a source of
variable voltage.
Surface of the metal plate is irradiated as the cathode.
Electrons reaching anode constitude a current called photoelectric
current measured by ammeter A.
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Experimental results
I) Curve shows how the current i varies as V and light intensity I:
Observe that:
1) The photoelectric current i depens on the anode potential:
2) V<0:
Thus, the minimum potential VStop. at which the photoelectric current dropst
to zero must equal to kinetic energy of the fastest electrons ejected:
.
2
max
2
1
StopeV mvK : Energy of the fastest electrons
3) The stopping potential is the same for intense and weak light.
4) The Photoelectric current i is proportional to the intensity of light I.
5) The Photoelectric current i appears without delay when the light is
applied.
A negative anode repels the
electrons. Only the fastest make it to
anode . The i steadily decreases as V
becomes increasingly negative until
at the VStop., All the electrons
are turned back and i terminates.
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II)
Observe that:
1) KE is proportional to the frequency , but NOT intensity I.
2) Photoelectrons are emitted only if light shining on metal will
have a frequency with0, where 0 is a treshold (or cut-
off) frequency. The value of 0 depends on the type of metal
from which the cathode is made . F.Ex.
0=5.6 x 1014 Hz for sodium
0=7.8 x 1014 Hz for calcium
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LIMITS OF CLASSICAL INTERPRETATION
According to classical EM theory;
I) because the energy in an EM wave is supposed to be spread
across the wavefronts, fairly straightforward calculations
show that a peroid of time should elapse before an individual
electron accumulates enough energy to leave the surface.
Experimental evidence is in sharp disagreement withthis.
II) Incident EM radiation (light) is considered as wave of
oscillation frequency and electric field amplitude E. In
this picture, electrons are ejected from the surface as a result
of an interaction between the oscillating electric field E of
the EM waves and the electric charge of electrons. Thus;
Kinetic Energy |Amplitude of oscillation|2
=|Amplitude of electric field|2=|E|2 ,
which gives the light intensity I.
Experimental evidence is in sharp disagreement with this,
too.
III) The existence of a cutt-off frequency can not be explained
by the classical EM theory of light, since according to this
theory photoelectric effect should occur at any of the
incident light provided that light is intensive enough.
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THE QUANTUM THEORY OF LIGHT
In 1905, A. Einstein resolved the paradox through the formulation
of the photon theory and he received the Nobel Prise in 1921 for
this work.
He generalised the Plancks notation that it was the absorption and
emission of radiation that occured in quanta.
Instead, Einstein proposed that radiation itself consisted of quanta
of energy.
Basic Postulates of the Einsteins Photon Theory:
EM radiation consists of zero rest mass particles called
photons that travel at the speed of light c, with energy
h .
Energy content of EM radiation of frequency in a radiant
source can only be an integral multiple of the quantity h:
nh E .
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The photoelectric effect by the Photon Theory
Increasing the intensity of light will increase the number of photons. Then
number of photoelectrons will increase too, so that photoelectric current i
increases, as observed.
However, instead, if the frequency is increased, the energy of each photon
h will then increase so that the photoelectrons will have more energy.
The Photoelectric Effect Experiment provides an important
confirmation of the particle nature of radiation.
According to Photon theory ,
light is composed of localised
bundles of EM energy called
photons and at frequency , the
nergy of a photon is h .
When striking the metal surface,
a photon interacts with a single
electron and ejects it from the
surface.
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The Explanation of the existence of a critical frequency0
in
The Photon Theory:
According to the Einsteins formulation, the fhotoelectric effect in a
given material should obey the equation:
hK max
with
0h : The work function , which is the minimum energy for
an electron to escape from a surface ( or else electrons
would pour out all the time)
Through the photon concept, the interaction between surface
electrons and incident EM radiation is a particle-particle
interaction.
If the photon energy is greater that the work function of the
metal, h , then electrons absorb the photon and partiallyuse the photon energy to overcome the work function. Then
rest of the energy appears as the kinetic energy for the electron.
On the other hand, if h , the surface electrons can not
accept this amounts of energy since interaction is particle-
particle like. Hence, no photon can liberate an electron if its
energy is less that the work function of the metal, irrespective
of the number of photons falling on it. Thus, when0,
which implies that Kmax<0 !, electrons will never be ejected
from the surface: Photoelectric effect is not observed below a
certain cut-off frequency0 .
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WHAT IS LIGHT?Today all physicists accept that the photoelectric effect (and many
other experiments) demonstrate beyond doubt the particle nature of
light. But, there are also many experiments that had established the
wave nature of light.Were these experiments somehow wrong? The
answer is that both kinds of experiments are right: Light exhibits wave
properties and particle properties. We can think of light as having a
dual character: The wave theory of light and the quantum theory of
light complement each other. Either theory by itself is only the part of the story and can explain only certain effects. The true nature of light
includes both wave and particle nature, even though there is nothing in
everyday life to help us visualize that.