SYLLABUS

CHEMISTRY (043)

CLASS- XII- (2013-14)

Time: 3 Hours

Total Periods : 180

70 marks

Unit No. Title Marks

Unit I Solid State 4

Unit II Solutions 5

Unit III Electrochemistry 5

Unit IV Chemical Kinetics 5

Unit V Surface Chemistry 4 General Principles and Processes of Isolation of Elements 3

Unit VI

Unit VII p-block Elements

Unit VIII d -and f -Block Elements 5

Unit IX Coordination Compounds 3

Unit X Haloalkanes and Haloarenes 4

Unit XI Alcohols, Phenols and Ethers 4

Unit XII Aldehydes, Ketones and Carboxylic Acids 6

Unit XIII Organic Compounds containing Nitrogen 4

Unit XIV Biomolecules 4

Unit XV Polymers 3

Unit XVI Chemistry in Everyday Life 3

Total: 70

The question paper will include value based question(s) to the extent

of 3-5 marks.

Unit I: Solid State (Periods 12) Classification of solids based on different binding forces: molecular, ionic, covalent and metallic

solids, amorphous and crystalline solids (elementary idea). Unit cell in two dimensional and three

dimensional lattices, calculation of density of unit cell, packing in solids, packing efficiency, voids,

number of atoms per unit cell in a cubic unit cell, point defects, electrical and magnetic properties.

Band theory of metals, conductors, semiconductors and insulators and n & p type semiconductors. Unit II: Solutions (Periods 12)

Types of solutions, expression of concentration of solutions of solids in liquids, solubility of gases

in liquids, solid solutions, colligative properties - relative lowering of vapour pressure, Raoult's law,

elevation of boiling point, depression of freezing point, osmotic pressure, determination of

molecular masses using colligative properties, abnormal molecular mass, van't Hoff factor.

8

Annexure 'I'

Redox reactions, conductance in electrolytic solutions, specific and molar conductivity, variations of

conductivity with concentration, Kohlrausch's Law, electrolysis and law of electrolysis (elementary

idea), dry cell -electrolytic cells and Galvanic cells, lead accumulator, EMF of a cell, standard electrode

potential, Nernst equation and its application to chemical cells, Relation between Gibbs energy change

and emf of a cell, fuel cells, corrosion.

Unit IV: Chemical Kinetics (Periods 12)

Rate of a reaction (Average and instantaneous), factors affecting rate of reaction: concentration,

temperature, catalyst; order and molecularity of a reaction, rate law and specific rate constant, integrated

rate equations and half life (only for zero and first order reactions), concept of collision theory

(elementary idea, no mathematical treatment). Activation energy, Arrhenious equation.

Unit V: Surface Chemistry (Periods 8)

Adsorption - physisorption and chemisorption, factors affecting adsorption of gases on

solids, catalysis, homogenous and heterogenous activity and selectivity; enzyme catalysis

colloidal state distinction between true solutions, colloids and suspension; lyophilic ,

lyophobic multimolecular and macromolecular colloids; properties of colloids; Tyndall

effect, Brownian movement, electrophoresis, coagulation, emulsion - types of emulsions.

Unit VI : General Principles and Processes of Isolation of Elements

(Periods 8)

Principles and methods of extraction - concentration, oxidation, reduction - electrolytic method and

refining; occurrence and principles of extraction of aluminium, copper, zinc and iron.

Unit VII: p -Block Elements (Periods 14)

Group -15 Elements: General introduction, electronic configuration, occurrence, oxidation states, trends

in physical and chemical properties; nitrogen preparation properties & uses ; compounds of nitrogen,

preparation and properties of ammonia and nitric acid, oxides of nitrogen (Structure only) ; Phosphorus -

allotropic forms, compounds of phosphorus: preparation and properties of phosphine, halides PCl 3 , PCl5 and oxoacids (elementary idea only).

Group 16 Elements: General introduction, electronic configuration, oxidation states, occurrence, trends in physical and chemical properties,dioxygen: Preparation, Properties and uses, classification of

oxides, Ozone, Sulphure -allotropic forms; compounds of sulphure: Preparation properties and uses of

sulphur-dioxide, sulphuric acid: industrial process of manufacture, properties and uses; oxoacids of

sulphur (Structures only).

Group 17 Elements: General introduction, electronic configuration, oxidation states, occurrence, trends in physical and chemical properties; compounds of halogens, Preparation properties and uses of

chlorine and hydrochloric acid, interhalogen compounds, oxoacids of halogens (structures only).

Group 18 Elements: General introduction, electronic configuration, occurrence, trends in physical and chemical properties, uses.

Unit VIII: d and f Block Elements (Periods 14)

General introduction, electronic configuration, occurrence and characteristics of transition

metals, general trends in properties of the first row transition metals - metallic character,

ionization enthalpy, oxidation states, ionic radii, colour, catalytic property, magnetic properties,

interstitial compounds, alloy formation, preparation and properties of K2Cr2O7 and KMnO4. Lanthanoids - Electronic configuration, oxidation states, chemical reactvity and

lanthanoid contraction and its consequences.

Actinoids - Electronic configuration, oxidation states and comparison with lanthanoids.

Unit IX: Coordination Compounds (Periods 12)

Coordination compounds - Introduction, ligands, coordination number, colour, magnetic

properties and shapes, IUPAC nomenclature of mononuclear coordination compounds.

Bonding, Werner's theory, VBT, and CFT; structure and stereo isomerism, importance of

coordination compounds (in qualitative inclusion, extraction of metals and biological system). Unit X : Haloalkanes and Haloarenes. (Periods 12)

Haloalkanes: Nomenclature, nature of C -X bond, physical and chemical properties,

mechanism of substitution reactions, optical rotation.

Haloarenes: Nature of C -X bond, substitution reactions (Directive influence of

halogen in monosubstituted compounds only.

Uses and environmental effects of - dichloromethane, trichloromethane,

tetrachloromethane, iodoform freons, DDT. Unit XI: Alcohols, Phenols and Ethers (Periods 12)

Alcohols: Nomenclature, methods of preparation, physical and chemical properties( of

primary alcohols only), identification of primary, secondary and tertiary alcohols,

mechanism of dehydration, uses with special reference to methanol and ethanol.

Phenols: Nomenclature, methods of preparation, physical and chemical properties,

acidic nature of phenol, electrophillic substitution reactions, uses of phenols.

Ethers: Nomenclature, methods of preparation, physical and chemical properties, uses.

Unit XII: Aldehydes, Ketones and Carboxylic Acids (Periods 12)

Aldehydes and Ketones: Nomenclature, nature of carbonyl group, methods of

preparation, physical and chemical properties, mechanism of nucleophillic addition,

reactivity of alpha hydrogen in aldehydes: uses.

Carboxylic Acids: Nomenclature, acidic nature, methods of preparation, physical and

chemical properties; uses.

Unit XIII: Organic compounds containing Nitrogen (Periods 10)

Amines: Nomenclature, classification, structure, methods of preparation, physical and

chemical properties, uses, identification of primary, secondary and tertiary amines.

Cyanides and Isocyanides - will be mentioned at relevant places in context.

Diazonium salts: Preparation, chemical reactions and importance in synthetic organic chemistry.

Unit XIV: Biomolecules (Periods 12)

Carbohydrates - Classification (aldoses and ketoses), monosaccahrides (glucose and

fructose), D-L configuration oligosaccharides (sucrose, lactose, maltose),

polysaccharides (starch, cellulose, glycogen) importance.

Proteins -Elementary idea of - amino acids, peptide bond, polypeptides, proteins, structure of

proteins - primary, secondary, tertiary structure and quaternary structures (qualitative idea

only), denaturation of proteins; enzymes. Hormones - Elementary idea excluding structure.

Vitamins - Classification and functions.

Nucleic Acids: DNA and RNA.

Unit XV: Polymers (Periods 8)

Classification - natural and synthetic, methods of polymerization (addition and condensation),

copolymerization, some important polymers: natural and synthetic like polythene, nylon

polyesters, bakelite, rubber. Biodegradable and non-biodegradable polymers. Unit XVI: Chemistry in Everyday life (Periods 8)

Chemicals in medicines - analgesics, tranquilizers antiseptics, disinfectants,

antimicrobials, antifertility drugs, antibiotics, antacids, antihistamines.

Chemicals in food - preservations, artificial sweetening agents, elementary idea of

antioxidants. Cleansing agents- soaps and detergents, cleansing action.

Practicals

Evaluation Scheme for Examination Marks

Volumetric Analysis 10

Salt Analysis 8

Content Based Experiment 6

Class record, project work and viva 6

Total 30

PRACTICAL SYLLABUS

Micro-chemical methods are available for several of the practical experiments.

Wherever possible, such techniques should be used.

A. Surface Chemistry (Periods 5)

(a) Preparation of one lyophilic and one lyophobic

sol Lyophilic sol - starch, egg albumin and gum

Lyophobic sol - aluminium hydroxide, ferric hydroxide, arsenous sulphide.

(b) Dialysis of sol-prepared in (a) above.

(c) Study of the role of emulsifying agents in stabilizing the emulsion of different oils.

B. Chemical Kinetics (Periods 4)

(a) Effect of concentration and temperature on the rate of reaction between sodium

thiosulphate and hydrochloric acid.

(b) Study of reaction rates of any one of the following:

(i) Reaction of iodide ion with hydrogen peroxide at room temperature using

different concentration of iodide ions.

(ii) Reaction between potassium iodate, (KIO3) and sodium sulphite: (Na2SO3) using

starch solution as indicator (clock reaction).

C. Thermochemistry (Periods 4)

Any one of the following experiments

i) Enthalpy of dissolution of copper sulphate or potassium nitrate.

ii) Enthalpy of neutralization of strong acid (HCI) and strong base (NaOH).

iii) Determination of enthaply change during interaction (Hydrogen bond formation)

between acetone and chloroform.

D. Electrochemistry (Periods 2)

Variation of cell potential in Zn/Zn2+

|| Cu2+

/Cu with change in concentration of

electrolytes (CuSO4 or ZnSO4) at room temperature. E. Chromatography (Periods 2) i) Separation of pigments from extracts of leaves and flowers by paper

chromatography and determination of Rf values. ii) Separation of constituents present in an inorganic mixture containing two cations

only (constituents having large difference in Rf values to be provided). F. Preparation of Inorganic Compounds (Periods 4) i) Preparation of double salt of ferrous ammonium sulphate or potash alum. ii) Preparation of potassium ferric oxalate.

G. Preparation of Organic Compounds (Periods 2)

Preparation of any one of the following compounds

i) Acetanilide

ii) Di -benzal acetone

iii) p-Nitroacetanilide

iv) Aniline yellow or 2 - Naphthol aniline dye.3 Al

H. Tests for the functional groups present in organic compounds: (Periods 6)

Unsaturation, alcoholic, phenolic, aldehydic, ketonic, carboxylic and amino (Primary)

groups.

I. Characteristic tests of carbohydrates, fats and proteins in pure samples and their

detection in given food stuffs. (Periods 4)

J. Determination of concentration/ molarity of KMnO4 solution by titrating it against

a standard solution of: (Periods 8) i) Oxalic acid, ii) Ferrous ammonium sulphate

(Students will be required to prepare standard solutions by weighing themselves). K. Qualitative analysis (Periods 14)

Determination of one cation and one anion in a given salt.

Cation - Pb2+

, Cu2+

, As3+

,Fe3+

,Mn2+

, Zn2+

, Co2+

, Ni2+

, Ca2+

, Sr2+

, Ba2+

, Mg2+

,NH4+

Anions - Co2-

3, S2-

, SO2-

3, SO2-

4, NO-2, NO

-3, Cl

-, Br

-, I

-, PO

3-4, C2O

2-4, CH3COO

-

(Note: Insoluble salts excluded) PROJECT Scientific investigations involving laboratory testing and collecting information from other sources. A few suggested Projects Study of the presence of oxalate ions in guava fruit at different stages of ripening. Study of quantity of casein present in different samples of milk. Preparation of soybean milk and its comparison with the natural milk with

respect to curd formation, effect of temperature, etc. Study of the effect of potassium bisulphate as food preservative under various

conditions (temperature, concentration, time etc.) Study of digestion of starch by salivary amylase and effect of pH and temperature on it. Comparative study of the rate of fermentation of following materials: wheat

flour, gram flour, potato juice, carrot juice etc. Extraction of essential oils present in Saunf (aniseed), Ajwain (carum), Illaichi (cardamom).

Study of common food adulterants in fat, oil, butter, sugar, turmeric power, chilli

powder and pepper.

Note: Any investigatory project, which involves about 10 periods of work,

can be chosen with the approval of the teacher. Recommended Textbooks. 1. Chemistry Part -I, Published by NCERT. 2. Chemistry Part -II, Published by NCERT.

SAMPLE QUESTION PAPER

CHEMISTRY (043)

CLASS XII (2013-14)

Design of Question paper

Time: 3 hrs. Maximum Marks:70

A. Weightage to different forms of questions

S. No. Type of question

Marks per Question

Total number of Questions

Total marks

1 VSA 1 8 8

2 SA I 2 10 20

3 SA II/Value Based

Question

3 9 27

4 LA 5 3 15

Total 30 70

B. Typology of Questions

S. No.

Typology Weightage in marks

Weightage in percentage

1 Knowledge Based 14 20%

2

Conceptual Understanding

21 30%

3 Inferential Type 14 20%

4 Reasoning Based 11 15%

5 Skill Based 10 15%

Total 70 100%

C. Scheme of options

There will be no overall choice. However, internal choice in any one question of two marks, any one question of three marks and all the three questions of five marks weightage has been provided.

D. Difficulty level of questions

S. No. Estimated difficulty level

Percentage of marks

1 Easy 15

2 Average 70

3 Difficult 15