battery energy storage system vanadium redox flow battery
TRANSCRIPT
RedoxFlow
Battery16, Yangil-ro 18beon-gil, Buk-gu, Gwangju, Korea
(Head Office, Factory)
ENERGY&AIRSYSTEM Co., Ltd.
T +82-70-7728-7797
F +82-62-973-2709
w w w. h i g r o u p . c o . k r
ENERGY&AIRSYSTEM
Vanadium Redox Flow Battery
Promoted By
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ENERGY&AIRSYSTEMImporters & Indenters
Battery Energy Storage SystemVanadium Redox Flow Battery
COMMITTED TO SERVE YOU BETTER
Business Portfolio
- LFP Cathode Material - Lithium Battery Reuse, Recycling
Redox Flow Battery E FIouJ
Energy Business
Material Construction
Facility Insulation
Air Conditioning
Building Enclosure
Rubber Foarh Insulation
High- Density Tape Semi-non-flammable PF Insulation
Construction
ESS ( Design, Production, Construction PV EPC Development Operation of Fuel Cell Power Plants
Electrical Design-Supervision Solar Plant A/S Overseas Solar Power Design-Supervision
Introduction of Business
Business 2018 Revenue * Flow Battery (Flour) Production * Flow Battery ESS Design, Construction * PV EPC, Fuel Cell Plant Development $19,644,300 * Lithium Battery ESS (4BBfL) * Design, Production
Construction * Secondary Battery * Cathode Material $5,101,600 * Lithium Battery Reuse
Recycling * Electrical Design * Supervision * Energy Consulting $59,200 * Overseas Solar Power * Design-Supervision
Business 2018 Revenue * Production of rubber Foam insulation * High-Density Tape * Mechanical Equipment $38,696,000 * Fire Fighting Equipment
* Semi-non-combustible PF Insulation Manufacturing * PV Module Reuse New Company
* Air Conditioner Freezer-Gwangju * Geothermal Heating & Cooling System $1,608,800 * Air Conditioner, Freezer-Seoul * Geothermal Heating & Cooling System $25,402,200
Energy Business:
Construction Business:
Companyintroduction
E N E R G Y & A I R S Y S T E M
Capital $1,133,000
Date of
establishment01 July 1995
Sales $23,251,000 (2018)
a major
product
ESS, Flow Battery,
Battery Pack(KEPCO)
PV EPC, Fuel cell power plant
General status
Corporate Name ENERGY&AIRSYSTEM Co,. Ltd
Verification status at home and abroad
Large utility ESS world scale
Market share by MWh
7trillion won
RFB ESSMarket Size
SITE
Business progress status Market size
Flow battery Demonstration center
Element Tech. R&D- Selection of major components- Cell Stack Development
kW class FB operation- Large Cell Stack Development- Trimming Cell PCS Control
Tens to hundreds of kW- High-Power Cell Stack Development- Cost reduction by injection of mold
Tens of MW class- Large Scale VRFB System with Renewable Energy- Future Electric Vehicle with FB R&D)
2011~2013
2014~2015
2016~2019.8
2016 S University of Japan
(2016 .08)5KW stack
2017
2019
Global RFB Status
GwangjuEnergy & Air systemVRFB 25kW/100kWh(2019 ~ )
Vanadium kw class for green IDC Technology Development of Redox Flow Battery
Task of the Keit(2012-2017)
Installing LIB + 20kW VRFB
Honam University(’17. 7)
Large-Scale demonstrationDrive renewable energy link
1MW/4MWh
Japan 60MWh China 3MWh Europe 2MWh
For emergency power and peak loads Development of Hybrid ESS Management System
Task of the Keit (2015-2017)
Energy Multipurpose Facility(BEMS) Installing PV+WF+FB(25kW /100kWh)
Company Demonstration Center(’19. 6)
Multifunction Flow Battery Installing PV+FB 5kW
S University of Japan (2016 -)
Installing 20kW VRFB
ETRI(’17. 5)
Tokyo,Japan
Ningbo,China
ETRI,Korea
Massive ESS World Market Size RFB Market Share
China H Research Institute (2019 .04) 5KW/10KWh
ENERGY SYSTEM(2019.06) 25KW/100KWhS University of Japan(2019.10) 5kw
ETRI (2017 .04) 20KWH University (2017.07) 20KW
H University, Korea
Time(mm)
Vo
ltag
e(V
)
Time(mm)
Vo
ltag
e(V
)
ESS Optimal System Flow Cells with Wind Power
Best suited for stable output variation
Simplify the power converter compared to other batteries
Can charge multiple devices simultaneously
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The wind generator is a generator whose power is determined by the speed of the
wind. The wind turbine rotates irregularly according to the speed of the wind, which
varies greatly in voltage/current of momentary alternating current.
Wind Turbine Characteristics
Advantage of Flow Cell in Wind Turbine
Wind power generation needs to be careful when connecting ESS because there is a
possibility of generating a large amount of power exceeding the instantaneously due to
the severe variability according to the wind strength.
In case of flow battery ESS, there is almost no variation between cells because it charges
electricity through electrolyte, and it has stable characteristics by absorbing electric
shock in wind power generation.
This stable power reception allows system operation to be configured without the need
for a multifunction power converter like other batteries.
It is possible to configure a system that can be charged at the same time in connection
with a plurality of power generators with different voltages such as solar, wind, grid and
regenerative current.
Controllers are required to stabilize alternating current voltage/current with high
variability at direct current
Demonstration of Flow Cells Connected to Wind Power
01
02
Power Generation Output of Wind Turbine
Wind generator voltage Wind-linked flow cell voltage
Flow Battery Overview
Mechanism
Characteristics
Application
Purpose
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The safest battery without fire and explosion
* Optimized for new and renewable energy and building ESS
Long-lived batteries that can be used for more than 20 years
Batteries with little reduction in energy efficiency despite long-term use
Store power energy in electrolyte for easy capacity selection and battery
suitable for high capacity production
Stable power supply for new and renewable energy
- Irregular power regulation, such as solar and wind power
- Adjusting the time difference between the time of
energy production and demand
Realizing the stabilization of the power supply
Load leveling and Power peak response
Emergency Power Function(Emergency Generator)
Power management for energy-heavy buildings (ex. Building, Hospital, Factory)
V5+
Electrode Membrane
PowerSource-Load
ElectrolyteTank
PumpPump
V4+/V
5+V
2+/V
3+
O² - O²-
O² -
O² -
O²-
O²-
O²-
O² -
V⁴+
V⁴+
CI+
CI-
CI-
CI-CI-
CI-H
+
H-
H-
H-
H- H-
H-
H-
H+
H+
H +
H+ H+
H +
H+
V2+
V2+
V3+
Large-capacity Secondary battery
Load Leveling
Wind Power Generation
PV Generation
Power Generation
Electric Power System
FrequencyControl
Control
Central Control Unit
Building
Factory
Surplus Electricity
8
Pump
Oxidation
ion exchangemembrane
Reduction
ElectrolyteTank
H+
PositiveElectrode Slide
e-
e- e-
Cell
NegativeElectrode Slide
ElectrolyteTank
Pump
ElectrodeElectrode
+ -
Pump
Reduction
ion exchangemembrane
Oxidation
ElectrolyteTank
H+
PositiveElectrode Slide
e-
e- e-
Cell
NegativeElectrode Slide
ElectrolyteTank
Pump
ElectrodeElectrode
+ -
V / V5+ 4+ V / V2+ 3+V4+
V5+
V2+
V3+
V / V5+ 4+V4+
V5+
V2+
V3+
V / V2+ 3+
Comparison of Lithium Battery and RFB(Characteristic)
Non-uniform deviation between cells may cause low
Li-ion Battery
1. Conceptual Diagram
2. Pros and Cons
2. Pros and Cons
3. Safety
3. Safety
[VRFB Charging Process] [VRFB Discharge Process]
Risk Lithium-ion Sodium Sulfur VRB Flow Battery
Arc-Flash/Blast ○ △ ◎
Toxicity ○ ○ ○
Fire △ △ ◎
Deflagration △ △ ◎
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High energy density & high operating voltage
Nonconformity with large capacity due to non-uniform
deviation between cells
Fire and explosion hazard
Long-term Available and Most Safe Cells
A battery suitable for large capacity
Low Energy Density & Pricing
It is safe that seperate by stack and live material also
no fire or explosion when it is mix anode with cathode
Anode material: graphite, Si, Sn,
LTO etc.
NegativeElectrode
PositiveElectrode
Aluminum positivecurrent collector
Charge
Charge
Discharge
DischargeCopper negativecurrent collector
Cathode material: transition metal oxide
(LiCoO2, LiFePO4, Li2Mn2O4, etc.)
e
e
e
Li+conductingelectrolyte
Aⓔ
ⓔ
ⓔ
ⓔ
e
e
e
Li+
Li+
Li+
Li+
Li+
Redox Flow Battery
1. Conceptual Diagram
9 ENERGY SYSTEM
10 ENERGY SYSTEM
Technical ability of our Flow Battery
1. Smart passage Design 2. High power and low cost
2. Concurrent design of charging
/discharge
3. High-capacity production capacity
3. LIB&VRFB Hybrid System1. Trimming System
Stack technical skills
System technical ability
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Minimized Design of Shunt Current
by Numerical Analysis of Passage
Design
Reducing cell resistance by
minimizing pressure loss
capacity-following system
Energy efficiency improvement
World's First Applied Technology
Special design utilizing flow-cell
characteristics to the fullest
24 hours of continuous load
availability
Hybrid System for Fully Independent
Operation
Leverage LIB and VRFB features
High Power Application through
Electrode Surface Treatment
Application of special ion exchange
membrane for high power use
Improved durability using cell frame
injection low-cost and special
injection materials
localization of Cell
Possessing the production capacity
of electrolyte using ash
(a)
+ -
battery
Stack Stack Stack Stack
Stack Stack Stack Stack
battery
11
Business Model_1
[ Wind power linkage ]
[ Photovoltaic linkage ]
New and Renewable Energy Linked Model
A Model for Multi-useFacilities Buildings
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Frequency regulation, driving reserve
Flow batteries are best suited for stabilising wind fluctuations
When connecting flow batteries, power conversion system can be simplified
compared to other batteries.
It is commercialized to sell hundreds of kilowatts
of electricity to energy-consuming buildings such
as schools, hospitals, hotels, and supermarkets for
peak-to-peak load/load-equalization purposes that
supplementing with the VRFB system.
Commercialize sales for uninterruptible power supply
to protect major structures from power failure.
Frequency regulation, driving reserve Peak load response
Solar EnergyHotel
Hospital
School
Mart
System Linkage
RFB-ESS(Storage)
Daytime powerdemand
Powergeneration
0h
Discharge
After ESS isintroduced
Before ESS isintroduced
Long period (time-discharge)
charge
Nightly powerdemand
12h 24h
1400
1200
1000
800
600
400
200
0
0 100 200
3 m/s5 m/s
7.5 m/s
10 m/s
12 m/s
maximum power curve
300 400 500 600 700 800 900 1000 1100 1200
Pow
er(W
)
Speed(rpm)
0
100
10
20
200
0
100
10
20
200
Time(mm)
Vo
lta
ge
(V)
Time(mm)
Vo
lta
ge
(V)
Wind power
Solar Energy
Short cycle(per-second/minutes development)
12 ENERGY SYSTEM
Business Model_2
Regenerative Powerand Biogas Model
Future Electric Vehicle (EV) Model
Select a business model(1) : For elevator regenerative power
RFB-EV RFB-EV Station
Select a business model(2) : For bio gas use.
System Linkage
RFB-ESS(storage)
EV Station
Electrode
Ion Exchange Membrane
Bipolar Cell Stack
Metal Deposit
AnolyteCatholyte
PVLIB
RFB
Feeding for shelter Emergency power for generator replacement
Emergency power in case of disaster
Normal demand management
Contract power saving peak shaving Load standardization
Grid(110V/220V)
Elevator (Regenerative power)
Anolyte Catholyte
I/C I/C
13
Demonstration center
Concept
Installation capacity
Installation period
PV(20kw), Wind Power
Power25kW, capacity 100KWh
July 2019
Establishment and operation of demonstration centerE-Flow Demonstration Center
14 ENERGY SYSTEM
Flow Battery demonstration case (Domestic)
Installation capacity
Installation period
ETRI Center Proof of Linkage in Etri Center
Concept
Installation capacity
Installation period
For solar-connected peak loads
20kWh
2017 June~
H University
Demonstration of Hybrid for emergency power and
peak loads
20kWh
2017 and October~
Concept
Proof of Linkage in H University
15
Flow Battery demonstration case(overseas)
Empirical evidencein Japan
Empirical evidencein China
Installation capacity
Installation period
Estimated installed capacity
Installation period
Optimizing RFB Advantage with Trimming System
20kWh
2019 April~
Proof of Linkage in Saitama Technical University
Proof of Linkage in Ningbo City, China
Front of the exhibition hall
PV position (left) Front door PV position (right) Pcs installationLeakage test Stack side Stack Backside
Stack transfer Pipe connection
2nd demonstration in connection with Saitama Technical University
Concept
Installation capacity
Installation period
Operation of RFB-ESS for solar-connected buildings
10kWh
2016 August~
Demand management for new and renewable
connections and disaster relief
20kWh
2019 and October~
Concept
PV-WF combined power generation RFB-ESS linkage. Concepts
16 ENERGY SYSTEM
Sortation Output Capacity Square measure Weight
3hrs AC 250kw AC 750 kWh 6.1m*4.9m*6m 120t
4.5hrs AC 250kw AC 1,125kWh 9.1m*4.9m*6m 170t
6hrs AC 250kw AC 1,500kWh 12.2m*4.9m*6m 220t
Output Capacity Installation area
1MW 3MWh 15m*17m
1MW 4.5MWh 21m*17m
1MW 6MWh 27m*17m
10MW 30MWh 85m*27m
10MW 45MWh 103m*27m
10MW 60MWh 131m*27m
PRODUCT SPECIFICATIONS
HISTORY OFBUSINESS IMPLEMENTATION
2011-2013 2014-2015 2016-2019.8 2019.9~
Element Tech.R&D
Selection of major componentsCell Stack Development
-
-
-
-
-
-
-
-
kW class FB operation
Large Cell Stack DevelopmentTrimming Cell PCS Control
Tens of MW class
Large Scale VRFB System with Renewable EnergyFuture Electric Vehiclewith FB R&D)
High power
ESS for Building
Tens to hundreds of kW
High-Power Cell Stack DevelopmentCost reduction by injection of mold
Renewable Energy Connected ESS
Vanadium kw class for green IDC
Technology Development of
Redox Flow Battery
Task of the Keit(2012-2017)
For emergency power and peak loads
Development of Hybrid ESS
Management System
Task of the Keit(2015-2017)
Energy Multipurpose Facility(BEMS)
Installing PV+WF+FB(25kW /100kWh)
Company Demonstration Center(’19.7)
Multifunction
Flow Battery Installing
PV+FB 5kW
S University of Japan(2016 -)
Installing 20kW VRFB
ETRI
(’17. 5)
(’17. 7)
Large-Scale demonstration
Drive renewable energy link
1MW/4MWh
Installing LIB + 20kW VRFB
H University
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