case no. 8019: organic lab data for samples df021201 ... · las vegas, mv 89109 usepa region vi...
TRANSCRIPT
^ *™ \ UNITED STATES ENVIRONMENTAL PROTECTION AGENCY\5S^' REGION VI
*'-. •TO'l1' HOUSTON BRANCH6608 HORNWOOD DRIVE
HOUSTON TEXAS 77071
Ref. Case No.
Site Name ^7^//?<L
Date: //-/3-y7
Subject: CLP Data Review•^6^— •f*-'—
From: Michael L. Daggett, Chief, Organic Lab Section, 6E-HL
To: Hank Thompson, 6E-SH
A review of the laboratory raw data for the reference site has beencompleted by members of the Laboratory Section. Samples were:
INORGANIC:
ORGAHIC : PR i) 3- ] 9- b I
DFQc»)^<>^
The data was found:
Z^-/^^TT/]y v^fiii-^'y/i^-1 '•• >! use of data requires caution. Problems are noted in Review Summa:
/ S G^"/'' '••^'•'-f:.' ''l. data should not be used. Problems are noted in Review Summary.^ V/^/'^ZQG^^J
g-/-' f-i Ml6f--Filo 'S the ""^visw can be addressed to me.
Attachments
cc: David Stockton, 6E-HLDuane Geuder, WH-548A
ORGANIC 0& CHECKLIST
Site V^XT^rC______ Contract No. fn^-^-7^0
Case NO. ^0 f Y /O 3 Contractor 7^U <'t7l) L
Reviewd By /^ c C. ^ (77€fi- Matrix 5^ ^ C__________
/ ( ^ / K 7 Acct. «y/^^^ SF ^^ oyDate
Sample No. PpCZ.(2--^ -M^f^^V O p 6 Z . J Z - Z >______ 00
l9F6J^/^-f} / ^(^^ ^PO^?-Q3 ^• -10
OVERALL COMMENTS ( To Be Conpleted By EPA PERSONNEL) 3- ? PA-ZC^r
m^^iTOA B/N A Pest Other
1. Holdiog Times2. Tun ing/Performance3. Calibrations4. Blanks5. Surrogates6 . Matrix Spike/Cup7. Compound Identity8. Case Assessment
COMMENTS OR CLARIFICATIONS (See Attached)
A - Acceptable - All items delivered; all criteria met.___________________
P - Provisional - Data usable; some non-essential review items missing or criteria
were not met._______________________________________________
U - Unacceptable - Data unusable; essential review items missing or criteria not met.
ORGANIC QA CHECKLIST
i/e^-V^-C Contract No. ^J-CJ/-7^0
Case No. y 0 ( J /Q Z. Contractor 77 ; ft-f^rf .
Reviewed By At- /. ^('•J'J^- Matrix _____^U ? C__________
Site
Date ^A /Y? Acct. » J^Zf^^SF Yp^^YDate
Sanple No. /9F O^fZ.-^^-________ ____________ __________
^Pczp.-Y\y 4-k^^L ^Po^z- /7
OVERALL COMMENTS ( TO Be Completed By EPA PERSONNEL)
1. Holding Times2. Tuning/Performance3. Calibrations4. Blanks5. Surrogates6. Matrix Spike/Dup7. Compound Identity8. Case Assessment
-J-
COMMENTS OR CLARIFICATIONS (See Attached)
A - Acceptable - All items delivered; all criteria met.____________________
P - Provisional - Data usable; some non-essential review items missing or criteria
were not met.__________________________________________________
U - Unacceptable - Data unusable; essential review items missing or criteria not met.
ORGANIC OA CHECKLIST
SiteCase No.
Contract No. ^'?~0f'-7 ^ ^°
Contractor
Reviewed By
Date ____
Matrix
Sample No. f) FOZ.f2.-Q/ j^P' 02. f 2.-(fC,
ft^P^Z/Z-oy VF6L(i'a7•ffF^iz'ar
'0•'0
T-l
--10
OVERALL COMMENTS ( . T o Be Completed By EPA PERSONNEL)
TOA B/N Pest
^A-7C(?/;j^ff"^Other
1. Holding Times2. Tuning/Performance3. Calibrations4. Blanks5. Surrogates6. Matrix Spike/Dup7. Compound Identity8. Case Assessment
A
COMMENTS OR CLARIFICATIONS (See Attached)A - Acceptable - All items delivered; all criteria met.P - Provisional - Data usable; some non-essential review items missing or criteria
were not met.U - Unacceptable - Data unusable; essential review items missing or criteria not met.
COMMENTS/CLARIFICATIONSREGION VI CLP QA REVIEW
CASE ^n/V! ^ <n SITE W^7^ C_______ LAB 7^1 S
The following is a summary of sample qual i f iers used by Region VI inreporting this CLP Case data:
No. Acceptable Provisional Unacceptable
VOA _________ ________ ___________BNA __________ __________ ____________PEST __________ _________ ___________ '-IOTHER yniY(^____^0___ 3 ___________ ^
' T-l
COMMENTS : rp-J"^ ^ c i\ *<H o( • ^tU^i"L€! FTM- ^-TWfc-S g^ dj ^-03 A/^ C^JC-<fiSfy.
/?ft7^ iPrC A 6-tT ^ fift^[ 5^f^\L ; T^hg -r s w L^S^^.^7 f^A-KC^Ll^ ^0-JSi^^^ QM^^Tj Ta-N cQF > i ^b^t0 ^r^pJ f?^aii^em^T^ /=f, -?i!< ir j'/^i^c^r "A-^ ^^^- ^^7^<^? /Ar7d ^^YV) ^ C^^/?^C74C
^L^L^W.______________________________________
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/AJ 1^37/^-70^ •AA^) ^^-7A tW- ^fi^ic/^- ^P^U-f^^f^.. AJ ftr ^(^^7._____________
Z. fe.T/(A- f-^TS FW. X)7fc'7^/yff LAJ^L^ F^(\/ff/A/ fiP 0 2 -/) 7 ^/ . •//M)'. OF 6 •Z--/6 ^ O^^bhOFbi(7^i( (^5-( f,^)_."ffF7a:L^^-/.^( ^^ ^i}. .f)F OZ./2-^b ^66,y»i^ ^0 /}Fcif2.--LQ ^'H./^^}.
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TMS ANALYTICAL SERVICES, INC.
TOS<?0?7-6-^
TMS ANALYTICAL SERVICES, INC.
October 2, 1987
Mr. Mike WittingtonCLP Sample Management OfficeViar & Co.209 Madison S t . , Suite 200Alexandria, VA 22314Dear Mr. Wittington:Enclosed is the complete Sample Data Package for the analysis ofsamples for 2 , 3 , 7 , 8 - T C D D according to the procedures specifiedunder CLP contract tt7390.These samples were received as Case #8019, Batch <tl on September14. Results were sent by overnight courier on October 2 forarrival on the October 5 , 1987 due date-
No special problems were experienced with these samples. On09/23/87, Tony Neskey from SMO called Dan Delinger from TMS tonotify the lab that Case #8910 Batch 1 should be Case tt8019 Batch1- Tony Neskey called Dan Delinger again on 09/25/87 to explainthat the duplicate and spike samples for Case #8019 Batch ttl willbe included in Case *8019 Batch tt3, therefore no B-4 Form will beincluded in this report. In addition, sample number PE-QIG182was mislabeled as PE-QIG187 on the sample tag. Adjustments weremade by Kelly E . Mills, Sample Custodian, on 09/14/87. Theresults for all samples meet all the QA/QC requirements and allresults should be considered valid.If you should have any questions regarding these data or thisreport, please feel free to contact me at ( 3 1 7 ) 2 9 1 - 5 6 9 7 .
Very truly yours,
/J^A/^ ^ ^^^ 4^)ennis L . Heuring, Ph.B.Dennis L . Heuring, Ph.President
CC:USEPA EMSL/LV QA Division944 E . Harmon Ave.Executive Center, Rm 226Las Vegas, MV 89109
USEPA REGION VI LABORATORYMonterey Park Plaza - Bidg. C6608 Hornwood DriveHouston, TX 77074Attn: Melvin Ritter
ENCLOSURES:
80/^-G3TMS Analytica. Services Inc.6376 MORENC1 TRAIL • TEL. 1317] 291.5697 • INDIANAPOLIS. INDIANA 46268
FORM B-1S. TCDD SOIL DATA REPORT FORM Page 1 of
Lab: '~" -5 /-AJ /? V T/C ft f-
Case/Batch Ho: ^p/^/ / ^ /
Report Date: / Q / / /^P ?
Co lunn: g?'/3 .J ,?.. ' /
Instrument ID: /^J^ /g;/) 'V'00 0
EFASample Mo.
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MB - Method BlankN - Native TCDD SpikeD - Duplicate/Fortified Field Blank
PE - EHSL-LV Performance Evaluation SampleMPC - Maximum Possible Concentration*Note: Relative Co ^C.--! ,2 ,3 ,4-TCDD
FB - Field BlankIS - Internal StandardRR - RerunRS - Recovery StandardND - Not Detected
TMS Analytica' Services Inc.6376 MORENC] TRAIL • TEL. Ql 7) 291.5697 • INDIANAPOLIS. INDIANA 46268
FORH B-IS. TCDD SOIL DATA REPORT FORM Page 2 of
La b: • / ^/.S / - / t . -i ft / v 7-/C / ) A.
Case/Batch Ho: ^p/^ /^f
Instruaent ID; ,^L\0/('7/7/~' ^/'C'CCi
- Report Date; /Q //- /^ 7
Column: 'S^1.-^^?/"3300era
Rel.ERA Response Ratios 0Response (Area)
SampleNumber
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320/322
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FE - EKSL-LV Pei-formance Evaluation SampleMFC =" Haxiaua Possible Concentration
FS - Field BlankIS - Internal StandardRR - RerunND - Mot DetectedRS - Recovery Standard
TANOEM MASS SPECTROMETRYIMS Analytical Sf-vices Inc. 80^-06376 MORENCI TRAIL • TEL. (31 7) 291.5697 • INDIANAPOLIS. INDIANA 46268
FORM B-2 " Page 1 of 2
INITIAL CALIBRATION SUMMARY
Labora to ry : CC Solution Alternative:
Case/Batch No . : ^nn / / Ins t rument ID;- ^ \ ••'\ \c' ^
ASJEA
Date
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CC1CC1CC1
CC2CC2CC2
CC3CC3CC3
CC4CC4CC4
320
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Solution ID Codes:
CC1 =• CcncsntraCion calibration solution ?I rt Hot present in CC SolutionCC2 " Concentration calibration solution •,72 Alternative Gne.CC3 °; Concentration calibration solution S3CC-'t " Concentration calibration solution i?4
T IS Analytical Se. vices Inc.6376 MORENC1 TRAH^TELpQy) 291-5697 • INDIANAPOLIS, INDIANA 46268
L a b o r a t o r y i
IMITIAL CALIGFJVUON SUi'iilARY
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Page 2 of 2
CC Solution Alternative: \ I
Caaa/BaCdi tlo. s ^Q \ °f / / Iiistrunient: ID: \- ^ ,^ c, fi '-(oof)
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IS Hea"of i;ea;;a; _/^"-?
TMS TMS ANALYTICAL SERVICES. INC.FANOEM MASS SPECTROMETRY
CiJ76 MorcriL-i TrailIndianapolis. Indiana -^2fcit!3.i'7-;9J-5o07
CLP Sample Management Off iceViar & Co.209 Madison St . , Suite 200Alexandria, VA 2 2 3 1 4
To whom it may concern:
Please replace the existing B-M F'-'rna found in the Sample DataPackage and the Sample Data Su'nm-yry F-icl-.'-i^e with those correctedB-3 Forms. Our files hnvo hi,'" ;.i iip'.ir; L.':-d nnd corrected by C.Krauss, Document Control Of f icer .
If you should have any questions pie-is.:1 ^'coi free to contact meat ( 3 1 7 ) 2 9 1 - 5 6 9 7 .
Thank You,
,Lmi-/ /y/^// /—^-- f^/-'.'.' •/n t h i a J . K r-i u 3 s'... '/h t h i a •-. . > i. .-. r'ocum':-nt Control Officer
USEPA EMSL/LV QA Division944 E . Harmon Ave.Executive Center, Rm 226Las Vegas, NV 89109
11;"? ' '? '^ REGION VI LABORATORYMont-^-"y Far]': Plasa - Bid^. C6^l"';-' Hornwood DriveHouston. TX 77074A tbn : Helvin Ritter
ENCLOSURES:
TMS Analytical Services Inc.6376 MORENC1 TRAIL • TEL. 1317) 291.S697 • INDIANAPOLIS. INDIANA 4626
FORM B-3
ROUTIHE CALIBRATION SUMMARY ' " ^ - V .
Laboratory: / /?/JS ,/^u / t/z'/g^._______ CC Solution Alternative: //_
Case/Batch Ho.: ePo/f 0/lrc.^ ^ / / l t •-•^ / Instrument ID: /^/-i/g^,^) ^/co Q
(CC1)CON. CALIB. SOL. Hi(PCS) PERFORMANCE GnECK SOL.
Data ( ^/ffy
V.V.-S.
Response
259
320
322
328
33 7 IS
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332RS
334RS
Ratios
320/322
332/33'iIS
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TANDEM MASS SPECTROMETRY
w-TMS Analytical Services Inc.6376 MORENCI TRAIL" TEL. BIT) 291-5697 • INDIANAPOLIS. INDIANA 46268
FORM B-3
ROUTINE CALIBRATION SUMMARY
Laboratory: / /)?J^ y^u /. ^7yo»<_______ CC Solution Alternative; _
Case/Batch Ho.: ifa/^ 0/l-rc.// ^/_____ Instrument ID: / .-w/ ,0 .^/.CO.Q.
(CC-1)CON. CALIB. SOL. 9\(PCS) PERFORMANCE CHECK SOL.
Bate
Time
RKsoonse
259
320
322
328
332IS
334IS
332RS
33^>RS
Ratios
320/322
332/334IS
332/334RS
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MID MASS CHROmTOGRAMS DATm SEP2803 »1 SCANS 1704 Tu 1S50S9-'28-'37 21! 56! 00 CflLI; CftLS325?7 »3SAMPLE: CnL 1 SOLNCOHOS.! E0M SP2331/100/100-200@25.''2S@-240e4/8RAHGE: G 1704,,1850 LflEEL; H 5, 2.5 QUHH; ft 1, 1.8 -1 @ BftSE: 1.1 28, 3
17574923.41523.
A
332.099± 8.51313
6024.
334.ISS± 0.500
1720 1749 1768 1780 1800 182^3 1840 SCANIR^S 18;56 r ' " ^ 19:23 ^•."'.K 19-4q m:W T T M P
N I D MASS CHRnNHTOQMIS DuTA; OCTenai ai SCHHS 17Q4 TO 1S5010-'@1.'87 13:83! 88 CftLI; CHL£i32587 a3SHMPLE; CHLIBRHTIOH SOLN 1CONDS.! GOM sp233i/-iee/ie;o-2eee25--2ee-24er4/8RHHGE; Ul7i34,lS50 LABEL: H 5, 2.5 QIJAH! ft 1, l . @ -1 0 Bf-'SE: 1.1 23. 3
17555S27,46518.
172913:43
174918:56
17'' 1786 1S09 1328 1849!? 'i !9;23 19;3f; 19:4^ •"'n-n-?
T S D T T O
H I D MASS CHRCIMHTDGRHMS DATA: OCT@101 ttl •SCHHS 17>34 TO 185t3H3/ei-'87 13;03:S@ CnLl! CflL892587 »3SftnPLE; CftLIBRATIOH SOLH 1COHDS.! SUM SP233l.•/l^"10/•lee-2^^£1e25.•'2^"l^3-24n!•:4/'aRRHGE; G1764,185i3 LABEL; H 5, 2.5 CiUftH; ft 1, 1.3 J 0 BASE! l-l 29, 3
17531188.9339./!
/'/
/'
//'
-.-—-J"-'—-..r- -^\A-^^A ,,,Ai | 1 j 1
17?21394.
11239 .fi,
t?'
/
)1f
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\
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I
~ • ,• 1 i " . , i i i
\ ^ - . J ' - - . - ^ /•"-••^,-^'\,/-^-^——--——,/>. -./ . ,.. / ---.
328.93b± B.50.3
14:
322.OS?±' fl.5w
1720 1743 17™ 1788 ISOe 1329 1848 SCRH18S43 1;-;;56 19; 10 19:23 1?:?? 19:49 20:82 TI^E
SC^HS 1764 TO 185HH I D MASS CHROMATOGRAMS DATA; Oi::T01£H #113.-'81.-'87 13;i33;S@ CftLIs CnL0925S7 S3SAMPLE; CALIBRATION SOLH 1COHDS.: 60n 5P2331/iei3/'106-2£in@25/'2&0-24e@4/3RANGE: G1704,1S5S LnBEL: N 5, 2.5 QUAH: A 1, 1.6 -1 9 BRSE; l-l 29; 3
1752345.
T
\ i \
A/•l•/h^v^ l--—^^^^^^^^wv'V^A^- 'MA—^——j——————g—————————————^——^——————————j———r-'-i—————'-1
,/-'---.-. -''"'\ /Vf'~• ' /''•A"••, /
172@18:43
17S919:23
1889l ^ i ^ R
1829iq;4q
1S40w-m
6rS6I0Z8I
9£!5I8081
es'ei08^1
at!6i03ZI
9SS8Iew
9ZZI ^1 88^1
8821
SS^Ts 'ez n !3sya 0 r @ ' T '9 y 'wnis @'t' 'e N s"i3a^ a58i't'a^T9 !39Nya8/'t'88t'3-90Z/SS3©e3-eei/0ei/I£S3dS M09 s'SOHOO
i mos Noiiyaanyo ••J}M)Seit 28SZ6enw inya eeisasei ^s/'Te/ei
i<t TeT@i30 smyo 3ia OIH8281 01 t-Q^I SNOTS
011453
SCANS 1704 TO 1850(•110 RIC DATA: SEP2894 ftlCALI; CRLS325S7 »303--'28--'87 22; 33; 89
SAMPLE; COLUMN PERFORMANCE MIHCOHDS.: eet'l 5P2331--l@0/'10@-2e0e25/20u-24£i@4.'8RANGE; G 1764,1858 LABEL; H Q, 4.0 QUAH; ft 9, l.S ..I 6 BASE: IJ 20, 3
1766
2,3,7,8TCDD
1756A
1742 /1721.
172U'•'••A'\
1743i.-'.iri-
1769 1788iq •'•:-:
1S00'^•^.F,
182919S49
184920; 92
S9HTOMID MASS CHROMATOGRAM3 DATA: SEP2804 #1 SCANS 1794 TO 1858@3-''28/87 22; 33; 06 CALI; CAL0925S7 #3SAMPLE; COLUMN PERFORMANCE MI/<;COUDS.: 60M SP2331/100./[email protected]: G1704,1850 LABEL: N 5.. 2.5
t.^170 -217b. 29114. ^5' 417b•ll• / '
^i °"i ^ / \^t\i'
! /^ 1 Q } ! \ f \
1742 ? i1 ^ ', / \. / \465. l3731. J
^\ /
- ,,,-,-,,-,.,,,.,^ ^ s
1 . ™-21230. ; \
.•• \f
/l/
1742 ^522. J3990. i'^\ /... ..... . y v
1729 1749i'-.., i -. 1.-.. '->-
9-24U@4/8G!LlHH: A 1, 1.0 J 0 BASE; 1-1.29, 3
17S8„ 2345.
\i\ ^'- / \ ^- /-., / 'i ± 0 . 5 0
'i /' '• ' '.
\ 1J \ /——]—————-.——L=^——————.——————i——————i——————]——————i——————|——————..
17873868.
-1490. / (
12624. ,' \ 322.09', .."-•.. ; 'i ± 0.56\ I ' M \\ /' i\ 1\./
1766 1789 1809 1820 1840 SCANl" : - 1 ^ i0"'"? I Q - W 19!49 20;02 . T I N E
\ ,„..„ ,
\\.
SCANS 1784 TO 1858MID MASS CHROMATOGRAMS DHTH; SEP2S04 #1CftLI; CftLS32587 tt309/2S/S7 22;33;08
SAMPLE; COLUMN PERFORMANCE MI^COHDS.; 68(1 SP2331/'100-''100-2e0e25-'[email protected]':3RANGE: G1704,185@ LABEL: H 5.. 2.5 QIJAH; 9 1 , 1.0 J 0 BASE: LI 20,1785
12181.104895.
SCANS 1794 TO 1850MID RIC DATA: SEP2827 #1CALI; CAL092587 S303/29/87 9;25:98
SAMPLE; COLUMN PERFORMANCE MI1--;COMDS.; een SP2331/'10e/'lS0-2@0e25/2@0-24u@4/8RANGE: G17@4,ie50 LABEL: N 0, 4.8 iUHH: A @ , 1.9 J 8 BASE; U 20, 3
178G
1769 1723
17281;';!4^
1740is-w
1769^•m
160019;;:P
182019; 49
184020; 62
N10 MASS CHROMftTOGRHMS DHTH: SEP2827 ttl SCANS 1704 TO [email protected] 9; 25; 69 CftLI; CAL032587 #3SAMPLE; COLUMN PERFORMANCE MIKCOHDS. s 60M SF•2^31/•109/•100-200@25./200-24£ll«4./8RANGE; £1764,1850 LABEL: N 5, 2.5 QUAH: H 1 , 1 .0 -I S BftSE; LI 20, 3
17871418.
1753 19532-116R.
19999.
i\1742 \ \ !• \223. \ .2846. ,' 1 / \I \ i \.r'-: / \ ! \
r- -—- ••-^.--"-.--—--,r'" __^L,-__ ''•, / _________\A_^\.,.._ ._. ,-•\.^_.-^-'\^t"\.^.^\,-r"——-i———r——°-———————-r- —————i———i———"i——--."—•' i" ' ' ^ • r1787
/ \
1742•—•• ( i ,'3935. / \ ^
\/ \ / \•t..- ..— .. J./"'________T__________•-, /_________________••,~-:^--~-^-—-^-.•-n .—A f-J'-f^-—-V--^ ,- '
1720 1740 IPTO 1780 1800 1820 1840i.-,.,i-. i . - . - r— i.-i--.!' i'-i. '•>:• la.-'-'c: 19!49 20S02
SCAHS 1704 TO 1850MID MASS CHROMnTOGRAHS DATA; SEP2827 Sl09/29/87 9;25;0@ CALI; CAL092587 it3SAMPLE: COLUMN PERFORMAHCE MIKCONDS.; 6SM SP2331/ie6/ie9-20©@25/2a0-240@4/8RHHGE; G1704,1850 LABEL: H 5/ 2.5 laUAH: A 1, 1-1 20, 31.0 J 0 BASE;
17857048.72647.
/-••.,
17573639.3G£83./-^/ \
"•'-.
17564550.46886.
f'~\
1726li-'..n
174@f '- ' .^r
1760lq- IP
1788iq--'"'!
1S00iq-^'C
182019:49
184020:02
•V Q
0 '3
I:"", 'V i—i i-n i— 3/CD S 2 B '?''~'!'-' o o T3 .a ~
• m 1.1-11— i-- •v,' — • m '-. —" " 1:1:1 o
'. 0 --Ji i-- cn o| a§PS1 -p- 'r: —- \ ^aaa^^s
1 —* 'S1 '.s.' Pi w',-..J •-l ~V
^ E5§\--'-- -^ r. ^i----—--——- . § " 5§a
32 '•"J '""3 ^CT ;§; 5 <0- K ^*" -H1^1 t-J __J
0 • 'i3 l—l C3 (~3
•2 I. !;• X. ——'
E ^ S"::" J- 0 0i:- ••• r <-.1:1:1 i" —<
'3 C'
f ^:-"• i:0
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MID MASS CHROMATOGRAMS DATA; OCT0102 ftlia/ei/8? i3;33;ee CALI; CALGS^SS? tt3SAMPLE; COLUMN PERFORMANCE my.COtlOS.; 60t1 SP2331/10e/l£i8-2B0e25-'-208-24@@4/8RANGE; Gl7@4,185t3 LABEL; H 5, 2.5 QUAD; A
174714S8.118S9.
1738325.2962.A\
SCANS 1764 TO 1850
BASE; U 26, 3
17471939.147S5.
17772176.18363./'•,
172S!f;43
174k»Ifi-^fi
17£ni q ; i r f
1780iq-?'!
180019;3R
182619; 49
1S4826:02
zs'-uz6W
B^bt808 T
Ul •6iQ31}
i iv•St-81'8•eewt?^i
s 'ez n sasya e
0S8T 01 t'9;'I SNTOS
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•I^SSS•ZSIt-t't'ZI
•I6I69^6;8t' !r e-i ' T y sHyrci e's ••s N nagyi eesi't'ezio saoNva
8.-'t-aOt'3-60Z.-'[email protected]'0eT/-T££ZdS ?39 ! •SOHO::i^IM 33NbHaOda3d NHIT103 S31dMyS
S# ^SS3ei319:i ;I-iy3 60!££!£I 28/-T9./STitt £u 161:11:1 ;yiya swaooiwiCKro ssyn oin
011462
SCAHS 1784 TO 1859f lID RIC DnTn; UL:T6110 ttlCftLIi CAL932587 fr316/01/87 20!18;0@
SAMPLE; COLUMN PERFORMANCE MI^COHDS.: 6eM SP2331/iee/160-20He25/2n9-24n@4./8RANGE; G1704.1850 LABEL; N 9. 4.S GUHri: H £1, 1.0^J 6 BASE; U 29, 3
1 f u 1
2,3,?.eTCDD
1752A
! \
/ 1/ \ 1
i \ /1735 /
/
1720 1740 17FO
KOi
^
1
17S©| I". - •'! •
13564.
\\
'''—-. ^ls^4 , 1S17 1839
i | r | r | iI'^a 1829 1840 SCAN
•' I1 ' -""' H-49 •?fl.O-? TTHF
DATA; i:iCT0iie ttiCALI; ?1092587 S3
MID MASS CHRCK1ATOGRAMS10/Q1-'87 20;18;@CiSAMPLE! COLUMN PERFORMANCE W,iCONDS.! sen sp233i/i£ie./ie9-2@ee25/2i30-24oe4./8RAHGE: G 1704,1859 LABEL; N 5, 2.5 laiJAH; ft 1 ; 1.6 J 6 BASE: U 28, 3
17S3385.
72£5.,(
SCANS 1704 TO 1858
. I..C..J.1 1 -1.- (
733. ^5S30. ; 1
M f/ \ / 11 i., , f 1 S2@,096/ \ r\ \ ^ 9-5^
1735 ; \ i V \158. \ f
1 2 1 1 > ,'
/^ / \ 1^r^~^.r— ''^ \f\^•i • i l • • ' - — i ' • • • i i i ' i ' -f——~-———i———•-
17811150.9232.
1752 A997. 11. - .7381. \ \
^-
1 1 1f 1 • / 322.996/ I , ' /1, ,,' \ t 0.5001737 / \ i \/ \2SW.. j '.. ; •-• '!
14,24. ,it-'\ ! ', i
-' "•••-. ,'1 ' ;
..,r..-. A -^ - r " ' —W \ /'17213 174H 17b0 1783r-,.,-1-:. •|.-.. fi~ )q. ] !-; IQ-''''3
\1 \ , - •''--""••-, / /w'-.' ^
\\
893.
1164.
.——- -^••^ ^f-——. .- --•''""- ' "V'"'" ,-'--'!.,/ -
" '"'"1 1 " ' " 1 1 • | • ==i3.
1889 1820 184@ SCANl0-'^ 1'5;49 20:02 TIME
M I D MASS CHRONATOGRAMS DATA: OCTailO #1 SCANS 1764 TO 185810/01.-87 20; 18; 0@ CALI; CAL092587 #3SAMPLE; COLUMN PERFORMANCE MIi<!COHDS.: 66M £P2331./100.'[email protected]'200-24ee4.-'8RAHGEi G1704.1850 LABELS N 5, 2.5 QlJAH: H 1, 1.9 J 0 BASE; U 20. 3
17793382.3m;;' 4012./ 1
1758 j 'i2008. ( 1,16860. 1 \ 332.09'
/'^ ]• I, ± 0.50(
, / V. / ^17794753.
™-
/ \1750 |1 |2613.
20•::l•:i2. t/•, 1 i 334.130
/ \ ' 1' i, ± 0.590
/" '-, ,'/ \ 1 \t '. ; \
'1..-.,,. —— ———— „ ^-^————.F^a==——, ^ -. .. ^,^-^^-,....^,,,,——^ - .,1720 1748 1769 178S 18S0 1820 1840 SCAN'n-.r-1 i'-'-^ ' • " • i . i 1-r?^! ^•^R 19S49 2@;02 TIME
~n1—1
1 1 1
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C-i --J
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l3
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- IJ-1 1—i-1 •O 01 •fr03 r-.l i3> —
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I'lID MASS CHROMATOGRAtIS DAI-H; SEP2816 ttl@3/29/87 4;14:08 CftLI; CAL932587 #3SAMPLE! CASE 8@13!BATCH1/M.B./10.25GCOHDS.! G0M SP23::!l/•l^30.•••l06-2e0^25/•2e1^3-24^^e4.••••8RANGE; G1704,185n LABEL: N 5, 2,5 eiJftH; ft 1, 1.9 -1 S BASE; U 26, 3
SCANS 1784 TO 1859
,AV•-"—i———i———r-. 1729
ifi-4 ')
^M' cA -/I/ U ^ i '174t3ifl .W
iv^%/
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176niq. i n
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17881?;?";
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1813163.1813.
\' 1
182919;49
I1\Mf
' i184020; 62
^ ,,"\; \
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SCANS 1794 TO 1850HID MASS CHROMATOGRAtIS DATA; SEP281G ttlm--'29.'8? 4;14;@9 CflLI: CAL932587 »3SAMPLE: CASE S019;BATCH1/M.B./'10.25GCONDS.: 60N SP2331/100/-100-200e25..-2e@-240e4/8RANGE; G1704..1850 LABEL; N 5, 2.5 QUAHs A 1, 1.6 -I @ BASE: U 20, 3
MID HASS CHROtlATOGRAMS DATA: SEP2816 ttlS3/29/87 4;14;00 CALI! Cffl-032587 #3SAMPLE; CASE 8819:BATCH1/-M.B./10.25GCONOS.; e0M SP2331/l@S/l@0-20ee25/20Q-240i'4./8RANGE; G 1704,1850 LABEL; H 5, 2.5 QIJAN; A 1, 1.0 J
17584438.40487.
SCANS 1704 TO 1859
0 BASE; LI 29,17875574.5814S.
1720is-^
17401•"•.•:-l•-
182819;43
184020:92
[)^V t- ^v
HID RIC UnTn; SEP2al8 ftl SCANS 1704 TO 1S5809/23-'S7 5; 11; 69 CnLIs CRL092587 tt3SAMPLE: CRSE 8eil9;BATCHl/212-ei/19.11QCONDS.: 60N SP2331/'108/'100-286625/299-24064/8RANGE; G 1704,1850 LABEL: H 0, 4.6 fflJAHi H 0, 1.0 J 0 BASE; U 29, 3
100.0-i ^ i,90 13584,
^1760
A.'i i' \ I \
/ A / \1709 „ . _ _ _ _ ..-.---l7-36^ __-•-'' --'.—-' -^-—vil2_-.. ^_183(L-_..-,1S42 ^
1720 1749 1760 1780 I860 1820 1848 SCflNlfl-4''' r-;-^ iq. i!- i iq-":^ 1.9!3G 19;49 20;@2 TIME
imioNID MASS CHROHATOGRAMS DATA; SEP2818 #1 SCANS 1704 TO 1859e3-'23-'-S7 5 ill! 68 CALIi CALB32587 #3SAMPLE; CASE 8913!E;ATCHl/212-01/ie. 11GCOHDS.: 661"! SP233L'10Ei/10]3-20Se25./20£i-24£i@4.'8RANGE; G 1704,1859 LABEL! N 5, 2,5 i3UnHi A 1, 1,0 -I 0 BASE: LI 26, 3
"'I | ft
^\^\M\"—————I————————|————————I————————]————————]———————j————————I————————[————'————!—————-——]————————!——'————-^————————I————————[———•———-I
1763235.
ISO, 6-1 w'7' 244.\
^V328 _ | 1,,/V^. 328-038
i' - V " i \ ± @.5e^3
' .WVW^--^A^v4^V.^/^.u——•^——l———^———r——i——————^——————^i.^.———^——————^——————^——————,—i————^——————I———l——^——————^.———^——————^
17213 1748 1760 1788 I860 1826 1846 SCAH1P-.1-:' tfi.'-.c i q . i s I?-?"-! I1?;?!; 19;49 20!02 TIME
SCANS 1704 TO 185»3MID MASS CHRCIHATOGRAMS DnTn; SEP2S18 ftlS3/23/-S7 5 i l l ; 09 CftLI; CftL6325S7 lt3SAMPLE; CASE 8t319;BATCHl/212-81..'10.11GCOHDS.: e0N SF'2331/100.''10Ei-200@25.''2i30-240S4'SRANGE: G17@4,1850 LABEL: H 5. 2.5 i:iUnH; R 1, l . d . J 0 BASE; U 28, 3
SCAHS 1794 TO 1850M I D MASS CHROMATOGRHNS DUTA: SEP2818 ttl09--'23.-'S7 5!ll;S@ CflLIs CftL@92587 #3SAMPLE: CASE 8019;BATCHl/212-efl/16.11GCOHDS.: 60n SP2331/100/'l 00-200e25/20e-24064/SRANGE; G1704/1850 LABEL: N 5, 2.5 QUAH; A 1, 1.0 J 0 BASE; U 20,
17395126.4782:3.
/'•,
t^TTOH I D RIC DMA: SEP2317 »1 SCAHS 1784 TO 1858@9/23/S7 4;43;S3 CALi , CAL9325S7 (*3SAMPLE: CASE 8ei9;eHTCHl/212-94/'10.25GCOHDS.: b9N SP2331/iee/100-2@9@25/2e0-240e4/8RANGE: G 1794,1850 LABEL; N 9, 4,9 GIIKN: H U.. 1.9 J 9 BASE: LI 2S, 3
100.n-i ^i61
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172FI 1749 17e8 1789 1S90 182S 1849ip.4'i i'-'- •-i- i q - r i---i.-^, fq;0!: 13;49 W-NZ
smroM I D MASS CHROMATOGRANS DATA: SEP2817 ttl SCANS 1704 Tn 185fl99/23/87 4;43;69 CALI; CHLQ32587 S3SAMPLE; CASE S819;BATCH1/212-04/'10.25GCOHDS.! 60M SP2331/ 108/100-2a0@25.'200-240@4,-8RHHGE; G 1784,1850 LABEL: H 5, 2.5 lai.lRNj A I , 1.0 J 0 BASE; U 20; 3
17b2
20:^8.1G3£6.
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VIRONMENTAL PROTECTION AGENCYOffice of Enforcement
CHAIN OF CUSTODY RECORD
REGION 6 00/7- /OFirst International BIdg.. 1201 Elm St.
Dallas, Texas 75270
NO.
OF
CON-TAINERS
REMARKS
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linquished b'y: ISignaiurft' Date /Time I Received for Laboratory by;{Signature)
Date/Time RemarksA>/b i l l ct -&4a.Q'?0&</t/
Distribution: Original Accompanies Shipment; Copy to Coordinator Field Files 011496
^4rA QZ 01149'?
^ - w^-oTMS ANALYTICAL SERVICES, INC.
6376 Morenc; TrailIndianapolis, Indiana 46268317-291-5697
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analysts LcgbaokBdif i t iDnal Reportinc Farts
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TMS ANALYTICAL SERVICES, INC.TANDEM MASS SPECTROMETRY
6J/6 Morenct TraiiIndiflnapo^s, Indiana 46268JI7-291.5697
October 5, 1987
CLP Sample Management OfficeViar & Co.209 Madison S t . , Suite 200Alexandria, VA 22314To whom it may concern:Enclosed is the complete Sample Data Package for the analysis ofsamples for 2,3,7,8-TCDD according to the procedures specifiedunder CLP contract #7390.These samples were received as Case #8019, Batch #2 on September15. Results were sent by overnight courier on October 5 forarrival on the October 6 , 1987 due date.No special problems were experienced with these samples. On09/23/87, Tony Neskey from SMO called Dan Delinger from TMS tonotify the lab that Case #8910 Batch 2 should be Case #8019 Batch2. Tony Neskey called Dan Delinger again on 09/25/87 to explainthat the duplicate and spike samples for Case #8019 Batch #2 willbe included in Case #8019 Batch #3, therefore no B-4 Form will beincluded in this report. Adjustments were made by Kelly E. Mills,Sample Custodian, on 09/14/87. The results for all samples meetall the QA/QC requirements and all results should be consideredvalid.If you should have any questions regarding these data or thisreport, please feel free to contact me at (317)291-5697.
Very truly yours,
Dennis L . Heuring, P h . D .President
CC:USEPA EMSL/LV QA Division944 E . Harmon Ave.Executive Center, Rm 226Las Vegas, NV 89109
USEPA REGION VI LABORATORYMonterey Park Plaza - Bidg. C6608 Hornwood DriveHouston, TX 77074Attn: Melvin Ritter
ENCLOSURES:
^ ' ' - Wr-^TMS Analytical Services Inc.TMS6376 MORENCI TRAIL • TEL. <317) 291.5697 • INDIANAPOLIS, INDIANA a626STANOEM MASS SPECIBOMtTBV
FORM B-1S. TCDD SOIL DATA REPORT FORM Page 1 of 2
'77C.At^_________ Report Dace; ^/J^/^^-_____Lab; ~/^^ /]^a^77C.A^
Case/Batch Ho; ^O/^ /^______ Column: '^A^>33/________
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Field BlankInternal StandardRerunRecovery StandardNot Detected
ITMSTANOEM MASS SPtCTBOMElT
^MS Analytical Jervices Inc.6376 MOF1ENCI TRAIL • TEL. 817) 291.5697 • INDIANAPOLIS. INDIANA 46268
FORM B-1S. TCDD SOIL DATA REPORT FORM Page 2 of 2
Lab; ./^/.S / - ) m •^r-/c^ i.________ - Report Date: ' y / ^ ' y /f7____
Case/Batch Mo; efo/^ / / ? / ) TCH *<a Column; 3^ ^?3~S /________
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TANDEM MASS SPECTROMETRYTA/IS Analytical Services Inc.^9^6376 MORENCI TRAIL . TEL. Ql7> 291.5697 . INDIANAPOLIS, INDIANA 46266
FORM B-2 . . page 1 of 2
INITIAL CALIBEATIOil SUMMARY
Laboratory: "T m •S • \ ,•, a, L,-r,^- ^ L_
Case/Batch No.: . .Q-i J..
CC Solution AlternaCive:
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TANDEM MASS SPECTRQMETRY
TMS Analytical Services Inc.6376 MORENC] TRAII -.'nTEI-. ey) 291. S697 • INDIANAPOLIS. INDIANA 4626B
I11ITIAL C/iLIG .IIOH SU.'UIARK Page 2 of 2
Labocntoryl v ^\\, S ^ >-3 0. i- . . --r if-^ CC Solution Alternat ive: l l
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TMS Analytical Services Inc.6376 MOREr-ICI TRAIL • TEL. (317) Z91-5697 • INDIANAPOLIS. INDIANA 46268
FORM B-3
ROUTINE CALIBRATIOM SUMMARY
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FORM B-3
ROUTINE CALIBRATION SUMMARY
Laboratory; / /fiJy /ft^tH ^/77C^C.______ CC Solution Alternative: ^/_
Case/Batch Ho.; pPo/*? ~3^TC^ *'/ /1t^- Instrument ID: /^w/g^.0 ^/co 0 °
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Date
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259
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MID RIC DATA: SEP2883 #103/-28/87 21s 56; 08 CALIi CRL992587 #3SAMPLE; CAL 1 SOLH
SCAHS 1764 TO 1858
COHOS.: eeM SP233l/100/'160-20£i@25/-200-2'lFi@4/8RAHGE; G1794..1850 LABEL; N 9, 4.9 iaUAH; A 0, 1,9 J
1757@ BASES U 28, 3
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1722 1737 .-••'.-.--''
172S 1748r-;-^i-
1766 178Siq.Tl
1800f q - ^ f i
182819;49
184829; 02
T99TTOHID MASS CHROMATOGRAMS DATA; SEP23&3 #1 SCANS 1704 TO 185883.'-28--'87 21; 56; 08 C.ftLI; CAL892587 #3SAMPLE: CAL 1 SOLHCONDS.: G>3M SP2331/l@9.•-'100-2eO@25/20@-240@4/'8RANGE; G1704..1S50 LABEL: N 5. 2.5 QUAN: A 1. 1.6-1 0 BASE; 1.128, 3
1759276.2491. ,„.;, JUi
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^v^AA^Vv—-^^AM^V^^A^WV^W..1759800.
\ 328.0Sj' 1, ± 0.5E
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1720 1748 17ei3 1780 1899 1823 1849 SCAN'R-4 '> ^—v i q - ' r ' iq-?^ 19!^ l9;49 2@;02 . T I M E
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S99TTOHID MASS CHROMATOGRAtIS DATA; SEP2803 #1 SCANS 1704 TO 185009/23/87 21!56;80 CALIs CfiL992587 #3SAMPLE! CAL 1 SOLHCOHOS.; 60H SP2331/10e/108-200@25/-260-24@e4/8RANGE; G1704,1850 LABEL; H 5, 2.5 QUAH; A 1 , 1.0 J 0 BASE; U 20- 31757
4923.41529.
1728 1740 1769 1739 1S08 1828 184019:4"1 iH;^ !9sl" 13:23 19;3? 19:49 20:02
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S9STTOMID MASS CHROMATOGRAHS DATA; OCTulOl #1 SCANS 1704 T0 1850le/Sl/S? 13;03;0@ CALI; CftL@925S7 #3SftMPLE: CALIBRATION SOLN 1COMDS.: 6811 SP2331/'l@9/100-200e25.'2@0-240@4/SRAHGE: G1704,1850 LABEL; H 5, 2.5 BUnH: R 1, 1,0 J BASE; U 28, 3
17531180.933S.
(.0CO10
0
MID RIC DATA;CALI;
OCT0101 #1r:flL092587 #3le-'ei-'s? i3!83;00
SAMPLE: CALIBRATION SOLN 1COMDS.: 6@M SP2331/'100/100-200e25/'2e0-240@4/8RANGE; 01704,1859 LABEL; N Q, 4.0 QUAH; A
175Q
SCANS 1704 TO 1858
8, 1.0 J 0 BASE; LI 20, 3
170.3 1717 1726
1720lR-4''i
1740iK-^f"
17E3iq-IFl
17801^:2^
18201S!49
194020; 92
99STTOSCANS 1794 TO 1859MID RIC DATA; SEP2804 ttl
CALI; CAL032587 ft303/28/87 22s33;80SAMPLE: COLUMN PERFORMANCE MI>iCOHDS.: G9M SP2331/-100/iee-20@@25/20@-24e@4/SRANGE; 01794,1850 LABEL; H 9. 4.9 UUAH; A S, 1.0 J 0 BASE; LI 26; 3
1786
39^TTODATA: SEP2804 ttlC'rlLI; CAL092587 #3
MID MASS CHROMATOGRAMSe9/28--87 22; 33 seeSAMPLES COLUMN PERFORMANCE MlisCOHDS.: G0M SP2331/100/l@0-200e25-'290-24£i@4/8RANGE; G1794.1850 LABEL; H 5. 2.5 QLlHH; A 1, 1.0 J 0 BASE; U 28,
178817W 2345.2176. 2S114.17641. /
SCANS 1704 TO 1850
Z l i - D17641
/\/ I
/1742 i'4G5. .13731.
/ \ /.- - ^ . ^ ^
1 i ^
17572636. ,/"'i
212.:^l:Ai \i
1742 js.-i {J-^-- /3990. i'
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1729 1748 17e@ 17S8 1808 1828 1840IK-.I:'! ^•'^•' :;R 1"
' A1776 / i1126. /8321. ;
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17873069.26068.
/- /1499.12624. ; \
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OZ.STTOMID MASS CHROMATOGRAMS DATA: SEP2S04 #1e9-'28-'S7 22; 33; 00 CALI; CAL032587 <t3SAMPLE: COLUMN PERFORMANCE MIXCOUDS.; 60M SP2331/le0/•le@-2@0@25/200-24C^e4•/8RANGE; G1704.1858 LABEL; N 5, 2.5 QL1AH; A I/
SCANS 1794 TO 1859
1.0 J 0 BASE:1785121S1.104895.
U 2@/ 3
USTTODATA: SEP2827 #1CALI; CAL092587 #3
MID MASS CHROMATOGRAMS09/29/87 9s25s@0SAMPLE; COLUMN PERFORMANCE MI^:CONDS.: 60M SP2331 /• 1 QQ-' 1 ee-200@25-•2QQ-24 W. •••8RANGE: G1794..1850 LABEL; H 5, 2,5 EHJHH; A 1, 1.0 J 0 BASE; U 20, 3
17871418.
1758 19532-lies.10903.
SCANS 1704 TO 1859
HID MASS CHROIWTOGRAMS DATA: SEP2S27 #103/29/8? 3!25!90 CALI; CAL692587 #3SAMPLE; COLUMN PERFORMANCE MIXCOHDS.; 60M SP2331/-100/'l@9-200@25/-200-240e4/8RANGE: G1704-1859 LABEL: N 5, 2.5 QUAH: A
SCANS 1704 TO 1859
LI 20, 31 . 9 J 0 BASE;17857048.72647.
17573G30.36683.•-\
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17564559.46036.
A
1728l?;^
1740f f l -^R i^i- in
1780iq-'?.'i
1800l?!^
182019S49
184S2@; 02
SCANS 1704 TO 1850MID RIC DATA; SEP2627 #1CALI: CAL092587 #3@9/29-'87 3; 25; 00
SAMPLE; COLUMN PERFORMANCE MIXCOHDS.: 60M SP2331/10e/100-200e25/200-240@4/8RANGE; 01704,1850 LABEL: N 0. 4.0 QUAH; A
M I D RIC DATA; OCT8192 #1 SCANS 1784 TO 185010/@1/87 13; 3.3! 89 CAL1; CAL0325S7 #3SAMPLE; COLUMN PERFORMANCE MIXCOHDS.: G0M SP2331/'100/'100-200@25/[email protected]! G1704/1850 LABEL: H 6, 4.0 QW\: A 0, 1 .0 J 9 BASE: U 20; 3
1 ^ 4 25632
2,3.7,8 ITCOO
1745
^
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1720 1740 17e£i 1789 1890 1820 1849 SCAN!.-...i-. i,-..,.-r,- i,3.ir. iq, •;.-, i.-i..-.p; ^;49 ^;g2 yrME
SASTTOMID MASS CHROMATOGRAMS DATA: OCT0162 #1 SCANS 1704 TO 1850le-'ei/S? 13; 33:06 CALI: CAL692587 #3SAMPLE: COLUMN PERFORMANCE MIKCONOS.; 60M SP2331/ie8/ie9-200e25/290-24n@4.'8RANGE: G1764.1850 LABEL; N 5.. 2.5 QUAN; A 1, 1.6 J 0 BASE: U 26, 3
17771736.
"••-I i^. T-11889. ; 'i
A - A326 ,1 \ ''31. ; 320.03,; 'i ei33- f ' ± 8,50
1730 / \ I \ j \325. / \ / •••,,t \2962. { \ / | \-A--. / \
.,... .. A^L^U, __\.. ^^^_.^.__^__ .1 -^-^^<,, , , -..J.L:.-:^*:::::';)^..—— i — — — ~ ~ • • ^ ^ --^ f-•'"^ ^•" ——— • . . , . , - , •, | '-,
17771747 2176-
1*38.9-1 1339. liyb3" 217614785. / \
322 / 'i , / I 322.031\ i / \ ± S.50(
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MID MASS CHROMATOGRAMS DATA; 0070102 ttl SCANS 1794 TO 1S501@/'@1.-87 13;33s80 CTLI! CftL0925S7 #3SAMPLE: COLUMN PERFORMANCE MIKCOHDS.; 60M SP2331/'160/'100-2ee@25/200-24ee4/-8RANGE: G1794.1850 LABEL: N 5. 2.5 6UAH; A 1, 1.6 J 0 BASE; 1-1 20, 3
1774S297.
l^TTOMID RIC DATA: UCTeil0 #119.'01/87 20!l8s00 CALI: CALe325S7 #3SAMPLE: COLUMN PERFORMANCE MI;','COHDS.s 6W SP2331/ie0/-iae-209e25/2e0-240@4/8RRHGE: G1704,1356 LABEL: N 9, 4.6 QUftH: A
2,3.7,S
TCDD1752
SCANS 1704 TO 1858
BASE: U 20> 3
1735 /"——--../ 1817 1830
1728IR-.il-''
1748^-•.c,.-
1766t'l! iri
178019-?^
1800iq.^R
1S2019549
184020:02
DATA! OCTOlie #1CALI; CAL8925S7 #3
MID MASS CHROMATOGRAMS1@--'01./87 20! 18; 08SAMPLE; COLUMN PERFORMANCE MIXCONDS.! 60M SP2331/'100/'100-2ee@25/[email protected]"eRANGE; G1704-1859 LABEL; N 5. 2.5 lai-lRH; A 1. 1.8 J 8 BASE; U 23.. 3
17S3885.
1752 7265-733.
5830.
SCANS 1704 TO 1850
SCANS 1704 TO 1859MID MASS CHROMATOGRAMS DATA: OCT8110 #1CALl! CAL032587 #310/01/87 20!18;00
SAMPLE; COLUMN PERFORMANCE MIXCONDS.s 60M SP2331/109/100-280@25/200-24ee4/'8RANGE; G1704,185@ LABEL; N 5< 2.5 QUAN; A 1 ,
989TTOSCANS 1704 TO 1850i l IO RIC DATA; SEP2385 »1
@9/2S/87 23; 08! 08 CftLIi L:ftL892587 fr3SmPLE; CASE 8019;BATCH2/M.B./-9.3SGCONDS.: 6aM SP2331/100/10S-20e@25/'200-246@4./8RANGE: G 1704.1858 LABEL; N Q, 4.8 Q1JRH; ft 0/ BASE; LI 20, 31.0 -1 0
1784
011581
\J'^8bT•36166ZIs 'yen :3sya e i -e ' l 't y wm s-e •s H s-iaay-i essi't'ezio iaswa
8/'i•^^jt'^-00^.•'•S^^B^^^-09I/09l-•'I£S^dS N83 = •SON0338b-6/'a'N-/ZH3iya!SI88 3Sy3 S31dH9S
£tt Z8SZ6i3'19'3 snKJ 8B!88S£3 2S/-S2.-'680fi8i 01 wi\ SNU-JS ift sessd3s ••ww suyaaoiyMoaHo SSHM am
58STTOMID MASS CHROMATOGRANS DATA; SEP2805 6109/2S/87 23;83;89 CALI; CftL0325S7 #3SfiNPLE; CASE 8013;BHTCH2/T1.B./9.38GCOHDS.! 60M SP2331/100/l@S-2S6e25/20e-246@4/8RANGE! 01784,1850 LABEL; N 5, 2.5 QUHH; A 1, 1.0 J 9 BASE; U 29, 3
SCANS 1794 TO 185@
389TTO
MID MUSS CHROMftTOGRRlK D H I H ; £EP2Sa5 #1 SCflNS 1764 TO 1850eS^S/S? 23; 98; 09 CftLI; CHL632587 tt3SANPLE: CASE 8B19:BftTCH241.B./9.98GCOHDS. s E9M SP2331/'ie0/106-200@25/200-24t3e4/8RAHGE: G1704..1850 LABEL; H 5. 2.5 QUftHi ft 1, 1.8 J 0 BASE: U 28.. 3
17S45961.5™ 5976
1 '.
1754 / 12883, i' 1 •2G474. \ 332,69
A 1\- . . . J • J < . , ., „ . , . . , . .. ,... ^ . .,.-ri ...y...,,... ...,.. ,... , ....——^ .... . ,...^.. -p . ^^. ^—————^—————,17847317.m- 7352
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1753 )' I3665. j' i
" 33752. 1 \ '^.le/\ - | ± 8.56
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HID RIC rinTn; Oi::Tnie4 #1IS-'ei/S? 14; 43:08 CALI; CHL992537 S3SAMPLE! CASE 8013;BftTCH2/212-02/10.ieGCOHDS.: 6@M SP2331.•-•160/10^3-2e0e25.-•2S^3-24(;l.^4/•8RAHGE; G17@4,1S5@ LABEL; N 0, 4.>3 HIAH: A 0. 1,0 J
17?4
SCANS 1704 TO 1850
0 BASE; U 29, 3
1745!\
/ \_17l0 1720 1800 „ 1S10 1819 . , 1833
1720^•41
17fc.tJi q ; 1H
1786iq-7:^!
180019:36
!S2t319:49
184020; 02
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HID I'lASS CHROtlATOGRANS DATA! OL:T>3104 ftlle/'Sl-'S? 14; 43; 98 CALI; CAL0325S7 »3SAMPLE! CASE 8013!BATCH2/212-B2/ia.ieGCOHDS. i 6911 SP2331/l@0/ie0-2Sa@25./200-24ee4/3RANGE! G 1784,1850 LABEL; H 5. 2.5 QUHH; 9 1, 1.0 J 0 BASE; U 20. 3
SCANS 1704 TO 1S50
98STTOMID MASS CHROMATQGRAMS DATA; UCT@104 #110/01/87 14; 43; 09 CTiLI; CAL1332587 #3SAMPLE; CASE S019!BATCH2/212-82/-10.16GCONDS.: 60M SP2331/ie0./ie0-260e25.'209-24£i@4/8RANGE; G 1704,1856 LABEL: N 5, 2.5 QlJnH! A 1, 1 .9 J
SCANS l7@4 TO 1850
0 BASE; U 20, 3
MID MASS CHROMATCCRAMS DATA: i:iCTeil34 #110--'@1/87 14; 43; @@ CALL- CftLa925S7 #3SAMPLE: CASE 8019; BftTCH2/-212-02.-' 10.16GCONDS.; 60M SP2331/100./ia9-200@25/269-240i'4/SRANGE; G17@4,1350 LABEL: N 5, 2.5 iaUftH: H
17462049.17192.
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17452671.21083.
SCAHS 1764 TO 1859
BASE; U 20, 3
174Ur'i-^fi
18@S19;3G
18213IS; 49
184B20:02
98STTOSCftilS 1734 TO 1858MID RIC DnTH; SEi-'281^ i,l
BS/ZS/R? 2;'^!^ CftLI; CftLSS^SS?' 83SAMPLE! CASE 8019!BATCH2/' 212-88 9.94GCOHOS.! S0M SP2331/'100/'ieS-20£i@25.''2eS-340@4..'8RANGE; G 1704.1359 LftBEL; H 0, 4.9 QUHN: H 0, 1,8 J S BASE: LI 2!3, 3
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38STTOSCANS 17H4 TO 1850MID MASS CHROriATOGRAMS OATH: SEP281" #1
03--29/S7 2; 50; 86 CftLI; ?1692587 SAMPLE; CASE 8@19;BATCH2/ 212-S8 3.94GCOHDS.; e0M SP2331/ie0/'100-2e6e25-''200-24£i@4.'SRANGE; G 1794.1850 LABEL: H 5, 2.5 WW: A I / l .@ -I BASE; LI 2@, 31793
178.1339.
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36STTOM I D MUSS CHROMATOLRHMS t.;,iTni ^i-^OlS ^1 SCH!^ 1764 Tn le^fy9/'23-'a7 3; 46s Pi" ! , ' , ' I ; ^;L:ww K:"!SuMPLE: CASE 8Sl^iBnTCH2/212-03/lt;,l: :;GCOHDS.: GOU SP2331.-'189/100 -LWiCT/'liXi^i^-l/'SRHHGE; G1F04,185!3 LrtGEL: U 5, 2.5 QUnN; fl 1, 1.H J 0 BftSE! U 28, 3
17865';ie.
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96STTOMID RIC SMI- ; £;Li"'28i2 iil SC9H3 1764 TO 1S5999/29/-87 2; 23; 08 C, iL; ; CiiL;-i3250?' S3SAMPLE: CASE SS13;BATCH2/ 212-19 l(J.£i,"GCuHDS.: 60N SP2331/le9/l09-^i3el^25/2^.^:!-2:i;.^I/•8RANGE: G17o4,185S LHBEL: H 6. 4 , ,M ••"J.i^: H n., l.i3 J^.8 BuSE: U 23, 3
109,0-1 ^^
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1718 l^a/
,/ -.. .J"® ^13. ^s^ ^sse
1729 1748 i , ,.:' i?SQ I^HO 1829 1848 S£:HH
SCWIS 1754 TO 1S59H I D MASS a-iRONnTOGr:HNS U n i n ; S;l'2t;12 iil03/23/87 2s23!@3 C?ii..l; •-.•il-'^^Sy? ^3SAMPLE; CHSE eS13!B9TCH2' 212-19 16.137GCOHDS.! RUM SP2331/lU0/ie9--?ee@25/2CiO ^ lOe i . 8RHHGE: G1704,185Q LABEL; H 5. 2.5 i:^.;!, ii 1, i.S J 6 BuSE; 1 28. 3
253.077± 0,58:3
214.
328.638± 9.589
SCHHTINE
S69TTOIIID MASS CHROHATOGkHMS i j . i i . i : :::i;r^c:i.; iti&3-'23-'S7 2; 23; 89 0,^.1; CiiL?3^";?7 i*3SHNPLE! CASE S8i9!BHTCH2/ 212-19 13.^'GCOHDS.: E6M SP2331/l£lM/leM-20Ci^:;;.•2i-l;l .•-^J-i'-i.-'yRflMGE; GirS4,1859 LABEL; H '5; 2.5 y!,.N: fl 1, 1..0 J 0 BftSE; U 29. 3
SWuE 1764 TO 1S56
l .
|;:' ^±iz±Lib.-/'r1720 \?W
--I—1869
^ •'' \^VJ^.A^./
1S2S 1846I0;-'? 2'?•f'•':
369TTOM I D MASS CHROmTOGRnMS D n i . i ; SEK31;- ti.1 SCrtMS 1704 TO 185963/23/37 2; 23; 08 Ciil I i CALLUS? S3SHHPLE; CASE 8019;BATCH2/ 212-16 l0.e7'GCOHDS.: 60H SP2331/le0/le0-290l^23/2l::^-2•^(:,,^^.-8RANGE; G1794,1S50 Li-iBEL; H 5. 2,5 QUni i ; H 1, 1.0 J 0 BASE; 11 20, 3
17S36591.61884.
A
009TTOSCANS 1704 TO 1850MID RIC DAT)'!! SliP2318 ttl
09/23/37 l!27;£i0 CALIs CHL6325S7 1*3SrtMPLE; CASE 8619;BATCH 2/ 212-11 9.96GCOHDS.: 6eM SP2331/16@/ie0-280@25/200-24li@-t/8RAHGE; G1704,1850 LABEL: H 6. 4.9 IIJHH: n 8, 1.6 J Q BASE; U 29, 3
S50 1782
J7.10 _ J722 17;31_
17261?;- i~'
1749-r"
17RO 17S9<••!••-"!
1800iq-'SF
182819:49
184028; 02
T09TTO
M I D MASS CHROmTOGRANS LinTn: Skh'2810 til SCAHS 1704 TO 1850@3/23-'87 l!27i08 CHLI; •::?.l.e32537 »3SAMPLE; CASE 8919:BATCH 2/ 212-11 9.36GCONDS.: 60n SP2331/l£ie/[email protected]'2ue-240rs4/8RANGE; G 1704 ..1856 LABEL; N 5, 2.5 i3Unt!: H 1 , 1 . 0 J 0 BASE; IJ 20. 3
1755533.51n3.A
638.
259.077± 9.580
333.
328.098± 0.500
-,————^.———————_^--.. -_-,————^————i^————,————^————,————^——^,1726 1740 1766 17SS 1800 1820 1840 SCAN1R-43 r':-'"!" 14; 1'! 19:23 19!3K 19:49 29:02 TIME
S09TTO
MID MASS CHROMATOGRAMS Di:i lH; SEP2818 ftl SCANS 1704 TO 185B03/29.'-87 l!27 see CftLI; CsLe32537 #3SAMPLES CASE 8019:BATCH 2/ 212-11 9.96GCOHDS.; e0M SP2331/'10a.'-10t3-200@25/'2i3Fi-24ne4./£;RANGE: 51704,1959 LABEL! H 5, 2.5 QI-lHH; A 1, 1.0 -J 0 BASE; LI 20, 3
17542252.20640.f'l
'•••'•—— -—^-—-—--^Y^ --^^---—^^———^-"—-
2252,
320.09(± 0.58<
28S8,
322,09E± 0.50C
1720 1740 17£u 1780 1890 1820 1840 SCANif-.1 ' ' r--^- r-. .i , i I'l-"'"! iq- t f i 19;49 20;02 TIME
S09TTO
SCANS 1794 TO 1858MID MASS CHROHATOGRAHS DH-I-H: SEP2810 [email protected]/87 1; 27 i00 CALI; C.HL092587 #3SAMPLE; CASE 8019;BATCH 2/ 212-11 9.96GCOUDS.: 60M SP2331/ ie0/ie9-20e825/'2e0-24£i@4.'8RANGE: G1784,1859 LABEL: H 5, 2.5 QIJAH; H 1, l.S J 8 BASE: 1.1 2'S, 3
17826543.57514. 6592.
332.699± 6.580
8832.
17525419.
47214.
A 334.100t 0.500
1725lfi-4^
1745""-)--•1760i '"<- i n
1789iq-?'!
189919; 36
182919; 49
184029; 92
SCANTIME
U3/29/87 3il8;R9 Cn: i i LML=-02:-.8,'&3SAMPLE: CASE SS19;BATCH2/ 212-12 1 M - Q 2 GCOHDS.; e01'l CP2331/lU0/•leS-2Mei^2c;. 200-2^1^: .=;RANGE: G1794,185S LABEL; N 6. 4.0 i ^ ! , , i ; ;•) 3, 1.9 J 9 BASE; I-' 2H. 3
190.0- 17%
R I C 1 !,
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£1 i;:i OT ?5 GIt— d —i r'-i u'l•:I — 135 €••1 O?E ro co e- i0 —< 1.1-1 -Q:: •• LU -tl-3: r'"i Ln E: 's'1—1 <E (Si r -
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M I D MftSS CHROMATOGRRrlS Dr,Tii; SEF2314 Sl SCAHS 1704 TO 1S5899/23/87 SilSseo • CHLT; ^;,! R925°7 t"SAMPLE; CHSE 8919;BATCH?/ 212-12 IS.K.ICOHDS.; 6aM SP2331/le9/ln9-2UO!^25.•2^S•2•4^;l;'l.'SRHHGE; Gl794;185@ LHBEL; H 5. 2.5 •;!";,;!: i-i 1, 1.9 J @ BRSEi U 2@, 3
17864849.
4''i474.
309TTO
I'lID I-IASS CHROMftTOGRHi-15 C i . i l ! : - ^,Lr'2COa i?l SCHUS 1794 TO 1850S3-'23-'37 0! 53 8 08 C f t L I s C(iL0325i;7 it3SAMPLE: CASE 3019;BATCH 2/' 212-13 10.13GCOHDS.: 60M SP2^3l/le^)./l^:^a-2@9@25.'20l^-^•Wl•;.1-SRaHGE: 61704,1850 LABEL; H 5, 2.5 Ciln!!; f i 1, 1.9 J 0 BflSE; U 29, 3
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3T9TTOMID RIC DnTn; OCTuluS ttlli3--'ei/87 15;45;S@ CULI; CrtLe92587 #3SAMPLE: CASE S819:BftTCH2/212-14/16.09GCOHDS.: 6en SP2331-/10^/•lS6-20eS25.'•2^[email protected]: G1704.1350 LABEL; H 6, 4.8 ei.lHH; A £1.. 1.6 J
1777
1743
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SCANS 17i34 TO 1858
BASE: LI 29, 3
1711 1S99 1828 1849
17291R-.1-'
1749 178810.'-.'-;
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184920; 02
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90B-0I.'-<'I-3t3./ZH3iyasSI08 aSTO !3-1dH9S£# ^SSSbuTO snTO 89i5t'!SI 28/Te.'01i# SOTO.I.OO sn.i.ya SNbaoomMoaHO ss"u QIH
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SCAMS 1704 TO 1859HID MASS CHROt'lATOGRANS DiiTu; IXT0195 #1le-'ei/s? is; 45 see CULI! WLSSSS? #3SAMPLE; CASE 8el9!BftTCH2/•2l2-l4/•l^3.L1C^GCONDS.; e@M SP2331/•100/l£^0-2^3ee25.•-•200-24H•i!4/8RRHGE; G1784,185@ LABEL; H 5, 2.5 QUAt!; R 1, 1.8..I 9 BASE; U 20, 3
M I D MASS CHROWiTOCiRAt'15 Dnin; UCT01S5 #110.--01/S7 15!45;90 CALI; r:9LS325S7 tt3SAMPLE; CASE 8©19!BATCH2---212-14/iei.98GCOHDS.; eeM SP23:31/-190/'ie0-200e25/2eS-24S@4..'8RANGE: 01704,1850 LABEL; H 5, 2.5 i2LlhH; H
17481961.16532.
A
17482512.21652.A/ \
SCANS 1704 TO 1858
BASE; LI 20, 3
1720lK-4^
17461F!.C:1-;
1780l0''^
1800iq-W
1828l9;49
184020; 82
3T9TTOHID RIC U . i n i ; Sf2^ I H139/23/87 1;55!09 CiiLi! ChLCi925S7 fi3SAHPLE; CASE 8913!BATCH2/ 212-15 ii3.0::GCONDS.! 69M SP2331/'ie9/100-206e25.'20M-2-!&(i'4.-3RANGE: G1704,185@ LffiEL; H 0, 4,0 QUi'ill! H a, 1.8 J 6 BftSE; U 26, 3
1763
SCflUS 17u4 TO 1858
1753
1712 J .1G. i829 ... 1842_
-~1~17213 1749
~~}—17SU 186S
iq.--:i"182S1 3 - 4 3
1849PFrPi?
9T9TTOSCftrlS 1784 TO 1859N I D MASS C:HRCiMA"TCRnl')S Dmf,; SQ-'26il ftl
83/29/87 l!55;00 CriLli Ciil.F.32537 »3SHMPLE; CHSE 8019;BATi::H2/ 212-15 10.QMCOHDS.; 60M SP2331/100/le0-20^'e25./2u(^-24(3@.^/5RANGE; G1794,1S59 LABEL; N 5, 2.5 WCvh A 1. l.i3 J 0 BASE; U 2B, 3
1?54lib.
HID riftSS CHROHnTOGRnNS Oiffn; SLP2S11 ttl SCnHS 17u4 TO 1850R9.'29/37 ls55!@9 CaLIs Cfil-e32b87 ft3SftMPLEi CASE 8919!BATL:H2/' 212-15 la.EG'QCONDS.: RSM SP2331/ll:l0•'•160-2eee25-•2r!'j-;MR@•^/SRnHGE; G1784,1859 LABEL! H 5, 2.5 C'Ui .N; H 1, 1.0 J 0 BftSE: U 29, 3
1 r";.o3S4.
74.5-1 :•^-?!"'L
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100,9-1
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3T9TTOSCAHS 1764 TO 1850M I D PIC [inli"i; iXTOlUt, itl
ie-'i31/-37 16;14;89 CHLI; CAL9325S7 tt3SftMPLE: CHSE S013:BftTCH2/'212-16/10.11GCOHDS.; 6BM SP2331/10S/169-2Sue25/200-240@4/QRANGE; G1794.1850 LABEL; H 6, 4.6 eUn!!: A 0, 1.9 J 8 BASE; 1-1 28, 3
1774
1745
A1712 1724 ''•---.—l l.?94 1S15 is26 18.34
17201;';-.!-;
T"1749 1780
1''"'?0 1800)9-^
182919:49
184020; 02
SCANS 1704 TO 1850M I D MASS CHROMOTOGRHMS D H ( H ; ni::l-i310b #118/131/87 16;14s00 CHLi; C:HH:i325S7 #3SAriPLE; CASE 8019;BATCH2/212-16/1S.11GCorns.; 6@t'l SP2331.-'ie£i/ie6-26e@25./2aO-24£ie4.--3RftHGE: 61704,1850 LABEL: H 5, 2.5 QlfnH: H 1, 1.0 J 9 BASE: U 20, 3
1746109.79S.
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MID MASS CHROMATOGRAMS DATA: HCTU166 ttl SCANS 1784 TO 185910/01/87 16; 14;80 CALIi CHL9925S7 #3SfWLE; CASE 8019;BATCH2/'212-16/10.11GCOHDS.; 6611 SP2331/10a/100-200e25/20t3-24ni'4/8RANGE: G1784..1S50 LRBEL; H 5, 2.5 13".-.!); A 1.. 1.6 -.1 9 BASE: U 29, 3
17746651.52836.
17451262. / ',16383. / ',
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1745 )156S. / \13429. ; •,i' ''/ \., / \
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1729 1746 l?'"n 1789 1899 1829 13481f':4l i?"'-7!- r-i i.-i 19:?"; If l - 'W 19S49 29;@2
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9S9TTOM I D MASS CHROHATOGRHtIS DATA; SEP2SOb ftl SCANS 1764 TO 1650eS-^S/S? 23; 36; 68 CnLI; CALe92537 #3SAMPLE: CASE 8819;BATCH 2 - 212-17 9.39GCONDS.; 60M SP233l.'ie0/'ie0-200@25/-2e0-24i3@4/SRANGE: G1704,1853 LABEL; N 5- 2.5 QIJAH; A 1, 1.8 J 9 BASE; U 2Q, 3
17826371.
61454. 6496
332.89;±^ 6.591
334. W± 0.5@B
SCANTIME
: ' • r*^ • 'USEPA Contract Laboratory Pr&_ ^mCASE NO: ^g^J? BATCH NO: .,.,
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gC/?- OfTMS ANALYTICAL SERVICES, INC.
6-S76 Morenci TrailIndianapolis, Indiana W68M7-291-S697
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TMS ANALYTICAL SERVICES, INC.TANDEM MASS SPECTROMETRY
6376 Morenci TrailIndianapolis, Indiana 46268317-291-M7
October 7 , 1987
CLP Sample Management Office 1-''Viar & Co. c0
209 Madison S t . , Suite 200 w
Alexandria, VA 22314 ' ' •T~"i
To whom it may concern ••Enclosed is the complete Sample Data Package for the analysis ofsamples for 2,3 , 7 , 8 - T C D D according to the procedures specifiedunder CLP contract #7390.These samples were received as Case #8019, Batch #3 on September18. Results were sent by overnight courier on October 7 forarrival on the October 8, one day early of the October 9 , 1987due date.Ho special problems were experienced with these samples. On09/23/87, Tony Neskey from SMO called Dan Delinger from TMS tonotify the lab that Case #8910 Batch 3 should be Case #8019 Batch3 . Regarding the high recovery on sample #213-02(native spike),TMS is aware of this problem. Our initial concern prompted us tore-run this sample twice, using fresh spike solution andreagents. Results from these re-runs duplicated the initialcalculations. Dan Delinger from TMS contacted Tony Neskey fromSMO on 10/06/87 reqarding this discrepancy. Adjustments weremade by Kelly E . Mills, Sample Custodian, on 09/18/87. Theresults for all samples meet all the QA/QC requirements and allresults should be considered valid.If you should have any questions regarding these data or thisreport, please feel free to contact me at (31 7 ) 2 9 1 - 5 6 9 7 .
Very truly yours,
l^iw^^'/4^'^/ ;Dennis L. Heuring, Ph.D.President
CC:USEPA EMSL/LV QA Division944 E. Harmon Ave.Executive Center, Rm 226Las Vegas, NV 89109
USEPA REGION VI LABORATORYMonterey Park Plaza - Bidg. C6608 Hornwood DriveHouston, TX 77074Attn: Melvin Ritter
ENCLOSURES:
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TANOEM MASS SPECTROMETRY
TMS Analytical Services Inc.6376 MORENC1 TRAIL • TEL. Sl 7) 291 -5697 • INDIANAPOLIS. INDIANA 46268
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TAKOEM MASS SP6CTROMETRYTViS Analytical Services Inc^-^6376 MORENCI TRAIL . TEL. 017) 291-5697 . INDIANAPOLIS. INDIANA 46268
FORM B-2 . page 1 of 2
INITIAL CALIBRATION SUMMARY
Laboratory: T \-v'\ *S ^ CC Solution Alternative:
Case/Batch No. : "SQ 1 ' /3 Instrument ID: V; , p M:, ^ c:-c-i 0
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TANDEM MASS SPECTROMETBY
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FORM B-3
ROUTHIE CALIBRATION SUMMARY
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QUALmf CONTROL SUMMARY^3'fCO
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17871413.19532.
MID MASS CHROMATOGRAI'IS Unln: SEF2827 ifl SCANS 17Q4 TO 185009-'29/87 3!25;6@ rni.1; Crli^92537 %3SAMPLE; COLUMN PERFORMANCE !•!!/:CONDS,: 60H SP2331/16e/'ie0-20S@25/2Q6-2-l>^-).'aRANGE; 01704,1858 LABEL; N 5, 2.5 i:!l i,,!); n 1 , 1 .S J 0 BASE; U 29.. 3
17857048.72647.A
MID RIC DH'm; SEP3UU2 (i.1 SCANSB3./3i3/87 12; 44; 98 CAL!; i::nL".32537 S3SAMPLE :'COLUm PERFORI'lRNCE HISCOHDS.! 6eM SP233l.••••l£'S.•'l0e1-2^3^@25.•'2El^:l-2^^jli'4./8RANGE; G 1.. 24 LftBEL; H 6. 4.9 G!!JnHi A 0, 1.6 J 6 BASE; U 29,
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M I D MASS CHROMATOGRAM5 DATn: SEF3U02 ttl SCANSOATH: SEF3002 ttlCuLI; CAL092587 #309/30/87 12;44 sea
SAMPLE: COLUMN PERFORMANCE MIXCOHDS.: 60M SP2331/'160/'10S-200e25/2£ie-2-)U@4/-SRf-iHGE: G 1, 1S0 LABEL; H 5.. 2.5 i:'L!nH: A 1, 1.0 J 9 BflSE; U 20,
10080G7.70466.
SCAHS 1704 TO 185@MID RIC [!nT,i: SLP3UU9 ttlC^Lis CC1L0325S7 #303,'30..37 21; 32; 88
SAMPLE: COLUHH PERFORMANCE MI;-;CONDS.: 66M SP233l/l09/l09-2Qe@25/•2(1n-2•^h@4.^RflNGE; G1784,185@ LABEL! H S, 4.6 6U,iil ; H S, 1,6 J 0 BASE; U 28, 3
1775
--J. .'
TCDD
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1732 y17.lM1717^..--"'" "'"""
——i————^————^————^————1725 1749r-..,)--. r-.,'--r ! , - • • . n--i.-.-> iq -^ f i 19S49 20S02 TIME
3.7,8
1745
^
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17m 1780 1800 1828 1S4@ SCAN
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MID MUSS CHROMATOGRAHS HA'Ti.; £c:K-iMi33 f t l SCANS 1704 TO 185309-'3S/87 21; 32; @0 Cft l - I i !:.iiLEiS.;537 tt3SAMPLE; COLUMN PERFORMfiHCE MIfiCOHDS.: b0M SF2331/'100/10a-2@0@25-'[email protected]./8RRNGE: 01704,1850 LABEL; N 5, 2.5 UHi-i!!; n 1, 1.0 ..I 0 BASE: U 29, 3
17471531. 1777
-,, „ 12514. 15U0.~-•l ••'-•"[ i\ 119G7.
M I D MASS CHROMATOGRuMS l in in ; £tf-3lJU9 iil SCANS 1704 TO 1S5009.-'3e.'87 21; 32 sea C.i'iLli C:HLn325S7 B3SAMPLE; COLUMN PERFORHAHCE MI^CONDS.: G9M SP2331/lSe/10Q-2S0@25/-2eei--2<i8@-!/SRAHGE; 01704,1850 LrtEEL: H 5 , 2 . 5 QUnN; ft 1..^3-1 0 BASE: U 20, 3
1- i I" \J
£8 '-W?61
Spihi8SST
-I •-•tii6681 ffi.L[
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SI^T
01301
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:'an 33nyHaoJ::)3d nnrno:i ;3idnys£S ,:l3S?c.n'i!-3 ;'n".J @U!£S!£I ^S/tO/'St
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SCHHS 17B4 TO 185t3MID MnSS CHROtlnTOGRHMS 1'in'in; OCl 'C' ln2 ttlCriLS; ?1.652587 #310/81/87 13;33;@0
SAMPLE: COLIJNH PERFORMANCE HIKCOt-IDS.: 6011 SP2^^1/10£l/160-29u@25/2eO Sin^! 3RAHGE; G17@4,185S L9EEL: H 5. 2.5 W^ n 1, 1.8 J 0 B9SE; U 29. 3
17743297.
C3191.
——m—Jiif-——.^—i.-——.J
17fr'
174441S7. l35371. ;
n I/ \./ \
1 \ !/ ••:/ '-- -•'1
1744 I5571. |44579. t
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2i3 1749 l7i?;i•;1-: i^.-.r 1.-.;, .,
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1774,e439.:•!a4s;l.
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1730 1806 1828 1848ic..-.^ IQ.-.;- 19;49 20;C12
M I D RIC:l@--'@l.''87 2t3!l8!0@SAMPLE; COLUMN PERFORMANCE MIK
UriTn; iXTOHO <}1CnLI; Cn;..8325S7 #3
SCANS 17S4 TO 185t3
COHDS.: 66(1 SF2331-'10M/100-206@25-';6Ci-2Sr!£4.'eRfiUGE: 01794,1350 LhBEL; 1) 0, 4.S M l J i i N ; a 0, 1.6 J 0 BASE; U 28, 3
1 7C;1
TCDD
1719 V-._, _.., 18,64 ^ is_i7 i830
172n 174 Ft 1739 1899f a. "c 1829
1.9; 491S4B^Fro"
LIHI'H; iJCTHllU ttlChLI; CuL993537 ft3
1'IID MASS CHROt'lATOGRHMSIQ-'-Ol-'S? 29!lS!@i3SAMPLE; COLUMN PERFORMANCE MI;!COHDS.; 60H £P2331/109/•lS@-200l^25./2^^-2^0e4/8RANGE s G 1704.1859 LABEL; H 5, 2.5 I:!LIH(!! H 1. 1.9 J 0 BftSE: U 29, 3
17S3885.
17S 7a5-I" •J •J B
5830.
SCANS 1704 TO 1859
i1ID MASS CHROMATOGRHt'lS DnTn; UCTeilO ttl SCANS 1764 TO 185819/01.'S7 2S;18!eS CHLI; CAL1392537 #3SAMPLE: COLUMN PERFORMANCE M I KCOHDS.; 6@M SP2331/100/10Q-280@25/269-240@4/SRANGE: G 1784,1858 LABEL; N 5, 2.5 C.l...lnHi A 1, 1 .0.J @ BASE: 1-120, 3
17733982.33583.
F'9,0-1
334
-
„ .-. „ . ,- , , , . •-"---., - .-' ,---'——•X. /-————I -— -"•-—————- —— - ~~- -————- - - - ^ -
17794753.
4u5a3.
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1750 |' 1^13- j
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r"\ \1 l. ^
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1729 1740 17L.) 1789 1899 1820 1849i o . ' - - . , , . . ,-,- , . ; - < - i , — . i".^r: 19S49 20;92
SCANS 1764 TO 1850MID MASS CHROIWOGRAHS DATA: SEP30B7 #109/38/87 18!l9;@B CftLl! C:AL892587 #3SAMPLE; CASE 8ei9;BATCH3/'M.B./16.18GCOMDS.: Gen SP2331/'ie0/lCi0-200@25./'200-24e@4/8RANGE: G1704,1850 LABEL; N 5, 2.5 iaUAH; A 1 , 1 . 0 J 0 BASE; LI 29, 3
1778118.758. 146
253.67± 6.58
i i • i . i • 1 • 1 • i •
1737j ; 299. •^
1728 1740 1769 17S9 1800 1620 1840 SCANl0^ f!""13^ i q - m 19!?3 19S3G 19;49 20!02 .TI11E
^2872.
rv^^,/ ^ 328.09!l, • ' ± 0.50!.'-',f "•
' ,A
^VW^^/\A^uA^^
semoHID MASS CHROMATOGRAMS DATA; SEP30S7 ttl SCANS 1704 TO 1850eS-'-SQ/S? 18; 10s 09 CALIs CALS92587 #3SAMPLE; CASE SBlSsBATCHS/M.B./ie.18GCONDS.: 6011 SP2331/-l@@/10e-200e25/2e0-240@4/-8RANGE! G1764;1850 LABEL: H 5. 2.5 OIJAH: A 1, 1.8 J 0 BASE; U 28, 3
109,9-1 i 82.
32B J1 i/' i I I N / ^ ' ^ ^ A J i Hi i\h /\^jf'l/^^Vfft/ I ' ! l ' I v f'—L'————i———•J———]————————I————i———]————,———,————,—I——,————,————,———L,
3S.2-1 I ?4.
-:fot\^^^1729 1749 17E0 17SS I860 1329 1840 SCANIfi-d:? if;!^ l9;1.n 19;23 ?.9;3? 19:43 20!@2 TIME
JG^ i- m
MID MASS CHROMATOGRAMS DATA: SEP3007 #1 SCANS 1764 TO 185809/30/87 IS;18:06 CALIs CAL092587 #3SAMPLE! CftSE 8019:BATCH3/M.B./10.18GCOHDS.! 60M SP2331/'100/'ie0-200@25/20e-240@4/8RANGE; 01704,1850 LABEL; H 5, 2.5 GUAM:, A 1.. 1.0 J 0 BASE; IJ 29, 3
17£5295G.
76.5. y 29G81736 / \2198. i,18413. i \
332 _ / \ \ 332.89i) I i• \ ± 8.5S(
. . , i V[ V , _17653346.
18FI.O-, :^42b• 3880
1737 i \2722.22573. i 1
334 _ / \ l' \ 334.10(\ f \ ± 0-506
/ \I . , ''. >-. ', >————————
1729 1748 1769 1789 1800 1820 1840 SCAN'•'•••i''-' l0-"^ I ' - i - iu iq.'"''' i q -^K 19;49 28:02 TIME
I^TTOMID RIC DHTH: Lii::rei87 #1 SCANS 1764 TO 1850H3/01/87 17;15!S@ CHLIs r:ftLt392587 ft3SAMPLE: CASE 8013!BHTC:H3/212-19/9.96GCOHDS. : een sp233i/i0a/i0e-2aoe25/20i3-2-iEie'), sRANGE: G1794,1S50 LABEL: H 6.. 4.S QLK-iH: H 6^1.0 J 9 BASE; U 29, 3
169.6-1 {?{2 64704,
' / 1
^RIC_
1743 ,i i
A, I,/ \ / ^
_1711 1721' __-•' '"--_..........-'' '•---_____^__J897_ 18J8 1828 1848
I———————^—————————^————,————^.-.-.——-,_———]————i————j————,————|————i————)————i1720 1746 17S@ 1783 1889 1620 1840 SCANI;"-,-!'-' r-"1-!" 1 • " i - J i • i I'a-'?- 1.9:'!F !9;49 20;62 TIME
3gmoMID MASS CHROMATOGRAMS DATA; OCT0107 ttl SCAHS 1704 TO 185910/01/87 17;15!00 CALI; CALe32587 ft3SAMPLE: CASE 8019.-BATCH3/212-19/-9.96GCOHDS.: G0M SP2331.-'100/'100-209e25/'209-240@4/3RANGE! 01794,1856 LABEL; H 5, 2.5 QUAN! ft I / 1 .9J 0 BASE; U 29, 3
24.3. ^ 84
•:M. t"ll-L,———^———,——————,———^——L,———^———pJ——^———,—————,——L^—l—^174532e.
109.0-1 3W' 346
h/''323 _ i 328.03Sj \ ~ ± 0.50(
,/' ^ ^
"^^L^^^^^^ ..1720 1749 1766 1780 1S00 1820 1349 SCANiSi+'i I R - W 19: I M 19;?3 19;3K 19:49 20:02 TIME
3SATTOHID MASS CHROMATOGRAMS DATA; OCTS107 »1 SCANS 1784 TO 185810/01/87 17sl5!0e CfiLI; CAL892587 #3SAMPLE: CASE 8019:BATCH3/212-19./9.9eGCOHOS.: 60M SP233l/•l£10./l00-20ee25./2e0-24UlM.••8RANGE! G1764,1859 LABEL; N 5.. 2.5 QUrtH; A 1, 1.9 J Q BASE; U 20, 3
•32,7-i i 89.
-l ^Hrir.00.8-1 i 96.
•^^^>fft°———I—^———,———^———,———^_——_,———^———L,———^———,———^_I——^J——^——1-4
172S 1740 1FEO 17S0 1800 1820 1849 SCANr-'.)-: i.r..c;s i Q , m i.a.-"; iq-^'c ' 19;49 2@!02 TIME
:)mToMID MUSS CHR0MATOGRAMS DATA: OCT0107 #1 SCANS 1784 TO 185010/01/87 17!l5;89 CALI; CAL0925S7 #3SAMPLE: CASE 8919;BATCH3/212-19/-9.96GCOHDS.: 66M 5P2331/'100/'100-200e25/'200-240@4/-8RANGE: G1704..1850 LABEL; H 5; 2.5 QUAD: A 1, 1.0 J 0 BASE: IJ 20, 3
177428B90.
52. l-i '53539. ^ggg
f\332 _ / \ 332.69'
1 'i ± 0.50
1743 / \4186. / I
36442. ; \____XX. y \________——,——————,—-,—^———r-———r"——————r-^—r-"——i———i———i—•—'———i—"—'1772
34112.1Q9.0-1 311831. ^^
1}
334 _ | I 334.19E\ ± 0.508
1743 / \5111. '.46391. / \
1720 1740 1750 1780 1830 1320 1840 SCAN).-....I--. (C'.Cir IQ.ll-1 1(1,'1'3 IQ.'IC f.a..4Q ••M.i-r-i TTMC
rmioM I D RIC DATA; SEP3@93 #1 SCANS 1704 TO 185893/39/87 12!53!98 CHLI; CAL9925S7 #3SAMPLE; CASE 8919;BATCH3.-'212-29.-'-19.03GCOHDS.: 69M SP2331./199.••••109-290@25.••••2n0-24^:le4.'•8RANGE; G1794,1853 LABEL: H 0, 4.9 QIJnH: H 9, 1.9 J 9^ BASE: U 20, 3
l»30.9-i lj^8 10528
1759 |
A ll/ \ / \
^1713^. _ 1732 1713__.-•/ - '--...-_..•'''' ^1•S03^ , 1818 1829 ^^ .^'
——,——————————————^————,————^——.__,————^————,————^—————————^————,————j————i1729 1746 1750 17S9 1899 1826 1846 SCANi-":-.f-"; !.-••'-.- iq : ! . ' i l'3!"^ <9!^R 19;49 29:82 TIME
MID MASS CHROMATOGRAMS DATA; SEP3003 #1 SCANS 1704 TO 185009/33/S7 l2!53;0@ CALI; CAL1392587 #3SAMPLE: CASE 8013:BATCH3/212-20/10.63GCOHOS.: 6@t1 SP2331/109./10^3-2^0e25..'•200-24£[email protected]'8RANGE; G1704,185@ LABEL: H 5, 2.5 QUAHs A 1.. 1.0 J 0 BASE; U 20, 3
17E212G.ln45. ,
/i
f \r ' i 259-
.f /JV j MA-L,———^————,——i—LJ,———i———,——— .——,———^———,—I!—^———,———jJ——L,1761168.isee. ,r\/ '-I
328.;i A ± 0.!
^^ ,l,,>VTw/V^^^i—i--^————j————,——^——j—————i-L^:——j————i————F1————i————j————i——1—p-1———i————F-—J——i
i ~?--)rt i "•7.1 ra i ~7fi~f 4 ~?rtfi < ruirt < ft-^n < n ,1 n cT i
St^TTOMID MASS CHROMftTOGRANS DATA; SEP3303 #1 SCANS 1794 TO 185089/30/87 12s59;0@ CALI; CAL032587 #3SAMPLE; CASE 8B19:BATCH3/212-20/ie.03GCONDS.: eBM sp233i/iee/i00-2eee25.'[email protected]: G1704-1850 LABEL; N 5; 2.5 GUAH: A 1.. l.B J @ BASE: U 20; 3
1 )' C-1
410.87.4-j ^P" 443.
A/"' 111'
328 j '•, 328.89(' \ ± @.58(
,''' '\. v-^v-yr^^AAJL-—U^^^V^^^ .
Li-——(————————^———————!L|———————^————————I————————^————————^———1———^————————,——I————^—————Si——,———t————^————————|————————)- " < ' • • • |
176H484.
199.0-1 4^' 507.
322 ,' 1- 322.936f I ± 0.506
/ \.^^^AM^^/^AJVJ————^/^/v^A^^^^
1729 1749 1768 1780 1880 1820 1840 SCANlff.,1'-' l'-'-^- i q - f i - 1 19-^ iq-?R 19;49 20:02 TIME
SCANS 1784 TO 1850MID MASS CHROMATOGRAMS DATA; SEP30@3 ftlCHLS925S7 #3OS-WS? 12; 59; 0@ CALI:
SAMPLE; CASE 8019SBATCH3/212-29/10.03GCOHDS.; EOM SP233l./l0e.''le0-200e25/2£1^3-24^^e4./8RANGE; 01764-1850 LABEL! H 5.. 2.5 QIJHH: A 1. 1.0 -I U 29, 3
17532165.1739S.
A
1753253U,225S4.
172918;43
1740fP!-^
-'-T—17601 - I - 1 H
1780ll'?"?
1800
l.q!^182019; 49
184020:82
SCANS 1794 TO 1850N I D RIC Di:iTn; SEP3U94 ttle3./3R/87 13; 27; @8 Cr'iLI; CAL0325S7 »3SAMPLE: CASE 8@19;BftTC.H3/'212-21/10.07GCOHDS.; 6t3M SP2331./100/lS0-20@e25.'[email protected]; G17©4,1856 LAEEL! N 8, 4.S 6IJHHi ft 8.. 1.6 .-I @ BASE; LI 20,
1784
17.19 1719 1730••-./-•
1726lfl;4"!
1740IS-^h
180019;3G
132619; 49
1.34S•2Q;92
MID MASS CHRONATOGRAMS DATA; SEP3304 #109/36/87 13!27!@e Cfil-I; CRL8325S7 »3SAMPLE! CftSE 8013;BATCH3/212-21/10.07GCONOS.! G9M SP2331.-•180-•'16^^-20^^S25.''20^-24ue4,'8RANGE! G17t34,185@ LABEL: H 5, 2.5 Q1JAH; A 1, 1.0 J 8 BASE; U 23, 3
SCANS 1764 TO 1858
SCANS 1794 TO 1859MID MASS CHROMATOGRAMS DATA; SEP3a04 ttl69/36/37 13;27 see CflLI ; CHL032587 tt3SAMPLE: CASE 80l9:BATCH:3/212-21/10.e7GCOHDS.; 6@M £P2331./lt3a/l£[email protected]'2e£i-2-1i3@4/8RANGE; Q1764,1850 LABEL; N 5, 2.5 QIJHH: ft 1, 1.0 J 8 BftSE; U 2@, 3
smioMID MASS CHROMATOGRAHS DATA; SEP3064 #1 SCANS 1794 TO 185B99/30/87 13; 27;00 CALI; CAH332537 ft3SAMPLE! CASE 8919;BATCH3/212-21/18.i37GCOHDS.: 60M SP2331.''lQ()/ie0-20i3@25/2S0-240r-4.-8RANGE; G1704,1850 LABEL: H 5. 2.5 QUftH; A 1, 1.9 J 9 BASE; U 20, 3
17844634.
79.7. y4- 467;
332 1-^ I \ 332.0;1572. \ ± "•5t
15629. / \
A \_________/ V. J \____________I—————-.——|—————- ————|——«r- , ^ . , ,f ^—————,——„»——^—————l- • • • I -'n——'——=——1—————i
17845848.
109.8-1 55339' 586'
334 _ 1755 / l 334.1E2161. } \ ± 0.5C19545. \
\/ \ j \_______
- - i —•- - -|———'•i— "• -—[—=^—i———^.-•..^fa-*-^;———^—i • | ~ — i — — ( — — = — r - ° — — T ^ " ^ ~ ~ '1728 1740 1768 1789 1800 1820 1840 SCAN
3^TTOM I D RIC DHlH; SEP2S23 ttl SCANS 1704 TO 1858>33/'23--'87 7! 33; 08 Cf.LI; CHL6925S7 tt3SAMPLE: CASE 8^319;BATCH3/•212-22.-•le. 16GCONDS.: 6BM SP2331/ie0/109-20£)@25/2£ii3-2-in64./8RANGE; G1704;1856 LABEL; H 0, 4.6 G U i i M ; H 0, 1.0 J 0 .BASE; U 29, 3
103.0-1 17?7 1192'
j \
/
I \
/ '/ \
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_1709__ . 1727,, 17;3^_—. / '•--, ,-'' '''--- v.- , 1814_ 18241831 1849^
1720 1746 1.7M 1780 1809 1820 1S4@ SCAh1.:,.,!-, i,-,..-,- , . , . ie,,.-..-, ici.-.c i9;49 20;@2 TIME
3S^TTO
MID MASS CHROMATOGRAMS DATA; SEP2823 #1 SCANS 1794 TO 185099/29.-S7 7; 33 :W CALI; CnL.e'32587 #3SAMPLE: CASE 8919:BATCH3/212-22/-10.16GCOHDS.: 60M 5P2331/'160/'ie0-2a6e25.-'2u@-240@4/'eRAHGE: G1784,1859 LABEL: N 5, 2.5 iai..lRH; R 1, 1.9 J 6 BASE: U 20; 3
5S.7-1 94.
2-9- 1\ lU ^ •/v ^ \\^ it\V /| | |l,l^/'i^^^^i^Ti'^tel-"^ ______.,. .,._.,,J.,____I_____\ II IJ|
17G11:: .
16.3.0-1 ^r'" 160.1 l^
n
132"- M ^ , 328.098' V ''I I j| ± 0-500
^ tJ^1 !1729 174n i;-h') 17SS 18S0 1828 1849 SCftHM--,^ i : ; , - . - ; •-, , , f q - ^ I'?-'??; 19;49 20!02 TIME
FSATTOHID MASS CHROMATOGRAMS DHTA; SEP2S23 #1 SCftHS 1764 TO 1859§9/29/87 7s33s@i3 CuLI; CftL@925S7 #3SAMPLE: CASE 8019;BftTCH3/212-22/10.1GGCOHDS.; 60M SP2331/139/109-200@25/[email protected]£i@4--SRANGE: G1704..1859 LABEL: H 5, 2.5 iaUHH: H 1 . 1 . 6 J 0 BASE: U 20, 3
98,0-i >, 96.
i ^I'l 1 I ^ * / t!1 ?• I ' (
320 1 h I l l l l l ( li' i im I I ; h h I lf\ ,. 320-096•^W •' fir '"100.0-1 I 98.
••-:^/4'/ll^l•i\^W<|A/l•-•i/," • r i ' ' ^ ' •rw',1720 1748 l i F 9 1780 1800 1820 1840 SCHN1R:4^ r"'-^ i i - l M jq-:;'? iq!:?? 19;49 2@;02 TIME
39ATTOM I D MASS CHROmTOGRANS DntH: SEP2a23 Itl SCANS 1704 TO 1850e9/29.'e7 7!33;&3 CftLI; CHLH32587 tt3SAHPLE; CASE 8019;BATCH3/212-22/'10.16GCONDS.: 6611 SP2331/'190/186-200e25/2e6-24ei^/SRANGE; 131704,1856 LABEL: N 5, 2.5 QUAH! n 1, 1.5-1 9 BASE; U 29, 3
17873586.40012. „„,,7-i ^-. 3608.
:; _ 1757 ,1 I 332.8991321. ; \ ± 8.590151.. \
/ '"\ ! \
17874416.
,0-, 4906S- 4472.r\—i 1 i
i _ 1758 / '! 334,139l . / \ t 0-500
/'"\ / \/,;
172H 1749 1769 173£i 16B0 1S2@ 184S SCAN!" .< - . r?.c:p i . - , . ip , i'""^ iq;^ 19;49 29s02 TIME
29-LTTON I D RIC Dhi 'H.; Sl:.F'2a24 fli SCANS 1784 TO 185009--'29-'87 8!@l;e0 Cnl.L Cnl.e32537 #3SAMPLE; CASE 8@19!BHTCH3/'213-02/10.SSl:COHDS.: 60M SF2331/ie0/16e-200e25/2CiO-2-!a@l/8RRNGE: G 1794.1850 LABEL: H 0. 4.0 i3UnH; n 9, 1.0 J ^ d BASE; U 2Q, 3
109.6-1 ^i64 11952
I \A 1
/ ^I 'i In \i \ ' \,/ "., ' \.! ': i'
- ,--.——-17-1F^ L725-.1-73!. -.•-'"' "--——••'' ''•-._ _ 18.15 1822 ^1933 1844
1728 1748 u'&.i 17S9 1S9S 1828 1S49 SCAMl;-;.,)-; i.-.-i— i . . - ; . , , iq.-:^ iq.'iR 19; 49 28; 62 .TIME
!^TTOMID MUSS CHROHATOGRAHS D H I H : .i::P2;:.;24 Sl SCANS 1704 TO 185609/'29-'87 S!@l!i3S Cf iLI ; CfiLy 32537 tt3SAMPLES CASE 8019; BATCH3/213-62--10.88GCOHDS.; 60M SP2331/-ie0.-'100-266e25.'2HO-2-li:i@4./SRANGE: G1764..185S LABEL: H 5, 2.5 QUA! I; A 1. l.t3 J 0 BASE; LI 28, 3
IP&'i
l '-;-••••87.2-, ;„- 191?n^y ' i i i253 _ 'I.I 259.07
, 1 | ± 0.58
^^M '---v^,^^^¥Wl_<—^——————^—————,————I—^——————^_———... ^._ —..—^l————j———!——,—————^————1—,——i———^——1———i—————j———l_i_,
1757132.
lOO.S-i "''1]M1' 219
k ,328 _ / 'i| I 32S.S9!
I • ^ l !''i ± 0.50(
^^Uy ' -^A^\^[——I—,——————^——————I-H————-^——————^—_.. __ . . . . _-.,——--——^——1———,——————p(—————,——————^——I—1—,——————pi————L,
1726 1740 17EO 17SS 1809 1828 1840 SCANi'"';'l''i i"-'^ n - m f^ -?? l^"^ 19;49 2@;02 .T IME
RANGE; G1704,1850 LABEL; N 5, 2.5 Ul.lntl: A 1 ,1 .6 .1 3 BASE; U 2Q, 3
T
H.' 'i 320.ai \ ± e.5
/ \/\^^^^\/^L_._^^^^^^ ^A^_^^^,^\J^
•—'—i——>"—]———i———(———i———i- • - -—-i—•'——[———:—JL——f-^——i—'—'-]———i———[—-"—•-iI ' ^ C ' " !
l JO
7'73.
T- 79
/I!' j 322.0:
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^^ATTOHID NftSS CHROMATOGRAMS [IHTH; SEP2824 »1 SCANS 1784 TO 185989/29/87 S!@l:@9 Cftl-I; MLU92537 B3SAMPLE: CASE 8019;BATCH3/213-92/' 10.Q8GCONDS.: G9M SP2331/lS0/•l@0-2e0@25/2^'9-2^0@4/HRANGE; G 1794,1859 LABEL; H 5, 2.5 QLIHN: A 1, 1.9 J 6 BASE; U 20, 3
1785391_8.
73.4- ™- 3968.
332., ^ / I 332.9991^341'. / ± @•50e
i \/ "^ \
^, , 7 K . / , . V ,17844977.
ISS.a-, 50^- 50B@.
„. / \334 _ -tifii / i 334.19019^1, / I ± 9-500
^'N / \____y ^ 1 1 . ^ i^,_ ^ , .^1726 1749 1760 1789 18@9 1820 1848 SCAHl f l ? 4 ^ if-^fi n;).', iq.?3 19S3S 19:49 20!92 .TIME
' -S^TTOM I D RIC i : i n l i i ; '•:,l-'P.3nu5 Sl SCANS 1794 TO 185803/30/87 14; 25; 89 Cii!-l; ChL0325S7 ft3SAMPLE: CASE 8919;BHTCH3./213-03.-'[email protected].: 66M SP2331/iae/ie0-280e25/2i3t3-24n@4./8RANGE; G 1704,1850 LABEL; N 0, 4.3 QUfil!; A 8, 1.9 J _@ BASE: U 2@; 3
109.@-i lr85 25664,
^RIC_ |
17?6
f --; i
/ \
1 \ I \,/ \ i \
___IJ2Q 17:35 .JTH ,.'' ''"•--^-•! \•^-—-_^—^—^:m..^J^'3'2 . _ _
1720 1749 l;'n:i 1780 1809 1820 1846 SCANr-'-.i"' "~-^ I ' i - f : - io-?'i ^•'y, l9;49 20:02 TIME
SCANS 1764 TO 1850MID MASS CHROHATOGRhiNS09/38/87 14;25;SOSAMPLE; CASE SBlSiBATChB/riS-iSS/'lFi.Q.iGCONDS.; 60M SP233l/'190/108-2eee25/2eO-2-!i:i@t/3RANGE: G 17Q4,1859 LABEL: N 5, 2.5 I"!UHN; 1-1 1 . 1 . 0 J 0 BASE; 1-120, 3
SCANS 1764 TO 1853MID MASS CHROtlHTOGRHNS iJnT,-i; ^?3003 ft l03/30/87 14; 25; 09 CuLli WLH325S7 »3SAMPLE; CASE S019:E;ATi::H3/-213-n3.'ie.S4GCOHDS.; 60M £P2331/ie0/10e-2M9@25./2uei-24ue4.'3RANGE; £1704,1:353 LABEL; H 5, 2.5 QUnH: H 1, 1.0 J 0 BASE: LI 20, 3
MID MftSS CHRCiMATOQRAMS DnTn: SEP38@5 ttl83/39/87 14;25;OS CHLI! CaL092587 83SAMPLE; CASE S919:BATCH3/213-03.-'19.04GCONDS.; GeM £P23^l/•lB0.•/l£^^^-2aE1l!25.•'20U-2•lOel^.••SRANGE: Gl ('94/185B LABEL; N 5, 2.5 l!UnH! A 1, 1 .0 J 0 BASE: U 20,
17859872.
33487.
SCAMS 1704 TO 1859
3416.3bl8b.r\
~s———'"17S512832.127057.
M
i.5&4959.
4953G.
-.--'
1720lK;4''i
1748f o > R
18£1@19-3G
132013:49
184920:02
t9^TTOHID RIC l iHln ; ;;B'3ei':i6 #1 SCANS 1784 TO 185S83/39/87 18; 38; 69 Cnl-Ii Ci',LF02587 it3SAMPLE; CASE 8ei9;BATCH3/213-03 D U F / l H . B I GCONDS.; G0M SP2331/189/100-260625/200.2.iui? I •8RANGE: G1704,1S50 LABEL; H 8, 4.Q I JH, , ! ) ; i-i 6, 1.9 J @ BASE; U 20. 3
1785
M
\"'•--.— ISie 1827 18421713 ,1723
1729 1746 17hn 1780 1800 1828 1840 SCAN1p.,i-. i^.-.r . - ; . i ^ iq-"? iq -W 19;43 20;02 TINE
MIO MASS CHROMATOGRAMS DrtTn; SEP30n6 #1 SCANS 1704 TO 1858R3/39/87 18:38!08 CALI; CHL032587 tt3SAMPLE; CASE S019;BATCH3./213-03 DllF'.-'in.UlGCONDS.: 68ri SP233l./l0e1/l£1L^-2£1ee25.•20El-24^!@4,'8RAHGE; G1764.1S5S LABEL; H 5, 2.5 OUft;!; H 1.. 1.9 J 0 BASE; 1-1 20; 3
;•' '
172S 1748
SCANS 1764 TO 1859MID MASS CHROmTOGRAMS DnTn; ;.hF3u>36 ttles/se/sp is; 38; @e CHi-ii ?1-592537 »3SAMPLE; CASE 8919;BATCH3./213-03 DlJP/l>3.i31GCOHDS.: G9I1 SP2331/lua-'10e-206@25/'2eO-2-l&£4/8RANGE; Gl7@4,1850 LABEL: H 5, 2.5 RU^i; H 1 . 1 .8 J 0 BASE: U 2B, 3
MID MASS CHROMATOGRflMS UH-TH; £EP30u6 #1 SCANS 1704 TO 1859e9--3e/87 18;38;e0 ffiLIi CnL8925S7 »3SAMPLE; CASE 8819:BATCH3/213-03 Dl-IP.-i .J.OlGCOHDS.: 68N SP2331/ie0.'lUO-230825/2UU-2.10@4/8RAHGE: G1704.1858 LABEL; H 5, 2.5 (li.^i!; H 1., 1.0 J 0 BASE; U 29, 3
178715723.188579.
A- 1\5376. 1 \- ^ ^
/ \. / <—^——"r" ""•'"•—-'-i—'—r- - T-— ~^-'————>——-r-—"•"•111'11111111•1"|—•""--'——i——'178519488.
234280.
(\1756 / ',63-14. ,1. ;• ^
/ \ „ / \1729 174S i 7 . 1788 1869 1820 ' 1846 SCAN
1 C <-^" i0!^ 13!49 20SS2 T I M E
39moM I D R I C P h l i - i ; SEF2S2G Sl SCANS 1704 TO 185689/29/87 8; 57:69 C.'iLl; Ci,LS325S7 »3SAMPLE: CASE 8019:BATCH3/'213-01/10.64GCDHOS.! 60M SP2331/180/100-209r.'25/20i3-2'lni-4/-8RANGE: G1784,185@ LABEL: N 0. 4.0 QLliiH; A u, 1.0 J 0 BASE: LI 29, 3
1784
MID MASS CHRONATOGRAMS [ lulu: SEP232G ttl63/23/87 S!57;Si3 CfiLl i Ci:iLu32537 #3SAMPLE; CASE 8ei9!BATCH3/213-81.''19.64GCONDS.: 6911 SP2331/100/168-200625 •••26k)-2'10i;!4.'8RANGE! G17>34..1S5u LABEL; H 5, 2.5 i;!Unt!i R 1, 1.9 ..I
SCANS 1704 TO 1850
Ci BASE: LI 20, 3
L9.LTTOMID HASS CHROt'lHTOGRnHS PnTn; £Lf2o2G ttl SCANS 1794 TO 185083-'29/87 8!57;88 CHLI; CftL0325S7 tt3SAMPLE: CASE 8919; BATCH3/213-01 /16.84 GCOHDS.: 68M SP2331.'100/100-2CiMi»25. 2nu-2-10@4.. c;RAHGE; G 1764,1859 LABEL; H 5, 2.5 QLlHll; H 1, 1.6 J 8 BASE; LI 28, 3
175939:;.•'-" i-'t1- 413
A1' l| 1738
/ \ ^. ^l/ \ p,,Aj \ i-J \\\r} !\ A^ MA/ML . -..-1,/< -A\A/v^\ AA rU,A AMV '-,1 V y ' , ' '; '"' ^J \; ^ \ f I/ V \-i v V •
1757452.y- 478
f\. i
/ ''i ^8 %2.e3
'i ,A„' 1. ./ ^,-
M/\'V-v^A/vi^------..--^.JV^'——^AsA^A/^A^v^1728 1740 17i::n 17SO 1800 1S20 1840 SCANi;..^ i'-..^ i \ i , , iq.o'5 (q .aR i9;49 2a;02 TIME
MID MASS CHROHATOGRHt'lS I:IHTM: SEP2326 ttl SCANS 1794 TO 1850@a--'2a--s? 8;57;e0 CALI; CALQSSSS? #3SAMPLE: CASE 8619; BATCH3/-213-01 /• 10.04';COHDS.: 69M SP2331/ie£i/10e-200@25/2e0-246@4/8RANGE: G1704,1S5S LABEL; N 5, 2.5 QIJAif; H 1, l .@ J 6 BASE; U 26, 3
17844360.43215.
A
A„ /16323. J 1
/•••-. ; \
1 \ \' \. / \
/ \ \] •••.. 1 \
/ "••- .•' \ —
4360,
332.99:± 0.53(
1729 1740 \7W 1788 1800 1829 1840 SCAN19-4'-! (•"'•FF < q - i 0 iq-?'"( ^•-PK 19!49 20S02 TIME