carbon nanotube applications in engg

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    CARBON NANOTUBEAPPLICATIONS IN ENGG

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    CONTENTS

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    INTRODUCTION

    PROPERTIES OF CARBON NANOTUBES

    APPLICATIONS CONCLUSION

    REFERENCES

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    INTRODUCTION

    A carbon nanotube is a sheet of carbon atoms joined in

    a pattern of hexagons and rolled into cylinder.

    They are several micrometers in length and a few

    nanometers in diameter, resulting in a larger length-to-

    diameter ratio of up to 132,000,000:1.

    Nanotubes are members of the fullerene structural

    family, which also includes the spherical buckyballs.

    The ends of a nanotube might be open or capped with a

    hemisphere of the buckyball structure.

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    TYPES OF CNTs

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    Figure 1: (a) Armchair,(b) zigzag, and (c) chiral shaped single Figure 2: Multi-wall carbon nanotubes

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    PROPERTIES OF CARBON NANOTUBES

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    Properties Numerical valuesTypical diameter 1-2nm

    Typical length 100-1000nm

    Resistivity at 300k 10-4-10-3 cm(metallic)

    10 cm (semiconductor)

    Current density 107-108A cm-2

    Thermal conductivity at 300k 20-300Wm-1K-1

    Thermal stability 2800 C (vacuum )

    750 C (air)

    Elastic modulus 1000-3000GPa, harder

    than steel

    Table 1: Properties of carbon nanotubes

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    APPLICATIONS

    PLANAR MICRO SUPERCAPACITOR

    A supercapacitor is a charge storage device composed of

    two electrodes with electrolyte in between.

    1-Butyl-3-methylimidazoliumtetrafluoro-borate

    ([BMIM] [BF4]) with its high breakdown voltage

    of3V was used as the electrolyte

    PDMS cap limit the flow of electrolyte

    within a fixed 5mmx7mm CNT region.

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    Figure 3: Schematic of planar micro

    supercapacitor using aligned, 3DCNT forest electrode

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    PRINCIPAL OF PLANAR MICRO SUPERCAPACITOR

    under a biased voltage, the positive and negative ions

    in electrolyte will separate, migrate and accumulate

    around the electrode surface, forming a nm-thin layer

    called electro-chemical double layer (EDL) whichenhances the capacitance.

    Moreover the porous electrodes maximize the EDL

    phenomenon and give supercapacitors an

    astonishingly high value of specific capacitance

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    ADVANTAGES OF PLANAR MICRO SUPERCAPACITOR

    The demonstration of the capability of "planar"

    structure for supercapacitors could inspire new

    architecture in circuit.

    CNT-covered supercapacitor has generated a specific

    capacitance of 428gf/cm2, three orders higher than

    those merely using metal electrodes.

    The samples show an excellent charge efficiency of

    92% and a robust cycling stability.

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    ELECTRONIC APPLICATIONS

    Due to the miniaturization of the computers, there is an

    increasing demand in increasing the number of switches in a

    chip.

    The metal wires with small diameter are used to do the

    interconnections between the computer and switches.

    A decrease in the diameter of a wire in turn increases the

    resistance and hence, the wire generates heat due to the flow

    of current.

    CNT have smaller dimensions and low resistivity. 9

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    ELECTRONIC APPLICATIONS (contd)

    Field effect transistor

    Figure 4: a) CNT based field effect transistor (b) Charactericstics

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    ELECTRONIC APPLICATIONS (contd)

    CNT switches

    Parallel carbon nanotube are placed on silicon substrate .

    The top array and the bottom array are perpendicular to

    each other and are not in contact .

    The crossing point

    represents switches .

    It is controlled by

    passing current through

    the tubes.

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    Figure 5: CNT switch arrays on a silicon substrate

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    ULTRA SMALL SINGLE WALLED CARBON

    NANOTUBE PRESSURE SENSORS

    The SWNT strain gauges are embedded between double

    layer membrane of 70nm SiO2 and 70nm of Al203

    These oxide layers are used to protect it from the

    environment.

    The SWNT is contacted in the

    form of FET

    The change in the resistance is

    used to measure the pressure

    These are more sensitive and more efficient

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    CONCLUSION

    The applications of CNT ensure a bright future for

    these materials.

    Attractive characteristics of CNTs have made

    researcher to fabricate products using CNT.

    Nanotubes are very user-friendly, very robust,

    they can also act as excellent model systems for

    learning manipulation at a nanometer scale.

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    REFERENCES

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    1. S.P.Basavaraju, A Text Book of Engineering Physics ,2010, 554-561

    2. M. R. Srinivasan, New Age International Publishers ,

    Physics for Engineers, 714-721

    3. V. Rajendran, Tata Mcgraw-Hill , EngineeringPhysics , 2009,27.22-27.31

    4.YQ. Jiang, Q. Zhou, and L. Lin , PLANAR MEMS

    SUPERCAPACITOR USINGCARBON NANOTUBE

    FORESTS, IEEE paper.5.T Helbling, S. Drittenbass, L. Durrer, C. Roman, C.

    Hierold, ULTRA SMALL SINGLE WALLED CARBON

    NANOTUBE PRESSURE SENSORS Micro and

    Nanosystems, IEEE paper.

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    THANK YOU!