biological filtration: methods for monitoring ... - pnws-awwa · pacific northwest awwa annual...
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BIOLOGICAL FILTRATION:
METHODS FOR MONITORING AND CONTROL
Pacific Northwest AWWA Annual Conference
April 30, 2015
Jennifer Hooper (Smith) and Patrick Evans (CDM Smith)
Mark LeChevallier,
Orren Schneider,
Lauren Weinrich, and Patrick Jjemba (American Water)
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Biological Filtration
GAC Filter
Filter media
with biofilm
Biofilm = bacteria + extra
polymeric substances
Granular media filtration operated for the dual
purpose of particle removal and removal of
biodegradable organic matter by biological
oxidation
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Conventional Filtration vs. Biological Filtration
Conventional
Filtration
Cl2
Aerobic
Biological
Filtration
Cl2
Anoxic
Biological
Filtration
Cl2
Electron
Donor
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Design Guidelines for Biological Filters
• There are no industry-standard guidelines for designing biological filters
• Ten States Standards does not contain recommendations for design of biological filters
• Ten States Standards states that biological filters may be considered based on pilot studies pre-approved by the reviewing authority
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Biological Filter Design and Management
Biological Filters
• Empty bed contact time
• Compounds targeted for removal
– AOC, BDOC
– Carboxylic acids, Aldehydes and Ketones
– DBP formation potental
– Geosmin & MIB
• Media Type
• Pre-oxidation
• Nutrients
Conventional Filters
• L/D ratio
• Media type
• Media effective size
• Media uniformity coefficient
• Filter loading rate
• Backwash rate & duration
• Backwash auxiliary scour type
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Level of control over parameters influencing biological filtration
Degree of Control () or Effect (t)
Parameter None Low Moderate High
Media Type t
Chlorination t
Filtration rate (EBCT) t
Backwashing method t
BOM loading t
Temperature t
Time since startup t
Source: Huck et al. 2000 (AwwaRF Report 90793)
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Empty Bed Contact Time for Various Plants with GAC Biological Filters
0
5
10
15
20
Design EBCT (min)
Source: WRF Project 4231
Slow Sand Filters
20+ min
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Backwashing Options for Biological Filters
• Probable backwashing intervals at 24 hours
• Simultaneous air and water (collapsed pulsing condition), followed by a standard water fluidization; not found to be detrimental to AOC reduction (many utilities)
• Non-chlorinated backwash water (most common)
• Chlorinated backwash (some still use)
– Chlorine does decrease biomass
– BOM removal much less affected
– Chlorine in air/water improves initial turbidity spike, improves headloss
• Monitor effluent microbial activity
Data from Huck et al. WQTC 1998
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Backwashing Strategies by 21 Utilities with Biological Filters
0%
20%
40%
60%
80%
100%
Surface Sweeping Surface Wash Air Scour ChlorinatedBackwash
ChloraminatedBackwash
Non-ChlorinatedBackwash
Source: WRF Project 4231
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How Do We Monitor & Control Biological Filters Today?
• Surface Loading Rate
• Pre-Oxidant Concentration
• Coagulant Concentration
• Backwash Duration
• Post-Backwash Rest Duration
• Backwash Disinfectant
• Differential Pressure
• Turbidity
• Particle counts
• Biomass (ATP)
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0%
10%
20%
30%
40%
50%
60%
70%
80%
90%
100%
Monitoring Parameters
No samples
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Monitoring and Control Tool Box
Water Research Foundation Project 4213:
Assessing and Enhancing Biological Filtration
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Monitoring Tools
Biological • DO
• ATP
• Enzyme
Activity
• HPC
• EPS
• PLFA
• Electron
Transport
System Activity
• TRFLP
Organic Carbon
• TOC
• DOC
• BDOC
• AOC
• Carboxylic Acids
• UV254
• UV/VIS Spectra
• SUVA
• Fluorescence
Spectroscopy
Water Quality
• Temperature
• pH
• Turbidity
• Nutrients (N & P)
• DBP Formation
Potential
• Trace Chemical
Constituents
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Dissolved Oxygen
• Calculate respirometric potential across filter (DO consumption) as indicator of biological activity
• Grab Samples
– SM 4500-O
• Iodometric/Titrimetric
• Membrane Electrode
• Online Probes
– Membrane Electrode
– Luminescent Dissolved Oxygen Probe - EPA Method 360.3
• account for elevation during set-up
• perform on-site calibration
• account for percent saturation
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0
5
10
15
20
25
30
35
0
2
4
6
8
10
12
14
16
9/13 11/2 12/22 2/10 4/1 5/21 7/10 8/29
Tem
pe
ratu
re (
oC
)
DO
(m
g/L)
F1 InfluentF1 Effluent/F2 InfluentF2 EffluentF1 Influent Temperature
Cleaned/calibrated
Cleaned/ calibrated
Cleaned
Cleaned/ calibrated
Cleaned
Cleaned Cleaned/calibrated
Cleaned/calibrated
Dissolved Oxygen Probes at Utility 14-OH
GAC Regen
15 GAC
Regen
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Biological Organic Carbon Removal on GAC
Linked DO consumption to theoretical biological carbon utilization for cellular respiration
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ATP
• Luciferase enzyme isolated from firefly
• Consumes ATP and Luciferin to produce
light
• Promega test kit
– GloMax® luminometer
– BacTiter-Glo™ reagents
• LuminUltra test kit
– Kikkoman Lumitester
– Quench-Gone Aqueous® reagents
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1.0E+00
1.0E+01
1.0E+02
1.0E+03
1.0E+04
1.0E+05
1.0E+06
ATP
(p
g/g)
ATP Ranges in Values
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ATP Temporal Variations
Relatively consistent over time
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Carboxylic Acids
• Most are formed during pre-oxidation
• Low concentrations
– mg/L or mg/L as C
• Typical acids
– Acetate
– Formate
– Oxalate
– Pyruvate
• May be used as a proxy for AOC measurements if higher concentrations are present
R² = 0.6895
0
50
100
150
200
250
300
0 200 400 600 800 1000 1200 1400 1600
Sum
Car
bo
xylic
Aci
ds
(mg-
C/L
)
AOC - Bioluminescent P17 and NOX (mg acetate-C/L)
4-NJ 7-NJ 17-CA
n=78
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Carboxylic Acids Range in Values
0
20
40
60
80
100
120
140
160
180
200
Sum
Car
bo
xylic
Aci
ds
(ug-
C/L
)
Influent
Effluent
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Tools Recommended for Use
Biological • ΔDO
• ATP
• EPS
Organic Carbon
• TOC/DOC
• AOC
• Carboxylic Acids
• UV254
• UV spectroscopy
• SUVA
Water Quality
• Temperature
• pH
• Turbidity
• Nutrients (N & P)
• DBP Formation
Potential
Operational
• Head Loss
• Oxidant
Residual
Control
• Oxidant Dose
• Nutrient Dose (phosphate)
• Flow rate/contact time
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Monitoring Integration
• Step 1 – Develop Treatment Objectives
• Step 2 – Select Tools
– Minimum of one tool from each category
• Step 3 – Develop a Baseline
– Include 1 year of monitoring to benchmark data and assess temporal variability
• Step 4 – Develop a Filter Management Plan
– Integrate monitoring and control tools for process control
– Develop benchmarks and set points for treatment objectives
• Step 5 – Revise Management Plan as needed
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Biological Filtration Monitoring and Control Toolbox Guidance Manual
Category
Analyte
Sample
Type
Analysis
Description
Recommendation
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Category
Analyte Method Overall Rating
Monitoring and Control Toolbox Guidance Manual
Evaluation Criteria
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Biological Filtration Monitoring and Control Toolbox Guidance Manual
Ratings by category
Recommendations
Method Description
Applicable Treatment
Objectives
Typical ranges
Interferences
Implementation
Requirements
Procurement
References
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Biological filtration is used today for production of high quality water BUT is often treated like a black box
Innovative tools have recently been developed for practical monitoring and control
Online tools can be used to monitor biological activity and performance real time, such as ΔDO and UV
Biological activity can be assessed through various techniques including ATP and ΔDO
Use these tools in combination with process knowledge and SCADA data
These tools will facilitate optimization and enhancement of biological filtration
Conclusions
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Acknowledgements
• Water Research Foundation
• Technical Advisory Group
• Edward Bouwer
• Anne Camper
• 21 Utilities
• Hsio-wen Chen
• Eva Nieminski (Utah DEQ)
• Nick Dugan (US EPA)
• Mary Jo Kirisits (University of Texas)
• Kerry Meyer (CH2M Hill)
• Jim Smith (East Bay Municipal Utility District)
• Chris Schulz
• Joep Van den Broeke
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Jennifer Hooper (Smith), P.E.
(425) 519-8313
Report and Guidance Document are FREE and available for download!
http://www.waterrf.org/Pages/Projects.aspx?PID=4231