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ASC Z223 NFPA 54 COMMITTEE ON NATIONAL FUEL GAS CODE DRAFT COMMITTEE MINUTES June 21-22, 2016 APPROVAL PENDING

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  • ASC Z223 NFPA 54 COMMITTEE ON NATIONAL FUEL GAS CODE

    DRAFT COMMITTEE MINUTES

    June 21-22, 2016

    APPROVAL PENDING

  • ASC Z223 NFPA 54 COMMITTEE ON NATIONAL FUEL GAS CODE

    Draft 07/12/16

    Minutes ASC Z223 / NFPA 54

    National Fuel Gas Code Committee

    Embassy Suites Biltmore Phoenix

    Phoenix, AZ

    June 21-22, 2016

    1. Call to Order, Self-Introductions & Attendance: Chair, Tom Crane, called the meeting to order and members and guests introduced themselves. (Attachment A).

    2. Adoption of Agenda: The agenda was approved as distributed.

    3. Announcements: Participants were made aware of the fire alarms/exists and the AGA and NFPA antitrust guidelines. An overview of NFPA voting options and process was provided.

    4. Membership Review: a. ASC Z223 Committee Updates – The membership roster and interest category balance was

    reviewed. The committee is in balance in accordance with its operating procedures.

    b. NFPA 54 Committee Updates – The membership roster was reviewed. The NFPA Standards Council is responsible for maintaining committee balance and was noted that it is in balance.

    c. Expiring Chair Term and Replacement – Mr. Crane’s term as the Chair of ASC Z223 and NFPA 54 will end with the publication of the 2018 National Fuel Gas Code (NFGC). The ASC Z223

    procedures require an election of their Chair. The NFPA Standard Council appoints Chairs to their

    committees. As has been customary, ASC Z223 formed a nominating committee (Papageorge,

    Fasel) to seek nominees for ASC Z223 Chair and as a recommendation to the NFPA Standards

    Council for their appointment. The Secretary is requested to email the memberships of both

    committees seeking interested persons to contact the nominating committee by September 30th.

    5. Approval of Committee Meeting Minutes: The October 2015 full committee were approved as distributed.

    6. Future Meeting Schedule: The proposed 2017 meeting schedule was reviewed without changes (Attachment B).

    7. Consideration of Public Comment: The committee reviewed and took action on the public comments. The committee actions will be the standing action (Summary - Attachment C) on the letter ballot

    scheduled to be conducted in mid-August, 2016. Approved actions will form the Second Revision Draft.

    Changes from the First Draft will be utilized by the ASC Z223 as their second public review document.

    The Second Revision Draft will be used by the NFPA 54 membership as part of the NITMAM process.

    8. Other Actions:

    a. ASC Z223 - Formal Interpretation Request (Attachment D) – Section 9.6.5.1 (A). Committee Response for Letter Ballot: “Section 9.6.5.1 intends to require a union or flanged joint only where

    appliances are connected with rigid piping. Although not expressly stated, it is understood that a

    union would be redundant and unnecessary where appliances are connected with semi-rigid tubing

    and listed appliance connectors. Appliance connectors utilize a flare-type mechanical joint that

    allows the appliance controls to be serviced or replaced without disturbing the gas piping upstream

  • ASC Z223 NFPA 54 COMMITTEE ON NATIONAL FUEL GAS CODE

    Draft 07/12/16

    of the shutoff valve outlet.” The Secretary was requested to add the issue to the Piping Advisory

    Panel agenda for consideration.

    b. ASC Z223 - Formal Interpretation Request (See Attachment E) – Section 9.6.5 Appliance Shutoff Valves and Connections. A formal interpretation is not needed since the code is clear. The

    committee authorized the Secretary to send the following response: “The code would require

    the installation of a shutoff valve only where an appliance is connected to the piping. Until such

    time that the appliance is installed, the piping could be capped without a valve present. If a valve

    is installed prior to the installation of an appliance, or when the appliance is removed, such valve

    would have to be capped or plugged.” The Secretary was requested to add the issue to the

    Appliance Advisory Panel agenda for consideration.

    9. New Business:

    a. Appointment of NFPA 54/ASC Z223 Representative to NFPA 72. Mr. Lemoff was advised by the Staff Liaison to NFPA 72 that the Initiating Devices Technical Committee of the NFPA

    Signaling Systems Project is proposing to expand the section on gas detectors in the 2019 edition

    of NFPA 72, National Fire Alarm and Signaling Code. A task force has been formed to develop

    proposals for this subject, which could include the location of gas detectors. Interested persons

    should contact Ted Lemoff of their interest to serve as the NFPA 54 liaison.

    b. Industrial Appliance Installation Requirements. Mr. Lemoff expressed his belief that the requirement for the installation of industrial appliances in the Code is less than specific. He noted

    areas where the National Fuel Gas Code could be more specific in regard to industrial appliances.

    An example is Section 9.6.4, Connection of Portable and Mobile Industrial Appliances. Unsure

    of what type of appliances are being referenced and is the section still needed. Another example

    is Section 9.2.2 and Chapter 10 requirements on clearances to combustible for larger industrial

    appliances. The requirements apply to all gas appliances but should the clearances be different

    (larger) for industrial-type appliances to allow for maintenance and inspection. The Secretary

    was requested to add the issue to the Appliance Advisory Panel agenda for consideration and

    possible revisions to the 2021 Edition.

    c. Possible Committee Project on the use of “listed and labeled.” Other model installation codes use “listed and labeled” in describing the requirements for specific certified appliances and

    equipment. The Committee several editions ago deleted “labeled” from the National Fuel Gas

    Code since the terms of the listing include the required labeling. The Secretary was requested

    to add a review of the NFGC practice on the three advisory panel agendas for possible revision

    to the 2021 Edition.

    10. Odorization Basics Presentation: Mr. John Roberts, Rimkus Consulting Group, was invited by the Chair and he provided a 15-minute refresher presentation on basic gas odorization topics. Topics included

    odorization methods, types of odorants, natural gas and propane specific issues, possible causes of

    odorant fade, and its recognition by persons (Attachment F).

    11. Adjourn: With business completed, the committee adjourned on June 22th at 11:34 a.m.

  • 7/12/16

    ATTACHMENT A - Attendance List1

    National Fuel Gas Code Committee

    Embassy Suites Biltmore Phoenix Phoenix, AZ

    June 21-22, 2016

    Members2 Name, Representing

    Thomas Crane - Chair, Crane Engineering Paul Cabot - Secretary, American Gas Association Stephen Abernathy, American Gas Association Dmitry Antonov, Intertek Testing Services David Berning, Intertek Testing Services Jonathan Brania, Underwriters Laboratories Shannon Corcoran, CSA Group Kody Daniel, Property Casualty Insurers Association Gerald Davis, American Gas Association Glen Edgar, VenTech Consulting Mark Fasel, Viega LLC Pennie Feehan, Copper Development Association

    Mike Gorham, National Propane Gas Assoc. Gregg Gress, International Code Council Theodore Lemoff, Consultant Andrea Papageorge, American Gas Association Phillip Ribbs, CA State Pipe Trades Council April Richardson, Railroad Commission of Texas Don Surrena, NAHB Peter Swim, Whirlpool Corporation Thomas Stroud, HPBA Franklin Switzer, S-afe Inc. Eric Smith, International Fire Marshals Association Jason Stanek, American Gas Association

    NFPA Staff - Laura Montville

    Guests Name, Organization

    Gaetano Altomare, IPEX, Inc. Curtis Dady, Viega, LLC Richard Gilbert, Texas Propane Gas Assoc. Larry Gill, IPEX USA LLC Mark Harris, Titeflex Corporation James Molloy, Centrotherm John Roberts, Rimkus Consulting Group

    Dan Snyder, American Water Heater Company James Ranfone, American Gas Association Frank Stanonik, AHRI Robert Torbin, Omega Flex James Wallace, A.O. Smith Corporation Art Weirauch, Omega Flex

    1 Attended all or part of the committee meeting, sign in sheet can be obtained from the Secretary. 2 Voting and alternate members of NFPA 54 and ASC Z223

  • ATTACHMENT B – FUTURE MEETING SCHEDULE

    DATE: June 3, 2016

    SUBJECT: 2017 Meetings: ASC Z223/NFPA 54 Committee

    The ASC Z223 and NFPA 54 committees meet jointly to maintain and develop the National Fuel Gas Code. For your planning purposes the National Fuel Gas Code Committee’s 2017 preliminary meeting schedule is proposed as follows:

    2018 EDITION: PUBLISHED OCTOBER 2017

    2017 MEETING:

    Date: ...................November 14-15, 2017 (Tuesday-Wednesday) Meeting Type: ....Full Committee Purpose:..............Complete Unfinished Business &Planning on 2021 Edition Location .............To Be Determined Host: ...................American Gas Association

    Timely meeting notices will be sent to you as each meeting date approaches. Meeting information will also be available on the AGA and NFPA websites. Please contact Paul Cabot with any questions or comments you may have at 202.824.7312 or [email protected].

  • ATTACHMENT C SUMMARY LIST OF COMMITTEE ACTIONS ON PUBLIC COMMENT

    (PENDING LETTER BALLOT APPROVAL) 7/23/16

    1 PC = Public Comment; SR = Second Draft Revision 2 Action as determine at meeting. Final action is subject to committee letter ballot.

    Comment1 Section Action2 Notes

    Chapter 2:

    SR 32 2.3.2 Accept Staff to review the standards list and update dates as appropriate.

    SR 3 2.4 Accept Staff to review the standards list and update dates as appropriate.

    Chapter 3:

    SR 1, 2, 27 3.3.11.3, 3.3.30.2, 3.3.34

    Accept Update these extracted NFPA definitions to their latest edition text.

    PC 31 3.3.78.3, 3.3.78.4

    Reject

    PC 32 3.3.78.3, 3.3.78.4

    Reject

    PC 42 3.3.84.4 Reject but See SR 19

    SR 19 3.3.84.4 Approved Revise definition as follows: A pressure regulator that is installed in series with another pressure regulator for the purpose of preventing an overpressure in the downstream piping system.

    Chapter 5:

    PC 68 5.4.4 Reject

    PC 34 5.5.1 Reject But See SR 4

    SR 4 5.5.1 Accept 5.5.1 Gas Piping System Operating Pressure Limitations. The maximum design operating pressure for any piping system shall not exceed 125 psi (862 kPa).

    PC 33 5.5.4 Reject But See SR 5

  • ATTACHMENT C SUMMARY LIST OF COMMITTEE ACTIONS ON PUBLIC COMMENT

    (PENDING LETTER BALLOT APPROVAL) 7/23/16

    1 PC = Public Comment; SR = Second Draft Revision 2 Action as determine at meeting. Final action is subject to committee letter ballot.

    Comment1 Section Action2 Notes

    SR 5 5.5.4 Accept 5.5.4 Maximum Design Maximum Operating Pressure in Buildings. The maximum design operating pressure for any piping systems located inside buildings shall not exceed 5 psi (34 kPa) unless one or more of the following conditions are met:

    (11) The piping system is an LP-Gas piping system with a design an operating pressure greater than 20 psi (138 kPa) and complies with NFPA 58.

    PC 41/SR 6 5.5.5 Accept

    PC 57 5.6.2.2 Reject but See SR 30

    SR 30 5.6.2.2 Accept 5.6.2.2 Steel, Stainless Steel, and Wrought Iron. Steel, stainless steel, and wrought-iron pipe shall be at least Schedule 40 and shall comply with one of the following dimensional standards: of (1) ANSI/ASME B36.10M, Welded and Seamless Wrought Steel Pipe and one of the following; (21) ASTM A53, Standard Specification for Pipe, Steel, Black and Hot-Dipped, Zinc-Coated Welded and Seamless (32) ASTM A106, Standard Specification for Seamless Carbon Steel Pipe for High-Temperature Service (43) ASTM A312 Standard Specification for Seamless, Welded, and Heavily Cold Worked Austentic Stainless Steel Pipes

    SR 20 5.6.2.2 [Detail] Accept In Section 5.6.2.2, change "Schedule 40" to "Schedule 10" 5.6.2.2 Steel, Stainless Steel, and Wrought Iron. Steel, stainless steel, and wrought-iron pipe shall be at least Schedule 40 10 and shall comply with the dimensional standards of ANSI/ASME B36.10M, Welded and Seamless Wrought Steel Pipe and one of the following; (1) ASTM A53, Standard Specification for Pipe, Steel, Black and Hot-Dipped, Zinc-Coated Welded and Seamless

  • ATTACHMENT C SUMMARY LIST OF COMMITTEE ACTIONS ON PUBLIC COMMENT

    (PENDING LETTER BALLOT APPROVAL) 7/23/16

    1 PC = Public Comment; SR = Second Draft Revision 2 Action as determine at meeting. Final action is subject to committee letter ballot.

    Comment1 Section Action2 Notes

    (2) ASTM A106, Standard Specification for Seamless Carbon Steel Pipe for High-Temperature Service (3) ASTM A312 Standard Specification for Seamless, Welded, and Heavily Cold Worked Austentic Stainless Steel Pipes

    SR 21 5.6.7.1 Accept 5.6.87.1* Pipe Joints. Pipe Schedule 40 and heavier pipe joints shall be threaded, flanged, brazed, welded, or assembled with press-connect fittings listed to ANSI LC 4, Press-Connect Metallic Fitting for Use in Fuel Gas Distribution Systems. (A) Pipe lighter than Schedule 40 shall be connected using press-connect fittings, flanges, brazing, or welding.

    (B) Where nonferrous pipe is brazed, the brazing materials shall have a melting point in excess of 1,000°F (538°C). (C) Brazing alloys shall not contain more than 0.05 percent phosphorus.

    SR 29 5.6.4.1.2 Accept 5.6.4.1.2 Plastic Polyamide pipe, tubing and fittings, other than polyethylene, shall be identified in and conform to the 2008 edition of ASTM D2513 F2945, Standard Specification for Thermoplastic Polyamide 11 Gas Pressure Pipe Tubing and Fittings. Pipe to be used shall be marked “gas” and “ASTM D2513 F2945”.

    PC 35 5.8.1, 5.8.2 Reject but See SR 7

    SR 7 5.8.1, 5.8.2 Accept 5.8.1. Where Required. A line pressure regulator or gas appliance pressure regulator, as applicable, shall be installed where the gas supply pressure exceeds the maximum allowable inlet pressure of the appliance served.

    5.8.2 Listing Line pressure regulators shall be listed in accordance with ANSI Z21.80/CSA 6.22, Line Pressure Regulators, where the outlet pressure is set to 2 psi or less.

    PC 53 5.9.2.2 Reject

    Chapter 6:

  • ATTACHMENT C SUMMARY LIST OF COMMITTEE ACTIONS ON PUBLIC COMMENT

    (PENDING LETTER BALLOT APPROVAL) 7/23/16

    1 PC = Public Comment; SR = Second Draft Revision 2 Action as determine at meeting. Final action is subject to committee letter ballot.

    Comment1 Section Action2 Notes

    PC 66 Table 6.2.1(p), Table 6.2.1(q) Reject but See SR 8

    SR 8 Table 6.2.1(p), Table 6.2.1(q) Accept Add a new column for EHD 39

    Chapter 7:

    PC 55/SR 9 7.1.6.2 Accept

    PC 43 7.8.2 Reject but See SR 10

    PC 58 7.8.2 Reject but See SR 10

    PC 88 7.8.2 Reject but See SR 10

    SR 10 7.8.2 Accept Delete Section 7.8.2 Point of Delivery Service Valve

    PC 81 7.12.2 New Reject

    PC 87 7.13.3 New Reject

    PC 64 7.12.2 Reject

    PC 94 7.12.2,.1 Reject

    PC 84 7.12.2.3 Reject

    PC 86 7.12.2.3 Reject

    PC 89 7.12.2.3 Reject

    PC 93 7.12.2.3 Reject

    PC 82 7.12.3 Reject

    PC 85 7.12.3 Reject

    PC 90 7.12.3 Reject

  • ATTACHMENT C SUMMARY LIST OF COMMITTEE ACTIONS ON PUBLIC COMMENT

    (PENDING LETTER BALLOT APPROVAL) 7/23/16

    1 PC = Public Comment; SR = Second Draft Revision 2 Action as determine at meeting. Final action is subject to committee letter ballot.

    Comment1 Section Action2 Notes

    Chapter 9:

    PC 69 9.1.8.2 Reject

    PC 49/SR 12 9.1.24 Accept

    PC 65 9.1.24 Reject and Hold The Committee wishes to review the newly suggested standards prior to considering taking an action. Hold for possible 2021 Edition revisions.

    PC 73 9.1.24 Reject

    PC 74 9.1.24 Reject

    PC 56/SR 22 9.6.5.3 Accept

    PC 44 Figure 9.6.8 Reject but See SR 23

    SR 23 Figure 9.6.8 Accept Return text to 2015 Edition text: “3 in. (80 mm) minimum”

    Chapter 10:

    SR 28 10.4.4.3 Accept 10.4.4.3 Exhaust ducts shall be constructed of rigid metallic material. Transition ducts used to connect the dryer to the exhaust duct shall be listed and labeled in accordance with ANSI/UL 2158A, Clothes Dryer Transition Ducts, for that application or and installed in accordance with the clothes dryer manufacturer’s installation instructions.

    PC 46 10.8 Reject but Hold New topic. Committee wishes to review the proposed changes prior to taking an action. Hold for possible 2021 Edition revision.

    PC 47 10.9 Reject but Hold New topic. Committee wishes to review the proposed changes prior to taking an action. Hold for possible 2021 Edition revision.

    PC 70 10.22.1.1 Reject but See SR 24

    PC 71 10.22.1.1 Reject but See SR 24

  • ATTACHMENT C SUMMARY LIST OF COMMITTEE ACTIONS ON PUBLIC COMMENT

    (PENDING LETTER BALLOT APPROVAL) 7/23/16

    1 PC = Public Comment; SR = Second Draft Revision 2 Action as determine at meeting. Final action is subject to committee letter ballot.

    Comment1 Section Action2 Notes

    PC 92 10.22.1.1 Reject but See SR 24

    SR 24 10.22.1.1 Accept Delete section 10.22.1.1

    Chapter 12:

    PC 51 Table 12.5.1 Reject but See SR 14

    SR 14 Table 12.5.1 Accept Revisions to format, editorial, and correct section reference.

    PC 76 Table 12.5.1 Reject PC 72 12.5.2, 12.5.3 Reject but See SR 13

    SR 13 12.5.2, 12.5.3 Accept 12.5.2 Plastic Piping. Where plastic piping is used to vent an appliance, the appliance shall be listed for use with such venting materials and the appliance manufacturer's installation instructions shall identify the specific plastic piping material. The plastic pipe venting materials shall be labelled in accordance with the product standards specified by the appliance manufacturer or shall be listed and labeled in accordance with UL 1738.

    12.5.3 Plastic Vent Joints. Plastic pipe and fittings used to vent appliances shall be installed in accordance with the appliance manufacturer's installation instructions. Plastic pipe venting materials listed and labeled in accordance with UL 1738 shall be installed in accordance with the vent manufacturer’s installation instructions. Where primer is required, it shall be of a contrasting color.

    CI 70 - Failed ballot item

    Table 12.5.1, 12.5.2, 12.5.3, 12.5.4

    No Action Needed – not a public comment

    See SR 13 and SR 14 for action on submitted public comments related to this issue.

    PC 77/SR 15 12.5.4 Accept

    PC 79 12.6.1.3 Reject and See SR 16

  • ATTACHMENT C SUMMARY LIST OF COMMITTEE ACTIONS ON PUBLIC COMMENT

    (PENDING LETTER BALLOT APPROVAL) 7/23/16

    1 PC = Public Comment; SR = Second Draft Revision 2 Action as determine at meeting. Final action is subject to committee letter ballot.

    Comment1 Section Action2 Notes

    SR 16 12.6.1.3 Accept Masonry chimneys shall be built and installed in accordance with NFPA 211 and lined with approved one of the following: 1. Approved clay flue lining, a listed chimney lining system, or other 2. A chimney lining system listed and labeled in accordance with ANSI/UL1777, Chimney Liners, or 3. Other approved material that resists corrosion, erosion, softening, or cracking from vent gases at temperatures up to 1800°F (982°C).

    Annex A:

    SR 33 Table A.5.6 Accepted after the meeting by consent

    Revise Table A.5.6 by updating the table to reflect the all of Section 5.6, piping materials and joining methods.

    PC 75 A.5.6.6.4 Reject

    PC 83 A.7.12.2 Reject

    PC 96 A.7.12.2 Reject but See SR 11

    SR 11 A.7.12.2 Accept Keep existing 2015 Edition text but move some to A.7.12.2.3

    PC 95 A.7.12.2.3 Reject

    Annex C:

    PC 50/SR 25 C.3 Accept

    Annex K:

    PC 52 K.1, K.2 Reject but See SR 31

    SR 31 K.1, K.2 Accept Staff to review the standards list and update dates as appropriate.

    PC 78 K.2.5 Reject

  • From: Tull, SteveTo: Cabot, PaulSubject: Request for formal interpretationDate: Wednesday, June 15, 2016 12:43:51 PMAttachments: image001.pngImportance: High

    Mr. Cabot,Per our conversation on 6/13/2016, I am requesting a formal interpretation of NFPA 54 Section9.6.5.1 (A).

    The code states “Where a connector is used, the valve shall be installed upstream of the connector. A union or flanged connection shall be provided downstream from the valve to permit removal ofappliance controls.”

    My question is whether a “union or flanged connector” is required when an appliance is connectedwith an approved appliance connector? I understand the intent of the code, which is forserviceability of the appliances gas valve. However, the appliance connectors are technically a flarefitting (as stated on the appliance connector) which doesn’t meet the “letter” of the code. The line Ihighlighted above is also located under the section of code discussing the location of the shut offvalves and not installation of piping or connecting appliances. I do not believe the intent of thissection of the code was to require unions or flanged connectors when using appliance connectors. Ibelieve that the wording in the code should be addressed and either eliminated or clarified.

    Thank you for your attention to this matter and I look forward to the Committee’s response.

    Steve TullManager of Compliance and Gas Conversions

    350 S Queen StDover, DE 19904302-734-6797 Ext. 6782302-363-3561 Cell302-735-3077 [email protected]

    ATTACHMENT D - Request for Formal Interpretation

    mailto:[email protected]:[email protected]:[email protected]

  • ATTACHMENT E – Formal Interpretation Request

    June 20, 2016

    Mr. Paul Cabot, Administrator - National Fuel Gas Code Committee C/O American Gas Association 400 North Capitol Street, NW Washington, DC 20001

    Re: Request for Formal Interpretation

    Mr. Cabot, The code states in section 9.6.5 Appliance Shutoff Valves and Connections. Each appliance connected to a piping system shall have an accessible, approved manual shut off valve with a nondisplaceable valve member, or a listed gas convenience outlet. Appliance shutoff valves and convenience outlets shall serve a single appliance only, and shall be installed with 9.6.5.1

    My question is “If an appliance is not installed, why would a need for a shutoff valve be installed?” I understand that the code shutoff valve intent, which is for the serviceability of the gas appliance. If a gas appliance is not installed, and a shutoff valve is be provided, it would marginalize the intent of code section 1.1.1.1 “This code is a safety code”. Since the pre placement of the shutoff valve would allow/ enable third parties, other than 3.3.81 a “Qualified Agency” to install the undetermined gas appliance readily, without any competency; eluding the approval of the 3.2.2 “AHJ” to their actions.

    However, with their potential for not knowing or understanding the true dynamics of the gas appliance to be installed, fosters the ability of a potentially dangerous installation, considering: Approval of Appliance to be Installed; Correct Fuel Gas Type; Appliance Support; Appliance Location; Pressure Regulator Requirements; Combustion Air Requirements; Materials and Their Applicable Listings; Proper Pipe Sizing / Piping Capacity; Joining Methods; Required Clearances; Servicing Accessibility; Appliance Venting and Vent Termination; Gas Delivery Pressure, Appliance Connectors; Leak Checking; Purging etc.

    I do not believe the intent of this section of the code was to require shutoff valves to be installed prior to the approved gas appliance being seated on site, so the aforementioned minimal code conditions can be reviewed and instituted to provide a safe installation and approval by the AHJ.

    Thank you for your attention, and I look forward to the Committee’s input and response.

    Regards,

    Mike Deegan Operations Coordinator Clearwater Gas System

  • 7/13/2016

    1

    A Quick Summary of Methods and Issues

    John S. RobertsRimkus Consulting Group

    6/21/2016NFPA 54 Phoenix, AZ 1

    Natural Gas – Odorant added at point of transfer◦ City Gates◦ Added to flowing gas, usually 0.5 to 1 lb per

    MMSCF Propane – Added at a point when the propane

    is transported by truck or rail◦ Pipeline terminal, refinery, rail terminal or gas plant◦ Added to liquefied gas◦ Gas becomes odorized when odorant and propane

    vaporize

    6/21/2016NFPA 54 Phoenix, AZ 2

    Usually tertiary Butyl Mercaptan and some other component

    Other components are Thiophane, n-Propyl Mercaptan, Isopropyl Mercaptan, sec-Butyl Mercaptan, Dimethyl Sulfide (DMS) or Methyl Ethyl Sulfide (MES)

    DMS and MES are diluents and have a much poorer odor than the mercaptans

    Added using injection or bypass odorizers to flowing gas

    6/21/2016NFPA 54 Phoenix, AZ 3

    tertiary-Butyl Mercaptan (TBM) used as it has a very good odor and is the most stable mercaptan odorant

    Best stability to oxidation and adsorption on soils

    Thiophane has some use, but may be more historic usage. Also does not oxidize

    The worst at soil adsorption and pipe adsorption

    The odor is not comparable to mercaptans

    6/21/2016NFPA 54 Phoenix, AZ 4

    ATTACHMENT F - Odorization Basics Presentation

  • 7/13/2016

    2

    Flow rates – Gas must flow – Static gas will not retain odorant

    Within a house or most commercial applications this is not a problem as the volume of gas is quite low and pressures are low

    With a gas distribution system with miles of pipe at high pressures, this becomes a significant problem

    6/21/2016NFPA 54 Phoenix, AZ 5

    Hydrocarbon liquids – pooling of liquids in distribution lines can remove odorant due to absorption.

    A problem that can be found in gas producing areas and is a function of the price of propane and other liquids found in Natural Gas Liquids (NGLs) (typically)

    TBM is a liquid with a melting point of 31 F so requires a diluent to keep the material in a liquid condition at much lower temperatures

    6/21/2016NFPA 54 Phoenix, AZ 6

    New lines – Gas distribution systems can have long stretches of new gas lines. These can become adsorption sites, and may need to have supplemental odorization. New lines need to be monitored for odorization.

    6/21/2016NFPA 54 Phoenix, AZ 7

    Ethyl Mercaptan is the only odorant for propane currently utilized in the US or Canada

    Added at a rate if 1.5 pound odorant per 10,000 gallons of propane, although standard is 1 pound per 10,000 gallons

    Added to liquefied propane using a pump or some other method

    6/21/2016NFPA 54 Phoenix, AZ 8

  • 7/13/2016

    3

    Propane/Odorant is a problem in vapor-liquid equilibrium

    Propane has a boiling point of -44 F. Ethyl Mercaptan (EM)has a boiling point of 95

    F This means that EM and propane are not

    found in the vapor at the same concentration as in the liquid

    The ratio of the concentration of EM in the vapor to EM in the liquid is the K-factor

    6/21/2016NFPA 54 Phoenix, AZ 9

    This changes with respect to temperature◦ K = 0.11 at -10 F◦ K = 0.22 at 95 F

    This means that at 95 F, the amount of EM in the vapor is 22% of the amount of EM in the liquid

    The odorant level is set up with this in mind Other odorants, such as thiophane, require much

    higher concentrations, which is why 6.4 pounds per 10,000 gallons is utilized◦ K = 0.007 at -10 F◦ K = 0.033 at 95 F

    6/21/2016NFPA 54 Phoenix, AZ 10

    Oxidation◦ Mercaptan odorants can be oxidized Natural gas by rust (Fe2O3) in pipelines Propane by rust in tankage◦ Thiophane is not oxidizable by rust

    Adsorption◦ All odorants can be adsorbed by surfaces◦ This can be piping, clothing, concrete, etc.◦ The higher the molecular weight the worse the

    problem, typically

    6/21/2016NFPA 54 Phoenix, AZ 11

    Adsorption – Soil◦ This is a slightly different problem◦ Odorants are adsorbed by soil in the following

    order: Clay >> Silt > Sand > Gravel This order is in terms of particle size of particles and

    also the surface area of each entity Clays have very high surface areas◦ Interestingly, the ease of movement of gas through

    these entities is: Gravel > Sand > Silt >> Clay

    6/21/2016NFPA 54 Phoenix, AZ 12

  • 7/13/2016

    4

    Adaptation – Getting used to the odor◦ One must respond immediately to a gas odor

    Recognition◦ Misidentification – Is that the odor of a dead rat or

    is it a gas leak?◦ Scratch and Sniffs have improved this issue for

    natural gas and propane◦ The increased presence of propane in the

    environment (propane grills) has increased propane odor recognition

    6/21/2016NFPA 54 Phoenix, AZ 13

    Anosmia – No sense of smell – not a well defined population but probably about 0.2% of population

    Aging – In general, as one grows older your nasal acuity decreases.

    One must be in the presence of gas in order to smell the odorant.

    Sleep – Thought to be a problem, but there are no real studies done on this issue. Last attempt was made in the 1930’s. Could be a subset of Adaptation

    6/21/2016NFPA 54 Phoenix, AZ 14

    6/21/2016NFPA 54 Phoenix, AZ 15

    Attachment A Meeting Attendance.pdfEmbassy Suites Biltmore Phoenix

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