application of nmr for evaluation of tight oil …dwls.spwla.org/2015-09-15 dwls...
TRANSCRIPT
![Page 1: Application of NMR for Evaluation of Tight Oil …dwls.spwla.org/2015-09-15 DWLS Presentation.pdfApplication of NMR for Evaluation of Tight Oil ... potential oil and gas • S3: CO](https://reader031.vdocuments.us/reader031/viewer/2022030812/5b1de8f87f8b9a397f8b7ca4/html5/thumbnails/1.jpg)
Rick Lewis & Erik Rylander
Iain Pirie
Stacy Reeder, Paul Craddock, Ravi Kausik, Bob
Kleinberg & Drew Pomerantz
Application of NMR for
Evaluation of Tight Oil
Reservoirs
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Lots of oil in place – what is pay?
•
•
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Organic Shale Pore System
Diameter (nm)
0.38 Methane Molecule
0.38 to 10 Oil Molecule
4 to 70 Pore Throat
15 to 200 Virus
5 to 750 Organic Pore
10 to 2000 Inter/Intra Particle Pores
200 to 2000 Bacteria
35000-65000 Shale Size Particle (mean)
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Evolution of organic fractions of shale with increasing thermal maturity.
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NMR T2 Time Distribution (Conventional vs. Organic Shale)
surfacebulk TTT 2
1
2
1
2
1
bulkTT 2
1
2
1
•
•
surfaceTT 2
1~
2
11.001.
2
1
T
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Comparison of Core NMR to Log NMR: investigate expelled fluids
0.01 0.1 1 10 100 10000
0.1
0.2
0.3
0.4
0.5
T2 (ms)
Po
ros
ity
(p
.u.)
CMR Porosity: 9.9 p.u.
Core NMR Porosity: 9.1 p.u.
Core Depth 9198 ft
T2 - Core
T2 - CMR
0.01 0.1 1 10 100 10000
0.1
0.2
0.3
0.4
0.5
T2 (ms)
Po
ros
ity
(p
.u.)
T2 - Core
T2 - CMR
Water
0.01 0.1 1 10 100 10000
0.1
0.2
0.3
0.4
0.5
T2 (ms)
Po
ros
ity
(p
.u.)
Oil - Core
Oil - CMR
0.01 0.1 1 10 100 10000
0.1
0.2
0.3
0.4
0.5
T2 (ms)
Po
ros
ity
(p
.u.)
Shifted Oil - Core
Oil - CMR
•
•
m
0.01 0.1 1 10 100 10000
0.1
0.2
0.3
0.4
0.5
T2 (ms)
Po
ros
ity
(p
.u.)
CMR Porosity: 9.9 p.u.
Core NMR Porosity: 9.1 p.u.
Core Depth 9198 ft
T2 - Core
T2 - CMR
0.01 0.1 1 10 100 10000
0.1
0.2
0.3
0.4
0.5
T2 (ms)
Po
ros
ity
(p
.u.)
T2 - Core
T2 - CMR
Water
0.01 0.1 1 10 100 10000
0.1
0.2
0.3
0.4
0.5
T2 (ms)
Po
ros
ity
(p
.u.)
Oil - Core
Oil - CMR
0.01 0.1 1 10 100 10000
0.1
0.2
0.3
0.4
0.5
T2 (ms)
Po
ros
ity
(p
.u.)
Shifted Oil - Core
Oil - CMR
•
0.01 0.1 1 10 100 10000
0.1
0.2
0.3
0.4
0.5
T2 (ms)
Po
ros
ity
(p
.u.)
CMR Porosity: 9.9 p.u.
Core NMR Porosity: 9.1 p.u.
Core Depth 9198 ft
T2 - Core
T2 - CMR
0.01 0.1 1 10 100 10000
0.1
0.2
0.3
0.4
0.5
T2 (ms)
Po
ros
ity
(p
.u.)
T2 - Core
T2 - CMR
Water
0.01 0.1 1 10 100 10000
0.1
0.2
0.3
0.4
0.5
T2 (ms)
Po
ros
ity
(p
.u.)
Oil - Core
Oil - CMR
0.01 0.1 1 10 100 10000
0.1
0.2
0.3
0.4
0.5
T2 (ms)
Po
ros
ity
(p
.u.)
Shifted Oil - Core
Oil - CMR
•
•
0.01 0.1 1 10 100 10000
0.1
0.2
0.3
0.4
0.5
T2 (ms)
Po
ros
ity
(p
.u.)
CMR Porosity: 9.9 p.u.
Core NMR Porosity: 9.1 p.u.
Core Depth 9198 ft
T2 - Core
T2 - CMR
0.01 0.1 1 10 100 10000
0.1
0.2
0.3
0.4
0.5
T2 (ms)
Po
ros
ity
(p
.u.)
T2 - Core
T2 - CMR
Water
0.01 0.1 1 10 100 10000
0.1
0.2
0.3
0.4
0.5
T2 (ms)
Po
ros
ity
(p
.u.)
Oil - Core
Oil - CMR
0.01 0.1 1 10 100 10000
0.1
0.2
0.3
0.4
0.5
T2 (ms)
Po
ros
ity
(p
.u.)
Shifted Oil - Core
Oil - CMR
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T2 Cutoff ~ 9.4 ms
10-2
10-1
100
101
102
103
xx99 ft10.1 pu
xx10 ft10 pu
xx23 ft13 pu
xx33 ft8.8 pu
xx40 ft5.8 pu
xx58 ft10.5 pu
xx65 ft7.5 pu
xx81 ft8.1 pu
xx93 ft9.9 pu
xx02 ft7.1 pu
T2 (ms)
T2 d
istr
ibution (
pu)
T2-cutoff = 9.4 ms
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Bulk Relaxivity
•
•
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Shale Constituents by Volume Tight Oil Reservoir
Kero
gen
Mineral matrix
Pore
Wate
r
Bitum
en
Total Phi
Cla
y b
ound w
ate
r
Lig
ht
oil
Eff Phi
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Pore Distribution
Cap-Bound Water
Cap-Bound Oil
(OM Pores)
Cap-Bound Water
Free Oil
(Larger OM Pore
> 250 nm)
Producible Fluids
Oil and Water
(Water wet pores)
Clay-Bound Water
Bitumen
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Eagle Ford Oil Producer
0
5000
10000
15000
20000
Mar-00 Jun-00 Oct-00 Jan-01 Apr-01
BO
PM
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Eagle Ford Oil Producer
0
5000
10000
15000
20000
Mar-00 May-00 Jun-00 Aug-00 Oct-00
BO
PM
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Tmax Data
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T2 relaxation of native and re-saturated shale
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T2 relaxation of native and re-saturated shale
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T2 relaxation of native and re-saturated shale
Native state porosity
Resaturated oil porosity
12.11 3.91
12.70 4.79
12.14 4.19
8.09 3.43
4.25 2.15
11.66 3.77
10.74 3.66
10.19 3.06
8.20 2.94
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Rock Eval Pyrolysis
Measurements of • S1: oil in the sample
• S2: potential oil and gas
• S3: CO2
• S4: residual hydrocarbon
• Tmax: maturity indicator
• TOC
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The Importance of Oil Saturation Index (OSI)
Jarvie, 2012: As much as 70-80 mg Oil / g TOC is sorbed to Kerogen
An OSI > 100 mg Oil / g TOC may produce oil
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Oil Saturation Index (OSI)
Matrix Bound
Water Oil
Free
Water Bitumen Kerogen
S1
TOC
Oil Bitumen Kerogen
Oil
= OSI = S1
TOC
Jarvie, 2012: As much as 70-80 mg Oil / g TOC is sorbed to Kerogen
An OSI > 100 mg Oil / g TOC may produce oil
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Shale-Oil Systems
Hybrid Shale
Juxtaposed organic-rich and
organic-lean intevals
Bakken is end member
OSI provides method to ID
contribution of organic-lean
intervals in finely juxtaposed
system
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TOC standard workflows
Estimating TOC from logs:
- Schmoker (density)
- Δ log R (Sonic-Resistivity)
- Uranium
- NMR-PHIA deficit
Based on indirect measurements
Require calibration to core data
Specific to a particular formation
All are kerogen-only TOC
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Direct measurement from Inelastic
Spectra
TIC = 0.120*Calcite+
0.130*Dolomite+
0.104*Siderite+
0.116*Ankerite
Ele
men
ts fr
om
Spe
ctro
scop
y
Si, Ca, Mg, S, Fe, K,
Na, Mn,P, etc.
Carbon
Minerals
TOC from Carbon workflow
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Carbon Saturation Index
)(g/cmdensity Bulk
)(g/cmdensity Oil
(v/v) dielectricor model calpetrophysi from water,eBulk volum
(v/v)bitumen Volume
(v/v)porosity NMR Total
(w/w) log lgeochemica fromdirectly content,carbon organic Total
(w/w)n hydrocarbolight in carbon offraction Weight Oil
1) to0 (unitless,Index SaturationCarbon
3
3
14
12
bulk
oil
W
W
CSI
BVW
bitumen
NMR
organicsc
oilc
bulk
oilBVWbitumenNMRoilcW
organicscW
oilcW
CSI
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Reservoir Producibility Index—Account for Porosity
Differences
Log generated index
Circumvents problems associated with recovery and analysis of hydrocarbons
from cuttings and/or core
OSI of 100 ~ RPI of 0.1 (fc of porosity)
(w/w)Scanner Litho fromdirectly content, (TOCj)carbon organic Total
(w/w)bitumen for correction requiremay n,hydrocarbolight in carbon offraction Weight Oil
1) to0 (unitless,Index SaturationCarbon
organicsc
oilc
oilc
W
W
CSI
organicscW
oilcW
CSI
where
WCSIRPI
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0
5000
10000
15000
20000
Mar-00 Jun-00 Oct-00 Jan-01 Apr-01
BO
PM
RPI – Good Well
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0
5000
10000
15000
20000
Mar-00 May-00 Jun-00 Aug-00 Oct-00
BO
PM
RPI - Poor Well
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•
•
-100
0
100
200
300
400
500
1 28 55 82 109
136
163
190
217
244
271
298
325
352
379
406
BB
L o
r M
CF
RPI, Woodford
(VRo ~ 0.7)
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•
•
RPI, Bakken (VRo ~ 1.0)
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T2 Distribution of Native Shale Sample Plotted Together with
Formation Oil and Brine Re-saturated Shale
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Pore Fluids from T1/T2
• Differentiate between
hydrocarbon and water-
filled pores
• Two pore system model
• Organic with
hydrocarbon
• Inorganic with water
• T1/T2 ratio higher for oil-
saturated pores
• Core work performed by
OU on Barnett Shale
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T1/T2 maps of Eagle Ford Shale at various depths
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Universal T1-T2 picture for shale at 2MHz
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WT(1) WT(2) WT(3) WT(4)
CPMG(1) CPMG(2) CPMG(3) CPMG(4)
t
WT(1)
WT(2)
WT(3)
WT(4)
Mz = M0 [1 - exp(-t/T1) ]
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Potential for T1-T2 in Tight Oil
• Differentiate and potentially quantify bitumen
• Differentiate and quantify OM and IP pores
• Limit from 2 to ~30ms
Initial Observations
• Can not differentiate between hydrocarbon and water
in IP pores
• All bitumen may not be quantified due to short
relaxation time
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Conclusions
• Non-producible hydrocarbons are common constituent in liquid
producing shales
• One type of non-producible hydrocarbon is viscous source rock
bitumen
• Another type of non-producible hydrocarbon are oils sorbed to
organic pore walls
• RPI methodology can be used to characterize producible
zones, and it takes porosity and pore water into account
It recognizes hybrid reservoirs
• T1/T2 shows potential to differentiate bitumen and OM vs. IP
pore fluids
Application of these metrics to landing point selection has had
dramatic positive impact to productivity in shale wells!