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BASF - ANL Collaboration on NCM
Cathode Materials
Michael Fetcenko
Commission to Review the Effectivenes of the National
Energy Laboratories
November 4, 2014 1
November 4, 2014 2
We combine economic success, social
responsibility and environmental
protection
Sales 2013: €73,973 million
EBIT 2013: €7,273 million
Employees (as of December 31, 2013):
112,206
6 Verbund sites and 376 other
production sites
Our chemistry is used in almost all
industries – Sales into automotive industry
around 15% of total sales
BASF – The Chemical Company
We Create Chemistry for a Sustainable Future
November 4, 2014
Chemistry-based innovations @ BASF
Growth fields
Resources,
Environment
& Climate
Food &
Nutrition
Quality of Life White
Biotechnology
Materials,
Systems &
Nanotechnology
Raw Material
Change
Key customer industries
Health & Nutrition
Consumer Goods
Transportation
Energy & Resources
Electronics
Agriculture
Construction
Technology fields Global needs
...
Batteries for Mobility
Enzymes
Heat Management for Construction
Organic Electronics
Functional Crop Care
Plant Biotechnology
E-Power Management
Wind Energy
Lightweight Composites
Water Solutions
3
November 4, 2014
Global business unit established 2012
Significant expansion of the scope of
its battery materials technologies over
the last two years
‒ Start-up of own production sites
‒ Licensing agreements
‒ Multiple acquisitions
‒ Investment into companies
In-house R&D and strategic
partnerships
BASF – The Chemical Company
BASF’s Comprehensive Battery Materials Portfolio
4
November 4, 2014
Argonne National Laboratory
ANL and Inventors – Strong Reputation
BASF collaboration with ANL on patent
protection and commercialization of
ANL Technology.
5
November 4, 2014
Argonne Battery Technology
Patent Confirmed by U.S. Patent Office
NMC cathode technology as described in this
patent can be found in commercial consumer
and vehicle lithium-ion batteries.
6
November 4, 2014
NCM Product Overview
Broad range of available
compositions
0.0 0.2 0.4 0.6 0.8 1.0
0.0
0.2
0.4
0.6
0.8
1.0 0.0
0.2
0.4
0.6
0.8
1.0
NCM-111
NCM-433
NCM-424 NCM-523
NCM-622
NCM-514 NCM-811
Co (LCO)
Ni (LNO) Mn (LMO)
NCM-929
HE-NCMs
HV spinel
LNCO
NCM-415
High capacity region
Lower cost region
Ni
High stability region
NCM COMPOSITION DIAGRAM
HE-NCM:
Discharge Capacity: 260 Ah/kg @ 0.1C
HV-Spinel:
Discharge Capacity: 140 Ah/kg @ 1C
NCM 111: Li1+x(Ni0.33Co0.33Mn0.33)1-xO2
Discharge Capacity: 154 Ah/kg @ 0.1C
NCM 523: Li1+x(Ni0.5Co0.2Mn0.3)1-xO2
Discharge Capacity: 164 Ah/kg @ 0.1C
NCM 424: Li1+x(Ni0.4Co0.2Mn0.4)1-xO2
Discharge Capacity: 155 Ah/kg @ 0.1C
NCM 622
Discharge Capacity: 178 Ah/kg @ 0.1C
Sta
te-o
f-th
e-a
rt
Hi N
ick
el
Mn
ric
h
NCM 811 and others
Discharge Capacity: >185 Ah/kg @ 0.1C
1
2
3
7
November 4, 2014
NCM & LFP Cathode Materials
Fully operational production
plants
Suitable for NCM materials
as well as for next generation
high energy NCM
BASF Battery Materials - Manufacturing
NCM plant – Elyria, Ohio
Electrolytes - Zachary, Louisiana and Suzhou, China
Electrolytes
State-of-the-art
manufacturing technology
Global presence: North
America and China
BASF Global Presence – includes R&D and Pilot Production in Ludwigshafen, Germany
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November 4, 2014 9
BASF’s battery materials portfolio:
Driving Your Success
Solid IP position ANL license for NCM cathode
materials
Ovonic patents for NCM
precursors
LFP license from LiFePO4+C
Licensing AG
VC license from Mitsubishi
Chemicals
Strong R&D R&D Centers in the US, Europe
and Asia
Strong development pipeline for
cathode materials and electrolytes
Global expert network to support
BASF’s R&D
Broad portfolio NiMH Technology from Ovonic
Batteries
Formulated electrolytes
NCM and LFP cathode materials
Li-Sulfur development together
with Sion Power
Global presence NCM production in Elyria, Ohio US
LFP production in Germany
Electrolyte production in Baton
Rouge (US) and Suzhou (China)
Customer application centers in
the US, Germany, China and
Japan
BASF’s
Battery
Materials:
Customer
centric
November 4, 2014
Marked capacity increase at slightly lower voltage “High Energy”
Discharge profiles HE-NCM vs. NCM-111
1.5
2.0
2.5
3.0
3.5
4.0
4.5
5.0
0 50 100 150 200 250 300
Capacity [Ah/kg]
HE-NCM
NCM-111
Vo
ltag
e [V
]
E = Q × U
Discharge profiles HV spinel vs. NCM-111
1.5
2.0
2.5
3.0
3.5
4.0
4.5
5.0
0 Capacity [Ah/kg]
Vo
ltag
e [V
]
50 100 150
NCM-111
HV spinel
E = Q × U
Performance benefit calculated in a model cell
Gravimetric energy
density [Wh/kg]
Volumetric energy
density [Wh/l]
NCM-111 219 606
HE-NCM +15% +5%
HV spinel +8% +8%
Marked voltage increase at slightly lower capacity “High Voltage”
HE NCM HV Spinel
High Energy Cathode Materials
Overview about next generation cathode materials
10
November 4, 2014
BASF Battery Materials
Global footprint
NCM production
NCM production plant in
Elyria, US (2.4 kt)
Application labs,
research centers
Amagasaki, Japan.
Further application labs
in the US, China and
Germany
Research centers in the
US and Germany
Ele
ctr
oly
te
pro
du
cti
on
Production
capacity in Suzhou,
China.
Further capacity in
Louisiana
LFP production LFP production in
Ludwigshafen and
Weimar, Germany
(3.0 kt)
11
November 4, 2014
BASF Collaboration with ANL
Multiple Fields including Battery and Agricultural
BASF is proud licensee of ANL NCM Cathode
Technology
Active development of next generation NCM
Materials
Capital Investment for Commercialization
− Elyria, Ohio factory for NCM Calcination
− Acquisition of Ovonic Precursor
Patent Collaboration
12