better choices for pesticide testing - phenomenexphx.phenomenex.com/lib/br22530514_i.pdf · synergi...

12
www.phenomenex.com/Pesticides BETTER CHOICES FOR PESTICIDE TESTING OPTIONS FOR: • INCREASED SELECTIVITY • IMPROVED ACCURACY • REPRODUCIBLE RESULTS • VERSATILE SAMPLE PREPARATION LC/GC/SAMPLE PREP/CHIRAL/REFERENCE MATERIALS

Upload: buicong

Post on 12-Jul-2019

213 views

Category:

Documents


0 download

TRANSCRIPT

Page 1: BETTER CHOICES FOR PESTICIDE TESTING - Phenomenexphx.phenomenex.com/lib/br22530514_i.pdf · Synergi Fusion -RP Polar Selectivity - Great Reproducibility Selectivity for all your pesticides

www.phenomenex.com/Pesticides

BETTER CHOICES FOR PESTICIDE TESTING

OPTIONS FOR:

• INCREASED SELECTIVITY

• IMPROVED ACCURACY

• REPRODUCIBLE RESULTS

• VERSATILE SAMPLE PREPARATION

LC/GC/SAMPLE PREP/CHIRAL/REFERENCE MATERIALS

Page 2: BETTER CHOICES FOR PESTICIDE TESTING - Phenomenexphx.phenomenex.com/lib/br22530514_i.pdf · Synergi Fusion -RP Polar Selectivity - Great Reproducibility Selectivity for all your pesticides

EASI

LY A

DVA

NC

E YO

UR

PEST

ICID

E A

NA

LYSI

S

2

Sample PreparationCleaning, extraction, and concentration of pesticides are key goals for

sample preparation. Selecting the appropriate sample preparation

technique can make your analysis easier and more effective.

Choose your options: pp. 4 - 5QuEChERS Solid Phase Extraction (SPE)

• Screening• Targeted Clean up

• Confirmation/Quantitation• Targeted Extraction

Liquid Chromatography (HPLC/UHPLC)Improvements in particle morphologies and surface chemistries have

increased pesticide analysis selectivity and productivity options.

Choose your options: pp. 6 - 7Fully Porous Core-Shell

Speed

Efficiency

Polar Selectivity

Portability (HPLC UHPLC)

Great Reproducibility

© 2014 Phenomenex, Inc. All rights reserved.

We guaranteed that if Phenomenex products in this guide do not provide at least an equivalent separation as compared to other products of the same phase and dimensions, send in your comparative data within 45 days and keep the Phenomenex product for FREE!

Page 3: BETTER CHOICES FOR PESTICIDE TESTING - Phenomenexphx.phenomenex.com/lib/br22530514_i.pdf · Synergi Fusion -RP Polar Selectivity - Great Reproducibility Selectivity for all your pesticides

33

EASILY

AD

VAN

CE YO

UR PESTIC

IDE A

NA

LYSIS

Gas ChromatographyAdvancements have provided more options to achieve

the best separations and identifications of 100’s of pesticides

on any GC instrument.

Choose your options: pp. 8 - 10

Guaranteed AlternativesImproved

Alternative Application Specific

ZB-XLB ZB-35 ZB-1701p ZB-SemiVolatilesZB-CLPesticides

PairZB-MultiResidue™

Pair

For Versatile GC/ECD DualColumn Chlorinated Pesticides

Optimized Selectivity forEnhanced Pesticide Separations

Supreme Inertness with 5%Phenyl-Arylene Selectivity

Traditional SelectivitiesCommonly Used

Phenomenex l WEB: www.phenomenex.com

Certified Reference MaterialsConsistent monitoring heavily relies on the quality of

calibration, surrogate and internal standards you use to

calibrate analytical equipment and qualify the trace-

ability of your samples.

Complement your pesticide analysis

with the right standard: p. 11

Chiral ChromatographySeparate enantiomeric and diastereoisomeric

pesticides easily with chiral polysaccharide columns.

Choose your options: p. 11

HH

H

H

H

H C

C

Cl

O

Page 4: BETTER CHOICES FOR PESTICIDE TESTING - Phenomenexphx.phenomenex.com/lib/br22530514_i.pdf · Synergi Fusion -RP Polar Selectivity - Great Reproducibility Selectivity for all your pesticides

4

SAM

PLE

PREP

ARA

TIO

N

QuEChERSPesticide Screening - Targeted Clean Up

roQ-An easier QuEChERS solutionAn improved solution for multi-residue pesticides extraction and clean up.

For more details on roQ QuEChERS Visit www.phenomenex.com/roQ

1 3

2

Built-inRemovable Rack

Stand Alone Extraction Tubes

Easy Pour Salt Packets

Leak-Free Tubes

Low Leachate Tubes

4 6 8 10 12 14 16 18 20 22 24 26 28 30 min

100000

200000

300000

400000

500000

600000

700000

800000

900000

Abundance

15 mL roQ centrifuge tube extracted with 1 % Acetic acid in Acetonitrile

and then with Toluene.

4

5

Improved with you in mind,

roQ picks up where other

QuEChERS kits fail.

The unique design of the

roQ QuEChERS kits

eliminates common problems

seen with current QuEChERS

kits on the market.

Ease of Use

Quality

Phenomenex l WEB: www.phenomenex.com

Ordering Information roQ™ Extraction KitsExtraction kits contain fifty easy-pour salt packets and fifty 50 mL stand-alone centrifuge tubes

Description Unit Part No. PriceEN 15662 Method Extraction Kits4.0 g MgSO4, 1.0 g NaCl, 1.0 g SCTD, 0.5 g SCDS 50/pk KS0-8909*

AOAC 2007.01 Method Extraction Kits6.0 g MgSO4, 1.5 g NaOAc 50/pk KS0-8911*

*AOAC and EN Extraction Kits also available in traditional non-collared 50 mL centrifuge tubes, Part No.: KSO-8911-NC and KSO-8909-NC

roQ dSPE KitsSPE kits contain pre-weighed sorbents/salts inside 2 mL or 15 mL centrifuge tubes

Description Unit Part No. Price2 mL dSPE Kits150 mg MgSO4, 25 mg PSA, 25 mg C18E 100/pk KS0-8913 150 mg MgSO4, 25 mg PSA, 2.5 mg GCB 100/pk KS0-8914 150 mg, MgSO4, 25 mg PSA, 7.5 mg GCB 100/pk KS0-8915 15 mL dSPE Kits900 mg MgSO4, 150 mg PSA, 150 mg C18E 50/pk KS0-8921 900 mg MgSO4, 150 mg PSA, 15 mg GCB 50/pk KS0-8922 900 mg MgSO4, 150 mg PSA, 45 mg GCB 50/pk KS0-8923

If roQ QuEChERS Kits do not perform as well or better than your current QuEChERS product, send in your comparative data within 45 days and keep the roQ QuEChERS Kit for FREE.

Page 5: BETTER CHOICES FOR PESTICIDE TESTING - Phenomenexphx.phenomenex.com/lib/br22530514_i.pdf · Synergi Fusion -RP Polar Selectivity - Great Reproducibility Selectivity for all your pesticides

5

SAM

PLE PREPARA

TION

Solid Phase ExtractionConfirmation - Quantitation - Targeted Extraction

A choice for every pesticide Strata -X polymer-based SPE sorbent designed to meet your pesticide separation needs.

Looking for traditional silica-based SPE sorbents? Visit www.phenomenex.com/Strata

Strong Acids(pKa < 2) Strata-X-AW

Weak Acids(pKa 2–4)

NeutralCompounds

Weak Bases(pKa 8–10)

Strong Bases(pKa > 10)

Strata-X-A

Strata-X

Strata-X-C

Strata-X-CW

AcidicPesticides

NeutralPesticides

BasicPesticides

Phenomenex l WEB: www.phenomenex.com

Ordering Information

Strata-X Strata-X-A Strata-X-AW Strata-X-C Strata-X-CW

FormatSorbent

Mass Unit Part Number Price Part Number Price Part Number Price Part Number Price Part Number PriceTube

100 mg 6 mL (30/box) 8B-S100-ECH 8B-S123-ECH 8B-S038-ECH 8B-S029-ECH 8B-S035-ECH 200 mg 3 mL (50/box) 8B-S100-FBJ 8B-S123-FBJ 8B-S038-FBJ 8B-S029-FBJ 8B-S035-FBJ 200 mg 6 mL (30/box) 8B-S100-FCH 8B-S123-FCH 8B-S038-FCH 8B-S029-FCH 8B-S035-FCH 500 mg 6 mL (30/box) 8B-S100-HCH 8B-S123-HCH 8B-S038-HCH 8B-S029-HCH 8B-S035-HCH

Giga™ Tube500 mg 12 mL (20/box) 8B-S100-HDG 8B-S123-HDG 8B-S038-HDG 8B-S029-HDG 8B-S035-HDG

1 g 12 mL (20/box) 8B-S100-JDG 8B-S123-JDG 8B-S038-JDG 8B-S029-JDG 8B-S035-JDG 1 g 20 mL (20/box) 8B-S100-JEG 8B-S123-JEG 8B-S038-JEG 8B-S029-JEG 8B-S035-JEG 2 g 20 mL (20/box) 8B-S100-KEG 8B-S123-KEG 8B-S038-KEG 8B-S029-KEG 8B-S035-KEG 5 g 60 mL (16/box) 8B-S100-LFF 8B-S123-LFF 8B-S038-LFF 8B-S029-LFF 8B-S035-LFF

If Strata-X SPE products do not perform as well or better than your current SPE product of similar phase, mass and size, send in your comparative data within 45 days and keep the Strata-X SPE product for FREE!

Page 6: BETTER CHOICES FOR PESTICIDE TESTING - Phenomenexphx.phenomenex.com/lib/br22530514_i.pdf · Synergi Fusion -RP Polar Selectivity - Great Reproducibility Selectivity for all your pesticides

SAM

PLE

PREP

ARA

TIO

N

6

LIQ

UID

CH

ROM

ATO

GRA

PHY

Synergi Fusion -RPPolar Selectivity - Great Reproducibility

Selectivity for all your pesticidesWhether your pesticides are hydrophobic or polar, Synergi Fusion-RP columns provide you with a full range of selectivity, ensuring separation of the most challenging and complex mixtures.

C18 Polar EmbeddedBalanced non-polar and polar performance

Screen 535 pesticides using LC/MS/MS

Learn more about Synergi columns at www.phenomenex.com/synergi

Column: Synergi 2.5 μm Fusion-RP 100 ÅDimensions: 50 x 2.0 mm

Part No.: 00B-4423-B0Mobile Phase: A: Water/Methanol (90:10) + 5 mm Ammonium formate

B: Methanol/Water (90:10) + 5 mm Ammonium formateGradient: Time (min)

011518

18.0520

% B00

10010000

Flow Rate: 400 μL/minTemperature: 40 °C

Detection: Tandem Mass Spectrometer (MS/MS) (400 °C)Detector: AB SCIEX API 3200™ SystemSample: 535 pesticide test mix

1.05e6

1.00e6

9.50e5

9.00e5

8.50e5

8.00e5

7.50e5

7.00e5

6.50e5

6.00e5

5.50e5

5.00e5

4.50e5

4.00e5

3.50e5

3.00e5

2.50e5

2.00e5

1.50e5

1.00e5

5.00e4

00 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 min

APP

ID 2

0035

Embedded polar group complements C18 ligand with balanced polar selectivity

TMS endcapping ensures sharp peaks

Ultra-pure Silica

TMS TMS

AqAq

Phenomenex l WEB: www.phenomenex.com

Ordering InformationSynergi 2.5 μm High Speed Technology (HST) Columns (mm)Phases 30 x 2.0 50 x 2.0 100 x 2.0 50 x 3.0 100 x 3.0 50 x 4.6

Fusion-RP 00A-4423-B0 00B-4423-B0 00D-4423-B0 00B-4423-Y0 00D-4423-Y0 00B-4423-E0

Synergi 4 µm Microbore and Minibore Columns (mm)SecurityGuard™

Cartridges (mm)Phases 50 x 1.0 150 x 1.0 30 x 2.0 50 x 2.0 75 x 2.0 150 x 2.0 250 x 2.0 4 x 2.0*

/10pkFusion-RP 00B-4424-A0 00F-4424-A0 00A-4424-B0 00B-4424-B0 00C-4424-B0 00F-4424-B0 00G-4424-B0 AJ0-7556

for ID: 2.0-3.0 mm

Synergi 4 μm Narrow Bore Columns (mm)SecurityGuard™

Cartridges (mm)Phases 50 x 3.0 150 x 3.0 250 x 3.0 4 x 2.0*

/10pk

Fusion-RP 00B-4424-Y0 00F-4424-Y0 00G-4424-Y0 AJ0-7556

for ID: 2.0-3.0 mm

Synergi 4 μm Analytical Columns (mm)SecurityGuard™

Cartridges (mm)Phases 50 x 4.6 75 x 4.6 150 x 4.6 250 x 4.6 4 x 3.0*

/10pk

Fusion-RP 00B-4424-E0 00C-4424-E0 00F-4424-E0 00G-4424-E0 AJ0-7557

for ID: 3.2-8.0 mm

*SecurityGuard™ Analytical Cartridges require holder, Part No.: KJ0-4282

If Synergi analytical columns do not provide at least an equivalent separation as compared to a competing column of similar particle size, similar phase and dimensions, send in your comparative data within 45 days and keep the column for FREE.

Page 7: BETTER CHOICES FOR PESTICIDE TESTING - Phenomenexphx.phenomenex.com/lib/br22530514_i.pdf · Synergi Fusion -RP Polar Selectivity - Great Reproducibility Selectivity for all your pesticides

SAM

PLE PREPARA

TION

7

LIQU

ID C

HRO

MA

TOG

RAPH

Y

Kinetex Biphenyl Core-ShellSpeed - Efficiency - Polar Selectivity - Portability - Reproducible

Selectivity that a C18 just can’t give youKinetex Biphenyl is a high efficiency core-shell product capable of adding extra separation power to your HPLC/UHPLC analysis of non-polar and polar pesticides.

• Remarkable Separation Power

• Rugged and Reliable

• Improved efficiency

Great selectivity for polar pesticides

For additional Kinetex dimensions and phases, please visit www.phenomenex.com/kinetex

Core-Shell Technology

TMSTMS

Biphenyl

5 µm 2.6

µm1.7 µm

Column: Kinetex 5 µm Biphenyl 100 ÅDimensions: 100 x 2.1 mm

Part No.: 00D-4627-ANMobile Phase: A: 5 mM Ammonium formate in Water

B: 5 mM Ammonium formate in MethanolGradient: Time (min)

0.01 1.0010.00 15.00 15.10 20.00

% B101090901010

Flow Rate: 0.5 mL/minTemperature: 35 °C

Detection: Tandem Mass Spectrometer (MS/MS) (0 °C)Detector: AB SCIEX 4500 QTRAP®

0 min1 2 3 4 5 6 7 8 9 10 11 12 13 140

5000.0

1.0e4

1.5e4

2.0e4

2.5e4

3.0e4

3.5e4

4.0e4

4.5e4

5.0e4

5.4e4AP

P ID

226

18

Enhanced Polar Pesticides Retention

Phenomenex l WEB: www.phenomenex.com

Ordering Information

Kinetex 5 μm Columns (mm)SecurityGuard™

ULTRA Cartridges‡SecurityGuard™

ULTRA Cartridges‡SecurityGuard™

ULTRA Cartridges‡

Phases 50 x 2.1 3/pk 50 x 3.0 3/pk 50 x 4.6 100 x 4.6 150 x 4.6 250 x 4.6 3/pk

Biphenyl 00B-4627-AN AJ0-9209 00B-4627-Y0 AJ0-9208 00B-4627-E0 00D-4627-E0 00F-4627-E0 00G-4627-E0 AJ0-9207

for 2.1 mm ID for 3.0 mm ID for 4.6 mm ID

Kinetex 2.6 μm Columns (mm)SecurityGuard™

ULTRA Cartridges‡SecurityGuard™

ULTRA Cartridges‡SecurityGuard™

ULTRA Cartridges‡

Phases 50 x 2.1 100 x 2.1 3/pk 50 x 3.0 3/pk 50 x 4.6 100 x 4.6 150 x 4.6 3/pk

Biphenyl 00B-4622-AN 00D-4622-AN AJ0-9209 00B-4622-Y0 AJ0-9208 00B-4622-E0 00D-4622-E0 00F-4622-E0 AJ0-9207

for 2.1 mm ID for 3.0 mm ID for 4.6 mm ID

Kinetex 1.7 μm Minibore Columns (mm)SecurityGuard

ULTRA Cartridges‡

Phases 50 x 2.1 100 x 2.1 150 x 2.1 3/pk

Biphenyl 00B-4628-AN 00D-4628-AN 00F-4628-AN AJ0-9209for 2.1 mm ID

‡SecurityGuard ULTRA cartridges require holder, Part No. AJ0-9000.

If you are not completely satisfied with Kinetex core-shell columns, send in your comparative data to a similar product within 45 days and keep the column for FREE.

Page 8: BETTER CHOICES FOR PESTICIDE TESTING - Phenomenexphx.phenomenex.com/lib/br22530514_i.pdf · Synergi Fusion -RP Polar Selectivity - Great Reproducibility Selectivity for all your pesticides

SAM

PLE

PREP

ARA

TIO

N

8

GA

S C

HRO

MA

TOG

RAPH

Y

ZB-CLPesticides-1 & -27 GC/ECD Chlorinated Pesticide Methods on One Set

• Versatile selectivity for chlorinated pesticides and herbicides by dual-column GC/ECD

• Run EPA Methods 8081, 8082, 8151, 504, 505, 508, and 552 on one set

• Guaranteed alternative to Restek® Rtx®-CLPesticides and Rtx-CLPesticides2

Chlorinated Pesticides, Herbicides, and Organohalides by GC/ECD

1. 2,4,5,6-Tetrachloro- m-xylene* 2. ∝-BHC 3. γ-BHC 4. β-BHC 5. δ-BHC 6. Heptachlor 7. Aldrin 8. Heptachlor epoxide (isomer B) 9. trans-Chlordane 10. cis-Chlordane 11. Endosulfan I

12. 4,4’-DDE 13. Dieldrin 14. Endrin 15. 4,4’-DDD 16. Endosulfan II 17. 4,4’-DDT 18. Endrin aldehyde 19. Endosulfan sulfate 20. Methoxychlor 21. Endrin ketone 22. Decachlorobiphenyl** surrogate standard

Column: Zebron ZB-CLPesticides-1 Zebron ZB-CLPesticides-2

Dimensions: 30 meter x 0.32 mm x 0.32 µm 30 meter x 0.32 mm x 0.25 µm

Part No.: 7HM-G028-51 7HM-G029-11

Injection: Splitless @ 250 °C, 1 µLCarrier Gas: Helium @ 3.9 mL/min (constant flow)

Oven Program: 120 °C to 200 °C @ 45 °C/min to 230 °C @15 °C/min to 330 °C @ 30 °C/min for 2 min

Detector: ECD @ 330 °CSample: Performed using a 5 m Z-Guard™

column and Y-Connector Analytes are 250 ppb in Hexane

min

1

2

3 5

67 9

10 1211

13

1415

1716

18

19

20

21

22

8

4

22631

32 4 5 6 7

APP

ID 2

2631

min

1

2

4

5

6 7

8 9 10

11

12 13

1516 17

18

19

20

21

22

14

3

22632

32 4 5 6 7

APP

ID 2

2632

ZB-CLPesticides-1

ZB-CLPesticides-2

For more details on Pesticides with GC visit www.phenomenex.com/PesticidesGC

Phenomenex l WEB: www.phenomenex.com

Ordering InformationZB-CLPesticides-1 GC Columns

ID (mm) df (µm) Temperature Limits (°C) Part No. Price30-Meter

0.25 0.25 40 to 320/340 7HG-G028-11

0.32 0.32 40 to 320/340 7HM-G028-51

0.32 0.50 40 to 320/340 7HM-G028-17

0.53 0.50 40 to 320/340 7HK-G028-17

ZB-CLPesticides-2 GC ColumnsID (mm) df (µm) Temperature Limits (°C) Part No. Price

30-Meter0.25 0.20 40 to 320/340 7HG-G029-10 0.32 0.25 40 to 320/340 7HM-G029-11 0.32 0.50 40 to 320/340 7HM-G029-17 0.53 0.42 40 to 320/340 7HK-G029-16

Available in convenient kits online.

If Zebron columns do not provide you with equivalent or better separations as compared to any other GC column of the same phase and comparable dimensions, send in your comparative data within 45 days and keep the column for FREE!

Page 9: BETTER CHOICES FOR PESTICIDE TESTING - Phenomenexphx.phenomenex.com/lib/br22530514_i.pdf · Synergi Fusion -RP Polar Selectivity - Great Reproducibility Selectivity for all your pesticides

SAM

PLE PREPARA

TION

9

GA

S CH

ROM

ATO

GRA

PHY

ZB-MultiResidue™-1 & -2Optimized Selectivity for Enhanced Pesticide Separations

• 2 novel phases optimized for versatile pesticide screening by GC/MS and confirmation methods by GC/ECD and other selective detectors

• Resolve common pesticide isomers with optimized selectivity

• Decrease breakdown for sensitive analytes like DDT and Endrin

• Well-suited for testing complex, multi-class pesticide lists

Multi-Residue Pesticide Screen by GC/MS

For more details on Pesticides with GC visit www.phenomenex.com/PesticidesGC

Column: Zebron MultiResidue-1Dimensions: 30 meter x 0.25 mm x 0.25 µm

Part No.: 7HG-G016-11Injection: Splitless @ 260 °C, 1 µL

Carrier Gas: Helium @ 0.9 mL/min (constant flow)Oven Program: 80 °C to 0.5 min to 150 °C @ 10 °C/min

to 240 °C @ 4 °C/min to 320 °C @ 15 °C/min for 3 minDetector: MSD @ 320 °C; 45-400 amuSample: Analytes are 1 ppm in Dichloromethane

View the full 112 compound list at www.phenomenex.com

8 10 12 14 16 18 20 22 24 26 28 30 32 34

14 16 18 min

min

22 24 min

18

19

20

21

22

23

24 25

27

28

29 3031

32

34

35

40

33

48

51

49

50

52

38

39

26

36,37 41-43

44-45

46-47

58

59

60

61

62

63

64-66

67

68

69

70

75

76

77,78

79

82

84

83

85

86 87

71-74

80-81

12

3

4

5

6,7

5354

55

57

56

9

10

12

13-15

17

1188

94,95

96

97

98

99100

101

102103

104

105

106

107

108

109

110,111

11292,93

90

91

89

8

16 APP

ID 1

6184

Phenomenex l WEB: www.phenomenex.com

Ordering Information ZB-MultiResidue-1 GC Columns

ID (mm) df (µm) Temperature Limits (°C) Part No. Price30-Meter

0.25 0.25 -60 to 320/340 7HG-G016-11

0.32 0.25 -60 to 320/340 7HM-G016-11

0.32 0.50 -60 to 320/340 7HM-G016-17

0.32 0.50 -60 to 320/340 7HK-G016-17

ZB-MultiResidue-2 GC ColumnsID (mm) df (µm) Temperature Limits (°C) Part No. Price

30-Meter0.25 0.20 -60 to 320/340 7HG-G017-10

0.32 0.25 -60 to 320/340 7HM-G017-11

0.53 0.50 -60 to 320/340 7HK-G017-17

Available in convenient kits online.

If Zebron columns do not provide you with equivalent or better separations as compared to any other GC column of the same phase and comparable dimensions, send in your comparative data within 45 days and keep the column for FREE!

Page 10: BETTER CHOICES FOR PESTICIDE TESTING - Phenomenexphx.phenomenex.com/lib/br22530514_i.pdf · Synergi Fusion -RP Polar Selectivity - Great Reproducibility Selectivity for all your pesticides

SAM

PLE

PREP

ARA

TIO

N

10

ZB-SemiVolatiles

Guaranteed Zebron Alternatives

Supreme Inertness for Tough Pesticide Samples

Traditional Selectivities

• Rugged performance for 5% phenyl-arylene selectivity with Enviro-Inert™ Technology

• Supreme inertness for acids, amines, and other notoriously active compounds

• Detect down to ultra-low levels (0.2 ng on-column) and improve critical pair resolution

Common Pesticides in Drinking Water by GC/MS

• Do away with downtime

• Minimize method development

Ordering Information

For more details on Pesticides with GC visit www.phenomenex.com/PesticidesGC

APP

ID 2

1439

4

1

2

3

4

5

6

7

10

11

13

15

16

17 18

19

21

20

2223

24

25,26

27

2829

3031

32

33 34

35

36

37 38

14

12

9

5 6 7 8 9 10 11 12 13 14 15 16 17

20000

40000

60000

80000

100000

120000

140000

160000

180000

200000

220000

240000

26000021439

min

ZB-XLB ZB-35 ZB-1701PEngineered for extra low

bleed and commonly used for confirmation of pesticides

and PCBs

Inert, rugged performance recommended specifically for herbicides and trace analysis

Specifically QC tested to ensure DDT, endrin, endrin

aldehyde, and endrin ketone response with pesticide work

Polarity 9 18 19

Temp. Limits* 30 to 340/360 °C 40 to 340/360 °C -20 to 280/300 °C

Phase Chemistry

Proprietary 35 % Phenyl 65 % Dimethylpolysiloxane

14 % Cyanopropylphenyl 86 % Dimethylpolysiloxane

Alternative ToRestek®:Agilent®:

Supelco®:

Rtx®-XLBDB-XLB,VF-XMS

MDN-12

Rtx-35DB-35, HP-35

MDN-35, SPB®-35

Rtx-1701DB-1701,CP-Sil 19 CB

SPB-1701, Equity®-1701

Column: Zebron ZB-SemiVolatiles Dimensions: 30 meter x 0.25 mm x 0.25 µm

Part No.: 7HG-G027-11Injection: Pulsed Splitless @ 260 °C, 1 µL @ 30 psi for 0.55 min

Carrier Gas: Helium @ 1.2 mL/min (constant flow)Oven Program: 80 °C for 0.75 min to 190 °C @ 35 °C/min to 240 °C @

5 °C/min to 300 °C @ 20 °C/min for 2 minDetector: MSD @ 320; 30-450 amu

Liner: AG0-8499 (Single Taper with Wool at Bottom)Inlet Seal: AG0-8620 (Gold-Plated Easy Seals™)

View the full compound list at www.phenomenex.com

Phenomenex l WEB: www.phenomenex.com

Zebron ZB-SemiVolatiles GC ColumnsID

(mm)df

(µm)Temperature Limits (°C) Part No. Price

20-Meter0.18 0.18 -60 to 325/350 7FD-G027-08 0.18 0.36 -60 to 325/350 7FD-G027-53

30-Meter0.25 0.25 -60 to 325/350 7HG-G027-11 0.25 0.50 -60 to 325/350 7HG-G027-17

30-Meter with 5-Meter Guardian™ Integrated Guard0.25 0.25 -60 to 325/350 7HG-G027-11-GGA 0.25 0.50 -60 to 325/350 7HG-G027-17-GGA

Zebron ZB-XLB GC ColumnsID

(mm)df

(µm)Temperature Limits (°C) Part No. Price

30-Meter0.25 0.25 30 to 340/360 7HG-G019-11 0.25 0.50 30 to 340/360 7HG-G019-17 0.32 0.25 30 to 340/360 7HM-G019-11 0.32 0.50 30 to 340/360 7HM-G019-17 0.53 1.50 30 to 320/340 7HK-G019-28

Zebron ZB-35 GC ColumnsID

(mm)df

(µm)Temperature Limits (°C) Part No. Price

30-Meter0.25 0.25 40 to 340/360 7HG-G003-110.25 0.50 40 to 340/360 7HG-G003-17 0.32 0.25 40 to 340/360 7HM-G003-11 0.32 0.50 40 to 340/360 7HM-G003-17 0.53 0.50 40 to 340/360 7HK-G003-17 0.53 1.00 40 to 340/360 7HK-G003-22

Zebron ZB-1701P GC ColumnsID

(mm)df

(µm)Temperature Limits (°C) Part No. Price

30-Meter0.25 0.25 -20 to 280/300 7HG-G012-11 0.32 0.25 -20 to 280/300 7HM-G012-11 0.53 1.00 -20 to 260/280 7HK-G012-22

If Zebron columns do not provide you with equivalent or better separations as compared to any other GC column of the same phase and comparable dimensions, send in your comparative data within 45 days and keep the column for FREE!

Page 11: BETTER CHOICES FOR PESTICIDE TESTING - Phenomenexphx.phenomenex.com/lib/br22530514_i.pdf · Synergi Fusion -RP Polar Selectivity - Great Reproducibility Selectivity for all your pesticides

SAM

PLE PREPARA

TION

11

CH

IRAL C

HRO

MA

TOG

RAPH

Y

Lux Chiral ColumnsEnantiomeric and Diastereoisomeric Resolutions for Pesticides

• High efficiency and loading capacity

• Stable in normal phase, polar organic, SFC, and reversed phase conditions

• 3 µm and 5 µm packed columns for separation and speed preferences

• 200+ chiral pesticides applications available to choose from

Stereoisomers mix of Cyproconazole

11Phenomenex l WEB: www.phenomenex.com

Ordering Information 5 µm Analytical Columns (mm) SecurityGuard Cartridges (mm)Phases 50 x 2.0 50 x 4.6 100 x 4.6 150 x 4.6 250 x 4.6 4 x 2.0* 4 x 3.0*

/10pk /10pkCellulose-1 00B-4459-B0 00B-4459-E0 00D-4459-E0 00F-4459-E0 00G-4459-E0 AJ0-8402 AJ0-8403Cellulose-2 00B-4457-B0 00B-4457-E0 00D-4457-E0 00F-4457-E0 00G-4457-E0 AJ0-8398 AJ0-8366Cellulose-3 00B-4493-B0 00B-4493-E0 00D-4493-E0 00F-4493-E0 00G-4493-E0 AJ0-8621 AJ0-8622Cellulose-4 00B-4491-B0 00B-4491-E0 00D-4491-E0 00F-4491-E0 00G-4491-E0 AJ0-8626 AJ0-8627Amylose-2 00B-4472-B0 00B-4472-E0 00D-4472-E0 00F-4472-E0 00G-4472-E0 AJ0-8471 AJ0-8470

for ID: 2.0–3.0 mm 3.2–8.0 mm

*SecurityGuard Analytical Cartridges require holder, Part No.: KJ0-4282

Pesticides and Herbicides Part Number Product Description PriceAL0-101255 8141 OP Pesticides 200 μg/mL Hexane/Acetone (90:10)AL0-101256 8270 OP Pesticides Mix 2000 μg/mL Methylene ChlorideAL0-101258 Toxaphene 2000 μg/mL in MethanolAL0-101253 8081 Chlorinated Pesticides 1000 μg/mL in Hexane/Toluene (1:1)AL0-101254 Chlorinated Pesticides Standard 2000 μg/mL in Hexane/Toluene (1:1)AL0-101260 Technical Chlordane 1000 μg/mL in MethanolAL0-101265 Simazine 1000 μg/mL in AcetoneAL0-101271 Atrazine 1000 μg/mL in AcetoneAL0-101288 Chlorinated Acid Herbicides 100 μg/mL in AcetonitrileAL0-101289 MCPP & MCPA 20000 μg/mL in AcetonitrileAL0-101266 Triazine Herbicides Mix 200 μg/mL in Acetone

Available in USA and Canada

If Lux analytical columns (≤ 4.6 mm ID) do not provide at least an equivalent or better separation as compared to a competing column of the same particle size, similar phase and dimensions, send in your comparative data within 45 days and keep the Lux column for FREE.

Polysaccharide Chiral ColumnsDependable. Scalable. A�ordable.

• Lot-to-lot consistency

• Minimized trending

• Personalized technical support

Access All Your Certified Reference Material Resources at www.phenomenex.com/Standards

CERTIFIED

REFERENC

E MA

TERIALS

Phenova Certified Reference Materials (CRMs)Improve Pesticide Analysis & Throughput

Column: Lux 5 µm Cellulose-4Dimensions: 250 x 4.6 mm

Part No.: 00G-4491-E0Mobile Phase: 0.1 % Diethylamine in Acetonitrile /

0.1 % Diethylamine in 20 mMAmmonium bicabonate (60:40)

Flow Rate: 1 mL/minDetection: UV @ 220 nm

0 2 4 6 8 10

0

200

400

App ID 21755

mAU

minAP

P ID

217

55

a = 1.20Rs = 3.05

Cl

OHN

N

N

*

*

Cl

OHN

N

N

*

*

Page 12: BETTER CHOICES FOR PESTICIDE TESTING - Phenomenexphx.phenomenex.com/lib/br22530514_i.pdf · Synergi Fusion -RP Polar Selectivity - Great Reproducibility Selectivity for all your pesticides

www.phenomenex.comPhenomenex products are available worldwide. For the distributor in your country, contact Phenomenex USA, International Department at [email protected]

t: f:

Australia02-9428-6444 02-9428-6445 [email protected]

t: f:

Austria 01-319-1301 01-319-1300 [email protected]

t: t: f:

Belgium02 503 4015 (French) 02 511 8666 (Dutch) +31 (0)30-2383749 [email protected]

t: f:

Canada(800) 543-3681 (310) 328-7768 [email protected]

t: f:

Denmark4824 8048 +45 4810 6265 [email protected]

t: f:

Finland09 4789 0063 +45 4810 6265 [email protected]

t: f:

France01 30 09 21 10 01 30 09 21 11 [email protected]

t: f:

Germany 06021-58830-0 06021-58830-11 [email protected]

t: f:

India 040-3012 2400 040-3012 2411 [email protected]

t: f:

Ireland 01 247 5405 +44 1625-501796 [email protected]

t: f:

Italy 051 6327511 051 6327555 [email protected]

t: f:

Luxembourg+31 (0)30-2418700 +31 (0)30-2383749 [email protected]

t: f:

Mexico001-800-844-5226 001-310-328-7768 [email protected]

t: f:

The Netherlands030-2418700 030-2383749 [email protected]

t: f:

New Zealand09-4780951 09-4780952 [email protected]

t: f:

Norway 810 02 005 +45 4810 6265 [email protected]

t: f:

Puerto Rico (800) 541-HPLC (310) 328-7768 [email protected]

t: f:

Sweden 08 611 6950 +45 4810 6265 [email protected]

t: f:

United Kingdom 01625-501367 01625-501796 [email protected]

t: f:

United States(310) 212-0555 (310) 328-7768 [email protected]

t: f:

All other countries: Corporate Office USA (310) 212-0555 (310) 328-7768 [email protected]

BETTER CHOICES FOR PESTICIDE TESTINGLC/GC/SAMPLE PREP/CHIRAL/REFERENCE MATERIALS

BR

2253

0514

_I

Terms and Conditions Subject to Phenomenex Standard Terms and Conditions which may be viewed at www.Phenomenex.com/TermsAndConditions

Trademarks Kinetex and Lux are registered trademarks, Zebron, Enviro-Inert, Guardian, Giga, Z-Guard, MultiResidue, Easy Seals, roQ, Strata-X and Synergi are trademarks of Phenomenex. Phenova is a registered trademark of Phenova Inc. API 3200 is a trademark and QTRAP is a registered trademark of AB SCIEX Pte. Ltd. AB SCIEX™ is being used under license. Restek and Rtx are registered trademarks of Restek Corporation. Supelco, SPB, and Equity are registered trademarks of Sigma-Aldrich Co., LLC.

Disclaimer Phenomenex is in no way affiliated with Restek Corporation or Sigma-Aldrich.

Strata-X is patented by Phenomenex. U.S. Patent No. 7,119,145

© 2014 Phenomenex, Inc. All rights reserved.