bruno bock · e-mail: [email protected] mexico merkinter, s.a. méxico, d.f. – mexico ......
TRANSCRIPT
BRUNO BOCK THIO-CHEMICAL-S
Mono- and Multifunctional
Thiocompounds as Chain
Transfer Agents in Radical
Polymerization Processes
Malaysia, Singapore, Thailand, Vietnam
Worlée-Chemie GmbHPetaling Jaya – MalaysiaPhone: +60 3 7118 2001 / 2003Fax: +60 3 7118 2004E-Mail: [email protected]
Mexico
Merkinter, S.A.México, D.F. – MexicoPhone: +52 55 5662 0983Fax: +52 55 5662 0984E-Mail: [email protected]
New Zealand
APS PolychemAuckland – New ZealandPhone: +64 9 270 1538Fax: +64 9 276 7231www.apsg.co.nz
Pakistan
LAHORE ESSCHEM (Pvt) Ltd.Rua São Benedito, Lahore – PakistanPhone: +92 42 36317501Fax: +92 42 36317505E-Mail: [email protected]
Spain
Worlée-Chemie GmbHBarcelona – SpainPhone & Fax: +34 93 778 11 86E-Mail: [email protected]
Taiwan
Dodecyl CorporationTaipei – TaiwanPhone: +886 (0)2 2764 5131Fax: +886 (0)2 2763 2778E-Mail: [email protected]
Turkey
Alfred Paluka & Co. Istanbul – TurkeyPhone: +90 212 245 1246Fax: +90 212 252 4458E-Mail: [email protected]
S
Built on Tradition
Customers Solution
– Monofunctional water soluble Mercaptocarboxylic Acids e.g. for the polymerization of Acrylic Acid and Methacrylic Acid
– Monofunctional water insoluble Esters of Mercaptocarboxylic Acids e.g. for polymerization of SBR, BR.
– Multifunctional water insoluble Esters of the Mercaptocarboxylic Acids e.g. for Acrylic Ceramics
The company Bruno Bock is one of the world’s leading
producers of Mercaptocarboxylic Acids and its
derivatives. Based on these Mercaptocarboxylic Acids
different multifunctional Mercaptocompounds which
are called Polythiols are produced. The range of
products includes compounds of different functionality
and molecular weights. Polythiols are applicable
manifold as reactive cross linking-agents in Coatings,
Adhesives and Sealants. Here they can be used
together with Isocyanates, Epoxies and Unsaturated
Compounds. All reactions can also be performed by
UV or electron beam curing. Among its high reactivity
these compounds show a low viscosity which makes
them interesting for VOC-conform Coatings.
On customer request also special Polythiols based on
Polyester polyols and Polyetherpolyols can be
synthesised.
To offer our customers optimal technical support,
we have established in 2010 a new Technical Service
Center for Coatings, Adhesives & Sealants. Our
intention is to answer your technical questions, give
recommendations for formulations and assist in
problem-solving.
Benefit from our expertise and state-of-the-art
laboratory equipment. Troubleshooting and new
product development can all be done in our
laboratories.
www.brunobock.de
We offer as CTA’s
CTA Product Range
Water soluble CTA’s Monofunctional Water insoluble CTA’s Multifunctional Water insoluble CTA’s
TGA 3-MPA 2-EHTG IOTG C13TG 2-EHMP IOMP BuMP C13MPTHIOCURE
PETMPTHIOCURE
TMPMPTHIOCURE
GDMPTHIOCURE
PETMATHIOCURE
TMPMATHIOCURE
GDMA
ChemicalDescription
Thioglycolic Acid
3-Mercapto-propionic Acid
2-Ethylhexyl Thioglycolate
Iso-Octyl Thioglycolate
Iso-Tridecyl Thioglycolate
2-Ethylhexyl 3-Mercapto-propionate
Iso-Octyl 3-Mercapto-propionate
n-Butyl 3-Mercapto-propionate
Iso-Tridecyl 3-Mercapto-propionate
Pentaerythritol Tetra-
3-Mercapto-propionate
Trimethylol-propane
Tri-3-mercapto-propionate
Glycol Di-3-Mercapto-
propionate
Pentaerythritol Tetramercapto-
acetate
Trimethylol-propane
Trimercapto-acetate
Glycol Dimercapto-
acetate
Molecular Weight
92,1 106,1 204,3 205,1 274,1 218,4 219,1 162,3 288,1 488,6 398,6 238,3 432,5 356,5 210,2
SH-Content%w/w
35,5 30,8 16,1 16 12 15,1 15 20,3 11,5 26 24 26,8 29 26,5 30,5
SH- functionality 1 1 1 1 1 1 1 1 1 4 3 2 4 3 2
Registrations
CAS-No. 68-11-1 107-96-0 7659-86-1 25103-09-7 57417-85-3 50448-95-8 30374-01-7 16215-21-71040871-35-91)
50727-77-02) 7575-23-7 33007-83-9 22504-50-3 10193-99-4 10193-96-1 123-81-9
EuropeREACh
registered registered registered registered phase in phase in registered phase in registered registered pre-registered pre-registered pre-registered pre-registered pre-registered
USATSCA + + + + + + + + + + + + + + +
CanadaDSL/NDSL + + + + + + + + + + + + + + +
AustralienAICS + + + + – + + + + + + + + – –
KoreaECL + + + + – + + + – + + + + – –
JapanENCS + + + + + + + + + + – – + + –
PhillipinesPICSS + + + + – – – + – + + – – – +
New ZealandNZIoC + + + + – – – + – + – – – – +
ChinaIECSC + + + + – – – + – + + – + – +
SwitzerlandSWISS + + + + – – – – – + – – + + +
We offer as CTA’s
Water soluble CTA’s Monofunctional Water insoluble CTA’s Multifunctional Water insoluble CTA’s
TGA 3-MPA 2-EHTG IOTG C13TG 2-EHMP IOMP BuMP C13MPTHIOCURE
PETMPTHIOCURE
TMPMPTHIOCURE
GDMPTHIOCURE
PETMATHIOCURETMPMA
THIOCUREGDMA
ChemicalDescription
Thioglycolic Acid
3-Mercapto-propionic Acid
2-Ethylhexyl Thioglycolate
Iso-Octyl Thioglycolate
Iso-Tridecyl Thioglycolate
2-Ethylhexyl 3-Mercapto-propionate
Iso-Octyl 3-Mercapto-propionate
n-Butyl 3-Mercapto-propionate
Iso-Tridecyl 3-Mercapto-propionate
Pentaerythritol Tetra-
3-Mercapto-propionate
Trimethylol-propane
Tri-3-mercapto-propionate
Glycol Di-3-Mercapto-
propionate
Pentaerythritol Tetramercapto-
acetate
Trimethylol-propane
Trimercapto-acetate
Glycol Dimercapto-
acetate
Molecular Weight
92,1 106,1 204,3 205,1 274,1 218,4 219,1 162,3 288,1 488,6 398,6 238,3 432,5 356,5 210,2
SH-Content%w/w
35,5 30,8 16,1 16 12 15,1 15 20,3 11,5 26 24 26,8 29 26,5 30,5
SH- functionality 1 1 1 1 1 1 1 1 1 4 3 2 4 3 2
Registrations
CAS-No. 68-11-1 107-96-0 7659-86-1 25103-09-7 57417-85-3 50448-95-8 30374-01-7 16215-21-71040871-35-91)
50727-77-02) 7575-23-7 33007-83-9 22504-50-3 10193-99-4 10193-96-1 123-81-9
EuropeREACh
registered registered registered registered phase in phase in registered phase in registered registered pre-registered pre-registered pre-registered pre-registered pre-registered
USATSCA + + + + + + + + + + + + + + +
CanadaDSL/NDSL + + + + + + + + + + + + + + +
AustralienAICS + + + + – + + + + + + + + – –
KoreaECL + + + + – + + + – + + + + – –
JapanENCS + + + + + + + + + + – – + + –
PhillipinesPICSS + + + + – – – + – + + – – – +
New ZealandNZIoC + + + + – – – + – + – – – – +
ChinaIECSC + + + + – – – + – + + – + – +
SwitzerlandSWISS + + + + – – – – – + – – + + +
1) New CAS-No.2) Old CAS-No.
BRUNO BOCK Chemische Fabrik GmbH & Co. KG is a privately owned
enterprise, founded 1937 in Hamburg as a trading company later
specializing in manufacturing of ORGANIC SULFUR CHEMICALS.
Production of Thioglycolic Acid started 1950. In 1968 the company
outgrew the available facilities in Hamburg and moved to Marschacht on
the southern bank of the river Elbe 30 km east of Hamburg. In the 1990s
the production of 3-Mercaptopropionic Acid, Thiolactic Acid and their
derivatives like Polythiols started.
In September 2005 BRUNO BOCK acquired the Evans Chemetics
business with its production site in Waterloo, NY, establishing
EVANS CHEMETICS LP as fully owned subsidiary in the USA. Since
January 2006 Evans Chemetics LP with its headquarter located now in
Teaneck, NJ, distributes also BRUNO BOCK products in the USA which
are only produced in Germany. See also www.evans-chemetics.com
We at BRUNO BOCK maintain with an innovative and highly skilled lean
organization and long, steady and successful experiences in the global
marketplace a commitment to our esteemed customer base. In this
regard, our foremost goal is to provide unmatched quality and undivided
dedication to our customers.
Our product line is flexible and reliable. Sustainability of our products
drives us continuously to develop better qualities with improved
processes under permanent control of our environment.
Company Information
BRUNO BOCK THIO-CHEMICAL-S
Acrylic Ceramic
Rubber
Rubber
Dispersions
BRUNO BOCK THIO-CHEMICAL-S
Your contact partners
China
Worlée (Shanghai) Trading Co., Ltd.Shanghai – ChinaPhone: +86 21 624 725 46Fax: +86 21 624 725 48E-Mail: [email protected]
Great Britain
Lake Chemicals & Minerals Ltd.Redditch – Great BritainPhone: +44 1527 594 630Fax: +44 1527 594 640www.lakecm.co.uk
India
Worlée-Chemie India Private LimitedNavi Mumbai – IndiaPhone: +91 22 2778 1042Fax: +91 22 2778 1043E-Mail: [email protected]
Iran
Grodab Chemie GmbHHamburg – GermanyPhone: +49 (0)40 601 1560Fax: +49 (0)40 601 4048E-Mail: [email protected]
Italy
Esperis S.p.A.Milano – ItalyPhone: +39 02 891 222 19Fax: +39 02 891 222 57E-Mail: [email protected]
Japan
Pacific Partners YC Inc.Musashino-City, Tokyo – JapanPhone: +81 422 272561Fax: +81 422 272562E-Mail: [email protected]
Korea
Young Shin Industrial., Co.Seoul – KoreaPhone: +82 2 577 6731~2Fax: +82 2 577 6734E-Mail: [email protected]
Malaysia, Singapore, Thailand, Vietnam
Worlée-Chemie GmbHPetaling Jaya – MalaysiaPhone: +60 3 7118 2001 / 2003Fax: +60 3 7118 2004E-Mail: [email protected]
Mexico
Merkinter, S.A.México, D.F. – MexicoPhone: +52 55 5662 0983Fax: +52 55 5662 0984E-Mail: [email protected]
New Zealand
APS PolychemAuckland – New ZealandPhone: +64 9 270 1538Fax: +64 9 276 7231www.apsg.co.nz
Pakistan
LAHORE ESSCHEM (Pvt) Ltd.Rua São Benedito, Lahore – PakistanPhone: +92 42 36317501Fax: +92 42 36317505E-Mail: [email protected]
Spain
Worlée-Chemie GmbHBarcelona – SpainPhone & Fax: +34 93 778 11 86E-Mail: [email protected]
Taiwan
Dodecyl CorporationTaipei – TaiwanPhone: +886 (0)2 2764 5131Fax: +886 (0)2 2763 2778E-Mail: [email protected]
Turkey
Alfred Paluka & Co. Istanbul – TurkeyPhone: +90 212 245 1246Fax: +90 212 252 4458E-Mail: [email protected]
Principal in Germany
Bruno Bock Chemische Fabrik GmbH & Co KGEichholzer Straße 2321436 MarschachtPhone: +49 (0) 4176 9098 0Fax: +49 (0) 4176 1396www.brunobock.de Principal in USA
Evans Chemetics LPTeaneck, New Jersey – USAPhone: +1 (201) 992 3100Fax: +1 (201) 992 3101www.evans-chemetics.com
Argentina
Lanpex S.A.Buenos Aires – ArgentinaPhone: +54 11 4362 4821Fax: +54 11 4362 4800 E-Mail: [email protected]
Australia
APS Healthcare a division ofNuplex Industries (Aust) Pty LtdSeven Hills – NSW – AustraliaPhone: +61 (0)2 98394100Fax: +61 (0)2 98380218E-Mail: [email protected]
BeNeLux
Brenntag Nederland BVLoosdrecht – The NetherlandsPhone: +31 35 5889 200Fax: +31 35 5824 364E-Mail: [email protected]
Brazil
MultiquimIndústria Comércio Import. Export. LtdaSão Paulo – BrazilPhone: +55 11 5524 0596Fax: +55 11 5524 6217E-Mail: [email protected]
Canada
Aldert Chemicals Ltd.Toronto, Ontario – CanadaPhone: +1 416 236 4222Fax: +1 416 236 4216E-Mail: [email protected]