car & home care - brb · pdf fileexterior car polish ... tire/rim care interior...
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Car Care
Surface CareWash and Rinse Aid
Exterior Car polish
Windscreen & glass cleaners
Tire/Rim Care
Interior Trim/Dashboard
Leather renovators
Home Care
Surface CareFurniture and wood polishes
Floor polish
Metal/stainless steel polish
Shoe & Leather care
Glass cleaners
Carpet cleaning products
Tile grout sealers
Antistatic solutions
Home Care
Laundry CareLaundry detergents additives
Fabric softeners additives
Dry cleaning
3
segments
What is a Polish ?
Polish = a temporary coating that enhances and protects the
substrate to which it is applied
Enhances by cleaning and increasing gloss/color
Protects by depositing a barrier film that repels water and
also gives a degree of dirt repellency
• Ease of application - Lubricant
• Polish cleaning ability - increase surface wettability
• Ease of polishing - lubricant, less effort to polish
• Gloss / Shine
• Increase Colour Intensity (depth of gloss)
• Surface Protection - Durability & Detergent Resistance
• Water Repellency – Long lasting
• Streakability - reduces “streaking” of polish
• Surface Smoothness/slip - less easy for dirt to adhere
Why are silicones used in Car Care?
CHARACTERISTIC
Low surface tension
Strong Si-O & Si-C bonds
High R.I:(1.375 -1.403)
Low intermolecular forces
(high chain flexibility)
Methyl groups
Low Glass Transition
Characteristics of Silicones
BENEFIT
Spreads on most surfaces
UV, oxidative, thermal &
chemical stability
Gloss
Lubricity & high permeability,
low surface friction
Water repellency
Liquids at high molecular weight
Silicones for the Car Care industry
Silicone Emulsions & Silicone Oils
- BRB Sempure 35, Sempure 60 & 66
- BRB Sempure HV 6500 & BRB Sempure 1997
- BRB Silicone Oils 50, 350, 1000, 12.500, 60.000 cSt
Aminofunctional Silicones
- BRB Sempure 3733, BRB Sempure 135
Paintable Silicones
- BRB Sempure 5332, BRB Alkyl Aryl Fluid
Volatile Silicones
- BRB CM 40, CM 50, Silicone oil 0,65 cst
Silicone Glycols
- BRB 526, 6373, 356
Ease of Application – Streak resistance
Improved Cleaning - Low surface tension, increases surface wetting.
Allows more intimate contact between the abrasives/solvents
and surface
Polishing - Lubrication properties makes this much easier
Depth of Gloss / Color
Water repellency - Forms a lower surface tension film that
promotes water beading
Slip - Gives a smooth/lower friction surface
Silicone emulsions : benefits
Silicone emulsions & oils: range
Sempure 35 & 60/6635 or 60% non-ionic emulsion of mid viscosity PDMS for general purpose polish formulations
Sempure HV 650060% non-ionic emulsion of high & low viscosity PDMS blend for premium polish formulationsOptimized balance between ease of application, spreading,gloss & durability
Sempure 199755% non-ionic emulsion of high viscosity PDMS for superior shine and long durability
Silicone oils 50, 350, 1.000, 12.500, 60.000 cStFor customers who want to emulsify by themselves and fine tune their own emulsions
Formulation of Silicone oils
Can be formulated into
Solvent in water emulsions, normally use 50-1000 cSt PDMS
Water in solvent - can include high visc fluids
Polish formulations - use a combination of high/medium
viscosity fluids to optimize benefits
3 : 1 : 1
350 1000 60.000
ease of use / optimise gloss / durability
Formulation properties
Oil soluble, not water soluble
Medium viscosity: easier application & emulsification
Higher viscosity: better protection & conditioning
Defoaming properties
Properties optimization by
formulating silicone oils
TYPE GLOSS DURABILITY EASY WETTING
PROTECTION TO APPLY SPREADING
PDMS (50cs) ## some ##### ####
PDMS (350cs) #### # #### ###
PDMS (1000cs) ##### ## ### ##
PDMS (12.500cs) ## ### ## #
PDMS (60.000cs) # #### # -
Aminofunctional Fluids for
durability• Polar amine groups effectively anchors the product to substrate
-> physical attraction to negatively charged surfaces
• Reactive grades crosslink to form a polymer film with high
detergent resistance and effective protection,
The amino functionality ensures a firm anchoring of the polish to the paintwork
NH2 NH2 NH2
+ + +
Paint ------------------------------------------
- - -
Reactive groups crosslink
How is durability achieved
Aminofunctional Fluids: range
BRB Sempure 373340% cationic emulsion of amino silicone for extended durability and slip
BRB Sempure 135 NEW35% non-ionic micro-emulsion for car care shampoo and windscreen washes
formulations (water repellency, gloss, durability, antifog)
Polish
Gloss
Ease of UseDurability
Silicone oil 1000
Silicone oil 350BRB Sempure 3733 or
BRB Sempure 135
Paintable Silicones
The Silicones listed below are all capable of being over-painted
Required for special polishes before car body repair work
or customizing
BRB Sempure 5332 Paintable 50% non-ionic emulsion of alkyl aryl silicone
BRB Alkyl Aryl Fluid
For customers who want to emulsify by themselves
Also volatile Fluids are over-paintable:
BRB CM 40
BRB CM 50
BRB Silicone oil 0.65 cst
Volatile FluidsApplications
Replace solvent as carriers in polish formulations (for “solventless” solvent
formulations)
Good spreading and easy to rub out
Cleaners-lift and remove dirt, low surface tension increases surface wettability,
provides more contact between abrasives & surface
Typical Properties / Benefits
Oil, alcohol solubility
Volatile
Non-greasy
Good spreadability/wetting
Leaves no residue
Colorless/odorless
Safe for most common surfaces
Product range
BRB CM 50 (cyclic)
BRB CM 40 (cyclic)
Silicone oil 0,65 cst (linear)
depending on required rate of evaporation
Silicone GlycolsApplications
Designed for formulating stable water in silicone emulsions or emulsions in which
volatile silicones make up the oil phase. Emulsions based on silicone glycols are less
greasy than typical water in oil products.
Typical Properties / Benefits
Foam booster / foam quality
Water/alcohol dispersible
Spreading, wetting agents
- Low surface tension
- Improve cleaning of oils & greases
Antifogging
Lubricity
Emulsification, dispersing agents
Product range
BRB 526
BRB 6373
BRB 356 (trisiloxane - superspreader)
Silicones for Car CareApplication selector guide
Water
based
Solvent
based
Wash and
Rinse Aid
Exterior car
polish/
conditioner
Glass
Care
Tire/
Rim
Care
Interior
Trim/
Dashboard
Leather
Silicone oils o o o o o
Silicone emulsions
o o o o o
Aminofunctionalsilicones (oils/emulsions)
o o o o o
Alkyl Aryl silicones
o o
Volatile silicones o o
Silicone glycols o o o
Silicones for Car CarePerformance characteristics
Shine Durability Ease of use Wetting
Silicone oils50 – 1000 cSt10.000 – 60.000 cSt
▲
▲ ▲
▲ ▲
Silicone emulsionsSempure 35, 60 & 66Sempure HV 6500Sempure 1997
▲
▲
▲
▲
▲
▲
▲
▲
▲
Aminofunctional silicones Sempure 3733Sempure 135BRB 864 / 869
▲
▲
▲
▲
▲
▲
▲
▲
Alkyl Aryl siliconesBRB Alkyl Aryl Fluid & Sempure 5332 ▲ ▲ ▲ ▲
Volatile siliconesSilicone oil 0,65 cSt, CM40, CM50 ▲ ▲
Silicone glycolsBRB 526 / 356 / 6373 ▲ ▲
Home - Surface Care applications
• Furniture and wood polish
Shine ingredients in liquid o/w furniture care emulsions providing
full surface conditioning & protection
• Floor polish additives
Active ingredients in o/w emulsions or solvent-based floor care
formulations providing a durable non-slip but easy-to-polish
protective film
• Shoe & leather care
High gloss, lubrication for sponges. Useful spreading, leveling &
wetting of shoe polishes
• Metal & Glass cleaners (+ mirrors & Shower cabinet sprays)
Offers transient shine, anti-streak by slow drying and anti-fogging
• Carpet cleaners
Defoamers are widely used in ‘foam-cleaning’ machines –
Rugdoctor
• Plant care
Aids gloss enhancement in leaf-shine products
Silicones for Surface Care
Silicone Oils
Solvent-based formulations basis or for emulsion production
Silicone Emulsions
Gloss & water repellent additive for water-based polish
Volatile Silicones
Replace organic solvent as carriers in polish formulations
Silicone Glycols
Foam boosters and wetting agents in floor & surface cleaners
Amino-functional Silicones
Provide durability & detergent resistance to surface care
products
Silicone resins
Provide enhanced film forming & water-repellency
Silicone antifoams
Foam control in floor polish and carpet cleaners
Inhibits foam development in formulations, aids bottle filling
BRB surface care product rangeSilicone oils & Silicone emulsions
BRB Silicone Oils 50, 350, 1000, 12.500, 60.000 cSt
BRB Sempure 35, Sempure 60
BRB Sempure 1997
BRB Sempure HV 6500
Volatile Silicones
BRB CM 40, CM 50, Silicone oil 0,65 cst
Silicone Glycols
BRB 526, 6373, BRB 356 NEW
Aminofunctional Emulsions
BRB Sempure 3733, Sempure 230 NEW
Silicone resins
BRB TMS
Silicone antifoams
BRB Snapsil RE 10, 20
BRB Snapsil 100
New Polyether modified Trisiloxane
• BRB 356 - properties• Superspreading surfactant based on trisiloxane ethoxylate• Outstanding surface tension reduction• Water soluble
• Benefits• Improves spray coverage• Excellent penetration, antifogging and sheeting properties• Reduces surface tension already at very low level (0,1%)
New for hard surface cleaners
• BRB Sempure 230 - properties• 30% active, micro-emulsion of silicone quaternium
polymer• Specifically developed for cleaning formulations• Offers shine and protection to ceramics, glass and
painted surfaces
• Benefits• Hydrophobising film former• Reduces formation of streaks and scale on tiles and glass• Increases the durability of water based polishes• Easy to formulate into aqueous blends
• Typical use : 0,5% as received
Silicone Antifoams
• BRB Snapsil RE 10, 20• Alkali resistant, silicone based antifoam emulsions• Specifically developed for technical applications and to
be used in a broad pH• Good high temperature performance• Excellent knockdown as well as defoaming performance• RE 10 : 15 % active content• RE 20 : 30 % active content
• BRB Snapsil 100• Highly effective, silicone based antifoam compound
which has been developed specifically for non-aqueous system
• Outstanding reliability and versatility • Excellent knockdown
Surface care: product selector
Product Shoe / Leather Care
Furniture Polish Cleaners
Silicone oils 50 to 60,000 cSt
X X
Silicone emulsionsSempure 35 & 60Sempure HV 6500 & Sempure 1997
X X X
Volatile siliconesSilicone oil 0,65 cSt, CM40, CM50
X
Silicone glycolsBRB 356, 526, 6373
X
Aminofunctional silicones Sempure 3733Sempure 230BRB 864 / 869
X X X
Silicone resinsBRB TMS
X X
AntifoamsBRB Snapsil RE 10, 20, Snapsil 100
X
Home Care segments
Laundry Care
Laundry detergents additives
Fabric softeners additives
Dry cleaning
Laundry Care applications
Requires a license from GreenEarth Cleaning
• Laundry detergentsSilicone antifoams prevent and knock down foam that occurs during
consumer use & during manufacture
For liquid, powder, tablet detergents
• Fabric softenersSilicones emulsions incorporated into fabric softeners & ironing aids
Enhanced softness, improves iron-glide and better water absorbency
• Dry cleaningAlternative to perchlorethylene
Silicone route is nontoxic, nonhazardous waste
Gentler on garments and does not cause colour loss
Usually requires spotting agents
Silicones for Laundry Care
Silicone antifoams
Foam control in liquid detergents & fabric conditioners
Antifoam systems for powder detergents
(post-addition or spray on)
Silicone Glycols
Wetting agent, ease of ironing benefit in liquid laundry
tablets
Silicone Emulsions
Softness, anti-wrinkle, ease of ironing and water
absorbency for fabric softeners
Volatile Silicones
Dry cleaning solvent
Laundry Care product range
Silicone antifoams
BRB Snapsil RE 10, RE 20
BRB Snapsil 100
BRB Snapsil 20LD NEW
Silicone Glycols
BRB 526
Silicone Emulsions
BRB Sempure 35, 60
BRB Sempure 3733
BRB Sempure 270 Under development
Volatile Silicones
BRB CM 50
New Antifoam for Laundry Care
• BRB Snapsil 20LD • 20% active, highly effective white emulsion
• Ideal for opaque liquid detergents
New Silicones for Laundry Care
• BRB Sempure 270 - properties• 70% active, micro-emulsion of Quat Polyether terpolymer• Specifically developed for fabric treatment• Recommended for use in rinse-cycle laundry products. • Compatible in aqueous dispersion with organic softeners
(e.g. esterquats). • Typical formulation contains 2.5% BRB Sempure 270 and
15% organics.• Post-addition with moderate agitation
• Benefits• Deposits onto fabric from the rinse cycle
• Enhance softness (silicones have a silky feel attenuating
the ‘greasier’ organics)
• Promotes ease ironing
• Improve water absorbency
Laundry care: product selector
Product Liquid laundry
detergent
Liquid laundry tablets
Powder laundry
detergents
Fabric softeners
Dry Cleaning
BRB Snapsil RE 10, 20 X
BRB Snapsil 100 X X
BRB Snapsil 20LD X
BRB 526 X
BRB Sempure 35 & 60 X
BRB Sempure 3733 & 270 X
BRB CM 50 X