appendix i - laboratory reports...filters, swabs, wipes, tubes and badges will not have duplicate...

Appendix I - Laboratory Reports

Envirolab Services Pty Ltd

ABN 37 112 535 645

12 Ashley St Chatswood NSW 2067

ph 02 9910 6200 fax 02 9910 6201

[email protected]

www.envirolab.com.au

CERTIFICATE OF ANALYSIS 188737

Level 19, Tower B, Citadel Tower, 799 Pacific Hwy, Chatswood, NSW, 2067Address

Ian Newby, Sarah RichardsAttention

Coffey EnvironmentClient

Client Details

05/04/2018Date completed instructions received

05/04/2018Date samples received

1 SERUMNumber of Samples

754-MELEN199420Your Reference

Sample Details

Please refer to the last page of this report for any comments relating to the results.

Results are reported on a dry weight basis for solids and on an as received basis for other matrices.

Samples were analysed as received from the client. Results relate specifically to the samples as received.

Please refer to the following pages for results, methodology summary and quality control data.

Analysis Details

Tests not covered by NATA are denoted with *Accredited for compliance with ISO/IEC 17025 - Testing.

NATA Accreditation Number 2901. This document shall not be reproduced except in full.

10/04/2018Date of Issue

19/04/2018Date results requested by

Report Details

Jacinta Hurst, Laboratory Manager

Authorised By

Phalak Inthakesone, Organics Development Manager, Sydney

Results Approved By

Revision No: R00

188737Envirolab Reference: Page | 1 of 7

Client Reference: 754-MELEN199420

104%Surrogate 13 C2 PFOA

100%Surrogate 13 C8 PFOS

<2ng/mLEtPerfluorooctanesulf- amid oacetic acid

<2ng/mLMePerfluorooctanesulf- amid oacetic acid

<50ng/mLN-Et perfluorooctanesulfonamid oethanol

<10ng/mLN-Me perfluorooctanesulfonamid oethanol

<10ng/mLN-Ethyl perfluorooctanesulfon amide

<10ng/mLN-Methyl perfluorooctane sulfonamide

<10ng/mLPerfluorooctane sulfonamide

<1ng/mL10:2 FTS

<1ng/mL8:2 FTS

<1ng/mL6:2 FTS

<1ng/mL4:2 FTS

<50ng/mLPerfluorotetradecanoic acid

<5ng/mLPerfluorotridecanoic acid

<5ng/mLPerfluorododecanoic acid

<5ng/mLPerfluoroundecanoic acid

<2ng/mLPerfluorodecanoic acid

<1ng/mLPerfluorononanoic acid

<1ng/mLPerfluorooctanoic acid PFOA

<1ng/mLPerfluoroheptanoic acid

<1ng/mLPerfluorohexanoic acid

<2ng/mLPerfluoropentanoic acid

<2ng/mLPerfluorobutanoic acid

<2ng/mLPerfluorodecanesulfonic acid

33ng/mLPerfluorooctanesulfonic acid PFOS

1ng/mLPerfluoroheptanesulfonic acid

3ng/mLPerfluorohexanesulfonic acid - PFHxS

<1ng/mLPerfluoropentanesulfonic acid

<1ng/mLPerfluorobutanesulfonic acid

09/04/2018-Date analysed

09/04/2018-Date prepared

SERUMType of sample

15/02/2018Date Sampled

0990_4527001UNITSYour Reference

188737-1Our Reference

PFAS in Serum Extended Suite

Envirolab Reference: 188737

R00Revision No:

Page | 2 of 7


Blood and Serum are carried through an acid crash followed by Solid Phase Extraction prior to analysis with LC-MS/MS. Serum results are generally reported, note there is some research suggesting that certain PFAS do not seperate into the Serum, please contact the lab for more information. PFAS results include the sum of branched and linear isomers where applicable.

Org-035

Methodology SummaryMethod ID


R00Revision No:

Page | 3 of 7


[NT]102[NT][NT][NT][NT]100Org-035%Surrogate 13 C2 PFOA

[NT]98[NT][NT][NT][NT]97Org-035%Surrogate 13 C8 PFOS

[NT]101[NT][NT][NT][NT]<2Org-0352ng/mLEtPerfluorooctanesulf- amid oacetic acid

[NT]109[NT][NT][NT][NT]<2Org-0352ng/mLMePerfluorooctanesulf- amid oacetic acid

[NT]85[NT][NT][NT][NT]<50Org-03550ng/mLN-Et perfluorooctanesulfonamid oethanol

[NT]88[NT][NT][NT][NT]<10Org-03510ng/mLN-Me perfluorooctanesulfonamid oethanol

[NT]97[NT][NT][NT][NT]<10Org-03510ng/mLN-Ethyl perfluorooctanesulfon amide

[NT]97[NT][NT][NT][NT]<10Org-03510ng/mLN-Methyl perfluorooctane sulfonamide

[NT]65[NT][NT][NT][NT]<10Org-03510ng/mLPerfluorooctane sulfonamide

[NT]85[NT][NT][NT][NT]<1Org-0351ng/mL10:2 FTS




[NT]91[NT][NT][NT][NT]<50Org-03550ng/mLPerfluorotetradecanoic acid

[NT]128[NT][NT][NT][NT]<5Org-0355ng/mLPerfluorotridecanoic acid

[NT]115[NT][NT][NT][NT]<5Org-0355ng/mLPerfluorododecanoic acid

[NT]101[NT][NT][NT][NT]<5Org-0355ng/mLPerfluoroundecanoic acid

[NT]98[NT][NT][NT][NT]<2Org-0352ng/mLPerfluorodecanoic acid

[NT]106[NT][NT][NT][NT]<1Org-0351ng/mLPerfluorononanoic acid

[NT]104[NT][NT][NT][NT]<1Org-0351ng/mLPerfluorooctanoic acid PFOA

[NT]105[NT][NT][NT][NT]<1Org-0351ng/mLPerfluoroheptanoic acid

[NT]108[NT][NT][NT][NT]<1Org-0351ng/mLPerfluorohexanoic acid

[NT]105[NT][NT][NT][NT]<2Org-0352ng/mLPerfluoropentanoic acid

[NT]107[NT][NT][NT][NT]<2Org-0352ng/mLPerfluorobutanoic acid

[NT]87[NT][NT][NT][NT]<2Org-0352ng/mLPerfluorodecanesulfonic acid

[NT]95[NT][NT][NT][NT]<1Org-0351ng/mLPerfluorooctanesulfonic acid PFOS

[NT]115[NT][NT][NT][NT]<1Org-0351ng/mLPerfluoroheptanesulfonic acid

[NT]101[NT][NT][NT][NT]<1Org-0351ng/mLPerfluorohexanesulfonic acid - PFHxS

[NT]92[NT][NT][NT][NT]<1Org-0351ng/mLPerfluoropentanesulfonic acid

[NT]111[NT][NT][NT][NT]<1Org-0351ng/mLPerfluorobutanesulfonic acid

[NT]09/04/2018[NT][NT][NT][NT]09/04/2018-Date analysed

[NT]09/04/2018[NT][NT][NT][NT]09/04/2018-Date prepared

[NT]LCS-1RPDDup.Base#BlankMethodPQLUnitsTest Description

Spike Recovery %DuplicateQUALITY CONTROL: PFAS in Serum Extended Suite


R00Revision No:

Page | 4 of 7


Not ReportedNR

National Environmental Protection MeasureNEPM

Not specifiedNS

Laboratory Control SampleLCS

Relative Percent DifferenceRPD

Greater than>

Less than<

Practical Quantitation LimitPQL

Insufficient sample for this testINS

Test not requiredNA

Not testedNT

Result Definitions

Australian Drinking Water Guidelines recommend that Thermotolerant Coliform, Faecal Enterococci, & E.Coli levels are less than1cfu/100mL. The recommended maximums are taken from "Australian Drinking Water Guidelines", published by NHMRC & ARMC2011.

Surrogates are known additions to each sample, blank, matrix spike and LCS in a batch, of compounds whichare similar to the analyte of interest, however are not expected to be found in real samples.

Surrogate Spike

This comprises either a standard reference material or a control matrix (such as a blank sand or water) fortifiedwith analytes representative of the analyte class. It is simply a check sample.

LCS (LaboratoryControl Sample)

A portion of the sample is spiked with a known concentration of target analyte. The purpose of the matrix spikeis to monitor the performance of the analytical method used and to determine whether matrix interferencesexist.

Matrix Spike

This is the complete duplicate analysis of a sample from the process batch. If possible, the sample selectedshould be one where the analyte concentration is easily measurable.

Duplicate

This is the component of the analytical signal which is not derived from the sample but from reagents,glassware etc, can be determined by processing solvents and reagents in exactly the same manner as forsamples.

Blank

Quality Control Definitions


R00Revision No:

Page | 5 of 7


Measurement Uncertainty estimates are available for most tests upon request.

Where sampling dates are not provided, Envirolab are not in a position to comment on the validity of the analysis whererecommended technical holding times may have been breached.

When samples are received where certain analytes are outside of recommended technical holding times (THTs), the analysis hasproceeded. Where analytes are on the verge of breaching THTs, every effort will be made to analyse within the THT or as soon aspracticable.

In circumstances where no duplicate and/or sample spike has been reported at 1 in 10 and/or 1 in 20 samples respectively, thesample volume submitted was insufficient in order to satisfy laboratory QA/QC protocols.

Matrix Spikes, LCS and Surrogate recoveries: Generally 70-130% for inorganics/metals; 60-140% for organics (+/-50% surrogates)and 10-140% for labile SVOCs (including labile surrogates), ultra trace organics and speciated phenols is acceptable.

Duplicates: <5xPQL - any RPD is acceptable; >5xPQL - 0-50% RPD is acceptable.

For VOCs in water samples, three vials are required for duplicate or spike analysis.

Spikes for Physical and Aggregate Tests are not applicable.

Filters, swabs, wipes, tubes and badges will not have duplicate data as the whole sample is generally extracted during sampleextraction.

Duplicate sample and matrix spike recoveries may not be reported on smaller jobs, however, were analysed at a frequency to meetor exceed NEPM requirements. All samples are tested in batches of 20. The duplicate sample RPD and matrix spike recoveries forthe batch were within the laboratory acceptance criteria.

Laboratory Acceptance Criteria


R00Revision No:

Page | 6 of 7


sample received in unfamiliar tube, so treated as is!

Report Comments


R00Revision No:

Page | 7 of 7

Certificate of Analysis

Coffey Environments Pty Ltd VIC

Level 1, 436 Johnston Street

Abbotsford

VIC 3067

Attention: Ian Newby

Report 578676-W

Project name DOD TINDAL

Project ID 754_MELEN199420-TINDAL

Received Date Dec 20, 2017

Client Sample ID 0990_SW177_171212

0990_SW178_171212

0990_SW179_171213

0990_QC3IV_171213

Sample Matrix Water Water Water Water

Eurofins | mgt Sample No. B17-De29463 B17-De29464 B17-De29465 B17-De29466

Date Sampled Dec 12, 2017 Dec 12, 2017 Dec 13, 2017 Dec 13, 2017

Test/Reference LOR Unit

Perfluoroalkyl carboxylic acids (PFCAs)

Perfluorobutanoic acid (PFBA)N11 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05

Perfluoropentanoic acid (PFPeA)N11 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01

Perfluorohexanoic acid (PFHxA)N11 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01

Perfluoroheptanoic acid (PFHpA)N11 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01

Perfluorooctanoic acid (PFOA)N11 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01

Perfluorononanoic acid (PFNA)N11 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01

Perfluorodecanoic acid (PFDA)N11 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01

Perfluoroundecanoic acid (PFUnA)N11 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01

Perfluorododecanoic acid (PFDoA)N11 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01

Perfluorotridecanoic acid (PFTrDA) 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01

Perfluorotetradecanoic acid (PFTeDA)N11 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01

13C4-PFBA (surr.) 1 % 94 102 114 118

13C5-PFPeA (surr.) 1 % 90 96 99 97

13C5-PFHxA (surr.) 1 % 65 72 74 72

13C4-PFHpA (surr.) 1 % 66 71 74 74

13C8-PFOA (surr.) 1 % 98 111 110 111

13C5-PFNA (surr.) 1 % 112 136 140 155

13C6-PFDA (surr.) 1 % 68 80 78 106

13C2-PFUnDA (surr.) 1 % 52 58 60 86

13C2-PFDoDA (surr.) 1 % 46 53 57 75

13C2-PFTeDA (surr.) 1 % 30 41 34 46

Perfluoroalkane sulfonamides (PFASAs)

Perfluorooctane sulfonamide (FOSA)N11 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05

N-methylperfluoro-1-octane sulfonamide (N-MeFOSA)N11 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05

N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA)N11 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05

2-(N-methylperfluoro-1-octane sulfonamido)-ethanol(N-MeFOSE)N11 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05

2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE)N11 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05

N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA)N11 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05

N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA)N11 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05

13C8-FOSA (surr.) 1 % 63 77 91 75

D3-N-MeFOSA (surr.) 1 % 54 70 84 87

Date Reported: Jan 05, 2018

Eurofins | mgt 1/21 Smallwood Place, Murarrie, QLD, Australia, 4172

ABN : 50 005 085 521 Telephone: +61 7 3902 4600

Page 1 of 14

Report Number: 578676-W

NATA AccreditedAccreditation Number 1261Site Number 20794

Accredited for compliance with ISO/IEC 17025 – TestingThe results of the tests, calibrations and/ormeasurements included in this document are traceableto Australian/national standards.

Client Sample ID 0990_SW177_171212

0990_SW178_171212

0990_SW179_171213

0990_QC3IV_171213

Sample Matrix Water Water Water Water





D5-N-EtFOSA (surr.) 1 % 40 59 60 71

D7-N-MeFOSE (surr.) 1 % 42 49 66 65

D9-N-EtFOSE (surr.) 1 % 41 52 63 63

D5-N-EtFOSAA (surr.) 1 % 55 61 64 87

D3-N-MeFOSAA (surr.) 1 % 70 75 73 105

Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)

Perfluorobutanesulfonic acid (PFBS)N11 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01

Perfluoropentanesulfonic acid (PFPeS) 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01

Perfluorohexanesulfonic acid (PFHxS)N11 0.01 ug/L < 0.01 < 0.01 N090.03 < 0.01

Perfluoroheptanesulfonic acid (PFHpS) 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01

Perfluorooctanesulfonic acid (PFOS)N11 0.01 ug/L < 0.01 < 0.01 N090.04 < 0.01

Perfluorodecanesulfonic acid (PFDS) 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01

13C3-PFBS (surr.) 1 % 60 66 69 69

18O2-PFHxS (surr.) 1 % 108 115 117 119

13C8-PFOS (surr.) 1 % 83 101 97 120

n:2 Fluorotelomer sulfonic acids

1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS)N11 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01

1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS)N11 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05

1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS)N11 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01

1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2FTS) 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01

13C2-4:2 FTS (surr.) 1 % 39 46 48 42

13C2-6:2 FTS (surr.) 1 % 70 81 80 73

13C2-8:2 FTS (surr.) 1 % 53 67 61 77

PFASs Summations

Sum (PFHxS + PFOS)* 0.01 ug/L < 0.01 < 0.01 0.07 < 0.01

Sum of US EPA PFAS (PFOS + PFOA)* 0.01 ug/L < 0.01 < 0.01 0.04 < 0.01

Sum of enHealth PFAS (PFHxS + PFOS + PFOA)* 0.01 ug/L < 0.01 < 0.01 0.07 < 0.01

Sum of WA DER PFAS (n=10)* 0.05 ug/L < 0.05 < 0.05 0.07 < 0.05

Sum of PFASs (n=28)* 0.1 ug/L < 0.1 < 0.1 < 0.1 < 0.1

Client Sample ID 0990_QC4FH_171215

Sample Matrix Water

Eurofins | mgt Sample No. B17-De29467

Date Sampled Dec 15, 2017



Perfluorobutanoic acid (PFBA)N11 0.05 ug/L < 0.05

Perfluoropentanoic acid (PFPeA)N11 0.01 ug/L < 0.01

Perfluorohexanoic acid (PFHxA)N11 0.01 ug/L < 0.01

Perfluoroheptanoic acid (PFHpA)N11 0.01 ug/L < 0.01

Perfluorooctanoic acid (PFOA)N11 0.01 ug/L < 0.01

Perfluorononanoic acid (PFNA)N11 0.01 ug/L < 0.01

Perfluorodecanoic acid (PFDA)N11 0.01 ug/L < 0.01

Perfluoroundecanoic acid (PFUnA)N11 0.01 ug/L < 0.01

Perfluorododecanoic acid (PFDoA)N11 0.01 ug/L < 0.01



ABN : 50 005 085 521 Telephone: +61 7 3902 4600

Page 2 of 14



Sample Matrix Water





Perfluorotridecanoic acid (PFTrDA) 0.01 ug/L < 0.01

Perfluorotetradecanoic acid (PFTeDA)N11 0.01 ug/L < 0.01

13C4-PFBA (surr.) 1 % 114

13C5-PFPeA (surr.) 1 % 96

13C5-PFHxA (surr.) 1 % 75

13C4-PFHpA (surr.) 1 % 73

13C8-PFOA (surr.) 1 % 112

13C5-PFNA (surr.) 1 % 139

13C6-PFDA (surr.) 1 % 86

13C2-PFUnDA (surr.) 1 % 65

13C2-PFDoDA (surr.) 1 % 62

13C2-PFTeDA (surr.) 1 % 45


Perfluorooctane sulfonamide (FOSA)N11 0.05 ug/L < 0.05

N-methylperfluoro-1-octane sulfonamide (N-MeFOSA)N11 0.05 ug/L < 0.05

N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA)N11 0.05 ug/L < 0.05

2-(N-methylperfluoro-1-octane sulfonamido)-ethanol(N-MeFOSE)N11 0.05 ug/L < 0.05

2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE)N11 0.05 ug/L < 0.05

N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA)N11 0.05 ug/L < 0.05

N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA)N11 0.05 ug/L < 0.05

13C8-FOSA (surr.) 1 % 82

D3-N-MeFOSA (surr.) 1 % 95

D5-N-EtFOSA (surr.) 1 % 73

D7-N-MeFOSE (surr.) 1 % 61

D9-N-EtFOSE (surr.) 1 % 63

D5-N-EtFOSAA (surr.) 1 % 74

D3-N-MeFOSAA (surr.) 1 % 85


Perfluorobutanesulfonic acid (PFBS)N11 0.01 ug/L < 0.01

Perfluoropentanesulfonic acid (PFPeS) 0.01 ug/L < 0.01

Perfluorohexanesulfonic acid (PFHxS)N11 0.01 ug/L < 0.01

Perfluoroheptanesulfonic acid (PFHpS) 0.01 ug/L < 0.01

Perfluorooctanesulfonic acid (PFOS)N11 0.01 ug/L < 0.01

Perfluorodecanesulfonic acid (PFDS) 0.01 ug/L < 0.01

13C3-PFBS (surr.) 1 % 67

18O2-PFHxS (surr.) 1 % 117

13C8-PFOS (surr.) 1 % 100


1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS)N11 0.01 ug/L < 0.01

1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS)N11 0.05 ug/L < 0.05

1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS)N11 0.01 ug/L < 0.01

1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2FTS) 0.01 ug/L < 0.01

13C2-4:2 FTS (surr.) 1 % 41



ABN : 50 005 085 521 Telephone: +61 7 3902 4600

Page 3 of 14



Sample Matrix Water





13C2-6:2 FTS (surr.) 1 % 65

13C2-8:2 FTS (surr.) 1 % 62

PFASs Summations

Sum (PFHxS + PFOS)* 0.01 ug/L < 0.01

Sum of US EPA PFAS (PFOS + PFOA)* 0.01 ug/L < 0.01

Sum of enHealth PFAS (PFHxS + PFOS + PFOA)* 0.01 ug/L < 0.01

Sum of WA DER PFAS (n=10)* 0.05 ug/L < 0.05

Sum of PFASs (n=28)* 0.1 ug/L < 0.1



ABN : 50 005 085 521 Telephone: +61 7 3902 4600

Page 4 of 14


Sample HistoryWhere samples are submitted/analysed over several days, the last date of extraction and analysis is reported.A recent review of our LIMS has resulted in the correction or clarification of some method identifications. Due to this, some of the method reference information on reports has changed. However,no substantive change has been made to our laboratory methods, and as such there is no change in the validity of current or previous results (regarding both quality and NATA accreditation).

If the date and time of sampling are not provided, the Laboratory will not be responsible for compromised results should testing be performed outside the recommended holding time.

Description Testing Site Extracted Holding Time

Per- and Polyfluorinated Alkyl Substances (PFASs)

Perfluoroalkyl carboxylic acids (PFCAs) Brisbane Dec 21, 2017 14 Day

- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS

Perfluoroalkane sulfonamides (PFASAs) Brisbane Dec 21, 2017 14 Day

- Method: LTM-ORG-2100 Determination of Per– and Polyfluoro Alkyl Substances (PFAS) in Aqueous and Soil Samples by LC-MS/MS

Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Brisbane Dec 21, 2017 14 Day


n:2 Fluorotelomer sulfonic acids Brisbane Dec 21, 2017 14 Day




ABN : 50 005 085 521 Telephone: +61 7 3902 4600

Page 5 of 14


.Company Name: Coffey Environments Pty Ltd VIC Order No.: Received: Dec 20, 2017 2:48 PMAddress: Level 1, 436 Johnston Street Report #: 578676 Due: Dec 29, 2017

Abbotsford Phone: 03 8413 6900 Priority: 5 DayVIC 3067 Fax: Contact Name: Ian Newby

Project Name: DOD TINDALProject ID: 754_MELEN199420-TINDAL

Eurofins | mgt Analytical Services Manager : Mary Makarios

Sample Detail

Per- and P

olyfluorinated Alkyl S

ubstances(P

FA

Ss)

Melbourne Laboratory - NATA Site # 1254 & 14271

Sydney Laboratory - NATA Site # 18217

Brisbane Laboratory - NATA Site # 20794 X

Perth Laboratory - NATA Site # 23736

External Laboratory

No Sample ID Sample Date SamplingTime

Matrix LAB ID

1 1302_SW177_171212

Dec 12, 2017 3:00PM Water B17-De29463 X

2 1302_SW178_171212

Dec 12, 2017 3:00PM Water B17-De29464 X

3 1302_SW179_171213

Dec 13, 2017 11:00AM Water B17-De29465 X

4 1302_QC3IV_171213

Dec 13, 2017 5:00PM Water B17-De29466 X

5 1302_QC4FH_171215

Dec 15, 2017 10:00AM Water B17-De29467 X

Test Counts 5

ABN– 50 005 085 521e.mail : [email protected] : www.eurofins.com.au

MelbourneMelbourneMelbourneMelbourne2-5 Kingston Town CloseOakleigh VIC 3166Phone : +61 3 8564 5000NATA # 1261Site # 1254 & 14271

SydneySydneySydneySydneyUnit F3, Building F16 Mars RoadLane Cove West NSW 2066Phone : +61 2 9900 8400NATA # 1261 Site # 18217

BrisbaneBrisbaneBrisbaneBrisbane1/21 Smallwood PlaceMurarrie QLD 4172Phone : +61 7 3902 4600NATA # 1261 Site # 20794

PerthPerthPerthPerth2/91 Leach HighwayKewdale WA 6105Phone : +61 8 9251 9600NATA # 1261Site # 23736

Date Reported:Jan 05, 2018


ABN : 50 005 085 521 Telephone: +61 7 3902 4600

Page 6 of 14


Internal Quality Control Review and Glossary

General

Holding Times

Units

Terms

QC - Acceptance Criteria

QC Data General Comments

1. Laboratory QC results for Method Blanks, Duplicates, Matrix Spikes, and Laboratory Control Samples are included in this QC report where applicable. Additional QC data may be available on

request.

2. All soil results are reported on a dry basis, unless otherwise stated.

3. All biota results are reported on a wet weight basis on the edible portion, unless otherwise stated.

4. Actual LORs are matrix dependant. Quoted LORs may be raised where sample extracts are diluted due to interferences.

5. Results are uncorrected for matrix spikes or surrogate recoveries except for PFAS compounds.

6. SVOC analysis on waters are performed on homogenised, unfiltered samples, unless noted otherwise.

7. Samples were analysed on an 'as received' basis.

8. This report replaces any interim results previously issued.

Please refer to 'Sample Preservation and Container Guide' for holding times (QS3001).

For samples received on the last day of holding time, notification of testing requirements should have been received at least 6 hours prior to sample receipt deadlines as stated on the Sample

Receipt Advice.

If the Laboratory did not receive the information in the required timeframe, and regardless of any other integrity issues, suitably qualified results may still be reported.

Holding times apply from the date of sampling, therefore compliance to these may be outside the laboratory's control.

**NOTE: pH duplicates are reported as a range NOT as RPD

mg/kg: milligrams per kilogram mg/L: milligrams per litre

ug/L: micrograms per litre ppm: Parts per million

ppb: Parts per billion %: Percentage

org/100mL: Organisms per 100 millilitres NTU: Nephelometric Turbidity Units

MPN/100mL: Most Probable Number of organisms per 100 millilitres

Dry Where a moisture has been determined on a solid sample the result is expressed on a dry basis.

LOR Limit of Reporting.

SPIKE Addition of the analyte to the sample and reported as percentage recovery.

RPD Relative Percent Difference between two Duplicate pieces of analysis.

LCS Laboratory Control Sample - reported as percent recovery.

CRM Certified Reference Material - reported as percent recovery.

Method Blank In the case of solid samples these are performed on laboratory certified clean sands and in the case of water samples these are performed on de-ionised water.

Surr - Surrogate The addition of a like compound to the analyte target and reported as percentage recovery.

Duplicate A second piece of analysis from the same sample and reported in the same units as the result to show comparison.

USEPA United States Environmental Protection Agency

APHA American Public Health Association

TCLP Toxicity Characteristic Leaching Procedure

COC Chain of Custody

SRA Sample Receipt Advice

QSM Quality Systems Manual ver 5.1 US Department of Defense

CP Client Parent - QC was performed on samples pertaining to this report

NCP Non-Client Parent - QC performed on samples not pertaining to this report, QC is representative of the sequence or batch that client samples were analysed within.

TEQ Toxic Equivalency Quotient

RPD Duplicates: Global RPD Duplicates Acceptance Criteria is 30% however the following acceptance guidelines are equally applicable:

Results <10 times the LOR : No Limit

Results between 10-20 times the LOR : RPD must lie between 0-50%

Results >20 times the LOR : RPD must lie between 0-30%

Surrogate Recoveries: Recoveries must lie between 50-150%-Phenols & PFASs

PFAS field samples that contain surrogate recoveries in excess of the QC limit designated in QSM 5.1 where no positive PFAS results have been reported have been reviewed and no data was

affected.

1. Where a result is reported as a less than (<), higher than the nominated LOR, this is due to either matrix interference, extract dilution required due to interferences or contaminant levels within

the sample, high moisture content or insufficient sample provided.

2. Duplicate data shown within this report that states the word "BATCH" is a Batch Duplicate from outside of your sample batch, but within the laboratory sample batch at a 1:10 ratio. The Parent

and Duplicate data shown is not data from your samples.

3. Organochlorine Pesticide analysis - where reporting LCS data, Toxaphene & Chlordane are not added to the LCS.

4. Organochlorine Pesticide analysis - where reporting Spike data, Toxaphene is not added to the Spike.

5. Total Recoverable Hydrocarbons - where reporting Spike & LCS data, a single spike of commercial Hydrocarbon products in the range of C12-C30 is added and it's Total Recovery is reported

in the C10-C14 cell of the Report.

6. pH and Free Chlorine analysed in the laboratory - Analysis on this test must begin within 30 minutes of sampling.Therefore laboratory analysis is unlikely to be completed within holding time.

Analysis will begin as soon as possible after sample receipt.

7. Recovery Data (Spikes & Surrogates) - where chromatographic interference does not allow the determination of Recovery the term "INT" appears against that analyte.

8. Polychlorinated Biphenyls are spiked only using Aroclor 1260 in Matrix Spikes and LCS.

9. For Matrix Spikes and LCS results a dash " -" in the report means that the specific analyte was not added to the QC sample.

10. Duplicate RPDs are calculated from raw analytical data thus it is possible to have two sets of data.



ABN : 50 005 085 521 Telephone: +61 7 3902 4600

Page 7 of 14


Quality Control Results

Test Units Result 1 AcceptanceLimits

PassLimits

QualifyingCode

Method Blank


Perfluorobutanoic acid (PFBA) ug/L < 0.05 0.05 Pass

Perfluoropentanoic acid (PFPeA) ug/L < 0.01 0.01 Pass

Perfluorohexanoic acid (PFHxA) ug/L < 0.01 0.01 Pass

Perfluoroheptanoic acid (PFHpA) ug/L < 0.01 0.01 Pass

Perfluorooctanoic acid (PFOA) ug/L < 0.01 0.01 Pass

Perfluorononanoic acid (PFNA) ug/L < 0.01 0.01 Pass

Perfluorodecanoic acid (PFDA) ug/L < 0.01 0.01 Pass

Perfluoroundecanoic acid (PFUnA) ug/L < 0.01 0.01 Pass

Perfluorododecanoic acid (PFDoA) ug/L < 0.01 0.01 Pass

Perfluorotridecanoic acid (PFTrDA) ug/L < 0.01 0.01 Pass

Perfluorotetradecanoic acid (PFTeDA) ug/L < 0.01 0.01 Pass

Method Blank


Perfluorooctane sulfonamide (FOSA) ug/L < 0.05 0.05 Pass

N-methylperfluoro-1-octane sulfonamide (N-MeFOSA) ug/L < 0.05 0.05 Pass

N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA) ug/L < 0.05 0.05 Pass

2-(N-methylperfluoro-1-octane sulfonamido)-ethanol (N-MeFOSE) ug/L < 0.05 0.05 Pass

2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE) ug/L < 0.05 0.05 Pass

N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA) ug/L < 0.05 0.05 Pass

N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA) ug/L < 0.05 0.05 Pass

Method Blank


Perfluorobutanesulfonic acid (PFBS) ug/L < 0.01 0.01 Pass

Perfluoropentanesulfonic acid (PFPeS) ug/L < 0.01 0.01 Pass

Perfluorohexanesulfonic acid (PFHxS) ug/L < 0.01 0.01 Pass

Perfluoroheptanesulfonic acid (PFHpS) ug/L < 0.01 0.01 Pass

Perfluorooctanesulfonic acid (PFOS) ug/L < 0.01 0.01 Pass

Perfluorodecanesulfonic acid (PFDS) ug/L < 0.01 0.01 Pass

Method Blank


1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2 FTS) ug/L < 0.01 0.01 Pass

1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS) ug/L < 0.05 0.05 Pass

1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2 FTS) ug/L < 0.01 0.01 Pass

1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2 FTS) ug/L < 0.01 0.01 Pass

LCS - % Recovery


Perfluorobutanoic acid (PFBA) % 89 50-150 Pass

Perfluoropentanoic acid (PFPeA) % 97 50-150 Pass

Perfluorohexanoic acid (PFHxA) % 84 50-150 Pass

Perfluoroheptanoic acid (PFHpA) % 109 50-150 Pass

Perfluorooctanoic acid (PFOA) % 79 50-150 Pass

Perfluorononanoic acid (PFNA) % 90 50-150 Pass

Perfluorodecanoic acid (PFDA) % 90 50-150 Pass

Perfluoroundecanoic acid (PFUnA) % 95 50-150 Pass

Perfluorododecanoic acid (PFDoA) % 79 50-150 Pass

Perfluorotridecanoic acid (PFTrDA) % 87 50-150 Pass

Perfluorotetradecanoic acid (PFTeDA) % 92 50-150 Pass

LCS - % Recovery




ABN : 50 005 085 521 Telephone: +61 7 3902 4600

Page 8 of 14



PassLimits

QualifyingCode

Perfluorooctane sulfonamide (FOSA) % 70 50-150 Pass

N-methylperfluoro-1-octane sulfonamide (N-MeFOSA) % 91 50-150 Pass

N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA) % 88 50-150 Pass

2-(N-methylperfluoro-1-octane sulfonamido)-ethanol (N-MeFOSE) % 107 50-150 Pass

2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE) % 102 50-150 Pass

N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA) % 98 50-150 Pass

N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA) % 90 50-150 Pass

LCS - % Recovery


Perfluorobutanesulfonic acid (PFBS) % 82 50-150 Pass

Perfluoropentanesulfonic acid (PFPeS) % 105 50-150 Pass

Perfluorohexanesulfonic acid (PFHxS) % 86 50-150 Pass

Perfluoroheptanesulfonic acid (PFHpS) % 88 50-150 Pass

Perfluorooctanesulfonic acid (PFOS) % 84 50-150 Pass

Perfluorodecanesulfonic acid (PFDS) % 56 50-150 Pass

LCS - % Recovery


1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2 FTS) % 89 50-150 Pass

1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS) % 84 50-150 Pass

1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2 FTS) % 92 50-150 Pass

1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2 FTS) % 53 50-150 Pass

Test Lab Sample ID QASource Units Result 1 Acceptance

LimitsPass

LimitsQualifying

Code

Spike - % Recovery

Perfluoroalkyl carboxylic acids (PFCAs) Result 1

Perfluorobutanoic acid (PFBA) B17-De29464 CP % 85 50-150 Pass

Perfluoropentanoic acid (PFPeA) B17-De29464 CP % 97 50-150 Pass

Perfluorohexanoic acid (PFHxA) B17-De29464 CP % 81 50-150 Pass

Perfluoroheptanoic acid (PFHpA) B17-De29464 CP % 104 50-150 Pass

Perfluorooctanoic acid (PFOA) B17-De29464 CP % 77 50-150 Pass

Perfluorononanoic acid (PFNA) B17-De29464 CP % 86 50-150 Pass

Perfluorodecanoic acid (PFDA) B17-De29464 CP % 84 50-150 Pass

Perfluoroundecanoic acid (PFUnA) B17-De29464 CP % 92 50-150 Pass

Perfluorododecanoic acid (PFDoA) B17-De29464 CP % 80 50-150 Pass

Perfluorotridecanoic acid (PFTrDA) B17-De29464 CP % 96 50-150 Pass

Perfluorotetradecanoic acid(PFTeDA) B17-De29464 CP % 98 50-150 Pass

Spike - % Recovery

Perfluoroalkane sulfonamides (PFASAs) Result 1

Perfluorooctane sulfonamide(FOSA) B17-De29464 CP % 70 50-150 Pass

N-methylperfluoro-1-octanesulfonamide (N-MeFOSA) B17-De29464 CP % 86 50-150 Pass

N-ethylperfluoro-1-octanesulfonamide (N-EtFOSA) B17-De29464 CP % 92 50-150 Pass

2-(N-methylperfluoro-1-octanesulfonamido)-ethanol (N-MeFOSE) B17-De29464 CP % 106 50-150 Pass

2-(N-ethylperfluoro-1-octanesulfonamido)-ethanol (N-EtFOSE) B17-De29464 CP % 103 50-150 Pass

N-ethyl-perfluorooctanesulfonamidoaceticacid (N-EtFOSAA) B17-De29464 CP % 89 50-150 Pass

N-methyl-perfluorooctanesulfonamidoaceticacid (N-MeFOSAA) B17-De29464 CP % 98 50-150 Pass

Spike - % Recovery

Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Result 1



ABN : 50 005 085 521 Telephone: +61 7 3902 4600

Page 9 of 14



LimitsPass

LimitsQualifying

Code

Perfluorobutanesulfonic acid(PFBS) B17-De29464 CP % 82 50-150 Pass

Perfluoropentanesulfonic acid(PFPeS) B17-De29464 CP % 95 50-150 Pass

Perfluorohexanesulfonic acid(PFHxS) B17-De29464 CP % 91 50-150 Pass

Perfluoroheptanesulfonic acid(PFHpS) B17-De29464 CP % 83 50-150 Pass

Perfluorooctanesulfonic acid(PFOS) B17-De29464 CP % 86 50-150 Pass

Perfluorodecanesulfonic acid(PFDS) B17-De29464 CP % 56 50-150 Pass

Spike - % Recovery

n:2 Fluorotelomer sulfonic acids Result 1

1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS) B17-De29464 CP % 90 50-150 Pass

1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTS) B17-De29464 CP % 83 50-150 Pass

1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS) B17-De29464 CP % 94 50-150 Pass

1H.1H.2H.2H-perfluorododecanesulfonic acid(10:2 FTS) B17-De29464 CP % 69 50-150 Pass

Spike - % Recovery













Spike - % Recovery









Spike - % Recovery





ABN : 50 005 085 521 Telephone: +61 7 3902 4600

Page 10 of 14



LimitsPass

LimitsQualifying

Code






Spike - % Recovery







LimitsPass

LimitsQualifying

Code

Duplicate

Perfluoroalkyl carboxylic acids (PFCAs) Result 1 Result 2 RPD

Perfluorobutanoic acid (PFBA) B17-De29463 CP ug/L < 0.05 < 0.05 <1 30% Pass

Perfluoropentanoic acid (PFPeA) B17-De29463 CP ug/L < 0.01 < 0.01 <1 30% Pass

Perfluorohexanoic acid (PFHxA) B17-De29463 CP ug/L < 0.01 < 0.01 <1 30% Pass

Perfluoroheptanoic acid (PFHpA) B17-De29463 CP ug/L < 0.01 < 0.01 <1 30% Pass

Perfluorooctanoic acid (PFOA) B17-De29463 CP ug/L < 0.01 < 0.01 <1 30% Pass

Perfluorononanoic acid (PFNA) B17-De29463 CP ug/L < 0.01 < 0.01 <1 30% Pass

Perfluorodecanoic acid (PFDA) B17-De29463 CP ug/L < 0.01 < 0.01 <1 30% Pass

Perfluoroundecanoic acid (PFUnA) B17-De29463 CP ug/L < 0.01 < 0.01 <1 30% Pass

Perfluorododecanoic acid (PFDoA) B17-De29463 CP ug/L < 0.01 < 0.01 <1 30% Pass

Perfluorotridecanoic acid (PFTrDA) B17-De29463 CP ug/L < 0.01 < 0.01 <1 30% Pass

Perfluorotetradecanoic acid(PFTeDA) B17-De29463 CP ug/L < 0.01 < 0.01 <1 30% Pass

Duplicate

Perfluoroalkane sulfonamides (PFASAs) Result 1 Result 2 RPD

Perfluorooctane sulfonamide(FOSA) B17-De29463 CP ug/L < 0.05 < 0.05 <1 30% Pass

N-methylperfluoro-1-octanesulfonamide (N-MeFOSA) B17-De29463 CP ug/L < 0.05 < 0.05 <1 30% Pass

N-ethylperfluoro-1-octanesulfonamide (N-EtFOSA) B17-De29463 CP ug/L < 0.05 < 0.05 <1 30% Pass

2-(N-methylperfluoro-1-octanesulfonamido)-ethanol (N-MeFOSE) B17-De29463 CP ug/L < 0.05 < 0.05 <1 30% Pass

2-(N-ethylperfluoro-1-octanesulfonamido)-ethanol (N-EtFOSE) B17-De29463 CP ug/L < 0.05 < 0.05 <1 30% Pass

N-ethyl-perfluorooctanesulfonamidoaceticacid (N-EtFOSAA) B17-De29463 CP ug/L < 0.05 < 0.05 <1 30% Pass

N-methyl-perfluorooctanesulfonamidoaceticacid (N-MeFOSAA) B17-De29463 CP ug/L < 0.05 < 0.05 <1 30% Pass



ABN : 50 005 085 521 Telephone: +61 7 3902 4600

Page 11 of 14


Duplicate

Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Result 1 Result 2 RPD

Perfluorobutanesulfonic acid(PFBS) B17-De29463 CP ug/L < 0.01 < 0.01 <1 30% Pass

Perfluoropentanesulfonic acid(PFPeS) B17-De29463 CP ug/L < 0.01 < 0.01 <1 30% Pass

Perfluorohexanesulfonic acid(PFHxS) B17-De29463 CP ug/L < 0.01 < 0.01 <1 30% Pass

Perfluoroheptanesulfonic acid(PFHpS) B17-De29463 CP ug/L < 0.01 < 0.01 <1 30% Pass

Perfluorooctanesulfonic acid(PFOS) B17-De29463 CP ug/L < 0.01 < 0.01 <1 30% Pass

Perfluorodecanesulfonic acid(PFDS) B17-De29463 CP ug/L < 0.01 < 0.01 <1 30% Pass

Duplicate

n:2 Fluorotelomer sulfonic acids Result 1 Result 2 RPD

1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS) B17-De29463 CP ug/L < 0.01 < 0.01 <1 30% Pass

1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTS) B17-De29463 CP ug/L < 0.05 < 0.05 <1 30% Pass

1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS) B17-De29463 CP ug/L < 0.01 < 0.01 <1 30% Pass

1H.1H.2H.2H-perfluorododecanesulfonic acid(10:2 FTS) B17-De29463 CP ug/L < 0.01 < 0.01 <1 30% Pass

Duplicate


Perfluorobutanoic acid (PFBA) B17-De29466 CP ug/L < 0.05 < 0.05 <1 30% Pass

Perfluoropentanoic acid (PFPeA) B17-De29466 CP ug/L < 0.01 < 0.01 <1 30% Pass

Perfluorohexanoic acid (PFHxA) B17-De29466 CP ug/L < 0.01 < 0.01 <1 30% Pass

Perfluoroheptanoic acid (PFHpA) B17-De29466 CP ug/L < 0.01 < 0.01 <1 30% Pass

Perfluorooctanoic acid (PFOA) B17-De29466 CP ug/L < 0.01 < 0.01 <1 30% Pass

Perfluorononanoic acid (PFNA) B17-De29466 CP ug/L < 0.01 < 0.01 <1 30% Pass

Perfluorodecanoic acid (PFDA) B17-De29466 CP ug/L < 0.01 < 0.01 <1 30% Pass

Perfluoroundecanoic acid (PFUnA) B17-De29466 CP ug/L < 0.01 < 0.01 <1 30% Pass

Perfluorododecanoic acid (PFDoA) B17-De29466 CP ug/L < 0.01 < 0.01 <1 30% Pass

Perfluorotridecanoic acid (PFTrDA) B17-De29466 CP ug/L < 0.01 < 0.01 <1 30% Pass

Perfluorotetradecanoic acid(PFTeDA) B17-De29466 CP ug/L < 0.01 < 0.01 <1 30% Pass

Duplicate


Perfluorooctane sulfonamide(FOSA) B17-De29466 CP ug/L < 0.05 < 0.05 <1 30% Pass

N-methylperfluoro-1-octanesulfonamide (N-MeFOSA) B17-De29466 CP ug/L < 0.05 < 0.05 <1 30% Pass

N-ethylperfluoro-1-octanesulfonamide (N-EtFOSA) B17-De29466 CP ug/L < 0.05 < 0.05 <1 30% Pass

2-(N-methylperfluoro-1-octanesulfonamido)-ethanol (N-MeFOSE) B17-De29466 CP ug/L < 0.05 < 0.05 <1 30% Pass

2-(N-ethylperfluoro-1-octanesulfonamido)-ethanol (N-EtFOSE) B17-De29466 CP ug/L < 0.05 < 0.05 <1 30% Pass

N-ethyl-perfluorooctanesulfonamidoaceticacid (N-EtFOSAA) B17-De29466 CP ug/L < 0.05 < 0.05 <1 30% Pass

N-methyl-perfluorooctanesulfonamidoaceticacid (N-MeFOSAA) B17-De29466 CP ug/L < 0.05 < 0.05 <1 30% Pass



ABN : 50 005 085 521 Telephone: +61 7 3902 4600

Page 12 of 14


Duplicate


Perfluorobutanesulfonic acid(PFBS) B17-De29466 CP ug/L < 0.01 < 0.01 <1 30% Pass

Perfluoropentanesulfonic acid(PFPeS) B17-De29466 CP ug/L < 0.01 < 0.01 <1 30% Pass

Perfluorohexanesulfonic acid(PFHxS) B17-De29466 CP ug/L < 0.01 < 0.01 <1 30% Pass

Perfluoroheptanesulfonic acid(PFHpS) B17-De29466 CP ug/L < 0.01 < 0.01 <1 30% Pass

Perfluorooctanesulfonic acid(PFOS) B17-De29466 CP ug/L < 0.01 < 0.01 <1 30% Pass

Perfluorodecanesulfonic acid(PFDS) B17-De29466 CP ug/L < 0.01 < 0.01 <1 30% Pass

Duplicate


1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS) B17-De29466 CP ug/L < 0.01 < 0.01 <1 30% Pass

1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTS) B17-De29466 CP ug/L < 0.05 < 0.05 <1 30% Pass

1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS) B17-De29466 CP ug/L < 0.01 < 0.01 <1 30% Pass

1H.1H.2H.2H-perfluorododecanesulfonic acid(10:2 FTS) B17-De29466 CP ug/L < 0.01 < 0.01 <1 30% Pass



ABN : 50 005 085 521 Telephone: +61 7 3902 4600

Page 13 of 14


Comments

Sample IntegrityCustody Seals Intact (if used) N/A

Attempt to Chill was evident Yes

Sample correctly preserved Yes

Appropriate sample containers have been used Yes

Sample containers for volatile analysis received with minimal headspace Yes

Samples received within HoldingTime Yes

Some samples have been subcontracted No

Comments

Qualifier Codes/Comments

Code DescriptionN09 Quantification of linear and branched isomers has been conducted as a single total response using the relative response factor for the corresponding linear/branched standard.

N11

Isotope dilution is used for calibration of each native compound for which an exact labelled analogue is available (Isotope Dilution Quantitation). The isotopically labelledanalogues allow identification and recovery correction of the concentration of the associated native PFAS compounds. Where the native PFAS compound does not have labelledanalogue then the quantification is made using the Extracted Internal Standard Analyte with the closest retention time to the analyte and no recovery correction has been made(Internal Standard Quantitation).

Authorised By

Mary Makarios Analytical Services Manager

Jonathon Angell Senior Analyst-Organic (QLD)

Glenn Jackson

National Operations Manager

- Indicates Not Requested

* Indicates NATA accreditation does not cover the performance of this service

Measurement uncertainty of test data is available on request or please click here.Eurofins | mgt shall not be liable for loss, cost, damages or expenses incurred by the client, or any other person or company, resulting from the use of any information or interpretation given in this report. In no case shall Eurofins | mgt be liable for consequential damages including, but notlimited to, lost profits, damages for failure to meet deadlines and lost production arising from this report. This document shall not be reproduced except in full and relates only to the items tested. Unless indicated otherwise, the tests were performed on the samples as received.



ABN : 50 005 085 521 Telephone: +61 7 3902 4600

Page 14 of 14


https://cdnmedia.eurofins.com/apac/media/601272/reporting-measurement-uncertainty-of-chemical-and-microbiology-test-results-hrks-20171221.pdf




Abbotsford

VIC 3067


Report 578707-S




Client Sample ID 0990_VG160_171212

0990_VG161_171212

0990_VG162_171212

0990_VG163_171213

Sample Matrix Plant Material Plant Material Plant Material Plant Material





Perfluorobutanoic acid (PFBA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5

Perfluoropentanoic acid (PFPeA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5

Perfluorohexanoic acid (PFHxA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5

Perfluoroheptanoic acid (PFHpA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5

Perfluorooctanoic acid (PFOA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5

Perfluorononanoic acid (PFNA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5

Perfluorodecanoic acid (PFDA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5

Perfluoroundecanoic acid (PFUnA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5

Perfluorododecanoic acid (PFDoA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5

Perfluorotridecanoic acid (PFTrDA) 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5

Perfluorotetradecanoic acid (PFTeDA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5

13C4-PFBA (surr.) 1 % 19 INT 61 17

13C5-PFPeA (surr.) 1 % 26 INT 97 18

13C5-PFHxA (surr.) 1 % 28 INT 105 21

13C4-PFHpA (surr.) 1 % 28 INT 143 22

13C8-PFOA (surr.) 1 % 23 INT 125 16

13C5-PFNA (surr.) 1 % 23 INT 132 20

13C6-PFDA (surr.) 1 % 27 INT 147 22

13C2-PFUnDA (surr.) 1 % 15 INT 99 13

13C2-PFDoDA (surr.) 1 % 21 16 123 20

13C2-PFTeDA (surr.) 1 % 10 24 76 INT


Perfluorooctane sulfonamide (FOSA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5

N-methylperfluoro-1-octane sulfonamide (N-MeFOSA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5

N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5

2-(N-methylperfluoro-1-octane sulfonamido)-ethanol(N-MeFOSE)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5

2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5

N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5

N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5

13C8-FOSA (surr.) 1 % INT 12 94 INT

D3-N-MeFOSA (surr.) 1 % INT INT 22 INT



ABN : 50 005 085 521 Telephone: +61 7 3902 4600

Page 1 of 22

Report Number: 578707-S


0990_VG161_171212

0990_VG162_171212

0990_VG163_171213






D5-N-EtFOSA (surr.) 1 % 18 INT 45 13

D7-N-MeFOSE (surr.) 1 % 24 INT 62 23

D9-N-EtFOSE (surr.) 1 % 20 INT 44 17

D5-N-EtFOSAA (surr.) 1 % 27 INT 183 21

D3-N-MeFOSAA (surr.) 1 % 22 INT 135 19


Perfluorobutanesulfonic acid (PFBS)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5

Perfluoropentanesulfonic acid (PFPeS) 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5

Perfluorohexanesulfonic acid (PFHxS)N11 0.3 ug/kg < 0.3 < 0.3 < 0.3 < 0.3

Perfluoroheptanesulfonic acid (PFHpS) 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5

Perfluorooctanesulfonic acid (PFOS)N11 0.3 ug/kg < 0.3 < 0.3 < 0.3 < 0.3

Perfluorodecanesulfonic acid (PFDS) 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5

13C3-PFBS (surr.) 1 % 37 7.0 95 31

18O2-PFHxS (surr.) 1 % 31 INT 116 28

13C8-PFOS (surr.) 1 % 31 INT 132 31


1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5

1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5

1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5

1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2FTS) 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5

13C2-4:2 FTS (surr.) 1 % 21 INT 86 12

13C2-6:2 FTS (surr.) 1 % 22 INT 125 16

13C2-8:2 FTS (surr.) 1 % 24 INT 147 21

PFASs Summations

Sum (PFHxS + PFOS)* 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5

Sum of US EPA PFAS (PFOS + PFOA)* 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5

Sum of enHealth PFAS (PFHxS + PFOS + PFOA)* 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5

Sum of WA DER PFAS (n=10)* 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5

Sum of PFASs (n=28)* 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5


0990_VG165_171213

0990_VG166_171211

0990_VG167_171211






Perfluorobutanoic acid (PFBA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 1.3











ABN : 50 005 085 521 Telephone: +61 7 3902 4600

Page 2 of 22



0990_VG165_171213

0990_VG166_171211

0990_VG167_171211








13C4-PFBA (surr.) 1 % INT 55 INT 39

13C5-PFPeA (surr.) 1 % 11 90 11 45

13C5-PFHxA (surr.) 1 % 10 102 INT 66

13C4-PFHpA (surr.) 1 % INT 129 INT 67

13C8-PFOA (surr.) 1 % INT 125 INT 52

13C5-PFNA (surr.) 1 % INT 145 INT 60

13C6-PFDA (surr.) 1 % INT 148 INT 64

13C2-PFUnDA (surr.) 1 % INT 98 INT 56

13C2-PFDoDA (surr.) 1 % INT 111 INT 89

13C2-PFTeDA (surr.) 1 % INT 55 INT 46









13C8-FOSA (surr.) 1 % INT 76 INT 27

D3-N-MeFOSA (surr.) 1 % INT 29 INT INT

D5-N-EtFOSA (surr.) 1 % INT 50 INT INT

D7-N-MeFOSE (surr.) 1 % INT 44 INT INT

D9-N-EtFOSE (surr.) 1 % INT 47 INT INT

D5-N-EtFOSAA (surr.) 1 % INT 120 INT 83

D3-N-MeFOSAA (surr.) 1 % INT 131 INT 58


Perfluorobutanesulfonic acid (PFBS)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 N090.6


Perfluorohexanesulfonic acid (PFHxS)N11 0.3 ug/kg N091.7 < 0.3 0.9 0.3


Perfluorooctanesulfonic acid (PFOS)N11 0.3 ug/kg N092.8 < 0.3 N095.1 N091.1


13C3-PFBS (surr.) 1 % 14 85 16 67

18O2-PFHxS (surr.) 1 % INT 122 12 68

13C8-PFOS (surr.) 1 % INT 146 INT 46






13C2-4:2 FTS (surr.) 1 % INT 85 INT 47



ABN : 50 005 085 521 Telephone: +61 7 3902 4600

Page 3 of 22



0990_VG165_171213

0990_VG166_171211

0990_VG167_171211






13C2-6:2 FTS (surr.) 1 % INT 121 INT 64

13C2-8:2 FTS (surr.) 1 % INT 151 11 57

PFASs Summations

Sum (PFHxS + PFOS)* 0.5 ug/kg 4.5 < 0.5 6 1.4

Sum of US EPA PFAS (PFOS + PFOA)* 0.5 ug/kg 2.8 < 0.5 5.1 1.1

Sum of enHealth PFAS (PFHxS + PFOS + PFOA)* 0.5 ug/kg 4.5 < 0.5 6 1.4

Sum of WA DER PFAS (n=10)* 0.5 ug/kg 4.5 < 0.5 6 3.3

Sum of PFASs (n=28)* 0.5 ug/kg 4.5 < 0.5 6 3.3


0990_VG169_171211

0990_VG170_171211

0990_VG171_171211






Perfluorobutanoic acid (PFBA)N11 0.5 ug/kg 0.7 0.6 < 0.5 < 0.5











13C4-PFBA (surr.) 1 % 32 23 27 40

13C5-PFPeA (surr.) 1 % 27 39 36 32

13C5-PFHxA (surr.) 1 % 37 41 43 78

13C4-PFHpA (surr.) 1 % 56 40 47 86

13C8-PFOA (surr.) 1 % 30 29 46 93

13C5-PFNA (surr.) 1 % 53 26 52 99

13C6-PFDA (surr.) 1 % 86 25 66 118

13C2-PFUnDA (surr.) 1 % 71 19 65 82

13C2-PFDoDA (surr.) 1 % 105 27 96 84

13C2-PFTeDA (surr.) 1 % 61 17 60 23










ABN : 50 005 085 521 Telephone: +61 7 3902 4600

Page 4 of 22



0990_VG169_171211

0990_VG170_171211

0990_VG171_171211







13C8-FOSA (surr.) 1 % 58 22 67 81


D5-N-EtFOSA (surr.) 1 % 11 13 36 13

D7-N-MeFOSE (surr.) 1 % 30 19 45 17

D9-N-EtFOSE (surr.) 1 % INT 18 37 INT

D5-N-EtFOSAA (surr.) 1 % 122 25 75 117

D3-N-MeFOSAA (surr.) 1 % 103 17 62 108




Perfluorohexanesulfonic acid (PFHxS)N11 0.3 ug/kg N090.9 0.3 < 0.3 N091.0


Perfluorooctanesulfonic acid (PFOS)N11 0.3 ug/kg N092.2 < 0.3 0.4 < 0.3


13C3-PFBS (surr.) 1 % 54 53 50 96

18O2-PFHxS (surr.) 1 % 34 44 60 107

13C8-PFOS (surr.) 1 % 74 35 79 87






13C2-4:2 FTS (surr.) 1 % INT 29 40 69

13C2-6:2 FTS (surr.) 1 % 58 26 40 79

13C2-8:2 FTS (surr.) 1 % 81 25 50 128

PFASs Summations

Sum (PFHxS + PFOS)* 0.5 ug/kg 3.1 < 0.5 < 0.5 1

Sum of US EPA PFAS (PFOS + PFOA)* 0.5 ug/kg 2.2 < 0.5 < 0.5 < 0.5

Sum of enHealth PFAS (PFHxS + PFOS + PFOA)* 0.5 ug/kg 3.1 < 0.5 < 0.5 1

Sum of WA DER PFAS (n=10)* 0.5 ug/kg 3.8 0.9 < 0.5 1

Sum of PFASs (n=28)* 0.5 ug/kg 3.8 0.9 < 0.5 1


0990_VG173_171211

0990_VG174_171211

0990_VG175_171211






Perfluorobutanoic acid (PFBA)N11 0.5 ug/kg 1.9 < 0.5 < 0.5 680

Perfluoropentanoic acid (PFPeA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 N09210

Perfluorohexanoic acid (PFHxA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 N09290

Perfluoroheptanoic acid (PFHpA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 N0927

Perfluorooctanoic acid (PFOA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 N0931



ABN : 50 005 085 521 Telephone: +61 7 3902 4600

Page 5 of 22



0990_VG173_171211

0990_VG174_171211

0990_VG175_171211






Perfluorononanoic acid (PFNA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 N091.3






13C4-PFBA (surr.) 1 % INT 59 33 51

13C5-PFPeA (surr.) 1 % 12 90 44 71

13C5-PFHxA (surr.) 1 % 14 96 48 82

13C4-PFHpA (surr.) 1 % INT 103 36 64

13C8-PFOA (surr.) 1 % 15 114 31 49

13C5-PFNA (surr.) 1 % 14 140 41 59

13C6-PFDA (surr.) 1 % 7.0 145 34 39

13C2-PFUnDA (surr.) 1 % INT 118 39 43

13C2-PFDoDA (surr.) 1 % INT 149 28 31

13C2-PFTeDA (surr.) 1 % INT 57 19 16









13C8-FOSA (surr.) 1 % INT 76 39 50

D3-N-MeFOSA (surr.) 1 % INT 20 20 22

D5-N-EtFOSA (surr.) 1 % INT 54 15 17

D7-N-MeFOSE (surr.) 1 % INT 24 25 27

D9-N-EtFOSE (surr.) 1 % INT 43 19 20

D5-N-EtFOSAA (surr.) 1 % INT 153 33 49

D3-N-MeFOSAA (surr.) 1 % INT 74 31 41


Perfluorobutanesulfonic acid (PFBS)N11 0.5 ug/kg 1.3 < 0.5 < 0.5 N09120

Perfluoropentanesulfonic acid (PFPeS) 0.5 ug/kg < 0.5 < 0.5 < 0.5 N0974

Perfluorohexanesulfonic acid (PFHxS)N11 0.3 ug/kg N093.9 < 0.3 N091.2 N09310

Perfluoroheptanesulfonic acid (PFHpS) 0.5 ug/kg < 0.5 < 0.5 < 0.5 N0912

Perfluorooctanesulfonic acid (PFOS)N11 0.3 ug/kg N097.0 0.4 < 0.3 N09530

Perfluorodecanesulfonic acid (PFDS) 0.5 ug/kg < 0.5 < 0.5 < 0.5 N092.1

13C3-PFBS (surr.) 1 % 22 86 75 90

18O2-PFHxS (surr.) 1 % 22 115 53 81

13C8-PFOS (surr.) 1 % 12 139 64 72



ABN : 50 005 085 521 Telephone: +61 7 3902 4600

Page 6 of 22



0990_VG173_171211

0990_VG174_171211

0990_VG175_171211










13C2-4:2 FTS (surr.) 1 % INT 105 42 59

13C2-6:2 FTS (surr.) 1 % 10 139 20 40

13C2-8:2 FTS (surr.) 1 % 14 160 22 33

PFASs Summations

Sum (PFHxS + PFOS)* 0.5 ug/kg 10.9 < 0.5 1.2 840

Sum of US EPA PFAS (PFOS + PFOA)* 0.5 ug/kg 7 < 0.5 < 0.5 561

Sum of enHealth PFAS (PFHxS + PFOS + PFOA)* 0.5 ug/kg 10.9 < 0.5 1.2 871

Sum of WA DER PFAS (n=10)* 0.5 ug/kg 14.1 < 0.5 1.2 2198

Sum of PFASs (n=28)* 0.5 ug/kg 14.1 < 0.5 1.2 2287.4


0990_VG177_171211

0990_VG178_171211

0990_VG179_171211






Perfluorobutanoic acid (PFBA)N11 0.5 ug/kg 1.3 57 90 < 0.5

Perfluoropentanoic acid (PFPeA)N11 0.5 ug/kg < 0.5 N0935 N0946 < 0.5

Perfluorohexanoic acid (PFHxA)N11 0.5 ug/kg < 0.5 N0937 N0981 < 0.5

Perfluoroheptanoic acid (PFHpA)N11 0.5 ug/kg < 0.5 N092.3 N093.2 < 0.5

Perfluorooctanoic acid (PFOA)N11 0.5 ug/kg < 0.5 N091.9 N092.5 < 0.5







13C4-PFBA (surr.) 1 % 38 40 47 36

13C5-PFPeA (surr.) 1 % 17 34 68 37

13C5-PFHxA (surr.) 1 % 85 55 70 56

13C4-PFHpA (surr.) 1 % 108 59 51 60

13C8-PFOA (surr.) 1 % 150 58 55 61

13C5-PFNA (surr.) 1 % 145 50 66 70

13C6-PFDA (surr.) 1 % 142 52 47 61

13C2-PFUnDA (surr.) 1 % 90 20 61 69

13C2-PFDoDA (surr.) 1 % INT INT 51 53

13C2-PFTeDA (surr.) 1 % 52 10 48 42



ABN : 50 005 085 521 Telephone: +61 7 3902 4600

Page 7 of 22



0990_VG177_171211

0990_VG178_171211

0990_VG179_171211













13C8-FOSA (surr.) 1 % 20 INT 54 52

D3-N-MeFOSA (surr.) 1 % INT INT 32 25

D5-N-EtFOSA (surr.) 1 % INT INT 23 17

D7-N-MeFOSE (surr.) 1 % 198 10 32 31

D9-N-EtFOSE (surr.) 1 % INT INT 27 26

D5-N-EtFOSAA (surr.) 1 % 28 11 57 64

D3-N-MeFOSAA (surr.) 1 % 19 INT 48 61


Perfluorobutanesulfonic acid (PFBS)N11 0.5 ug/kg 1.4 100 N09100 < 0.5

Perfluoropentanesulfonic acid (PFPeS) 0.5 ug/kg N091.3 N0973 N0930 < 0.5

Perfluorohexanesulfonic acid (PFHxS)N11 0.3 ug/kg N095.8 N09140 N0984 < 0.3

Perfluoroheptanesulfonic acid (PFHpS) 0.5 ug/kg < 0.5 N092.6 N093.8 < 0.5

Perfluorooctanesulfonic acid (PFOS)N11 0.3 ug/kg N090.8 N0942 N09380 < 0.3


13C3-PFBS (surr.) 1 % 118 73 83 77

18O2-PFHxS (surr.) 1 % 72 65 80 72

13C8-PFOS (surr.) 1 % 63 86 83 89






13C2-4:2 FTS (surr.) 1 % 15 70 43 57

13C2-6:2 FTS (surr.) 1 % 45 121 62 63

13C2-8:2 FTS (surr.) 1 % 23 50 65 53

PFASs Summations

Sum (PFHxS + PFOS)* 0.5 ug/kg 6.6 182 464 < 0.5

Sum of US EPA PFAS (PFOS + PFOA)* 0.5 ug/kg 0.8 43.9 382.5 < 0.5

Sum of enHealth PFAS (PFHxS + PFOS + PFOA)* 0.5 ug/kg 6.6 183.9 466.5 < 0.5

Sum of WA DER PFAS (n=10)* 0.5 ug/kg 9.3 415.2 786.7 < 0.5

Sum of PFASs (n=28)* 0.5 ug/kg 10.6 490.8 820.5 < 0.5



ABN : 50 005 085 521 Telephone: +61 7 3902 4600

Page 8 of 22



0990_VG181_171211

0990_VG182_171211

0990_VG183_171211

















13C4-PFBA (surr.) 1 % 10 30 26 61

13C5-PFPeA (surr.) 1 % INT 33 45 76

13C5-PFHxA (surr.) 1 % 11 48 66 92

13C4-PFHpA (surr.) 1 % 10 55 49 83

13C8-PFOA (surr.) 1 % 13 85 70 81

13C5-PFNA (surr.) 1 % 16 75 78 86

13C6-PFDA (surr.) 1 % 15 67 84 74

13C2-PFUnDA (surr.) 1 % 18 43 86 63

13C2-PFDoDA (surr.) 1 % 17 19 82 45

13C2-PFTeDA (surr.) 1 % 16 INT 73 30









13C8-FOSA (surr.) 1 % 18 INT 70 61

D3-N-MeFOSA (surr.) 1 % 12 INT 39 27

D5-N-EtFOSA (surr.) 1 % 7.0 INT 28 21

D7-N-MeFOSE (surr.) 1 % 12 37 47 30


D5-N-EtFOSAA (surr.) 1 % 11 16 104 49

D3-N-MeFOSAA (surr.) 1 % 11 10 69 57






Perfluorooctanesulfonic acid (PFOS)N11 0.3 ug/kg < 0.3 < 0.3 < 0.3 N091.6


13C3-PFBS (surr.) 1 % 27 56 94 101

18O2-PFHxS (surr.) 1 % 26 56 83 92

13C8-PFOS (surr.) 1 % 29 87 107 100



ABN : 50 005 085 521 Telephone: +61 7 3902 4600

Page 9 of 22



0990_VG181_171211

0990_VG182_171211

0990_VG183_171211










13C2-4:2 FTS (surr.) 1 % 11 81 55 78

13C2-6:2 FTS (surr.) 1 % 8.0 173 71 63

13C2-8:2 FTS (surr.) 1 % 7.0 106 78 55

PFASs Summations

Sum (PFHxS + PFOS)* 0.5 ug/kg < 0.5 < 0.5 < 0.5 1.6

Sum of US EPA PFAS (PFOS + PFOA)* 0.5 ug/kg < 0.5 < 0.5 < 0.5 1.6

Sum of enHealth PFAS (PFHxS + PFOS + PFOA)* 0.5 ug/kg < 0.5 < 0.5 < 0.5 1.6

Sum of WA DER PFAS (n=10)* 0.5 ug/kg < 0.5 < 0.5 < 0.5 1.6

Sum of PFASs (n=28)* 0.5 ug/kg < 0.5 < 0.5 < 0.5 1.6



ABN : 50 005 085 521 Telephone: +61 7 3902 4600

Page 10 of 22
















ABN : 50 005 085 521 Telephone: +61 7 3902 4600

Page 11 of 22


.Company Name: Coffey Environments Pty Ltd VIC Order No.: Received: Dec 20, 2017 2:48 PMAddress: Level 1, 436 Johnston Street Report #: 578707 Due: Jan 8, 2018




Sample Detail

Per- and P


ubstances(P

FA

Ss)





External Laboratory


Matrix LAB ID

1 0990_VG160_171212

Dec 12, 2017 Plant Material B17-De29704 X

2 0990_VG161_171212


3 0990_VG162_171212


4 0990_VG163_171213


5 0990_VG164_171213


6 0990_VG165_ Dec 13, 2017 Plant Material B17-De29709 X








ABN : 50 005 085 521 Telephone: +61 7 3902 4600

Page 12 of 22


Company Name: Coffey Environments Pty Ltd VIC Order No.: Received: Dec 20, 2017 2:48 PMAddress: Level 1, 436 Johnston Street Report #: 578707 Due: Jan 8, 2018




Sample Detail

Per- and P


ubstances(P

FA

Ss)





171213

7 0990_VG166_171211


8 0990_VG167_171211


9 0990_VG168_171211


10 0990_VG169_171211


11 0990_VG170_171211


12 0990_VG171_171211










ABN : 50 005 085 521 Telephone: +61 7 3902 4600

Page 13 of 22






Sample Detail

Per- and P


ubstances(P

FA

Ss)





171211

14 0990_VG173_171211


15 0990_VG174_171211


16 0990_VG175_171211


17 0990_VG176_171211


18 0990_VG177_171211


19 0990_VG178_171211










ABN : 50 005 085 521 Telephone: +61 7 3902 4600

Page 14 of 22






Sample Detail

Per- and P


ubstances(P

FA

Ss)





171211

21 0990_VG180_171211


22 0990_VG181_171211


23 0990_VG182_171211


24 0990_VG183_171211


Test Counts 24








ABN : 50 005 085 521 Telephone: +61 7 3902 4600

Page 15 of 22



General

Holding Times

Units

Terms




request.










Receipt Advice.

































affected.

















ABN : 50 005 085 521 Telephone: +61 7 3902 4600

Page 16 of 22




PassLimits

QualifyingCode

Method Blank


Perfluorobutanoic acid (PFBA) ug/kg < 0.5 0.5 Pass

Perfluoropentanoic acid (PFPeA) ug/kg < 0.5 0.5 Pass

Perfluorohexanoic acid (PFHxA) ug/kg < 0.5 0.5 Pass

Perfluoroheptanoic acid (PFHpA) ug/kg < 0.5 0.5 Pass

Perfluorooctanoic acid (PFOA) ug/kg < 0.5 0.5 Pass

Perfluorononanoic acid (PFNA) ug/kg < 0.5 0.5 Pass

Perfluorodecanoic acid (PFDA) ug/kg < 0.5 0.5 Pass

Perfluoroundecanoic acid (PFUnA) ug/kg < 0.5 0.5 Pass

Perfluorododecanoic acid (PFDoA) ug/kg < 0.5 0.5 Pass

Perfluorotridecanoic acid (PFTrDA) ug/kg < 0.5 0.5 Pass

Perfluorotetradecanoic acid (PFTeDA) ug/kg < 0.5 0.5 Pass

Method Blank


Perfluorooctane sulfonamide (FOSA) ug/kg < 0.5 0.5 Pass

N-methylperfluoro-1-octane sulfonamide (N-MeFOSA) ug/kg < 0.5 0.5 Pass

N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA) ug/kg < 0.5 0.5 Pass

2-(N-methylperfluoro-1-octane sulfonamido)-ethanol (N-MeFOSE) ug/kg < 0.5 0.5 Pass

2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE) ug/kg < 0.5 0.5 Pass

N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA) ug/kg < 0.5 0.5 Pass

N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA) ug/kg < 0.5 0.5 Pass

Method Blank


Perfluorobutanesulfonic acid (PFBS) ug/kg < 0.5 0.5 Pass

Perfluoropentanesulfonic acid (PFPeS) ug/kg < 0.5 0.5 Pass

Perfluorohexanesulfonic acid (PFHxS) ug/kg < 0.3 0.3 Pass

Perfluoroheptanesulfonic acid (PFHpS) ug/kg < 0.5 0.5 Pass

Perfluorooctanesulfonic acid (PFOS) ug/kg < 0.3 0.3 Pass

Perfluorodecanesulfonic acid (PFDS) ug/kg < 0.5 0.5 Pass

Method Blank


1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2 FTS) ug/kg < 0.5 0.5 Pass

1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS) ug/kg < 0.5 0.5 Pass

1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2 FTS) ug/kg < 0.5 0.5 Pass

1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2 FTS) ug/kg < 0.5 0.5 Pass

LCS - % Recovery













LCS - % Recovery




ABN : 50 005 085 521 Telephone: +61 7 3902 4600

Page 17 of 22



PassLimits

QualifyingCode








LCS - % Recovery








LCS - % Recovery







LimitsPass

LimitsQualifying

Code

Spike - % Recovery













Spike - % Recovery









Spike - % Recovery




ABN : 50 005 085 521 Telephone: +61 7 3902 4600

Page 18 of 22



LimitsPass

LimitsQualifying

Code







Spike - % Recovery







LimitsPass

LimitsQualifying

Code

Duplicate


Perfluorobutanoic acid (PFBA) B17-De29709 CP ug/kg < 0.5 < 0.5 <1 30% Pass

Perfluoropentanoic acid (PFPeA) B17-De29709 CP ug/kg < 0.5 < 0.5 <1 30% Pass

Perfluorohexanoic acid (PFHxA) B17-De29709 CP ug/kg < 0.5 < 0.5 <1 30% Pass

Perfluoroheptanoic acid (PFHpA) B17-De29709 CP ug/kg < 0.5 < 0.5 <1 30% Pass

Perfluorooctanoic acid (PFOA) B17-De29709 CP ug/kg < 0.5 < 0.5 <1 30% Pass

Perfluorononanoic acid (PFNA) B17-De29709 CP ug/kg < 0.5 < 0.5 <1 30% Pass

Perfluorodecanoic acid (PFDA) B17-De29709 CP ug/kg < 0.5 < 0.5 <1 30% Pass

Perfluoroundecanoic acid (PFUnA) B17-De29709 CP ug/kg < 0.5 < 0.5 <1 30% Pass

Perfluorododecanoic acid (PFDoA) B17-De29709 CP ug/kg < 0.5 < 0.5 <1 30% Pass

Perfluorotridecanoic acid (PFTrDA) B17-De29709 CP ug/kg < 0.5 < 0.5 <1 30% Pass

Perfluorotetradecanoic acid(PFTeDA) B17-De29709 CP ug/kg < 0.5 < 0.5 <1 30% Pass

Duplicate


Perfluorooctane sulfonamide(FOSA) B17-De29709 CP ug/kg < 0.5 < 0.5 <1 30% Pass

N-methylperfluoro-1-octanesulfonamide (N-MeFOSA) B17-De29709 CP ug/kg < 0.5 < 0.5 <1 30% Pass

N-ethylperfluoro-1-octanesulfonamide (N-EtFOSA) B17-De29709 CP ug/kg < 0.5 < 0.5 <1 30% Pass

2-(N-methylperfluoro-1-octanesulfonamido)-ethanol (N-MeFOSE) B17-De29709 CP ug/kg < 0.5 < 0.5 <1 30% Pass

2-(N-ethylperfluoro-1-octanesulfonamido)-ethanol (N-EtFOSE) B17-De29709 CP ug/kg < 0.5 < 0.5 <1 30% Pass

N-ethyl-perfluorooctanesulfonamidoaceticacid (N-EtFOSAA) B17-De29709 CP ug/kg < 0.5 < 0.5 <1 30% Pass

N-methyl-perfluorooctanesulfonamidoaceticacid (N-MeFOSAA) B17-De29709 CP ug/kg < 0.5 < 0.5 <1 30% Pass



ABN : 50 005 085 521 Telephone: +61 7 3902 4600

Page 19 of 22


Duplicate


Perfluorobutanesulfonic acid(PFBS) B17-De29709 CP ug/kg < 0.5 < 0.5 <1 30% Pass

Perfluoropentanesulfonic acid(PFPeS) B17-De29709 CP ug/kg < 0.5 < 0.5 <1 30% Pass

Perfluorohexanesulfonic acid(PFHxS) B17-De29709 CP ug/kg < 0.3 < 0.3 <1 30% Pass

Perfluoroheptanesulfonic acid(PFHpS) B17-De29709 CP ug/kg < 0.5 < 0.5 <1 30% Pass

Perfluorooctanesulfonic acid(PFOS) B17-De29709 CP ug/kg < 0.3 < 0.3 <1 30% Pass

Perfluorodecanesulfonic acid(PFDS) B17-De29709 CP ug/kg < 0.5 < 0.5 <1 30% Pass

Duplicate


1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS) B17-De29709 CP ug/kg < 0.5 < 0.5 <1 30% Pass

1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTS) B17-De29709 CP ug/kg < 0.5 < 0.5 <1 30% Pass

1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS) B17-De29709 CP ug/kg < 0.5 < 0.5 <1 30% Pass

1H.1H.2H.2H-perfluorododecanesulfonic acid(10:2 FTS) B17-De29709 CP ug/kg < 0.5 < 0.5 <1 30% Pass

Duplicate


Perfluorobutanoic acid (PFBA) B17-De29720 CP ug/kg 1.3 1.3 1.0 30% Pass











Duplicate











ABN : 50 005 085 521 Telephone: +61 7 3902 4600

Page 20 of 22


Duplicate


Perfluorobutanesulfonic acid(PFBS) B17-De29720 CP ug/kg 1.4 1.4 3.0 30% Pass

Perfluoropentanesulfonic acid(PFPeS) B17-De29720 CP ug/kg 1.3 1.5 8.0 30% Pass

Perfluorohexanesulfonic acid(PFHxS) B17-De29720 CP ug/kg 5.8 6.4 10 30% Pass


Perfluorooctanesulfonic acid(PFOS) B17-De29720 CP ug/kg 0.8 0.8 <1 30% Pass


Duplicate








ABN : 50 005 085 521 Telephone: +61 7 3902 4600

Page 21 of 22


Comments








Comments



N11


Authorised By



Glenn Jackson







ABN : 50 005 085 521 Telephone: +61 7 3902 4600

Page 22 of 22






Abbotsford

VIC 3067


Report 578759-S




Client Sample ID 0990_IV141_171213

0990_IV142_171213

0990_IV143_171213

0990_IV144_171213

Sample Matrix Insect Insect Insect Insect
















13C4-PFBA (surr.) 1 % 49 60 50 108

13C5-PFPeA (surr.) 1 % 50 168 18 34

13C5-PFHxA (surr.) 1 % 74 72 86 110

13C4-PFHpA (surr.) 1 % 89 63 78 118

13C8-PFOA (surr.) 1 % 110 90 77 124

13C5-PFNA (surr.) 1 % 135 101 102 127

13C6-PFDA (surr.) 1 % 124 97 104 145

13C2-PFUnDA (surr.) 1 % 93 36 97 132

13C2-PFDoDA (surr.) 1 % 126 99 117 117

13C2-PFTeDA (surr.) 1 % 105 67 83 95









13C8-FOSA (surr.) 1 % 43 21 55 106

D3-N-MeFOSA (surr.) 1 % INT INT INT 17



ABN : 50 005 085 521 Telephone: +61 7 3902 4600

Page 1 of 26



0990_IV142_171213

0990_IV143_171213

0990_IV144_171213







D7-N-MeFOSE (surr.) 1 % 39 INT INT 39

D9-N-EtFOSE (surr.) 1 % INT INT INT 41

D5-N-EtFOSAA (surr.) 1 % 192 108 INT INT

D3-N-MeFOSAA (surr.) 1 % INT 182 INT INT






Perfluorooctanesulfonic acid (PFOS)N11 0.3 ug/kg N092.3 N091.4 N090.7 N092.1


13C3-PFBS (surr.) 1 % 84 72 80 92

18O2-PFHxS (surr.) 1 % 77 63 60 80

13C8-PFOS (surr.) 1 % 127 101 99 136






13C2-4:2 FTS (surr.) 1 % 106 113 130 199

13C2-6:2 FTS (surr.) 1 % 178 164 194 INT

13C2-8:2 FTS (surr.) 1 % INT INT INT INT

PFASs Summations

Sum (PFHxS + PFOS)* 0.5 ug/kg 2.3 1.4 0.7 2.1

Sum of US EPA PFAS (PFOS + PFOA)* 0.5 ug/kg 2.3 1.4 0.7 2.1

Sum of enHealth PFAS (PFHxS + PFOS + PFOA)* 0.5 ug/kg 2.3 1.4 0.7 2.1

Sum of WA DER PFAS (n=10)* 0.5 ug/kg 2.3 1.4 0.7 2.1

Sum of PFASs (n=28)* 0.5 ug/kg 2.3 1.4 0.7 2.1


0990_IV146_171213

0990_IV147_171213

0990_IV148_171213 - A

















ABN : 50 005 085 521 Telephone: +61 7 3902 4600

Page 2 of 26



0990_IV146_171213

0990_IV147_171213

0990_IV148_171213 - A








13C4-PFBA (surr.) 1 % 106 44 49 61

13C5-PFPeA (surr.) 1 % 75 30 16 13

13C5-PFHxA (surr.) 1 % 99 54 70 85

13C4-PFHpA (surr.) 1 % 97 70 64 79

13C8-PFOA (surr.) 1 % 111 91 90 77

13C5-PFNA (surr.) 1 % 104 101 90 110

13C6-PFDA (surr.) 1 % 107 109 95 96

13C2-PFUnDA (surr.) 1 % 83 16 120 117

13C2-PFDoDA (surr.) 1 % 75 100 129 130

13C2-PFTeDA (surr.) 1 % 66 34 104 89









13C8-FOSA (surr.) 1 % 84 INT 53 54

D3-N-MeFOSA (surr.) 1 % 54 INT INT INT


D7-N-MeFOSE (surr.) 1 % 88 INT 11 INT

D9-N-EtFOSE (surr.) 1 % 65 INT INT INT

D5-N-EtFOSAA (surr.) 1 % 152 30 INT INT

D3-N-MeFOSAA (surr.) 1 % 146 149 193 INT




Perfluorohexanesulfonic acid (PFHxS)N11 0.3 ug/kg < 0.3 < 0.3 0.3 < 0.3


Perfluorooctanesulfonic acid (PFOS)N11 0.3 ug/kg < 0.3 N094.9 N093.8 N093.5


13C3-PFBS (surr.) 1 % 84 59 67 75

18O2-PFHxS (surr.) 1 % 70 64 60 63

13C8-PFOS (surr.) 1 % 99 113 93 101






13C2-4:2 FTS (surr.) 1 % 150 73 95 144



ABN : 50 005 085 521 Telephone: +61 7 3902 4600

Page 3 of 26



0990_IV146_171213

0990_IV147_171213

0990_IV148_171213 - A






13C2-6:2 FTS (surr.) 1 % 156 156 INT 199

13C2-8:2 FTS (surr.) 1 % 125 INT INT INT

PFASs Summations

Sum (PFHxS + PFOS)* 0.5 ug/kg < 0.5 4.9 4.1 3.5

Sum of US EPA PFAS (PFOS + PFOA)* 0.5 ug/kg < 0.5 4.9 3.8 3.5

Sum of enHealth PFAS (PFHxS + PFOS + PFOA)* 0.5 ug/kg < 0.5 4.9 4.1 3.5

Sum of WA DER PFAS (n=10)* 0.5 ug/kg < 0.5 4.9 4.1 3.5

Sum of PFASs (n=28)* 0.5 ug/kg < 0.5 4.9 4.1 3.5

Client Sample ID 0990_IV148_171213 - B

0990_IV149_171213

0990_IV150_171213

0990_IV151_171213

















13C4-PFBA (surr.) 1 % 56 103 99 51

13C5-PFPeA (surr.) 1 % 13 48 69 75

13C5-PFHxA (surr.) 1 % 93 98 97 71

13C4-PFHpA (surr.) 1 % 82 102 100 104

13C8-PFOA (surr.) 1 % 76 107 107 112

13C5-PFNA (surr.) 1 % 107 120 102 141

13C6-PFDA (surr.) 1 % 91 125 91 117

13C2-PFUnDA (surr.) 1 % 108 123 74 128

13C2-PFDoDA (surr.) 1 % 122 122 79 119

13C2-PFTeDA (surr.) 1 % 88 103 60 90


Perfluorooctane sulfonamide (FOSA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 0.5








ABN : 50 005 085 521 Telephone: +61 7 3902 4600

Page 4 of 26


Client Sample ID 0990_IV148_171213 - B

0990_IV149_171213

0990_IV150_171213

0990_IV151_171213







13C8-FOSA (surr.) 1 % 59 80 86 36


D5-N-EtFOSA (surr.) 1 % 17 39 91 INT


D9-N-EtFOSE (surr.) 1 % INT 20 67 INT

D5-N-EtFOSAA (surr.) 1 % INT INT 135 195

D3-N-MeFOSAA (surr.) 1 % INT INT 133 172


Perfluorobutanesulfonic acid (PFBS)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 0.9

Perfluoropentanesulfonic acid (PFPeS) 0.5 ug/kg < 0.5 < 0.5 < 0.5 N090.9

Perfluorohexanesulfonic acid (PFHxS)N11 0.3 ug/kg < 0.3 < 0.3 < 0.3 N096.9

Perfluoroheptanesulfonic acid (PFHpS) 0.5 ug/kg < 0.5 < 0.5 < 0.5 N091.2

Perfluorooctanesulfonic acid (PFOS)N11 0.3 ug/kg N094.0 N095.5 < 0.3 N0964


13C3-PFBS (surr.) 1 % 78 79 75 84

18O2-PFHxS (surr.) 1 % 60 71 66 78

13C8-PFOS (surr.) 1 % 95 114 87 107




1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 1.6


13C2-4:2 FTS (surr.) 1 % 155 186 170 133

13C2-6:2 FTS (surr.) 1 % INT INT 173 INT

13C2-8:2 FTS (surr.) 1 % INT INT 125 INT

PFASs Summations

Sum (PFHxS + PFOS)* 0.5 ug/kg 4 5.5 < 0.5 70.9

Sum of US EPA PFAS (PFOS + PFOA)* 0.5 ug/kg 4 5.5 < 0.5 64

Sum of enHealth PFAS (PFHxS + PFOS + PFOA)* 0.5 ug/kg 4 5.5 < 0.5 70.9

Sum of WA DER PFAS (n=10)* 0.5 ug/kg 4 5.5 < 0.5 73.4

Sum of PFASs (n=28)* 0.5 ug/kg 4 5.5 < 0.5 76


0990_IV153_171213 - A

0990_IV153_171213 - B

0990_IV153_171213 - C






Perfluorobutanoic acid (PFBA)N11 0.5 ug/kg 4.0 < 0.5 < 0.5 < 0.5


Perfluorohexanoic acid (PFHxA)N11 0.5 ug/kg N091.3 N090.8 N090.8 N090.8


Perfluorooctanoic acid (PFOA)N11 0.5 ug/kg < 0.5 N09< 0.5 N090.5 N090.6



ABN : 50 005 085 521 Telephone: +61 7 3902 4600

Page 5 of 26



0990_IV153_171213 - A

0990_IV153_171213 - B

0990_IV153_171213 - C












13C4-PFBA (surr.) 1 % 51 48 54 52

13C5-PFPeA (surr.) 1 % INT 35 20 15

13C5-PFHxA (surr.) 1 % 79 91 83 96

13C4-PFHpA (surr.) 1 % 69 90 94 96

13C8-PFOA (surr.) 1 % 81 79 82 85

13C5-PFNA (surr.) 1 % 89 117 131 141

13C6-PFDA (surr.) 1 % 71 98 91 101

13C2-PFUnDA (surr.) 1 % 95 127 128 141

13C2-PFDoDA (surr.) 1 % 89 129 133 137

13C2-PFTeDA (surr.) 1 % 42 88 82 80









13C8-FOSA (surr.) 1 % 27 55 50 43

D3-N-MeFOSA (surr.) 1 % INT INT INT INT

D5-N-EtFOSA (surr.) 1 % INT 17 INT 12


D9-N-EtFOSE (surr.) 1 % INT INT INT INT

D5-N-EtFOSAA (surr.) 1 % INT INT INT INT

D3-N-MeFOSAA (surr.) 1 % 198 INT INT INT


Perfluorobutanesulfonic acid (PFBS)N11 0.5 ug/kg 1.3 3.6 3.6 3.4

Perfluoropentanesulfonic acid (PFPeS) 0.5 ug/kg N090.8 N095.9 N097.9 N096.4

Perfluorohexanesulfonic acid (PFHxS)N11 0.3 ug/kg N097.9 N0935 N0946 N0982

Perfluoroheptanesulfonic acid (PFHpS) 0.5 ug/kg N090.7 N091.1 N091.8 N091.9

Perfluorooctanesulfonic acid (PFOS)N11 0.3 ug/kg N09100 N09110 N09160 N09150


13C3-PFBS (surr.) 1 % 70 76 82 79

18O2-PFHxS (surr.) 1 % 57 58 123 106

13C8-PFOS (surr.) 1 % 65 85 90 101



ABN : 50 005 085 521 Telephone: +61 7 3902 4600

Page 6 of 26



0990_IV153_171213 - A

0990_IV153_171213 - B

0990_IV153_171213 - C








1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS)N11 0.5 ug/kg 0.6 0.5 0.7 0.5


13C2-4:2 FTS (surr.) 1 % 119 127 161 158

13C2-6:2 FTS (surr.) 1 % 179 151 185 197


PFASs Summations

Sum (PFHxS + PFOS)* 0.5 ug/kg 107.9 145 206 232

Sum of US EPA PFAS (PFOS + PFOA)* 0.5 ug/kg 100 110 160.5 150.6

Sum of enHealth PFAS (PFHxS + PFOS + PFOA)* 0.5 ug/kg 107.9 145 206.5 232.6




0990_IV155_171213

0990_IV159_171213

0990_IV160_171213

















13C4-PFBA (surr.) 1 % 125 107 44 40

13C5-PFPeA (surr.) 1 % 37 85 92 INT

13C5-PFHxA (surr.) 1 % 137 115 38 85

13C4-PFHpA (surr.) 1 % 146 123 104 96

13C8-PFOA (surr.) 1 % 145 134 110 105

13C5-PFNA (surr.) 1 % 158 126 126 120

13C6-PFDA (surr.) 1 % 158 123 132 129

13C2-PFUnDA (surr.) 1 % 148 104 122 130

13C2-PFDoDA (surr.) 1 % 130 89 116 136

13C2-PFTeDA (surr.) 1 % 111 78 67 52



ABN : 50 005 085 521 Telephone: +61 7 3902 4600

Page 7 of 26



0990_IV155_171213

0990_IV159_171213

0990_IV160_171213













13C8-FOSA (surr.) 1 % 114 114 44 46

D3-N-MeFOSA (surr.) 1 % 34 81 INT INT

D5-N-EtFOSA (surr.) 1 % 92 111 INT INT

D7-N-MeFOSE (surr.) 1 % 19 86 INT INT

D9-N-EtFOSE (surr.) 1 % 38 73 INT INT

D5-N-EtFOSAA (surr.) 1 % INT 171 INT 185

D3-N-MeFOSAA (surr.) 1 % INT 169 177 INT




Perfluorohexanesulfonic acid (PFHxS)N11 0.3 ug/kg N094.9 N091.0 < 0.3 < 0.3


Perfluorooctanesulfonic acid (PFOS)N11 0.3 ug/kg N0920 N092.7 N090.6 < 0.3


13C3-PFBS (surr.) 1 % 108 94 81 90

18O2-PFHxS (surr.) 1 % 93 84 76 86

13C8-PFOS (surr.) 1 % 140 128 137 145






13C2-4:2 FTS (surr.) 1 % INT 171 133 101



PFASs Summations

Sum (PFHxS + PFOS)* 0.5 ug/kg 24.9 3.7 0.6 < 0.5

Sum of US EPA PFAS (PFOS + PFOA)* 0.5 ug/kg 20 2.7 0.6 < 0.5






ABN : 50 005 085 521 Telephone: +61 7 3902 4600

Page 8 of 26


Client Sample ID 0990_IV161_171213 - A

0990_IV161_171213 - B

0990_IV161_171213 - C

0990_IV162_171213

















13C4-PFBA (surr.) 1 % 34 37 38 53

13C5-PFPeA (surr.) 1 % 14 14 19 79

13C5-PFHxA (surr.) 1 % 84 95 105 106

13C4-PFHpA (surr.) 1 % 97 112 122 115

13C8-PFOA (surr.) 1 % 74 81 90 117

13C5-PFNA (surr.) 1 % 117 137 145 104

13C6-PFDA (surr.) 1 % 120 143 158 116

13C2-PFUnDA (surr.) 1 % 109 133 154 100

13C2-PFDoDA (surr.) 1 % 101 126 143 70

13C2-PFTeDA (surr.) 1 % 45 55 60 19









13C8-FOSA (surr.) 1 % 39 46 47 64

D3-N-MeFOSA (surr.) 1 % INT INT INT 17

D5-N-EtFOSA (surr.) 1 % 11 14 13 20


D9-N-EtFOSE (surr.) 1 % INT INT INT 17

D5-N-EtFOSAA (surr.) 1 % 170 INT INT 127

D3-N-MeFOSAA (surr.) 1 % 138 170 174 139








13C3-PFBS (surr.) 1 % 82 94 103 103

18O2-PFHxS (surr.) 1 % 71 79 85 79

13C8-PFOS (surr.) 1 % 127 144 159 132



ABN : 50 005 085 521 Telephone: +61 7 3902 4600

Page 9 of 26


Client Sample ID 0990_IV161_171213 - A

0990_IV161_171213 - B

0990_IV161_171213 - C

0990_IV162_171213










13C2-4:2 FTS (surr.) 1 % 97 106 122 154

13C2-6:2 FTS (surr.) 1 % 151 189 INT INT


PFASs Summations

Sum (PFHxS + PFOS)* 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5

Sum of US EPA PFAS (PFOS + PFOA)* 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5

Sum of enHealth PFAS (PFHxS + PFOS + PFOA)* 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5

Sum of WA DER PFAS (n=10)* 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5

Sum of PFASs (n=28)* 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5


Sample Matrix Insect





Perfluorobutanoic acid (PFBA)N11 0.5 ug/kg < 0.5

Perfluoropentanoic acid (PFPeA)N11 0.5 ug/kg < 0.5

Perfluorohexanoic acid (PFHxA)N11 0.5 ug/kg < 0.5

Perfluoroheptanoic acid (PFHpA)N11 0.5 ug/kg < 0.5

Perfluorooctanoic acid (PFOA)N11 0.5 ug/kg < 0.5

Perfluorononanoic acid (PFNA)N11 0.5 ug/kg < 0.5

Perfluorodecanoic acid (PFDA)N11 0.5 ug/kg < 0.5

Perfluoroundecanoic acid (PFUnA)N11 0.5 ug/kg < 0.5

Perfluorododecanoic acid (PFDoA)N11 0.5 ug/kg < 0.5

Perfluorotridecanoic acid (PFTrDA) 0.5 ug/kg < 0.5

Perfluorotetradecanoic acid (PFTeDA)N11 0.5 ug/kg < 0.5

13C4-PFBA (surr.) 1 % 51

13C5-PFPeA (surr.) 1 % 63

13C5-PFHxA (surr.) 1 % 83

13C4-PFHpA (surr.) 1 % 87

13C8-PFOA (surr.) 1 % 86

13C5-PFNA (surr.) 1 % 54

13C6-PFDA (surr.) 1 % 65

13C2-PFUnDA (surr.) 1 % 52

13C2-PFDoDA (surr.) 1 % 33

13C2-PFTeDA (surr.) 1 % 16



ABN : 50 005 085 521 Telephone: +61 7 3902 4600

Page 10 of 26



Sample Matrix Insect





Perfluorooctane sulfonamide (FOSA)N11 0.5 ug/kg < 0.5

N-methylperfluoro-1-octane sulfonamide (N-MeFOSA)N11 0.5 ug/kg < 0.5

N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA)N11 0.5 ug/kg < 0.5

2-(N-methylperfluoro-1-octane sulfonamido)-ethanol(N-MeFOSE)N11 0.5 ug/kg < 0.5

2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE)N11 0.5 ug/kg < 0.5

N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA)N11 0.5 ug/kg < 0.5

N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA)N11 0.5 ug/kg < 0.5

13C8-FOSA (surr.) 1 % 13

D3-N-MeFOSA (surr.) 1 % INT

D5-N-EtFOSA (surr.) 1 % INT

D7-N-MeFOSE (surr.) 1 % INT

D9-N-EtFOSE (surr.) 1 % INT

D5-N-EtFOSAA (surr.) 1 % 57

D3-N-MeFOSAA (surr.) 1 % 71


Perfluorobutanesulfonic acid (PFBS)N11 0.5 ug/kg < 0.5

Perfluoropentanesulfonic acid (PFPeS) 0.5 ug/kg < 0.5

Perfluorohexanesulfonic acid (PFHxS)N11 0.3 ug/kg < 0.3

Perfluoroheptanesulfonic acid (PFHpS) 0.5 ug/kg < 0.5

Perfluorooctanesulfonic acid (PFOS)N11 0.3 ug/kg < 0.3

Perfluorodecanesulfonic acid (PFDS) 0.5 ug/kg < 0.5

13C3-PFBS (surr.) 1 % 90

18O2-PFHxS (surr.) 1 % 60

13C8-PFOS (surr.) 1 % 72


1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS)N11 0.5 ug/kg < 0.5

1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS)N11 0.5 ug/kg < 0.5

1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS)N11 0.5 ug/kg < 0.5

1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2FTS) 0.5 ug/kg < 0.5

13C2-4:2 FTS (surr.) 1 % 170

13C2-6:2 FTS (surr.) 1 % INT

13C2-8:2 FTS (surr.) 1 % INT

PFASs Summations

Sum (PFHxS + PFOS)* 0.5 ug/kg < 0.5

Sum of US EPA PFAS (PFOS + PFOA)* 0.5 ug/kg < 0.5

Sum of enHealth PFAS (PFHxS + PFOS + PFOA)* 0.5 ug/kg < 0.5

Sum of WA DER PFAS (n=10)* 0.5 ug/kg < 0.5

Sum of PFASs (n=28)* 0.5 ug/kg < 0.5



ABN : 50 005 085 521 Telephone: +61 7 3902 4600

Page 11 of 26
















ABN : 50 005 085 521 Telephone: +61 7 3902 4600

Page 12 of 26


.Company Name: Coffey Environments Pty Ltd VIC Order No.: Received: Dec 20, 2017 3:17 PMAddress: Level 1, 436 Johnston Street Report #: 578759 Due: Jan 8, 2018




Sample Detail

HO

LD

Per- and P


ubstances(P

FA

Ss)



Brisbane Laboratory - NATA Site # 20794 X X


External Laboratory


Matrix LAB ID

1 0990_IV141_171213

Dec 13, 2017 Insect B17-De30470 X

2 0990_IV142_171213

Dec 13, 2017 Insect B17-De30471 X

3 0990_IV143_171213

Dec 13, 2017 Insect B17-De30472 X

4 0990_IV144_171213

Dec 13, 2017 Insect B17-De30473 X

5 0990_IV145_171213

Dec 13, 2017 Insect B17-De30474 X

6 0990_IV146_1 Dec 13, 2017 Insect B17-De30476 X








ABN : 50 005 085 521 Telephone: +61 7 3902 4600

Page 13 of 26






Sample Detail

HO

LD

Per- and P


ubstances(P

FA

Ss)





71213

7 0990_IV147_171213

Dec 13, 2017 Insect B17-De30477 X

8 0990_IV148_171213 - A

Dec 13, 2017 Insect B17-De30478 X

9 0990_IV148_171213 - B

Dec 13, 2017 Insect B17-De30479 X

10 0990_IV149_171213

Dec 13, 2017 Insect B17-De30480 X

11 0990_IV150_171213

Dec 13, 2017 Insect B17-De30481 X

12 0990_IV151_171213

Dec 13, 2017 Insect B17-De30482 X









ABN : 50 005 085 521 Telephone: +61 7 3902 4600

Page 14 of 26






Sample Detail

HO

LD

Per- and P


ubstances(P

FA

Ss)





71213

14 0990_IV153_171213 - A

Dec 13, 2017 Insect B17-De30484 X

15 0990_IV153_171213 - B

Dec 13, 2017 Insect B17-De30485 X

16 0990_IV153_171213 - C

Dec 13, 2017 Insect B17-De30486 X

17 0990_IV154_171213

Dec 13, 2017 Insect B17-De30487 X

18 0990_IV155_171213

Dec 13, 2017 Insect B17-De30488 X

19 0990_IV159_171213

Dec 13, 2017 Insect B17-De30489 X









ABN : 50 005 085 521 Telephone: +61 7 3902 4600

Page 15 of 26






Sample Detail

HO

LD

Per- and P


ubstances(P

FA

Ss)





71213

21 0990_IV161_171213 - A

Dec 13, 2017 Insect B17-De30491 X

22 0990_IV161_171213 - B

Dec 13, 2017 Insect B17-De30492 X

23 0990_IV161_171213 - C

Dec 13, 2017 Insect B17-De30493 X

24 0990_IV162_171213

Dec 13, 2017 Insect B17-De30494 X

25 0990_IV163_171213

Dec 13, 2017 Insect B17-De30495 X

26 0990_IV156_171213

Dec 13, 2017 Insect B17-De30496 X









ABN : 50 005 085 521 Telephone: +61 7 3902 4600

Page 16 of 26






Sample Detail

HO

LD

Per- and P


ubstances(P

FA

Ss)





71213

28 0990_IV158_171213

Dec 13, 2017 Insect B17-De30498 X

Test Counts 3 25








ABN : 50 005 085 521 Telephone: +61 7 3902 4600

Page 17 of 26



General

Holding Times

Units

Terms




request.










Receipt Advice.

































affected.

















ABN : 50 005 085 521 Telephone: +61 7 3902 4600

Page 18 of 26




PassLimits

QualifyingCode

Method Blank









Perfluoroundecanoic acid (PFUnA) ug/kg < 0.5 0.5 Pass

Perfluorododecanoic acid (PFDoA) ug/kg < 0.5 0.5 Pass



Method Blank









Method Blank








Method Blank


1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2 FTS) ug/kg < 0.5 0.5 Pass

1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS) ug/kg < 0.5 0.5 Pass

1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2 FTS) ug/kg < 0.5 0.5 Pass

1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2 FTS) ug/kg < 0.5 0.5 Pass

LCS - % Recovery













LCS - % Recovery




ABN : 50 005 085 521 Telephone: +61 7 3902 4600

Page 19 of 26



PassLimits

QualifyingCode








LCS - % Recovery








LCS - % Recovery







LimitsPass

LimitsQualifying

Code

Spike - % Recovery













Spike - % Recovery









Spike - % Recovery




ABN : 50 005 085 521 Telephone: +61 7 3902 4600

Page 20 of 26



LimitsPass

LimitsQualifying

Code







Spike - % Recovery






Spike - % Recovery













Spike - % Recovery









Spike - % Recovery





ABN : 50 005 085 521 Telephone: +61 7 3902 4600

Page 21 of 26



LimitsPass

LimitsQualifying

Code






Spike - % Recovery







LimitsPass

LimitsQualifying

Code

Duplicate













Duplicate


Perfluorooctane sulfonamide(FOSA) B17-De30482 CP ug/kg 0.5 < 0.5 25 30% Pass









ABN : 50 005 085 521 Telephone: +61 7 3902 4600

Page 22 of 26


Duplicate


Perfluorobutanesulfonic acid(PFBS) B17-De30482 CP ug/kg 0.9 0.7 21 30% Pass

Perfluoropentanesulfonic acid(PFPeS) B17-De30482 CP ug/kg 0.9 0.8 13 30% Pass

Perfluorohexanesulfonic acid(PFHxS) B17-De30482 CP ug/kg 6.9 6.1 13 30% Pass

Perfluoroheptanesulfonic acid(PFHpS) B17-De30482 CP ug/kg 1.2 0.9 22 30% Pass

Perfluorooctanesulfonic acid(PFOS) B17-De30482 CP ug/kg 64 72 12 30% Pass


Duplicate




1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS) B17-De30482 CP ug/kg 1.6 1.3 19 30% Pass


Duplicate













Duplicate











ABN : 50 005 085 521 Telephone: +61 7 3902 4600

Page 23 of 26


Duplicate






Perfluorooctanesulfonic acid(PFOS) B17-De30489 CP ug/kg 0.6 0.8 22 30% Pass


Duplicate






Duplicate













Duplicate











ABN : 50 005 085 521 Telephone: +61 7 3902 4600

Page 24 of 26


Duplicate






Perfluorooctanesulfonic acid(PFOS) B17-De30495 CP ug/kg < 0.3 < 0.3 <1 30% Pass


Duplicate








ABN : 50 005 085 521 Telephone: +61 7 3902 4600

Page 25 of 26


Comments








Comments



N11


Authorised By



Glenn Jackson







ABN : 50 005 085 521 Telephone: +61 7 3902 4600

Page 26 of 26






Abbotsford

VIC 3067


Report 592492-W



Received Date Apr 05, 2018

Client Sample ID 0990_QCTV001_180328

0990_QCTV002_180328

0990_QCTV003_180328

Sample Matrix Water Water Water

Eurofins | mgt Sample No. B18-Ap03751 B18-Ap03752 B18-Ap03753

Date Sampled Mar 28, 2018 Mar 28, 2018 Mar 28, 2018



Perfluorobutanoic acid (PFBA)N11 0.05 ug/L < 0.05 < 0.05 < 0.05

Perfluoropentanoic acid (PFPeA)N11 0.01 ug/L < 0.01 < 0.01 < 0.01

Perfluorohexanoic acid (PFHxA)N11 0.01 ug/L < 0.01 < 0.01 < 0.01

Perfluoroheptanoic acid (PFHpA)N11 0.01 ug/L < 0.01 < 0.01 < 0.01

Perfluorooctanoic acid (PFOA)N11 0.01 ug/L < 0.01 < 0.01 < 0.01

Perfluorononanoic acid (PFNA)N11 0.01 ug/L < 0.01 < 0.01 < 0.01

Perfluorodecanoic acid (PFDA)N11 0.01 ug/L < 0.01 < 0.01 < 0.01

Perfluoroundecanoic acid (PFUnDA)N11 0.01 ug/L < 0.01 < 0.01 < 0.01

Perfluorododecanoic acid (PFDoDA)N11 0.01 ug/L < 0.01 < 0.01 < 0.01

Perfluorotridecanoic acid (PFTrDA)N15 0.01 ug/L < 0.01 < 0.01 < 0.01

Perfluorotetradecanoic acid (PFTeDA)N11 0.01 ug/L < 0.01 < 0.01 < 0.01

13C4-PFBA (surr.) 1 % 84 83 94

13C5-PFPeA (surr.) 1 % 145 139 127

13C5-PFHxA (surr.) 1 % 119 119 120

13C4-PFHpA (surr.) 1 % 104 101 95

13C8-PFOA (surr.) 1 % 100 97 91

13C5-PFNA (surr.) 1 % 130 117 113

13C6-PFDA (surr.) 1 % 111 90 86

13C2-PFUnDA (surr.) 1 % 67 53 57

13C2-PFDoDA (surr.) 1 % 65 63 65

13C2-PFTeDA (surr.) 1 % 60 68 67

Perfluoroalkane sulfonamido substances

Perfluorooctane sulfonamide (FOSA)N11 0.05 ug/L < 0.05 < 0.05 < 0.05

N-methylperfluoro-1-octane sulfonamide (N-MeFOSA)N11 0.05 ug/L < 0.05 < 0.05 < 0.05

N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA)N11 0.05 ug/L < 0.05 < 0.05 < 0.05

2-(N-methylperfluoro-1-octane sulfonamido)-ethanol(N-MeFOSE)N11 0.05 ug/L < 0.05 < 0.05 < 0.05

2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE)N11 0.05 ug/L < 0.05 < 0.05 < 0.05

N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA)N11 0.05 ug/L < 0.05 < 0.05 < 0.05

N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA)N11 0.05 ug/L < 0.05 < 0.05 < 0.05

13C8-FOSA (surr.) 1 % 83 78 69

D3-N-MeFOSA (surr.) 1 % 75 70 61

Date Reported: Apr 13, 2018


ABN : 50 005 085 521 Telephone: +61 7 3902 4600

Page 1 of 12




Client Sample ID 0990_QCTV001_180328

0990_QCTV002_180328

0990_QCTV003_180328

Sample Matrix Water Water Water





D5-N-EtFOSA (surr.) 1 % 83 71 64

D7-N-MeFOSE (surr.) 1 % 58 60 54

D9-N-EtFOSE (surr.) 1 % 53 53 50

D5-N-EtFOSAA (surr.) 1 % 94 76 73

D3-N-MeFOSAA (surr.) 1 % 94 73 73

Perfluoroalkane sulfonic acids (PFSAs)

Perfluorobutanesulfonic acid (PFBS)N11 0.01 ug/L < 0.01 < 0.01 < 0.01

Perfluoropentanesulfonic acid (PFPeS)N15 0.01 ug/L < 0.01 < 0.01 < 0.01

Perfluorohexanesulfonic acid (PFHxS)N11 0.01 ug/L < 0.01 < 0.01 < 0.01

Perfluoroheptanesulfonic acid (PFHpS)N15 0.01 ug/L < 0.01 < 0.01 < 0.01

Perfluorooctanesulfonic acid (PFOS)N11 0.01 ug/L < 0.01 < 0.01 < 0.01

Perfluorodecanesulfonic acid (PFDS)N15 0.01 ug/L < 0.01 < 0.01 < 0.01

13C3-PFBS (surr.) 1 % 96 96 96

18O2-PFHxS (surr.) 1 % 102 103 102

13C8-PFOS (surr.) 1 % 131 109 105

n:2 Fluorotelomer sulfonic acids (n:2 FTSAs)

1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTSA)N11 0.01 ug/L < 0.01 < 0.01 < 0.01

1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTSA)N11 0.05 ug/L < 0.05 < 0.05 < 0.05

1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTSA)N11 0.01 ug/L < 0.01 < 0.01 < 0.01

1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2FTSA)N15 0.01 ug/L < 0.01 < 0.01 < 0.01

13C2-4:2 FTSA (surr.) 1 % 89 94 72

13C2-6:2 FTSA (surr.) 1 % 115 116 90

13C2-8:2 FTSA (surr.) 1 % 119 102 85

PFASs Summations

Sum (PFHxS + PFOS)* 0.01 ug/L < 0.01 < 0.01 < 0.01

Sum of US EPA PFAS (PFOS + PFOA)* 0.01 ug/L < 0.01 < 0.01 < 0.01

Sum of enHealth PFAS (PFHxS + PFOS + PFOA)* 0.01 ug/L < 0.01 < 0.01 < 0.01

Sum of WA DER PFAS (n=10)* 0.05 ug/L < 0.05 < 0.05 < 0.05

Sum of PFASs (n=28)* 0.1 ug/L < 0.1 < 0.1 < 0.1



ABN : 50 005 085 521 Telephone: +61 7 3902 4600

Page 2 of 12






Perfluoroalkyl carboxylic acids (PFCAs) Brisbane Apr 05, 2018 14 Day

- Method: LTM-ORG-2100 Per- and Polyfluoro Alkyl Substances (PFAS)

Perfluoroalkane sulfonamido substances Brisbane Apr 05, 2018 14 Day


Perfluoroalkane sulfonic acids (PFSAs) Brisbane Apr 05, 2018 14 Day


n:2 Fluorotelomer sulfonic acids (n:2 FTSAs) Brisbane Apr 05, 2018 14 Day




ABN : 50 005 085 521 Telephone: +61 7 3902 4600

Page 3 of 12


.Company Name: Coffey Environments Pty Ltd VIC Order No.: Received: Apr 5, 2018 9:00 AMAddress: Level 1, 436 Johnston Street Report #: 592492 Due: Apr 12, 2018




Sample Detail

Per- and P


ubstances(P

FA

Ss)





External Laboratory


Matrix LAB ID

1 0990_QCTV001_180328

Mar 28, 2018 5:00PM Water B18-Ap03751 X

2 0990_QCTV002_180328

Mar 28, 2018 5:00PM Water B18-Ap03752 X

3 0990_QCTV003_180328

Mar 28, 2018 5:00PM Water B18-Ap03753 X

Test Counts 3






Date Reported:Apr 13, 2018


ABN : 50 005 085 521 Telephone: +61 7 3902 4600

Page 4 of 12



General

Holding Times

Units

Terms




request.


3. All biota/food results are reported on a wet weight basis on the edible portion, unless otherwise stated.







For samples received on the last day of holding time, notification of testing requirements should have been received at least 6 hours prior to sample receipt deadlines as stated on the SRA.



For VOCs containing vinyl chloride, styrene and 2-chloroethyl vinyl ether the holding time is 7 days however for all other VOCs such as BTEX or C6-10 TRH then the holding time is 14 days.


mg/kg: milligrams per kilogram mg/L: milligrams per litre ug/L: micrograms per litre

ppm: Parts per million ppb: Parts per billion %: Percentage

org/100mL: Organisms per 100 millilitres NTU: Nephelometric Turbidity Units MPN/100mL: Most Probable Number of organisms per 100 millilitres

























affected.

















ABN : 50 005 085 521 Telephone: +61 7 3902 4600

Page 5 of 12




PassLimits

QualifyingCode

Method Blank


Perfluorobutanoic acid (PFBA) ug/L < 0.05 0.05 Pass

Perfluoropentanoic acid (PFPeA) ug/L < 0.01 0.01 Pass

Perfluorohexanoic acid (PFHxA) ug/L < 0.01 0.01 Pass

Perfluoroheptanoic acid (PFHpA) ug/L < 0.01 0.01 Pass

Perfluorooctanoic acid (PFOA) ug/L < 0.01 0.01 Pass

Perfluorononanoic acid (PFNA) ug/L < 0.01 0.01 Pass

Perfluorodecanoic acid (PFDA) ug/L < 0.01 0.01 Pass

Perfluoroundecanoic acid (PFUnDA) ug/L < 0.01 0.01 Pass

Perfluorododecanoic acid (PFDoDA) ug/L < 0.01 0.01 Pass

Perfluorotridecanoic acid (PFTrDA) ug/L < 0.01 0.01 Pass

Perfluorotetradecanoic acid (PFTeDA) ug/L < 0.01 0.01 Pass

Method Blank


Perfluorooctane sulfonamide (FOSA) ug/L < 0.05 0.05 Pass

N-methylperfluoro-1-octane sulfonamide (N-MeFOSA) ug/L < 0.05 0.05 Pass

N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA) ug/L < 0.05 0.05 Pass

2-(N-methylperfluoro-1-octane sulfonamido)-ethanol (N-MeFOSE) ug/L < 0.05 0.05 Pass

2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE) ug/L < 0.05 0.05 Pass

N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA) ug/L < 0.05 0.05 Pass

N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA) ug/L < 0.05 0.05 Pass

Method Blank


Perfluorobutanesulfonic acid (PFBS) ug/L < 0.01 0.01 Pass

Perfluoropentanesulfonic acid (PFPeS) ug/L < 0.01 0.01 Pass

Perfluorohexanesulfonic acid (PFHxS) ug/L < 0.01 0.01 Pass

Perfluoroheptanesulfonic acid (PFHpS) ug/L < 0.01 0.01 Pass

Perfluorooctanesulfonic acid (PFOS) ug/L < 0.01 0.01 Pass

Perfluorodecanesulfonic acid (PFDS) ug/L < 0.01 0.01 Pass

Method Blank


1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2 FTSA) ug/L < 0.01 0.01 Pass

1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTSA) ug/L < 0.05 0.05 Pass

1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2 FTSA) ug/L < 0.01 0.01 Pass

1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2 FTSA) ug/L < 0.01 0.01 Pass

LCS - % Recovery









Perfluoroundecanoic acid (PFUnDA) % 98 50-150 Pass

Perfluorododecanoic acid (PFDoDA) % 106 50-150 Pass



LCS - % Recovery




ABN : 50 005 085 521 Telephone: +61 7 3902 4600

Page 6 of 12



PassLimits

QualifyingCode








LCS - % Recovery








LCS - % Recovery


1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2 FTSA) % 104 50-150 Pass

1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTSA) % 96 50-150 Pass

1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2 FTSA) % 96 50-150 Pass

1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2 FTSA) % 106 50-150 Pass


LimitsPass

LimitsQualifying

Code

Spike - % Recovery


Perfluorobutanoic acid (PFBA) B18-Ap03752 CP % 93 50-150 Pass

Perfluoropentanoic acid (PFPeA) B18-Ap03752 CP % 95 50-150 Pass

Perfluorohexanoic acid (PFHxA) B18-Ap03752 CP % 118 50-150 Pass

Perfluoroheptanoic acid (PFHpA) B18-Ap03752 CP % 104 50-150 Pass

Perfluorooctanoic acid (PFOA) B18-Ap03752 CP % 112 50-150 Pass

Perfluorononanoic acid (PFNA) B18-Ap03752 CP % 110 50-150 Pass

Perfluorodecanoic acid (PFDA) B18-Ap03752 CP % 99 50-150 Pass

Perfluoroundecanoic acid(PFUnDA) B18-Ap03752 CP % 98 50-150 Pass

Perfluorododecanoic acid(PFDoDA) B18-Ap03752 CP % 103 50-150 Pass

Perfluorotridecanoic acid (PFTrDA) B18-Ap03752 CP % 82 50-150 Pass

Perfluorotetradecanoic acid(PFTeDA) B18-Ap03752 CP % 84 50-150 Pass

Spike - % Recovery

Perfluoroalkane sulfonamido substances Result 1

Perfluorooctane sulfonamide(FOSA) B18-Ap03752 CP % 108 50-150 Pass

N-methylperfluoro-1-octanesulfonamide (N-MeFOSA) B18-Ap03752 CP % 84 50-150 Pass

N-ethylperfluoro-1-octanesulfonamide (N-EtFOSA) B18-Ap03752 CP % 82 50-150 Pass

2-(N-methylperfluoro-1-octanesulfonamido)-ethanol (N-MeFOSE) B18-Ap03752 CP % 97 50-150 Pass

2-(N-ethylperfluoro-1-octanesulfonamido)-ethanol (N-EtFOSE) B18-Ap03752 CP % 106 50-150 Pass

N-ethyl-perfluorooctanesulfonamidoaceticacid (N-EtFOSAA) B18-Ap03752 CP % 106 50-150 Pass

N-methyl-perfluorooctanesulfonamidoaceticacid (N-MeFOSAA) B18-Ap03752 CP % 105 50-150 Pass

Spike - % Recovery



ABN : 50 005 085 521 Telephone: +61 7 3902 4600

Page 7 of 12



LimitsPass

LimitsQualifying

Code

Perfluoroalkane sulfonic acids (PFSAs) Result 1

Perfluorobutanesulfonic acid(PFBS) B18-Ap03752 CP % 110 50-150 Pass

Perfluoropentanesulfonic acid(PFPeS) B18-Ap03752 CP % 103 50-150 Pass

Perfluorohexanesulfonic acid(PFHxS) B18-Ap03752 CP % 105 50-150 Pass

Perfluoroheptanesulfonic acid(PFHpS) B18-Ap03752 CP % 106 50-150 Pass

Perfluorooctanesulfonic acid(PFOS) B18-Ap03752 CP % 99 50-150 Pass

Perfluorodecanesulfonic acid(PFDS) B18-Ap03752 CP % 108 50-150 Pass

Spike - % Recovery

n:2 Fluorotelomer sulfonic acids (n:2 FTSAs) Result 1

1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTSA) B18-Ap03752 CP % 103 50-150 Pass

1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTSA) B18-Ap03752 CP % 104 50-150 Pass

1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTSA) B18-Ap03752 CP % 95 50-150 Pass

1H.1H.2H.2H-perfluorododecanesulfonic acid(10:2 FTSA) B18-Ap03752 CP % 102 50-150 Pass


LimitsPass

LimitsQualifying

Code

Duplicate


Perfluorobutanoic acid (PFBA) B18-Ap03751 CP ug/L < 0.05 < 0.05 <1 30% Pass

Perfluoropentanoic acid (PFPeA) B18-Ap03751 CP ug/L < 0.01 < 0.01 <1 30% Pass

Perfluorohexanoic acid (PFHxA) B18-Ap03751 CP ug/L < 0.01 < 0.01 <1 30% Pass

Perfluoroheptanoic acid (PFHpA) B18-Ap03751 CP ug/L < 0.01 < 0.01 <1 30% Pass

Perfluorooctanoic acid (PFOA) B18-Ap03751 CP ug/L < 0.01 < 0.01 <1 30% Pass

Perfluorononanoic acid (PFNA) B18-Ap03751 CP ug/L < 0.01 < 0.01 <1 30% Pass

Perfluorodecanoic acid (PFDA) B18-Ap03751 CP ug/L < 0.01 < 0.01 <1 30% Pass

Perfluoroundecanoic acid(PFUnDA) B18-Ap03751 CP ug/L < 0.01 < 0.01 <1 30% Pass

Perfluorododecanoic acid(PFDoDA) B18-Ap03751 CP ug/L < 0.01 < 0.01 <1 30% Pass

Perfluorotridecanoic acid (PFTrDA) B18-Ap03751 CP ug/L < 0.01 < 0.01 <1 30% Pass

Perfluorotetradecanoic acid(PFTeDA) B18-Ap03751 CP ug/L < 0.01 < 0.01 <1 30% Pass

Duplicate

Perfluoroalkane sulfonamido substances Result 1 Result 2 RPD

Perfluorooctane sulfonamide(FOSA) B18-Ap03751 CP ug/L < 0.05 < 0.05 <1 30% Pass

N-methylperfluoro-1-octanesulfonamide (N-MeFOSA) B18-Ap03751 CP ug/L < 0.05 < 0.05 <1 30% Pass

N-ethylperfluoro-1-octanesulfonamide (N-EtFOSA) B18-Ap03751 CP ug/L < 0.05 < 0.05 <1 30% Pass

2-(N-methylperfluoro-1-octanesulfonamido)-ethanol (N-MeFOSE) B18-Ap03751 CP ug/L < 0.05 < 0.05 <1 30% Pass

2-(N-ethylperfluoro-1-octanesulfonamido)-ethanol (N-EtFOSE) B18-Ap03751 CP ug/L < 0.05 < 0.05 <1 30% Pass

N-ethyl-perfluorooctanesulfonamidoaceticacid (N-EtFOSAA) B18-Ap03751 CP ug/L < 0.05 < 0.05 <1 30% Pass

N-methyl-perfluorooctanesulfonamidoaceticacid (N-MeFOSAA) B18-Ap03751 CP ug/L < 0.05 < 0.05 <1 30% Pass



ABN : 50 005 085 521 Telephone: +61 7 3902 4600

Page 8 of 12


Duplicate

Perfluoroalkane sulfonic acids (PFSAs) Result 1 Result 2 RPD

Perfluorobutanesulfonic acid(PFBS) B18-Ap03751 CP ug/L < 0.01 < 0.01 <1 30% Pass

Perfluoropentanesulfonic acid(PFPeS) B18-Ap03751 CP ug/L < 0.01 < 0.01 <1 30% Pass

Perfluorohexanesulfonic acid(PFHxS) B18-Ap03751 CP ug/L < 0.01 < 0.01 <1 30% Pass

Perfluoroheptanesulfonic acid(PFHpS) B18-Ap03751 CP ug/L < 0.01 < 0.01 <1 30% Pass

Perfluorooctanesulfonic acid(PFOS) B18-Ap03751 CP ug/L < 0.01 < 0.01 <1 30% Pass

Perfluorodecanesulfonic acid(PFDS) B18-Ap03751 CP ug/L < 0.01 < 0.01 <1 30% Pass

Duplicate

n:2 Fluorotelomer sulfonic acids (n:2 FTSAs) Result 1 Result 2 RPD

1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTSA) B18-Ap03751 CP ug/L < 0.01 < 0.01 <1 30% Pass

1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTSA) B18-Ap03751 CP ug/L < 0.05 < 0.05 <1 30% Pass

1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTSA) B18-Ap03751 CP ug/L < 0.01 < 0.01 <1 30% Pass

1H.1H.2H.2H-perfluorododecanesulfonic acid(10:2 FTSA) B18-Ap03751 CP ug/L < 0.01 < 0.01 <1 30% Pass

Duplicate


Perfluorobutanoic acid (PFBA) B18-Ap03753 CP ug/L < 0.05 < 0.05 <1 30% Pass

Perfluoropentanoic acid (PFPeA) B18-Ap03753 CP ug/L < 0.01 < 0.01 <1 30% Pass

Perfluorohexanoic acid (PFHxA) B18-Ap03753 CP ug/L < 0.01 < 0.01 <1 30% Pass

Perfluoroheptanoic acid (PFHpA) B18-Ap03753 CP ug/L < 0.01 < 0.01 <1 30% Pass

Perfluorooctanoic acid (PFOA) B18-Ap03753 CP ug/L < 0.01 < 0.01 <1 30% Pass

Perfluorononanoic acid (PFNA) B18-Ap03753 CP ug/L < 0.01 < 0.01 <1 30% Pass

Perfluorodecanoic acid (PFDA) B18-Ap03753 CP ug/L < 0.01 < 0.01 <1 30% Pass

Perfluoroundecanoic acid(PFUnDA) B18-Ap03753 CP ug/L < 0.01 < 0.01 <1 30% Pass

Perfluorododecanoic acid(PFDoDA) B18-Ap03753 CP ug/L < 0.01 < 0.01 <1 30% Pass

Perfluorotridecanoic acid (PFTrDA) B18-Ap03753 CP ug/L < 0.01 < 0.01 <1 30% Pass

Perfluorotetradecanoic acid(PFTeDA) B18-Ap03753 CP ug/L < 0.01 < 0.01 <1 30% Pass

Duplicate

Perfluoroalkane sulfonamido substances Result 1 Result 2 RPD

Perfluorooctane sulfonamide(FOSA) B18-Ap03753 CP ug/L < 0.05 < 0.05 <1 30% Pass

N-methylperfluoro-1-octanesulfonamide (N-MeFOSA) B18-Ap03753 CP ug/L < 0.05 < 0.05 <1 30% Pass

N-ethylperfluoro-1-octanesulfonamide (N-EtFOSA) B18-Ap03753 CP ug/L < 0.05 < 0.05 <1 30% Pass

2-(N-methylperfluoro-1-octanesulfonamido)-ethanol (N-MeFOSE) B18-Ap03753 CP ug/L < 0.05 < 0.05 <1 30% Pass

2-(N-ethylperfluoro-1-octanesulfonamido)-ethanol (N-EtFOSE) B18-Ap03753 CP ug/L < 0.05 < 0.05 <1 30% Pass

N-ethyl-perfluorooctanesulfonamidoaceticacid (N-EtFOSAA) B18-Ap03753 CP ug/L < 0.05 < 0.05 <1 30% Pass

N-methyl-perfluorooctanesulfonamidoaceticacid (N-MeFOSAA) B18-Ap03753 CP ug/L < 0.05 < 0.05 <1 30% Pass



ABN : 50 005 085 521 Telephone: +61 7 3902 4600

Page 9 of 12


Duplicate

Perfluoroalkane sulfonic acids (PFSAs) Result 1 Result 2 RPD

Perfluorobutanesulfonic acid(PFBS) B18-Ap03753 CP ug/L < 0.01 < 0.01 <1 30% Pass

Perfluoropentanesulfonic acid(PFPeS) B18-Ap03753 CP ug/L < 0.01 < 0.01 <1 30% Pass

Perfluorohexanesulfonic acid(PFHxS) B18-Ap03753 CP ug/L < 0.01 < 0.01 <1 30% Pass

Perfluoroheptanesulfonic acid(PFHpS) B18-Ap03753 CP ug/L < 0.01 < 0.01 <1 30% Pass

Perfluorooctanesulfonic acid(PFOS) B18-Ap03753 CP ug/L < 0.01 < 0.01 <1 30% Pass

Perfluorodecanesulfonic acid(PFDS) B18-Ap03753 CP ug/L < 0.01 < 0.01 <1 30% Pass

Duplicate


1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTSA) B18-Ap03753 CP ug/L < 0.01 < 0.01 <1 30% Pass

1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTSA) B18-Ap03753 CP ug/L < 0.05 < 0.05 <1 30% Pass

1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTSA) B18-Ap03753 CP ug/L < 0.01 < 0.01 <1 30% Pass

1H.1H.2H.2H-perfluorododecanesulfonic acid(10:2 FTSA) B18-Ap03753 CP ug/L < 0.01 < 0.01 <1 30% Pass



ABN : 50 005 085 521 Telephone: +61 7 3902 4600

Page 10 of 12


Quality Control Analyte Summary Compliance

The table below is the actual occurrence of QC performed on the batch of samples within this report and as defined below

Analysis SamplesAnalysed

LaboratoryDuplicatesReported

LaboratoryMatrix Spikes

Reported

Method BlanksReported

LaboratoryControl Samples

Reported

Perfluoroalkyl carboxylic acids (PFCAs) 3 2 1 1 1

Perfluoroalkane sulfonamido substances 3 2 1 1 1

Perfluoroalkane sulfonic acids (PFSAs) 3 2 1 1 1

n:2 Fluorotelomer sulfonic acids (n:2 FTSAs) 3 2 1 1 1

Quality Control Parameter Frequency Compliance follows guidelines delineated in the National Environment Protection (Assessment of SiteContamination) Measure April 2011, Schedule B3, Guideline on Laboratory Analysis of Potentially Contaminated Soils and US EPA SW-846Chapter 1: 'Quality Control'.

It comprises the following when a laboratory process batch is deemed to consist of up to 20 samples that are similar in terms of matrix and testprocedure, and are processed as one unit for QC purposes. If more than 20 samples are being processed, they are considered as more than onebatch.

Method blank

One method blank per process batch.

Laboratory duplicate

There should be at least one duplicate per process batch, or two duplicates if the process batch exceeds 10 samples.

Laboratory control sample (LCS)

There should be at least one LCS per process batch.

Matrix spikes

There should be one matrix spike per matrix type per process batch.



ABN : 50 005 085 521 Telephone: +61 7 3902 4600

Page 11 of 12


Comments









Code Description

N11Isotope dilution is used for calibration of each native compound for which an exact labelled analogue is available (Isotope Dilution Quantitation). The isotopically labelledanalogues allow identification and recovery correction of the concentration of the associated native PFAS compounds.

N15Where the native PFAS compound does not have labelled analogue then the quantification is made using the Extracted Internal Standard Analyte with the closest retention timeto the analyte and no recovery correction has been made (Internal Standard Quantitation).

Authorised By



Glenn Jackson







ABN : 50 005 085 521 Telephone: +61 7 3902 4600

Page 12 of 12






Abbotsford

VIC 3067


Report 592572-S


Project ID 754-MELEN199421

Received Date Apr 05, 2018

Client Sample ID 0990_TV001_180328

0990_TV002_180328

0990_TV003_180328

0990_TVC01_180328

Sample Matrix Animal tissue Animal tissue Animal tissue Animal tissue

Eurofins | mgt Sample No. B18-Ap04256 B18-Ap04257 B18-Ap04258 B18-Ap04259

Date Sampled Mar 28, 2018 Mar 28, 2018 Mar 28, 2018 Mar 28, 2018



Perfluorobutanoic acid (PFBA)N11 0.5 ug/kg 0.5 < 0.5 < 0.5 < 0.5







Perfluoroundecanoic acid (PFUnDA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5

Perfluorododecanoic acid (PFDoDA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5

Perfluorotridecanoic acid (PFTrDA)N15 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5


13C4-PFBA (surr.) 1 % 42 67 105 89

13C5-PFPeA (surr.) 1 % 71 76 129 113

13C5-PFHxA (surr.) 1 % 86 89 109 96

13C4-PFHpA (surr.) 1 % 17 15 76 54

13C8-PFOA (surr.) 1 % 48 85 40 44

13C5-PFNA (surr.) 1 % 83 124 43 74

13C6-PFDA (surr.) 1 % 126 140 136 112

13C2-PFUnDA (surr.) 1 % 113 122 120 93

13C2-PFDoDA (surr.) 1 % 88 116 114 82

13C2-PFTeDA (surr.) 1 % 165 95 63 66

Perfluoroalkyl sulfonamido substances








13C8-FOSA (surr.) 1 % 62 90 87 38

D3-N-MeFOSA (surr.) 1 % 27 11 60 19

Date Reported: May 23, 2018


ABN : 50 005 085 521 Telephone: +61 7 3902 4600

Page 1 of 50





0990_TV002_180328

0990_TV003_180328

0990_TVC01_180328






D5-N-EtFOSA (surr.) 1 % INT INT 42 INT

D7-N-MeFOSE (surr.) 1 % 45 11 68 13

D9-N-EtFOSE (surr.) 1 % 30 INT 59 INT

D5-N-EtFOSAA (surr.) 1 % 112 134 181 123

D3-N-MeFOSAA (surr.) 1 % 98 139 145 74

Perfluoroalkyl sulfonic acids (PFSAs)


Perfluoropentanesulfonic acid (PFPeS)N15 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5

Perfluorohexanesulfonic acid (PFHxS)N11 0.3 ug/kg N090.7 < 0.3 N091.0 N091.4

Perfluoroheptanesulfonic acid (PFHpS)N15 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5


Perfluorodecanesulfonic acid (PFDS)N15 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5

13C3-PFBS (surr.) 1 % 66 58 96 87

18O2-PFHxS (surr.) 1 % 53 101 100 83

13C8-PFOS (surr.) 1 % 81 94 107 85


1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTSA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5

1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTSA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5

1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTSA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5

1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2FTSA)N15 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5

13C2-4:2 FTSA (surr.) 1 % 87 84 130 117

13C2-6:2 FTSA (surr.) 1 % 134 70 172 152

13C2-8:2 FTSA (surr.) 1 % INT INT 130 INT

PFASs Summations

Sum (PFHxS + PFOS)* 0.5 ug/kg 12.7 11 19 24.4

Sum of US EPA PFAS (PFOS + PFOA)* 0.5 ug/kg 12 11 18 23

Sum of enHealth PFAS (PFHxS + PFOS + PFOA)* 0.5 ug/kg 12.7 11 19 24.4

Sum of WA DER PFAS (n=10)* 0.5 ug/kg 13.2 11 19 24.4

Sum of PFASs (n=28)* 0.5 ug/kg 13.2 11 19 24.4

Client Sample ID 0990_TVC02_180328

0990_TV011_180328

0990_TV012_180328

0990_TV013_180328
















ABN : 50 005 085 521 Telephone: +61 7 3902 4600

Page 2 of 50



0990_TV011_180328

0990_TV012_180328

0990_TV013_180328









13C4-PFBA (surr.) 1 % 103 107 90 111

13C5-PFPeA (surr.) 1 % 123 120 109 118

13C5-PFHxA (surr.) 1 % 105 118 80 108

13C4-PFHpA (surr.) 1 % 63 87 96 72

13C8-PFOA (surr.) 1 % 24 91 110 61

13C5-PFNA (surr.) 1 % 42 101 54 75

13C6-PFDA (surr.) 1 % 124 101 86 104

13C2-PFUnDA (surr.) 1 % 111 77 62 79

13C2-PFDoDA (surr.) 1 % 98 71 74 75

13C2-PFTeDA (surr.) 1 % 90 53 77 43









13C8-FOSA (surr.) 1 % 35 97 99 83

D3-N-MeFOSA (surr.) 1 % 34 57 50 58

D5-N-EtFOSA (surr.) 1 % 17 49 39 45

D7-N-MeFOSE (surr.) 1 % 31 70 48 61

D9-N-EtFOSE (surr.) 1 % 26 53 62 47

D5-N-EtFOSAA (surr.) 1 % 134 103 117 124

D3-N-MeFOSAA (surr.) 1 % 87 119 82 94




Perfluorohexanesulfonic acid (PFHxS)N11 0.3 ug/kg N090.7 1.3 1.7 2.0

Perfluoroheptanesulfonic acid (PFHpS)N15 0.5 ug/kg N090.7 < 0.5 N091.2 N090.7


Perfluorodecanesulfonic acid (PFDS)N15 0.5 ug/kg < 0.5 1.1 2.1 1.3

13C3-PFBS (surr.) 1 % 92 87 82 87

18O2-PFHxS (surr.) 1 % 89 87 64 71

13C8-PFOS (surr.) 1 % 93 75 120 86








ABN : 50 005 085 521 Telephone: +61 7 3902 4600

Page 3 of 50



0990_TV011_180328

0990_TV012_180328

0990_TV013_180328






13C2-4:2 FTSA (surr.) 1 % 135 121 114 149

13C2-6:2 FTSA (surr.) 1 % 142 173 130 149

13C2-8:2 FTSA (surr.) 1 % 152 140 78 159

PFASs Summations

Sum (PFHxS + PFOS)* 0.5 ug/kg 20.7 66.3 74.7 66


Sum of enHealth PFAS (PFHxS + PFOS + PFOA)* 0.5 ug/kg 20.7 66.3 74.7 66

Sum of WA DER PFAS (n=10)* 0.5 ug/kg 20.7 66.3 74.7 66

Sum of PFASs (n=28)* 0.5 ug/kg 21.4 67.4 78 68


0990_TV015_180328

0990_TV016_180328

0990_TV017_180328






Perfluorobutanoic acid (PFBA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 1.0








Perfluorododecanoic acid (PFDoDA)N11 0.5 ug/kg 1.7 < 0.5 0.6 < 0.5

Perfluorotridecanoic acid (PFTrDA)N15 0.5 ug/kg 1.5 < 0.5 < 0.5 < 0.5

Perfluorotetradecanoic acid (PFTeDA)N11 0.5 ug/kg 2.8 < 0.5 0.6 < 0.5

13C4-PFBA (surr.) 1 % 72 74 57 72

13C5-PFPeA (surr.) 1 % 87 67 54 84

13C5-PFHxA (surr.) 1 % 90 54 46 73

13C4-PFHpA (surr.) 1 % 99 40 36 55

13C8-PFOA (surr.) 1 % 54 36 31 47

13C5-PFNA (surr.) 1 % 61 20 17 41

13C6-PFDA (surr.) 1 % 97 12 10 66

13C2-PFUnDA (surr.) 1 % 81 INT INT 54

13C2-PFDoDA (surr.) 1 % 128 INT INT 71

13C2-PFTeDA (surr.) 1 % 115 10 INT 52









ABN : 50 005 085 521 Telephone: +61 7 3902 4600

Page 4 of 50



0990_TV015_180328

0990_TV016_180328

0990_TV017_180328








13C8-FOSA (surr.) 1 % 98 46 49 66

D3-N-MeFOSA (surr.) 1 % 29 35 34 41

D5-N-EtFOSA (surr.) 1 % 35 29 30 25

D7-N-MeFOSE (surr.) 1 % 47 28 37 29

D9-N-EtFOSE (surr.) 1 % 33 24 31 33

D5-N-EtFOSAA (surr.) 1 % 101 15 10 100

D3-N-MeFOSAA (surr.) 1 % 64 15 10 73




Perfluorohexanesulfonic acid (PFHxS)N11 0.3 ug/kg 3.2 0.5 0.5 0.7

Perfluoroheptanesulfonic acid (PFHpS)N15 0.5 ug/kg N090.7 < 0.5 < 0.5 < 0.5

Perfluorooctanesulfonic acid (PFOS)N11 0.3 ug/kg N0953 N099.8 N0911 N099.5

Perfluorodecanesulfonic acid (PFDS)N15 0.5 ug/kg 0.6 < 0.5 < 0.5 < 0.5

13C3-PFBS (surr.) 1 % 82 34 30 58

18O2-PFHxS (surr.) 1 % 80 32 29 58

13C8-PFOS (surr.) 1 % 134 11 10 60






13C2-4:2 FTSA (surr.) 1 % 113 116 71 97

13C2-6:2 FTSA (surr.) 1 % 110 73 53 93

13C2-8:2 FTSA (surr.) 1 % 164 23 15 74

PFASs Summations


Sum of US EPA PFAS (PFOS + PFOA)* 0.5 ug/kg 53 9.8 11 9.5






ABN : 50 005 085 521 Telephone: +61 7 3902 4600

Page 5 of 50



0990_TVC10_180328

0990_TVC12_180328

0990_TV028_180328






Perfluorobutanoic acid (PFBA)N11 0.5 ug/kg 0.8 24 9.7 0.6

Perfluoropentanoic acid (PFPeA)N11 0.5 ug/kg N090.6 N099.5 N093.5 < 0.5

Perfluorohexanoic acid (PFHxA)N11 0.5 ug/kg N090.7 N099.8 N097.2 < 0.5


Perfluorooctanoic acid (PFOA)N11 0.5 ug/kg < 0.5 N094.1 N091.1 N097.3

Perfluorononanoic acid (PFNA)N11 0.5 ug/kg < 0.5 N093.1 < 0.5 N098.0

Perfluorodecanoic acid (PFDA)N11 0.5 ug/kg 1.0 N096.5 7.1 11

Perfluoroundecanoic acid (PFUnDA)N11 0.5 ug/kg 6.1 18 8.7 14

Perfluorododecanoic acid (PFDoDA)N11 0.5 ug/kg 11 31 14 14

Perfluorotridecanoic acid (PFTrDA)N15 0.5 ug/kg 3.4 20 3.9 6.0

Perfluorotetradecanoic acid (PFTeDA)N11 0.5 ug/kg 2.5 7.0 2.8 4.1

13C4-PFBA (surr.) 1 % 68 61 66 73

13C5-PFPeA (surr.) 1 % 67 69 74 76

13C5-PFHxA (surr.) 1 % 73 111 59 66

13C4-PFHpA (surr.) 1 % 59 106 53 99

13C8-PFOA (surr.) 1 % 58 150 51 130

13C5-PFNA (surr.) 1 % 54 148 35 115

13C6-PFDA (surr.) 1 % 68 133 39 103

13C2-PFUnDA (surr.) 1 % 60 112 42 92

13C2-PFDoDA (surr.) 1 % 63 92 40 88

13C2-PFTeDA (surr.) 1 % 51 80 25 67


Perfluorooctane sulfonamide (FOSA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 0.9

N-methylperfluoro-1-octane sulfonamide (N-MeFOSA)N11 0.5 ug/kg < 0.5 < 0.5 0.5 < 0.5






13C8-FOSA (surr.) 1 % 56 126 61 44

D3-N-MeFOSA (surr.) 1 % 36 85 35 60

D5-N-EtFOSA (surr.) 1 % 30 74 27 49

D7-N-MeFOSE (surr.) 1 % 43 73 26 56

D9-N-EtFOSE (surr.) 1 % 30 60 44 47

D5-N-EtFOSAA (surr.) 1 % 103 125 60 64

D3-N-MeFOSAA (surr.) 1 % 56 105 41 66


Perfluorobutanesulfonic acid (PFBS)N11 0.5 ug/kg 0.9 6.8 4.7 0.9

Perfluoropentanesulfonic acid (PFPeS)N15 0.5 ug/kg < 0.5 N093.7 N092.9 1.8

Perfluorohexanesulfonic acid (PFHxS)N11 0.3 ug/kg 6.0 N0931 N0944 N09200

Perfluoroheptanesulfonic acid (PFHpS)N15 0.5 ug/kg N091.1 N0926 N0911 N0924


Perfluorodecanesulfonic acid (PFDS)N15 0.5 ug/kg 7.6 72 26 66

13C3-PFBS (surr.) 1 % 56 109 48 51

18O2-PFHxS (surr.) 1 % 50 126 53 111

13C8-PFOS (surr.) 1 % 50 94 37 76



ABN : 50 005 085 521 Telephone: +61 7 3902 4600

Page 6 of 50



0990_TVC10_180328

0990_TVC12_180328

0990_TV028_180328








1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTSA)N11 0.5 ug/kg 1.0 5.9 3.2 5.9

1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2FTSA)N15 0.5 ug/kg 2.1 1.1 < 0.5 < 0.5

13C2-4:2 FTSA (surr.) 1 % 94 79 84 90

13C2-6:2 FTSA (surr.) 1 % 65 82 96 75

13C2-8:2 FTSA (surr.) 1 % 88 66 83 66

PFASs Summations

Sum (PFHxS + PFOS)* 0.5 ug/kg 286 1831 1444 2600

Sum of US EPA PFAS (PFOS + PFOA)* 0.5 ug/kg 280 1804.1 1401.1 2407.3

Sum of enHealth PFAS (PFHxS + PFOS + PFOA)* 0.5 ug/kg 286 1835.1 1445.1 2607.3

Sum of WA DER PFAS (n=10)* 0.5 ug/kg 290 1891.1 1473.4 2614.7



0990_TVC13_180328

0990_TVC15_180328

0990_TV034_180328






Perfluorobutanoic acid (PFBA)N11 0.5 ug/kg 0.7 2.3 < 0.5 < 0.5


Perfluorohexanoic acid (PFHxA)N11 0.5 ug/kg < 0.5 N090.9 < 0.5 < 0.5

Perfluoroheptanoic acid (PFHpA)N11 0.5 ug/kg < 0.5 0.5 < 0.5 < 0.5

Perfluorooctanoic acid (PFOA)N11 0.5 ug/kg N093.2 N0913 1.0 0.7

Perfluorononanoic acid (PFNA)N11 0.5 ug/kg N093.2 N0918 3.1 2.4

Perfluorodecanoic acid (PFDA)N11 0.5 ug/kg 3.9 21 3.0 2.9

Perfluoroundecanoic acid (PFUnDA)N11 0.5 ug/kg 2.8 24 3.5 3.0

Perfluorododecanoic acid (PFDoDA)N11 0.5 ug/kg 3.3 31 3.9 3.7

Perfluorotridecanoic acid (PFTrDA)N15 0.5 ug/kg 1.3 11 1.1 1.0

Perfluorotetradecanoic acid (PFTeDA)N11 0.5 ug/kg 0.9 5.1 0.8 0.7

13C4-PFBA (surr.) 1 % 100 114 108 99

13C5-PFPeA (surr.) 1 % 124 141 124 115

13C5-PFHxA (surr.) 1 % 104 119 131 122

13C4-PFHpA (surr.) 1 % 62 68 101 69

13C8-PFOA (surr.) 1 % 136 154 83 55

13C5-PFNA (surr.) 1 % 64 144 98 83

13C6-PFDA (surr.) 1 % 94 120 88 90

13C2-PFUnDA (surr.) 1 % 66 64 66 70

13C2-PFDoDA (surr.) 1 % 94 76 60 65

13C2-PFTeDA (surr.) 1 % 91 54 42 47



ABN : 50 005 085 521 Telephone: +61 7 3902 4600

Page 7 of 50



0990_TVC13_180328

0990_TVC15_180328

0990_TV034_180328






Perfluorooctane sulfonamide (FOSA)N11 0.5 ug/kg < 0.5 10 < 0.5 < 0.5







13C8-FOSA (surr.) 1 % 121 152 90 81

D3-N-MeFOSA (surr.) 1 % 52 118 44 47

D5-N-EtFOSA (surr.) 1 % 43 119 42 42

D7-N-MeFOSE (surr.) 1 % 53 128 58 58

D9-N-EtFOSE (surr.) 1 % 16 127 46 42

D5-N-EtFOSAA (surr.) 1 % 120 98 91 121

D3-N-MeFOSAA (surr.) 1 % 90 61 124 99


Perfluorobutanesulfonic acid (PFBS)N11 0.5 ug/kg < 0.5 1.5 < 0.5 < 0.5

Perfluoropentanesulfonic acid (PFPeS)N15 0.5 ug/kg 1.0 N094.1 < 0.5 < 0.5

Perfluorohexanesulfonic acid (PFHxS)N11 0.3 ug/kg N09110 N09530 N0970 N0975

Perfluoroheptanesulfonic acid (PFHpS)N15 0.5 ug/kg N0929 N0987 N0911 N0913


Perfluorodecanesulfonic acid (PFDS)N15 0.5 ug/kg 26 190 8.1 7.9

13C3-PFBS (surr.) 1 % 95 99 93 90

18O2-PFHxS (surr.) 1 % 133 132 114 91

13C8-PFOS (surr.) 1 % 98 88 75 82




1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTSA)N11 0.5 ug/kg 1.0 4.6 3.6 2.5

1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2FTSA)N15 0.5 ug/kg < 0.5 0.9 < 0.5 < 0.5

13C2-4:2 FTSA (surr.) 1 % 140 160 186 149

13C2-6:2 FTSA (surr.) 1 % 187 160 177 164

13C2-8:2 FTSA (surr.) 1 % 198 144 130 111

PFASs Summations

Sum (PFHxS + PFOS)* 0.5 ug/kg 1210 5930 580 515

Sum of US EPA PFAS (PFOS + PFOA)* 0.5 ug/kg 1103.2 5413 511 440.7

Sum of enHealth PFAS (PFHxS + PFOS + PFOA)* 0.5 ug/kg 1213.2 5943 581 515.7





ABN : 50 005 085 521 Telephone: +61 7 3902 4600

Page 8 of 50



0990_TV037_180328

0990_TV038_180328

0990_TVC16_180328








Perfluorohexanoic acid (PFHxA)N11 0.5 ug/kg < 0.5 N091.6 N090.9 N090.7


Perfluorooctanoic acid (PFOA)N11 0.5 ug/kg < 0.5 N091.1 N090.8 N090.6

Perfluorononanoic acid (PFNA)N11 0.5 ug/kg < 0.5 1.5 2.0 0.5

Perfluorodecanoic acid (PFDA)N11 0.5 ug/kg < 0.5 9.3 19 2.4

Perfluoroundecanoic acid (PFUnDA)N11 0.5 ug/kg 1.1 21 35 4.8

Perfluorododecanoic acid (PFDoDA)N11 0.5 ug/kg 2.4 16 23 4.8

Perfluorotridecanoic acid (PFTrDA)N15 0.5 ug/kg 0.6 2.3 2.0 0.9

Perfluorotetradecanoic acid (PFTeDA)N11 0.5 ug/kg < 0.5 1.8 1.2 0.6

13C4-PFBA (surr.) 1 % 78 80 83 78

13C5-PFPeA (surr.) 1 % 100 119 105 106

13C5-PFHxA (surr.) 1 % 88 90 100 98

13C4-PFHpA (surr.) 1 % 71 69 77 81

13C8-PFOA (surr.) 1 % 85 90 105 102

13C5-PFNA (surr.) 1 % 77 70 79 81

13C6-PFDA (surr.) 1 % 122 92 87 113

13C2-PFUnDA (surr.) 1 % 105 87 73 85

13C2-PFDoDA (surr.) 1 % 83 73 56 81

13C2-PFTeDA (surr.) 1 % 81 70 36 73


Perfluorooctane sulfonamide (FOSA)N11 0.5 ug/kg < 0.5 34 17 7.0







13C8-FOSA (surr.) 1 % 80 59 69 87

D3-N-MeFOSA (surr.) 1 % 59 38 54 68

D5-N-EtFOSA (surr.) 1 % 37 14 35 34

D7-N-MeFOSE (surr.) 1 % 62 31 38 52

D9-N-EtFOSE (surr.) 1 % 44 19 26 42

D5-N-EtFOSAA (surr.) 1 % 159 108 93 131

D3-N-MeFOSAA (surr.) 1 % 135 115 97 141


Perfluorobutanesulfonic acid (PFBS)N11 0.5 ug/kg < 0.5 1.2 0.9 0.6

Perfluoropentanesulfonic acid (PFPeS)N15 0.5 ug/kg < 0.5 N091.1 N091.0 < 0.5

Perfluorohexanesulfonic acid (PFHxS)N11 0.3 ug/kg 0.5 N0992 N09130 N0914

Perfluoroheptanesulfonic acid (PFHpS)N15 0.5 ug/kg < 0.5 N098.8 N0912 N091.8


Perfluorodecanesulfonic acid (PFDS)N15 0.5 ug/kg 13 32 35 16

13C3-PFBS (surr.) 1 % 129 132 123 127

18O2-PFHxS (surr.) 1 % 71 144 140 85

13C8-PFOS (surr.) 1 % 96 96 91 83



ABN : 50 005 085 521 Telephone: +61 7 3902 4600

Page 9 of 50



0990_TV037_180328

0990_TV038_180328

0990_TVC16_180328








1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTSA)N11 0.5 ug/kg < 0.5 3.6 8.2 1.1

1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2FTSA)N15 0.5 ug/kg < 0.5 0.6 < 0.5 < 0.5

13C2-4:2 FTSA (surr.) 1 % 100 109 126 128

13C2-6:2 FTSA (surr.) 1 % 90 110 118 102

13C2-8:2 FTSA (surr.) 1 % 114 128 112 101

PFASs Summations

Sum (PFHxS + PFOS)* 0.5 ug/kg 250.5 3292 4230 484




Sum of PFASs (n=28)* 0.5 ug/kg 267.6 3427.9 4388 525.8


0990_TV041_180328

0990_TV043_180328

0990_TV044_180328












Perfluorodecanoic acid (PFDA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 0.5


Perfluorododecanoic acid (PFDoDA)N11 0.5 ug/kg 0.6 < 0.5 < 0.5 0.6



13C4-PFBA (surr.) 1 % 80 90 76 95

13C5-PFPeA (surr.) 1 % 108 116 88 112

13C5-PFHxA (surr.) 1 % 89 96 70 117

13C4-PFHpA (surr.) 1 % 73 71 34 101

13C8-PFOA (surr.) 1 % 79 68 27 112

13C5-PFNA (surr.) 1 % 73 78 41 98

13C6-PFDA (surr.) 1 % 131 157 78 111

13C2-PFUnDA (surr.) 1 % 82 107 54 102

13C2-PFDoDA (surr.) 1 % 62 97 51 77

13C2-PFTeDA (surr.) 1 % 122 149 72 74



ABN : 50 005 085 521 Telephone: +61 7 3902 4600

Page 10 of 50



0990_TV041_180328

0990_TV043_180328

0990_TV044_180328






Perfluorooctane sulfonamide (FOSA)N11 0.5 ug/kg 0.6 < 0.5 < 0.5 < 0.5







13C8-FOSA (surr.) 1 % 90 69 23 97

D3-N-MeFOSA (surr.) 1 % 55 43 36 76

D5-N-EtFOSA (surr.) 1 % 24 22 11 62

D7-N-MeFOSE (surr.) 1 % 47 42 10 62

D9-N-EtFOSE (surr.) 1 % 34 31 72 53

D5-N-EtFOSAA (surr.) 1 % 151 158 45 125

D3-N-MeFOSAA (surr.) 1 % 132 171 74 117




Perfluorohexanesulfonic acid (PFHxS)N11 0.3 ug/kg 1.8 2.9 < 0.3 < 0.3


Perfluorooctanesulfonic acid (PFOS)N11 0.3 ug/kg N0919 N0919 N090.7 N0917

Perfluorodecanesulfonic acid (PFDS)N15 0.5 ug/kg 5.2 3.4 < 0.5 < 0.5

13C3-PFBS (surr.) 1 % 123 133 90 130

18O2-PFHxS (surr.) 1 % 57 51 53 89

13C8-PFOS (surr.) 1 % 93 103 78 95






13C2-4:2 FTSA (surr.) 1 % 117 123 96 192

13C2-6:2 FTSA (surr.) 1 % 87 94 67 107

13C2-8:2 FTSA (surr.) 1 % 119 190 117 90

PFASs Summations

Sum (PFHxS + PFOS)* 0.5 ug/kg 20.8 21.9 0.7 17

Sum of US EPA PFAS (PFOS + PFOA)* 0.5 ug/kg 19 19 0.7 17

Sum of enHealth PFAS (PFHxS + PFOS + PFOA)* 0.5 ug/kg 20.8 21.9 0.7 17





ABN : 50 005 085 521 Telephone: +61 7 3902 4600

Page 11 of 50



0990_TV046_180328

0990_TV047_180328

0990_TV048_180328












Perfluorodecanoic acid (PFDA)N11 0.5 ug/kg 1.1 < 0.5 0.6 < 0.5


Perfluorododecanoic acid (PFDoDA)N11 0.5 ug/kg 1.6 0.5 0.9 < 0.5

Perfluorotridecanoic acid (PFTrDA)N15 0.5 ug/kg 0.8 < 0.5 < 0.5 < 0.5

Perfluorotetradecanoic acid (PFTeDA)N11 0.5 ug/kg 1.5 < 0.5 1.4 < 0.5

13C4-PFBA (surr.) 1 % 81 100 40 118

13C5-PFPeA (surr.) 1 % 98 116 59 136

13C5-PFHxA (surr.) 1 % 100 120 58 127

13C4-PFHpA (surr.) 1 % 69 97 54 93

13C8-PFOA (surr.) 1 % 103 117 75 125

13C5-PFNA (surr.) 1 % 83 96 46 107

13C6-PFDA (surr.) 1 % 129 134 87 153

13C2-PFUnDA (surr.) 1 % 94 93 16 148

13C2-PFDoDA (surr.) 1 % 98 78 57 133

13C2-PFTeDA (surr.) 1 % 121 101 54 126









13C8-FOSA (surr.) 1 % 67 104 23 84

D3-N-MeFOSA (surr.) 1 % 29 74 INT 69

D5-N-EtFOSA (surr.) 1 % 11 65 INT 29

D7-N-MeFOSE (surr.) 1 % 23 86 INT 56

D9-N-EtFOSE (surr.) 1 % 17 61 INT 51

D5-N-EtFOSAA (surr.) 1 % 197 129 62 158

D3-N-MeFOSAA (surr.) 1 % 117 124 54 177




Perfluorohexanesulfonic acid (PFHxS)N11 0.3 ug/kg < 0.3 < 0.3 0.5 < 0.3


Perfluorooctanesulfonic acid (PFOS)N11 0.3 ug/kg N0936 N0913 N0950 N095.5


13C3-PFBS (surr.) 1 % 123 135 91 158

18O2-PFHxS (surr.) 1 % 107 97 73 124

13C8-PFOS (surr.) 1 % 102 111 73 138



ABN : 50 005 085 521 Telephone: +61 7 3902 4600

Page 12 of 50



0990_TV046_180328

0990_TV047_180328

0990_TV048_180328










13C2-4:2 FTSA (surr.) 1 % 124 186 83 INT

13C2-6:2 FTSA (surr.) 1 % 90 119 76 140

13C2-8:2 FTSA (surr.) 1 % 113 109 132 159

PFASs Summations

Sum (PFHxS + PFOS)* 0.5 ug/kg 36 13 50.5 5.5

Sum of US EPA PFAS (PFOS + PFOA)* 0.5 ug/kg 36 13 50 5.5

Sum of enHealth PFAS (PFHxS + PFOS + PFOA)* 0.5 ug/kg 36 13 50.5 5.5

Sum of WA DER PFAS (n=10)* 0.5 ug/kg 36 13 50.5 5.5

Sum of PFASs (n=28)* 0.5 ug/kg 41 13.5 53.4 5.5


0990_TV050_180328

0990_TV051_180328

0990_TV052_180328

















13C4-PFBA (surr.) 1 % 91 39 85 71

13C5-PFPeA (surr.) 1 % 117 51 86 74

13C5-PFHxA (surr.) 1 % 106 57 56 51

13C4-PFHpA (surr.) 1 % 84 32 24 28

13C8-PFOA (surr.) 1 % 115 52 20 24

13C5-PFNA (surr.) 1 % 101 16 30 26

13C6-PFDA (surr.) 1 % 135 120 56 41

13C2-PFUnDA (surr.) 1 % 135 72 55 28

13C2-PFDoDA (surr.) 1 % 126 75 36 22

13C2-PFTeDA (surr.) 1 % 106 67 53 31



ABN : 50 005 085 521 Telephone: +61 7 3902 4600

Page 13 of 50



0990_TV050_180328

0990_TV051_180328

0990_TV052_180328













13C8-FOSA (surr.) 1 % 91 20 31 49

D3-N-MeFOSA (surr.) 1 % 82 INT 49 25



D9-N-EtFOSE (surr.) 1 % 61 28 107 19

D5-N-EtFOSAA (surr.) 1 % 155 101 45 57

D3-N-MeFOSAA (surr.) 1 % 159 94 57 43




Perfluorohexanesulfonic acid (PFHxS)N11 0.3 ug/kg < 0.3 0.6 0.7 N094.2

Perfluoroheptanesulfonic acid (PFHpS)N15 0.5 ug/kg < 0.5 < 0.5 N091.0 N091.4

Perfluorooctanesulfonic acid (PFOS)N11 0.3 ug/kg N097.6 N0924 N0921 N0949

Perfluorodecanesulfonic acid (PFDS)N15 0.5 ug/kg < 0.5 0.9 1.8 1.3

13C3-PFBS (surr.) 1 % 139 83 85 72

18O2-PFHxS (surr.) 1 % 107 84 54 42

13C8-PFOS (surr.) 1 % 130 94 66 38






13C2-4:2 FTSA (surr.) 1 % 194 68 94 82

13C2-6:2 FTSA (surr.) 1 % 119 16 51 52

13C2-8:2 FTSA (surr.) 1 % 140 175 82 53

PFASs Summations


Sum of US EPA PFAS (PFOS + PFOA)* 0.5 ug/kg 7.6 24 21 49






ABN : 50 005 085 521 Telephone: +61 7 3902 4600

Page 14 of 50



0990_TV054_180328

0990_TV055_180328

0990_TV056_180328

















13C4-PFBA (surr.) 1 % 34 66 65 36

13C5-PFPeA (surr.) 1 % 42 72 69 53

13C5-PFHxA (surr.) 1 % 30 66 55 53

13C4-PFHpA (surr.) 1 % 17 47 34 9.0

13C8-PFOA (surr.) 1 % 16 58 33 46

13C5-PFNA (surr.) 1 % 20 44 33 20

13C6-PFDA (surr.) 1 % 37 42 43 34

13C2-PFUnDA (surr.) 1 % 19 35 38 INT

13C2-PFDoDA (surr.) 1 % 39 28 33 INT

13C2-PFTeDA (surr.) 1 % 33 10 26 20









13C8-FOSA (surr.) 1 % 12 28 37 18

D3-N-MeFOSA (surr.) 1 % 17 11 20 INT


D7-N-MeFOSE (surr.) 1 % INT 10 21 INT

D9-N-EtFOSE (surr.) 1 % 26 INT 16 INT

D5-N-EtFOSAA (surr.) 1 % 18 35 42 14

D3-N-MeFOSAA (surr.) 1 % 42 46 45 INT




Perfluorohexanesulfonic acid (PFHxS)N11 0.3 ug/kg N092.3 N094.1 1.3 0.8

Perfluoroheptanesulfonic acid (PFHpS)N15 0.5 ug/kg < 0.5 N090.6 < 0.5 < 0.5


Perfluorodecanesulfonic acid (PFDS)N15 0.5 ug/kg 0.9 0.9 < 0.5 < 0.5

13C3-PFBS (surr.) 1 % 41 75 75 71

18O2-PFHxS (surr.) 1 % 29 55 48 50

13C8-PFOS (surr.) 1 % 32 33 42 29



ABN : 50 005 085 521 Telephone: +61 7 3902 4600

Page 15 of 50



0990_TV054_180328

0990_TV055_180328

0990_TV056_180328







1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTSA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 0.5



13C2-4:2 FTSA (surr.) 1 % 46 105 82 69

13C2-6:2 FTSA (surr.) 1 % 32 62 45 27

13C2-8:2 FTSA (surr.) 1 % 70 44 50 14

PFASs Summations







0990_TVC03_180328

0990_TVC06_180328

0990_TVC04_180328

















13C4-PFBA (surr.) 1 % 73 76 91 82

13C5-PFPeA (surr.) 1 % 74 83 105 99

13C5-PFHxA (surr.) 1 % 65 67 94 84

13C4-PFHpA (surr.) 1 % 59 46 70 56

13C8-PFOA (surr.) 1 % 55 39 47 37

13C5-PFNA (surr.) 1 % 44 59 78 63

13C6-PFDA (surr.) 1 % 30 77 95 115

13C2-PFUnDA (surr.) 1 % 21 67 75 93

13C2-PFDoDA (surr.) 1 % 17 66 103 101

13C2-PFTeDA (surr.) 1 % INT 69 96 93



ABN : 50 005 085 521 Telephone: +61 7 3902 4600

Page 16 of 50



0990_TVC03_180328

0990_TVC06_180328

0990_TVC04_180328













13C8-FOSA (surr.) 1 % 29 26 44 23

D3-N-MeFOSA (surr.) 1 % 17 14 51 32


D7-N-MeFOSE (surr.) 1 % 21 18 50 21

D9-N-EtFOSE (surr.) 1 % 15 40 95 76

D5-N-EtFOSAA (surr.) 1 % 11 26 32 20

D3-N-MeFOSAA (surr.) 1 % 30 82 100 112




Perfluorohexanesulfonic acid (PFHxS)N11 0.3 ug/kg < 0.3 < 0.3 N091.8 N090.8

Perfluoroheptanesulfonic acid (PFHpS)N15 0.5 ug/kg < 0.5 < 0.5 < 0.5 0.7

Perfluorooctanesulfonic acid (PFOS)N11 0.3 ug/kg N090.5 N094.2 N0943 N0918


13C3-PFBS (surr.) 1 % 68 79 102 106

18O2-PFHxS (surr.) 1 % 55 67 64 92

13C8-PFOS (surr.) 1 % 24 53 70 82






13C2-4:2 FTSA (surr.) 1 % 38 46 63 54

13C2-6:2 FTSA (surr.) 1 % 39 110 95 91

13C2-8:2 FTSA (surr.) 1 % 22 116 99 164

PFASs Summations


Sum of US EPA PFAS (PFOS + PFOA)* 0.5 ug/kg 0.5 4.2 43 18






ABN : 50 005 085 521 Telephone: +61 7 3902 4600

Page 17 of 50



0990_TV069_180328

0990_TV070_180328

0990_TV071_180328

















13C4-PFBA (surr.) 1 % 72 61 87 74

13C5-PFPeA (surr.) 1 % 117 98 120 106

13C5-PFHxA (surr.) 1 % 121 114 120 102

13C4-PFHpA (surr.) 1 % 91 86 94 63

13C8-PFOA (surr.) 1 % 107 89 114 62

13C5-PFNA (surr.) 1 % 116 90 104 87

13C6-PFDA (surr.) 1 % 159 138 167 106

13C2-PFUnDA (surr.) 1 % 147 99 123 71

13C2-PFDoDA (surr.) 1 % 119 73 108 74

13C2-PFTeDA (surr.) 1 % 99 72 118 74









13C8-FOSA (surr.) 1 % 46 54 68 31

D3-N-MeFOSA (surr.) 1 % 21 14 39 27

D5-N-EtFOSA (surr.) 1 % 11 INT 14 INT

D7-N-MeFOSE (surr.) 1 % 17 22 37 24

D9-N-EtFOSE (surr.) 1 % 21 13 26 24

D5-N-EtFOSAA (surr.) 1 % 96 77 105 20

D3-N-MeFOSAA (surr.) 1 % 111 78 127 79






Perfluorooctanesulfonic acid (PFOS)N11 0.3 ug/kg N095.0 N096.3 N090.9 N095.1


13C3-PFBS (surr.) 1 % 124 112 120 106

18O2-PFHxS (surr.) 1 % 81 96 88 86

13C8-PFOS (surr.) 1 % 95 89 100 72



ABN : 50 005 085 521 Telephone: +61 7 3902 4600

Page 18 of 50



0990_TV069_180328

0990_TV070_180328

0990_TV071_180328










13C2-4:2 FTSA (surr.) 1 % 91 90 93 83

13C2-6:2 FTSA (surr.) 1 % 91 80 96 106

13C2-8:2 FTSA (surr.) 1 % 163 170 140 189

PFASs Summations

Sum (PFHxS + PFOS)* 0.5 ug/kg 5 6.3 0.9 5.1


Sum of enHealth PFAS (PFHxS + PFOS + PFOA)* 0.5 ug/kg 5 6.3 0.9 5.1

Sum of WA DER PFAS (n=10)* 0.5 ug/kg 5 6.3 0.9 5.1

Sum of PFASs (n=28)* 0.5 ug/kg 5 6.3 0.9 5.1


0990_TV073_180328

0990_TV074_180328

0990_TV075_180328

















13C4-PFBA (surr.) 1 % 74 62 79 81

13C5-PFPeA (surr.) 1 % 103 89 108 112

13C5-PFHxA (surr.) 1 % 126 107 123 129

13C4-PFHpA (surr.) 1 % 68 62 94 101

13C8-PFOA (surr.) 1 % 107 92 118 117

13C5-PFNA (surr.) 1 % 134 110 132 134

13C6-PFDA (surr.) 1 % 162 149 160 162

13C2-PFUnDA (surr.) 1 % 111 152 149 151

13C2-PFDoDA (surr.) 1 % 78 133 117 139

13C2-PFTeDA (surr.) 1 % 95 101 129 94



ABN : 50 005 085 521 Telephone: +61 7 3902 4600

Page 19 of 50



0990_TV073_180328

0990_TV074_180328

0990_TV075_180328













13C8-FOSA (surr.) 1 % 61 49 48 83

D3-N-MeFOSA (surr.) 1 % 19 10 21 42


D7-N-MeFOSE (surr.) 1 % 22 13 20 37

D9-N-EtFOSE (surr.) 1 % INT INT 20 27

D5-N-EtFOSAA (surr.) 1 % 93 106 90 119

D3-N-MeFOSAA (surr.) 1 % 88 126 102 141






Perfluorooctanesulfonic acid (PFOS)N11 0.3 ug/kg N091.0 N093.1 N094.1 N0914


13C3-PFBS (surr.) 1 % 111 103 113 114

18O2-PFHxS (surr.) 1 % 25 106 78 72

13C8-PFOS (surr.) 1 % 97 90 99 85



1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTSA)N11 0.5 ug/kg < 0.5 < 0.5 2.1 < 0.5



13C2-4:2 FTSA (surr.) 1 % 102 79 106 113

13C2-6:2 FTSA (surr.) 1 % 68 59 98 101

13C2-8:2 FTSA (surr.) 1 % 162 INT INT 164

PFASs Summations

Sum (PFHxS + PFOS)* 0.5 ug/kg 1 3.1 4.1 14

Sum of US EPA PFAS (PFOS + PFOA)* 0.5 ug/kg 1 3.1 4.1 14

Sum of enHealth PFAS (PFHxS + PFOS + PFOA)* 0.5 ug/kg 1 3.1 4.1 14

Sum of WA DER PFAS (n=10)* 0.5 ug/kg 1 3.1 6.2 14

Sum of PFASs (n=28)* 0.5 ug/kg 1 3.1 6.2 14



ABN : 50 005 085 521 Telephone: +61 7 3902 4600

Page 20 of 50



0990_TV077_180328

0990_TVC07_180328

0990_TVC08_180328














Perfluorododecanoic acid (PFDoDA)N11 0.5 ug/kg < 0.5 < 0.5 0.9 < 0.5



13C4-PFBA (surr.) 1 % 73 67 84 81

13C5-PFPeA (surr.) 1 % 101 94 107 97

13C5-PFHxA (surr.) 1 % 107 111 98 68

13C4-PFHpA (surr.) 1 % 90 85 77 45

13C8-PFOA (surr.) 1 % 104 96 63 19

13C5-PFNA (surr.) 1 % 118 104 90 36

13C6-PFDA (surr.) 1 % 132 148 137 90

13C2-PFUnDA (surr.) 1 % 106 117 105 74

13C2-PFDoDA (surr.) 1 % 73 100 118 63

13C2-PFTeDA (surr.) 1 % 96 76 96 90









13C8-FOSA (surr.) 1 % 74 54 44 23

D3-N-MeFOSA (surr.) 1 % 58 13 23 40

D5-N-EtFOSA (surr.) 1 % 37 INT INT 25

D7-N-MeFOSE (surr.) 1 % 62 16 23 35


D5-N-EtFOSAA (surr.) 1 % 96 84 51 28

D3-N-MeFOSAA (surr.) 1 % 81 124 121 63




Perfluorohexanesulfonic acid (PFHxS)N11 0.3 ug/kg < 0.3 < 0.3 < 0.3 0.5


Perfluorooctanesulfonic acid (PFOS)N11 0.3 ug/kg < 0.3 < 0.3 N099.1 N092.9

Perfluorodecanesulfonic acid (PFDS)N15 0.5 ug/kg < 0.5 < 0.5 6.1 < 0.5

13C3-PFBS (surr.) 1 % 101 109 103 85

18O2-PFHxS (surr.) 1 % 73 90 112 72

13C8-PFOS (surr.) 1 % 79 89 76 65



ABN : 50 005 085 521 Telephone: +61 7 3902 4600

Page 21 of 50



0990_TV077_180328

0990_TVC07_180328

0990_TVC08_180328










13C2-4:2 FTSA (surr.) 1 % 86 82 84 62

13C2-6:2 FTSA (surr.) 1 % 124 89 139 92

13C2-8:2 FTSA (surr.) 1 % 120 184 159 119

PFASs Summations

Sum (PFHxS + PFOS)* 0.5 ug/kg < 0.5 < 0.5 9.1 3.4

Sum of US EPA PFAS (PFOS + PFOA)* 0.5 ug/kg < 0.5 < 0.5 9.1 2.9

Sum of enHealth PFAS (PFHxS + PFOS + PFOA)* 0.5 ug/kg < 0.5 < 0.5 9.1 3.4

Sum of WA DER PFAS (n=10)* 0.5 ug/kg < 0.5 < 0.5 9.1 3.4

Sum of PFASs (n=28)* 0.5 ug/kg < 0.5 < 0.5 16.1 3.4


0990_TV100_180328

0990_TV108_180328

0990_TV109_180328










Perfluorooctanoic acid (PFOA)N11 0.5 ug/kg < 0.5 0.6 < 0.5 < 0.5

Perfluorononanoic acid (PFNA)N11 0.5 ug/kg < 0.5 1.3 < 0.5 < 0.5

Perfluorodecanoic acid (PFDA)N11 0.5 ug/kg < 0.5 0.7 < 0.5 < 0.5

Perfluoroundecanoic acid (PFUnDA)N11 0.5 ug/kg < 0.5 < 0.5 0.9 < 0.5

Perfluorododecanoic acid (PFDoDA)N11 0.5 ug/kg < 0.5 0.6 2.7 < 0.5

Perfluorotridecanoic acid (PFTrDA)N15 0.5 ug/kg < 0.5 < 0.5 2.3 < 0.5

Perfluorotetradecanoic acid (PFTeDA)N11 0.5 ug/kg < 0.5 < 0.5 0.5 < 0.5

13C4-PFBA (surr.) 1 % 72 99 81 78

13C5-PFPeA (surr.) 1 % 90 123 114 116

13C5-PFHxA (surr.) 1 % 86 111 132 134

13C4-PFHpA (surr.) 1 % 63 88 89 69

13C8-PFOA (surr.) 1 % 41 54 109 97

13C5-PFNA (surr.) 1 % 62 59 129 122

13C6-PFDA (surr.) 1 % 85 120 152 168

13C2-PFUnDA (surr.) 1 % 73 105 130 142

13C2-PFDoDA (surr.) 1 % 92 131 131 112

13C2-PFTeDA (surr.) 1 % 62 101 61 96



ABN : 50 005 085 521 Telephone: +61 7 3902 4600

Page 22 of 50



0990_TV100_180328

0990_TV108_180328

0990_TV109_180328













13C8-FOSA (surr.) 1 % 13 35 55 59

D3-N-MeFOSA (surr.) 1 % 18 26 14 19

D5-N-EtFOSA (surr.) 1 % INT 20 INT INT


D9-N-EtFOSE (surr.) 1 % 52 90 11 14

D5-N-EtFOSAA (surr.) 1 % 23 42 93 98

D3-N-MeFOSAA (surr.) 1 % 66 108 183 129




Perfluorohexanesulfonic acid (PFHxS)N11 0.3 ug/kg N091.4 N0930 0.4 < 0.3

Perfluoroheptanesulfonic acid (PFHpS)N15 0.5 ug/kg < 0.5 N099.6 < 0.5 < 0.5

Perfluorooctanesulfonic acid (PFOS)N11 0.3 ug/kg N095.3 N09180 N0921 0.4

Perfluorodecanesulfonic acid (PFDS)N15 0.5 ug/kg < 0.5 3.4 7.0 < 0.5

13C3-PFBS (surr.) 1 % 98 107 108 112

18O2-PFHxS (surr.) 1 % 100 98 68 49

13C8-PFOS (surr.) 1 % 70 106 86 99






13C2-4:2 FTSA (surr.) 1 % 71 98 123 108

13C2-6:2 FTSA (surr.) 1 % 88 137 95 90

13C2-8:2 FTSA (surr.) 1 % 134 141 162 191

PFASs Summations

Sum (PFHxS + PFOS)* 0.5 ug/kg 6.7 210 21.4 < 0.5

Sum of US EPA PFAS (PFOS + PFOA)* 0.5 ug/kg 5.3 180.6 21 < 0.5






ABN : 50 005 085 521 Telephone: +61 7 3902 4600

Page 23 of 50



0990_TV111_180328

0990_TV096_180328

Sample Matrix Animal tissue Animal tissue Animal tissue





Perfluorobutanoic acid (PFBA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5

Perfluoropentanoic acid (PFPeA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5

Perfluorohexanoic acid (PFHxA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5

Perfluoroheptanoic acid (PFHpA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5

Perfluorooctanoic acid (PFOA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5

Perfluorononanoic acid (PFNA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5

Perfluorodecanoic acid (PFDA)N11 0.5 ug/kg < 0.5 1.1 < 0.5

Perfluoroundecanoic acid (PFUnDA)N11 0.5 ug/kg < 0.5 1.7 < 0.5

Perfluorododecanoic acid (PFDoDA)N11 0.5 ug/kg < 0.5 1.8 < 0.5

Perfluorotridecanoic acid (PFTrDA)N15 0.5 ug/kg < 0.5 < 0.5 < 0.5

Perfluorotetradecanoic acid (PFTeDA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5

13C4-PFBA (surr.) 1 % 53 61 86

13C5-PFPeA (surr.) 1 % 98 64 116

13C5-PFHxA (surr.) 1 % 113 103 119

13C4-PFHpA (surr.) 1 % 29 24 49

13C8-PFOA (surr.) 1 % 110 117 100

13C5-PFNA (surr.) 1 % 71 106 93

13C6-PFDA (surr.) 1 % 165 152 136

13C2-PFUnDA (surr.) 1 % 130 153 119

13C2-PFDoDA (surr.) 1 % 84 98 104

13C2-PFTeDA (surr.) 1 % 93 71 114


Perfluorooctane sulfonamide (FOSA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5

N-methylperfluoro-1-octane sulfonamide (N-MeFOSA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5

N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5

2-(N-methylperfluoro-1-octane sulfonamido)-ethanol(N-MeFOSE)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5

2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5

N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5

N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5

13C8-FOSA (surr.) 1 % 55 42 67

D3-N-MeFOSA (surr.) 1 % 22 15 66

D5-N-EtFOSA (surr.) 1 % 10 INT 48

D7-N-MeFOSE (surr.) 1 % 20 10 73

D9-N-EtFOSE (surr.) 1 % 10 INT 64

D5-N-EtFOSAA (surr.) 1 % 62 21 92

D3-N-MeFOSAA (surr.) 1 % 131 76 124


Perfluorobutanesulfonic acid (PFBS)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5

Perfluoropentanesulfonic acid (PFPeS)N15 0.5 ug/kg < 0.5 < 0.5 < 0.5

Perfluorohexanesulfonic acid (PFHxS)N11 0.3 ug/kg < 0.3 N092.1 < 0.3

Perfluoroheptanesulfonic acid (PFHpS)N15 0.5 ug/kg < 0.5 < 0.5 < 0.5

Perfluorooctanesulfonic acid (PFOS)N11 0.3 ug/kg < 0.3 N0964 N094.4

Perfluorodecanesulfonic acid (PFDS)N15 0.5 ug/kg < 0.5 < 0.5 < 0.5

13C3-PFBS (surr.) 1 % 99 60 96

18O2-PFHxS (surr.) 1 % 129 120 74

13C8-PFOS (surr.) 1 % 93 94 77



ABN : 50 005 085 521 Telephone: +61 7 3902 4600

Page 24 of 50



0990_TV111_180328

0990_TV096_180328

Sample Matrix Animal tissue Animal tissue Animal tissue





1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTSA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5

1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTSA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5

1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTSA)N11 0.5 ug/kg < 0.5 0.8 < 0.5

1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2FTSA)N15 0.5 ug/kg < 0.5 < 0.5 < 0.5

13C2-4:2 FTSA (surr.) 1 % 85 38 112

13C2-6:2 FTSA (surr.) 1 % 6.0 78 62

13C2-8:2 FTSA (surr.) 1 % 133 184 120

PFASs Summations

Sum (PFHxS + PFOS)* 0.5 ug/kg < 0.5 66.1 4.4

Sum of US EPA PFAS (PFOS + PFOA)* 0.5 ug/kg < 0.5 64 4.4

Sum of enHealth PFAS (PFHxS + PFOS + PFOA)* 0.5 ug/kg < 0.5 66.1 4.4

Sum of WA DER PFAS (n=10)* 0.5 ug/kg < 0.5 66.9 4.4

Sum of PFASs (n=28)* 0.5 ug/kg < 0.5 71.5 4.4



ABN : 50 005 085 521 Telephone: +61 7 3902 4600

Page 25 of 50





Per- and Polyfluoroalkyl Substances (PFASs)

Perfluoroalkyl carboxylic acids (PFCAs) Brisbane Apr 06, 2018 180 Day

- Method: LTM-ORG-2100 Per- and Polyfluoroalkyl Substances (PFAS)

Perfluoroalkyl sulfonamido substances Brisbane Apr 06, 2018 180 Day


Perfluoroalkyl sulfonic acids (PFSAs) Brisbane Apr 06, 2018 180 Day


n:2 Fluorotelomer sulfonic acids (n:2 FTSAs) Brisbane Apr 06, 2018 180 Day




ABN : 50 005 085 521 Telephone: +61 7 3902 4600

Page 26 of 50


.Company Name: Coffey Environments Pty Ltd VIC Order No.: Received: Apr 5, 2018 9:00 AMAddress: Level 1, 436 Johnston Street Report #: 592572 Due: Apr 27, 2018


Project Name: DOD TINDALProject ID: 754-MELEN199421


Sample Detail

Per- and P

olyfluoroalkyl Substances (P

FA

Ss)





External Laboratory


Matrix LAB ID

1 0990_TV001_180328

Mar 28, 2018 Animal tissue B18-Ap04256 X

2 0990_TV002_180328


3 0990_TV003_180328


4 0990_TVC01_180328


5 0990_TVC02_180328


6 0990_TV011_ Mar 28, 2018 Animal tissue B18-Ap04261 X






Date Reported:May 23, 2018


ABN : 50 005 085 521 Telephone: +61 7 3902 4600

Page 27 of 50


Company Name: Coffey Environments Pty Ltd VIC Order No.: Received: Apr 5, 2018 9:00 AMAddress: Level 1, 436 Johnston Street Report #: 592572 Due: Apr 27, 2018




Sample Detail

Per- and P


FA

Ss)





180328

7 0990_TV012_180328


8 0990_TV013_180328


9 0990_TV014_180328


10 0990_TV015_180328


11 0990_TV016_180328


12 0990_TV017_180328


13 0990_TVC09_ Mar 28, 2018 Animal tissue B18-Ap04268 X








ABN : 50 005 085 521 Telephone: +61 7 3902 4600

Page 28 of 50






Sample Detail

Per- and P


FA

Ss)





180328

14 0990_TVC10_180328


15 0990_TVC12_180328


16 0990_TV028_180328


17 0990_TVC14_180328


18 0990_TVC13_180328


19 0990_TVC15_180328










ABN : 50 005 085 521 Telephone: +61 7 3902 4600

Page 29 of 50






Sample Detail

Per- and P


FA

Ss)





180328

21 0990_TV036_180328


22 0990_TV037_180328


23 0990_TV038_180328


24 0990_TVC16_180328


25 0990_TV040_180328


26 0990_TV041_180328










ABN : 50 005 085 521 Telephone: +61 7 3902 4600

Page 30 of 50






Sample Detail

Per- and P


FA

Ss)





180328

28 0990_TV044_180328


29 0990_TV045_180328


30 0990_TV046_180328


31 0990_TV047_180328


32 0990_TV048_180328


33 0990_TV049_180328










ABN : 50 005 085 521 Telephone: +61 7 3902 4600

Page 31 of 50






Sample Detail

Per- and P


FA

Ss)





180328

35 0990_TV051_180328


36 0990_TV052_180328


37 0990_TV053_180328


38 0990_TV054_180328


39 0990_TV055_180328


40 0990_TV056_180328










ABN : 50 005 085 521 Telephone: +61 7 3902 4600

Page 32 of 50






Sample Detail

Per- and P


FA

Ss)





180328

42 0990_TVC03_180328


43 0990_TVC06_180328


44 0990_TVC04_180328


45 0990_TVC05_180328


46 0990_TV069_180328


47 0990_TV070_180328










ABN : 50 005 085 521 Telephone: +61 7 3902 4600

Page 33 of 50






Sample Detail

Per- and P


FA

Ss)





180328

49 0990_TV072_180328


50 0990_TV073_180328


51 0990_TV074_180328


52 0990_TV075_180328


53 0990_TV076_180328


54 0990_TV077_180328


55 0990_TVC07_ Mar 28, 2018 Animal tissue B18-Ap04311 X








ABN : 50 005 085 521 Telephone: +61 7 3902 4600

Page 34 of 50






Sample Detail

Per- and P


FA

Ss)





180328

56 0990_TVC08_180328


57 0990_TV099_180328


58 0990_TV100_180328


59 0990_TV108_180328


60 0990_TV109_180328


61 0990_TV110_180328










ABN : 50 005 085 521 Telephone: +61 7 3902 4600

Page 35 of 50






Sample Detail

Per- and P


FA

Ss)





180328

63 0990_TV096_180328


Test Counts 63








ABN : 50 005 085 521 Telephone: +61 7 3902 4600

Page 36 of 50



General

Holding Times

Units

Terms




request.









































affected.

















ABN : 50 005 085 521 Telephone: +61 7 3902 4600

Page 37 of 50




PassLimits

QualifyingCode

Method Blank









Perfluoroundecanoic acid (PFUnDA) ug/kg < 0.5 0.5 Pass

Perfluorododecanoic acid (PFDoDA) ug/kg < 0.5 0.5 Pass



Method Blank









Method Blank








Method Blank


1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2 FTSA) ug/kg < 0.5 0.5 Pass

1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTSA) ug/kg < 0.5 0.5 Pass

1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2 FTSA) ug/kg < 0.5 0.5 Pass

1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2 FTSA) ug/kg < 0.5 0.5 Pass

LCS - % Recovery













LCS - % Recovery




ABN : 50 005 085 521 Telephone: +61 7 3902 4600

Page 38 of 50



PassLimits

QualifyingCode








LCS - % Recovery








LCS - % Recovery







LimitsPass

LimitsQualifying

Code

Spike - % Recovery













Spike - % Recovery

Perfluoroalkyl sulfonamido substances Result 1








Spike - % Recovery



ABN : 50 005 085 521 Telephone: +61 7 3902 4600

Page 39 of 50



LimitsPass

LimitsQualifying

Code

Perfluoroalkyl sulfonic acids (PFSAs) Result 1







Spike - % Recovery






Spike - % Recovery













Spike - % Recovery









Spike - % Recovery



ABN : 50 005 085 521 Telephone: +61 7 3902 4600

Page 40 of 50



LimitsPass

LimitsQualifying

Code








Spike - % Recovery






Spike - % Recovery













Spike - % Recovery









Spike - % Recovery



ABN : 50 005 085 521 Telephone: +61 7 3902 4600

Page 41 of 50



LimitsPass

LimitsQualifying

Code








Spike - % Recovery






Spike - % Recovery













Spike - % Recovery









Spike - % Recovery



ABN : 50 005 085 521 Telephone: +61 7 3902 4600

Page 42 of 50



LimitsPass

LimitsQualifying

Code








Spike - % Recovery







LimitsPass

LimitsQualifying

Code

Duplicate


Perfluorobutanoic acid (PFBA) B18-Ap04258 CP ug/kg < 0.5 < 0.5 <1 30% Pass

Perfluoropentanoic acid (PFPeA) B18-Ap04258 CP ug/kg < 0.5 < 0.5 <1 30% Pass

Perfluorohexanoic acid (PFHxA) B18-Ap04258 CP ug/kg < 0.5 < 0.5 <1 30% Pass

Perfluoroheptanoic acid (PFHpA) B18-Ap04258 CP ug/kg < 0.5 < 0.5 <1 30% Pass

Perfluorooctanoic acid (PFOA) B18-Ap04258 CP ug/kg < 0.5 < 0.5 <1 30% Pass

Perfluorononanoic acid (PFNA) B18-Ap04258 CP ug/kg < 0.5 < 0.5 <1 30% Pass

Perfluorodecanoic acid (PFDA) B18-Ap04258 CP ug/kg < 0.5 < 0.5 <1 30% Pass

Perfluoroundecanoic acid(PFUnDA) B18-Ap04258 CP ug/kg < 0.5 < 0.5 <1 30% Pass

Perfluorododecanoic acid(PFDoDA) B18-Ap04258 CP ug/kg < 0.5 < 0.5 <1 30% Pass

Perfluorotridecanoic acid (PFTrDA) B18-Ap04258 CP ug/kg < 0.5 < 0.5 <1 30% Pass

Perfluorotetradecanoic acid(PFTeDA) B18-Ap04258 CP ug/kg < 0.5 < 0.5 <1 30% Pass

Duplicate

Perfluoroalkyl sulfonamido substances Result 1 Result 2 RPD

Perfluorooctane sulfonamide(FOSA) B18-Ap04258 CP ug/kg < 0.5 < 0.5 <1 30% Pass

N-methylperfluoro-1-octanesulfonamide (N-MeFOSA) B18-Ap04258 CP ug/kg < 0.5 < 0.5 <1 30% Pass

N-ethylperfluoro-1-octanesulfonamide (N-EtFOSA) B18-Ap04258 CP ug/kg < 0.5 < 0.5 <1 30% Pass

2-(N-methylperfluoro-1-octanesulfonamido)-ethanol (N-MeFOSE) B18-Ap04258 CP ug/kg < 0.5 < 0.5 <1 30% Pass

2-(N-ethylperfluoro-1-octanesulfonamido)-ethanol (N-EtFOSE) B18-Ap04258 CP ug/kg < 0.5 < 0.5 <1 30% Pass

N-ethyl-perfluorooctanesulfonamidoaceticacid (N-EtFOSAA) B18-Ap04258 CP ug/kg < 0.5 < 0.5 <1 30% Pass

N-methyl-perfluorooctanesulfonamidoaceticacid (N-MeFOSAA) B18-Ap04258 CP ug/kg < 0.5 < 0.5 <1 30% Pass



ABN : 50 005 085 521 Telephone: +61 7 3902 4600

Page 43 of 50


Duplicate

Perfluoroalkyl sulfonic acids (PFSAs) Result 1 Result 2 RPD

Perfluorobutanesulfonic acid(PFBS) B18-Ap04258 CP ug/kg < 0.5 < 0.5 <1 30% Pass

Perfluoropentanesulfonic acid(PFPeS) B18-Ap04258 CP ug/kg < 0.5 < 0.5 <1 30% Pass

Perfluorohexanesulfonic acid(PFHxS) B18-Ap04258 CP ug/kg 1.0 0.9 10 30% Pass

Perfluoroheptanesulfonic acid(PFHpS) B18-Ap04258 CP ug/kg < 0.5 < 0.5 <1 30% Pass

Perfluorooctanesulfonic acid(PFOS) B18-Ap04258 CP ug/kg 18 17 7.0 30% Pass

Perfluorodecanesulfonic acid(PFDS) B18-Ap04258 CP ug/kg < 0.5 < 0.5 <1 30% Pass

Duplicate


1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTSA) B18-Ap04258 CP ug/kg < 0.5 < 0.5 <1 30% Pass

1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTSA) B18-Ap04258 CP ug/kg < 0.5 < 0.5 <1 30% Pass

1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTSA) B18-Ap04258 CP ug/kg < 0.5 < 0.5 <1 30% Pass

1H.1H.2H.2H-perfluorododecanesulfonic acid(10:2 FTSA) B18-Ap04258 CP ug/kg < 0.5 < 0.5 <1 30% Pass

Duplicate




Perfluorohexanoic acid (PFHxA) B18-Ap04277 CP ug/kg 1.6 1.5 1.0 30% Pass


Perfluorooctanoic acid (PFOA) B18-Ap04277 CP ug/kg 1.1 1.1 <1 30% Pass

Perfluorononanoic acid (PFNA) B18-Ap04277 CP ug/kg 1.5 1.5 2.0 30% Pass

Perfluorodecanoic acid (PFDA) B18-Ap04277 CP ug/kg 9.3 9.4 <1 30% Pass

Perfluoroundecanoic acid(PFUnDA) B18-Ap04277 CP ug/kg 21 22 4.0 30% Pass

Perfluorododecanoic acid(PFDoDA) B18-Ap04277 CP ug/kg 16 16 2.0 30% Pass

Perfluorotridecanoic acid (PFTrDA) B18-Ap04277 CP ug/kg 2.3 2.8 17 30% Pass

Perfluorotetradecanoic acid(PFTeDA) B18-Ap04277 CP ug/kg 1.8 1.7 7.0 30% Pass

Duplicate


Perfluorooctane sulfonamide(FOSA) B18-Ap04277 CP ug/kg 34 32 3.0 30% Pass









ABN : 50 005 085 521 Telephone: +61 7 3902 4600

Page 44 of 50


Duplicate


Perfluorobutanesulfonic acid(PFBS) B18-Ap04277 CP ug/kg 1.2 1.3 1.0 30% Pass

Perfluoropentanesulfonic acid(PFPeS) B18-Ap04277 CP ug/kg 1.1 1.1 5.0 30% Pass

Perfluorohexanesulfonic acid(PFHxS) B18-Ap04277 CP ug/kg 92 90 <1 30% Pass

Perfluoroheptanesulfonic acid(PFHpS) B18-Ap04277 CP ug/kg 8.8 8.2 8.0 30% Pass

Perfluorooctanesulfonic acid(PFOS) B18-Ap04277 CP ug/kg 3200 3100 <1 30% Pass

Perfluorodecanesulfonic acid(PFDS) B18-Ap04277 CP ug/kg 32 36 10 30% Pass

Duplicate




1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTSA) B18-Ap04277 CP ug/kg 3.6 3.5 1.0 30% Pass

1H.1H.2H.2H-perfluorododecanesulfonic acid(10:2 FTSA) B18-Ap04277 CP ug/kg 0.6 0.5 12 30% Pass

Duplicate




Perfluorohexanoic acid (PFHxA) B18-Ap04279 CP ug/kg 0.7 0.7 6.0 30% Pass


Perfluorooctanoic acid (PFOA) B18-Ap04279 CP ug/kg 0.6 0.6 1.0 30% Pass

Perfluorononanoic acid (PFNA) B18-Ap04279 CP ug/kg 0.5 < 0.5 5.0 30% Pass

Perfluorodecanoic acid (PFDA) B18-Ap04279 CP ug/kg 2.4 2.2 12 30% Pass

Perfluoroundecanoic acid(PFUnDA) B18-Ap04279 CP ug/kg 4.8 4.9 3.0 30% Pass

Perfluorododecanoic acid(PFDoDA) B18-Ap04279 CP ug/kg 4.8 4.6 3.0 30% Pass

Perfluorotridecanoic acid (PFTrDA) B18-Ap04279 CP ug/kg 0.9 1.0 15 30% Pass

Perfluorotetradecanoic acid(PFTeDA) B18-Ap04279 CP ug/kg 0.6 0.6 2.0 30% Pass

Duplicate


Perfluorooctane sulfonamide(FOSA) B18-Ap04279 CP ug/kg 7.0 7.2 3.0 30% Pass









ABN : 50 005 085 521 Telephone: +61 7 3902 4600

Page 45 of 50


Duplicate


Perfluorobutanesulfonic acid(PFBS) B18-Ap04279 CP ug/kg 0.6 0.5 6.0 30% Pass


Perfluorohexanesulfonic acid(PFHxS) B18-Ap04279 CP ug/kg 14 13 2.0 30% Pass

Perfluoroheptanesulfonic acid(PFHpS) B18-Ap04279 CP ug/kg 1.8 1.6 12 30% Pass

Perfluorooctanesulfonic acid(PFOS) B18-Ap04279 CP ug/kg 470 440 <1 30% Pass

Perfluorodecanesulfonic acid(PFDS) B18-Ap04279 CP ug/kg 16 14 15 30% Pass

Duplicate




1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTSA) B18-Ap04279 CP ug/kg 1.1 1.0 3.0 30% Pass


Duplicate













Duplicate











ABN : 50 005 085 521 Telephone: +61 7 3902 4600

Page 46 of 50


Duplicate




Perfluorohexanesulfonic acid(PFHxS) B18-Ap04298 CP ug/kg 1.8 1.8 3.0 30% Pass


Perfluorooctanesulfonic acid(PFOS) B18-Ap04298 CP ug/kg 43 39 10 30% Pass


Duplicate






Duplicate













Duplicate











ABN : 50 005 085 521 Telephone: +61 7 3902 4600

Page 47 of 50


Duplicate




Perfluorohexanesulfonic acid(PFHxS) B18-Ap04300 CP ug/kg < 0.3 < 0.3 <1 30% Pass


Perfluorooctanesulfonic acid(PFOS) B18-Ap04300 CP ug/kg 5.0 5.0 <1 30% Pass


Duplicate






Duplicate













Duplicate











ABN : 50 005 085 521 Telephone: +61 7 3902 4600

Page 48 of 50


Duplicate




Perfluorohexanesulfonic acid(PFHxS) B18-Ap04318 CP ug/kg < 0.3 < 0.3 <1 30% Pass


Perfluorooctanesulfonic acid(PFOS) B18-Ap04318 CP ug/kg < 0.3 0.3 2.0 30% Pass


Duplicate








ABN : 50 005 085 521 Telephone: +61 7 3902 4600

Page 49 of 50


Comments












Authorised By



Glenn Jackson







ABN : 50 005 085 521 Telephone: +61 7 3902 4600

Page 50 of 50



ABN – 50 005 085 521 e.mail : [email protected] web : www.eurofins.com.au

MelbourneMelbourneMelbourneMelbourne3-5 Kingston Town CloseOakleigh Vic 3166Phone : +61 3 8564 5000NATA # 1261Site # 1254 & 14271



PerthPerthPerthPerth2/91 Leach HighwayKewdale WA 6105Phone : +61 8 9251 9600NATA # 1261 Site # 23736

Environmental LaboratoryAir AnalysisWater AnalysisSoil Contamination Analysis

NATA AccreditationStack Emission Sampling & AnalysisTrade Waste Sampling & AnalysisGroundwater Sampling & Analysis

38 Years of Environmental Analysis & Experience38 Years of Environmental Analysis & Experience38 Years of Environmental Analysis & Experience38 Years of Environmental Analysis & Experience

Sample Receipt AdviceSample Receipt AdviceSample Receipt AdviceSample Receipt Advice

Company name: Coffey Environments Pty Ltd VICCoffey Environments Pty Ltd VICCoffey Environments Pty Ltd VICCoffey Environments Pty Ltd VIC

Contact name: Ian NewbyProject name: DOD TINDALProject ID: 754-MELEN199420 TINDALCOC number: Not providedTurn around time: 10 DayDate/Time received: Aug 17, 2018 9:00 AMEurofins | mgt reference: 612989612989612989612989

Sample informationSample informationSample informationSample information

☑ A detailed list of analytes logged into our LIMS, is included in the attached summary table.

☑ All samples have been received as described on the above COC.

☑ COC has been completed correctly.

☑ Attempt to chill was evident.

☑ Appropriately preserved sample containers have been used.

☑ All samples were received in good condition.

☑ Samples have been provided with adequate time to commence analysis in accordance with therelevant holding times.

☑ Appropriate sample containers have been used.

☑ Sample containers for volatile analysis received with zero headspace.

☑ Split sample sent to requested external lab.

☒ Some samples have been subcontracted.

N/A Custody Seals intact (if used).NotesNotesNotesNotes

0990_TV119_180815, 0990_SD279_180815 SENT TO ALS

Contact notesContact notesContact notesContact notes

If you have any questions with respect to these samples please contact:

Mary Makarios on Phone : +61 3 8564 5000 or by e.mail: [email protected]

Results will be delivered electronically via e.mail to Ian Newby - [email protected].

.Company Name: Coffey Environments Pty Ltd VIC Order No.: Received: Aug 17, 2018 9:00 AMAddress: Level 1, 436 Johnston Street Report #: 612989 Due: Aug 31, 2018


Project Name: DOD TINDALProject ID: 754-MELEN199420 TINDAL


Sample Detail

HO

LD

Moisture S

et

Per- and P


FA

Ss)

Per- and P


FA

Ss)



Brisbane Laboratory - NATA Site # 20794 X X X X


External Laboratory


Matrix LAB ID

1 0990_FH550_180814

Aug 14, 2018 Fish B18-Au23577 X

2 0990_FH551_180814

Aug 14, 2018 Meat B18-Au23578 X

3 0990_FH552_180814

Aug 14, 2018 Meat B18-Au23579 X

4 0990_FH553_180814

Aug 14, 2018 Meat B18-Au23580 X

5 0990_FH554_180814

Aug 14, 2018 Meat B18-Au23581 X

6 0990_FH555_ Aug 15, 2018 Fish B18-Au23582 X






Company Name: Coffey Environments Pty Ltd VIC Order No.: Received: Aug 17, 2018 9:00 AMAddress: Level 1, 436 Johnston Street Report #: 612989 Due: Aug 31, 2018




Sample Detail

HO

LD

Moisture S

et

Per- and P


FA

Ss)

Per- and P


FA

Ss)





180815

7 0990_FH556_180815

Aug 15, 2018 Fish B18-Au23583 X

8 0990_FH557_180815

Aug 15, 2018 Meat B18-Au23584 X

9 0990_FH558_180815

Aug 15, 2018 Meat B18-Au23585 X

10 0990_FH559_180815

Aug 15, 2018 Meat B18-Au23586 X

11 0990_FH560_180815

Aug 15, 2018 Meat B18-Au23587 X

12 0990_FH561_180815

Aug 15, 2018 Meat B18-Au23588 X

13 0990_FH562_ Aug 15, 2018 Eggs B18-Au23589 X










Sample Detail

HO

LD

Moisture S

et

Per- and P


FA

Ss)

Per- and P


FA

Ss)





180815

14 0990_FH563_180815

Aug 15, 2018 Meat B18-Au23590 X

15 0990_FH564_180815

Aug 15, 2018 Meat B18-Au23591 X

16 0990_TV112_180814

Aug 14, 2018 Meat B18-Au23592 X

17 0990_TV113_180814

Aug 14, 2018 Meat B18-Au23593 X

18 0990_TV114_180814

Aug 14, 2018 Meat B18-Au23594 X

19 0990_TV115_180814

Aug 14, 2018 Meat B18-Au23595 X

20 0990_TV116_ Aug 15, 2018 Meat B18-Au23596 X










Sample Detail

HO

LD

Moisture S

et

Per- and P


FA

Ss)

Per- and P


FA

Ss)





180815

21 0990_TV117_180815

Aug 15, 2018 Meat B18-Au23597 X

22 0990_TV118_180815

Aug 15, 2018 Meat B18-Au23598 X

23 0990_SW190_180814

Aug 14, 2018 9:00AM Water B18-Au23599 X

24 0990_SW191_180814

Aug 14, 2018 9:05AM Water B18-Au23600 X

25 0990_SW192_180815

Aug 15, 2018 10:30AM Water B18-Au23601 X

26 0990_SW193_180815

Aug 15, 2018 10:35AM Water B18-Au23602 X

27 0990_QC300_ Aug 15, 2018 10:00PM Water B18-Au23603 X










Sample Detail

HO

LD

Moisture S

et

Per- and P


FA

Ss)

Per- and P


FA

Ss)





180815

28 0990_QC301_180815

Aug 15, 2018 Water B18-Au23604 X

29 0990_QC302_180815

Aug 15, 2018 Water B18-Au23605 X

30 0990_SD276_180814

Aug 14, 2018 9:10AM Sediment B18-Au23606 X X

31 0990_SD277_180814


32 0990_SD278_180815


Test Counts 2 3 10 20






DR

AF

T




Abbotsford

VIC 3067


Report 612989-S


Project ID 754-MELEN199420 TINDAL

Received Date Aug 17, 2018

Client Sample ID 0990_FH550_180814

0990_FH551_180814

0990_FH552_180814

0990_FH553_180814

Sample Matrix Fish Meat Meat Meat

Eurofins | mgt Sample No. B18-Au23577 B18-Au23578 B18-Au23579 B18-Au23580

Date Sampled Aug 14, 2018 Aug 14, 2018 Aug 14, 2018 Aug 14, 2018














13C4-PFBA (surr.) 1 % 59 56 48 54

13C5-PFPeA (surr.) 1 % 60 61 68 57

13C5-PFHxA (surr.) 1 % 19 78 89 70

13C4-PFHpA (surr.) 1 % 32 72 86 64

13C8-PFOA (surr.) 1 % 75 64 86 59

13C5-PFNA (surr.) 1 % 92 63 101 65

13C6-PFDA (surr.) 1 % 80 54 82 56

13C2-PFUnDA (surr.) 1 % 69 53 91 51

13C2-PFDoDA (surr.) 1 % 72 50 111 46

13C2-PFTeDA (surr.) 1 % 75 52 92 48









13C8-FOSA (surr.) 1 % 58 55 70 64

D3-N-MeFOSA (surr.) 1 % 71 56 32 63

Date Reported: Aug 27, 2018


ABN : 50 005 085 521 Telephone: +61 7 3902 4600

Page 1 of 21


DR

AF

T


0990_FH551_180814

0990_FH552_180814

0990_FH553_180814

Sample Matrix Fish Meat Meat Meat





D5-N-EtFOSA (surr.) 1 % 94 73 39 79

D7-N-MeFOSE (surr.) 1 % 31 26 30 28

D9-N-EtFOSE (surr.) 1 % 35 28 25 30

D5-N-EtFOSAA (surr.) 1 % 81 54 134 53

D3-N-MeFOSAA (surr.) 1 % 87 51 108 48




Perfluorohexanesulfonic acid (PFHxS)N11 0.3 ug/kg N091.3 < 0.3 N090.4 < 0.3


Perfluorooctanesulfonic acid (PFOS)N11 0.3 ug/kg N0945 N0919 N0952 N094.8


13C3-PFBS (surr.) 1 % 42 87 91 76

18O2-PFHxS (surr.) 1 % 87 69 91 64

13C8-PFOS (surr.) 1 % 82 53 88 54






13C2-4:2 FTSA (surr.) 1 % 50 88 85 95

13C2-6:2 FTSA (surr.) 1 % 88 72 121 77

13C2-8:2 FTSA (surr.) 1 % 131 78 207 85


0990_FH555_180815

0990_FH556_180815

0990_FH557_180815

Sample Matrix Meat Fish Fish Meat
















13C4-PFBA (surr.) 1 % 37 60 60 57

13C5-PFPeA (surr.) 1 % 50 65 70 69

13C5-PFHxA (surr.) 1 % 73 23 46 72



ABN : 50 005 085 521 Telephone: +61 7 3902 4600

Page 2 of 21


DR

AF

T


0990_FH555_180815

0990_FH556_180815

0990_FH557_180815

Sample Matrix Meat Fish Fish Meat





13C4-PFHpA (surr.) 1 % 76 36 56 69

13C8-PFOA (surr.) 1 % 75 68 80 61

13C5-PFNA (surr.) 1 % 92 83 94 62

13C6-PFDA (surr.) 1 % 50 74 88 53

13C2-PFUnDA (surr.) 1 % 82 68 94 51

13C2-PFDoDA (surr.) 1 % 102 70 87 52

13C2-PFTeDA (surr.) 1 % 87 75 68 61









13C8-FOSA (surr.) 1 % 69 48 66 54

D3-N-MeFOSA (surr.) 1 % 19 62 71 46

D5-N-EtFOSA (surr.) 1 % 35 77 92 62


D9-N-EtFOSE (surr.) 1 % 10 30 31 26

D5-N-EtFOSAA (surr.) 1 % 124 77 102 50

D3-N-MeFOSAA (surr.) 1 % 98 77 104 51




Perfluorohexanesulfonic acid (PFHxS)N11 0.3 ug/kg < 0.3 0.6 N091.5 < 0.3




13C3-PFBS (surr.) 1 % 85 44 56 84

18O2-PFHxS (surr.) 1 % 85 77 90 71

13C8-PFOS (surr.) 1 % 47 62 74 55






13C2-4:2 FTSA (surr.) 1 % 72 57 75 80

13C2-6:2 FTSA (surr.) 1 % 92 88 90 64

13C2-8:2 FTSA (surr.) 1 % 170 119 143 68



ABN : 50 005 085 521 Telephone: +61 7 3902 4600

Page 3 of 21


DR

AF

T


0990_FH559_180815

0990_FH560_180815

0990_FH561_180815

Sample Matrix Meat Meat Meat Meat
















13C4-PFBA (surr.) 1 % 51 56 55 24

13C5-PFPeA (surr.) 1 % 59 68 62 34

13C5-PFHxA (surr.) 1 % 69 75 71 53

13C4-PFHpA (surr.) 1 % 68 77 64 65

13C8-PFOA (surr.) 1 % 69 69 59 73

13C5-PFNA (surr.) 1 % 76 68 59 92

13C6-PFDA (surr.) 1 % 75 61 52 90

13C2-PFUnDA (surr.) 1 % 88 67 52 84

13C2-PFDoDA (surr.) 1 % 81 56 49 109

13C2-PFTeDA (surr.) 1 % 66 54 55 67









13C8-FOSA (surr.) 1 % 77 68 50 52

D3-N-MeFOSA (surr.) 1 % 46 59 50 12

D5-N-EtFOSA (surr.) 1 % 70 81 65 15

D7-N-MeFOSE (surr.) 1 % INT 28 24 INT

D9-N-EtFOSE (surr.) 1 % 21 31 27 INT

D5-N-EtFOSAA (surr.) 1 % 96 73 50 141

D3-N-MeFOSAA (surr.) 1 % 70 58 41 99




Perfluorohexanesulfonic acid (PFHxS)N11 0.3 ug/kg < 0.3 < 0.3 < 0.3 N090.7


Perfluorooctanesulfonic acid (PFOS)N11 0.3 ug/kg N0919 N0916 N096.0 N09120


13C3-PFBS (surr.) 1 % 90 89 79 70

18O2-PFHxS (surr.) 1 % 81 77 64 84

13C8-PFOS (surr.) 1 % 79 61 50 92



ABN : 50 005 085 521 Telephone: +61 7 3902 4600

Page 4 of 21


DR

AF

T


0990_FH559_180815

0990_FH560_180815

0990_FH561_180815










13C2-4:2 FTSA (surr.) 1 % 69 85 89 37

13C2-6:2 FTSA (surr.) 1 % 109 91 75 73

13C2-8:2 FTSA (surr.) 1 % 98 84 82 156


0990_FH563_180815

0990_FH564_180815

0990_TV112_180814

Sample Matrix Eggs Meat Meat Meat
















13C4-PFBA (surr.) 1 % 52 57 12 59

13C5-PFPeA (surr.) 1 % 62 68 38 68

13C5-PFHxA (surr.) 1 % 76 72 53 81

13C4-PFHpA (surr.) 1 % 72 68 63 81

13C8-PFOA (surr.) 1 % 71 65 37 85

13C5-PFNA (surr.) 1 % 75 69 86 91

13C6-PFDA (surr.) 1 % 69 60 95 93

13C2-PFUnDA (surr.) 1 % 73 57 93 98

13C2-PFDoDA (surr.) 1 % 63 51 96 90

13C2-PFTeDA (surr.) 1 % 59 44 63 71









ABN : 50 005 085 521 Telephone: +61 7 3902 4600

Page 5 of 21


DR

AF

T


0990_FH563_180815

0990_FH564_180815

0990_TV112_180814

Sample Matrix Eggs Meat Meat Meat







13C8-FOSA (surr.) 1 % 73 65 66 84

D3-N-MeFOSA (surr.) 1 % 71 62 21 74

D5-N-EtFOSA (surr.) 1 % 95 90 27 94

D7-N-MeFOSE (surr.) 1 % 32 27 INT 27

D9-N-EtFOSE (surr.) 1 % 34 30 INT 33

D5-N-EtFOSAA (surr.) 1 % 81 58 140 124

D3-N-MeFOSAA (surr.) 1 % 66 51 95 98




Perfluorohexanesulfonic acid (PFHxS)N11 0.3 ug/kg 0.3 < 0.3 < 0.3 < 0.3


Perfluorooctanesulfonic acid (PFOS)N11 0.3 ug/kg N09140 N092.0 N0912 < 0.3


13C3-PFBS (surr.) 1 % 90 79 71 95

18O2-PFHxS (surr.) 1 % 84 73 88 96

13C8-PFOS (surr.) 1 % 62 60 81 85






13C2-4:2 FTSA (surr.) 1 % 86 86 35 93

13C2-6:2 FTSA (surr.) 1 % 91 75 46 120

13C2-8:2 FTSA (surr.) 1 % 105 100 147 129


0990_TV114_180814

0990_TV116_180815

0990_TV118_180815

















ABN : 50 005 085 521 Telephone: +61 7 3902 4600

Page 6 of 21


DR

AF

T


0990_TV114_180814

0990_TV116_180815

0990_TV118_180815








13C4-PFBA (surr.) 1 % 58 58 62 53

13C5-PFPeA (surr.) 1 % 70 73 79 72

13C5-PFHxA (surr.) 1 % 82 80 84 81

13C4-PFHpA (surr.) 1 % 86 79 81 77

13C8-PFOA (surr.) 1 % 88 73 79 79

13C5-PFNA (surr.) 1 % 100 74 81 81

13C6-PFDA (surr.) 1 % 102 65 76 75

13C2-PFUnDA (surr.) 1 % 106 64 70 72

13C2-PFDoDA (surr.) 1 % 103 58 64 64

13C2-PFTeDA (surr.) 1 % 87 59 65 66









13C8-FOSA (surr.) 1 % 88 64 74 70

D3-N-MeFOSA (surr.) 1 % 27 65 86 73

D5-N-EtFOSA (surr.) 1 % 35 86 114 96

D7-N-MeFOSE (surr.) 1 % 24 31 33 32

D9-N-EtFOSE (surr.) 1 % 29 33 35 37

D5-N-EtFOSAA (surr.) 1 % 144 66 79 80

D3-N-MeFOSAA (surr.) 1 % 89 69 82 79








13C3-PFBS (surr.) 1 % 96 95 99 95

18O2-PFHxS (surr.) 1 % 96 84 89 83

13C8-PFOS (surr.) 1 % 93 68 75 67






13C2-4:2 FTSA (surr.) 1 % 92 95 96 88



ABN : 50 005 085 521 Telephone: +61 7 3902 4600

Page 7 of 21


DR

AF

T


0990_TV114_180814

0990_TV116_180815

0990_TV118_180815






13C2-6:2 FTSA (surr.) 1 % INT 86 94 87

13C2-8:2 FTSA (surr.) 1 % 149 104 128 113



ABN : 50 005 085 521 Telephone: +61 7 3902 4600

Page 8 of 21


DR

AF

T




Per- and Polyfluoroalkyl Substances (PFASs)

Perfluoroalkyl carboxylic acids (PFCAs) Brisbane Aug 20, 2018 180 Day


Perfluoroalkyl sulfonamido substances Brisbane Aug 20, 2018 180 Day


Perfluoroalkyl sulfonic acids (PFSAs) Brisbane Aug 20, 2018 180 Day


n:2 Fluorotelomer sulfonic acids (n:2 FTSAs) Brisbane Aug 20, 2018 180 Day




ABN : 50 005 085 521 Telephone: +61 7 3902 4600

Page 9 of 21


DRAFT

.Company Name: Coffey Environments Pty Ltd VIC Order No.: Received: Aug 17, 2018 9:00 AMAddress: Level 1, 436 Johnston Street Report #: 612989 Due: Aug 31, 2018




Sample Detail

HO

LD

Moisture S

et

Per- and P


FA

Ss)

Per- and P


FA

Ss)





External Laboratory


Matrix LAB ID

1 0990_FH550_180814

Aug 14, 2018 Fish B18-Au23577 X

2 0990_FH551_180814

Aug 14, 2018 Meat B18-Au23578 X

3 0990_FH552_180814

Aug 14, 2018 Meat B18-Au23579 X

4 0990_FH553_180814

Aug 14, 2018 Meat B18-Au23580 X

5 0990_FH554_180814

Aug 14, 2018 Meat B18-Au23581 X

6 0990_FH555_ Aug 15, 2018 Fish B18-Au23582 X






Date Reported:Aug 27, 2018


ABN : 50 005 085 521 Telephone: +61 7 3902 4600

Page 10 of 21


DRAFT





Sample Detail

HO

LD

Moisture S

et

Per- and P


FA

Ss)

Per- and P


FA

Ss)





180815

7 0990_FH556_180815

Aug 15, 2018 Fish B18-Au23583 X

8 0990_FH557_180815

Aug 15, 2018 Meat B18-Au23584 X

9 0990_FH558_180815

Aug 15, 2018 Meat B18-Au23585 X

10 0990_FH559_180815

Aug 15, 2018 Meat B18-Au23586 X

11 0990_FH560_180815

Aug 15, 2018 Meat B18-Au23587 X

12 0990_FH561_180815

Aug 15, 2018 Meat B18-Au23588 X

13 0990_FH562_ Aug 15, 2018 Eggs B18-Au23589 X








ABN : 50 005 085 521 Telephone: +61 7 3902 4600

Page 11 of 21


DRAFT





Sample Detail

HO

LD

Moisture S

et

Per- and P


FA

Ss)

Per- and P


FA

Ss)





180815

14 0990_FH563_180815

Aug 15, 2018 Meat B18-Au23590 X

15 0990_FH564_180815

Aug 15, 2018 Meat B18-Au23591 X

16 0990_TV112_180814

Aug 14, 2018 Meat B18-Au23592 X

17 0990_TV113_180814

Aug 14, 2018 Meat B18-Au23593 X

18 0990_TV114_180814

Aug 14, 2018 Meat B18-Au23594 X

19 0990_TV115_180814

Aug 14, 2018 Meat B18-Au23595 X

20 0990_TV116_ Aug 15, 2018 Meat B18-Au23596 X








ABN : 50 005 085 521 Telephone: +61 7 3902 4600

Page 12 of 21


DRAFT





Sample Detail

HO

LD

Moisture S

et

Per- and P


FA

Ss)

Per- and P


FA

Ss)





180815

21 0990_TV117_180815

Aug 15, 2018 Meat B18-Au23597 X

22 0990_TV118_180815

Aug 15, 2018 Meat B18-Au23598 X

23 0990_SW190_180814

Aug 14, 2018 9:00AM Water B18-Au23599 X

24 0990_SW191_180814

Aug 14, 2018 9:05AM Water B18-Au23600 X

25 0990_SW192_180815

Aug 15, 2018 10:30AM Water B18-Au23601 X

26 0990_SW193_180815

Aug 15, 2018 10:35AM Water B18-Au23602 X

27 0990_QC300_ Aug 15, 2018 10:00PM Water B18-Au23603 X








ABN : 50 005 085 521 Telephone: +61 7 3902 4600

Page 13 of 21


DRAFT





Sample Detail

HO

LD

Moisture S

et

Per- and P


FA

Ss)

Per- and P


FA

Ss)





180815

28 0990_QC301_180815

Aug 15, 2018 Water B18-Au23604 X

29 0990_QC302_180815

Aug 15, 2018 Water B18-Au23605 X

30 0990_SD276_180814


31 0990_SD277_180814


32 0990_SD278_180815


Test Counts 2 3 10 20








ABN : 50 005 085 521 Telephone: +61 7 3902 4600

Page 14 of 21


DR

AF

T


General

Holding Times

Units

Terms




request.









































affected.

WA DWER (n=10): PFBA, PFPeA, PFHxA, PFHpA, PFOA, PFBS, PFHxS, PFOS, 6:2 FTSA, 8:2 FTSA

















ABN : 50 005 085 521 Telephone: +61 7 3902 4600

Page 15 of 21


DR

AF

T



PassLimits

QualifyingCode

Method Blank









Perfluoroundecanoic acid (PFUnDA) ug/kg < 0.5 0.5 Pass

Perfluorododecanoic acid (PFDoDA) ug/kg < 0.5 0.5 Pass



Method Blank









Method Blank








Method Blank


1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2 FTSA) ug/kg < 0.5 0.5 Pass

1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTSA) ug/kg < 0.5 0.5 Pass

1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2 FTSA) ug/kg < 0.5 0.5 Pass

1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2 FTSA) ug/kg < 0.5 0.5 Pass

LCS - % Recovery













LCS - % Recovery




ABN : 50 005 085 521 Telephone: +61 7 3902 4600

Page 16 of 21


DR

AF

T


PassLimits

QualifyingCode








LCS - % Recovery








LCS - % Recovery







LimitsPass

LimitsQualifying

Code

Spike - % Recovery


Perfluorobutanoic acid (PFBA) B18-Au23589 CP % 105 50-150 Pass

Perfluoropentanoic acid (PFPeA) B18-Au23589 CP % 102 50-150 Pass

Perfluorohexanoic acid (PFHxA) B18-Au23589 CP % 101 50-150 Pass

Perfluoroheptanoic acid (PFHpA) B18-Au23589 CP % 99 50-150 Pass

Perfluorooctanoic acid (PFOA) B18-Au23589 CP % 104 50-150 Pass

Perfluorononanoic acid (PFNA) B18-Au23589 CP % 96 50-150 Pass

Perfluorodecanoic acid (PFDA) B18-Au23589 CP % 104 50-150 Pass

Perfluoroundecanoic acid(PFUnDA) B18-Au23589 CP % 99 50-150 Pass

Perfluorododecanoic acid(PFDoDA) B18-Au23589 CP % 99 50-150 Pass

Perfluorotridecanoic acid (PFTrDA) B18-Au23589 CP % 99 50-150 Pass

Perfluorotetradecanoic acid(PFTeDA) B18-Au23589 CP % 100 50-150 Pass

Spike - % Recovery


Perfluorooctane sulfonamide(FOSA) B18-Au23589 CP % 105 50-150 Pass

N-methylperfluoro-1-octanesulfonamide (N-MeFOSA) B18-Au23589 CP % 103 50-150 Pass

N-ethylperfluoro-1-octanesulfonamide (N-EtFOSA) B18-Au23589 CP % 105 50-150 Pass

2-(N-methylperfluoro-1-octanesulfonamido)-ethanol (N-MeFOSE) B18-Au23589 CP % 101 50-150 Pass

2-(N-ethylperfluoro-1-octanesulfonamido)-ethanol (N-EtFOSE) B18-Au23589 CP % 107 50-150 Pass

N-ethyl-perfluorooctanesulfonamidoaceticacid (N-EtFOSAA) B18-Au23589 CP % 102 50-150 Pass

N-methyl-perfluorooctanesulfonamidoaceticacid (N-MeFOSAA) B18-Au23589 CP % 102 50-150 Pass

Spike - % Recovery



ABN : 50 005 085 521 Telephone: +61 7 3902 4600

Page 17 of 21


DR

AF

T


LimitsPass

LimitsQualifying

Code


Perfluorobutanesulfonic acid(PFBS) B18-Au23589 CP % 88 50-150 Pass

Perfluoropentanesulfonic acid(PFPeS) B18-Au23589 CP % 102 50-150 Pass

Perfluorohexanesulfonic acid(PFHxS) B18-Au23589 CP % 103 50-150 Pass

Perfluoroheptanesulfonic acid(PFHpS) B18-Au23589 CP % 92 50-150 Pass

Perfluorooctanesulfonic acid(PFOS) B18-Au23589 CP % 114 50-150 Pass

Perfluorodecanesulfonic acid(PFDS) B18-Au23589 CP % 94 50-150 Pass

Spike - % Recovery


1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTSA) B18-Au23589 CP % 104 50-150 Pass

1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTSA) B18-Au23589 CP % 95 50-150 Pass

1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTSA) B18-Au23589 CP % 92 50-150 Pass

1H.1H.2H.2H-perfluorododecanesulfonic acid(10:2 FTSA) B18-Au23589 CP % 93 50-150 Pass


LimitsPass

LimitsQualifying

Code

Duplicate


Perfluorobutanoic acid (PFBA) B18-Au23583 CP ug/kg < 0.5 < 0.5 <1 30% Pass

Perfluoropentanoic acid (PFPeA) B18-Au23583 CP ug/kg < 0.5 < 0.5 <1 30% Pass

Perfluorohexanoic acid (PFHxA) B18-Au23583 CP ug/kg < 0.5 < 0.5 <1 30% Pass

Perfluoroheptanoic acid (PFHpA) B18-Au23583 CP ug/kg < 0.5 < 0.5 <1 30% Pass

Perfluorooctanoic acid (PFOA) B18-Au23583 CP ug/kg < 0.5 < 0.5 <1 30% Pass

Perfluorononanoic acid (PFNA) B18-Au23583 CP ug/kg < 0.5 < 0.5 <1 30% Pass

Perfluorodecanoic acid (PFDA) B18-Au23583 CP ug/kg < 0.5 < 0.5 <1 30% Pass

Perfluoroundecanoic acid(PFUnDA) B18-Au23583 CP ug/kg < 0.5 < 0.5 <1 30% Pass

Perfluorododecanoic acid(PFDoDA) B18-Au23583 CP ug/kg < 0.5 < 0.5 <1 30% Pass

Perfluorotridecanoic acid (PFTrDA) B18-Au23583 CP ug/kg < 0.5 < 0.5 <1 30% Pass

Perfluorotetradecanoic acid(PFTeDA) B18-Au23583 CP ug/kg < 0.5 < 0.5 <1 30% Pass

Duplicate


Perfluorooctane sulfonamide(FOSA) B18-Au23583 CP ug/kg < 0.5 < 0.5 <1 30% Pass

N-methylperfluoro-1-octanesulfonamide (N-MeFOSA) B18-Au23583 CP ug/kg < 0.5 < 0.5 <1 30% Pass

N-ethylperfluoro-1-octanesulfonamide (N-EtFOSA) B18-Au23583 CP ug/kg < 0.5 < 0.5 <1 30% Pass

2-(N-methylperfluoro-1-octanesulfonamido)-ethanol (N-MeFOSE) B18-Au23583 CP ug/kg < 0.5 < 0.5 <1 30% Pass

2-(N-ethylperfluoro-1-octanesulfonamido)-ethanol (N-EtFOSE) B18-Au23583 CP ug/kg < 0.5 < 0.5 <1 30% Pass

N-ethyl-perfluorooctanesulfonamidoaceticacid (N-EtFOSAA) B18-Au23583 CP ug/kg < 0.5 < 0.5 <1 30% Pass

N-methyl-perfluorooctanesulfonamidoaceticacid (N-MeFOSAA) B18-Au23583 CP ug/kg < 0.5 < 0.5 <1 30% Pass



ABN : 50 005 085 521 Telephone: +61 7 3902 4600

Page 18 of 21


DR

AF

T

Duplicate


Perfluorobutanesulfonic acid(PFBS) B18-Au23583 CP ug/kg < 0.5 < 0.5 <1 30% Pass

Perfluoropentanesulfonic acid(PFPeS) B18-Au23583 CP ug/kg < 0.5 < 0.5 <1 30% Pass

Perfluorohexanesulfonic acid(PFHxS) B18-Au23583 CP ug/kg 1.5 1.5 3.0 30% Pass

Perfluoroheptanesulfonic acid(PFHpS) B18-Au23583 CP ug/kg < 0.5 < 0.5 <1 30% Pass

Perfluorooctanesulfonic acid(PFOS) B18-Au23583 CP ug/kg 30 30 1.0 30% Pass

Perfluorodecanesulfonic acid(PFDS) B18-Au23583 CP ug/kg < 0.5 < 0.5 <1 30% Pass

Duplicate


1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTSA) B18-Au23583 CP ug/kg < 0.5 < 0.5 <1 30% Pass

1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTSA) B18-Au23583 CP ug/kg < 0.5 < 0.5 <1 30% Pass

1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTSA) B18-Au23583 CP ug/kg < 0.5 < 0.5 <1 30% Pass

1H.1H.2H.2H-perfluorododecanesulfonic acid(10:2 FTSA) B18-Au23583 CP ug/kg < 0.5 < 0.5 <1 30% Pass

Duplicate


Perfluorobutanoic acid (PFBA) B18-Au23593 CP ug/kg < 0.5 < 0.5 <1 30% Pass

Perfluoropentanoic acid (PFPeA) B18-Au23593 CP ug/kg < 0.5 < 0.5 <1 30% Pass

Perfluorohexanoic acid (PFHxA) B18-Au23593 CP ug/kg < 0.5 < 0.5 <1 30% Pass

Perfluoroheptanoic acid (PFHpA) B18-Au23593 CP ug/kg < 0.5 < 0.5 <1 30% Pass

Perfluorooctanoic acid (PFOA) B18-Au23593 CP ug/kg < 0.5 < 0.5 <1 30% Pass

Perfluorononanoic acid (PFNA) B18-Au23593 CP ug/kg < 0.5 < 0.5 <1 30% Pass

Perfluorodecanoic acid (PFDA) B18-Au23593 CP ug/kg < 0.5 < 0.5 <1 30% Pass

Perfluoroundecanoic acid(PFUnDA) B18-Au23593 CP ug/kg < 0.5 < 0.5 <1 30% Pass

Perfluorododecanoic acid(PFDoDA) B18-Au23593 CP ug/kg < 0.5 < 0.5 <1 30% Pass

Perfluorotridecanoic acid (PFTrDA) B18-Au23593 CP ug/kg < 0.5 < 0.5 <1 30% Pass

Perfluorotetradecanoic acid(PFTeDA) B18-Au23593 CP ug/kg < 0.5 < 0.5 <1 30% Pass

Duplicate


Perfluorooctane sulfonamide(FOSA) B18-Au23593 CP ug/kg < 0.5 < 0.5 <1 30% Pass

N-methylperfluoro-1-octanesulfonamide (N-MeFOSA) B18-Au23593 CP ug/kg < 0.5 < 0.5 <1 30% Pass

N-ethylperfluoro-1-octanesulfonamide (N-EtFOSA) B18-Au23593 CP ug/kg < 0.5 < 0.5 <1 30% Pass

2-(N-methylperfluoro-1-octanesulfonamido)-ethanol (N-MeFOSE) B18-Au23593 CP ug/kg < 0.5 < 0.5 <1 30% Pass

2-(N-ethylperfluoro-1-octanesulfonamido)-ethanol (N-EtFOSE) B18-Au23593 CP ug/kg < 0.5 < 0.5 <1 30% Pass

N-ethyl-perfluorooctanesulfonamidoaceticacid (N-EtFOSAA) B18-Au23593 CP ug/kg < 0.5 < 0.5 <1 30% Pass

N-methyl-perfluorooctanesulfonamidoaceticacid (N-MeFOSAA) B18-Au23593 CP ug/kg < 0.5 < 0.5 <1 30% Pass



ABN : 50 005 085 521 Telephone: +61 7 3902 4600

Page 19 of 21


DR

AF

T

Duplicate


Perfluorobutanesulfonic acid(PFBS) B18-Au23593 CP ug/kg < 0.5 < 0.5 <1 30% Pass

Perfluoropentanesulfonic acid(PFPeS) B18-Au23593 CP ug/kg < 0.5 < 0.5 <1 30% Pass

Perfluorohexanesulfonic acid(PFHxS) B18-Au23593 CP ug/kg < 0.3 < 0.3 <1 30% Pass

Perfluoroheptanesulfonic acid(PFHpS) B18-Au23593 CP ug/kg < 0.5 < 0.5 <1 30% Pass

Perfluorooctanesulfonic acid(PFOS) B18-Au23593 CP ug/kg < 0.3 < 0.3 <1 30% Pass

Perfluorodecanesulfonic acid(PFDS) B18-Au23593 CP ug/kg < 0.5 < 0.5 <1 30% Pass

Duplicate


1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTSA) B18-Au23593 CP ug/kg < 0.5 < 0.5 <1 30% Pass

1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTSA) B18-Au23593 CP ug/kg < 0.5 < 0.5 <1 30% Pass

1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTSA) B18-Au23593 CP ug/kg < 0.5 < 0.5 <1 30% Pass

1H.1H.2H.2H-perfluorododecanesulfonic acid(10:2 FTSA) B18-Au23593 CP ug/kg < 0.5 < 0.5 <1 30% Pass



ABN : 50 005 085 521 Telephone: +61 7 3902 4600

Page 20 of 21


DR

AF

T

Comments












Authorised By



Steven Trout Senior Analyst-Metal (QLD)

Glenn Jackson







ABN : 50 005 085 521 Telephone: +61 7 3902 4600

Page 21 of 21


https://cdnmedia.eurofins.com/apac/media/601543/reporting-measurement-uncertainty-of-chemical-and-microbiology-test-results-may-2018.pdf

0 0.00 True

Environmental

CERTIFICATE OF ANALYSISWork Order : Page : 1 of 5ES1810307

:: LaboratoryClient COFFEY ENVIRONMENTS PTY LTD Environmental Division Sydney

: :ContactContact MR IAN NEWBY Angelene Kumar

:: AddressAddress LEVEL 7, TCG BUILDING 80 MITCHELL ST PO BOX 717

DARWIN NT 0801

277-289 Woodpark Road Smithfield NSW Australia 2164

:Telephone +61 03 5215 4600 :Telephone +61 2 8784 8555

:Project 754-MELEN199420 DoD Tindal Date Samples Received : 10-Apr-2018 11:00

:Order number Date Analysis Commenced : 17-Apr-2018

:C-O-C number ---- Issue Date : 08-May-2018 15:55

Sampler : Ian Dixon

Site : 2017 Blanket Quote - Primary Samples

Quote number : EN/007/16

4:No. of samples received

1:No. of samples analysed

This report supersedes any previous report(s) with this reference. Results apply to the sample(s) as submitted. This document shall not be reproduced, except in full.

This Certificate of Analysis contains the following information:

l General Comments

l Analytical Results

l Surrogate Control Limits

Additional information pertinent to this report will be found in the following separate attachments: Quality Control Report, QA/QC Compliance Assessment to assist with

Quality Review and Sample Receipt Notification.

SignatoriesThis document has been electronically signed by the authorized signatories below. Electronic signing is carried out in compliance with procedures specified in 21 CFR Part 11.

Signatories Accreditation CategoryPosition

Alex Rossi Organic Chemist Sydney Organics, Smithfield, NSW

Franco Lentini Sydney Organics, Smithfield, NSW

R I G H T S O L U T I O N S | R I G H T P A R T N E R

2 of 5:Page

Work Order :

:Client

ES1810307

754-MELEN199420 DoD Tindal:Project

COFFEY ENVIRONMENTS PTY LTD

General Comments

The analytical procedures used by the Environmental Division have been developed from established internationally recognized procedures such as those published by the USEPA, APHA, AS and NEPM. In house

developed procedures are employed in the absence of documented standards or by client request.

Where moisture determination has been performed, results are reported on a dry weight basis.

Where a reported less than (<) result is higher than the LOR, this may be due to primary sample extract/digestate dilution and/or insufficient sample for analysis.

Where the LOR of a reported result differs from standard LOR, this may be due to high moisture content, insufficient sample (reduced weight employed) or matrix interference.

When sampling time information is not provided by the client, sampling dates are shown without a time component. In these instances, the time component has been assumed by the laboratory for processing

purposes.

Where a result is required to meet compliance limits the associated uncertainty must be considered. Refer to the ALS Contact for details.

CAS Number = CAS registry number from database maintained by Chemical Abstracts Services. The Chemical Abstracts Service is a division of the American Chemical Society.

LOR = Limit of reporting

^ = This result is computed from individual analyte detections at or above the level of reporting

ø = ALS is not NATA accredited for these tests.

~ = Indicates an estimated value.

Key :

EP231X (Biota): ALS NATA accreditation for PFAS in Biota covers all Perfluoroalkyl Sulfonic Acids, Perfluoroalkyl Carboxylic Acids and (n:2) Fluorotelomer Sulfonic Acids in fish (whole and muscle), plants and

vegetable matrices, with the exception PFBA (fish only), EtFOSA, MeFOSE, EtFOSE, MeFOSAA, EtFOSAA.

l

3 of 5:Page

Work Order :

:Client

ES1810307



Analytical Results

----------------0909_TVC11_180328Client sample IDSub-Matrix: BIOTA

(Matrix: BIOTA)

----------------28-Mar-2018 00:00Client sampling date / time

--------------------------------ES1810307-010UnitLORCAS NumberCompound

Result ---- ---- ---- ----

Biota Sample Pre-Preparation

frogsø ---- ---- ---- -----------Sample Description

36.0ø ---- ---- ---- ----g0.1----Weight of Sample Prepared

EP231A: Perfluoroalkyl Sulfonic Acids

1Perfluorobutane sulfonic acid

(PFBS)

---- ---- ---- ----µg/kg1375-73-5

<1Perfluoropentane sulfonic acid

(PFPeS)

---- ---- ---- ----µg/kg12706-91-4

16Perfluorohexane sulfonic acid

(PFHxS)

---- ---- ---- ----µg/kg1355-46-4

5Perfluoroheptane sulfonic acid

(PFHpS)

---- ---- ---- ----µg/kg1375-92-8

1330Perfluorooctane sulfonic acid

(PFOS) - Linear

---- ---- ---- ----µg/kg12795-39-3

<1 ---- ---- ---- ----µg/kg1----Perfluorooctane sulfonic acid (PFOS) -

Branched

1330Perfluorooctane sulfonic acid

(PFOS)

---- ---- ---- ----µg/kg11763-23-1

167Perfluorodecane sulfonic acid

(PFDS)

---- ---- ---- ----µg/kg2335-77-3

EP231B: Perfluoroalkyl Carboxylic Acids

<5Perfluorobutanoic acid (PFBA) ---- ---- ---- ----µg/kg5375-22-4

<2Perfluoropentanoic acid (PFPeA) ---- ---- ---- ----µg/kg22706-90-3

2Perfluorohexanoic acid (PFHxA) ---- ---- ---- ----µg/kg1307-24-4

<1Perfluoroheptanoic acid (PFHpA) ---- ---- ---- ----µg/kg1375-85-9

<1Perfluorooctanoic acid (PFOA) ---- ---- ---- ----µg/kg1335-67-1

<1Perfluorononanoic acid (PFNA) ---- ---- ---- ----µg/kg1375-95-1

7Perfluorodecanoic acid (PFDA) ---- ---- ---- ----µg/kg1335-76-2

13Perfluoroundecanoic acid

(PFUnDA)

---- ---- ---- ----µg/kg12058-94-8

26Perfluorododecanoic acid

(PFDoDA)

---- ---- ---- ----µg/kg2307-55-1

15Perfluorotridecanoic acid

(PFTrDA)

---- ---- ---- ----µg/kg272629-94-8

8Perfluorotetradecanoic acid

(PFTeDA)

---- ---- ---- ----µg/kg2376-06-7

4 of 5:Page

Work Order :

:Client

ES1810307



Analytical Results

----------------0909_TVC11_180328Client sample IDSub-Matrix: BIOTA

(Matrix: BIOTA)

----------------28-Mar-2018 00:00Client sampling date / time

--------------------------------ES1810307-010UnitLORCAS NumberCompound

Result ---- ---- ---- ----

EP231C: Perfluoroalkyl Sulfonamides

<5Perfluorooctane sulfonamide

(FOSA)

---- ---- ---- ----µg/kg5754-91-6

<5N-Methyl perfluorooctane

sulfonamide (MeFOSA)

---- ---- ---- ----µg/kg531506-32-8

<2N-Ethyl perfluorooctane

sulfonamide (EtFOSA)

---- ---- ---- ----µg/kg24151-50-2


sulfonamidoethanol (MeFOSE)

---- ---- ---- ----µg/kg224448-09-7


sulfonamidoethanol (EtFOSE)

---- ---- ---- ----µg/kg21691-99-2


sulfonamidoacetic acid

(MeFOSAA)

---- ---- ---- ----µg/kg12355-31-9


sulfonamidoacetic acid

(EtFOSAA)

---- ---- ---- ----µg/kg12991-50-6

EP231D: (n:2) Fluorotelomer Sulfonic Acids

<24:2 Fluorotelomer sulfonic acid

(4:2 FTS)

---- ---- ---- ----µg/kg2757124-72-4


(6:2 FTS)

---- ---- ---- ----µg/kg227619-97-2

28:2 Fluorotelomer sulfonic acid

(8:2 FTS)

---- ---- ---- ----µg/kg239108-34-4


(10:2 FTS)

---- ---- ---- ----µg/kg2120226-60-0

EP231P: PFAS Sums

1590^ ---- ---- ---- ----µg/kg1----Sum of PFAS

EP231S: PFAS Surrogate

74.0 ---- ---- ---- ----%1----13C4-PFOS

111 ---- ---- ---- ----%1----13C8-PFOA

5 of 5:Page

Work Order :

:Client

ES1810307



Surrogate Control Limits

Recovery Limits (%)Sub-Matrix: BIOTA

Compound CAS Number Low High

EP231S: PFAS Surrogate

13C4-PFOS ---- 50 130

13C8-PFOA ---- 50 130

REPORT OF ANALYSISPage: 1 of 4

Report No. RN1184142

Client : COFFEY ENVIRONMENTS PTY LTD Job No. : COFF23/171222

LEVEL 1 Quote No. : QT-02012

436 JOHNSTON STREET Order No. :

ABBOTSFORD VIC 3067 Date Sampled : 11-DEC-2017

Date Received : 22-DEC-2017

Attention : IAN NEWBY Sampled By : CLIENT

Project Name : 754-MELEN199421TINDAL

Your Client Services Manager : Tim Reddan Phone : 03 9644 4854

Lab Reg No. Sample Ref Sample Description

N17/037257 0990_VG173_171211 VEGETATION

Lab Reg No. N17/037257

Sample Reference 0990_VG173_171211

Units Method

Perfluorinated Compounds

PFPeA (Perfluoro pentanoic acid) mg/kg <0.0005 AUTL07

PFHxA (Perfluoro hexanoic acid) mg/kg <0.0005 AUTL07

PFHpA (Perfluoro heptanoic acid) mg/kg <0.0005 AUTL07

PFOA (Perfluoro octanoic acid) mg/kg <0.0003 AUTL07

PFNA (Perfluoro nonanoic acid) mg/kg <0.0005 AUTL07

PFDA (Perfluoro decanoic acid) mg/kg <0.0005 AUTL07

PFUdA (Perfluoro undecanoic acid) mg/kg <0.0005 AUTL07

PFDoA (Perfluoro dodecanoic acid) mg/kg <0.0005 AUTL07

PFBS (Perfluoro butane sulfonic acid) mg/kg <0.0005 AUTL07

PFHxS (Perfluoro hexane sulfonic acid) mg/kg <0.0005 AUTL07

PFOS (Perfluoro octane sulfonic acid) mg/kg <0.0003 AUTL07

6:2 FTS (C2H4-perfluorooctane sulfonate) mg/kg <0.0005 AUTL07

8:2 FTS (C2H4-perfluorodecane sulfonate) mg/kg <0.0005 AUTL07

PFHxA surrogate recovery %REC 60 AUTL07

PFOA surrogate recovery %REC 57 AUTL07

PFNA surrogate recovery %REC 58 AUTL07

PFDA surrogate recovery %REC 66 AUTL07

PFUdA surrogate recovery %REC 50 AUTL07

PFDoA surrogate recovery %REC 63 AUTL07

PFHxS surrogate recovery %REC 60 AUTL07

PFOS surrogate recovery %REC 66 AUTL07

6:2 FTS surrogate recovery %REC 50 AUTL07


Date extracted 12-JAN-2018 00:00:00 AUTL07

Date analysed 17-JAN-2018 00:00:00 AUTL07

105 Delhi Road, North Ryde NSW 2113 Tel: +61 2 9449 0111 www.measurement.gov.au_______________________________________________________________________________________

N a t i o n a l M e a s u r e m e n t I n s t i t u t e





Units Method

Gavin Stevenson, Analyst

Australian Ultra Trace Laboratory

24-JAN-2018









Date Received : 22-DEC-2017





N17/037258 0990_VG180_171211 VEGETATION



Units Method












PFOS (Perfluoro octane sulfonic acid) mg/kg <0.0003 AUTL07





















Units Method



24-JAN-2018

All results are reported on a wet weight basis, and are corrected for labelled surrogate recoveries.

PFHxS and PFOS were quantified using combined branched and linear standards, for all PFAS linear and branched isomers in samples

are totalled for reporting.

Results relate only to the sample(s) tested.

This Report shall not be reproduced except in full.









Date Received : 2-JAN-2018





N18/000006 0990_FH237_171213 BIOTA 13/12/2017 PROJECT NO. 754-MELEN199421

TASK NO.TINDAL CONTAINER TYPE & PRESERVATIVE

Z/NP


Sample Reference 0990_FH237_171213

Units Method












PFOS (Perfluoro octane sulfonic acid) mg/kg 0.022 AUTL07















