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  • 8/11/2019 Automotive Gas Oil

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    Automotive Gas Oil

    SAFETY DATA SHEET

    Product name

    Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II - Europe

    :1.1 Product identifier

    Index number : 649-224-00-6

    REACH Registration number

    EC number : 269-822-7

    Registration number Legal entity

    01-2119484664-27 -

    Automotive Gas Oil

    Material uses : Automotive diesel fuel

    CAS number

    1.3 Details of the supplier of the safety data sheet

    e-mail address of personresponsible for this SDS

    :

    : 68334-30-5

    1.2 Relevant identified uses of the substance or mixture and uses advised against

    1.4 Emergency telephone number

    Not applicable.

    Manufacturer / Distributor : Kuwait Petroleum CorporationP.O. Box 26565 Safat13126 SafatKuwaitTel. +965 1858585, Fax 2423371/2467159/246

    [email protected], communication preferably in English only.

    SECTION 1: Identification of the substance/mixture and of thecompany/undertaking

    Middle East : +44 (0) 1235 239 671

    Global (English only) : +44 (0) 1865 407 333

    See Section 11 for more detailed information on health effects and symptoms.

    Classification according to Regulation (EC) No. 1272/2008 [CLP/GHS]

    None.

    None.

    SECTION 2: Hazards identification

    2.1 Classification of the substance or mixture

    Product definition : UVCB

    Classification according to Directive 67/548/EEC [DSD]

    See Section 16 for the full text of the R phrases or H statements declared above.

    Ingredients of unknowntoxicity

    :

    Ingredients of unknownecotoxicity

    :

    Carc. Cat. 3; R40Xn; R20, R65Xi; R38N; R51/53

    Flam. Liq. 3, H226

    Acute Tox. 4, H332Skin Irrit. 2, H315

    Carc. 2, H351sSTOT RE 2, H373sSTOT RE 2, H373i

    Asp. Tox. 1, H304Aquatic Chronic 2, H411

    Date of issue/Date of revision : 1/141/10/2012.

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    Automo tive Gas Oil

    Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II - Europe

    SECTION 2: Hazards identification

    :Other hazards which do notresult in classification

    Hazardous concentrations of hydrogen sulphide (H2S) gas may accumulate in thevapour space of storage vessels. Standard procedures for opening or entering tanks,vessels or other containers must strictly be followed to avoid inhalation of this acutelytoxic gas.

    2.2 Label elements

    Hazard pictograms :

    Signal word :

    Hazard statements :

    Prevention :

    Precautionary statements

    Response :

    Storage :

    Disposal :

    Danger

    P261 - Avoid breathing dust/fume/gas/mist/vapors/spray.P280 - Wear protective gloves/protective clothing/eye protection/face protection.

    P301 - IF SWALLOWED:P310 - Immediately call a POISON CENTER or doctor/physician.P331 - Do NOT induce vomiting.

    P235 - Keep cool.

    P501 - Dispose of contents and container in accordance with all local, regional,national and international regulations.

    Supplemental labelelements

    Containers to be fittedwith child-resistantfastenings

    Yes, applicable.

    Tactile warning of danger Yes, applicable.

    :

    :

    : Not applicable.

    Special packaging requirements

    2.3 Other hazards

    Substance meets thecriteria for PBT accordingto Regulation (EC) No.1907/2006, Annex XIII

    : No.

    PBT: Specified

    Substance meets thecriteria for vPvB accordingto Regulation (EC) No.1907/2006, Annex XIII

    : No.

    vPvB: Specified

    H226 Flammable liquid and vapor.H332 Harmful if inhaled.H315 Causes skin irritation.H351s Suspected of causing cancer.H373s May cause damage to organs through prolonged or repeated exposure in

    contact with skin.

    H373i May cause damage to organs through prolonged or repeated exposure ifinhaled.

    H304 May be fatal if swallowed and enters airways.H411 Toxic to aquatic life with long lasting effects.

    Substance/mixture UVCB:

    SECTION 3: Composition/information on ingredients

    Date of issue/Date of revision : 2/141/10/2012.

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    Automo tive Gas Oil

    Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II - Europe

    SECTION 3: Composition/information on ingredients

    Fuels, diesel REACH #: 01-2119484664-27EC: 269-822-7

    CAS: 68334-30-5Index: 649-224-00-6

    100 Carc. Cat. 3; R40

    Xn; R20, R65

    Xi; R38N; R51/53

    Flam. Liq. 3, H226

    Acute Tox. 4, H332

    Skin Irrit. 2, H315Carc. 2, H351sSTOT RE 2, H373sSTOT RE 2, H373i

    Asp. Tox. 1, H304Aquatic Chronic 2, H411

    [A]

    Occupational exposure limits, if available, are listed in Section 8.

    Identifiers 67/548/EECProduct/ingredientname

    See Section 16 forthe full text of the R-phrases declaredabove.

    % TypeRegulation (EC) No.1272/2008 [CLP]

    Classification

    See Section 16 for thefull text of the Hstatements declaredabove.

    [*] Substance[A] Constituent[B] Impurity[C] Stabilizing additive

    Type

    There are no additional ingredients present which, within the current knowledge of the supplier, are classified and

    contribute to the classification of the substance and hence require reporting in this section.

    Get medical attention immediately. Call a poison center or physician. Wash outmouth with water. Remove dentures if any. Remove victim to fresh air and keep atrest in a position comfortable for breathing. If material has been swallowed and theexposed person is conscious, give small quantities of water to drink. Stop if theexposed person feels sick as vomiting may be dangerous. Aspiration hazard ifswallowed. Can enter lungs and cause damage. Do not induce vomiting. If vomitingoccurs, the head should be kept low so that vomit does not enter the lungs. Nevergive anything by mouth to an unconscious person. If unconscious, place in recoveryposition and get medical attention immediately. Maintain an open airway. Loosentight clothing such as a collar, tie, belt or waistband.

    Skin contact

    Immediately flush eyes with plenty of water, occasionally lifting the upper and lowereyelids. Check for and remove any contact lenses. Continue to rinse for at least 10minutes. Get medical attention.

    Wash contaminated skin with soap and water. Remove contaminated clothing andshoes. Wash contaminated clothing thoroughly with water before removing it, or weargloves. Continue to rinse for at least 10 minutes. Get medical attention. Washclothing before reuse. Clean shoes thoroughly before reuse.

    4.1 Description of first aid measures

    Remove victim to fresh air and keep at rest in a position comfortable for breathing. Ifexposure to hydrogen sulphide is suspected or cannot be excluded, obtain medicalattention IMMEDIATELY. If it is suspected that fumes are still present, the rescuershould wear an appropriate mask or self-contained breathing apparatus. If notbreathing, if breathing is irregular or if respiratory arrest occurs, provide artificialrespiration or oxygen by trained personnel. It may be dangerous to the personproviding aid to give mouth-to-mouth resuscitation. Get medical attention. Ifnecessary, call a poison center or physician. If unconscious, place in recoveryposition and get medical attention immediately. Maintain an open airway. Loosentight clothing such as a collar, tie, belt or waistband.

    Ingestion

    Inhalation

    Eye contact

    :

    :

    :

    :

    Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. If it issuspected that fumes are still present, the rescuer should wear an appropriate maskor self-contained breathing apparatus. It may be dangerous to the person providingaid to give mouth-to-mouth resuscitation.

    SECTION 4: First aid measures

    Date of issue/Date of revision : 3/141/10/2012.

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    Automo tive Gas Oil

    Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II - Europe

    SECTION 4: First aid measures

    Notes to physician Treat symptomatically. Contact poison treatment specialist immediately if largequantities have been ingested or inhaled.

    :

    Specific treatments

    4.2 Most important symptoms and effects, both acute and delayed

    Potential acute health effects

    Inhalation : Harmful if inhaled.

    May be fatal if swallowed and enters airways. Irritating to mouth, throat and stomach.:Ingestion

    Skin contact : Causes skin irritation.

    Causes serious eye irritation.:Eye contact

    Over-exposure signs/symptoms

    Skin contact

    Ingestion

    Inhalation No specific data.

    Adverse symptoms may include the following:nausea or vomiting

    Adverse symptoms may include the following:irritationredness

    :

    :

    :

    Eye contact : Adverse symptoms may include the following:pain or irritationwateringredness

    4.3 Indication of any immediate medical attention and special treatment needed

    No specific treatment.:

    Promptly isolate the scene by removing all persons from the vicinity of the incident ifthere is a fire. No action shall be taken involving any personal risk or without suitabletraining. Move containers from fire area if this can be done without risk. Use waterspray to keep fire-exposed containers cool.

    Hazardous thermaldecomposition products

    Hazards from thesubstance or mixture

    Decomposition products may include the following materials:carbon dioxidecarbon monoxide

    sulfur oxidesHydrogen sulphide

    Flammable liquid and vapor. In a fire or if heated, a pressure increase will occur andthe container may burst, with the risk of a subsequent explosion. Runoff to sewer maycreate fire or explosion hazard. This material is toxic to aquatic life with long lastingeffects. Fire water contaminated with this material must be contained and preventedfrom being discharged to any waterway, sewer or drain.

    Fire-fighters should wear appropriate protective equipment and self-containedbreathing apparatus (SCBA) with a full face-piece operated in positive pressuremode. Clothing for fire-fighters (including helmets, protective boots and gloves)conforming to European standard EN 469 will provide a basic level of protection for

    chemical incidents.

    Special protectiveequipment for fire-fighters

    Use dry chemical, CO2, water spray (fog) or foam.

    5.1 Extinguishing media

    :

    :

    :

    Do not use water jet.

    Suitable extinguishingmedia

    :

    Unsuitable extinguishingmedia

    :

    SECTION 5: Firefighting measures

    5.2 Special hazards arising from the substance or mixture

    5.3 Advice for firefighters

    Special protective actionsfor fire-fighters

    :

    Date of issue/Date of revision : 4/141/10/2012.

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    Automo tive Gas Oil

    Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II - Europe

    6.2 Environmentalprecautions

    Stop leak if without risk. Move containers from spill area. Approach release fromupwind. Prevent entry into sewers, water courses, basements or confined areas.Wash spillages into an effluent treatment plant or proceed as follows. Contain andcollect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculiteor diatomaceous earth and place in container for disposal according to localregulations (see section 13). Use spark-proof tools and explosion-proof equipment.Dispose of via a licensed waste disposal contractor. Contaminated absorbentmaterial may pose the same hazard as the spilled product. Note: see section 1 foremergency contact information and section 13 for waste disposal.

    Avoid dispersal of spilled material and runoff and contact with soil, waterways, drainsand sewers. Inform the relevant authorities if the product has caused environmentalpollution (sewers, waterways, soil or air). Water polluting material. May be harmful tothe environment if released in large quantities. Collect spillage.

    Large spill :

    Stop leak if without risk. Move containers from spill area. Dilute with water and mop

    up if water-soluble. Alternatively, or if water-insoluble, absorb with an inert drymaterial and place in an appropriate waste disposal container. Use spark-proof toolsand explosion-proof equipment. Dispose of via a licensed waste disposal contractor.

    Small spill :

    6.3 Methods and materials for containment and cleaning up

    SECTION 6: Accidental release measures

    6.1 Personal precautions, protective equipment and emergency procedures

    For non-emergencypersonnel

    :

    For emergency responders :

    6.4 Reference to othersections

    See Section 1 for emergency contact information.See Section 8 for information on appropriate personal protective equipment.See Section 13 for additional waste treatment information.

    No action shall be taken involving any personal risk or without suitable training.Evacuate surrounding areas. Keep unnecessary and unprotected personnel fromentering. Do not touch or walk through spilled material. Shut off all ignition sources.No flares, smoking or flames in hazard area. Avoid breathing vapor or mist. Provideadequate ventilation. Wear appropriate respirator when ventilation is inadequate. Puton appropriate personal protective equipment.

    If specialised clothing is required to deal with the spillage, take note of any informationin Section 8 on suitable and unsuitable materials. See also the information in "Fornon-emergency personnel".

    :

    :

    SECTION 7: Handling and storage

    The information in this section contains generic advice and guidance. The list of Identified Uses in Section 1 should beconsulted for any available use-specific information provided in the Exposure Scenario(s).

    7.1 Precautions for safe handling

    Protective measures :

    Advice on generaloccupational hygiene

    :

    Put on appropriate personal protective equipment (see Section 8). Hazardousconcentrations of hydrogen sulphide (H2S) gas may accumulate in the vapour space

    of storage vessels. Standard procedures for opening or entering tanks, vessels orother containers must strictly be followed to avoid inhalation of this acutely toxic gas.

    Avoid exposure - obtain special instructions before use. Do not handle until all safetyprecautions have been read and understood. Do not get in eyes or on skin orclothing. Do not breathe vapor or mist. Do not swallow. Avoid release to theenvironment. Use only with adequate ventilation. Wear appropriate respirator whenventilation is inadequate. Do not enter storage areas and confined spaces unlessadequately ventilated. Keep in the original container or an approved alternative madefrom a compatible material, kept tightly closed when not in use. Store and use awayfrom heat, sparks, open flame or any other ignition source. Use explosion-proofelectrical (ventilating, lighting and material handling) equipment. Use only non-sparking tools. Take precautionary measures against electrostatic discharges.Empty containers retain product residue and can be hazardous. Do not reuse

    container.

    Eating, drinking and smoking should be prohibited in areas where this material ishandled, stored and processed. Workers should wash hands and face before eating,drinking and smoking. Remove contaminated clothing and protective equipmentbefore entering eating areas. See also Section 8 for additional information on hygienemeasures.

    Date of issue/Date of revision : 5/141/10/2012.

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    Automo tive Gas Oil

    Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II - Europe

    SECTION 7: Handling and storage

    Store in accordance with local regulations. Store in a segregated and approved area.Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see section 10) and food anddrink. Store locked up. Eliminate all ignition sources. Separate from oxidizingmaterials. Keep container tightly closed and sealed until ready for use. Containersthat have been opened must be carefully resealed and kept upright to prevent

    leakage. Do not store in unlabeled containers. Use appropriate containment to avoidenvironmental contamination. Provide adequate ventilation.

    7.2 Conditions for safestorage, including anyincompatibilities

    7.3 Specific end use(s)

    Recommendations :

    :Industrial sector specificsolutions

    Not available.

    Not available.

    :

    Product/ingredient name Exposure limit values

    Recommended monitoringprocedures

    Fuels, diesel ACGIH TLV (United States, 2/2010). Absorbed through skin. TWA: 100 mg/m, (measured as total hydrocarbons) 8 hour(s).Form: Total hydrocarbons

    Occupational exposure limits

    If this product contains ingredients with exposure limits, personal, workplaceatmosphere or biological monitoring may be required to determine the effectivenessof the ventilation or other control measures and/or the necessity to use respiratoryprotective equipment. Reference should be made to European Standard EN 689 formethods for the assessment of exposure by inhalation to chemical agents andnational guidance documents for methods for the determination of hazardoussubstances.

    Safety eyewear complying with an approved standard should be used when a riskassessment indicates this is necessary to avoid exposure to liquid splashes, mists,gases or dusts.

    Eye/face protection :

    :

    Skin protection

    Appropriate engineering

    controls

    : Product may release hydrogen sulphide: a specific assessment of inhalation risks

    from the presence of hydrogen sulphide in tank headspaces, confinedspaces, product residue, tank waste and waste water and unintentional releasesshould be made to help determine controls appropriate to local circumstances. Useonly with adequate ventilation. Use process enclosures, local exhaust ventilation orother engineering controls to keep worker exposure to airborne contaminants belowany recommended or statutory limits. The engineering controls also need to keepgas, vapor or dust concentrations below any lower explosive limits. Use explosion-proof ventilation equipment.

    Wash hands, forearms and face thoroughly after handling chemical products, beforeeating, smoking and using the lavatory and at the end of the working period.

    Appropriate techniques should be used to remove potentially contaminated clothing.

    Wash contaminated clothing before reusing. Ensure that eyewash stations andsafety showers are close to the workstation location.

    8.2 Exposure controls

    Hygiene measures :

    No DELs available.

    Predicted effect concentrations

    No PECs available.

    SECTION 8: Exposure controls/personal protection

    The information in this section contains generic advice and guidance. The list of Identified Uses in Section 1 should be

    consulted for any available use-specific information provided in the Exposure Scenario(s).8.1 Control parameters

    Derived effect levels

    Individual protection measures

    Date of issue/Date of revision : 6/141/10/2012.

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    Automo tive Gas Oil

    Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II - Europe

    SECTION 8: Exposure controls/personal protection

    Hand protection

    Use a properly fitted, air-purifying or air-fed respirator complying with an approvedstandard if a risk assessment indicates this is necessary. Respirator selection mustbe based on known or anticipated exposure levels, the hazards of the product andthe safe working limits of the selected respirator.

    Chemical-resistant, impervious gloves complying with an approved standard shouldbe worn at all times when handling chemical products if a risk assessment indicatesthis is necessary. Wear suitable gloves tested to EN374.

    Respiratory protection :

    :

    Personal protective equipment for the body should be selected based on the taskbeing performed and the risks involved and should be approved by a specialistbefore handling this product.

    :

    Environmental exposurecontrols

    : Emissions from ventilation or work process equipment should be checked to ensurethey comply with the requirements of environmental protection legislation. In somecases, fume scrubbers, filters or engineering modifications to the process equipmentwill be necessary to reduce emissions to acceptable levels.

    Body protection :

    Other skin protection Appropriate footwear and any additional skin protection measures should be selected

    based on the task being performed and the risks involved and should be approved bya specialist before handling this product.

    SECTION 9: Physical and chemical properties

    9.1 Information on basic physical and chemical properties

    150 to 390C

    Physical state

    Melting point/freezing point

    Initial boiling point and boilingrange

    Vapor pressure

    Relative density

    Vapor density

    Solubility(ies)

    Liquid. [Oily liquid.]

    225C

    Closed cup: >55C [ASTM D93.]

    Lower: 1%Upper: 6%

    Not applicable.

    Not available.

    7

    Not available.Odor threshold

    Partition coefficient: n-octanol/water

    Upper/lower flammability orexplosive limits

    Explosive properties

    :

    :

    :

    :

    :

    :

    :

    :

    :

    :

    :

    :

    :

    :

    :

    :

    :

    Not applicable.Oxidizing properties :

    Appearance

    9.2 Other information

    Decomposition temperature : >225C

    Flammability (solid, gas) : Not applicable.

    No additional information.

    Appearance : Clear.

    Viscosity (40C)

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    Automo tive Gas Oil

    Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II - Europe

    10.6 Hazardousdecomposition products

    10.4 Conditions to avoid Avoid all possible sources of ignition (spark or flame). Do not pressurize, cut, weld,braze, solder, drill, grind or expose containers to heat or sources of ignition.

    Decomposition products may include the following materials:sulfur oxidesHydrogen sulphide

    The product is stable.10.2 Chemical stability

    Reactive or incompatible with the following materials:oxidizing materials

    :

    :

    :

    10.5 Incompatible materials :

    10.3 Possibility of hazardousreactions

    : Under normal conditions of storage and use, hazardous reactions will not occur.

    SECTION 10: Stability and reactivity

    10.1 Reactivity : No specific test data related to reactivity available for this product or its ingredients.

    Acute toxicity

    Conclusion/Summary : Not available.

    Carcinogenicity

    Fuels, diesel Positive - Dermal - TC Rat - Male 25 ug/kg -

    Product/ingredient name Result Species Dose Exposure

    Conclusion/Summary : Not available.

    Mutagenicity

    Fuels, diesel 471 Bacterial ReverseMutation Test

    Subject: BacteriaCell: Germ

    Positive

    Product/ingredient name Test Experiment Result

    Conclusion/Summary : Not available.

    Teratogenicity

    Reproductive toxicity

    Product/ingredient name Maternaltoxicity

    Fertility Developmenttoxin

    Species

    Conclusion/Summary : Not available.

    Dose Exposure

    Fuels, diesel Positive - Positive Rat Dermal:

    125mg/kg

    20 days; 7

    days perweek

    Irritation/Corrosion

    Fuels, diesel Skin - Severe irritant Rabbit - 24 hours 500microliters

    -

    Skin - Severe irritant Rabbit - 240 hours 80Grams

    -

    Product/ingredient name Result Score Exposure Observation

    Conclusion/Summary : Not available.

    Sensitization

    Conclusion/Summary : Not available.

    Species

    SECTION 11: Toxicological information

    11.1 Information on toxicological effects

    Fuels, diesel LC50 Inhalation Dusts and mists Rat 4.1 mg/l 4 hours

    LD50 Oral Rat 7500 mg/kg -

    Product/ingredient name Result Species Dose Exposure

    Date of issue/Date of revision : 8/141/10/2012.

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    Automo tive Gas Oil

    Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II - Europe

    SECTION 11: Toxicological information

    Potential chronic health effects

    Potential acute health effects

    Inhalation : Harmful if inhaled.

    May be fatal if swallowed and enters airways. Irritating to mouth, throat and stomach.:Ingestion

    Skin contact : Causes skin irritation.

    Causes serious eye irritation.:Eye contact

    May cause damage to organs through prolonged or repeated exposure if inhaled or incontact with skin.

    General :

    Fuels, diesel Sub-chronic NOAEL Dermal Rat - Male,

    Female

    30 mg/kg 90 days; 5 days

    per weekSub-chronic NOEL InhalationDusts and mists

    Rat - Male,Female

    750 mg/m 90 days

    Product/ingredient name Result Species Dose Exposure

    Conclusion/Summary : Not available.

    Fuels, diesel Positive - Dermal Rat - Male 125 mg/kg 20 days; 7 daysper week

    Product/ingredient name Result Species Dose Exposure

    Conclusion/Summary : Not available.

    Symptoms related to the physical, chemical and toxicological characteristics

    Skin contact

    Ingestion

    Inhalation No specific data.

    Adverse symptoms may include the following:nausea or vomiting

    Adverse symptoms may include the following:irritationredness

    :

    :

    :

    Eye contact : Adverse symptoms may include the following:pain or irritationwateringredness

    Not available.

    Specific target organ toxicity (single exposure)

    Specific target organ toxicity (repeated exposure)

    Product/ingredient name Category

    Aspiration hazard

    Product/ingredient name Result

    Route ofexposure

    Target organs

    Information on the likelyroutes of exposure

    :

    Delayed and immediate effects and also chronic effects from short and long term exposure

    Short term exposure

    Long term exposure

    Potential immediateeffects

    Potential delayed effects :

    :

    Potential immediateeffects

    Potential delayed effects :

    :

    Not available.

    Not available.

    Not available.

    Not available.

    Fuels, diesel ASPIRATION HAZARD - Category 1

    Not available.

    Fuels, diesel Category 2 Skin Not determined

    Inhalation Not determined

    Date of issue/Date of revision : 9/141/10/2012.

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    Automo tive Gas Oil

    Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II - Europe

    SECTION 11: Toxicological informationSuspected of causing cancer in contact with skin. Risk of cancer depends on durationand level of exposure.

    Carcinogenicity :

    No known significant effects or critical hazards.Mutagenicity :

    No known significant effects or critical hazards.Teratogenicity :

    Developmental effects : No known significant effects or critical hazards.

    Fertility effects : No known significant effects or critical hazards.

    Other information : Not available.

    Mobility Not available.:

    12.3 Bioaccumulative potential

    12.6 Other adverse effects No known significant effects or critical hazards.

    Not available.

    Product/ingredient name Aquatic half-life Photolysis Biodegradability

    Fuels, diesel - - Readily

    12.1 Toxicity

    Fuels, diesel Acute EC50 210 mg/l Fresh water Daphnia 48 hoursAcute EC50 65 mg/l Fresh water Fish 96 hours

    Product/ingredient name SpeciesResult Exposure

    Conclusion/Summary : Not available.

    12.2 Persistence and degradability

    Fuels, diesel 301E ReadyBiodegradability -Modified OECDScreening Test

    60 % - Readily - 28 days - -

    Product/ingredient name Test DoseResult Inoculum

    Conclusion/Summary : Not available.

    PBT : No.

    PBT: Specified

    vPvB : No.

    vPvB: Specified

    SECTION 12: Ecological information

    12.4 Mobility in soil

    Soil/water partitioncoefficient (KOC)

    Not available.:

    12.5 Results of PBT and vPvB assessment

    :

    Date of issue/Date of revision : 10/141/10/2012.

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    Automo tive Gas Oil

    Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II - Europe

    European waste catalogue (EWC)

    Yes.Hazardous waste :

    The generation of waste should be avoided or minimized wherever possible.Significant quantities of waste product residues should not be disposed of via the foul

    sewer but processed in a suitable effluent treatment plant. Dispose of surplus andnon-recyclable products via a licensed waste disposal contractor. Disposal of thisproduct, solutions and any by-products should at all times comply with therequirements of environmental protection and waste disposal legislation and anyregional local authority requirements.

    :Methods of disposal

    SECTION 13: Disposal considerations

    The information in this section contains generic advice and guidance. The list of Identified Uses in Section 1 should beconsulted for any available use-specific information provided in the Exposure Scenario(s).

    13.1 Waste treatment methods

    Product

    Packaging

    Waste code Waste designation

    Methods of disposal :

    Special precautions :

    13 07 01* fuel oil and diesel

    The generation of waste should be avoided or minimized wherever possible. Wastepackaging should be recycled. Incineration or landfill should only be consideredwhen recycling is not feasible.

    This material and its container must be disposed of in a safe way. Care should betaken when handling emptied containers that have not been cleaned or rinsed out.Empty containers or liners may retain some product residues. Vapor from productresidues may create a highly flammable or explosive atmosphere inside the container.Do not cut, weld or grind used containers unless they have been cleaned thoroughlyinternally. Avoid dispersal of spilled material and runoff and contact with soil,waterways, drains and sewers.

    DIESEL FUEL

    3

    III

    DIESEL FUEL. Marinepollutant (Fuels,diesel)

    3

    III

    Diesel fuel

    UN1202

    33

    Diesel fuel

    III

    1202

    III

    UN1202 UN1202

    Hazard identificationnumber30

    Limited quantityLQ7

    Special provisions640K

    Tunnel code

    - Emergencyschedules (EmS)F-E, S-E

    Passenger and CargoAircraftQuantitylimitation: 60 LPackaging instructions:

    309Cargo Aircraft OnlyQuantity limitation:220 LPackaging instructions:310Limited Quantities -

    SECTION 14: Transport information

    ADR/RID IMDG IATA

    14.1 UN number

    14.2 UN propershipping name

    14.3 Transporthazard class(es)

    14.4 Packing group

    ADN/ADNR

    Additionalinformation

    14.5 Environmentalhazards

    14.6 Specialprecautions foruser

    Yes. Yes. Yes. Yes.

    Not available. Not available. Not available. Not available.

    Date of issue/Date of revision : 11/141/10/2012.

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    Automo tive Gas Oil

    Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II - Europe

    SECTION 14: Transport information(D/E) Passenger Aircraft

    Quantity limitation: 10 LPackaging instructions:Y309

    14.7 Transport in bulkaccording to Annex II of

    MARPOL 73/78 and the IBCCode

    : Not available.

    Other EU regulations

    Not applicable.Annex XVII - Restrictionson the manufacture,placing on the market anduse of certain dangeroussubstances, mixtures andarticles

    :

    National Inventory List : Australia inventory (AICS): This material is listed or exempted.China inventory (IECSC): This material is listed or exempted.Japan inventory: Not determined.Korea inventory: This material is listed or exempted.New Zealand Inventory of Chemicals (NZIoC): This material is listed or exempted.Philippines inventory (PICCS): This material is listed or exempted.

    United States inventory (TSCA 8b): This material is listed or exempted.Europe inventory: This material is listed or exempted.Canada inventory: This material is listed or exempted.

    Black List Chemicals : Not listed

    Priority List Chemicals : Not listed

    Integrated pollutionprevention and control list(IPPC) - Air

    : Not listed

    Integrated pollutionprevention and control list(IPPC) - Water

    : Not listed

    Chemical Weapons

    Convention List Schedule I

    Chemicals

    : Not listed

    Chemical WeaponsConvention List Schedule II

    Chemicals

    : Not listed

    Chemical Weapons

    Convention List Schedule IIIChemicals

    : Not listed

    International regulations

    SECTION 15: Regulatory information

    15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture

    EU Regulation (EC) No. 1907/2006 (REACH)

    Annex XIV - List of substances subject to authorization

    Product/ingredient name Carcinogeniceffects

    Mutagenic effects Developmentaleffects

    Fertility effects

    Fuels, diesel Carc. 2, H351s - - -

    15.2 Chemical SafetyAssessment

    Not available.

    Substances of very high concern

    :

    None of the components are listed.

    Date of issue/Date of revision : 12/141/10/2012.

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    Automo tive Gas Oil

    Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II - Europe

    SECTION 15: Regulatory information

    1/10/2012.Date of printing

    Date of issue/ Date ofrevision

    Version

    Notice to reader

    Date of previous issue

    :

    :

    :

    :

    R40- Limited evidence of a carcinogenic effect.

    R20- Harmful by inhalation.R65- Harmful: may cause lung damage if swallowed.R38- Irritating to skin.R51/53- Toxic to aquatic organisms, may cause long-term adverse effects in theaquatic environment.

    Full text of abbreviated R

    phrases

    :

    Carc. Cat. 3 - Carcinogen category 3Xn - HarmfulXi - IrritantN - Dangerous for the environment

    :Full text of classifications[DSD/DPD]

    Indicates information that has changed from previously issued version.

    1/10/2012.

    No previous validation.

    1

    SECTION 16: Other information

    Full text of abbreviated Hstatements

    :

    Abbreviations and acronyms : ATE = Acute Toxicity EstimateCLP = Classification, Labelling and Packaging Regulation [Regulation (EC) No.1272/2008]

    DNEL = Derived No Effect LevelEUH statement = CLP-specific Hazard statementPNEC = Predicted No Effect ConcentrationRRN = REACH Registration Number

    Procedure used to derive the classification according to Regulation (EC) No. 1272/2008 [CLP/GHS]

    Classification Justification

    Flam. Liq. 3, H226 On basis of test dataAcute Tox. 4, H332 On basis of test data

    Skin Irrit. 2, H315 On basis of test dataCarc. 2, H351s On basis of test dataSTOT RE 2, H373s On basis of test data

    STOT RE 2, H373i On basis of test dataAsp. Tox. 1, H304 On basis of test data

    Aquatic Chronic 2, H411 On basis of test data

    Full text of classifications[CLP/GHS]

    :

    H226 Flammable liquid and vapor.H304 May be fatal if swallowed and enters airways.H315 Causes skin irritation.

    H332 Harmful if inhaled.H351s Suspected of causing cancer.

    H373i May cause damage to organs through prolonged or repeated exposure ifinhaled.

    H373s May cause damage to organs through prolonged or repeated exposure incontact with skin.

    H411 Toxic to aquatic life with long lasting effects.

    Acute Tox. 4, H332 ACUTE TOXICITY: INHALATION - Category 4Aquatic Chronic 2, H411 AQUATIC TOXICITY (CHRONIC) - Category 2Asp. Tox. 1, H304 ASPIRATION HAZARD - Category 1

    Carc. 2, H351s CARCINOGENICITY: SKIN - Category 2Flam. Liq. 3, H226 FLAMMABLE LIQUIDS - Category 3Skin Irrit. 2, H315 SKIN CORROSION/IRRITATION - Category 2

    STOT RE 2, H373i SPECIFIC TARGET ORGAN TOXICITY (REPEATEDEXPOSURE): INHALATION - Category 2

    STOT RE 2, H373s SPECIFIC TARGET ORGAN TOXICITY (REPEATEDEXPOSURE): SKIN - Category 2

    Prepared by : Kuwait Petroleum Research & Technology B.V., The Netherlands

    Date of issue/Date of revision : 13/141/10/2012.

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    Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II - Europe

    SECTION 16: Other information

    To the best of our knowledge, the information contained herein is accurate. However, neither the above-namedsupplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of theinformation contained herein.Final determination of suitability of any material is the sole responsibility of the user. All materials may presentunknown hazards and should be used with caution. Although certain hazards are described herein, we cannotguarantee that these are the only hazards that exist.