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Page 1: ASSESSMENT REPORT SILT AND MOSS MAT SAMPLING
Page 2: ASSESSMENT REPORT SILT AND MOSS MAT SAMPLING
Page 3: ASSESSMENT REPORT SILT AND MOSS MAT SAMPLING

ASSESSMENT REPORT SILT AND MOSS MAT SAMPLING

on the DHC1 Mineral Claim

(928255) Cariboo Mining Division, British Columbia, Canada

Owner: Theodore VanderWart Operator: Theodore VanderWart

by

Theodore (Ted) VanderWart, B.Sc.

December 28, 2012

NTS: 083D14, 083D15

TRIM: 083D075, 076

Latitude: 52° 47’44” N

Longitude: 119° 00’ 17”W

ldegroot
Text Box
BC Geological Survey Assessment Report 33926
Page 4: ASSESSMENT REPORT SILT AND MOSS MAT SAMPLING

ii

TABLE OF CONTENTS page

1.0 INTRODUCTION ...........................................................................................................1

1.1 PHYSIOGRAPHY AND ACCESS .......................................................................................... 1

1.2 TITLE ...................................................................................................................................... 3

2.0 GEOLOGICAL SETTING ..............................................................................................3

3.0 WORK HISTORY ...........................................................................................................6

4.0 EXPLORATION .............................................................................................................6

4.1 SILT AND MOSS MAT SAMPLING ...................................................................................... 6

4.1.1 Results ............................................................................................................................... 7

5.0 CONCLUSIONS ........................................................................................................... 11

6.0 REFERENCES .............................................................................................................. 12

7.0 CERTIFICATE.............................................................................................................. 13

8.0 STATEMENT OF COSTS ............................................................................................ 14

9.0 LIST OF SOFTWARE USED ....................................................................................... 15

LIST OF TABLES page

Table 1: Claim Status, DHC Property .....................................................................................3

Table 2: Sample Locations......................................................................................................6

Table 3: Silt and moss mat sample results ...............................................................................8

LIST OF FIGURES page

1. Location Map DHC Property (1:850,000) ......................................................................2

2. Claim Map, DHC1 Property (1:125,000) .......................................................................4

3. Geology Map, DHC1 Property (1:125,000) ...................................................................5

4. Silt Geochemistry Plan Map, DHC1 Property (1:5,000) ..................................................9

5. Moss Mat Geochemistry Plan Map, DHC1 Property (1:5,000) ...................................... 10

LIST OF APPENDICES

I. Certificate of Analysis

II. Sample Preparation and Analytical Methods

Page 5: ASSESSMENT REPORT SILT AND MOSS MAT SAMPLING

1

1.0 INTRODUCTION

The DHC1 property (the “Property”) is located in the Cariboo Mining Division in east-

central British Columbia, Canada, centred at latitude 52°47’N and longitude 118°59’W,

approximately 20 km south-southeast of the town of Valemount (Figure 1). The Property is

located on NTS mapsheets 083D14 and 083D15, and TRIM maps 083D075 and 083D076.

A Property visit was carried out by the author to conduct a geochemical survey on the claim.

The survey consisted of the collection of 5 conventional stream sediment samples and 2 moss

mat samples from 5 sample sites.

1.1 PHYSIOGRAPHY AND ACCESS

Physiography of the Property is mountainous, lying on the eastern side of the Rocky

Mountain Trench. The lower slopes are steep and timbered along with some older clear-cuts.

The upper elevations of the property cover flatter terrain between several cirques. Abundant

talus is noted at the highest elevations. Relief of the Property ranges from 1,260 metres at the

logging road on Dave Henry Creek to approximately 2,500 metres at the mountain peaks.

Drainage is the region is generally dendritic, with all creeks on the Property draining into

Dave Henry creek.

Access to the Property from Valemount, BC is gained by traveling south on Highway 5

(South Yellowhead Highway) for approximately 2 km, then turning left onto Cedarside

Road which becomes the Canoe East Forest Service Road (FSR). Just past the 10 km mark

of the Canoe East FSR, a logging road branches left which heads up Dave Henry creek.

This road can be traveled for 8 km until a series of washouts in the road (Figure 2).

Currently, an ATV can traverse the washouts and cross Dave Henry creek approximately

2.5 km further up the road. The creek that drains the Property is approximately 3 km from

the washout or 500 metres from the crossing on Dave Henry creek. Alternately, helicopter

charters are available out of Valemount.

Page 6: ASSESSMENT REPORT SILT AND MOSS MAT SAMPLING

V

DHC1 Claim

0 200km

Figure No.: 1Drawn by: TVDate: December 2012

Property Location MapDHC1 Claim

Cariboo Mining Division, British Columbia, Canada

Valemount REE Project

Page 7: ASSESSMENT REPORT SILT AND MOSS MAT SAMPLING

3

1.2 TITLE

The Property consists of one MTO cell claim covering a total of 488.80 hectares (Figure 2).

The tenure is 100% owned by the author.

Table 1: Claim Status, DHC Property

Tenure Number Area (ha) Owner (100%) Good To Date Worked On Claim Type

928255 488.80 T. VanderWart 2013/nov/05 Yes Mineral

2.0 GEOLOGICAL SETTING

Geological mapping has been completed in the general area on a regional scale by Campbell

(1968) and Price and Mountjoy (1970). More detailed geological mapping has been

reportedly carried out in the general vicinity of the Property. A compilation of all mapping

has been presented on Map 2110A produced by the Geological Survey of Canada Map

(Murphy, 1991).

The rocks in this area are mapped as belonging to the Proterozoic age Miette Group, which

forms part of the Windermere Supergroup.

The Property itself straddles the contact of the Upper Proterozoic Lower Middle Division of

the Miette Group and the Lower Division of the Miette Group (Figure 3). The former consists

of commonly graded and locally cross-bedded quartzofeldspathic metasandstone, granule and

pebble conglomerate (grit), siltstone, grey-green silty phyllite, and schist. The latter is

comprised of mainly grits (quartzofeldspathic sandstone, grit and minor phyllite). The contact

is mapped as a thrust fault which appears follow the main creek draining the claim area.

Near the southwest corner of the Property, the Old Fort Point Formation of the Miette Group

is mapped (Figure 3). This formation is comprised of a triad of: upper dark grey to black

carbonaceous phyllite; middle, dolomitic and calcareous siltstone and phyllite; and, basal

green phyllite slate and locally calcareous quartz siltstone. This formation is used for

stratigraphic correlation within the Miette Group (Grasby, 1991)

Page 8: ASSESSMENT REPORT SILT AND MOSS MAT SAMPLING

567177

956989

953128

967729

1012406

831227

510199

1013837

1013638

510200

957009

979294

1014354

928255

Washouts

Dav

e H

enry

Cre

ek

Canoe East FSR

Valemount

Yello

wjack

et C

reek

Packsa

ddle Cree

k

CAN

OE REAC

H (K

INBASK

ET LAKE)

Canoe River

CANADIAN NATIO

NAL RAILWAY

5YELLOWHEAD

B.C.

8km

Cedarside Rd

DHC1 Claim

Area of Work(Figures 4 and 5)

35

00

00

E

35

50

00

E

36

00

00

E

36

50

00

E

5830000N

5835000N

5840000N

5845000N

5850000N

5855000N

5860000N

0 5000m

NAD83, UTM Zone 11 North083D14, 15

Figure No.: 2Drawn by: TVDate: December 2012

Mineral Tenure MapDHC 1 Claim

Cariboo Mining Division, British Columbia, Canada

Valemount REE Project

ClaimsLEGEND

DHC1 Claim

Mineral tenures as of December 8, 2012

Topography

Waterbody

Gravel road

Watercourse

Railway

Highway

553480

Paved road

1:125,000

Sources of data:Mineral tenures: MTO /

Topography: GeoGratis Natural Resources Canada

Land and Resource Data Warehouse (Tenures current as of December 8, 2012)

©

Page 9: ASSESSMENT REPORT SILT AND MOSS MAT SAMPLING

567177

956989

953128

967729

1012406

831227

510199

1013837

1013638

928255

510200

957009

979294

1014354

Dav

e H

enry

Cre

ek

Canoe East FSR

Valemount

Yello

wjack

et C

reek

Packsa

ddle Cree

k

Canoe River

CANADIAN NATIO

NAL RAILWAY

5YELLOWHEAD

B.C.

Cedarside RdArea of Work

(Figures 4 and 5)

350000E

355000E

360000E

365000E

5830000N

5835000N

5840000N

5845000N

5850000N

5855000N

5860000N

35

00

00

E

35

50

00

E

36

00

00

E

36

50

00

E

Figure No.: 3Drawn by: TVDate: December 2012

Regional Geology

Cariboo Mining Division, British Columbia, Canada

Valemount REE Project

GEOLOGY

Windermere Supergroup

Lower Division

Upper Division

Upper Middle Division

Lower Middle Division

Yellowjacket gneiss

Malton gneiss

Old Fort Point Formation

Unnamed: marble and pelitic schist

Bulldog gneiss

Upper Proterozoic

Early Proterozoic

Cambrian-Ordovician(?)

Lower Kaza Group

Upper Proterozoic

Early Proterozoic

Rocky Mountains

Cariboo and Monashee Mountains

Sources of data:Mineral tenures: MTO /

Topography: GeoGratis Natural Resources CanadaGeology: BC GeoFile 2005-1 (Massey et al)

Land and Resource Data Warehouse (Tenures current as of December 8, 2012)

©

0 5000m

NAD83, UTM Zone 11 North083D14, 15

1:125,000

Miette Group

Undifferentiated basal unit

Page 10: ASSESSMENT REPORT SILT AND MOSS MAT SAMPLING

6

3.0 WORK HISTORY

The only known exploration in the area of the Property consisted of the Regional

Geochemical Survey (RGS) conducted in 2005 for Geoscience BC. The current Property was

staked based on the results of a stream sediment sample (83D053003) collected during this

survey. This sample demonstrates anomalous values of rare earth elements (REE); in

particular: lanthanum (693.4ppm); cerium (1,120ppm); europium (20 ppm); samarium (116.0

ppm); terbium (16.0ppm); and, ytterbium (27ppm). The europium value represents the

highest concentration in the current BC RGS dataset. The multiple anomalous values of REE

suggest the presence of a common source.

4.0 EXPLORATION

4.1 SILT AND MOSS MAT SAMPLING

Field work was undertaken between September 28 and September 30, 2012. Exploration

consisted of collection of 5 silt samples and 2 moss mat samples from five sample sites. One

sample (34117) was taken to duplicate the historical regional geochemical sample

(83D053003) that precipitated the staking of the current Property. Further sampling was also

undertaken at selected locations higher up the creek, up to the first split of the creek into its

secondary tributaries that drain the upper elevations of the property.

Silt material was collected from trap sites along the creek banks. The material collected

appeared quite sandy so large samples (2–3 kg) were collected to ensure enough silt would be

available for analysis. At the two sites above the confluence of the secondary tributaries of

the main creek, moss mat samples were collected along with conventional silt samples. These

were collected as a means to check whether there would be an advantage in this type sample

media versus conventional silt samples.

Sample locations were GPS located where possible with a hand-held Garmin GPS12XL unit.

Flagging tape labeled with the sample number was also affixed to a nearby tree. Sample

coordinates are presented in Table 2. Figures 4 and 5 show the sample locations of the silt

samples and moss mat samples, respectively.

Table 2: Sample Locations

Sample No. Sample Type Location (UTM Zone 11 North)

Easting Northing

34111 Silt 364678 5851502

34112 Silt 364958 5851335

34113 Silt 365064 5851242

34114 Moss Mat 365064 5851242

34115 Silt 365042 5851221

34116 Moss Mat 365042 5851221

34117 Silt 364409 5851587

Page 11: ASSESSMENT REPORT SILT AND MOSS MAT SAMPLING

7

Both silt and moss mat samples were placed in a labeled polyethylene sample bag and sealed

with plastic tie locks. Samples were delivered to ALS Minerals (ALS) laboratory in North

Vancouver, BC. ALS carried out sample preparation and geochemical analysis. Sample

preparation consisted of drying and sieving the material to 180µm fraction (ALS preparation

code PREP-41, Appendix I). The remaining fraction has been retained for future use.

Sample decomposition was by lithium metaborate fusion and analysis for 38 elements by

induced coupled plasma with mass spectrometer finish (ICP-MS) (ALS analysis code ME-

MS81, Appendix I). This analysis specifically targets REE’s as well as other rare metals. A

prepared sample (0.200 g) is added to lithium metaborate flux (0.90 g), mixed well and fused

in a furnace at 1,000°C. The resulting melt is then cooled and dissolved in 100 mL of 4%

HNO3/2% HCl3 solution. This solution is then analyzed by ICP-MS. All elements are

reported in parts per million (ppm). The certificates of analysis is found in Appendix II.

ALS quality control consisted of routine use of standards, blanks and duplicates.

4.1.1 Results

A table of the key REE results are presented in Table 3. Results returned demonstrate that

anomalous values of REE’s are present in the creek, but most notably in samples 34111 and

34112, which were collected from the main creek below the first split (Figure 4). The sample

results from the secondary tributaries were significantly lower than sample 34112 collected

below the confluence. This strongly suggests that a possible source of the REE anomalies

may be very close to the location of sample 34112. The samples from the eastern split in the

creek (34113 and 34114) show slightly anomalous REE values as compared to the samples

collected on the western side (34115, 34116). Further investigation on the eastern slopes is

warranted.

Sample 34117, taken at the site of the 2005 RGS sample, demonstrated moderately anomalous

values, somewhat lower than the historical results. The historical results were determined by

neutron activation methods whereas the current results were determined by ICP-MS methods,

Neutron activation methods are likely to return more accurate values (pers comm, L. Bruce).

There is a fairly dramatic increase in the REE concentrations moving up the creek from

sample 34117 to 34111 and then to 34112. Between the latter two samples the concentration

effectively doubles in every analyzed REE element.

Moss mat samples 34114 and 34116 were taken at the same site as the convention silt samples

34113 and 34115 as a test to see if there was any advantage to this type of sample as

compared to convential silt samples. Comparison of the results shows very good correlation

of the values from the two sample media types which suggest that either sample type is an

effective means of testing the silt geochemistry. Sample locations and results of the moss mat

samples are presented in Figure 5.

Page 12: ASSESSMENT REPORT SILT AND MOSS MAT SAMPLING

8

Table 3: Silt and moss mat sample results

Sample

No.

Sample

Type

Ce Dy Er Eu Gd Ho La Lu Nd Pr Sm Tb Tm Y Yb

ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm

34111 Silt 1160 83.20 40.9 21.60 109.0 16.05 729.0 3.30 679.0 177.5 113.00 15.55 4.95 464.0 25.8

34112 Silt 2050 168.50 84.0 42.30 221.0 33.10 1455.0 6.48 1370.0 358.0 226.00 31.60 10.05 1065.0 51.0

34113 Silt 802 17.35 8.6 5.60 22.9 3.19 156.0 0.97 161.0 42.2 30.40 3.28 1.19 69.6 7.3

34114 Moss Mat 305 17.75 8.9 5.94 23.5 3.30 140.5 1.08 160.5 40.2 32.50 3.39 1.28 69.6 8.0

34115 Silt 222 6.75 3.4 2.62 10.6 1.25 117.0 0.44 90.7 25.4 14.55 1.37 0.50 35.4 3.1

34116 Moss Mat 229 7.38 3.7 2.72 10.9 1.37 120.5 0.44 94.5 26.3 15.10 1.45 0.54 37.8 3.2

34117 Silt 514 27.80 13.6 7.68 37.3 5.40 317.0 1.22 256.0 69.4 40.60 5.25 1.71 163.0 9.4

Page 13: ASSESSMENT REPORT SILT AND MOSS MAT SAMPLING

Dav

e H

enry

Cre

ek

34111

34112

3411334115

34117

83D053003

CePrNdSmEuGdDyTbY

YbLu

1160.0177.5679.0113.021.6

109.083.215.6

464.025.8

3.3

CePrNdSmEuGdDyTbYYbLu

2050.0358.0

1370.0226.0

42.3221.0168.5

31.61065.0

51.06.5

CePrNdSmEuGdDyTbYYbLu

514.069.4

256.040.6

7.737.327.8

5.3163.0

9.41.2

CePrNdSmEuGdDyTbY

YbLu

802.042.2

161.030.4

5.622.917.4

3.369.6

7.31.0

CePrNdSmEuGdDyTbY

YbLu

222.025.490.714.6

2.610.6

6.81.4

35.43.10.4

3642

00E

3644

00E

3646

00E

3648

00E

3650

00E

3652

00E

5851000N

5851200N

5851400N

5851600N

0 200m

NAD83, UTM Zone 11 NorthTRIM 083D076

1:5,000

Figure No.: 4Drawn by: TVDate: December 2012

Silt GeochemistryDHC1 Claim

Cariboo Mining Division, British Columbia, Canada

Valemount REE Project

LEGEND

DHC1 Claim

34115 ¼ Silt sample site and number

CePrNdSmEuGdDyTbY

YbLu

83D053003 RGS silt sample site and number

Page 14: ASSESSMENT REPORT SILT AND MOSS MAT SAMPLING

Dav

e H

enry

Cre

ek

3411434116 Ce

PrNdSmEuGdDyTbY

YbLu

305.040.2

160.532.5

5.923.517.8

3.469.6

8.01.1

CePrNdSmEuGdDyTbY

YbLu

229.026.394.515.1

2.710.9

7.41.5

37.83.20.4

3642

00E

3644

00E

3646

00E

3648

00E

3650

00E

3652

00E

5851000N

5851200N

5851400N

5851600N

Figure No.: 5Drawn by: TVDate: December 2012

Moss Mat GeochemistryDHC1 Claim

Cariboo Mining Division, British Columbia, Canada

Valemount REE Project

0 200m

NAD83, UTM Zone 11 NorthTRIM 083D076

1:5,000

LEGEND

DHC1 Claim

34116 ¼ Moss mat sample site and number

Page 15: ASSESSMENT REPORT SILT AND MOSS MAT SAMPLING

11

5.0 CONCLUSIONS

The current claim was staked on the strength of multiple anomalous values of rare earth

elements (REE) in a regional geochemical survey (RGS) stream sediment survey conducted

for Geoscience BC in 2005.

Exploration was successful in confirming the presence of anomalous values of REE’s in the

silt of the sampled creek. Moreover, sampling above the original RGS sample showed

increasing concentrations of all analyzed REE elements until the first split of the creek into its

secondary tributaries.

Analysis of the convention silt samples and moss mat sample pairs demonstrated very good

correlation between analytical results. This indicates that either sample media should be

adequate for sampling purposes.

Respectfully Submitted,

Theodore (Ted) W. F. VanderWart, B.Sc.

December 28, 2012.

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12

6.0 REFERENCES

Grasby, S.E.

1991. Stratigraphy of the Miette Group and Tctonic History of the Southern Selwyn Range,

Western Main Ranges, British Columbia. M.Sc. thesis, Department of Geological

Sciences, McGill University, Montreal.

Massey, N.W.D., MacIntyre, D.G., Desjardins, P.J., Cooney, R.T.

2005. Digital Geology Map of British Columbia: Whole Province, B.C. Ministry of Energy

and Mines, Geofile 2005-1.

Murphy, D.C. (comp.)

1991. Geological compilation of the Canoe River Map-Area, Map 2110A, Geological

Survey of Canada

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13

7.0 CERTIFICATE

I, Theodore (Ted) W.F VanderWart, B.Sc., do hereby certify that:

• I am a graduate in geology of the University of British Columbia (B.Sc., 1994); and

have practiced in my profession continuously since 1996;

• I am presently a Consulting Geologist, and have been so since March 1996; and,

• Since 1996, I have been involved in mineral exploration for precious and/or base

metals in Canada (British Columbia, Yukon Territory), Ghana, and Democratic

Republic of Congo.

• I have visited the DHC1 Property and collected the samples as part of the exploration

program described herein.

Dated at New Westminster, British Columbia, this 28th

day of December, 2012.

___________________________

Theodore W.F VanderWart, B.Sc.

Page 18: ASSESSMENT REPORT SILT AND MOSS MAT SAMPLING

14

8.0 STATEMENT OF COSTS

Field Work

Personnel Unit Rate

T. VanderWart 3 400 1,200.00

R. Herfst 3 200 600.00

1,800.00

Equipment

Field Supplies 95.47

95.47

Disbursements

Food 211.25

Fuel 218.81

Hotel 181.56

Analytical Services (prep, analysis)

Silt and Moss Mat samples 7 34.94 244.58

856.20

Office Work (Reporting)

Personnel Unit Rate

T. VanderWart 1 400 400.00

400.00

Total $3,151.67

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15

9.0 LIST OF SOFTWARE USED

In the preparation of this report the following software was used:

Microsoft Word 2010

Excel 2010

Corel CorelDraw x5

Adobe Acrobat version 7

Micromine: Micromine 2011 (v12.5.5)

Page 20: ASSESSMENT REPORT SILT AND MOSS MAT SAMPLING

APPENDIX I

SAMPLE PREPARATION AND ANALYTICAL METHODS

Page 21: ASSESSMENT REPORT SILT AND MOSS MAT SAMPLING

Sample preparation package

prep- 41Standard preparation: dry Sample and dry- Sieve to –180 micron

Revision 02.01 | Feb 22, 2010 www.alsglobal.com

sample preparation is the most critical step in the entire laboratory operation. The purpose of preparation is to produce a homogeneous analytical sub-sample that is fully representative of the material submitted to the laboratory.

an entire sample is dried and then dry-sieved using a 180 micron (Tyler 80 mesh) screen. The plus fraction is retained unless disposal is requested. This method is appropriate for soil or sediment samples up to 1 kg in weight.

Sample preparation Flowchart package –prep- 41

* if samples air-dry overnight, no charge to client. if samples are excessively wet, the sample should be dried to a maximum of 120°c. (DRY-21)

# The plus fraction is the material remaining on the screen. The minus fraction is the material passing through the screen.

† The plus fraction is retained unless disposal is requested.

Receieve Sample

log-22 Affix Bar Code and log sample in lims

Wei-21 Record Received sample weight

ScR-41#

Dry sieve to 180 micron

Retain sample?

Retain pluS FRaction

Retain minuS FRaction FoR analYSiS

is the sample dry?*

no

minus Fraction

Yes

Plus Fraction

Dry sample

method code deScription

log-22 sample is logged in tracking system and a bar code label is attached.

DRY-22low temperature drying of excessively wet samples where the oven temperature is not to exceed 60°c. This method is suitable for more soil and sediment samples that are analyzed for volatile elements.

scR-41 sample is dry-sieved to – 180 micron and both the plus and minus fractions are retained.

Page 22: ASSESSMENT REPORT SILT AND MOSS MAT SAMPLING

Geochemical Procedure

me- mS81ultra- trace level methodS

Revision 05.00 | Feb 26, 2009 www.alsglobal.com

SamPle decomPoSitionLithium Metaborate Fusion (FUs-li01)

analytical methodInductively Coupled Plasma - Mass Spectroscopy (icP - ms)

A prepared sample (0.200 g) is added to lithium metaborate flux (0.90 g), mixed well and fused in a furnace at 1000°C. The resulting melt is then cooled and dissolved in 100 mL of 4% HNO3 / 2% HCl3 solution. This solution is then analyzed by inductively coupled plasma - mass spectrometry.

element Symbol unitS lower limit uPPer limit

Silver* ag ppm 1 1000

barium ba ppm 0.5 10000

cerium ce ppm 0.5 10000

Cobalt* co ppm 0.5 10000

chromium cr ppm 10 10000

cesium cs ppm 0.01 10000

Copper* cu ppm 5 10000

Dysprosium Dy ppm 0.05 1000

erbium er ppm 0.03 1000

europium eu ppm 0.03 1000

gallium ga ppm 0.1 1000

Gadolinium gd ppm 0.05 1000

Hafnium Hf ppm 0.2 10000

Holmium Ho ppm 0.01 1000

Lanthanum la ppm 0.5 10000

lutetium lu ppm 0.01 1000

Molybdenum* mo ppm 2 10000

Page 23: ASSESSMENT REPORT SILT AND MOSS MAT SAMPLING

me- mS81

www.alsglobal.com

element Symbol unitS lower limit uPPer limit

niobium nb ppm 0.2 10000

Neodymium nd ppm 0.1 10000

Nickel* ni ppm 5 10000

Lead* Pb ppm 5 10000

Praseodymium Pr ppm 0.03 1000

Rubidium Rb ppm 0.2 10000

samarium sm ppm 0.03 1000

Tin Sn ppm 1 10000

Strontium sr ppm 0.1 10000

Tantalum Ta ppm 0.1 10000

Terbium Tb ppm 0.01 1000

Thorium Th ppm 0.05 1000

Thallium Tl ppm 0.5 1000

Thulium Tm ppm 0.01 1000

Uranium U ppm 0.05 1000

Vanadium v ppm 5 10000

Tungsten w ppm 1 10000

Yttrium Y ppm 0.5 10000

Ytterbium Yb ppm 0.03 1000

Zinc* Zn ppm 5 10000

Zirconium Zr ppm 2 10000

* Note: Some base metal oxides and sulfides may not be completely decomposed by the lithium borate fusion. Results for Ag, Co, Cu, Mo, Ni, Pb, and Zn will not likely be quantitative by this method.

Revision 05.00 | Feb 26, 2009

Page 24: ASSESSMENT REPORT SILT AND MOSS MAT SAMPLING

me- mS81

www.alsglobal.comRevision 05.00 | Feb 26, 2009

Adding Base Metals – ME- AQ81, ME- 4ACD81

SamPle decomPoSitionAqua Regia (geo-aR01) or 4-acid (GEO-4ACID)

analytical methodInductively Coupled Plasma – Atomic emission spectroscopy (icP - aes)

The lithium metaborate fusion is not the preferred method for the determination of base metals. Many sulfides and some metal oxides are only partially decomposed by the borate fusion and some elements such as cadmium and zinc can be volatilized.

Base metals can be reported with ME-MS81 for either an aqua regia digestion (ME- AQ81) or a four acid digestion (ME- 4ACD81). The four acid digestion is preferred when the targets include more resistive mineralization such as that associated with nickel and cobalt

element Symbol unitS lower limit uPPer limit

Silver ag ppm 0.5 100

Arsenic as ppm 5 10000

cadmium cd ppm 0.5 10000

cobalt co ppm 1 10000

copper cu ppm 1 10000

Mercury** Hg ppm 1 10000

Molybdenum mo ppm 1 10000

Nickel ni ppm 1 10000

lead Pb ppm 1 10000

Zinc Zn ppm 2 10000

**Hg is only offered with the aqua regia digestion.

Page 25: ASSESSMENT REPORT SILT AND MOSS MAT SAMPLING

APPENDIX II

CERTIFICATES OF ANALYSIS

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