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APPENDIX DHEALTH AND SAFETY PLANWR GRACE SUPERFUND SITE

ACTON MASSACHUSETTS

HSI GEOTRANS PROJECT No N099-007 MARCH 102000HSI GeoTrans inc

HSI GeoTrans inc

PROJECT NO N099

Plan Preparation

Prepared by (3Joo)

Reviewed and Approved by

Approval

HSI GeoTrans Project Manager ( 5 2 )

Health and Safety Program Manag i too)

FOR WR GRACE amp Co - CONN MWPJXXSN0992000FINA1 PHASC I RI0225 1 600 WTO HSI lllC

Workplace Hazard Assessment Certification

Hazard Assessment Prepared by

Workplace Evaluated WR Grace Superfund Site Acton Massachusetts Facility Name and Location

Date(s) of Evaluation -S^^ Date associated with plan preparation

I hereby certify on behalf of HSI GeoTrans Inc that I have assessed the above identified workplace to identify the presence of likely presence of hazards and have selected appropriate personal protective equipment for site personnel in accordance with OSHA Standard 1910132 The workplace assessed is neither owned nor operated by HSI GeoTrans therefore this assessment is based in whole or in part on information provided to the assessor by other sources

FOR WR GRACE amp Co - CONN HSI GeoTrans inc MWP DOCSN0992000F1NALPHASEIIU0225I600WPD III

TABLE OF CONTENTS

PAGE

1 INTRODUCTION APP Dl-1 11 SITE-SPECIFIC INFORMATION APP Dl-3

111 SITE CONTACTS AND PERSONNEL APPD1-3 112 EMERGENCY RESOURCES APP Dl-4

1121 EMERGENCY ROUTES APPD1-5 1122 EMERGENCY INVENTORY APPD1-6 1123 SITE EMERGENCY PROCEDURES APP Dl-6

113 BACKGROUND INFORMATION APPD1-11 1131 FACILITY DESCRIPTION APP Dl-11 1132 EXISTING CHEMICAL DATA APPD1-13 1133 CHARACTERISTICS OF CONTAMINANTS APPD1-15

2 TASK-SPECIFIC PROCEDURES APP D2-1 21 TASK 1 GROUND WATER SURFACE WATER AND SEDIMENT

SAMPLING APP D2-1 211 BOUNDARY CONTROL APPD2-1 212 DECONTAMINATION AND DISPOSAL PROCEDURES APPD2-2 213 TASK PREPARATIONSOPS APP D2-3 214 AIR MONITORING PROCEDURES APP D2-4 215 POTENTIAL HAZARDS APP D2-7 216 PERSONAL PROTECTION EQUIPMENT (PPE) APP D2-7

22 TASK 2 MONITORING WELL INSTALLATION APP D2-10 221 BOUNDARY CONTROL APP D2-10 222 DECONTAMINATION AND DISPOSAL PROCEDURES APPD2-11 223 TASK PREPARATIONSOPS APP D2-12 224 AIR MONITORING PROCEDURES APP D2-13 225 POTENTIAL HAZARDS APPD2-15 226 PERSONAL PROTECTION EQUIPMENT (PPE) APP D2-15

23 TASK 3 SUB-RIVERBED SAMPLING APP D2-18 231 BOUNDARY CONTROL APP D2-18 232 DECONTAMINATION AND DISPOSAL PROCEDURES APPD2-19 233 TASK PREPARATIONSOPS APP D2-20 234 AIR MONITORING PROCEDURES APP D2-21 235 POTENTIAL HAZARDS APPD2-23 236 PERSONAL PROTECTION EQUIPMENT (PPE) APPD2-23

FOR WR GRACE amp Co - CONN M WP_DOCSN0992000FINALPHASEIIU02251600WPO JV HSI GeOlfailS 1HC

LIST OF ATTACHMENTS

ATTACHMENT A POTENTIAL HEALTH HAZARD AND EXPOSURE RISK SCREENING

ATTACHMENT B DEFINITIONS AIR MONITORING DECONTAMINATION HEALTH AND SAFETY TRAINING MEDICAL SURVEILLANCE PROGRAM SITE CONTROL GENERAL WORKER SAFETY PROCEDURES SITE EVACUATION ROUTES AND PROCEDURES PERSONAL INJURY RESPONSE PLAN EMERGENCY OR ACCIDENT REPORT WATER SAFETY NON-PERMIT REQUIRED CONFINED SPACE ENTRY PRACTICES

ATTACHMENT C ISOPROPYL ALCOHOL NITRIC ACID (METALS SAMPLING) HYDROCHLORIC ACID AUTOMOTIVE GASOLINE OILS LUBRICATING OILS PENETRATING METHANE

ATTACHMENT D ACCIDENT AND ILLNESS INVESTIGATION REPORT AIR MONITORING LOG DAILY TAILGATE SAFETY MEETING FORM FIELD AUDIT CHECKLIST INSTRUMENT CALIBRATION LOG PLAN ACCEPTANCE FORM PREPARATION AND TESTING OF NON-PERMIT REQUIRED CONFINED SPACE PROTECTIVE EQUIPMENT INSPECTION SERIOUS NEAR-MISS INCIDENT REPORT UTILITY CLEARANCE REQUEST

ATTACHMENT E HEALTH AND SAFETY PLAN FOR ECOLOGICAL RISK ASSESSMENT

FOR WR GRACE amp Co - CONN M WP_DOCSN0992000FINAI PHASE I R]02251600 WD V HSI GeOTTanS lltC

LIST OF TABLES

PAGE

TABLE 1-1 SUMMARY OF VOCs SVOCs AND INORGANICS DETECTED APP Dl-16 TABLE 1 -2 COMPOUNDS OF MONITORING CONCERN THAT HAVE VAPOR

EXPOSURE LIMITS LESS THAN 5 PPM APP Dl-21 TABLE 2-1 SUMMARY OF RESPONSE FACTORS FOR COMPOUNDS OF

MONITORING CONCERN APP D2-26 TABLE A-1 HEALTH HAZARDS AND PHYSICAL DESCRIPTIONS OF

DETECTED COMPOUNDS ATT Al-5 TABLE A-2 EXPOSURE LIMITS AND OTHER MONITORING - RELATED

PROPERTIES OF DETECTED COMPOUNDS ATT Al-18 TABLE A-3 COMPOUNDS WITH GAS AND VAPOR EXPOSURE LIMITS LESS

THAN 5 PPM ATT Al-24 TABLE A-4 COMPOUNDS WITH PARTICULATE EXPOSURE LIMITS LESS

THAN 1 MGM3 ATT Al-25 TABLE A-5 COMPOUND LEL s AND CORRESPONDING ACTION LEVELS ATT A1 -26

FOR WR GRACE amp Co - CONN Mwp_DocsN099uoooFiNALpHASEiRro225i6oowpo vl HSI GeoTrans inc

LIST OF FIGURES

PAGE

FIGURE 1-1 HOSPITAL ROUTE MAP APP Dl-22 FIGURE 1-2 SCHEMATIC SITE MAP APP Dl-23

FOR WR GRACE amp Co - CONN M WP_DOCSW0992000FINALPHASE1RI02251600WPD VM HSI GCOlTanS IMC

LIST OF ACRONYMS AND ABBREVIATIONS

ACGIH

CA Grace HSP IDLH LFC MBTA MSDS NIOSH OSHA PEL PPE REL Site SSO STEL SVOC TLV TWA VDC VOC

American Conference of Governmental Industrial Hygienists potential occupational carcinogen according to NIOSH WR Grace amp Co - Conn Health and Safety Plan immediately dangerous to life or health lowest feasible concentration Massachusetts Bay Transportation Authority material safety data sheet National Institute for Occupational Safety and Health Occupational Health and Safety permissible exposure limits personal protective equipment Recommended exposure limits WR Grace amp Co - Conn Acton Superfund Site Site Safety Officer short term exposure limit semi-volatile organic compound threshold limit values time weighted average 11-dichloroethene volatile organic compound

FOR WR GRACE amp Co - CONN MWP DOCSN0992000FINALPHASEIRI02251600WPD V I I I HSI GeoTrans inc

1 INTRODUCTION

This Health and Safety Plan (HSP) has been designed to protect the health and

safety of project personnel and the surrounding community The purpose of the plan is to

assign responsibilities establish personal protection standards and mandatory safety

practices and procedures and provide for contingencies that may arise while operations

are being conducted at the WR Grace amp Co - Conn (Grace) Acton Superfund Site (the

Site) The HSP incorporates the Occupational Health and Safety (OSHA) requirements

presented in 29 CFR Part 1910 The selection of the level of personal protective

equipment (PPE) is based on OSHA Permissible Exposure Limits (PELs) the American

Conference of Governmental Industrial Hygienists (ACGIH) Threshold Limit Values

(TLVs) and the National Institute for Occupational Safety and Health (NIOSH)

Recommended Exposure Limits (RELs) The Workplace Hazard Assessment

Certification required by 29 CFR Part 1910132 is provided following the signature page

for this HSP Detailed information on the HSI GeoTrans comprehensive corporate health

and safety program is contained in the Terra Tech Inc Health and Safety Manual (HSI

GeoTrans is a wholly owned subsidiary of Tetra Tech) Included in this manual is

information on corporate programs including the Health and Safety Audit Program

(Volume 1 Section 1-3) and the Personnel Protective Equipment Program (Volume 1

Section 2-7)

The provisions of the HSP are mandatory for all on-Site HSI GeoTrans

employees They set forth minimum requirements for other contractors involved in the

field activities For contamination investigations it is required that each field contractor

provide a HSP for its employees covering any exposure to hazardous materials and

complete all work in accordance with that plan HSI GeoTrans maintains no

responsibility whatsoever for the safety and welfare of any on-Site personnel except for

their own employees

FOR W R GRACE amp Co - CONN APR D1-1 HSI GeoTrans inc

Section 1 of the HSP specifies site contacts emergency resources and site

background Section 2 of the HSP provides task-specific procedures for air monitoring

PPE selection decontamination and site control Attachment A contains the Chemicals

of Concern for the Site and Attachment B outlines HSI GeoTrans corporate policies

general procedures and a general guide to first aid for all work conducted at field sites

Copies of all pertinent material safety data sheets (MSDS) and field forms are given in

Attachments C and D respectively

FOR WR GRACE amp Co - CONN M wp_DocsN099uoooFiNAipHASEiRio225i6oowpo APR D1-2 HSI GeoTrans inc

11 SITE-SPECIFIC INFORMATION

111 SITE CONTACTS AND PERSONNEL

Client Name WR Grace amp Co - Conn

Address 62 Whittemore Ave Cambridge Massachusetts 02140

Client ContactPhone No Maryellen Johns (WR Grace) (617)498-2668

Site Location 51 Independence Rd Acton Massachusetts 01720

Purpose of Site Work Remedial InvestigationFeasibility Study Operable Unit

Three Implementation of the groundwater surface

water and sediment sampling programs Installation of

monitoring wells for assessment purposes Type of Project

S Hazardous Waste Water Supply UST Work

Radioactive Waste Construction Research

Non-Hazardous Site

Characterization

Proposed Site Investigation Team

Key Personnel Project Position

Anne Benjamin (978)772-7557 Ext 105 HSI GeoTrans Project Coordinator

Scott Buchanan (978)772-7557 Ext 133 HSI GeoTrans Staff Hydrogeologist

Michael Jordan (978)772-7557 Ext 132 HSI GeoTrans Project Hydrogeologist (SSO)

FOR WR GRACE amp Co - CONN MWP DOCSN0992000FINALPHASEIRMgt2251600WPD APR D1-3 HSI GeoTrans inc

112 EMERGENCY RESOURCES

Emergency Information

Site Office

Ambulance

Hospital

Police (Local or State)

Fire Department

Poison Control

Nearest Phone

Emergency Reporting Contacts

Site Safety Officer (SSO)

Client Contact

Project Coordinator

EPA Project Coordinator

State Project Coordinator

Occupational Health Physician

National Response center (for Pollution Reporting Only)

Person Responsible for Reporting Releases

NameLocation Number

Site Trailer (978)897-8642

Acton Fire Department 911

Emerson Hospital 911

Rte 2 Concord MA (978)369-1400

Acton Police Department 911

State Police (978)369-4100

Fire Emergency 911

Concord Fire Dept (Nonshy (978)369-4054

Massachusetts Center (800)682-9211


Michael Jordan HSI GeoTrans (978)772-7557

Maryellen Johns WR Grace (617)498-2668

Anne Benjamin HSI GeoTrans (978)772-7557

Derrick Golden US EPA Region I

Donald Hanson MADEP

Workcare Inc

(800)424-8426

Maryellen Johns WR Grace

FOR WR GRACE amp Co - CONN MWP DOCSN099UOOOFINAL PHASE I RI02251600 WPD APR D1-4 HSI GeoTrans inc

1121 EMERG ENCY ROUTES

To Hospital from Site Trailer

From the Site entrance proceed southwest on Independence Road to Parker Street

Take a left turn on Parker Street and proceed southwest to High Street Go left on High

Street and proceed to Route 62 take a left onto Route 62 heading east and follow to the

intersection of Route 2 Take a right onto Route 2 east Emerson hospital is on the right

side of the road at the intersection of Route 2 east and Emerson Street (see attached map

Figure 1-1)

Alternate Directions to the Hospital


Take a right on Parker Street heading north Go right on School Street heading northeast

follow to Route 2 Take a right onto Route 2 east and proceed to the intersection of

Route 2 and Emerson Street The Hospital is on the right side of the road (see attached

map Figure 1-1)

Routes checked Yes No

FOR WR GRACE amp Co - CONN MWP_DOCSN0992000FINAL PHASE 1 RJ02251600 WPD APP D1-5 HSI GCOTraHS 1I1C

1122 EMERGENCY INVENTORY

In addition to those items specified elsewhere the SSO will maintain the

following equipment and protective clothing in the event of emergencies (check all that

apply)

full-face air-purifying respirator __ potable water

and extra cartridges blankets bull chemical-resistant gloves inner

and outer

hard hats

chemical-resistant disposable boot

covers

disposable chemical resistant suit

(coated chemical resistant

TYVEK)

five minute positive pressure

escape air pack

safety glasses

bottled breathing air

washable coveralls

emergency eye-wash apparatus

(five gallon minimum if working

with corrosives or pure product)

first aid kit

fire extinguisher

1123 SITE EMERGENCY PROCEDURES

FireExplosion

A fire that cannot be readily extinguished with one ten pound fire extinguisher

will be considered major and may require evacuation of Site personnel to safe areas The

SSO will call the fire department and will coordinate with fire emergency personnel as to

the selection of protective clothing and equipment as well as the use of proper fire

FOR wR GRACE amp Co - CONN M Wgt DOCSN0992000FINA1 PHASE I RIX02251600 wpo APR D1-6 HSI GeoTrans inc

fighting techniques The air downwind from any fireexplosion is to be monitored

immediately in order to protect workers and the nearby community If so required by the

air monitoring results the Vapor Emission Response Plan will be placed into effect If

personal injuries result from any fire or explosion the procedures outlined in the Personal

Injury Response Plan will be followed

Hazardous Spill

Any release or threat of release occurring during the work that constitutes an

emergency or may present an immediate threat to public health welfare or the

environment will be reported by the SSO or clients representative to the government

parties In the event of a spill the two main goals are to contain the spill as much as

possible and to minimize vapor emissions In order to accomplish these goals the

following equipment should be available at the Site

(1) an empty container

(2) polyethylene sheets

(3) absorbent materials and

(4) a shovel

Vapor Emission Response Plan

If any of the following conditions are identified at the Site exclusion zone

boundary all activities must be halted

(1) organic levels observed on air monitoring equipment of unknown

constituents are greater than 5 ppm above known background or

action levels requiring evacuation are reached or

(2) LEL levels greater than 10

If following the cessation of activities or as the result of an emergency

such as that described in the section on FireExplosion any of the above levels

persist downwind from the Site at the boundary of the exclusion zone then this

FOR W R GRACE amp Co - CONN MWP_DOCSW0992000F1NALPHASEIRI022SI600WPD APP D1-7 HSI GfiOTfanS lllC

Emergency Plan will automatically be placed into effect Upon activation of the

Emergency Plan the nearest perimeter of the closest downwind residential or

commercial property will immediately be monitored If organic levels from an

unknown source approach 5 ppm the local police authorities or property owner

will immediately be contacted by the SSO or clients representative and advised of

the situation

Personal Injury Response Plan

Accidents - Depending on the seriousness of the injury treatment may be

given at the Site by the SSO For more serious injuries additional assistance by

ambulance may be required at the Site or the victim may have to be treated at a

medical facility The SSO will assess the seriousness of the injury and will

consult by phone with a physician if necessary The SSO will file a complete

incident report with the Office Health and Safety Officer and the Project

Coordinator as soon as possible

Chemical Overexposure - Personnel including unauthorized personnel

that suffer chemical overexposure shall be treated in the following manner

bull Skin Contact Remove contaminated clothing Wash immediately with water Use soap if available

bull Inhalation Remove from contaminated atmosphere Artificial respiration if necessary Transport to hospital

bull Ingestion Never induce vomiting on an unconscious person Also never induce vomiting when acids alkalis or petroleum products are suspected Contact the poison control center

These personnel shall be observed by the SSO to ascertain whether there

are any symptoms resulting from overexposure If there is any visible

manifestation of overexposure such as skin irritation Project Personnel should be

FOR WR GRACE amp Co - CONN MWP DOCSN0992000F1NAL PHASE I RI02251600 WPD APP D1-8 HSI GeOTfanS IRC

examined by a physician All episodes of obvious chemical contamination are to

be reviewed by the SSO in order to determine whether changes are needed in

work procedures The SSO will file a complete incident report with the Office

Health and Safety Representative and the Project Coordinator as soon as possible

Radiation

Background for ionizing radiation is normally 001 to 005 mRhr

Background levels at the site that exceed these values should be listed under

background information If levels exceed background but are less than 1 mRhr

the investigation may continue with caution If levels exceed 1 mRhr all

activities must stop and personnel must evacuate the Site or portions of the Site

that exceed 1 mRhr

FOR WR GRACE amp Co - CONN APR D1-9 HSI GeoTrans inc

Additional Physical Hazards of Site

HAZARD

RAILROAD TRACKS

SURFACE WATER

(RIVER BROOK PONDS)

WETLANDSSWAMPS

POISON IVY POISON OAK SNAKES

SPIDERS TICKS

STRESS DUE TO EXTREME

TEMPERATURE

(access weather topography)

PROCEDURES TO REDUCE RISK

Be aware of rail traffic at all times when

working in the vicinity of the Massachusetts Bay

Transportation Authority (MBTA) railroad

tracks Look in both directions prior to crossing

and do not walk on rails or stop while crossing

the tracks

Be aware of the surface water and use caution

when completing work activities located on or

adjacent to the surface water Life jackets or

buoyant work vests will be worn at all times

when working on the surface water The

buddy system and policies and procedures

outlined in Attachment B for water safety

should be implemented during work activities

located on or adjacent to the surface water

Be aware of wetland locations and use caution

when completing activities in these areas

Full body clothing will be worn at all times

Extra caution will be used when working in high

vegetation areas

Persons working outdoors may be subjected to

temperature extremes resulting in either heat

stress or cold stress upon ones body Heat

stress and cold stress are discussed in

Attachment B

FOR WR GRACE amp Co - CONN M WP DOCSVN0992000FINAL PHASE I RMJ2251600 WPO APPD1-10 HSI GeoTrans inc

113 BACKGROUND INFORMATION

Overall Risk is High Moderate _

Low Unknown

1131 FACILITY DESCRIPTION

The Site is located in Acton and Concord Massachusetts on Independence Road

The Grace property is bordered by residential property on the northwest east and west

and industrial properties to the south and northeast Fort Pond Brook bounds the Grace

property to the northwest and the Assabet River bounds the Grace property to the

southeast The Assabet well field which supplies water for the Town of Acton is located

southwest of the Grace property Two inactive sand and gravel pits Massachusetts

Broken Stone Pit and Assabet Sand and Gravel are located south of the Grace property

Former occupants of the Site include American Cyanamid Company which

manufactured explosives and Dewey amp Almy Chemical Company Dewey amp Almy

acquired the property in 1946 and manufactured synthetic rubber container sealant

products An organic chemical plant which produced latex products plasticizers and

resins commenced operation in 1949 A paper battery separator production facility was

constructed in 1951

Grace acquired Dewey and Almy in 1954 and chemical operations were

continued at the Site Grace produced materials used to make concrete and organic

chemicals container sealing compounds latex products and paper and plastic battery

separators Wastewater and solid industrial wastes from these operations were disposed

in several on-site lagoons and an on-site landfill In addition the by-products of some

chemical processes were disposed of in the Slowdown Pit located in the central portion of

the property (Figure 1-2) Discharge to these areas ceased in 1980 Production of organic

chemicals was discontinued in 1982 A small distribution center for concrete additives

(Grace Construction Products) was moved to another location in September 1996 A

FOR WR GRACE amp Co - CONN M WP_DOCSN0992000FINAL PHASE I RI022S1600 WPD APPD1-11 HSI GeOTianS lllC

second battery separator plant (Daramic) was constructed in 1979 and operations there

continued until 1991 The Daramic facility has not been considered part of the Site All

buildings with the exception of the building associated with the ARS have been

demolished

In 1978 groundwater contamination consisting mainly of 11-dichloroethene

(VDC) and lesser amounts of vinyl chloride ethylbenzene and benzene was detected in

two Acton municipal supply wells Assabet 1 and Assabet 2 located southwest of the

Grace property This discovery prompted a series of investigations which culminated in

the installation of the ARS beginning in late 1983 The ARS is a network of eleven

extraction wells designed to contain and cleanup contaminated groundwater and it is

currently operational

Following installation of the ARS extensive investigations were done by Grace

on in beneath and immediately surrounding the source areas to determine the nature and

extent of contamination by waste disposal practices Following a complete engineering

analysis of cleanup and remedial alternatives for the sources referred to as Operable

Unit-1 (OU-1) a remedy was selected for OU-1 Implementation of the remedy began in

November 1994 and was completed in July 1997 Following completion of the OU-1

remedy a comprehensive review of the groundwater quality and groundwater flow

conditions observed at the Site since the early 1980s and an evaluation of the

effectiveness of the ARS to contain and remediate groundwater affected by the Site was

done in the Initial Site Characterization Report (ISCR) (HSI GeoTrans 1998) While

data reviewed in the ISCR indicated that most areas of the Site containing groundwater

contamination are within the ARS capture zone and that contaminant concentrations in

most wells located outside of the capture zone have decreased significantly since 1984

uncertainties remain regarding the flow of groundwater and the distribution of

contaminants in certain areas of the Site The RIFS is designed to evaluate the extent of

FOR WR GRACE amp Co - CONN M wp_DocsN0992ooofiNALpnASEiRno225i6oowpo APPD1-12 HSI GeoTrans inc

groundwater contamination on- and off-Site and to determine whether additional remedial

measures are necessary to ensure accelerated restoration of the groundwater affected by

the Site to a fully usable condition

The Site property is now inactive as a manufacturing center The perimeter is

identified but due to the size is not secured Access to the Site is controlled through

locked gated entrances and exits The surrounding area is heavily wooded and restricts

the entrance of vehicles to the Site

1132 EXISTING CHEMICAL DATA

The existing historical chemical data for the Site has been compiled through a

thorough review of past activities at the Site and a review of the Site electronic database

For the purposes of this HSP only data collected after the completion of the source

removal activities will be used to evaluate health and safety concerns at the Site The

electronic database was queried in March of 1999 to determine the maximum

concentration and frequency of compounds detected in groundwater at the Site since

January 1 1996 (Table 1-1)

The volatile organic compounds (VOCs) with the highest frequency of detections

and maximum detection shown in parentheses at the Site are benzene (8600 ugL)

VDC (1000 ugL) and vinyl chloride (280 ugL) The semi-volatile organic compounds

(SVOCs) with the highest frequency of detections and maximum detection shown in

parenthesis at the Site are diethlyphthalate (110 ugL) bis(2-ethylhexyl)phthalate (120

ugL) and bis(2- chloroethyl)ether (41 ugL) The inorganic compounds with the highest

frequency of detections and maximum detection shown in parenthesis at the Site are

arsenic (13000 ugL) aluminum (42000 yUgL) nickel (890 ugL) and cadmium (16

ugL) The groundwater data collected indicate that pesticides and PCBs are not a

concern at the Site (HSI GeoTrans 1998) Therefore no pesticides or PCBs will be

monitored for during work tasks at the Site

FOR WR GRACE amp Co - CONN M WP_DOCSN0992000FINM PHASE I RI0225I600 wro APPD1-13 HSI GeOTfanS lllC

Other compounds have been detected at varying concentrations and at a wide

range of frequencies at the Site Because such a wide range of VOCs SVOCs and

inorganics have been detected at the Site it was necessary to screen these compounds for

potential health hazards and exposure risks A full discussion of the potential health

hazard and exposure risk screening is provided in Attachment A Attachment A also

includes tables which indicate the physical description and associated health hazards for

each compound detected at the Site (Attachment A Table A-l) the exposure limits and

monitoring properties for each compound detected at the Site (Attachment A Table A-2)

compounds with gas and vapor exposure limits less than 5 ppm (Attachment A Table Ashy

3) compounds with particulate exposure limits less than 1 mgm3 (Attachment A Table

A-4) and a listing of compounds with explosive limits (LELsUELs) and their

corresponding action levels (10 percent of the LEL) (Attachment A Table A-5)

Based on the screening discussed in Attachment A it was determined that the

compounds listed in Table 1-2 are contaminants of monitoring concern These

compounds have vapor exposure limits less than 5 ppm have been detected at least four

times and have a maximum detection concentration greater than 10 ppb (ugL) The

compounds found at the highest frequency and with greatest maximum concentration at

the Site benzene VDC and vinyl chloride are included in the list of compounds of

monitoring concern and comprise the lowest exposure limits Therefore benzene VDC

and vinyl chloride will be used as indicator compounds for vapor monitoring during work

tasks No dust monitoring will be conducted Work practices and investigation derived

waste (IDW) management practices will be used that will minimize the potential for

contaminated soil to be suspended in breathing space air Because vapor monitoring

action levels are lower than LEL action levels (10 percent of the LEL) no LEL

monitoring is required aside from that associated with confined space entry of the

recovery well vaults

FOR WR GRACE amp Co - CONN M WP_DOCSN0992000FWAI PHASE IR1N022S1600 WPO APPD1-14 HSI GeOTfanS lllC

1133 CHARACTERISTICS OF CONTAMINANTS

Corrosive Flammable Radioactive Inert

Toxic Volatile S Reactive Not Applicable

FOR WR GRACE amp Co - CONN M WPDOCSN0992000FINALPHASEIR102251600WPD APPD1-15 HSI GfiOTranS IflC

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Table 1-2 Compounds of monitoring concern with vapor exposure limits less than or equal to 5 ppm

PARAMETER Most Stringent HCA Exposure Limit Carcinogenicity

SVOC

VOC

14-Dichloro benzene

4-Methylphenol

Bis(2-chloroethyl)ether

Nitrobenzene

Phenol

1122-Tetrachloroethane

11-Dichloroethene

12-Dichloroethane

12-Dichloropropane

Benzene

Carbon disulfide

Chloroform

Chloromethane

Methylene chloride

Vinyl chloride

LFC(lOppm)

2 3 ppm

5 ppm

1 ppm [skin]

5 ppm

1 ppm

LFC( lppm)

1 ppm

LFC (75ppm)

0 1 ppm

1 ppm

2 ppm

LFC (50ppm)

LFC (25ppm)

LFC (1 ppm)

0 (A3)

n

3 (A3)

V) (A4)

S(A4)

n a (A3) 3 (A4)

g (A3) VI ( A l )

Notes CA indicates NIOSH (National Institute for Occupational Safety amp Health) considers substance to be potential occupational carcinogen NIOSH recommends the most protective respirators for these substances at concentrations above the MOSH recommended exposure l imi t (REL) or where there is no REL at the lowest feasible concentration (LFC)

Carcinogenicity = American Conference of Governmental Industrial Hygienists (ACGIH) Carcinogenicity Al = Confirmed human carcinogen A2 = Suspected Human carcinogen A3 = Confirmed animal carcinogen with unknown relevance to humans A4 = not classifiable as a h u m a n carcinogen AS = not suspected as a human carcinogen Most Stringent Exposure Limit The more stringent of either Occupational Safety and Health Administration (OSHA) 1989 Permissible Exposure Limit (PEL) the American Conference of Industrial Hygienists (ACGIH) Threshold Limit Value (TLV) or the MOSH REL time-weighted average (TWAs) for an 8-hour day (PEL or TLV) or for up to a 10 hour workday (REL) If NIOSH considers a substance to be a potential occupational carcinogen and there is no NIOSH REL then NIOSH recommends the lowest feasible concentrat ion (LFC) LFC compounds are noted with the most stringent OSHA PEL or ACGIH TLV in parenthesis unless no other exposure limits exist |skin| indicates the potential for dermal absorption skin exposure should be prevented as necessary through the use of good work practices and gloves coveralls goggles and other appropriate equipment Low FrequencyLow Concentration Those compounds that have been detected historically three or fewer times and at a concentration less than 10 ppb (ugL)

mgm3 milligrams per cubic meter

ppm parts per million

FOR W R GRACE Page I of 1 HSI GeoTrans inc P PROECrWRGACTONACCESS97HASP mdb - RPT_Less_5_ppm_vipor_iub5laquo

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APPROXIMATE W R GRACE PROPERTY BOUNDARY

SITE FEATURES INDUSTRIAL LANDF1LL

SECONDARY LAGOON

ACID NUTRALIZATION PIT

SLOWDOWN PIT

EMERGENCY LAGOON

PRIMARY LAGOON

BATTERY SEPARATOR AREA

NORTH LAGOON

TANK CAR AREA

MONITORING WELL (SINGLE OR CLUSTER)

AHAKT2

AMAKT (HUE BASE UAP COMPILED FROM INFORMATION PROVIDED BY CAMP DRESSER UcKEE

31000 AIL LOCATIONS ARE APPROXIMATE

HSI

Figure 1-2 Schemottc Sife Mop Original includes color coding GBOTDANS

A T C T I A T C C H C O y P A M f

h-s_SCH-smdwg

2 TASK-SPECIFIC PROCEDURES

21 TASK 1 GROUNDWATER SURFACE WATER AND SEDIMENT SAMPLING

Task Description Groundwater will be collected from monitoring wells and

surface water and sediment samples will be collected from

several surface water bodies during the RIFS Each

sample will take several hours to collect

211 BOUNDARY CONTROL

The work zone will cover several properties in and around the Site When

working in an area accessible to the public safety cones andor caution tape will be used

to delineate the work zone

FOR WR GRACE amp Co - CONN M WPJXKSN0992000FlNAlPHASElRJ0225l600WPD APR D2-1 HSI GeOTlflnS lllC

212 DECONTAMINATION AND DISPOSAL PROCEDURES

All decontamination procedures will be in accordance with OSHA regulations and

HSI GeoTrans corporate policies (Attachment B)

STATION PROTOCOL

Personnel and Equipment Rinse all non-disposable equipment which Decontamination Procedures has come in contact with contaminants

Remove boots and coveralls

Decontamination Solutions Required wateralconox isopropyl alcohol deionized water

Decontamination Equipment Required bristle brushes buckets poly-sheeting

Disposal Procedures

Fluids Decon fluids containing isopropyl alcohol will be drummed in 55-gallon E-drums

Purge water will be discharged to the ground in the vicinity of the well

Solids None Anticipated

PPE Stored in on-Site trash container for offsite disposal

FOR WR GRACE amp Co - CONN MWP DOCSN0992000FNAI PHASE IRIX02251600 WD APR D2-2 HSI GeoTrans inc

213 TASK PREPARATIONSOPS

Procedures for Utility Clearances SOP attached Yes _ No (if no describe below or justify) Permit required Yes _ No Issued by

There will be no invasive equipment or procedures utilized in the task

Procedures for Excavation SOP attached Yes _ No (if no describe below or justify) Permit required Yes _ No Issued by


Procedures for Confined space Work SOP attached Yes No (if no describe below or justify) Permit required Yes No Issued by

The vaults surrounding the groundwater recovery wells are non-permit required confined spaces See the Non-Permit Required Confined Space Entry Practices in Attachment B and the Preparation and Testing of Non-Permit Required Confined Space form in Attachment D

Procedures for Hot Work SOP attached Yes _ No (if no describe below or justify) Permit required Yes No Issued by

There are no hot work situations associated with the task

FOR W R GRACE amp Co - CONN M wp_rocsN0992oooFiNALpHASEiwo225i6oowpD APR D2-3 HSI GeoTrans inc

214 AIR MONITORING PROCEDURES Operations and Monitoring equipment checklist

TYPE OF INSTRUMENT NUMBER NEEDED CALIBRATION EQUIP

FID 1 OVA (Model 128) or 10 ppm and 9500 ppm

methane in air OVA (Model 108) 10 ppm or 100 ppm

methane in air

PID HNu(102eVlamp) 100 ppm isobutylene in

air

Dreager Pump Not Applicable

Confined Space

OxygenCombustible Gas 1 50 LEL Meter 15O2

10ppm~H2S 28 ppm CO

See Table 2-1 for a summary of response factors for compounds of monitoring concern

Potential Hazards (check all that apply) Toxic Vapors Explosion CO2 _ HS

Radiation Reactive Substances Toxic Dust Other Non-Permit Required Confined Space (Recovery Wells Vaults)

FOR WR GRACE amp Co - CONN M WP DOCSVN0992000f INA1 PHASE I RJ02251600 WPD APR D2-4 HSI GeoTrans inc

Monitoring Methods Action Levels And PPE Levels For Each Hazard 1 Toxic Vapors

Instrument

Action Level

Protocol

PPE

Action Level

Protocol

PPE

Action Level

Protocol

PPE

OVA andor HNu

Background

Monitor breathing zone periodically at a minimum of once per sampling location or as indicated by odor

Level D

l-2ppm sustained above background

If readings are consistently between 1 -2 ppm above background or greater screen for benzene VDC and vinyl chloride with detector tubes If specific compound action levels are reached (Apendix A Table A-2) use mechanical ventilation or change work practices to decrease exposure If the concentration of the screening compounds remain stop work and reevaluate otherwise Level D is sufficient

Level D

5-10 ppm above background and screening for benzene VDC and vinyl chloride are below action levels

Screen for methane with carbon tip on OVA Institute mechanical ventilation to reduce levels If levels decrease below 5 ppm and benzene VDC and vinyl chloride are not present above action levels use Level D otherwise Level C is required If Level C is used respirator cartridges must be replaced after four hours of use or daily (if respirator is used for less than four hours in one day)

Level D

FOR WR GRACE amp Co - CONN M WP DOCSN099UOOOFINAL PHASE [ RIX02251600 WTO APR D2-5 HSI GeoTrans inc

2 Confined Space (Recovery Well Vaults)

Instrument OxygenCombustible Gas Meter

Action Level O2 between 195 and 234 and Combustible gases lt 10 of lower explosive limit

Protocol Monitor all levels of space (top middle bottom) prior to entry Test every 30 minutes during first two hours then hourly afterwards while entrants within confined space

PPE Level D

Action Level O2 lt 195 or gt 234 or Combustible gases gt 10 of lower explosive limit

Protocol No entry permitted Let space ventilate and recheck parameters

PPE Level D

FOR WR GRACE amp Co - CONN M WP_DOCSN099aOOOFlNAI PHASE I RI0225i 600 WPD APP D2-6 HSI GeOltanS ItlC

215 POTENTIAL HAZARDS bull Slipping on wet muddy surfaces created by spilled water bull Exposure to vapors of volatile organic compounds bull Electrical hazards associated with the use of electrical equipment

around water or wet surfaces bull Water splashing in eyes during sampling bull Drowning due to slipping tripping or falling while sampling bull Contact with contaminated watersediment

Safe work practices (Attachment B) will be followed to prevent occurrence of these potential hazards

216 PERSONAL PROTECTION EQUIPMENT (PPE) The following checklists specify the PPE required for each level of protection that

may be necessary during the groundwater surface water and sediment sampling task The SSO shall have the authority to modify the PPE used in the field as appropriate for the conditions encountered (with consultation)

FOR W R GRACE amp Co - CONN MWP_DOCSN0992000FlNALPHASE]RI02251600wpo APP D2-7 HSI GeOiraRS 1TIC

LEVEL OF PROTECTION D FOR GROUNDWATER SURFACE WATER AND SEDIMENT SAMPLING TASK

Positive-pressure (pressure-demand) self-contained breathing apparatus (OSHANIOSH approved)

Full-face air-purifying respirator (OSHANIOSH approved) Cartridge or canister type

Half-face air purifying respirator (OSHANIOSH approved) Cartridge type

Escape mask (respirator)

Fully-encapsulating chemical-resistant suit Material

Chemical resistant clothing Type Material

Protective coveralls

Boots with steel toe and shank

Chemical resistant boot cover

Protective boots or shoes

Chemical resistant inner gloves Material Nitrile or latex

Chemical resistant outer gloves Material Nitrile

Protective gloves

Thermal Luminescent Detector (TLD) Badge for Radiation

Personal radiation detector

Dosimeter Type

Hard hat

Face shield for sampling or

Safety eye wear for sampling

Hearing protection

Two-way radio communications (intrinsically safe)

Other

FOR WR GRACE amp Co - CONN M WP_DOCSN0992000FINAL PHASE I RTi0251600 WPD APR D2-8 HSI GeoTrans inc

LEVEL OF PROTECTION C FOR GROUND WATER SURFACE WATER AND SEDIMENT SAMPLING TASK


Full-face air-purifying respirator (OSHANIOSH approved) Cartridge or canister type organic vaporacid gas




Chemical resistant clothing Type Coveralls Material Poly-coat TYVEK







Protective gloves



Dosimeter Type

Hard hat



Hearing protection


Other

FOR WR GRACE amp Co - CONN M WP DOCSN0992000FINA1 PHASE IRIW2251600 WPD APR D2-9 HSI GeoTrans inc

22 TASK 2 MONITORING WELL INSTALLATION

Task Description Soil samples and groundwater samples will be collected from soil borings installed utilizing a drill rig with auger rotosonic drive and wash andor rotary drilling capabilities Monitoring wells will be installed with a drill rig developed and sampled Drill cuttings will be field screened and either spread on ground near well or drummed sampled and stored on-site Development water will be discharged to ground near the monitoring well Installation and development of each well cluster will take from several days up to approximately two weeks


When working in an area accessible to the public safety cones andor caution tape

will be used to delineate the work zone

FOR wR GRACE amp Co - CONN M WPDOCSN099200WlNALPHASElRTl02251600 wro APPD2-10 HSI


All decontamination procedures wall be in accordance with OSHA regulations and


Personnel and Equipment Decontamination Procedures

STATION PROTOCOL



Steam clean all downhole drilling equipment

Decontamination Solutions Required Wateralconox isopropyl alcohol deionized water

Decontamination Equipment Required Bristle brush buckets poly-sheeting and steam cleaner

Disposal Procedures

Fluids Decon fluids containing isopropyl alcohol will be drummed in 55shygallon E-drums

Purge water will be released in the vicinity of the well

Solids Either spread on ground near well or placed in 55-gallon E-drum stored on-site for possible offsite disposal


FOR WR GRACE amp Co - CONN MWP DOCSN0992000FINAL PHASE I RI02251600 WPD APPD2-11 HSI GeoTrans inc

223 TASK PREPARATIONSOPS Procedures for Utility Clearances SOP attached Yes No (if no describe below or justify) Permit required Yes No Issued by

Procedures for Excavation SOP attached Yes No (if no describe below or justify) Permit required Yes No Issued by There are no excavation processes associated with the task

Procedures for Confined space Work SOP attached Yes No (if no describe below or justify) Permit required Yes No Issued by There are no confined space situations associated with the task

Procedures for Hot Work SOP attached Yes __No (if no describe below or justify) Permit required Yes No Issued by Will be provided by drilling contractor

FOR wR GRACE amp Co - CONN MWP DOCSN0992000FINA1 PHASE ]RI02251600 WPD APR D2-12 HSI GeoTrans inc





methane in air

PID 1 HNu (102eV lamp) 100 ppm isobutylene in

air

Dreager Pump and Tubes 1 Not Applicable See Table 2-1 for a summary of response factors for compounds of monitoring concern

Potential Hazards (check all that apply) Toxic Vapors Explosion CO2 H2S

Radiation Reactive Substances Toxic Dust Other

FOR WR GRACE amp Co - CONN M VT_DOCSN0992000FlNAL PHASE I Rl02251600 WPD APPD2-13 HSI GeoTfaHS U1C


Instrument

Action Level

Protocol

PPE

Action Level

Protocol

PPE

Action Level

Protocol

PPE

OVA andor HNu

Background

Monitor breathing zone periodically during drilling at a minimum of once per sampling location and development event or as indicated by odor

Level D

1-2 ppm sustained above background

If readings are consistently between 1-2 ppm above background or greater screen for benzene VDC and vinyl chloride with detector tubes If specific compound action levels are reached (Attachment A Table A-2) use mechanical ventilation or change work practices to decrease exposure If the concentration of the screening compounds remain stop work and reevaluate otherwise Level D is sufficient

Level D

5-10 ppm above background and screening for Benzene VDC and Vinyl Chloride are below action levels


Level D

FOR WR GRACE amp Co - CONN MWP DOCSN0992000F1NALPHASEIRI0225I600WPD APR D2-14 HSI GeoTrans inc

225 POTENTIAL HAZARDS bull Exposure to vapors of volatile organic compounds bull Noise levels bull Fumes (carbon monoxide) from the drill rig bull Overhead utility wires (ie electrical and telephone) when the drill

rig boom is in the upright position bull Underground pipelines and utility lines that are ruptured or

damaged during active drilling operations bull Moving parts on the drill rig which may catch clothing or free or

falling parts from the drill rig which may cause head injury bull Contact with contaminated soil



may be necessary during the monitoring well installation task The SSO shall have the authority to modify the PPE used in the field as appropriate for the conditions encountered (with consultation)

FOR W R GRACE amp Co - CONN M WP_DOCSN0992000fINAl PHASE IRA02251600 WPO APP D2-15 HSI GeOlfanS 1I1C

LEVEL OF PROTECTION D FOR MONITORING WELL INSTALLATION TASK











_ Chemical resistant inner gloves Material Nitrile or Latex


_ Protective gloves



Dosimeter Type

Hard hat



Hearing protection


Other

FOR WR GRACE amp Co - CONN M WP DOCSN0992000FINAL PHASE I RIW251600 WPD APR D2-16 HSI GeoTrans inc

LEVEL OF PROTECTION C FOR MONITORING WELL INSTALLATION TASK


Full-face air-purifying respirator (OSHANIOSH approved) Cartridge or canister type Organic vaporacid gas




Chemical resistant clothing Type Coveralls Material Polv-coated TYVEK





Chemical resistant inner gloves Material Nitrile


Protective gloves



Dosimeter Type

Hard hat



Hearing protection


Other

FOR WR GRACE amp Co - CONN MWP DOCSN0992000VFINALPHASEIRI0225I600 WPD APPD2-17 HSI GeoTrans inc

23 TASK 3 SUB-RIVERBED SAMPLING

Task Description Groundwater samples will be taken in the Assabet River by a direct push method of temporary well installation or temporary installation of passive bags Any development and purge water will be placed on the ground adjacent to the river Collection of the sub-riverbed samples will take several days


The work zone will be limited to the Assabet River adjacent to the Grace property

If working in an area accessible to the public safety cones andor caution tape will be

used to delineate the work zone

FOR W R GRACE amp Co - CONN MWP_DOCSN0992000FINALPHASE|IU0225I600WPD APP D2-18 HSI GeOTrailS IRC





STATION PROTOCOL


Remove boots and coveralls Clean all downhole equipment



Disposal Procedures

Fluids Decon fluids containing isoproyl alcohol will be drummed in 55-gallon E-drums

Purge water will be placed on the ground adjacent to the river



FOR WR GRACE amp Co - CONN M WP DOCSN0992000F1NAL PHASE I RM225I600 WPD APR D2-19 HSI GeoTrans inc


Procedures for Excavation SOP attached Yes No (if no describe below or justify) Permit required Yes S No Issued by

There are no excavation processes associated with the task


There are no confined space situations associated with the task

Procedures for Hot Work SOP attached Yes No (if no describe below or justify) Permit required Yes No Issued by


FOR wR GRACE amp Co - CONN MWP DOCSN0992000FINAL PHASE I W02251600 WPD APR D2-20 HSI GeoTrans inc





methane in air


air





Instrument OVA andor FINu

Action Level Background

Protocol Monitor breathing zone periodically at a minimum of once per sampling location or as indicated by odor

PPE Level D

Action Level l-2ppm sustained above background

Protocol If readings are consistently between 1-2 ppm above background or greater screen for benzene VDC and vinyl chloride with detector tubes If specific compound action levels are reached (Attachment A Table A-2) use mechanical ventilation or change work practices to decrease exposure If the concentration of the screening compounds remain stop work and reevaluate otherwise Level D is sufficient

FOR WR GRACE amp Co - CONN M wp_DocsN0992ooovFiNALPiiASEiwo225i6oowpo APR D2-21 HSI GeoTrans inc

PPE Level D

Action Level 5-10 ppm above background and screening for benzene VDC and vinyl chloride are below action levels

Protocol Screen for methane with carbon tip on OVA Institute mechanical ventilation to reduce levels If levels decrease below 5 ppm and benzene VDC and vinyl chloride are not present above action levels use Level D otherwise Level C is required If Level C is used respirator cartridges must be replaced after four hours of use or daily (if respirator is used for less than four hours in one day)

PPE Level D

FOR wR GRACE amp Co - CONN APP D2-22 HSI GcoTfans inc

235 POTENTIAL HAZARDS bull Slipping on wet surfaces created by spilled water bull Exposure to vapors of volatile organic compounds bull Water splashing in eyes during sampling bull Drowning due to slipping tripping or falling while sampling or

installation of the temporary wells bull Contact with contaminated watersediment



may be necessary during the sub-riverbed sampling task The Site Safety Officer shall have the authority to modify the PPE used in the field as appropriate for the conditions encountered (with consultation)

FOR WR GRACE amp Co - CONN MWP_DOCSN0992000FINALPHASE I RJN02251600 wro APP D2-23 HSI

LEVEL OF PROTECTION D FOR SUB-RIVERBED SAMPLING


Full-face air-purifying respirator (OSHANIOSH approved)

Cartridge or canister type Half-face air purifying respirator (OSHANIOSH approved)

Cartridge type Escape mask (respirator)


Chemical resistant clothing Type Material Protective coveralls




Chemical resistant inner gloves Material Nitrile or Latex


Protective gloves



Dosimeter Type

Hard hat



Hearing protection


Other Life Vest

FOR WR GRACE amp Co - CONN M WP DOCSN0992000FINAL PHASE I RMgt2251600 WTO APR D2-24 HSI GeoTrans inc

LEVEL OF PROTECTION C FOR SUB-RIVERBED SAMPLING






Chemical resistant clothing Type Coveralls Material Poly-coated TYVEK







Protective gloves



Dosimeter Type

Hard hat

_bull_



Hearing protection


Other Life Vest

FOR WR GRACE amp Co - CONN MWP DOCSN0992000FINAIPHASE|RI0225I600WPD APP D2-25 HSI GeoTrans inc

Table 2-1 Summary of response factors for compounds of monitoring concern

Compound

1 4-dichlorobenzene

4-methylphenol

bis(2-chloroethyl)ether

nitrobenzene

phenol

1 1 gt 9shy1 51 gtbullmdash T^~

tetrachloroethane

11 -dichloroethene

1 2-dichloroethane

1 2-dichloropropane

benzene

carbon disulfide

chloroform

chloromethane

methylene chloride

vinyl chloride

NA Not Available

HNul 02 eV Lamp1

119

NA

NA

NA

NA

NA

64

NA

02

10

49

NA

NA

014

32

Response Factor

Foxboro OVAshy108

NA

no response

2212

1641

1638

164

273

NA

149

056

3387

206

197

167

203

Foxboro OVAshy128

NA

no response

251

1652

4489

169

297

NA

148

054

5306

238

238

172

211

1 Molar sensitivity relative to benzene (=10) Low instrument response detectedhigh response factor calculated Volatility problem with compound

FOR WR GRACE amp Co - CONN M WP DOCSN0992000FINAL PHASE I RA0225I600 WPO APR D2-26 HSI GeoTrans inc

ATTACHMENT A

POTENTIAL HEALTH HAZARD AND EXPOSURE RISK SCREENING

FOR WR GRACE amp Co - CONN M wp_Docswo992oooFiNALpiiASE i wo225 i6oo wro ATTA1-1 HSI GeoTrans inc


The historical chemical data for the Site has been compiled through a thorough

review of past activities at the Site and a review of the Site electronic database For the

purposes of this HSP only data collected after the completion of the source removal

activities will be used to evaluate health and safety concerns at the Site The electronic

database was queried in March of 1999 to determine the maximum concentration and

frequency of compounds detected in groundwater at the Site since January 1 1996 (see

Table 1-1)

A hazard screening evaluation was performed for each compound identified in the

database search described above Table A-l indicates the associated health hazards

(exposure routes symptoms and target organs) for compounds detected at the Site and

the physical description (eg color solidliquidgas phase odor) Compounds for which

the NIOSH guide (NIOSH 1998) did not contain health hazard or physical description

information are shown with no information in the table row Some physical descriptions

for compounds were gathered from other sources (See Table A-l citation notes)

Table A-2 provides the exposure limits a summary of daily time weighted

average (Per Day TWA) and the 15 minute short term (15 min STEL) ceiling and

immediately dangerous to life or health (IDLH) exposure limits The limits shown are the

most stringent quantified exposure limits put forth by OSHA NIOSH and ACGIH for

each exposure limit category

Compounds that NIOSH considers to be potential occupational carcinogens are

designated with a check in the CA box in Tables A-2 A-3 and A-4 NIOSH usually

recommends that occupational exposures to carcinogens be limited to the lowest feasible

concentration (LFC) Those compounds NIOSH has identified as potential carcinogens

but has not quantified recommended exposure limits (REL) are designated with LFC

under the Most Stringent Exposure Limit column in Attachment A Table A-3 The

FOR WR GRACE amp Co - CONN M WP_DOCSN0992000FINA1 PHASE I RT02251600 WPD ATT A1 -2 HSI GeOTiaHS lllC

ACGIH has categorized compounds into five carcinogenicity groups based on available

information Al for confirmed human carcinogens A2 for suspected human carcinogens

A3 for confirmed animal carcinogen with unknown relevance to humans A4 for not

classifiable as a human carcinogen and A5 for compounds not suspected as a human

carcinogen The carcinogenicity category for compounds which ACGIH has designated

is also shown in Tables A-2 A-3 and A-4

The compounds that have potential air monitoring concerns for this Site are those

compounds designated in Table A-3 with LFC an ACGIH carcinogenicity of Al or A2

a gas and vapor exposure limit of 5 ppm or less or with a suspended-in-air particulate

exposure limit of 1 mgm3 or less Tables A-3 and A-4 summarize the most stringent gas

and vapor and particulate exposure limits for these compounds respectively

The compounds with gas and vapor exposure limits of 5 ppm or less which were

detected at low frequency and low concentration (three or fewer times and at a

concentration less than 10 ppb (^gL)) are not considered to be of monitoring concern

(Table A-3) The remaining compounds in Table A-3 have only been detected at

locations where the concentration of benzene VDC and vinyl chloride represent the

majority of the total concentration of chemicals with monitoring concerns Because the

exposure limits for benzene VDC and vinyl chloride are low and these compounds make

up the majority of contamination in groundwater at the Site monitoring for benzene

VDC and vinyl chloride is a conservative means to evaluate work task exposure risks

which establish action level PPE modifications In order to screen for the compounds in

Table A-3 detector tubes or other compound specific monitoring devices for the indicator

parameters (benzene VDC and vinyl chloride) will be used according to action levels

associated with the tasks to be performed

The compounds with a suspended-in-air particulate exposure limit of 1 mgm3 or

less which were detected at low frequency and low concentration (three or fewer times

and at a concentration less than 10 ppb (^gL)) are not considered to be of monitoring

FOR WR GRACE amp Co - CONN M WP_DOCSN0992000FlNALPHAbElRI02251600 WO ATTA1-3 HSI GCOTfanS 1HC

concern (Table A-4) Work practices and investigation derived waste (1DW)

management practices will be used that will minimize the potential for contaminated soil

to be suspended in breathing space air above the exposure levels for the remaining

compounds

Table A-5 is a listing of compounds with explosive limits (LELsUELs) and their

corresponding action levels (10 percent of the LEL) Because vapor monitoring action

levels are lower than LEL action levels (10 percent of the LEL) no LEL monitoring is

required

FOR wR GRACE amp Co - CONN M wp_oocsN0992oooFiNALpHASEiRio225i6oowpo ATTA1-4 HSI GeoTtans inc

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01 Sj 2 J ~ B 2 B c 5 ft a ^ a S-3 as 8 g I s iraquo o g r f l s 04 3 g sect laquo g ill II|

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vj J2 2i -^ gt IT 2 S | bullpound E g mdash bull Q O ^fl 2mdash^gt 3 5 S | 3 |S 8 || | - 1 u (5 s =laquo UJ C5 UJ C3 _S ^ z o i UÔ o ^ CJ H

c u~ gt- o laquo E pound cdeg- 1 1 _ S 1 u

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bullo s u bull0 U -n u bulla ubullo o v u o 2 S c 2 2-r So ^ -deg -o i3 = 3 o Q E o 3 -i 3 J= O 3 _ 3 mdash J3 C O 3 U 0 laquo T 0- raquogt gt 0 O C T 5 _ 3 mdash 5shy2J2 u U i-lll 2T~ bullH 1 s sect mdash gtgt 3 mdash deg mdash c deg -c 8 shya î s bull5 -s ~ sect is raquo 3 bull n =gt a1 lt = ^ CD S S -2 JS 2^1 8 g 5 = 8 s 3 S lt g

w 3 u O ~ S laquo ~ ^ ~w B H -3u -r- ffi c 13 || mdash 5 f 2 -8 c mdash laquo mdash So 2 5 o o litti Ill

o ^ 2 O 9 2 o deg deg ^ o a- -7 5 Q CJ oo ^gt tj Q 0 -0 0 E a u c31S U pound S U a U 4 U = = S

pound EI laquo U i S | 1 |O f I

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C = gt u g E mdash 1 II lilt poundbull pound-1 poundbull e-sl s laquogt o tS o traquo o -^ - gt 5

03 gtbull J3 tli5 s- 1 1 M ico - 5 C5 mdash laquo laquo 2 2 T 2 t^1 2 pound -^ b^ Q ltn Een ||||| O 3 S- E-g S 3 amp 3 amp 3 5rz mdash U UW) laquo M- s i U O O O u 3 Ifi g 11 aigt ai gt as gt lt 5 s ampbull sect-5b Q u _- 0 S _ U _ C 2

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cs gt U gt4gt gt1gt3 gt^S gt raquo ^ O fisHiLU CJ u = co E UJCJ L U O - ^ U J O UJJ3XI JS5IH

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V) M3 Ê mdash e gC

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_ u T mdash laquo an -ê 5 S oo g -r omdash ~ poundshyC C mdash C W ^ c bull C

E 3 S-S-i ON g-ô _i 0 UcJ ^-51 t r t p wi j _^ i C v 1 c i C ^ shy

vf o wf ^ i- =

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c1 -B D O - 1^^ pound a U Ugtbull ^ Z ^ û ~Zshy c

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111fcl

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Q ^ ^ 30 2 5 I degdeg 1 -t ~trade _r pound laquo o 3 ^ amp o u s bull5 ~r ^ 3 S = H ~ o3- U -^ S

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= uQgt O S degdeg e 5 igt p 2 o bull= -8 0 = ^ 5 bullo 3 O 3 w 0- u CP Os-s )mdashI

08 mdash VI

0 all gt = l-o 2 s| mdash -A Ilil

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Table A-3 Compounds with gas and vapor exposure limits less than or equal to 5 ppm Most Stringent HCA Low Frequency

PARAMETER Exposure Limit Carcinogenicity Low Concentration

SVOC 124-Tnchloro benzene 5 ppm

14-Dichlorobenzene LFC(lOppm)

4-MethylphenoI 23 ppm

B is(2-chloroethyl)ether 5 ppm

Hexachlorobutadiene 0 02 ppm [skin]

Da

D

(A3)

3 (A3)

D(A4)

a D

aa

nn nnnnnaanannanan

Hexachlorocyclopentadiene 001 ppm

Hexachloroethane 1 ppm [skin] 3 (A3)

VOC

Isophorone

N-mtrosodimethylamme

Nitrobenzene

Phenol


11-DichIoroethene

12-Dichloroethane

12-Dichloropropane

Benzene

Bromoform

Bromomethane

4 ppm

LFC

1 ppm [skin]

5 ppm

1 ppm

LFC (Ippm

1 ppm

LFC (75ppm)

0 1 ppm

0 5 ppm [skin]

LFC(lppm[skm])

3 (A3)

D(A3) D(A4)

a (A3) a(A4)

3 (A4)

Carbon disulfide 1 ppm

Carbon tetrachlonde 2 ppm

Chloroform 2 ppm

D

(A3) Chloromethane LFC (50ppm)

cis-13-dichloropropene 1 ppm [skin] 0(A4) Methylene chloride LFC (25ppm) 3 (A3) trans-13-dichloropropene 1 ppm [skin]

Vml chloride LFC (1 ppm)

Notes

a

CA indicates NIOSH (National Institute for Occupational Safety amp Health) considers substance to be potential occupational carcinogen NIOSH recommends the most protective respirators for these substances at concentrations above the NIOSH recommended exposure limit (REL) or where there is no REL at the lowest feasible concentration (LFC) Carcinogenicity = American Conference of Governmental Industrial Hygienists (ACGIH) carcinogenicity Al = Confirmed human carcinogen A2 = Suspected human carcinogen A3 = Confirmed animal carcinogen with unknown relevance to humans A4 mdash not classifiable as a human carcinogen AS = not suspected as a human carcinogen Most Stringent Exposure Limit The more stringent of either Occupational Safety and Health Administration (OSHA) 1989 Permissible Exposure Limit (PEL) the American Conference of Industrial Hygienists (ACGIH) Threshold Limit Value (TLV) or the MOSH REL time-weighted average (TWAs) for an 8-hour day (PEL or TLV) or for up to a 10 hour work day (REL) If NIOSH considers a substance to be a potential occupational carcinogen and there is no NIOSH REL then NIOSH recommends the lowest feasible concentration (LFC) LFC compounds are noted with the most stringent OSHA PEL or ACGIH TLV in parenthesis unless no other exposure limits exist [skin) indicates the potential for dermal absorption skin exposure should be prevented as necessary through the use of good work practices and gloves coveralls goggles and other appropriate equipment

Low FrequencyLow Concentration Those compounds that have been detected historically three or fewer times and at a concentration less than 10 ppb (ugL)



FOR WR GRACE of 1 HSI GeoTrans inc P PROJECRWRGACTONACCESS97HASP mdb - RPT_Lc=u_5_ppm_vapor

Table A-4 Compounds with participate exposure limits less than or equal to 1 mgrrf

Most Stringent H CA PARAMETER Exposure Limit Carcinogenicity

Inorganics Arsenic 0002 mgm3 0(A1)

Beryllium 0 0005 mgm3 0(A1)

Cadmium 0002 mgm3 D(A2)

Chromium 001 mgm3 D (Al) Copper 02 mgm3 D Iron I mgm3 D Lead 005 mgm3 n (A^) Nickel 0015 mgm3 0(A5)

svoc 24-Dimtrotoluene 02 mgm3 0(A3)

26-Dmitrotoluene 02 mgm3 0(A3)

46-Dmitro-2-Methylphenol 02 mgm3 [skin] C Acenaphthylene 0 1 mgm3 0 Anthracene 0 I mgm3

Benzo(a)anthracene 0 1 mgm3

Benzo(a)pyrene 01 mgm3 0(A2)

Benzo(b)fluoranthene 0 1 mgm3 0 (A2)

Benzo(gh i)pery lene 01 mgm3 0 Benzo(k)fluoranthene 0 1 mgm3 0 Chrysene 01 mgm3 0(A3)

Dibenz(ah)anthracene 01 mgm3 0 Fluoranthene 0 1 mgm3

Fluorene 0 1 mgm3 0 Hexach lorobenzene 0002 mgm3 [skin]

Indeno( 123-cd)pyrene 01 mgm3

Pentachlorophenol 05 mgm3 [skin]

Phenanthrene 0 1 mgm3 0 Pyrene 0 1 mgm3 0

Notes CA indicates NIOSH (National Institute for Occupational Safety amp Health) considers substance to be potential occupational carcinogen NIOSH recommends the most protective respirators for these substances at concentrations above the NIOSH recommended exposure limit (REL) or where there is no REL at the lowest feasible concentration (LFC) Carcinogenicity = American Conference of Governmental Industrial Hygienists (ACGIH) Carcinogenicity Al = Confirmed human carcinogen A2 - Suspected Human carcinogen A3 = Confirmed animal carcinogen with unknown relevance to humans A4 = not classifiable as a human carcinogen A5 = not suspected as a human carcinogen Most Stringent Exposure Limit The more stringent of either Occupational Safety and Health Administration (OSHA) 1989 Permissible Exposure Limit (PEL) the American Conference of Industrial Hygienists (ACGIH) Threshold Limit Value (TLV) or the NIOSH REL time-weighted average (TWAs) for an 8-hour day (PEL or TLV) or for up to a 10 hour work day (REL) If NIOSH considers a substance to be a potential occupational carcinogen and there is no NIOSH REL then NIOSH recommends the lowest feasible concentration (LFC) LFC compounds are noted with the most stringent OSHA PEL or ACGIH TLV in parenthesis unless no other exposure limits exist [skinj indicates the potential for dermal absorption skin exposure should be prevented as necessary through the use of good work practices and gloves coveralls goggles and other appropriate equipment mgm3 milligrams per cubic meter


FOR WRGRACE Page 1 of 1 HSI GeoTrans inc P PROreCTWRGACTONACCESS97HASP mdb - RPT_Uss_5j)pm_dust

Table A-5 Compound LELs and corresponding LEL action levels (10 of LEL)

Explosive Limit Range LEL Action Level PARAMETER LEL () UEL () () (ppm)

svoc 1 24-Tnchlorobenzene 2 50 6 60 0 25 2500 1 2-Dich lorobenzene 2 20 9 20 0 22 2200 13-Dichlorobenzene 2 02 9 20 0 20 2020 14-Dichlorobenzene 2 50 0 25 2500 4-Methylphenol 1 10 0 11 1100 Anthracene 0 60 0 06 600 Bis(2-chloroethyl)ether 2 70 0 27 2700 Bis(2-ethylhexyl)phthalate 0 30 0 03 300 Di-n-butylphthalate 0 50 0 05 500 Diethylphthalate 0 70 0 07 700 Dimethylphthalate 0 90 0 09 900 Isophorone 0 80 3 80 0 08 800 Isopropylbenzene 0 90 6 50 0 09 900 Naphthalene 0 90 5 90 0 09 900 Nitrobenzene 1 80 0 18 1800 Phenol 1 80 8 60 0 18 1800

VOC

111-Tnchloroethane 7 50 12 50 0 75 7500 11 2-Tnchloroethane 6 00 15 50 0 60 6000 11-Dichloroethane 5 40 1 1 40 0 54 5400 11-Dichloroethene 6 50 15 50 0 65 6500 1 2-Dichloroethane 6 20 1600 0 62 6200 12-Dichloroethene 5 60 12 80 0 56 5600 1 2-Dichloropropane 3 40 14 50 0 34 3400 2-Butanone 1 40 1 1 40 0 14 1400 4-Methyl-2-pentanone 1 20 8 00 0 12 1200 Acetone 2 50 12 80 0 25 2500 Benzene 1 20 7 80 0 12 1200 Bromomethane 10 00 1600 1 00 10000 Carbon dtsulfide 1 30 50 00 0 13 1300 Chlorobenzene 1 30 9 bO 0 13 1300 Chloroethane 3 80 1540 0 38 3800 Chloromethane g 10 1740 081 8100 cis-l2-dichloroethene 5 60 12 80 0 56 5600 cis- 1 3-dichloropropene 5 30 14 50 0 53 5300 Ethyl benzene 0 80 6 70 0 08 800 M-xylene 1 10 7 00 0 11 1100 Methylene chloride 1300 23 00 1 30 13000 O-xylene 0 90 6 70 0 09 900 P-xylene 1 10 7 00 0 11 1100 Styrene 0 90 6 80 0 09 900 Toluene 1 10 7 10 0 11 1100 trans- 12-dichloroethene 5 60 12 80 0 56 5600 trans- 1 3-dichloropropene 5 30 14 50 0 53 5300 Tnchloroethene 8 00 10 50 0 80 8000 Vinyl chloride 3 60 33 00 0 36 3600

FORWR GRACE Page 1 of 1 HSI GeoTrans inc P PROJECTWRGACTONACCESS9THASP mdb - RPT LELaction

ATTACHMENT B

CORPORATE POLICIES AND GENERAL PROCEDURES

FOR W R GRACE amp Co - CONN MwpDocsNts92oooFiNwPHASEiRT02251600 WPD ATTB1-1 HSI GeoTians inc

DEFINITIONS

Buddy System means a system of organizing employees into work groups in such a

manner that each employee of the work group is designated to observe the activities of at

least one other employee in the work group The purpose of the buddy system is to

provide quick assistance to those other employees in the event of an emergency

Decontamination means the removal of hazardous substances from employees and

their equipment to the extent necessary to preclude the occurrence of foreseeable adverse

health effects

Emergency Response means response to any occurrence which results or is likely

to result in a release of a hazardous substance due to an unforeseen event

Hazardous Substance means any substance designed or listed under (i) through (iv)

below exposure to which results or may result in adverse effects on the health or safety

of employees (i) any substance defined under section 101(14) of CERCLA (ii) any

biological agent or other disease-causing agent as defined in section 104(a)(2) of

CERCLA (iii) any substance listed by the US Department of Transportation and

regulated as hazardous materials under 49 CFR 172101 and appendices and (iv)

hazardous waste as defined in 40 CFR 2613 or 49 CFR 1718

Health Hazard means a chemical mixture of chemicals or a pathogen for which

there is statistically significant evidence based on at least one study conducted in

accordance with established scientific principles that acute or chronic health effects may

occur in exposed employees The term includes chemicals which are carcinogens toxic

or highly toxic agents reproductive toxins irritants corrosives sensitizes hepatotoxins

nephrotoxins neurotoxins agents which act on the hematopoietic system and agents

which damage the lungs skin eyes or mucous membranes

Immediately Dangerous to Life or Health (IDLH) means any condition that poses

an immediate threat to life or which is likely to result in acute or immediate severe health

effects This includes oxygen deficiency conditions

FOR WR GRACE amp Co - CONN M WP_DOCSVN0992000FINAL PHASE I RJ02251500 wpo ATT B1-2 HSI GeOTrailS IRC

LEL stands for the Lower Explosion Limit and means the lowest concentration by

volume of a combustible gas or vapor in air which will explode ignite or burn when

there is an ignition source

Oxygen Deficiency means that concentration of oxygen by volume below which air

supplying respiratory protection must be provided It exists in atmospheres where the

percentage of oxygen by volume is less than 195 percent oxygen

Permissible Exposure Limit (PEL-TWA) means the inhalation or dermal

permissible exposure limit as a time-weighted average specified in 29 CFR Part 1910

Subpart Z or if none is specified the exposure limits in NIOSH Recommendations for

Occupational Health Standards incorporated by reference or if neither of the above is

specified the standards specified by the American Conference of Governmental Industrial

Hygienists in their publication Threshold Limit Values and Biological Exposure Indices

for 1988-1989 incorporated by reference or if none of the above is specified a limit

based upon a published study or manufacturers safety data sheet brought to the

employers attention

Project Personnel means all persons designated to work at the Project Site by HSI

GeoTrans

Project Site means field office facilities stagingstorage area and all other areas to

which access is required for execution of the investigations

Site Safety Officer means the individual located on a site who is responsible for

implementing the site safety and health plan and verifying compliance with applicable

safety and health requirements

Survey Site means that designated portion of the Project Site where field activities

are in progress Where appropriate boundaries of the Survey Site shall be established by

the Site Safety Officer in the field as the activity progresses

Survey Site Personnel means all persons designated to work at the Survey Site by

HSI GeoTrans

FOR WR GRACE amp Co - CONN M WPJXXrSVN0992000FlNALftlASElRJ0225l600wro ATTB1-3 HSI GfiOTfanS lllC

TLV-TWA stands for the Threshold Limit ValuemdashTime-Weighted Average and

means the time-weighted average concentration for a normal 8-hour workday and 40-hour

workweek to which nearly all workers may be repeatedly exposed day after day without

adverse effect Recommended by ACGIH

FOR W R GRACE amp Co - CONN MWP DOCSN0992000FINAL PHASE IRA02251600 WPD ATT B1-4 HSI GeOTrailS IRC

AIR MONITORING

Air monitoring shall be used during hazardous waste and contamination

investigations to identify and quantify airborne levels of hazardous substances in order to

determine the appropriate level of employee protection needed on site As a first step air

monitoring shall be conducted to identify any IDLH and other dangerous situations such

as the presence of flammable atmospheres oxygen-deficient environments toxic levels of

airborne contaminants and radioactive materials As a minimum periodic monitoring

shall be conducted when

(1) Work begins on a different portion of the site

(2) Contaminants other than those previously identified are being handled

(3) A different type of operation is initiated or

(4) Workers are handling leaking containers or working in areas with obvious liquid contamination

FOR WR GRACE amp Co - CONN M wp_DocsN0992oooFiNAiPHASE iRivgt2251600 WTD ATTB1-5 HSI GeoTratis inc

DECONTAMINATION

OSHA regulations regarding decontamination at hazardous waste sites are

incorporated into this plan and include the following

(1) A decontamination procedure shall be developed and implemented before workers or equipment can go into areas where exposure to contaminants may occur

(2) Standard operating procedures shall be developed to minimize the exposure to contaminants

(3) Decontamination shall be performed in areas that will minimize the exposure of uncontaminated workers or equipment to contaminated workers or equipment

(4) All employees leaving a contaminated area shall be decontaminated all clothing and equipment leaving a contaminated area shall be appropriately disposed of or decontaminated

(5) Decontamination measures shall be monitored by the Safety Officer and shall be modified to correct any deficiencies

(6) All equipment and solvents used for decontamination shall be disposed of properly

(7) Protective clothing and equipment shall be decontaminated cleaned laundered maintained or replaced as needed to maintain their effectiveness

(8) Impermeable protective clothing which contacts or is likely to have contacted hazardous substances shall be decontaminated before being removed by the worker

(9) Employees whose non-impermeable clothing becomes wetted with hazardous substances shall immediately remove that clothing and proceed to shower The clothing shall be disposed of or decontaminated before it is removed from the work zone

FOR WR GRACE amp Co - CONN MWP DOCSN099V2000F[NAL PHASE 1RI02251600 wro ATT B1-6 HSI GeOTfaflS illC

(10) Unauthorized workers shall not remove protective clothing or equipment from change rooms

(11) Where the decontamination procedure indicates a need for showers and change rules they shall be provided and meet applicable requirements

FOR WR GRACE amp Co - CONN Mwp_oocsN0992oooFiNAiPHASEiwo225i600wro ATTB1-7 HSI GeoTrans inc

HEALTH AND SAFETY TRAINING

All hazardous waste site workers will be certified by their employer as having

received basic required health and safety training prior to working at the site Training

required by OSHA includes a minimum of forty hours of initial health and safety

instruction off the site (or equivalent prior work experience training) and a minimum of

three days of actual field experience under the direct supervision of a trained and

experienced supervisor at the time of job assignment Supervisors directly responsible

for hazardous waste site operations are to receive at least an additional eight hours of

training on managing hazardous waste site operations In addition eight hours of

refresher training are required for each year that the employee participates in site work

The required health and safety training will include but not necessarily be limited to

bull Work rules and safety requirements

bull Personal protective equipment (purpose use storage and care of)

bull Air monitoring instrumentation

bull Potential hazardous chemicals

bull Other potential hazards

bull Emergency equipment

bull Emergency procedures and response

bull Injury reporting and response

bull Personal hygiene

All site workers must read this Health and Safety Plan and attend a start-up health and

safety meeting to be held prior to commencement of field work On-site training will be

conducted as warranted and whenever the Health and Safety Plan is modified in response

to site developments

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MEDICAL SURVEILLANCE PROGRAM

A medical surveillance program shall be instituted and paid for by the employer for

all employees

(1) who are or may be exposed to hazardous substances or health hazards at or above the established permissible exposure limits for these substances without regard to the use of respirators for 30 days or more a year or

(2) who wear a respirator for 30 days or more a year or

(3) who have been exposed in an emergency situation to hazardous substances at concentrations above the permissible exposure limits

The medical surveillance program shall include a medical examination and

consultation

(1) at least once a year and

(2) as soon as possible upon notification by an employee either that the employee has developed signs or symptoms indicating possible overexposure to hazardous substances or health hazards and

(3) at more frequent times if the examining physician determines that an increased frequency of examination is medically necessary and

(4) at the termination of employment or reassignment to an area where the employee would not be covered if the employee has not had an examination within the last six months

Medical examinations shall include a medical and work history with special emphasis

on symptoms related to the handling of hazardous substances and to fitness for duty

including the ability to wear any required PPE under conditions (ie temperature

extremes) that may be expected at the work site The content of medical examinations or

consultations shall be determined by the examining physician The examining physician

shall be provided with information pertaining to the employees anticipated exposure to

chemical and health hazards prior medical examination and anticipated use of personal

FOR WR GRACE amp Co - CONN MWP _DOCSN0992000FINAL PHASE [RI02251600 WPD ATTB1-9 HSI GCOTtanS IllC

protection equipment In addition to the required medical and work history

recommended components of the first or baseline medical examination include

(1) pulmonary function test

(2) EKG

(3) chest x-ray (unless a chest x-ray has been given within 90 days prior to the medical examination and the results of that x-ray are provided to the examining physician)

(4) urinalysis

(5) blood profile

(6) hearing and vision test

Recommended components of subsequent examinations include the components

described above except for the EKG and chest x-ray unless recommended by the

examining physician In addition such examinations shall include an updated rather than

complete medical history

Following the completion of each medical examination the following actions shall be

taken

(1) In accordance with good medical practice the examining physician or other appropriate representative of the physician group shall discuss the results of such medical examination with the individual examined Such discussion shall include an explanation of the findings of the examination and as appropriate an explanation of any medical condition which the physician believes requires further evaluation or treatment and any medical condition which the physician believes would be adversely affected by such individuals employment at the site

(2) The examining physician shall notify the Safety Officer in writing that the individual has received a medical examination and shall advise as to any specific limitations upon such individuals ability to work at the site

FOR WR GRACE amp Co - CONN M wp_DocsN0992oooFiNALpHASEiRio225i6oowpD A I I B1-10 HSI GeoTrans inc

HSI GeoTrans shall maintain an accurate record of the medical surveillance program

The record shall include

(1) name and social security number of the employee

(2) physicians written opinions

(3) any employee medical complaints related to exposure to hazardous materials and

(4) a copy of the information provided by HSI GeoTrans to the examining physician

FOR W R GRACE amp Co - CONN M WP_DOCSN0992000FINALPHASEIRM2251600WPD ATTB1-11 HSI GCOTraHS IllC

SITE CONTROL

OSHA regulations regarding site control for hazardous waste site work include the

following

(1) A site control program for preventing contamination of employees shall be developed during the planning stages of a hazardous waste investigation and clean-up

(2) The site control program shall as a minimum include a site map site work zones use of a buddy system site communications safe work practices and identification of the nearest medical assistance

FOR WR GRACE amp Co - CONN M WP_DOCSN099UOOOFINA1 PHASE IWV02251600 WPD ATT B1-12 HSI GeOTfanS IllC

GENERAL WORKER SAFETY PROCEDURES

Workers will be expected to adhere to the established safety practices for their

respective specialties The need to exercise caution in the performance of work is made

more acute due to weather conditions and restrictions in mobility peripheral vision and

communication caused by the personal protective equipment To enhance site safety the

following general worker safety procedures have been established

(1) Smoking on the project site is prohibited except in specifically designated areas

(2) Eating on the project site is prohibited except in specifically designated areas

(3) In any unknown situation always assume the worst conditions and plan responses accordingly

(4) Employ the buddy system Be alert

(5) Minimize contact with contaminated materials Do not breathe in chemical odors Stay upwind of the contaminant source if possible Do not expose skin to water chemicals or soil If you get dirty or wet with contaminated fluids clean up immediately using plenty of water Designate work areas and decontamination areas and procedures to accomplish this

(6) Hands must be washed before eating drinking and smoking and before using toilets

(7) Avoid heat and other work stresses related to wearing the protective gear Work breaks should be planned to prevent stress related accidents or fatigue

(8) Maintain monitoring systems Conditions can change quickly if subsurface areas of contamination are penetrated

(9) Withdrawal from a hazardous situation to reassess procedures is the preferred course of action

(10) Shower at the end of each work day

FOR WR GRACE amp Co - CONN MWP DOCSN0992000FINAL PHASE [RIN02251600 WPD ATT B1-13 HSI G6OiranS 1T1C

(11) All Project Personnel should check for any personal habit which may allow contaminated soil or water onto or into the body Jewelry including watches shall not be worn

(12) Be aware that chemical contaminants may mimic or enhance symptoms of other illnesses or intoxication Avoid excess use of alcohol and working while ill during field investigation assignments

(13) Maintain and keep clean your personal protection equipment Check it daily to ensure that it is in good working order

(14) Wear hearing protection when large machinery and equipment in use

(15) Follow the procedures set forth in this Health and Safety Plan If a need to change the health and safety procedures arises notify the Site Safety Officer

FOR W R GRACE amp Co - CONN MWP_DOCSVN099V200(AfINAL PHASE I RI02251600 WPD ATT B1-14 HSI GeoTrailS IIIC

SITE EVACUATION ROUTES AND PROCEDURES

In the event that an emergency develops on-site the procedures delineated herein are

to be immediately followed Check the contingency plans described in Section 1 for

specific details Emergency conditions are considered to exist if

bull Any member of the field crew is involved in an accident or experiences any adverse exposure symptoms while on-site or

bull A condition is discovered that suggests the existence of a situation more hazardous than anticipated

The following emergency procedures should be followed

(1) Personnel on-site should use the buddy system (pairs) The team should prearrange hand signals or other emergency signals for communication in case of lack of radios or radio breakdown (see the following items)

bull Hand gripping throat Out of air cant breathe

bull Gripping partners wrist or placing both hands around waist Leave area immediately no debate

bull Hand on top of head Need assistance

bull Thumbs up Okay Im alright I understand

bull Thumbs down No negative

(2) Task specific work area entrance and exit routes site alarm procedures and emergency escape routes will be delineated by the Site Safety Officer (SSO) during the daily safety briefing

(3) Visual contact should be maintained between pairs on-site with the team remaining in proximity to assist each other in case of emergencies

(4) In the event that any member of the field crew experiences any adverse exposure symptoms while on-site the entire field crew should immediately halt work and act according to the instruction provided by the SSO

FOR W R GRACE amp Co - CONN MWP _DOCSN0992000FINAI PHASE IR1N02251600 wpo ATTB1-15 HSI GCOTfanS lllC

(5) If informed to evacuate the Survey Site all Survey Site Personnel shall proceed away at right angles to the wind direction and then toward an upwind assembly site at a safe distance (usually gt 100 ft) from the hazard At the assembly area the SSO will assess the condition of the Survey Site Personnel and the hazard

(6) The discovery of any condition that would suggest the existence of a situation more hazardous than anticipated should result in the re-evaluation of the hazard and the level of protection required

FOR WR GRACE amp Co - CONN M WP_DOCSVN0992000FINA1 PHASE I R10225I600 WPD ATTB1-16 HSI GeoTraHS IllC

PERSONAL INJURY RESPONSE PLAN

Accidents

Physical injuries can range from a sprained ankle to a compound fracture or from a

minor cut to massive bleeding Depending on the seriousness of the injury treatment

may be given at the site by the Site Safety Officer For more serious injuries additional

assistance by ambulance may be required at the site or the victim may have to be treated

at a medical facility The Safety Officer will assess the seriousness of the injury and will

consult by phone with a physician if necessary

Chemical Exposure

Personnel including unauthorized personnel that suffer chemical overexposure shall

be treated in the following manner


bull Inhalation Remove from contaminated atmosphere Artificial respiration is necessary Transport to hospital


bull Ionizing Radiation Normal background 001 to 005 mRhr If less than 1 mRhr continue investigation with caution If greater than 1 mRhr evacuate site

These personnel shall be observed by the Site Safety Officer to ascertain whether

there are any symptoms resulting from overexposure If there is any visible manifestation

of overexposure such as skin irritation Project Personnel should be examined by a

physician All episodes of obvious chemical contamination are to be reviewed by the Site

Safety Officer in order to determine whether changes are needed in work procedures

FOR WR GRACE amp Co - CONN M wp_DocsN0992ooofiNALpnASEiiuo225i6oowpD ATT B1-17 HSI GcoTrflns inc

Cold Stress

Persons working outdoors in temperatures at or below freezing may be frostbitten

Exposure to extreme cold for a short time may cause severe injury to the surface of the

body or result in profound generalized cooling causing death Areas of the body that

have a high surface-area-to-volume ratio such as fingers toes and ears are the most

susceptible Two factors influence the development of a cold injury ambient temperature

and the velocity of the wind Wind chill is used to describe the chilling effect of moving

air in combination with low temperature For instance 10degF with a wind of 15 mph is

equivalent in chilling effect to still air at -18degF

As a general rule the greatest incremental increase in wind chill occurs when a wind

of 5 mph increases to 10 mph Additionally water conducts heat 240 times faster than

air Thus the body cools suddenly when chemical-protective equipment is removed if the

clothing underneath is soaked with perspiration Local injury resulting from cold is

included in the generic term frostbite There are several degrees of damage

Systemic hypothermia is caused by exposure to freezing or rapidly dropping

temperature Its symptoms are usually exhibited in five stages (1) shivering (2) apathy

listlessness sleepiness and (sometimes) rapid cooling of the body to less than 95 degF (3)

unconsciousness glassy stare slow pulse and slow respiratory rate (4) freezing of the

extremities and finally (5) death

Prevention of Cold Stress can be achieved by (1) Modification of work schedules as

required by site conditions and personnel monitoring (2) Provision of shelters to protect

workers during rest periods (3) Maintenance of body heat at normal levels by wearing

adequate layers of clothing (4) Training site personnel to recognize and treat cold stress

(5) Frequent warm up breaks (6) Acclimation

Heat Stress

Wearing personal protective equipment puts a field worker at considerable risk of

developing heat stress This can result in health effects ranging from transient heat

fatigue to serious illness or death Heat stress is an aggregate of all the heat factors both

internal and external that work on the body

FOR WR GRACE amp Co - CONN MWP_DOCSNON2000F[NALP11ASEIRI0225600WPO ATT B1-18 HSI GCOTfanS IHC

External factors that contribute to heat stress include ambient air temperature

radiant temperature air velocity and the relative humidity Internal factors include

metabolic heat body core temperature respiration rate and acclimation

Early symptoms of heat stress include mental confusion and the inability to

concentrate heat rash and heat cramps (muscle spasms andor pain in hands feet and

abdomen) Acute and chronic heat stress impacts a workers temperament causing

impulsive aggressive and violent acts to be committed by the victim Signs of heat

exhaustion include pale cool moist skin heavy sweating dizziness nausea and fainting

Heat stroke is the most serious form of heat stress Immediate action must be taken to

cool the body and prevent serious injury Competent medical help must be obtained

Signs include red hot dry skin lack of or reduced perspiration nausea dizziness and

confusion strong rapid pulse and coma The case-fatality of heat-stroke and heat

exhaustion is probably no lower than 10 percent Because heat stress is one of the most

common (and potentially serious) illnesses at field sites regular monitoring and other

preventative precautions are vital

To monitor for heat stress measure

(1) Heart rate mdash Count the radial pulse during a 30-second period as early as possible during rest periods If the heart exceeds 110 beats per minute at the beginning of the rest period shorten the next work cycle by one-third and keep the rest period the same If the heart rate still exceeds 110 beats per minute at the next rest period shorten the following work cycle by one-third again

(2) Oral temperatures mdash Use an oral thermometer to measure the oral temperature at the end of the work period (before drinking) If oral temperature exceeds 996 degrees F shorten the next work cycle by one-third without changing the rest period Repeat if necessary Do not permit a worker to wear PPE when the workers oral temperature is above 1006 degrees F

(3) Body weight mdash If possible measure weight at the beginning and end of each day to see if enough fluids are being taken during the day The body water loss should not exceed 15 percent of total body weight in a work day

FOR WR GRACE amp Co - CONN M wp_DocsN099v2oooFiNALpHASFinjo22si6oowpD A I I B1-19 HSI GeoTrans inc

Prevention of heat stress can be achieved by

(1) Modification of work schedules as required by site conditions and personnel monitoring

(2) Provision of shelters or shaded areas to protect workers during rest periods

(3) Maintenance of body fluids at normal levels by drinking cold water and

(4) Training Site Personnel to recognize and treat heat stress signs

(5) Acclimation

First Aid

Bites (Animal) mdash Thoroughly wash the wound with soap and water Flush the area with running water and apply a sterile dressing Immobilize affected part until the victim has been attended by a physician See that the animal is kept alive and in quarantine Obtain name and address of the owner of the animal

Bites (Insect) ~ Remove stinger if present Keep affected part down below the level of the heart Apply ice bag For minor bites and stings apply soothing lotions such as calamine

Burns (minor) ~ Do not apply Vaseline or grease of any kind Apply cold water applications until pain subsides Cover with a dry sterile gauze dressing Do not break blisters or remove tissue Seek medical attention

Burns (severe) mdash Do not remove adhered particles of clothing Do not apply ice or immerse in cold water Do not apply ointment grease or Vaseline Cover burns with thick sterile dressings Keep burned feet or legs elevated Seek medical attention immediately

Chemical Burns ~ Wash away the chemical soaked clothing with large amounts of water Remove victims chemical soaked clothing If dry lime brush away before flushing Apply sterile dressing and seek medical attention

Cramps ~ Same as for heat exhaustion

Cuts ~ Apply pressure with sterile gauze dressing and elevate the area until bleeding stops Apply a bandage and seek medical attention

FOR WR GRACE amp Co - CONN MWP DOCSN0992000F[NAL PHASE I RTi02251600 WPD ATT B1-20 HSI GeoTianS IflC

Eyes (Foreign Objects) mdash Keep the victim from rubbing his eye Flush the eye with water If flushing fails to remove the object apply a dry protective dressing and consult a physician

Eyes (Chemicals) mdash Flood the eye thoroughly with water for fifteen minutes Cover the eye with a dry pad and seek medical attention

Fainting ~ Keep the victim lying down Loosen tight clothing If victim vomits roll him onto his side or turn his head to the side If necessary wipe out his mouth Maintain an open airway Bathe his face gently with cool water Unless recovery is prompt seek medical attention

Fracture mdash Deformity of an injured part usually means a fracture If fracture is suspected splint the part Do not attempt to move the injured person Seek medical attention immediately

Heat Exhaustion ~ Symptoms include near normal body temperature skin is pale and clammy profuse sweating tiredness weakness headache perhaps cramps nausea dizziness and possible fainting Treatment Keep in lying position and raise victims feet Loosen clothing apply cool wet clothes If conscious give sips of salt water (1 teaspoon of salt per glass) over a period of one hour If vomiting occurs discontinue the salt water Seek medical attention

Heatstroke mdash Symptoms include high body temperature (106 degrees F or higher) hot red dry skin rapid and strong pulse Victim may be unconscious Treatment Keep victim in lying position with head elevated Remove clothing and repeatedly sponge the bare skin with cool water or alcohol Seek medical attention immediately

Poisoning ~ Call the poison control center for instruction on immediate care If victim becomes unconscious keep the airway open If breathing stops give artificial respiration by mouth to mouth breathing Call an emergency squad as soon as possible

Poison Ivy ~ Remove contaminated clothing wash all exposed areas thoroughly with soap and water followed by rubbing alcohol If rash is mild apply calamine or other soothing skin lotion If a severe reaction occurs seek medical attention

Puncture Wounds mdash If puncture wound is deeper than skin surface seek medical attention Serious infection can arise unless proper treatment is received

Sprains ~ Elevate injured part and apply ice bag or cold packs Do not soak in hot water If pain and swelling persists seek medical attention

FOR WR GRACE amp Co - CONN M wpjxxrsN0992oooFiNALpiiASEiiuo225i600 wo A i l B1-21 HSI GeoTrans inc

Unconsciousness mdash Never attempt to give anything by mouth Keep victim lying flat maintain open airway If victim is not breathing provide artificial respiration by mouth to mouth breathing and call an emergency squad as soon as possible

FOR WR GRACE amp Co - CONN MWP_DocsNow2oooFiNAi PHASE i wo2251600 wo ATTB1-22 HSI GcoTrans inc

EMERGENCY OR ACCIDENT REPORT

In the event that an accident occurs the Site Safety Officer and the injured person are

to complete an Incident Report (copy of form provided in Attachment D) for submittal to

HSI GeoTrans Project Manager Health and Safety Officer and Director of Business

Operations The above personnel must be notified of the accident as soon as possible and

no later than 24 hours after the incident The written report should be submitted as soon

as possible and no later than 48 hours after the incident The Director of Health and

Safety should ensure that the follow-up action is taken to correct the situation that caused

the accident The incident report may include but is not limited to the nature of the

problem time location areas affected manner and methods used to control the

emergency sampling andor monitoring data impact if any to the surrounding

community and corrective actions that will be taken to minimize the potential for future

occurrences Notification of the local officer of OSHA will occur should the emergency

cause five or more personnel to be injured and transported to the hospital or if there is a

fatality

FOR WR GRACE amp Co - CONN M wp_DocsN0997oooFiNALpnASb i Rio2251600 wro ATT B1-23 HSI GeoTrans inc

WATER SAFETY

All workers will follow general guidelines for water safety while working in or

around water bodies where the danger of drowning exists Workers will be expected to

adhere to the established general safety practices for their respective specialities and to

the following water safety guidelines as required by OSHA

1 Employees working over or near water where the danger of drowning exists shall

wear US Coast Guard approved life jackets or buoyant work vests

2 Prior to and after use life jackets or work vests will be inspected for defects in

strength or buoyancy

3 Ring buoys or equivalent with at least 90 feet of line will be stationed near work areas

at all times and there shall be no more than 200 feet between buoys

4 At least one life saving skiff shall be immediately available where deemed necessary

at locations where workers are over or adjacent to water bodies

FOR WR GRACE amp Co - CONN M wpjxxsN0992oooFrNu PHASE i njo2251600 WPD ATT B1-24 HSI GeoTrans inc

Terra Tech Inc Safe Work Practices Issue Date July 1998 Non-Permit-Required Confined Space Entry Practices Revision No 1 SWPNo 6-24 Page 1

NON-PERMIT-REQUIRED CONFINED SPACE ENTRY PRACTICES

The following safe work practices (SWP) apply to entry into confined spaces classified as non-permitshy

required The confined space must conform to the definition of a non-permit-required confined space as

discussed in the Confined Space Entry Program (see Document Control No 2-5 in Volume I) Entry into

spaces classified as non-permit-required are preferable over entry into permit-required spaces When

feasible efforts shall be directed to prepare confined spaces so they meet the definitions of non-permitshy

required confined space

If any of the procedures discussed in this SWP cannot be completed or an unanticipated hazard is

identified the non-permit-required status of the space will be revoked until the space is re-evaluated and

reapproved as a non-permit-required space by a technically qualified individual such as a Tetra Tech

health and safety specialist

Non-permit-required confined space entry procedures before entry into the space are listed below

bull The project manager and the site safety coordinator (SSC) should be notified of the need to enter into a confined space This notification must allow sufficient time to assemble necessary safety equipment

bull A blank Preparation and Testing of Non-Permit Required Confined Space form (Form CS-2) must be obtained (see Volume HI)

bull The necessary safety equipment can include but is not limited to atmospheric testing meters and devices a mechanical ventilator and a ladder for entry and exit

bull All equipment to be used during entry must be tested and inspected before use Atmospheric testing equipment shall be calibrated in accordance with the manufacturers instructions to ensure proper operation Calibration parameters shall be documented in the field logbook and the equipment will be tagged with a label specifying these parameters

bull Hazardous conditions associated with the removal of the entrance cover should be eliminated before opening the confined space After removal of the entrance cover the opening should be promptly barricaded by a railing temporary cover or other temporary barrier to prevent employees and equipment from accidentally falling through the opening

bull The internal atmosphere should be tested for the following conditions in the order given

Disclaimer This safe work practice (SWP) is the property of Tetra Tech Inc (Tetra Tech) and its subsidiaries Any reuse of the SWP without Terra Techs permission is at the sole nsk of the user The user will hold harmless Tetra Tech for any damages that result from unauthorized reuse of this SWP Authorized users are responsible for obtaining proper training and qualification from their employer before performing operations described in this SWP

swp6-24_non-permit-required_confined_space_entry_pracncesdoc

Tetra Tech Inc Safe Work Practices Issue Date July 1998 Non-Permit-Required Confined Space Entry Practices Revision No 1 SWPNo 6-24 Page 2

- Oxygen content (should be between 195 to 235 percent)

- Combustible gases (should be less than 10 percent of the lower explosive limit)

- Potential toxic air contaminants

bull The space should be tested at all levels (top middle and bottom) and in all areas where work may occur The atmosphere within the space must not be hazardous whenever an employee is inside the space

bull If forced-air ventilation is used the following conditions apply

mdash Ventilation should not be used to control continuous sources of hazardous contaminants

- There must be a clean source of air that will not increase the hazard within the space

bull The entrant shall document on Form CS-2 that the space is safe for entry and that preshyentry measures required by this SWP have been taken The form shall be made available to each employee entering the space and shall be kept at the work site until completion of confined space work The certificate will then become part of the permanent project file

The atmosphere within the confined space must be tested periodically while entrants are within the

confined space Frequency of testing shall be every 30 minutes during the first 2 hours then hourly

afterwards when entrants are in the confined space If at any time during occupancy a hazardous

atmosphere is detected the entrants shall leave the space immediately The space shall then be evaluated

to determine how the hazardous atmosphere developed and measures shall be implemented to protect

employees from the hazardous atmosphere before any subsequent entry Re-entry shall not be allowed

until atmospheric testing demonstrates acceptable conditions

When changes in the use or configuration of a non-permit-required space cannot be eliminated or

controlled the SSC shall re-evaluate the space and if necessary reclassify it as a permit-required

confined space

Disclaimer This safe work practice (SWP) is the property of Tetra Tech Inc (Tetra Tech) and its subsidiaries Any reuse of the SWP without Tetra Techs permission is al the sole risk of the user The user will hold harmless Tetra Tech for any damages chat result from unauthorized reuse of this SWP Authorized users are responsible for obtaining proper training and qualification from their employer before performing operations described in this SWP

swp6-24_non-penrut-required_confined_space_entry_practicesdoc

ATTACHMENT C

MATERIAL SAFETY DATA SHEETS (MSDS)

FOR W R GRACE amp Co - CONN M WP_DOCSN0992000FINM PHASE IRIV02251600 WPO ATT C1-1 HSI GeOTrailS 1F1C

ISOPROPYL ALCOHOL (90 - 100) httpwwwjtbakercommsdsi8840htm

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MSDS Material Safety Data Sheet Ovtraquoldraquo US wid Cufwd ChMMrtc 20Z-W3-7818

From Malllnckrodt Baker Inc NOTE CH6MTREC CANUTEC and Nation 222 Rod School Uno LLINCKRODT

Phllllpaburg NJ 08885 uud only In the mml laquo4 ehairtcal crmigknGlM mvaMng a spa leek lira axpoaura or laquoeddlaquonl

All non-emergency question should be directed to Customer Service (1-800-582-2537) for auistanoe

ISOPROPYL ALCOHOL (90 - 100)

MSDS Number 18840 mdash Effective Date 090897

1 Product Identification

Synonyms 2-Propanol sec-propyl alcohol isopropanol sec-propanol dimethylcarbinol CAS No 67-63-0 Molecular Weight 6010 Chemical Formula (CH3)2 CHOH Product Codes JT Baker 5082 9080 U298 Mallinckrodt 3027 3031 3032 3035 3037 3043 4359 6569 H604 V073 V345 V555 V566

2 CompositionInformation on Ingredients

Ingredient CAS No Percent Hazardous

Isopropyl Alcohol 67-63-0 90 - 100 Yes Water 7732-18-5 0 - 1 0 No

3 Hazards Identification

Emergency Overview

WARNING FLAMMABLE LIQUID AND VAPOR HARMFUL IF SWALLOWED OR INHALED CAUSES IRRITATION TO EYES AND RESPIRATORY TRACT AFFECTS CENTRAL NERVOUS SYSTEM MAY BE HARMFUL IF ABSORBED

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THROUGH SKIN MAY CAUSE IRRITATION TO SKIN

JT Baker SAF-T-DATA^tm^ Ratings (Provided here for your convenience)

Health Rating 1 - Slight Flammability Rating 4 - Extreme (Flammable) Reactivity Rating 2 - Moderate Contact Rating 2 - Moderate Lab Protective Equip GOGGLES LAB COAT VENT HOOD PROPER GLOVES CLASS B EXTINGUISHER Storage Color Code Red (Flammable)

Potential Health Effects

Inhalation Inhalation of vapors irritates the respiratory tract Exposure to high concentrations has a narcotic effect producing symptoms of dizziness drowsiness headache staggering unconsciousness and possibly death Ingestion Can cause drowsiness unconsciousness and death Gastrointestinal pain cramps nausea vomiting and diarrhea may also result The single lethal dose for a human adult = about 250 mis (8 ounces) Skin Contact May cause irritation with redness and pain May be absorbed through the skin with possible systemic effects Eye Contact Vapors cause eye irritation Splashes cause severe irritation possible corneal burns and eye damage Chronic Exposure Chronic exposure may cause skin effects Aggravation of Pre-existing Conditions Persons with pre-existing skin disorders or impaired liver kidney or pulmonary function may be more susceptible to the effects of this agent

4 First Aid Measures

Inhalation Remove to fresh air If not breathing give artificial respiration If breathing is difficult give oxygen Call a physician Ingestion Give large amounts of water to drink Never give anything by mouth to an unconscious person Get medical attention Skin Contact Immediately flush skin with plenty of water for at least 15 minutes Call a physician if irritation develops Eye Contact

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Immediately flush eyes with plenty of water for at least 15 minutes lifting lower and upper eyelids occasionally Get medical attention immediately

5 Fire Fighting Measures

Fire Flashpoint 12C(54F)CC Autoignition temperature 399C (750F) Flammable limits in air by volume lei 20 uel 127 Listed fire data is for Pure Isopropyl Alcohol Explosion Above flash point vapor-air mixtures are explosive within flammable limits noted above Contact with strong oxidizers may cause fire or explosion Vapors can flow along surfaces to distant ignition source and flash back Sensitive to static discharge Fire Extinguishing Media Water spray dry chemical alcohol foam or carbon dioxide Water spray may be used to keep fire exposed containers cool dilute spills to nonflammable mixtures protect personnel attempting to stop leak and disperse vapors Special Information In the event of a fire wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full facepiece operated in the pressure demand or other positive pressure mode

6 Accidental Release Measures

Ventilate area of leak or spill Remove all sources of ignition Wear appropriate personal protective equipment as specified in Section 8 Isolate hazard area Keep unnecessary and unprotected personnel from entering Contain and recover liquid when possible Use non-sparking tools and equipment Collect liquid in an appropriate container or absorb with an inert material (e g vermiculite dry sand earth) and place in a chemical waste container Do not use combustible materials such as saw dust Do not flush to sewer If a leak or spill has not ignited use water spray to disperse the vapors to protect personnel attempting to stop leak and to flush spills away from exposures

J T Baker SOLUSORB(tm) solvent adsorbent is recommended for spills of this product

7 Handling and Storage

Protect against physical damage Store in a cool dry well-ventilated location away from any area where the fire hazard may be acute Outside or detached storage is preferred Separate from incompatibles Containers should be bonded and grounded for transfers to avoid static sparks Storage and use areas should be No Smoking areas Use non-sparking type tools and equipment including explosion proof ventilation Containers of this material may be

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hazardous when empty since they retain product residues (vapors liquid) observe all warnings and precautions listed for the product

8 Exposure ControlsPersonal Protection

Airborne Exposure Limits For Isopropyl Alcohol (2-Propanol) -OSHA Permissible Exposure Limit (PEL) 400 ppm (TWA)

-ACGIH Threshold Limit Value (TLV) 400 ppm (TWA) 500 ppm (STEL) Ventilation System A system of local andor general exhaust is recommended to keep employee exposures below the Airborne Exposure Limits Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source preventing dispersion of it into the general work area Please refer to the ACGIH document Industrial Ventilation A Manual of Recommended Practices most recent edition for details Personal Respirators (NIOSH Approved) If the exposure limit is exceeded a full facepiece respirator with organic vapor cartridge may be worn up to 50 times the exposure limit or the maximum use concentration specified by the appropriate regulatory agency or respirator supplier whichever is lowest For emergencies or instances where the exposure levels are not known use a full-facepiece positive-pressure air-supplied respirator WARNING Air purifying respirators do not protect workers in oxygen-deficient atmospheres Skin Protection Wear impervious protective clothing including boots gloves lab coat apron or coveralls as appropriate to prevent skin contact Neoprene and nitrile rubber are recommended materials Eye Protection Use chemical safety goggles andor a full face shield where splashing is possible Maintain eye wash fountain and quick-drench facilities in work area

9 Physical and Chemical Properties

Appearance Clear colorless liquid Odor Rubbing alcohol Solubility Miscible in water Specific Gravity 079 20C4C pH No information found Volatiles by volume 21C (70F) 100

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Boiling Point 82C(180F) Melting Point -89C(-128F) Vapor Density (Air=l) 21 Vapor Pressure (mm Hg) 44 25C (77F) Evaporation Rate (BuAc=l) 283

10 Stability and Reactivity

Stability Stable under ordinary conditions of use and storage Heat and sunlight can contribute to instability Hazardous Decomposition Products Carbon dioxide and carbon monoxide may form when heated to decomposition Hazardous Polymerization Will not occur Incompatibilities Heat flame strong oxidizers acetaldehyde acids chlorine ethylene oxide hydrogen-palladium combination hydrogen peroxide-sulfuric acid combination potassium tert-butoxide hypochlorous acid isocyanates nitroform phosgene aluminum oleum and perchloric acid Conditions to Avoid Heat flames ignition sources and incompatibles

11 Toxicological Information

Oral rat LD50 5045 mgkg skin rabbit LD50 128 gmkg inhalation rat LC50 16000 ppm8-hour investigated as a tumorigen mutagen reproductive effector

Cancer Lists NTP Carcinogen

Ingredient Known Anticipated IARC Category

Isopropyl Alcohol (67-63-0) No No 3 Water (7732-18-5) No No None

12 Ecological Information

Environmental Fate When released into the soil this material is expected to quickly evaporate When released into

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the soil this material may leach into groundwater When released into the soil this material may biodegrade to a moderate extent When released to water this material is expected to quickly evaporate When released into the water this material is expected to have a half-life between 1 and 10 days When released into water this material may biodegrade to a moderate extent This material is not expected to significantly bioaccumulate When released into the air this material is expected to be readily degraded by reaction with photochemically produced hydroxyl radicals When released into the air this material is expected to have a half-life between 1 and 10 days When released into the air this material may be removed from the atmosphere to a moderate extent by wet deposition Environmental Toxicity The LC5096-hour values for fish are over 100 mg1 This material is not expected to be toxic to aquatic life

13 Disposal Considerations

Whatever cannot be saved for recovery or recycling should be handled as hazardous waste and sent to a RCRA approved incinerator or disposed in a RCRA approved waste facility Processing use or contamination of this product may change the waste management options State and local disposal regulations may differ from federal disposal regulations Dispose of container and unused contents in accordance with federal state and local requirements

14 Transport Information

Domestic (Land DOT)

Proper Shipping Name ISOPROPANOL Hazard Class 3 UNNA UN1219 Packing Group II Information reported for productsize 355LB

International (Water IMO)

Proper Shipping Name ISOPROPANOL Hazard Class 32 UNNA UNI219 Packing Group II Information reported for productsize 355LB

15 Regulatory Information Chemical Inventory Status - Part 1

Ingredient TSCA EC Japan Australia

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ISOPROPYL ALCOHOL (90 - 100) http wwwjtbaker commsdsi8840 htm

Isopropyl Alcohol (67-S3-0) Yes Yes Yes Yes Water (7732-18-5) Yes Yes Yes Yes

Chemical Inventory Status - Part 2shy--Canada-shy

Ingredient Korea DSL NDSL Phil

Isopropyl Alcohol (67-63-0) Yes Yes No Yes Water (7732-18-5) Yes Yes No Yes

Federal State amp International Regulations - Part 1 -SARA 302- SARA 313

Ingredient RQ TPQ List Chemical Catg

Isopropyl Alcohol (67-63-0) No No Yes No Water (7732-18-5) No No No No

Federal State amp International Regulations -RCRA- -TSCA-

Ingredient CERCLA 26133 8(d)

Isopropyl Alcohol (67-63-0) No No No Water (7732-18-5) No No No

Chemical Weapons Convention No TSCA 1 2 ( b ) Yes CDTA Yes SARA 311312 Acute Yes Chronic Yes Fire Yes Pressure No Reactivity No (Mixture Liquid)

Australian Hazchem Code 2[S]2 Poison Schedule No information found WHMIS This MSDS has been prepared according to the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all of the information required by the CPR

16 Other Information

NFPA Ratings Health 2 Flammability 3 Reactivity 0 Label Hazard Warning WARNING FLAMMABLE LIQUID AND VAPOR HARMFUL IF SWALLOWED OR INHALED CAUSES IRRITATION TO EYES AND RESPIRATORY TRACT AFFECTS CENTRAL NERVOUS SYSTEM MAY BE HARMFUL IF ABSORBED THROUGH SKIN MAY CAUSE IRRITATION TO SKIN Label Precautions Keep away from heat sparks and flame Keep container closed Use only with adequate ventilation Wash thoroughly after handling Avoid breathing vapor or mist Avoid contact with eyes skin and clothing Label First Aid If swallowed give large amounts of water to drink Never give anything by mouth to an unconscious person If inhaled remove to fresh air If not breathing give artificial respiration

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If breathing is difficult give oxygen In case of contact immediately flush eyes or skin with plenty of water for at least 15 minutes Remove contaminated clothing and shoes Wash clothing before reuse In all cases get medical attention

- Product Use Laboratory Reagent Revision Information MSDS Section(s) changed since last revision of document include 15 Disclaimer

Mallinckrodt Baker Inc provides the information contained herein in good faith but makes no representation as to its comprehensiveness or accuracy This document is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product Individuals receiving the information must exercise their independent judgment in determining its appropriateness for a particular purpose MALLINCKRODT BAKER INC MAKES NO REPRESENTATIONS OR WARRANTIES EITHER EXPRESS OR IMPLIED INCLUDING WITHOUT LIMITATION ANY WARRANTIES OF MERCHANTABILITY FITNESS FOR A PARTICULAR PURPOSE WITH RESPECT TO THE INFORMATION SET FORTH HEREIN OR THE PRODUCT TO WHICH THE INFORMATION REFERS ACCORDINGLY MALLINCKRODT BAKER INC WILL NOT BE RESPONSIBLE FOR DAMAGES RESULTING FROM USE OF OR RELIANCE UPON THIS INFORMATION

Prepared by Strategic Services Division Phone Number (314) 539-1600 (USA)

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MALLINCKRODT - NITRIC ACID 70 - NITRIC ACID ACS httpwwwvetmeducdavisedUmsdshq483q4I6html

MALLINCKRODT -- NITRIC ACID 70 - NITRIC ACID ACS MATERIAL SAFETY DATA SHEET NSN 6810001301912 Manufacturers CAGE 62910

__ Part No Indicator A Part NumberTrade Name NITRIC ACID 70

General Information

Item Name NITRIC ACID ACS Companys Name MALLINCKRODT INC Companys P O Box M Companys City PARIS Companys State KY Companys Country US Companys Zip Code 40361 Companys Emerg Ph 314-982-5000 Companys Info Ph 314-982-5000 Record No For Safety Entry 005 Tot Safety Entries This Stk 006 Status SMJ Date MSDS Prepared 06APR89 Safety Data Review Date 14APR95 MSDS Serial Number BLVZN Hazard Characteristic Code Cl

IngredientsIdentity Information

Proprietary NO Ingredient NITRIC ACID Ingredient Sequence Number 01 NIOSH (RTECS) Number QU5775000 CAS Number 7697-37-2 OSHA PEL 2 PPM4 PPM STEL ACGIH TLV 2 PPM4 PPM STEL

Proprietary NO Ingredient SUPDAT LIFTING LIDS OCCASIONALLY GET MED ATTN IMMED Ingredient Sequence Number 02 NIOSH (RTECS) Number 9999999ZZ OSHA PEL NOT APPLICABLE ACGIH TLV NOT APPLICABLE

Proprietary NO Ingredient SPILL PROC ALKALINE MATL PICKUP WABSORB MATL(SAND EARTH VERMICULITE) amp DISPOSE IN RCRA-APPRVD WASTE FACILITY(ING 4) Ingredient Sequence Number 03 NIOSH (RTECS) Number 9999999ZZ OSHA PEL NOT APPLICABLE ACGIH TLV NOT APPLICABLE

Proprietary NO Ingredient ING 3OR SEWER NEUT SLURRY WEXCESS H2O IF LOG ORDINACES ALLOW PROVIDE FORCED VENTILAITON TO DISSIPATE FUMES Ingredient Sequence Number 04 NIOSH (RTECS) Number 9999999ZZ OSHA PEL NOT APPLICABLE ACGIH TLV NOT APPLICABLE

Proprietary NO Ingredient OTHER PREC CAUSTIC POISON ACT Ingredient Sequence Number 05 NIOSH (RTECS) Number 9999999ZZ OSHA PEL NOT APPLICABLE ACGIH TLV NOT APPLICABLE

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MALLINCKRODT -- NITRIC ACID 70 - NITRIC ACID ACS http www vetmed ucdavis edumsdshq483q416 html

Proprietary NO Ingredient VENTPREF BECAUSE IT CAN CTRL EMISSIONS OF CONTAM reg ITS SOURCE PVNT DISPERSION OF IT INTO GEN WORK AREA PLEASE (ING 7) Ingredient Sequence Number 06 NIOSH (RTECS) Number 9999999ZZ OSHA PEL NOT APPLICABLE ACGIH TLV NOT APPLICABLE

Proprietary NO Ingredient ING 6 REFER TO ACGIH DOCUMENT INDUST VENT MANUAL OF RECOMMENDED PRACTICES MOST RECENT EDITION FOR DETAILS Ingredient Sequence Number 07 NIOSH (RTECS) Number 9999999ZZ OSHA PEL NOT APPLICABLE ACGIH TLV NOT APPLICABLE

Proprietary NO Ingredient HNDLTSTOR PREC MOISTURE Ingredient Sequence Number 08 NIOSH (RTECS) Number 9999999ZZ OSHA PEL NOT APPLICABLE ACGIH TLV NOT APPLICABLE

PhysicalChemical Characteristics

Appearance And Odor CLEAR COLORLESS TO SLIGHTLY YELLOW LIQUID SUFFOCATING ACRID ODOR Boiling Point 252F122C Melting Point -29F-34C Vapor Pressure (MM Hg70 F) 62O68F Vapor Density (Air=l) 2-3 Specific Gravity 141 Evaporation Rate And Ref NON INFORMATION FOUND Solubility In Water INFINITE IN WATER

Fire and Explosion Hazard Data

Extinguishing Media IF INVOLVED IN FIRE USE WATER SPRAY Special Fire Fighting Proc WEAR NIOSHMSHA APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT (FP N) INCREASES FLAMMABILITY OF COMBUSTIBLE ORGANIC AND READILY OXIDIZABLE MATERIALS Unusual Fire And Expl Hazrds NOT COMBUSTBUT SUBSTANCE IS STRONG OXIDIZERITS HEAT OF RXN WREDUCING AGENTSCOMBUST MAY CAUSE IGNIT CAN REACT WMETALS TO REL FLAM HYDROGEN GAS (SUPDAT)

Reactivity Data =======================mdash ======== ==========S================== == ======== == =

Stability YES Cond To Avoid (Stability) CONTAINERS MAY BURST WHEN HEATED Materials To Avoid DANGEROUSLY POWERFUL OXIDIZING AGENTCONC NITRIC ACID IS INCOMP WMOST SUBSTANCESESP STRONG BASES METALLIC (SUPDAT) Hazardous Decomp Products WHEN HEATED TO DECOMP EMITS TOX NITROGEN OXIDES FUMES amp HYDROGEN NITRATE WILL REACT WH2OSTEAM TO PRDCE HEAT(SUPDAT) Hazardous Poly Occur NO Conditions To Avoid (Poly) NOT RELEVANT

Health Hazard Data

LD50-LC50 Mixture NONE SPECIFIED BY MANUFACTURER Route Of Entry - Inhalation YES Route Of Entry - Skin NO Route Of Entry - Ingestion YES Health Haz Acute And Chronic ACUTEINHALCORR INHAL OF VAP CAN CAUSE

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BRTHG DFCLT amp LEAD TO PENUM amp PULMONARY EDEMA WHICH CAN BE FATAL OTHER SYM MAY INCL COUGHCHOKINGIRRIT OF NOSETHROATRESP TRACT INGESTCORR SWALLOW NITRIC ACID CAN CAUSE IMMED PAIN amp BURNS OF MOUTHTHROATESOPHAGUS amp GI TRACT SKINCORR CAN CAUSE RED (EFTS OF OVEREXP)

__ Carcinogenicity - NTP NO Carcinogenicity - IARC NO Carcinogenicity - OSHA NO Explanation Carcinogenicity NOT RELEVANT SignsSymptoms Of Overexp HLTH HAZPAINSEV SKIN BURNS CONC SOLN CAUSE DEEP ULCERS amp STAIN SKIN YELLOWYELLOW-BROWN COLOR EYECORR VAP ARE IRRITATINGMAY CAUSE DAM TO EYES SPLASHES MAY CAUSE SEV BURNS amp PERM EYE DAM CHRONICLONG-TERM EXPOS TO CONC VAP MAY CAUSE EROSION OF TEETH LONG TERM EXPOS SELDOM OCCUR DUE TO CORR PROPERTIES OF ACID Med Cond Aggravated By Exp PERSONS WITH PRE-EXISTING SKIN DISORDERS OR EYE DISEASE MAY BE MORE SUSCEPTIBLE TO EFFECTS OF THIS SUBSTANCE EmergencyFirst Aid Proc INHALREMOVE TO FRESH AIR IF NOT BRTHG GIVE ARTF RESP IF BRTHG DFCLT GIVE 02 CALL PHYS INGESTDO NOT INDUCE VOMIT GIVE LG QTY OF H2OMILK IF AVAIL NEVER GIVE ANYTHING BY MOUTH TO AN UNCON PERSON GET MED ATTN IMMED SKINIMMED FLUSH WPLENTY OF H2O FOR reg LST 15 MIN WHILE REMOVING CONTAMD CLTHGSHOES WASH CLTHG BEFORE REUSE THORO CLEAN SHOES BEFORE REUSE GET MED ATTN IMMED (SUPDAT)

Precautions for Safe Handling and Use

Steps If Matl ReleasedSpill ISOLATEENCLOSE AREA OF LEAKSPILL CLEAN-UP PERS SHOULD WEAR PROT CLTHG amp RESP EQUIP SUITABLE FOR TOXCORR FLUIDSVAP SM SPILLSFLUSH WH20 amp NEUT WALKALINE MATL(SODA ASH LIME ETC) SEWER W EXCESS H2O LG SPILLLOT SIZESNEUT W (ING 3) Neutralizing Agent SEE MATERIAL RELEASED SPILLED PROCEDURES Waste Disposal Method ENSURE COMPLIANCE WITH LOCAL STATE AND FEDERAL REGULATIONS Precautions-HandlingStoring KEEP IN TIGHTLY CLSD CONTR STORED IN COOL DRYVENTD AREA PROTECT FROM PHYS DAMDIRECT SUNLIGHT ISOLATE FROM INCOMP SUBSTANCE PROTECT FROM (ING 8) Other Precautions DO NOT GET IN EYESON SKINCLTHG AVOID BRTHG MIST USE ONLY WADEQ VENT KEEP FROM CONT WCLTHGOTHER COMBUST MATL DO NOT STORE NEAR COMBUST MATL REMOVEWASH CONTAMD CLTHG PROMPTLY SUBSTANCE IS CLASSIFIED AS POISON UNDER FED (ING 5)

Control Measures

Respiratory Protection IF TLV IS EXCEEDED WEAR NIOSHMSHA APPRVD SUPPLIED AIR FULL-FACEPIECE RESP AIRLINED HOOD OR SCBA NITRIC ACID IS AN OXIDIZER amp SHOULD NOT COME IN CONT WCARTRIDGES amp CANNISTERS THAT CNTN OXIDIZABLE MATL SUCH AS ACTIVATED CHARCOAL Ventilation SYS OF LOCGEN EXHAUST IS RECOM TO KEEP EMPLOYEE EXPOS BELOW AIRBORNE EXPOS LIM LOG EXHAUST VENT IS GENERALLY (ING 6) Protective Gloves IMPERVIOUS GLOVES Eye Protection CHEM WRKRS GOG amp FULL LGTH FSHLD(FP N) Other Protective Equipment IMPERVIOUS CLOTHING BOOTS LAB COAT APRON OR COVERALLS TO PREVENT SKIN CONTACT Work Hygienic Practices WASH THOROUGHLY AFTER HANDLING MAINTAIN EYEWASH FOUNTAIN AND QUICK DRENCH FACILITIES IN WORK AREA Suppl Safety amp Health Data EXPLOS HAZrREACTS EXPLOS WCOMBUSTORG READILY OXIDIZABLE MATL SUCH ASALCOHOLS TURPETINE CHARCOAL ORG REFUSE METAL POWDERHYDROGEN SULFIDEETC MATL TO AVOIDPOWDERS CARBIDES HYDROGEN SULFIDE TURPETINE COMBUST ORG HAZ DECOMPamp TOX amp CORR FUMES FIRST AID PROCEYEWASH WPLENTY OF H2O FOR LST 15 MIN(ING 2

Transportation Data

Trans Data Review Date 92092 DOT PSN Code KFD DOT Proper Shipping Name NITRIC ACID DOT Class 8

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MALLINCKRODT -- NITRIC ACID 70 - NITRIC ACID ACS httpwwwvetmeducdavisedUmsdshq483q416html

DOT ID Number UN2031 DOT Pack Group II DOT Label CORROSIVE IMO PSN Code KPF

mdash IMO Proper Shipping Name NITRIC ACID IMO Regulations Page Number 8195 IMO UN Number 2031 IMO UN Class 8 IMO Subsidiary Risk Label shyIATA PSN Code RWF IATA UN ID Number 2031 IATA Proper Shipping Name NITRIC ACID IATA UN Class 8 IATA Label CORROSIVE API PSN Code RWF API Symbols 0 API Prop Shipping Name NITRIC ACID API Class 8 API ID Number UN2031 API Pack Group II API Basic Pac Ref 12-14

Disposal Data

Label Data

Label Required YES Technical Review Date 16DEC91 Label Date 27NOV91 Label Status G Common Name NITRIC ACID 70 Chronic Hazard YES Signal Word DANGER Acute Health Hazard-Slight X Contact Hazard-Severe X Fire Hazard-None X Reactivity Hazard-Slight X Special Hazard Precautions STRONG OXIDIZER CONT WOTHER MATL MAY CAUSE FIRE CORROSIVE ACUTELIQUIDMIST CAUSE SEVERE BURNS TO ALL BODY TISSUE MAY BE FATAL IF SWALLOWED HARMFUL IF INHALED INHAL MAY CAUSE LUNG DAMAGE CAN CAUSE SEVERE BURNS TO EYESSKIN CAN STAIN SKIN YELLOWYELLOW-BROWN COLOR CAN CAUSE PERMANENT EYE DAMAGE INHAL OF VAPORS CAN CAUSE BRTHG DIFFICULTIES amp LEAD TO PNEUMONIA amp PULMONARY EDEMA WHICH MAY BE FATAL OTHER INHAL SYMPCOUGHING CHOKING amp IRRIT OF NOSETHROATRESP TRACT SWALLOWING NITRIC ACID CAN CAUSE IMMEDIATE PAIN amp BURNS OF MOUTHTHROAT ESOPHAGUS amp GI TRACT CHRONICLONG TERM EXPOSURE TO CONCENTRATED VAP MAY CAUSE EROSION OF TEETH Protect Eye Y Protect Skin Y Protect Respiratory Y Label Name MALLINCKRODT INC SCIENCE PROD DIV Label PO Box M Label City PARIS Label State KY Label Zip Code 40361 Label Country US Label Emergency Number 314-982-5000

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HYDROCHLORIC ACID 33 - 40 http www jtbaker commsdsh3880 htm

Please reduce your browser font size for better viewing and printing 24 Hour Emergency Tlaquollaquophont 9W-KB-21S1 CHEMTREC 1-WXM2M900

Notional Rwpon In Cmdi MSDS Material Safety Data Sheet CANUTEC 8134064M6

Outold 08 laquond Onwto Chwnlrte 3OH93-79W

From Malllnckrodt Baker Inc NOTE CHEMTREC CANUTEC laquond National 222 Rd School Lan LLINCKRODT JTBafcCf Rraquolaquoporaquoraquo Claquolaquoraquof bullnwigmcy numbm raquo blaquo

Phlllipsburg NJ 08865 uMd onty in the laquovml laquol ehamloJ laquornefgraquondM involving tpa llaquoaK lira exposure or aocMtnt Involving dwnlcals

All non-emergency questions should be directed to Custamr Service (1-800-582-2537) for assistance

HYDROCHLORIC ACID 33 - 40

MSDS Number H3880 mdash Effective Date 120896


Synonyms Muriatic acid hydrogen chloride aqueous CAS No 7647-01-0 Molecular Weight 3646 Chemical Formula HC1 Product Codes JT Baker 5367 5537 5575 5800 5814 5839 6900 7831 9529 9530 9534 9535 9536 9537 9538 9539 9540 9544 9548 Mallinckrodt 2062 2612 2624 2626 5587 H611 H613 H615 V078



Hydrogen Chloride 7647-01-0 33 - 40 Yes Water 7732-18-5 60 - 67 No


Emergency Overview

POISON DANGER CORROSIVE LIQUID AND MIST CAUSE SEVERE BURNS TO ALL BODY TISSUE MAY BE FATAL IF SWALLOWED OR INHALED INHALATION MAY CAUSE LUNG DAMAGE

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HYDROCHLORIC ACID 33 - 40 httpwwwjtbakCTcommsdsh3880htm

JT Baker SAF-T-DATA(tm) Ratings (Provided here for your convenience)

Health Rating 3 - Severe (Poison) Flammability Rating 0 - None Reactivity Rating 2 - Moderate Contact Rating 3 - Severe (Corrosive) Lab Protective Equip GOGGLES amp SHIELD LAB COAT amp APRON VENT HOOD PROPER GLOVES Storage Color Code White (Corrosive)


Inhalation Corrosive Inhalation of vapors can cause coughing choking inflammation of the nose throat and upper respiratory tract and in severe cases pulmonary edema circulatory failure and death Ingestion Corrosive Swallowing hydrochloric acid can cause immediate pain and bums of the mouth throat esophagus and gastrointestinal tract May cause nausea vomiting and diarrhea Swallowing may be fatal Skin Contact Corrosive Can cause redness pain and severe skin burns Concentrated solutions cause deep ulcers and discolor skin Eye Contact Corrosive Vapors are irritating and may cause damage to the eyes Contact may cause severe burns and permanent eye damage Chronic Exposure Long-term exposure to concentrated vapors may cause erosion of teeth Long term exposures seldom occur due to the corrosive properties of the acid Aggravation of Pre-existing Conditions Persons with pre-existing skin disorders or eye disease may be more susceptible to the effects of this substance


Inhalation Remove to fresh air If not breathing give artificial respiration If breathing is difficult give oxygen Get medical attention immediately Ingestion DO NOT INDUCE VOMITING Give large quantities of water or milk if available Never give anything by mouth to an unconscious person Get medical attention immediately Skin Contact hi case of contact immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes Wash clothing before reuse Thoroughly clean shoes before reuse Get medical attention immediately

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HYDROCHLORIC ACID 33 - 40 httpwwwjtbakercommsdsh3880htm

Eye Contact Immediately flush eyes with plenty of water for at least 15 minutes lifting lower and upper eyelids occasionally Get medical attention immediately


Fire Extreme heat or contact with metals can release flammable hydrogen gas Explosion Not considered to be an explosion hazard Fire Extinguishing Media If involved in a fire use water spray Neutralize with soda ash or slaked lime Special Information In the event of a fire wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full facepiece operated in the pressure demand or other positive pressure mode Structural firefighters protective clothing is ineffective for fires involving hydrochloric acid Stay away from ends of tanks Cool tanks with water spray until well after fire is out


Ventilate area of leak or spill Wear appropriate personal protective equipment as specified in Section 8 Isolate hazard area Keep unnecessary and unprotected personnel from entering Contain and recover liquid when possible Neutralize with alkaline material (soda ash lime) then absorb with an inert material (e g vermiculite dry sand earth) and place in a chemical waste container Do not use combustible materials such as saw dust Do not flush to sewer US Regulations (CERCLA) require reporting spills and releases to soil water and air in excess of reportable quantities The toll free number for the US Coast Guard National Response Center is (800) 424-8802

J T Baker NEUTRASORB(tm) or TEAM(tm) Low Na+ acid neutralizers are recommended for spills of this product


Store in a cool dry ventilated storage area with acid resistant floors and good drainage Protect from physical damage Keep out of direct sunlight and away from heat water and incompatible materials Do not wash out container and use it for other purposes When diluting the acid should always be added slowly to water and in small amounts Never use hot water and never add water to the acid Water added to acid can cause uncontrolled boiling and splashing When opening metal containers use non-sparking tools because of the possibility of

mdash- hydrogen gas being present Containers of this material may be hazardous when empty since they retain product residues (vapors liquid) observe all warnings and precautions listed for the product

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Airborne Exposure Limits -OSHA Permissible Exposure Limit (PEL) 5 ppm Ceiling -ACGIH Threshold Limit Value (TLV) 5 ppm Ceiling

Ventilation System A system of local andor general exhaust is recommended to keep employee exposures below the Airborne Exposure Limits Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source preventing dispersion of it into the general work area Please refer to the ACGIH document Industrial Ventilation A Manual of Recommended Practices most recent edition for details Personal Respirators (NIOSH Approved) If the exposure limit is exceeded a full facepiece respirator with an acid gas cartridge may be worn up to 50 times the exposure limit or the maximum use concentration specified by the appropriate regulatory agency or respirator supplier whichever is lowest For emergencies or instances where the exposure levels are not known use a full-facepiece positive-pressure air-supplied respirator WARNING Air purifying respirators do not protect workers in oxygen-deficient atmospheres Skin Protection Rubber or neoprene gloves and additional protection including impervious boots apron or coveralls as needed in areas of unusual exposure to prevent skin contact Eye Protection Use chemical safety goggles andor a full face shield where splashing is possible Maintain eye wash fountain and quick-drench facilities in work area


Appearance Colorless fuming liquid Odor Pungent odor of hydrogen chloride Solubility Infinite in water with slight evolution of heat Density 118 PH For HCL solutions 01 (10 N) 11 (01 N) 202 (001 N) Volatiles by volume 21C (70F) 100 Boiling Point 53C (127F) Azeotrope (202) boils at 109C (228F) Melting Point

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-74C(-101F) Vapor Density (Air=l) No information found Vapor Pressure (mm Hg) 19025C(77F) Evaporation Rate (BuAc=l) No information found


Stability Stable under ordinary conditions of use and storage Containers may burst when heated Hazardous Decomposition Products When heated to decomposition emits toxic hydrogen chloride fumes and will react with water or steam to produce heat and toxic and corrosive fumes Thermal oxidative decomposition produces toxic chlorine fumes and explosive hydrogen gas Hazardous Polymerization Will not occur Incompatibilities A strong mineral acid concentrated hydrochloric acid is incompatible with many substances and highly reactive with strong bases metals metal oxides hydroxides amines carbonates and other alkaline materials Incompatible with materials such as cyanides sulfides sulfites and formaldehyde Conditions to Avoid Heat direct sunlight

11 lexicological Information

Inhalation rat LC50 3124 ppmlH oral rabbit LD50 900 mgkg (Hydrochloric acid concentrated) investigated as a tumorigen mutagen reproductive effector



Hydrogen Chloride (7647-01-0) No No 3 Water (7732-18-5) No No None


Environmental Fate When released into the soil this material is not expected to biodegrade When released into the soil this material may leach into groundwater Environmental Toxicity

5 of 8 10199 1217 PM


This material is expected to be toxic to aquatic life


Whatever cannot be saved for recovery or recycling should be handled as hazardous waste and sent to a RCRA approved waste facility Processing use or contamination of this product may change the waste management options State and local disposal regulations may differ from federal disposal regulations Dispose of container and unused contents in accordance with federal state and local requirements


Domestic (Land DOT)

Proper Shipping Name HYDROCHLORIC ACID Hazard Class 8 UNNA-UN1789 Packing Group II Information reported for productsize 475LB


Proper Shipping Name HYDROCHLORIC ACID Hazard Class 8 UNNA UNI789 Packing Group II Information reported for productsize 475LB

15 Regulatory Information Chemical Inventory Status

Ingredient - Part 1shy

TSCA EC Japan Australia

Hydrogen ChlorideWater (7732-18-5)

(7647-01-0) YesYes

Yes Yes

Yes Yes

Yes Yes

Chemical Inventory Status

Ingredient

- Part 2shy

Korea--C

DSLanada-shy NDSL Phil


(7647-01-0) YesYes

Yes Yes

No No

Yes Yes



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Hydrogen Chloride (7647-01-0) 5000 500 Yes No Water (7732-18-5) No No No No

Federal

Ingredient

State amp International Regulations

CERCLA

shy Part 2 -RCRAshy

26133 -TSCAshy 8 (d )


(7647-01-0 ) 5000 No

No No

No No

Chemical Weapons Convention No TSCA 1 2 ( b ) No CDTA Yes SARA 311312 Acute Yes Chronic Yes Fire No Pressure No Reactivity No (Mixture Liquid)

Australian Hazchem Code 2R Poison Schedule No information found WHMIS This MSDS has been prepared according to the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all of the information required by the CPR


NFPA Ratings Health 3 Flammabiliry 0 Reactivity 0 Label Hazard Warning POISON DANGER CORROSIVE LIQUID AND MIST CAUSE SEVERE BURNS TO ALL BODY TISSUE MAY BE FATAL IF SWALLOWED OR INHALED INHALATION MAY CAUSE LUNG DAMAGE Label Precautions Do not get in eyes on skin or on clothing Do not breathe vapor or mist Use only with adequate ventilation Wash thoroughly after handling Store in a tightly closed container Remove and wash contaminated clothing promptly Label First Aid In case of contact immediately flush eyes or skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes Wash clothing before reuse If swallowed DO NOT INDUCE VOMITING Give large quantities of water Never give anything by mouth to an unconscious person If inhaled remove to fresh air If not breathing give artificial respiration If breathing is difficult give oxygen In all cases get medical attention immediately Product Use Laboratory Reagent Revision Information New 16 section MSDS format all sections have been revised Disclaimer

Mallinckrodt Baker Inc provides the information contained herein in good faith but

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makes no representation as to its comprehensiveness or accuracy This document is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product Individuals receiving the information must exercise their independent judgment in determining its appropriateness for a particular purpose MALLINCKRODT BAKER INC MAKES NO REPRESENTATIONS OR WARRANTIES EITHER EXPRESS OR IMPLIED INCLUDING WITHOUT LIMITATION ANY WARRANTIES OF MERCHANTABILITY FITNESS FOR A PARTICULAR PURPOSE WITH RESPECT TO THE INFORMATION SET FORTH HEREIN OR THE PRODUCT TO WHICH THE INFORMATION REFERS ACCORDINGLY MALLINCKRODT BAKER INC WILL NOT BE RESPONSIBLE FOR DAMAGES RESULTING FROM USE OF OR RELIANCE UPON THIS INFORMATION


8 of 8 10199 1217PM

AMOCO OIL -- AMOCO REGULAR LEAD-FREE GASOLINE - GASOLINEAUTOMOTIVE httpsiriuvmedUmsdshq295q292htinl f bull bull

AMOCO OIL -- AMOCO REGULAR LEAD-FREE GASOLINE - GASOLINEAUTOMOTIVE MATERIAL SAFETY DATA SHEET NSN 9130001487103 Manufacturer s CAGE 15958

-mdash Part No Indicator D Part NumberTrade Name AMOCO REGULAR LEAD-FREE GASOLINE

General Information

Item Name GASOLINEAUTOMOTIVE Companys Name AMOCO OIL COMPANY Companys Street 200 EAST RANDOLPH DRIVE Companys City CHICAGO Companys State IL Companys Country US Companys Zip Code 60601 Companys Emerg Ph 800-447-8735 (HEALTH) Companys Info Ph 312-856-3907 Record No For Safety Entry 048 Tot Safety Entries This Stk 120 Status FE Date MSDS Prepared 24SEP93 Safety Data Review Date 200CT94 Supply Item Manager KY MSDS Preparers Name DONALD M BARKER DIR Preparers Company PRODUCT STEWARDSHIP amp TOXICOLOY Preparers St Or P O Box (MSDS02003992) MSDS Serial Number BVGZB Specification Number W-G-1690A Spec Type Grade Class CL ABCDE GR REG Hazard Characteristic Code F2 Unit Of Issue GL Unit Of Issue Container Qty BULK Type Of Container BULK Net Unit Weight UNKNOWN ====== ===== =========================== ============== = =


Proprietary NO Ingredient GASOLINE Ingredient Sequence Number 01 Percent NGIVEN NIOSH (RTECS) Number LX3300000 CAS Number 8006-61-9 OSHA PEL 300 PPM ACGIH TLV 300 PPM500STEL9394 Other Recommended Limit NONE RECOMMENDED

Proprietary NO Ingredient BENZENE (SARA III) Ingredient Sequence Number 02 Percent 4 NIOSH (RTECS) Number CY1400000 CAS Number 71-43-2 OSHA PEL SEE 19101028 ACGIH TLV 10 PPM A2 9394 Other Recommended Limit NONE RECOMMENDED

Proprietary NO Ingredient ETHYL BENZENE (SARA III) Ingredient Sequence Number 03 Percent 2 NIOSH (RTECS) Number DA0700000 CAS Number 100-41-4 OSHA PEL 100 PPM

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AMOCO OIL -- AMOCO REGULAR LEAD-FREE GASOLINE - GASOLINEAUTOMOTIVE httpsmuvmedUmsdshq295q292html

ACGIH TLV 100 PPM125STEL9394 Other Recommended Limit NONE RECOMMENDED

Proprietary NO Ingredient TOLUENE (SARA III) Ingredient Sequence Number 04 Percent 22 NIOSH (RTECS) Number XS5250000 CAS Number 108-88-3 OSHA PEL 200 PPM Z-2 ACGIH TLV S 50 PPM 9394 Other Recommended Limit NONE RECOMMENDED

Proprietary NO Ingredient CYCLOHEXANE (SARA III) Ingredient Sequence Number 05 Percent 5 NIOSH (RTECS) Number GU6300000 CAS Number 110-82-7 OSHA PEL 300 PPM ACGIH TLV 300 PPM 9394 Other Recommended Limit NONE RECOMMENDED

Proprietary NO Ingredient XYLENES (O-M-P- ISOMERS) (SARA III) Ingredient Sequence Number 06 Percent 10 NIOSH (RTECS) Number ZE2100000 CAS Number 1330-20-7 OSHA PEL 100 PPM ACGIH TLV 100 PPM150STEL9394 Other Recommended Limit NONE RECOMMENDED

Proprietary NO Ingredient METHYL TERT-BUTYL ETHER (SARA III) Ingredient Sequence Number 07 Percent 15 NIOSH (RTECS) Number KN5250000 CAS Number 1634-04-4 OSHA PEL NOT ESTABLISHED ACGIH TLV NOT ESTABLISHED Other Recommended Limit NONE RECOMMENDED

Proprietary NO Ingredient BUTANE Ingredient Sequence Number 08 Percent NGIVEN NIOSH (RTECS) Number EJ4200000 CAS Number 106-97-8 OSHA PEL 800 PPM ACGIH TLV 800 PPM 9394 Other Recommended Limit NONE RECOMMENDED

Proprietary NO Ingredient N-HEPTANE Ingredient Sequence Number 09 Percent NGIVEN NIOSH (RTECS) Number MI7700000 CAS Number 142-82-5 OSHA PEL 500 PPM ACGIH TLV 400 PPM500STEL9394 Other Recommended Limit NONE RECOMMENDED

Proprietary NO Ingredient HEXANE (N-HEXANE)

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AMOCO OIL- AMOCO REGULAR LEAD-FREE GASOLINE - GASOLINEAUTOMOTIVE httpsiriuvmedUtnsdshq295q292html

Ingredient Sequence Number 10 Percent NGIVEN NIOSH (RTECS) Number MN9275000 CAS Number 110-54-3

OSHA PEL 500 PPM ACGIH TLV 50 PPM 9394 Other Recommended Limit NONE RECOMMENDED

Proprietary NO Ingredient PENTANE Ingredient Sequence Number 11 Percent NGIVEN NIOSH (RTECS) Number RZ9450000 CAS Number 109-66-0 OSHA PEL 1000 PPM ACGIH TLV 600 PPM750STEL9394 Other Recommended Limit NONE RECOMMENDED

Proprietary NO Ingredient TRIMETHYL BENZENE (SARA III) Ingredient Sequence Number 12 Percent NGIVEN NIOSH (RTECS) Number DC3220000 CAS Number 25551-13-7 OSHA PEL 25 PPM ACGIH TLV 25 PPM 9394 Other Recommended Limit NONE RECOMMENDED


Appearance And Odor CLEAR BRIGHT LIQUID CHARACTERISTIC ODOR Boiling Point 80OF267C Vapor Pressure (MM Hg70 F) 7-15LBS Vapor Density (Air=l) 3-4 Specific Gravity 075 Solubility In Water NEGLIGIBLE lt01 Autoignition Temperature 495F


Flash Point -45F-43C Lower Explosive Limit 13 Upper Explosive Limit 76 Extinguishing Media- AGENTS APPROVED FOR CLASS B HAZARDS (EG DRY CHEMICAL CARBON DIOXIDE HALOGENATED AGENTS FOAM STEAM) OR WATER FOG Special Fire Fighting Proc NONE SPECIFIED BY MFG HOWEVER WEAR SELFshyCONTAINED BREATHING APPARATUS amp PROTECTIVE EQPMT IF SITUATION WARRENTS Unusual Fire And Expl Hazrds EXTREMELY FLAMM VAPAIR MIXTURES FORM EXTINGUISHMENT OF FIRE BEFORE SURGE OF VAP IS SHUT OFF CAN CREATE AN EXPLOSIVE MIXTURE IN AIR

Reactivity Data

Stability YES Cond To Avoid (Stability) BURNING CAN BE STARTED EASILY KEEP AWAY FROM IGNITION SOURCES (DG HEATSPARKSOPEN FLAMES) Materials To Avoid AVOID CHLORINE FLUORINE AND OTHER STRONG OXIDIZERS Hazardous Decomp Products BURNING CAN PRODUCE CARBON MONOXIDE ampOR CARBON DIOXIDE AND OTHER HARMFUL PRODUCTS Conditions To Avoid (Poly) NONE SPECIFIED BY MFG

Health Hazard Data

LD50-LC50 Mixture LD50 (ORAL RATS) = 188MLKG Route Of Entry - Inhalation YES

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lAMOCO OIL -- AMOCO REGULAR LEAD-FREE GASOLINE - GASOLINEAUTOMOTIVE httpsinuvmedUmsdshq295q292htm

Route Of Entry - Skin YES Route Of Entry - Ingestion NO Health Haz Acute And Chronic EYEHIGH CONCEN OF VAPMIST MAY CAUSE DISCOMFORT SKINPRLONGREPEAT CONTACT CAN DEFAT amp LEAD TO IRRIT ampOR DERM INHALVAPOUR HARMFUL HIGH VAP CONCEN CAN CAUSE HEADACHES DIZZINESS DROWSINESS NAUSEA INGESTLOW VISCOSITY PRODUCT HARMFULFATAL IF ASPIRATED INTO LUNGS CAUSING CHEM PNEUMONIAFATAL Carcinogenicity - NTP YES Carcinogenicity - IARC YES Carcinogenicity - OSHA YES Explanation Carcinogenicity CONTAINS BENZENE WHICH IS KNOWN TO CAUSE CANCER SignsSymptoms Of Overexp MAY PRODUCE HEADACHES DIZZ NAU DROWSINESS IRRIT OF EYENOSETHROATCNS DEPRESSION Med Cond Aggravated By Exp NONE SPECIFIED BY MFG EmergencyFirst Aid Proc EYEFLUSH WPLENTY OF WATER GET MED ATTN IF IRRIT PERSISTS SKINWASH WSOAP amp WATER REMOVE CONTAMIN CLOTHINGSHOES GET MED ATTN IF IRRIT DEVELOPS INHALREMOVE TO UNCONTAMINATED AREA GIVE ARTIFICIAL RESP IF NOT BREATHING GET MED ATTN INGESTDO NOT INDUCE VOMIT GET IMMED MED ATTN


Steps If Matl ReleasedSpill REMOVESHUT OFF ALL IGN SOURCESUSE WATER SPRAY TO DISPERSE VAPINCREASE VENTILATION IF POSSIBLECONTAIN ON ABSORBENT MATL(SANDSAWDUSTDIRTCLAY)KEEP OUT OF SEWERS amp WATERWAYSREPORT SPILLS TO APPROPRIATE AUTHORITIES Neutralizing Agent NONE SPECIFIED BY MFG Waste Disposal Method RESIDUESSPILLED MATL ARE HAZ WASTE DUE TO IGNITABILITY DISPOSAL MUST BE IAW APPLICABLE LOCAL STATE AND FEDERAL REGULATIONS ENCLOSED-CONTROLLED INCINERATION IS RECOMMENDED UNLESS DIRECTED OTHERWISE BY APPLICABLE ORDINANCES Precautions-HandlingStoring STORE IN FLAMM LIQ STORAGE AREA KEEP CNTNR CLOSED STORE AWAY FROM HEATING SOURCESOPEN FLAME IAW APPLICABLE FED STATELOG REGS Other Precautions KEEP AWAY FROM IGNITION SOURCES KEEP CONTAINER CLOSED USE WADEQUATE VENTILATION ABOID BREATHING VAPOR ampOR MIST USE AS MOTOR FUEL ONLY AVOID STRONG OXIDIZERS

Control Measures

Respiratory Protection IF VENTILATION IS INADEQUATE USE NIOSHMSHA CERTIFIED RESP WHICH WILL PROTECT AGAINST ORGANIC VAPMIST Ventilation USE WITH ADEQUATE VENTILATION Protective Gloves RECOMMENDED-PVC Eye Protection RECOMMENDED-SAFETY GLASSESGOGGLES Other Protective Equipment WEAR PROTECTIVE CLOTHING IF PRLONGEDREPEATED CONTACT IS LIKELY Work Hygienic Practices THOROUGHLY CLEANDRY CONTAMIN CLOTHING BEFORE REUSE WASH HANDS AFTER HANDLING amp BEFORE EATSMOKEDRINK Suppl Safety amp Health Data LONG-TERM INHAL STUDY OF WHOLE UNLEADED GASOLINE VAP EXPOSURE-RELATED KIDNEY DAMAGETUMORS WERE OBSERVED IN MALE RATS amp NOT SEEN IN FEMALESCHRONIC EXPOSURE TO BENZENE CAUSES LEUKEMIA IN HUMAND amp OTHER ADVERSE BLOOD EFFECTS (ANEMIA)

Transportation Data

Trans Data Review Date 94293 DOT PSN Code GTN DOT Proper Shipping Name GASOLINE DOT Class 3 DOT ID Number UN1203 DOT Pack Group II DOT Label FLAMMABLE LIQUID IMO PSN Code HRV

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AMOCO OIL -- AMOCO REGULAR LEAD-FREE GASOLINE - GASOLINEAUTOMOTIVE httpsiriuvmedUmsdshq295q292htmI

IMO Proper Shipping Name GASOLINE IMO Regulations Page Number 3141 IMO UN Number 1203 IMO UN Class 31 IMO Subsidiary Risk Label shy

I A T A P S N Code MUC IATA UN ID Number 1203 IATA Proper Shipping Name GASOLINE IATA UN Class 3 IATA Label FLAMMABLE LIQUID API PSN Code MUC API Prop Shipping Name GASOLINE API Class 3 API ID Number UN1203 API Pack Group II API Basic Pac Ref 7-7 Additional Trans Data PER MSDSDOT SHIPPING DESCRIPTIONGASOLINE 3 UN1203 II

Disposal Data

Label Data

Label Required YES Technical Review Date 200CT94 Label Status F Common Name AMOCO REGULAR LEAD-FREE GASOLINE Signal Word DANGER Acute Health Hazard-Moderate X Contact Hazard-Moderate X Fire Hazard-Severe X Reactivity Hazard-None X Special Hazard Precautions EYEHIGH CONCEN OF VAPMIST MAY CAUSE DISCOMFORT SKINPROLONGREPEAT CONTACT CAN DEFAT amp LEAD TO IRRIT ampOR DERM INHALVAPOUR HARMFUL HIGH VAP CONCEN CAN CAUSE HEADACHES DIZZINESS DROWSINESS NAUSEA INGESTLOW VISCOSITY PRODUCT HARMFULFATAL IF ASPIRATED INTO LUNGS CAUSING CHEM PNEUMONIAFATAL 1STAIDEYEFLUSH W PLENTY OF WATERIRRIT PERSISTS GET MED ATTNSKINWASH WSOAP amp WATERREMOVE CONTAMIN CLOTHSHOESIRRIT DEVELOPS GET MED ATTNINHALREMOVE TO UNCONTAMIN AREAGIVE ARTIFICIAL RESP IF NOT BREATHINGGET MED ATTNINGESTDO NOT INDUCE VOMITGET IMMED MED ATTN Protect Eye Y Protect Skin Y Protect Respiratory Y Label Name AMOCO OIL COMPANY Label Street 200 EAST RANDOLPH DRIVE Label City CHICAGO Label State IL Label Zip Code 60601 Label Country US Label Emergency Number 800-447-8735 (HEALTH)

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xNOCO -- 7620 PETROLEUM LUBRICATING OILGEAR OILS - GEAR OIL 68100150220320460 httpsiriuvmedUmsdshq219q494html i~

mdash

CONOCO -- 7620 PETROLEUM LUBRICATING OILGEAR OILS - GEAR OIL 68100150220320460 MATERIAL SAFETY DATA SHEET NSN 915000F049688 Manufacturers CAGE 5R396

Part No Indicator A Part NumberTrade Name 7620 PETROLEUM LUBRICATING OILGEAR OILS

General Information

Item Name GEAR OIL 68100150220320460 Companys Name CONOCO INC Companys Street 5 GREENWAY PLAZA E Companys P O Box 2197 Companys City HOUSTON Companys State IX Companys Country US Companys Zip Code 77252-5000 Companys Emerg Ph 800-441-3637713-293-5550 Companys Info Ph 713-293-5550800-441-3637 Record No For Safety Entry 001 Tot Safety Entries This Stk 001 Status SE Date MSDS Prepared 13OCT92 Safety Data Review Date 12AUG96 Preparers Company CONOCO INC Preparers St Or P O Box- 5 GREENWAY PLAZA E Preparers City HOUSTON Preparers State TX Preparers Zip Code 77252-5000 MSDS Serial Number BZWKC ====== = = === ss== === === =s=5============= sssssz3ss= sss= ====== ss = =r ==== = ====== == === =


Proprietary NO Ingredient MINERAL OIL PETROLATUM-LIQUID WHITE MINERAL OIL PARAFFIN OIL Ingredient Sequence Number 01 NIOSH (RTECS) Number PY8030000 CAS Number 8012-95-1 OSHA PEL 5 MGCUM ACGIH TLV 5 MGCUM Other Recommended Limit 10 MGCUM STEL


Appearance And Odor LIGHT AMBER TO BROWN LIQUID TO VISCOUS LIQUID WMILD PETROLEUM HYDROCARBON ODOR Boiling Point 750-1200F Vapor Pressure (MM Hg70 F) 0 Vapor Density (Air=l) gt1 Specific Gravity 087-0896 Evaporation Rate And Ref 0 Solubility In Water INSOLUBLE Percent Volatiles By Volume 0


Flash Point 300-470F Flash Point Method PMCC Extinguishing Media WATER SPRAY FOAM DRY CHEMICAL CO2 Special Fire Fighting Proc WATERFOAM MAY CAUSE FROTHING USE WATER TO KEEP FIRE EXPOSED CONTAINERS COOL WATER SPRAY MAY BE USED TO FLUSH SPILLS AWAY FROM EXPOSURES Unusual Fire And Expl Hazrds COMBUSTIBLE LIQUID PRODUCTS OF COMBUSTION MAY CONTAIN CO CO2 amp OTHER TOXIC MATERIALS AUTOIGNITION TEMP 690-750F

I o f 3 10199 1213PM

_ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _

CONOCO - 7620 PETROLEUM LUBRICATING OILGEAR OILS - GEAR OIL 68100150220320460 httpsinuvmedUmsdshq219q494html

Reactivity Data

Stability YES Cond To Avoid (Stability) SPARKS FLAME Materials To Avoid INCOMPATIBLE WSTRONG OXIDIZING AGENTS CO Hazardous Poly Occur NO

Health Hazard Data

Route Of Entry - Inhalation YES Route Of Entry - Skin NO Route Of Entry - Ingestion NO Health Haz Acute And Chronic OVEREXPOSURE CAN CAUSE MINOR amp REVERSIBLE IRRITATION TO THE EYES SKIN amp LUNGS Carcinogenicity - NTP NO Carcinogenicity - IARC NO Carcinogenicity - OSHA NO Explanation Carcinogenicity NONE SignsSymptoms Of Overexp IRRITATION Med Cond Aggravated By Exp SKIN EYE amp LUNG IRRITATION EmergencyFirst Aid Proc INHALATION REMOVE TO FRESH AIR GIVE CPR IMMEDIATELY FLUSH WPLENTY OF WATER FOR 15 MINS INGESTION DONT INDUCE VOMITING IMMEDIATELY GIVE 2 GLASSES OF WATER NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON OBTAIN MEDICAL ATTENTION IN ALL CASES


Steps If Matl ReleasedSpill USE APPROPRIATE PERSONAL PROTECTIVE EQUIPMENT DURING CLEANUP REMOVE SOURCES OF IGNITION amp DIKE PREVENT LIQUID FROM ENTERING SEWERS WATERWAYSLOW AREAS RECOVER FREE LIQUID FOR REUSE RECLAMATION SOAK UP WSAWDUSTSANDOIL DRYABSORBENT MATERIAL Waste Disposal Method TREATMENT STORAGE TRANSPORTATION amp DISPOSAL MUST BE IAWFEDERAL STATE amp LOCAL REGULATIONS RECOVER NONUSABLE FREE LIQUID amp DISPOSE OF IN AN APPROVED 4 PERMITTED INCINERATOR DONT FLUSH TO SURFACE WATERSANITARY SEWER SYSTEM Precautions-HandlingStoring STORE IAWNATIONAL FIRE PROTECTION ASSN REGULATIONS Other Precautions DONT ENTER ENCLOSEDCONFINED SPACE WO PROPER PROTECTIVE EQUIPMENT amp RESPIRATORY PROTECTION

Control Measures

Respiratory Protection WEAR APPROPRIATE NIOSH APPROVED RESPIRATORY PROTECTION TO MAINTAIN EXPOSURES BELOW ACCEPTABLE LIMITS PROPER RESPIRATOR SELECTION SHOULD BE DETERMINED BY ADEQUATELY TRAINED PERSONNEL amp BASED ON THE CONTAMINANTS Ventilation NORMAL Protective Gloves NITRIL BUTYL RUBBERNEOPRENE Eye Protection SAFETY GLASSES WSIDE SHIELDS Other Protective Equipment COVERALLS WLONG SLEEVES Work Hygienic Practices REMOVELAUNDER CONTAMINATED CLOTHING BEFORE REUSE WASH THOROUGHLY AFTER HANLDING WASH CLOTHING AFTER USE Suppl Safety amp Health Data NOTES TO PHYSICIAN ACTIVATED CHARCOAL SLURRY MAY BE GIVEN TO PREPARE ACTIVATED CHARCOAL SLURRY SUSPEND 50 GRAMS ACTIVATED CHARCOAL IN 400 ML WATER amp MIX THOROUGHLY GIVE 5MLKG350 ML FOR AN AVERAGE ADULT

Transportation Data

= = == ====== = ==ss = == = = =

Disposal Data

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CONOCO - 7620 PETROLEUM LUBRICATING OILGEAR OILS - GEAR OIL 68100150220320460 http sin uvm edumsdshq219q494 html lt

Label Data

Label Required YES Label Status G Common Name 7620 PETROLEUM LUBRICATING OILGEAR OILS

~mdash Special Hazard Precautions OVEREXPOSURE CAN CAUSE MINOR amp REVERSIBLE IRRITATION TO THE EYES SKIN amp LUNGS IRRITATION Label Name CONOCO INC Label Street 5 GREENWAY PLAZA E Label PO Box 2197 Label City HOUSTON Label State TX Label Zip Code 77252-5000 Label Country US Label Emergency Number 800-441-3637713-293-5550

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CLASSIC CHEMICAL - PENETRATING OIL - PENETRATING OIL http MSDS PDC CORNELL EDUmsdssinq251ql02 html

CLASSIC CHEMICAL -- PENETRATING OIL - PENETRATING OIL MATERIAL SAFETY DATA SHEET NSN 9150005987123 Manufacturers CAGE 22402 Part No Indicator A

mdash Part NumberTrade Name PENETRATING OIL

General Information

Item Name PENETRATING OIL Companys Name CLASSIC CHEMICAL Companys Street 3131 TURTLE CREEK SUITE 1010 Companys City DALLAS Companys State TX Companys Country US Companys Zip Code 75219-5415 Companys Emerg Ph NOT LISTED OUT OF BUSINESS Companys Info Ph ft 214-555-1212 NO LISTING Record No For Safety Entry 001 Tot Safety Entries This Stk 003 Status SE Date MSDS Prepared 21FEB92 Safety Data Review Date 21FEB92 Supply Item Manager CX MSDS Preparers Name DGSC-SSH Preparers Company DEFENSE GENERAL SUPPLY CENTER Preparers City RICHMOND Preparers State VA Preparers Zip Code 23297-5000 MSDS Serial Number BLZFX Specification Number A-A-50493 Spec Type Grade Class TYPE I Hazard Characteristic Code F4 Unit Of Issue PT Unit Of Issue Container Qty 10 PT Type Of Container CAN


Proprietary NO Ingredient ALIPHATIC PETROLEUM SOLVENT Ingredient Sequence Number 01 NIOSH (RTECS) Number OA5500000 CAS Number 8008-20-6 OSHA PEL NOT ESTABLISHED ACGIH TLV NOT ESTABLISHED Other Recommended Limit NONE SPECIFIED

Proprietary NO Ingredient UNIDENTIFIED COMPONENTS Ingredient Sequence Number 02 NIOSH (RTECS) Number 1001272UC


Appearance And Odor LIQUID WITH TYPICAL PETROLEUM HYDROCARBON ODOR Boiling Point gt200Fgt93C Vapor Density (Air=l) gt1 Decomposition Temperature UNKNOWN Solubility In Water NEGLIGIBLE Corrosion Rate (IPY) UNKNOWN

Fire and Explosion Hazard Data ======= = ============================== = ================ ===== = = =============

Flash Point gt100Fgt38C

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CLASSIC CHEMICAL -- PENETRATING OIL - PENETRATING OIL http MSDSPDC CORNELLEDUmsdssinq251q 102html

Extinguishing Media CARBON DIOXIDE FOAM OR DRY CHEMICAL WATER SPRAY MAY BE USED TO KEEP FIRE EXPOSED CONTAINERS COOL amp FLUSH SPILLS AWAY Special Fire Fighting Proc WEAR FULL PROTECTIVE CLOTHING AND NIOSHshyAPPROVED SELF-CONTAINED BREATHING APPARATUS WITH FULL FACEPIECE OPERATED IN THE POSITIVE PRESSURE MODE Unusual Fire And Expl Hazrds FLOWING PETROLEUM PRODUCTS CAN BE IGNITED BY STATIC ELECTRICITY

Reactivity Data

Stability YES Cond To Avoid (Stability) HIGH HEAT SPARKS STATIC ELECTRICITY OPEN FLAMES AND OTHER SOURCES OF IGNITION Materials To Avoid STRONG OXIDIZING AGENTS Hazardous Decomp Products CARBON MONOXIDE CARBON DIOXIDE AND OTHER UNIDENTIFIED COMPONENTS Hazardous Poly Occur NO Conditions To Avoid (Poly) NOT APPLICABLE ====================== ========================= ========== = ====== ======== == =

Health Hazard Data

Route Of Entry - Inhalation YES Route Of Entry - Skin YES Route Of Entry - Ingestion NO Health Haz Acute And Chronic ACUTE- IRRITATION OF EYES SKIN RESPIRATORY OR GI TRACTS CNS EFFECTS LIKE HEADACHE DIZZINESS NAUSEA AND VOMITING REDNESS OR BURNS OF EYESSKIN POSSIBLE CHRONIC DRYING OF SKIN DEFATTING OR DERMATITIS Carcinogenicity - NTP NO Carcinogenicity - IARC NO Carcinogenicity - OSHA NO SignsSymptoms Of Overexp IRRITATION OF EYES SKIN RESPIRATORY OR G I TRACTS CNS EFFECTS LIKE HEADACHE DIZZINESS NAUSEA AND VOMITING REDNESS OR BURNS OF EYESSKIN POSSIBLE Med Cond Aggravated By Exp PERSONS WITH A HISTORY OF AILMENTS OR WITH A PRE-EXISTING DISEASE INVOLVING THE EYES SKIN OR RESPIRATORY TRACT MAY BE AT INCREASED RISK FROM EXPOSURE WASH WITH SOAP amp WATER EYE FLUSH WITH WATER FOR 15 MINUTES HOLDING EYELIDS OPEN INHALED REMOVE TO FRESH AIR amp PROVIDE OXYGENCPR IF NEEDED ORAL DO NOT INDUCE VOMITING IF VOMITING OCCURS KEEP HEAD BELOW HIPS DUE TO ASPIRATION HAZARD CALL PHYSICIAN IMMEDIATELY


Steps If Matl ReleasedSpill USE PROPER PERSONAL PROTECTION CONTAIN FREE MATERIAL IF POSSIBLE USE SUITABLE INERT ABSORBENT MATERIAL AND RECOVER FOR PROPER DISPOSAL IN AN APPROVED CONTAINER PREVENT SPILLS ENTERING WATERWAYS OR SEWERS Neutralizing Agent NOT APPLICABLE Waste Disposal Method CONSULT LOCAL AUTHORITIES DISPOSAL MUST BE MADE IN ACCORDANCE WITH ALL APPLICABLE FEDERAL STATE AND LOCAL LAWS AND REGULATIONS REPORT SPILLS TO AUTHORITIES Precautions-HandlingStoring STORAGE-STORE IN COOL DRY WELL VENTILATED AREA AWAY FROM STRONG OXIDIZERS Other Precautions DO NOT TAKE INTERNALLY DO NOT BREATHE MISTS OR VAPORS AVOID CONTACT WITH EYES DO NOT GET IN EYES ON SKIN OR ON CLOTHING USE WITH ADEQUATE VENTILATION WASH THOROUGHLY AFTER HANDLING

Control Measures

Respiratory Protection USE NIOSHMSHA APPROVED RESPIRATOR WITH ORGANIC VAPOR FILTER AS REQUIRED IF ABOVE PELTLV OR SELF CONTAINED BREATHING APPARATUS IN AN ENCLOSED AREA Ventilation LOCALGENERAL TO MAINTAIN PELTLV Protective Gloves NEOPRENE NITRILE OR NATURAL RUBBER

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CLASSIC CHEMICAL -- PENETRATING OIL - PENETRATING OIL http MSDS PDC CORNELL EDUmsdssmq251ql02 html

Eye Protection SAFETY GOGGLES WITH OPTIONAL FACE SHIELD Other Protective Equipment EYE WASH STATION AND SAFETY SHOWERWORK CLOTHING AND APRON AS REQUIRED Work Hygienic Practices OBSERVE GOOD PERSONAL HYGIENE PRACTICES AND RECOMMENDED PROCEDURES DO NOT WEAR CONTAMINATED CLOTHING OR FOOTWEAR Suppl Safety amp Health Data NO MSDS WAS AVAILABLE FROM MANUFACTURER THIS MSDS WAS PREPARED BY THE PROFESSIONALS OF DGSC-SSH WITHOUT ANY WARRANTY IT IS THE USERS RESPONSIBILITY TO GATHER INFORMATION AND USE THE MATERIAL PROPERLY TO PROTECT EMPLOYEES AND ENVIRONMENT THE NSN CANCELLED EFFECTIVE 82121 AND REPLACED BY 9150-00-261-7899

Transportation Data

Trans Data Review Date 92052 DOT PSN Code LKZ DOT Proper Shipping Name PETROLEUM DISTILLATES NOS OR PETROLEUM PRODUCTS NOS DOT Class 3 DOT ID Number UN1268 DOT Pack Group III DOT Label FLAMMABLE LIQUID IMO PSN Code LMH IMO Proper Shipping Name PETROLEUM DISTILLATES NOS o IMO Regulations Page Number 3375 IMO UN Number 1268 IMO UN Class 33 IMO Subsidiary Risk Label shyIATA PSN Code TJB IATA UN ID Number 1268 IATA Proper Shipping Name PETROLEUM DISTILLATES NOS IATA UN Class 3 IATA Label FLAMMABLE LIQUID AFI PSN Code- TJB AFI Prop Shipping Name PETROLEUM DISTILLATES NOS AFI Class 3 AFI ID Number UN1268 AFI Pack Group III AFI Basic Pac Ref 7-7 NOS Shipping Name CONTAINS LIGHT PETROLEUM DISTILLATE

Disposal Data = = = = = = = = 5= = = = ==

= = == = ===== = S3SSpound

Label Data

Label Required YES Technical Review Date 21FEB92 MFR Label Number UNKNOWN Label Status F Common Name PENETRATING OIL Signal Word WARNING1

Acute Health Hazard-Moderate X Contact Hazard-Moderate X Fire Hazard-Moderate X Reactivity Hazard-None X Special Hazard Precautions ACUTE- IRRITATION OF EYES SKIN RESPIRATORY OR GI TRACTS CNS EFFECTS LIKE HEADACHE DIZZINESS NAUSEA AND VOMITING REDNESS OR BURNS OF EYESSKIN POSSIBLE CHRONIC DRYING OF SKIN DEFATTING OR DERMATITIS STORAGE-STORE IN COOL DRY WELL VENTILATED AREA AWAY FROM STRONG OXIDIZERS FIRST AID- GET MEDICAL ATTENTION IF SYMPTOMS PERSIST SKIN WASH WITH SOAP amp WATER EYE FLUSH WITH WATER FOR 15 MINUTES HOLDING EYELIDS OPEN INHALED REMOVE TO FRESH AIR amp PROVIDE OXYGENCPR IF NEEDED ORAL DO NOT INDUCE VOMITING IF VOMITING OCCURS KEEP HEAD BELOW HIPS DUE TO ASPIRATION HAZARD CALL PHYSICIAN IMMEDIATELY Protect Eye Y

3of4 10199 12 29PM

CLASSIC CHEMICAL -- PENETRATING OIL - PENETRATING OIL httpMSDSPDCCORNELLEDUmsdssiriq251ql02html

Protect Skin Y Protect Respiratory Y Label Name CLASSIC CHEMICAL Label Street 3131 TURTLE CREEK SUITE 1010 Label City DALLAS

mdash Label State TX Label Zip Code 75219-5415 Label Country US Label Emergency Number NOT LISTED OUT OF BUSINESS

4 of 4 10199 1229 PM

lMATHESON GAS PRODS DI OF ILL ROSS - QUIGAS 3 LOW - METHANE COMPRESSED GAS httpsinorgmsdshql 13ql50 htm

MATHESON GAS PRODS DIV OF WILL ROSS -- QUIGAS 3 LOW - METHANE COMPRESSED GAS MATERIAL SAFETY DATA SHEET NSN 683000F048995 Manufacturers CAGE 23972 Part No Indicator C

mdash Part NumberTrade Name QUIGAS 3 LOW

General Information

Item Name METHANE COMPRESSED GAS Companys Name MATHESON GAS PRODS DIV OF WILL ROSS INC Companys Street 1920 WEST J ST Companys P 0 Box 908 Companys City LA PORTE Companys State TX Companys Country US Companys Zip Code 77571 Companys Emerg Ph 713-471-2544 Companys Info Ph ft 713-471-2544 DistributorVendor 1 BENTLEY WELDING SUPPLY DistributorVendor ft 1 Cage 73200 Record No For Safety Entry 003 Tot Safety Entries This Stkft 004 Status KE Date MSDS Prepared 25JUN90 Safety Data Review Date 16JUL96 Preparers Company MATHESON GAS PRODS DIV OF WILL ROSS INC Preparers St Or P 0 Box 1920 WEST J ST Preparers City LA PORTE Preparers State TX Preparers Zip Code 77571 MSDS Serial Number BZVFN


Proprietary NO Ingredient METHANE Ingredient Sequence Number 01 Percent 25 NIOSH (RTECS) Number PA1490000 CAS Number 74-82-8 ACGIH TLV SIMPLE ASPHYXIANT


Appearance And Odor COLORLESS TASTELESS GAS WNO ODOR Boiling Point -260F Melting Point -296F Vapor Pressure (MM Hg70 F) 76 Vapor Density (Air=l) 0555 Specific Gravity 0717 Solubility In Water 35


Flash Point -369F Lower Explosive Limit 5 Upper Explosive Limit 15 Extinguishing Media DRY CHEMICAL C02HALON FOR LARGE WATER SPRAY FOG STANDARD FOAM Special Fire Fighting Proc MOVE CONTAINER FROM AREA STAY AWAY FROM STORAGE TANK ENDS FOR MASSIVE FIRE USE UNMANNED HOSE HOLDERMONITOR NOZZLESWDRAW FROM AREA amp LET BURN (SEE SUPP) Unusual Fire And Expl Hazrds VAPOR-AIR MIXTURES ARE EXPLOSIVE gtFLASHPOINT CYLINDER MAY EXPLODE IN HEATFIRE DUE TO ELECTROCONDUCTIVITY

I o f 3 10199 207 PM

lMATHESON GAS PRODS D1V OF WILL ROSS -- QUIGAS 3 LOW - METHANE COMPRESSED GAS httpsiriOrgmsdshql 13ql50htm

FLOWAGITATION MAY GENERATE SPARKS WIGNITION(SUPP

Reactivity Data

Stability YES Cond To Avoid (Stability) HEAT SPARKS FLAMES STATIC ELECTRICITY amp OTHER IGNTION SOURCES Materials To Avoid BROMINE CHLORINE CHLORINE DIOXIDE DIOXYGEN DIFLUORIDE FLUORINE INTERHALOGENS OXIDIZERS OXYGEN DIFLUORIDE OXYGEN Hazardous Decomp Products OXIDES OF CARBON Hazardous Poly Occur NO = ============= = =mdash=== =========== ==== = ===== ===mdash =====pound= mdash = = = = ====== == =========

Health Hazard Data

Route Of Entry - Inhalation YES Route Of Entry - Skin NO Route Of Entry - Ingestion YES Health Haz Acute And Chronic MAY CAUSE ASPHYXIATION WRAPID RESPIRATION amp PULSE COLLAPSE DEEP COMA amp DEATH SKIN MAY CAUSE FROSTBITE amp DEVELOP BLISTERS EYES FROSTBITE amp BLURRED VISION INGESTION FROSTBITE MAY DAMAGE THE LIPS MOUTH amp MUCOUS MEMBRANES Carcinogenicity - NTP NO Carcinogenicity - IARC NO Carcinogenicity - OSHA NO Explanation Carcinogenicity NONE SignsSymptoms Of Overexp ASPHYXIATION UNCONSCIOUSNESS RAPID RESPIRATION amp PULSE AIR HUNGER DIZZINESS REDUCED AWARENESS TIGHTNESS IN THE HEAD TINGLING SENSATIONS INCOORDINATION FAULTY JUDGEMENT EMOTIONAL INSTABILITY RAPID FATIGUE NAUSEA VOMITING COLLAPSE CONVULSIONS COMA REDNESS PAIN NUMBNESS BLURRED VISION EmergencyFirst Aid Proc INHALATION REMOVE TO FRESH AIR IMMEDIATELY IF BREATHING HAS STOPPED GIVE CPR MAINTAIN AIRWAY amp BLOOD PRESSURE amp GIVE OXGYGEN KEEP WARM amp AT REST TREAT SYMPTOMATICALLYSUPPORTIVELY OXYGEN

SHOULD BE GIVEN BY QUALIFIED PERSONNEL SKIN WASH WWARM WATER AT TEMP OF 107F EYES WASH WLARGE AMOUNTS OF WARM WATER FOR 15-20 MINS OBTAIN MEDICAL ATTENTION IN ALL CASES NO SPECIFIC ANTIDOTE


Steps If Matl ReleasedSpill SHUT OFF IGNITION SOURCES STOP LEAK SAFELY WO RISK USE WATER SPRAY TO REDUCE VAPORS ISOLATE AREA UNTIL GAS HAS DISPERSED NO SMOKINGFLAMESFLARES KEEP PEOPLE AWAY ISOLATE HAZARD AREA amp DENY ENTY VENTILATE CLOSED SPACES BEFORE ENTERING Waste Disposal Method DISPOSE OF IN ACCORDANCE WLOCAL STATE amp FEDERAL REGULATIONS UN1971 EPA HAZARDOUS WASTE NUMBER D001 Precautions-HandlingStoring STORE AWAY FROM INCOMPATIBLE SUBSTANCES AVOID CONTACT WHEATSPARKSFLAMESOTHER IGNITION SOURCES Other Precautions CONTENTS UNDER PRESSURE CONTAINERS MAY RUPTURE VIOLENTLY amp TRAVEL A CONSIDERABLE DISTANCE

Control Measures

Respiratory Protection USE ANY SUPPLIED-AIR RESPIRATOR OPERATED IN PRESSURE-DEMANDOTHER POSITIVE PRESSURE MODE ANY SELF CONTAINED BREATHING APPARATUS FOR FIREFIGHTING A SCBA WFULL FACEPIECE OPERATED IN PRESSUREshyDEMANDPOSITIVE PRESSURE MODE Ventilation GENERAL DILUTION VENTILATION Protective Gloves FULL PROTECTIVE COLD INSULATING Eye Protection SPLASH-PROOF SAFETY GOGGLESFACESHIELD Other Protective Equipment EYEWASH FOUNTAIN QUICK DRENCH SHOWER Work Hygienic Practices CONTACT LENSES SHOULDNT BE WORN Suppl Safety amp Health Data FIRE PROC CONTD WDRAW IMMEDIATELY IF RISING SOUND FROM VENTING SAFETY DEVICEANY DISCOLORATION OF STORAGE TANK FROM FIRE LET STORAGE VESSEL BURNEXTINGUISH IF FLOW CAN BE STOPPED COOL CONTAINERS WFLOODING AMOUNTS OF WATER APPLY FROM A FAR DISTANCE AVOID

2 of3 10199 207 PM

MATHESON GAS PRODS DIV OF WILL ROSS - QUIGAS 3 LOW - METHANE COMPRESSED GAS httpsiriOrgmsdshql 13q 150html

BREATHING VAPORS KEEP UPWIND EVACUATE-RADIUS OF 1500 FT

Transportation Data

Disposal Data = ===== = == = S5== ==

===============

Label Data

Label Required YES Label Status G Common Name QUIGAS 3 LOW Special Hazard Precautions MAY CAUSE ASPHYXIATION WRAPID RESPIRATION amp PULSE COLLAPSE DEEP COMA amp DEATH SKIN MAY CAUSE FROSTBITE amp DEVELOP BLISTERS EYES FROSTBITE amp BLURRED VISION INGESTION FROSTBITE MAY DAMAGE THE LIPS MOUTH amp MUCOUS MEMBRANES ASPHYXIATION UNCONSCIOUSNESS RAPID RESPIRATION amp PULSE AIR HUNGER DIZZINESS REDUCED AWARENESS TIGHTNESS IN THE HEAD TINGLING SENSATIONS INCOORDINATION FAULTY JUDGEMENT EMOTIONAL INSTABILITY RAPID FATIGUE NAUSEA VOMITING COLLAPSE CONVULSIONS COMA REDNESS PAIN NUMBNESS BLURRED VISION Label Name MATHESON GAS PRODS DIV OF WILL ROSS INC Label Street 1920 WEST J ST Label PO Box 908 Label City LA PORTE Label State TX Label Zip Code 77571 Label Country US Label Emergency Number 713-471-2544

3 of 3 10199 207 PM

ATTACHMENT D

FIELD FORMS

FOR wR GRACE amp Co - CONN MWP_DOCSN0992000F1NALPHASEIRJ02251600WPD ATTD1-1 HSI GeOTfaHS lllC

TETRA TECH INC

ACCIDENT AND ILLNES INVESTIGATION REPORT

To From Division or Subsidiary Health and Safety Representative

Office Project Name_ Telephone Project No Fax

E-mail

Information Regarding Injured or III Employee

Name Office

Home address Gender M I I No of dependents

Marital status

Home telephone Date of birth

Date of Accident Time of Accident

Location of Accident

Street address

City state and zip code

County

Narrative Description of How Accident Occurred (Explain what the employee was doing and describe work process )

Was employee performing regular job duties YeQ NoQ

Was safety equipment provided Yesd NoQ

Was safety equipment used YesO NoQ

Note Attach any police reports or related diagrams to this accident report

Witness(es)

Name

Address

Telephone

Nature of Illness or Injury and Part of Body Affected

Form AR-l Page 1 of3

Medical Treatment Required Lost Work Days

D No D Yes D First Aid Only [H No of Lost Work Days

Physicians Name Last Date Worked

Hospital or Office Name Time employee left Work

Address D No of Restricted Work Days

D None

Telephone No

Corrective Action(s) Taken by Unit Reporting the Accident

Corrective Action Still to be Taken (by whom and when)

Name of Tetra Tech employee the injury or illness wa s first reported to

Date of Report Time of Report

Printed Name Signature Telephone No Date

Project or Office Manager

Site Safety Coordinator

Injured Employee

To be completed by Human Resources SSN

Date of hire Hire date in current job

Wage information $_ per (hour day week or month)

Position at time of hire

Current position Shift hours

State in which employee was hired

Status [~1 Full-time l~1 Part-time Hours per week Days per week

Temporary job end date - bullbullgtbdquo

To be completed during report to workers compensation insurance carrier

Date reported Reported by

FormAR-l Page 2 of3

TETRA TECH INC

ACCIDENT AND ILLNES INVESTIGATION REPORT (Gntinued)

r itwpound v Confirmation number bullraquo f y I bull Name of contact s Field office of claims adjuster

FormAR-1 Page 3 of3

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TETRA TECH INC

DAILY TAILGATE SAFETY MEETING FORM

Date Time Project No

Client Site Location

Site Activities Planned for Today

Safety Topics Discussed

Protective clothing and equipment

Chemical hazards

Physical hazards

Environmental and biohazards

Equipment hazards

Decontamination procedures

Other

Review of emergency procedures

Employee Questions or Comments

Form HST-2 Page 1 of 2

TETJRA TECH INC i- ~ shy

DAILY TAILGATE SAFETY MEETING FORM (Continued)

Attendees

Printed Name Signature

Meeting Conducted by

Name Title

Signature


TETRA TECH INC

FIELD AUDIT CHECKLIST

Project Name

Field Location

Project Manager

General Items

Health and Safety Plan Requirements

Project No

Completed by

Sice Safety Coordinator

1 Approved health and safety plan (HASP) on sue or available

~gt Names of on-site personnel recorded in field logbook or daily log

3 HASP compliance agreement form signed by all on-site personnel

4 Material Safety Data Sheets on site or available

5 Designated sue safety coordinator present

6 Daily tailgate safety meetings conducted and documented

7 On-site personnel meet HASP requirements for medical examinations fit testing and training including subcontractors)

8 Compliance with specified safe work practices

9 Documentation of training medical examinations and fit tests available from employer

10 Exclusion decontamination and support zones delineated and enforced

11 Wmdsock or nboons in place to indicate wmc direction

12 Illness and injury preennon program reports completed (California only)

Emergency Planning

13 Emergency telephone numbers posted

14 Emergency route to hospital posted

15 Local emergency providers notified of site activities

16 Adequate safer equipment inventory availaole

17 First aid provider and supplies available

18 Eyewash stations in place

Air Monitoring

19 Monitoring equipment specified in HASP available and in working order

20 Monitoring equipment calibrated and calibration records available

21 Personnel know how to operate monitoring equipment and equipment manuals available on sue

23 Environmental and personnel monitoring performed as specified in HASP

In Compliance

Yes No NA

1

Form F-1 Paae 1 of 2

TETRA TECH INC laquobullmdashbull

FIELD AUDIT CHECKLIST (Continued)

Safety Items In Compliance

Personal Protection Yes No NA

1 Splash suit

2 Chemical protective clothing

3 Safety glasses or goggles

4 Gloves

5 Overboots

6 Hard hat

7 Dust mask

8 Hearing protection

9 Respirator

Instrumentation

10 Combustible gas meter

11 Oxygen meter

i mdash Organic vapor analyzer

Supplies

13 Decontamination equipment and supplies

1-i Fire extinguishers

15 Spill cleanup supplies

Corrective Action Taken During Audit

Corrective Action Still Needed

Note NA = No applicable

Auditor s Signature Site Safetv Coordinators Signature

Date

Form F-I Page 2 of 2

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PLAN ACCEPTANCE FORM

PROJECT HEALTH AND SAFETY PLAN PROJECT NAME

Instructions This form is to be completed by each person to work on the subject project work site and returned to the Director of Health and Safety

I represent that I have read and understand the contents of the above plan and agree to perform my work in accordance with it

Worker Signature SSO Signature

Print Name CompanyOffice

CompanyOffice Date

Date

TETRA TECH - gtmdashshy

PREPARATION AND TESTING OF NON-PERMIT REQUIRED CONFINED SPACE

Site Information

Project Name Date

Specific Field Location Project Manager Initials

Project No

Description of Work Performed

Space Preparation

Precautions taken for entrance cover opening

Entrance barrier(s) used

Ventilation equipment used

Atmospheric Testing Record

Result

Acceptable Conditions ampm ampm ampm ampm ampm ampm

Oxygen-nun gt195

Oxygen-max lt235

Flam inability lt10 LEL

HS lt10 ppm

Cl lt05 ppm

CO lt35 ppm

SO lt2 ppm

Heat degFdegC

Toxic (specify)

Other

Tester Initials

If acceptable conditions are not met describe techniques used to control the hazard

Signature of Tester

Notes

CI Chlonne LEL Lower explosive limit CO Carbon monoxide ppm Pan per million HS Hydrogen sulfide SO Sulfur Dioxide

If atmospheric testing indicates that the hazards are not being controlled within acceptable conditions entrants must leave the confined space Procedures for a permit-required confined space must then be followed

Form No CS-2 Page 1 of 1

TETRA TECH INC

PROTECTIVE EQUIPMENT INSPECTION

PROTECTIVE CLOTHING

Before use

bull Determine that the clothing material is correct for the specific task at hand

bull Visually inspect the equipment for

- Imperfect seams

- Nonuniform coatings

- Tears

- Malfunctioning closures

bull Hold up to light and check for pinholes

bull Flex the equipment and

- Observe for cracks

Observe for other signs of shelf deterioration

After use inspect inside and out for the same signs of chemical attack

During use periodically inspect equipment for

bull Evidence of chemical attack such as discoloration swelling stiffening and softening Keep in mind however that chemical permeation can occur without any visible effects

bull Closure failure

bull Tears

bull Punctures

bull Seam discontinuities

Note Discard any protective clothing that has any of the conditions listed above

GLOVES

Before use

bull Visually inspect gloves for

- Imperfect seams

Tears and abrasions


bull Pressurize glove with air and listen for pinhole leaks

Note Discard any gloves that exhibit any of the conditions listed above

FomPPE-l Page 1 Of 2

TETRA TECH INC

PROTECTIVE EQUIPMENT INSPECTION (Continued)

FOOTWEAR

Before use inspect footwear for

bull Holes and cuts

bull Interior wetness

bull Integrity of closures

bull Cracks in sole

Note Discard any footwear that exhibits any of the conditions listed above

EYEWEAR

Before use inspect eyewear for

bull Cracks

Fogginess

bull Scratches

bull Sturdiness of frame or supports and suspension

Note Discard any eyewear that exhibits any of the conditions listed above

HEADGEAR

Before use inspect headgear for

Cracks or gouges

bull Sturdiness of suspension system

Note Discard any headgear that exhibits any of the conditions listed above

Page 2 of 2

TETRA TECH INC

SERIOUS NEAR-MISS NCIDENT REPORT

Note Not to be usedfor OSHA recordable cases or cases involving Workers Compensation

Report date Office Project number

Site name

Site address

City state and zip

TYPE OF INCIDENT Q Near-miss (injury) D Operational error

I I Fire or explosion I I Environmental release

I I Equipment damage I I Other (explain on back of page)

DESCRIBE EVCIDENT(if necessary use separate sheet)

RESULTS OF INCIDENT(explain fully damage losses and so on)

BASIC CAUSES(designate all possible causes and explain fully)

CORRECTIVE MEASURES TAKEN

ADDITIONAL CORRECTIVE MEASURES TO BE TAKEN

Signature of Project Manager Date

Signature of Employee Date

Reviewed by Date

Form AR-2 Page 1 of 1

UTILITY CLEARANCE REQUEST WorkClearance Previously at this location Y a N a

oday s Date Dia-ln Start Date

Proiec Name Task No

Exact Location of Utility Clearance (address etc)

Faaiitv Contact Name Teleohone No

Facility Enqmeer Name Teleohone No

Site Descnotion

What Facility Utility Drawings are Available (If available please provide)

CHECKLIST Comoleted ay P3ject ManagerDelegate) (Completed by Clearance Engineer)

bull SiteFacility Drawings Available Y z N z 2 Checxeo with (Fac Engr Facility contract Other) Y 3 N r FIELD VERIFICATION 3 EmergeneSaTety Shut-Off Switcned Located on Utility Plan Yz N

IDENTIFY KNOWN UTILITY IWITTAI OATC NOTES (CHECK EVERY SITE) INITIALDATE

A Water Unes Y - N _ A

3 Sanitarylndustnal Sewer Y C N - 8

C Storm Drains Y- N r C

D Electrical Lines or Vaults Y r N 0

= Natural Gas Y - N E

F Louid Fuel Y - N r F

G Stream Y - N z G

H Comoressor Air Y - N H

1 TeiecnoneCaole Y - N -

- Ovemeaa Lines or degioes Y - N r J

lt Other lt list) Y = N K

Clearance Enaineer (Namraquo-rmt) (Signature i (Oatai

HSI GeoT-ans Review 3-0| MgrCeiwgatei (Namlaquo-Pnnt) (Sisnatu-91 (Oata)

Client Review (Nam -Pint) (Signatu-9i (Oaie)

Attachments Must be included Distnbution

Site Safer Plan (By P M) P-oiect Manaqer

Site Sketcn (By Clearance Engineer) Fielo Suoervisor

Others Lst) Poiect File

Health and Saretv Manaoer

ATTACHMENT E

HEALTH AND SAFETY PLAN FOR ECOLOGICAL RISK ASSESSMENT

FOR WR GRACE amp Co - CONN MWP_DOCSN0992000FINALPHASEIRI0225I600WPD A I I E1-1 HSI GCOTfanS IRC

Menzie-Cura amp Associates Addendum to the HIS Geotrans Health and Safety Plan WR Grace Superfund Site

Acton Massachusetts

Menzie-Cura amp Associates Inc adopts the HSI Geotrans Health and Safety Plan (HSP) The HSP contains a hazard assessment for contaminants found at the Site historically In addition to HSI Geotrans HSP Menzie-Cura amp Associates Inc personnel will following the boating safety procedures identified here when sampling in Sinking Pond and the reference pond

This work will take place in a small boat (possibly using a gasoline run outboard motor) All personnel will wear a United States Coast Guard approved personal flotation device (PFD) whenever working from the boat No smoking is allowed at any time in the boat or within 50 feet of it during refueling The Captain will be named at a later date At the Captains discretion he or she can modify or cancel any on-board operation for safety reasons Such reasons may include but are not limited to weather condition of boat or motor condition of sampling equipment or preparedness of personnel All personnel working on board will follow his or her orders

We will follow small boat safety procedures The boats transom or seats will contain a plate which describes the total weight capacity and other limitations of the particular boat used We will not exceed these The boats equipment will include motor full spare gasoline tank oars installed oar locks Danforth anchor 50 feet of half inch nylon anchor line terminated in three feet of half inch galvanized chain a metered and weighted line to estimate depth personal flotation devices (PFDs) for everyone on board a two quart canteen of drinking water (otherwise there should be no food on-board) and a cell phone

Personnel on board will each carry a belted and sheathed jack knife or rigging knife On-board personnel will be aware of the position of their bodies relative to coiled or faired lines or lines under tension Especially do not put hands or feet in any basket containing a faired line or sit upon a coiled deck line Always position yourself to one side of a line under tension Never position yourself behind a line under tension or between such a line and the gunnel of the boat or any other immovable object During over the side operations lower all lines Never let a weighted line free fall The most common way to drown is to go over the side with a free falling anchor or equipment line tangled around a leg arm or neck Grab samplers are not intended to free fall they are designed to be lowered It may be necessary to let certain samplers free fall a short distance (ie several feet) from above the bottom Lower them to that height above bottom Always know the depth to bottom before deploying equipment

Generally stay seated in the boat It is sometimes necessary to stand when deploying equipment Do this keeping your center of gravity as low as possible and as near the center line of the boat as possible Before standing or changing your position in the boat announce your intentions to all on-board

APPENDIX E COMMUNITY RELATIONS SUPPORT PLAN

WR GRACE SUPERFUND SITE ACTON MASSACHUSETTS

HSI GEOTRANS PROJECT No N099-007 MARCH 102000 HSI GeoTrans inc

WR Grace amp Co - Conn (Grace) will support the government parties in their

community relations efforts At their request Grace will support the government parties in the

following at a minimum

bull participation in public informational or technical meetings including the

provision of visual aids and equipment

bull publication and copying of fact sheets or updates and

bull assistance in preparing a responsiveness summary after the remedial

investigationfeasibility study public comment period

FOR WR GRACE amp Co - CONN M WP_DOCSN0992000FINALPHASEIIU0228I155WPD APPE1-1 HSI GfiOTranS lllC

barcode 43196

barcodetext SEMS Doc ID 43196

HSI GeoTrans inc

PROJECT NO N099

Plan Preparation

Prepared by (3Joo)

Reviewed and Approved by

Approval

HSI GeoTrans Project Manager ( 5 2 )

Health and Safety Program Manag i too)

FOR WR GRACE amp Co - CONN MWPJXXSN0992000FINA1 PHASC I RI0225 1 600 WTO HSI lllC







TABLE OF CONTENTS

PAGE










LIST OF ATTACHMENTS







LIST OF TABLES

PAGE









LIST OF FIGURES

PAGE




ACGIH




1 INTRODUCTION


















Section 2-7)







their own employees






















Non-Hazardous Site

Characterization









Site Office

Ambulance

Hospital


Fire Department

Poison Control

Nearest Phone



Client Contact

Project Coordinator






NameLocation Number







Fire Emergency 911








Donald Hanson MADEP

Workcare Inc

(800)424-8426










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Radiation






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HAZARD

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46

-TR

ICH

LOR

OPH

ENO

L

4-D

INIT

RO

PHEN

OL

APH

THA

LEN

E I-

n-B

UTY

LPH

THA

LATE

ITR

OB

ENZE

NE

4-D

lCH

LOR

OB

ENZE

NE

2-D

ICH

LOR

OB

ENZE

NE

I-n-

OC

TY

LPm

HA

LA

TE

CE

NA

PHT

HE

NE

UTY

LBEN

ZYLP

I ITH

ALA

TE

LUO

RA

NIH

ENE

IbTH

YLP

HTH

ALA

TE


shyCO H u

e ^ c -2 M 1 g3

ill 58 4gt w

S sect |

U Q

e poundbull 2 5D





^ s i O U uo


fl

SB

A g H


S BB 8 8 5 0


o w e Z y S

a) H

ej)pm


ltN

S _3 ^

| gt 3 C0

tU

U jB



sectO bulla

c s

l o


LU ^trade

Z gt EM S C tlJ

w ^ Z o z ^ 1 ^


rs

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uT 2 ^

^

O 2 ^

S z sect J

C ^ - - 1 - ^ ^ 1 ^ 2 ^ ^ ^ ^ sect


U

U JG

C

H2

O

C^^3 K

W~l

3 (N U

^

rlt o 5

g

J |

0 J3

1

Q 03

S f

RG

RA

CE

RC

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nA

ccraquos9

sect1

ai ^ 2O JLL a

_C

w C 5 Hllf

oIs- o o




u a

So 7s gv lt


^ rraquo

c +z u c

Cfl


bull



m

_ bull

M H 12

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HLO

RO

PR

OP


QJ CQ r- s

3

C5 1 Q Z |

UJ tO C c f

lt 1O QU aj a


cont

inue

BE

NZ

EN

E

11

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HLO

RO

ET

HE

VIN

YL C

HLO

RID

E

ET

HY

LB

EN

ZE

NE

AC

ET

ON

E

CH

LO

RO

ET

HA

NE

11 -D

ICH

LO

RO

ET

HA

XY

LE

NE

(T

OT

AL)

FO

R W

RG

RA

CE

H H

rojtc

tsW

RG

Act

oMA

cccs

s97t


TJ - s s s o G

12

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HLO

RO

ET

HA

D S D 2 W LU S

AR

SE

NIC

I S_U

UJ


gt

J

e s- C reg Si fl

raquo raquo

S bullpound 3

3 g ~ S

sect a 2 d V



U C E

c o O gv



0 raquo u c

CA

laquobullB


_^ ^ mdash 1

O U Z bullpound

O

5 j elaquo

^ 4gt 00 C5


S gtbull -5 bull C5


O U R

Z laquo S 1

11 2

-TE

TR

AC

l ILO

RO

ET

l IA

N^ r



0 S -bull3u ^

C3 j

1

a UJ Uj UJ

z0 Z X


11

2-T

RIC

HLO

RO

ET

IIAN

F

TR

ICH

LO

RO

I-LU

OR

OM

ET

HA

N

CH

LOR

OB

EN

ZE

NE

CH

LOR

OFO

RM

BR

OM

OM

ETH

AN

E

n-P

RO

PY

LBE

NZ

EN

E

BR

OM

OF

OR

M

2-C

HLO

RO

ET

HY

LV

INY

L E

TH

E

BR

OM

OD

ICH

LOR

OM

ET

HA

NE

CA

RB

ON

TE

TR

AC

HLO

RID

E

cis-

1 3

-DIC

HLO

RO

PR

OP

EN

E

p-X

YLE

NE

FO

R W

RG

RA

CE

P P

roje

cls

WR

GA

clon

Ucc

ess9

7N

099B

D m

dbshy

Tab

le 1

-1 (c

ontin

ued)

Com

pound


Cbull

H CO


S 2 oE bull bullo V



c _o i



eji

lt C o igt

ciU fi u c


o T3 C

6 V cs

bull ^ c]Z bull0U



^ rjr laquoQ^ jE DC


trt

6 0flj 3 T3

U CZ U 0 O

5 H 1 0gt

^Jlt2J 6JD c S ltuc

W

utJ3 v-




C e 3

Z gtltu E

a- 5TlkJ

Com

poun

d de

tect

ed a s

om

pound

trans-

l3-D

ICH

LO

RO

PR

O

1U

_c -raquo

o o

ltuf raquo U

_3 a

00

ltU D

c 9gt V

CO U 1 oco

1



SVOC

VOC

14-Dichloro benzene

4-Methylphenol


Nitrobenzene

Phenol


11-Dichloroethene

12-Dichloroethane

12-Dichloropropane

Benzene

Carbon disulfide

Chloroform

Chloromethane

Methylene chloride

Vinyl chloride

LFC(lOppm)

2 3 ppm

5 ppm

1 ppm [skin]

5 ppm

1 ppm

LFC( lppm)

1 ppm

LFC (75ppm)

0 1 ppm

1 ppm

2 ppm

LFC (50ppm)

LFC (25ppm)

LFC (1 ppm)

0 (A3)

n

3 (A3)

V) (A4)

S(A4)

n a (A3) 3 (A4)

g (A3) VI ( A l )






O O

a

d O

rgta

0 O

o tt

_o cL o

pound=i O)



SECONDARY LAGOON


SLOWDOWN PIT

EMERGENCY LAGOON

PRIMARY LAGOON


NORTH LAGOON

TANK CAR AREA


AHAKT2



HSI



h-s_SCH-smdwg















STATION PROTOCOL





Disposal Procedures




















methane in air


air


Confined Space


10ppm~H2S 28 ppm CO






Instrument

Action Level

Protocol

PPE

Action Level

Protocol

PPE

Action Level

Protocol

PPE

OVA andor HNu

Background


Level D



Level D



Level D






PPE Level D



PPE Level D





















Protective gloves



Dosimeter Type

Hard hat



Hearing protection


Other















Protective gloves



Dosimeter Type

Hard hat



Hearing protection


Other












STATION PROTOCOL






Disposal Procedures















methane in air


air






Instrument

Action Level

Protocol

PPE

Action Level

Protocol

PPE

Action Level

Protocol

PPE

OVA andor HNu

Background


Level D



Level D



Level D























_ Protective gloves



Dosimeter Type

Hard hat



Hearing protection


Other















Protective gloves



Dosimeter Type

Hard hat



Hearing protection


Other













STATION PROTOCOL





Disposal Procedures


















methane in air


air








PPE Level D




PPE Level D



PPE Level D




















Protective gloves



Dosimeter Type

Hard hat



Hearing protection


Other Life Vest















Protective gloves



Dosimeter Type

Hard hat

_bull_



Hearing protection


Other Life Vest



Compound

1 4-dichlorobenzene

4-methylphenol


nitrobenzene

phenol


tetrachloroethane

11 -dichloroethene

1 2-dichloroethane

1 2-dichloropropane

benzene

carbon disulfide

chloroform

chloromethane

methylene chloride

vinyl chloride

NA Not Available

HNul 02 eV Lamp1

119

NA

NA

NA

NA

NA

64

NA

02

10

49

NA

NA

014

32

Response Factor

Foxboro OVAshy108

NA

no response

2212

1641

1638

164

273

NA

149

056

3387

206

197

167

203

Foxboro OVAshy128

NA

no response

251

1652

4489

169

297

NA

148

054

5306

238

238

172

211



ATTACHMENT A










Table 1-1)



















































compounds




required


i bull U e

1 i bullltH

bullo I n cn

V


i S I0gt



Irrit

atio

n e

yes

ski

n

Res

pira

tory

Sys

u

J mdash o CO


bullsect


t^ 0

bull y)lt1 gt U

lcer

atio

n of

nas

al s

eptu

m

Der

mat

iti


Oas

trom

test

mal

dis

turb

ance

s P

crip

he



00Ily

perp

igm

enta

tion

of s

kin

Car

cmog

i 1 E pound U

3c





chills

Mus

cle

ach

es

Nau

sea

Vom

itn


c S

1 H w


Wea

knes

s L

assi

tude

In

som

nia

tac

ia

pallo

r a

nore

xia

Wei

ght

loss

Mal

nuti

anem

ia

gmgi

val

lead

lin

e t

rem

or P

a

Sen

sitiz

atio

n D

erm

atiti

s a

llerg

ic a

sth

c ~ =

Ber

ylllo

sis

(chr

onic

exp

osur

e) a

nore

gt W

eigh

t lo

ss

Wea

knes

s c

hest

pai

n u

cl

ubbi

ng o

t fin

gers

C

yano

sis

Pul

moi

in

suffi

cien

cy

irrita

tion

eye

s d

erm

atll

carc

inog

en

Pul

mon

ary

edem

a D

yspn

ea

coug

h c

Dia

rrhe

a a

nosm

ia E

mph

ysem

aP

rote

mur

ia m

ild a

nem

ia C

arci

noge

n

Irrit

atio

n e

yes

ski

n lu

ng T

ibro

sis

rfll

ct^l

trade^

Irrit

atio

n egt

es

nose

ph

aryn

x n

asal

si

Per

fora

tion

met

allic

tas

te D

erm

atiti

s an

imal

s lu

ng

liver

ki

dney

dam

age

lt

wris

t an

kles

en

ceph

alop

athy

kid

ney

dise

ase

Irr

itatio

n e

yes

hyp

oten

sion

Tig

htne

ss

Sub

ster

nal p

ain

Hea

dach

e

Con

stip

atio

n a

bdom

inal

pai

n c

olic

neur

opat

hy

Res

pira

tory

Irr

itatio

n

dete

cted

com

poun

ds

amp S o

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umom

tis

Car

cino

gen lt-n

a o

1 iC3

Cu

o


Sshyn

c

i O o C2ltu

T3

-


SI bullS

1 3 C ^

a T3

s =g- su f

n a G S1

S s a s s a |

bullS 3 ~

CO co

1N laquo _c jC

-raquo

S~

SG ^|

lt

SJOrtH

e o 85^5 c

j gj

i

w c 2 1 r g

9S

ff O G shy

| lt

a

j 5

IS

1

u ca

S

imdash

1o

1

S

I C

ll u

i

s

i l

8 o

jU1

i

as

I

S

u -^2Z

G

i

u = N

i

ag^

js 1

5 lt

K 3 CJ U

LLJ I

^ sect4raquo U


c

i U _c

u c M ic T3

Phys

ical D

esc

riptio

Col

orle

ss liq

uid

or

crys

tal

solid

(be

low

63

degh)

with

ai

arom

atic

odo

r

Col

orle

ss t

o pa

le-y

ello

w

liquid

wit

h a p

leds

diit

dr

omat

ic o

dor

[her

bici

de

colo

rless

liq

uid

Col

orle

ss o

r w

hite

cry

stal

lso

lid w

ith a

moth

bdll-

like

odor

[in

sect

icid

e]

Yel

low

to

red

need

les

or

yello

w l

iquid

with

a s

llghl

odor

Ora

nge-

yello

wcr

ysta

lline

solid

will)

a

char

acte

ristic

odo

r [N

ote

Ofte

n sh

ippe

d m

olte

n ]

Ora

nge-

yello

w c

ryst

alline

so

lid w

ith d

cha

ract

eris

ticod

or

[Not

e

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n sh

ippc

m

olte

n J

t

3 ci

HS

I G

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ra

1 pound ^ E a S ii

i


gt gt J2 11C3 U

o H-5 bullo j ^ ^ u



5-T

nchl

orop

h i -^shy


46

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loro

ph


_

a s= S ~ SO a s ggt

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sect ijj C 30 tft







bull2 1 u


s

U d

la

tA w


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CT

WR

GA

t rO

NU

( V bull3


mdash a

o jj

e


a _g 00 c^ ^ c

10) u c Q bullM


^

1 2-

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hlor

oben

zi

1 3-D

ichlo

robenz

4-D

ichlo

rophen

4-D

imet

hylp

her

2-C

hlor

onap

htha

l

2-C

hlor

ophe

nol

2-M

eth

ylnaphth

al

WR

G

RA

CE

26

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itroto

luemi s

1

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oben

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12

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nchl

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e

22

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bis

(l-c

hl

O



i rpound ampO gt

i t^ U_ a pound

2

1

1

9 e o c 1^ J



-gt vi 13 U U

Oat o



O ol u sl 5 Q^ ^1

I Iu

|


S ^ 5^ q 3 1 ^



Q

tmdash

u


V)

2 c pound

C3


o V) S


3 C


e

1o




c

2



pound E i bull 2


u


a

Ski

n S

ensi

tizat

ion

Der

mat

itis

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dach

e

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zine

ss

caus

tic b

urns

fre

quen

t ur

inat

ion

dy

suria

H

emat

una

Gas

troin

test

inal

ups

et

uppe

r R

espi

rato

ry i

nfec

tion

Car

cino

gen

Sens

e of

wel

l be

ing

Hea

dach

e f

ever

I

assi

tude

pr

ofus

e S

wea

ting

exc

ess

thirs

t Ta

chyc

ardi

a h

ypei

pnea

co

ugh

Sho

rtnes

s B

reat

hing

com

a

Irrit

atio

n e

yes

ski

n m

ucou

s m

embr

ane

Cen

tral

Ner

vous

Sys

tem

effe

cts

Con

fusi

on

Dep

ress

antD

epre

ssio

n R

espi

rato

ry 1

ailu

re

Dys

pnea

Irr

egul

arIr

regu

larit

ies

rapi

dR

espi

rato

ry

Wea

knes

s pu

lse

eye

ski

n bu

rns

Der

mat

itis

lung

liv

er

kidn

ey

panc

reas

Irrit

atio

n no

se

thro

at

Cya

nosi

s a

taxi

a

Tach

ycar

dia

tac

hypn

ea

Dys

pnea

Ir

rita

bili

ty

Vom

iting

D

iarr

hea

C

onvu

lsio

ns

Res

pira

tory

arr

est

anem

ia

Met

hem

oglo

bmem

ia j

aund

ice

2

laquo P

hys

ical D

esc

riptio

n

solid

C

onst

ituen

t in

coa

l tar

pi

tch

vola

tlles

C

oal t

ar is

a

blac

k or

dar

k-br

own

amor

phou

s re

sidu

e

whi

te t

o ye

llow

cry

stal

s w

ithbl

uish

or

viol

et fl

uore

scen

cean

d a

wea

k ar

omat

ic o

dor

Con

stitu

ent

in c

oal t

ar p

itch

vo

latil

es

Coa

l ta

r is

a b

lack

or

dar

k-br

own

amor

phou

s re

sidu

e

colo

rless

leaf

lets

or p

late

s w

ith a

gre

enis

h-ye

llow

fluor

esce

nce

Con

stitu

ent

in

coal

tar

pitc

h v

olat

iles

C

oal

tar

is a

bla

ck o

r da

rk-b

row

n

amor

phou

s re

sidu

e

odor

less

ye

llow

cry

stal

s

Con

stitu

ent

in c

oal t

ar p

itch

vo

latil

es

Coa

l tar

is a

bla

ck

or d

ark-

brow

n am

orph

ous

resi

due

solid

C

onst

ituen

t in

coa

l tar

pi

tch

vola

tiles

C

oal

tar

is a

bl

ack

or d

ark-

brow

nam

orph

ous

resi

due

solid

C

onst

ituen

t in

coa

l tar

pi

tch

vola

tiles

C

oal

tar

is a

bl

ack

or d

ark-

brow

nam

orph

ous

resi

due

solid

C

onst

ituen

t in

coa

l tar

pi

tch

vola

tlles

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oal

tar

is a

bl

ack

or d

ark-

brow

nam

orph

ous

resi

due

O H-1

CD

1

iV

c a o ogt u cs

I H

c -^ 15 ao w c - 3

c mdash

bulllaquo C U

o ^ i 2 amp B

sectbullbullsect -^

cpound 2 ltJ

u T3

c -^ 3 00 gt C

E=

|l|

S u e ^bull^ ^2

oi 35 ^J

S T3

c - gpound

laquo S


O ~^ trade

2 S i-l5 _laquo

S T3

c - 5 gjj

s M gti

lyen |J| a S $t

tgt c

TJ

cf bull

bull5 ^

c 5_

tS gtraquo VI C 0gt


ci S

u cbullo

=bull ~z degdeg


2 u e 5-3 JZ 13 s

otf S =laquo

u c

T3



c c c E c c c

V)

o

U)o c

laquo o

u 00 o c u

u

o c 5

0

amp o c 3

0

00 O

)mdash

0

o

j-3

U

oo

s J-]

o | Q

pound en

ltgt mdash 1 c

wf bullS o c o

i o

bull~ _

o o

claquo

^

C o

(X1

S

c o

vT c o


J

E

S2

ec

^

S =

S3

i C

amp

= a c

^

Wl

I C

amp

wf

fl S

1


c _o 4gt C

D n a D D n D ||

U 3 B

o -^


s o


ltU 3 C

+2

u c o

u c u

c

C O

1 1

u

=Hjj1

s C CO C

lt

u g

n

lt

u

bulls c 1

IV

03

u jgt graquo -5

t a

i o 3

2 N

U 03

u c bullmdashbdquo

00

ca

^

o 3

2

N

U CQ

H

C bull1

1

Phy

sica

l D

esc

riptio

n

colo

rless

to

whi

te n

eedl

es

scal

es

or p

owde

r w

ith a

fai

nt

benz

oin

or

ben

alde

hyde

-like

odor

Col

orle

ss li

quid

with

ach

lorin

ated

so

lve

nt-

like

odor

Col

orle

ss

oily

liq

uid

with

a

slig

ht

odor




HS

I G

eoT

rans

| 5 c c






E pound i otil s


0 o 0c H n

1 2 V) 2 - mdash -o o


0 vT 0^ cf _- Z 13 3 0 S 5

~






1 |

s o VI ~


i3 S


w _f J~

a c


^ ~ lt w ~ i


VJ



1

tfR

GR

AC

EC

TW

RG

AC

TO

NY

laquo eg ^ O

S J iO 3 _O Q 2


is(2

-Chl

oroe

th

uty

l be

nzyl

phi

ffl

|Clt3 o U- a H 1


1jU

rs rs 1 _

Q 15 S1gt a 1 0 a03 C Q gt S

pound 2

1

0

1

i

HS

I G

eoT

rans

inc

Colo

rless

to

wate

r-w

hite

oily

liquid

with

a v

ery

slig

ht

aro

matic

odo

r [p

est

icid

e]

Colo

rless

oily

liq

uid

with a




ar

colo

rless

liq

uid

with

a

mild

tu

rpentin

e-lik

e o

dor

Pa

le-y

ello

w t

o a

mber-

colo

red

liquid

with

a p

ungent

Colo

rless

cry

sta

ls w

ith

a

cam

phor-

like odor

Sol

id

Con

stitu

ent in

coa

l tar

pi

tch

vola

tiles

C

oal t

ar is

a

Gast

roin

test

inal tr

act

slig

ht

aro

matic

odo

r [N

ote

A

solid

belo

w 4

2degF

J

Physic

al D

escription

ea

Saliv

atio

n

Pul

mon

ary

unple

asa

nt

odor

[N

ote

A

a

Vom

iting

Dia

rrhea

in

solid

belo

w I

6degF

] ki

dney

Inju

ry

amp s

kin c

ance

r]

blac

k or

dar

k-br

own

amor

phou

s re

sidu

e

sk

in

nose

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Da

D

(A3)

3 (A3)

D(A4)

a D

aa

nn nnnnnaanannanan



VOC

Isophorone


Nitrobenzene

Phenol


11-DichIoroethene

12-Dichloroethane

12-Dichloropropane

Benzene

Bromoform

Bromomethane

4 ppm

LFC

1 ppm [skin]

5 ppm

1 ppm

LFC (Ippm

1 ppm

LFC (75ppm)

0 1 ppm

0 5 ppm [skin]

LFC(lppm[skm])

3 (A3)

D(A3) D(A4)

a (A3) a(A4)

3 (A4)



Chloroform 2 ppm

D




Notes

a





FOR WR GRACE Page 1 of 1 HSI GeoTrans inc P PROJECRWRGACTONACCESS97HASP mdb - RPT_Lc=u_5_ppm_vapor

























VOC



ATTACHMENT B



DEFINITIONS







health effects



































employers attention


GeoTrans










HSI GeoTrans







AIR MONITORING













DECONTAMINATION











































all employees





consultation
















(2) EKG


(4) urinalysis

(5) blood profile







taken











SITE CONTROL


following
















































Accidents







Chemical Exposure













Cold Stress
























Heat Stress































(5) Acclimation

First Aid




































fatality


WATER SAFETY



































Tetra Tech Inc Safe Work Practices Issue Date July 1998 Non-Permit-Required Confined Space Entry Practices Revision No 1 SWPNo 6-24


















confined space



ATTACHMENT C

















Emergency Overview


I o f 8 10199 1208 PM









2 of 8 10199 1208 PM










3 of 8 10199 1208 PM








4 of 8 10199 1208 PM












5 of 8 10199 1208 PM






Domestic (Land DOT)






6 of 8 10199 1208 PM
















7 of8 101991208 PM






8 of 8 10199 1208 PM




General Information








I o f 4 10199 212 PM











Health Hazard Data


2 of 4 10199 2 12 PM






Control Measures


Transportation Data


3 of 4 10199 212 PM




Disposal Data

Label Data


4 of4 10199 212 PM
















Emergency Overview


I o f 8 10199 12 17PM








2 of 8 10199 1217 PM











3 of 8 10199 1217PM







4 of 8 10199 1217 PM












5 of 8 10199 1217 PM






Domestic (Land DOT)








(7647-01-0) YesYes

Yes Yes

Yes Yes

Yes Yes


Ingredient

- Part 2shy

Korea--C



(7647-01-0) YesYes

Yes Yes

No No

Yes Yes



6 of 8 10199 12 17PM



Federal

Ingredient


CERCLA

shy Part 2 -RCRAshy

26133 -TSCAshy 8 (d )


(7647-01-0 ) 5000 No

No No

No No






7of8 10199 1217 PM




8 of 8 10199 1217PM




General Information






I o f 5 10199 1212 PM










2 of 5 10199 1212 PM










Reactivity Data


Health Hazard Data


3 of 5 10199 1212PM





Control Measures


Transportation Data


4 of 5 10199 1212 PM




Disposal Data

Label Data


5 of 5 10199 1212 PM


mdash



General Information








I o f 3 10199 1213PM

_ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _


Reactivity Data


Health Hazard Data




Control Measures


Transportation Data

= = == ====== = ==ss = == = = =

Disposal Data

2 of 3 10199 1213 PM


Label Data



3of3 10199 12 13PM




General Information









I o f 4 10199 1229PM



Reactivity Data


Health Hazard Data




Control Measures


2 of 4 10199 1229 PM



Transportation Data


Disposal Data = = = = = = = = 5= = = = ==

= = == = ===== = S3SSpound

Label Data



3of4 10199 12 29PM




4 of 4 10199 1229 PM




General Information








I o f 3 10199 207 PM



Reactivity Data


Health Hazard Data





Control Measures


2 of3 10199 207 PM



Transportation Data

Disposal Data = ===== = == = S5== ==

===============

Label Data


3 of 3 10199 207 PM

ATTACHMENT D

FIELD FORMS


TETRA TECH INC




E-mail


Name Office


Marital status




Street address


County






Witness(es)

Name

Address

Telephone








D None

Telephone No








Injured Employee











FormAR-l Page 2 of3

TETRA TECH INC



FormAR-1 Page 3 of3

b O

U1

c

CQ

t3

C ltu s pound o O

I O

C3 0)

_i w S j mdashshy

c u

O O

O Z 2

Q

CC o o

(U

03ltu

O

i i U

pound ab

is

sr a

Q U

degshy s a


s OH t4_ o

u

a 9 deg

o

gt^ -4mdashraquo

bull5

3 T3 C

3

I|

OS c 2

pi ^3 laquow y 1)

ll -4-

O

O -4mdashraquo

2 _bull -

oa ltu CD

3ltu H bulla

TETRA TECH INC







Chemical hazards

Physical hazards


Equipment hazards


Other






Attendees



Name Title

Signature


TETRA TECH INC


Project Name

Field Location

Project Manager

General Items


Project No

Completed by














Emergency Planning







Air Monitoring





In Compliance

Yes No NA

1






1 Splash suit



4 Gloves

5 Overboots

6 Hard hat

7 Dust mask


9 Respirator

Instrumentation


11 Oxygen meter


Supplies








Date


ft a u S |

Bar

omet

ric

Pre

ssur

e(u

nits

)

00 o

u -4mdash

ltu

-4mdashoo C

S 8 H mdash

B1) E T 1 i bullo

bull5 2

bullB L

bullo e

S 3 u

C

w

=

2

tJ

j-

C

^

a

k

iduc

tivi

ty

a X gC

E c bull3 X T3








CompanyOffice Date

Date



Site Information

Project Name Date


Project No


Space Preparation





Result


Oxygen-nun gt195

Oxygen-max lt235


HS lt10 ppm

Cl lt05 ppm

CO lt35 ppm

SO lt2 ppm

Heat degFdegC

Toxic (specify)

Other

Tester Initials


Signature of Tester

Notes




TETRA TECH INC


PROTECTIVE CLOTHING

Before use



- Imperfect seams


- Tears










bull Tears

bull Punctures



GLOVES

Before use


- Imperfect seams

Tears and abrasions





TETRA TECH INC


FOOTWEAR


bull Holes and cuts



bull Cracks in sole


EYEWEAR


bull Cracks

Fogginess

bull Scratches



HEADGEAR


Cracks or gouges



Page 2 of 2

TETRA TECH INC




Site name

Site address

City state and zip











Reviewed by Date




Proiec Name Task No




Site Descnotion











G Stream Y - N z G













ATTACHMENT E




Acton Massachusetts


















barcode 43196








TABLE OF CONTENTS

PAGE










LIST OF ATTACHMENTS







LIST OF TABLES

PAGE









LIST OF FIGURES

PAGE




ACGIH




1 INTRODUCTION


















Section 2-7)







their own employees






















Non-Hazardous Site

Characterization









Site Office

Ambulance

Hospital


Fire Department

Poison Control

Nearest Phone



Client Contact

Project Coordinator






NameLocation Number







Fire Emergency 911








Donald Hanson MADEP

Workcare Inc

(800)424-8426










Figure 1-1)






map Figure 1-1)






apply)



and outer

hard hats


covers



TYVEK)


escape air pack

safety glasses


washable coveralls




first aid kit

fire extinguisher


FireExplosion











Hazardous Spill










(4) a shovel

















the situation






















Radiation






that exceed 1 mRhr



HAZARD

RAILROAD TRACKS

SURFACE WATER

(RIVER BROOK PONDS)

WETLANDSSWAMPS


SPIDERS TICKS


TEMPERATURE








the tracks














vegetation areas





Attachment B




Low Unknown














constructed in 1951














demolished


















































































bull _c 0






Ml^ w^^ C -u

O 0 U Q


gt o o 03 Z S 3 c

5E N

EU

TR

AL

EX

TR

AC

T

C03

- mdash5 3

IS (

2-E

TH

YL

HE

XY

L)

PHTH

Al

O _c 0 IS

(2-

CH

LOR

OET

HY

L) E

THEI

~~~ u



u C tflME ~T X


bull ^ ^^

S ^^ L ^^ C3 z 5 oSO o

T3 C S laquo


WR

GR

AC



cls

WR

GA

clon

Acc

ess9

7N

099B

D m

db

2O b ^ ^bull t3 00 =

cf g1


o

S3

E 3

00

_Q 6-D

INIT

RO

-2-M

ETH

YLP

HEN

-CH

LOR

OPH

ENO

LC

HL

OR

O-3

-ME

TH

YL

PHE

NO

4-D

IME

TH

YL

PHE

NO

L

ME

TH

YL

PHE

NO

LM

ETH

YLP

HEN

OL

bull

fN

ID E

XT

RA

CT

AB

LE

HEN

OL

^j

ENZO

IC A

CIDbullo


ENTA

CH

LOR

OPH

ENO

L4-

DIC

HL

OR

OPH

EN

OL

NIT

RO

PHEN

OL

bull 45-

TRIC

HLO

RO

PHEN

OL

NIT

RO

PHEN

OL

46

-TR

ICH

LOR

OPH

ENO

L

4-D

INIT

RO

PHEN

OL

APH

THA

LEN

E I-

n-B

UTY

LPH

THA

LATE

ITR

OB

ENZE

NE

4-D

lCH

LOR

OB

ENZE

NE

2-D

ICH

LOR

OB

ENZE

NE

I-n-

OC

TY

LPm

HA

LA

TE

CE

NA

PHT

HE

NE

UTY

LBEN

ZYLP

I ITH

ALA

TE

LUO

RA

NIH

ENE

IbTH

YLP

HTH

ALA

TE


shyCO H u

e ^ c -2 M 1 g3

ill 58 4gt w

S sect |

U Q

e poundbull 2 5D





^ s i O U uo


fl

SB

A g H


S BB 8 8 5 0


o w e Z y S

a) H

ej)pm


ltN

S _3 ^

| gt 3 C0

tU

U jB



sectO bulla

c s

l o


LU ^trade

Z gt EM S C tlJ

w ^ Z o z ^ 1 ^


rs

O lt = gtdeg O sect

uT 2 ^

^

O 2 ^

S z sect J

C ^ - - 1 - ^ ^ 1 ^ 2 ^ ^ ^ ^ sect


U

U JG

C

H2

O

C^^3 K

W~l

3 (N U

^

rlt o 5

g

J |

0 J3

1

Q 03

S f

RG

RA

CE

RC

Aclo

nA

ccraquos9

sect1

ai ^ 2O JLL a

_C

w C 5 Hllf

oIs- o o




u a

So 7s gv lt


^ rraquo

c +z u c

Cfl


bull



m

_ bull

M H 12

-DIC

HLO

RO

PR

OP


QJ CQ r- s

3

C5 1 Q Z |

UJ tO C c f

lt 1O QU aj a


cont

inue

BE

NZ

EN

E

11

-DIC

HLO

RO

ET

HE

VIN

YL C

HLO

RID

E

ET

HY

LB

EN

ZE

NE

AC

ET

ON

E

CH

LO

RO

ET

HA

NE

11 -D

ICH

LO

RO

ET

HA

XY

LE

NE

(T

OT

AL)

FO

R W

RG

RA

CE

H H

rojtc

tsW

RG

Act

oMA

cccs

s97t


TJ - s s s o G

12

-DIC

HLO

RO

ET

HA

D S D 2 W LU S

AR

SE

NIC

I S_U

UJ


gt

J

e s- C reg Si fl

raquo raquo

S bullpound 3

3 g ~ S

sect a 2 d V



U C E

c o O gv



0 raquo u c

CA

laquobullB


_^ ^ mdash 1

O U Z bullpound

O

5 j elaquo

^ 4gt 00 C5


S gtbull -5 bull C5


O U R

Z laquo S 1

11 2

-TE

TR

AC

l ILO

RO

ET

l IA

N^ r



0 S -bull3u ^

C3 j

1

a UJ Uj UJ

z0 Z X


11

2-T

RIC

HLO

RO

ET

IIAN

F

TR

ICH

LO

RO

I-LU

OR

OM

ET

HA

N

CH

LOR

OB

EN

ZE

NE

CH

LOR

OFO

RM

BR

OM

OM

ETH

AN

E

n-P

RO

PY

LBE

NZ

EN

E

BR

OM

OF

OR

M

2-C

HLO

RO

ET

HY

LV

INY

L E

TH

E

BR

OM

OD

ICH

LOR

OM

ET

HA

NE

CA

RB

ON

TE

TR

AC

HLO

RID

E

cis-

1 3

-DIC

HLO

RO

PR

OP

EN

E

p-X

YLE

NE

FO

R W

RG

RA

CE

P P

roje

cls

WR

GA

clon

Ucc

ess9

7N

099B

D m

dbshy

Tab

le 1

-1 (c

ontin

ued)

Com

pound


Cbull

H CO


S 2 oE bull bullo V



c _o i



eji

lt C o igt

ciU fi u c


o T3 C

6 V cs

bull ^ c]Z bull0U



^ rjr laquoQ^ jE DC


trt

6 0flj 3 T3

U CZ U 0 O

5 H 1 0gt

^Jlt2J 6JD c S ltuc

W

utJ3 v-




C e 3

Z gtltu E

a- 5TlkJ

Com

poun

d de

tect

ed a s

om

pound

trans-

l3-D

ICH

LO

RO

PR

O

1U

_c -raquo

o o

ltuf raquo U

_3 a

00

ltU D

c 9gt V

CO U 1 oco

1



SVOC

VOC

14-Dichloro benzene

4-Methylphenol


Nitrobenzene

Phenol


11-Dichloroethene

12-Dichloroethane

12-Dichloropropane

Benzene

Carbon disulfide

Chloroform

Chloromethane

Methylene chloride

Vinyl chloride

LFC(lOppm)

2 3 ppm

5 ppm

1 ppm [skin]

5 ppm

1 ppm

LFC( lppm)

1 ppm

LFC (75ppm)

0 1 ppm

1 ppm

2 ppm

LFC (50ppm)

LFC (25ppm)

LFC (1 ppm)

0 (A3)

n

3 (A3)

V) (A4)

S(A4)

n a (A3) 3 (A4)

g (A3) VI ( A l )






O O

a

d O

rgta

0 O

o tt

_o cL o

pound=i O)



SECONDARY LAGOON


SLOWDOWN PIT

EMERGENCY LAGOON

PRIMARY LAGOON


NORTH LAGOON

TANK CAR AREA


AHAKT2



HSI



h-s_SCH-smdwg















STATION PROTOCOL





Disposal Procedures




















methane in air


air


Confined Space


10ppm~H2S 28 ppm CO






Instrument

Action Level

Protocol

PPE

Action Level

Protocol

PPE

Action Level

Protocol

PPE

OVA andor HNu

Background


Level D



Level D



Level D






PPE Level D



PPE Level D





















Protective gloves



Dosimeter Type

Hard hat



Hearing protection


Other















Protective gloves



Dosimeter Type

Hard hat



Hearing protection


Other












STATION PROTOCOL






Disposal Procedures















methane in air


air






Instrument

Action Level

Protocol

PPE

Action Level

Protocol

PPE

Action Level

Protocol

PPE

OVA andor HNu

Background


Level D



Level D



Level D























_ Protective gloves



Dosimeter Type

Hard hat



Hearing protection


Other















Protective gloves



Dosimeter Type

Hard hat



Hearing protection


Other













STATION PROTOCOL





Disposal Procedures


















methane in air


air








PPE Level D




PPE Level D



PPE Level D




















Protective gloves



Dosimeter Type

Hard hat



Hearing protection


Other Life Vest















Protective gloves



Dosimeter Type

Hard hat

_bull_



Hearing protection


Other Life Vest



Compound

1 4-dichlorobenzene

4-methylphenol


nitrobenzene

phenol


tetrachloroethane

11 -dichloroethene

1 2-dichloroethane

1 2-dichloropropane

benzene

carbon disulfide

chloroform

chloromethane

methylene chloride

vinyl chloride

NA Not Available

HNul 02 eV Lamp1

119

NA

NA

NA

NA

NA

64

NA

02

10

49

NA

NA

014

32

Response Factor

Foxboro OVAshy108

NA

no response

2212

1641

1638

164

273

NA

149

056

3387

206

197

167

203

Foxboro OVAshy128

NA

no response

251

1652

4489

169

297

NA

148

054

5306

238

238

172

211



ATTACHMENT A










Table 1-1)



















































compounds




required


i bull U e

1 i bullltH

bullo I n cn

V


i S I0gt



Irrit

atio

n e

yes

ski

n

Res

pira

tory

Sys

u

J mdash o CO


bullsect


t^ 0

bull y)lt1 gt U

lcer

atio

n of

nas

al s

eptu

m

Der

mat

iti


Oas

trom

test

mal

dis

turb

ance

s P

crip

he



00Ily

perp

igm

enta

tion

of s

kin

Car

cmog

i 1 E pound U

3c





chills

Mus

cle

ach

es

Nau

sea

Vom

itn


c S

1 H w


Wea

knes

s L

assi

tude

In

som

nia

tac

ia

pallo

r a

nore

xia

Wei

ght

loss

Mal

nuti

anem

ia

gmgi

val

lead

lin

e t

rem

or P

a

Sen

sitiz

atio

n D

erm

atiti

s a

llerg

ic a

sth

c ~ =

Ber

ylllo

sis

(chr

onic

exp

osur

e) a

nore

gt W

eigh

t lo

ss

Wea

knes

s c

hest

pai

n u

cl

ubbi

ng o

t fin

gers

C

yano

sis

Pul

moi

in

suffi

cien

cy

irrita

tion

eye

s d

erm

atll

carc

inog

en

Pul

mon

ary

edem

a D

yspn

ea

coug

h c

Dia

rrhe

a a

nosm

ia E

mph

ysem

aP

rote

mur

ia m

ild a

nem

ia C

arci

noge

n

Irrit

atio

n e

yes

ski

n lu

ng T

ibro

sis

rfll

ct^l

trade^

Irrit

atio

n egt

es

nose

ph

aryn

x n

asal

si

Per

fora

tion

met

allic

tas

te D

erm

atiti

s an

imal

s lu

ng

liver

ki

dney

dam

age

lt

wris

t an

kles

en

ceph

alop

athy

kid

ney

dise

ase

Irr

itatio

n e

yes

hyp

oten

sion

Tig

htne

ss

Sub

ster

nal p

ain

Hea

dach

e

Con

stip

atio

n a

bdom

inal

pai

n c

olic

neur

opat

hy

Res

pira

tory

Irr

itatio

n

dete

cted

com

poun

ds

amp S o

Pne

umom

tis

Car

cino

gen lt-n

a o

1 iC3

Cu

o


Sshyn

c

i O o C2ltu

T3

-


SI bullS

1 3 C ^

a T3

s =g- su f

n a G S1

S s a s s a |

bullS 3 ~

CO co

1N laquo _c jC

-raquo

S~

SG ^|

lt

SJOrtH

e o 85^5 c

j gj

i

w c 2 1 r g

9S

ff O G shy

| lt

a

j 5

IS

1

u ca

S

imdash

1o

1

S

I C

ll u

i

s

i l

8 o

jU1

i

as

I

S

u -^2Z

G

i

u = N

i

ag^

js 1

5 lt

K 3 CJ U

LLJ I

^ sect4raquo U


c

i U _c

u c M ic T3

Phys

ical D

esc

riptio

Col

orle

ss liq

uid

or

crys

tal

solid

(be

low

63

degh)

with

ai

arom

atic

odo

r

Col

orle

ss t

o pa

le-y

ello

w

liquid

wit

h a p

leds

diit

dr

omat

ic o

dor

[her

bici

de

colo

rless

liq

uid

Col

orle

ss o

r w

hite

cry

stal

lso

lid w

ith a

moth

bdll-

like

odor

[in

sect

icid

e]

Yel

low

to

red

need

les

or

yello

w l

iquid

with

a s

llghl

odor

Ora

nge-

yello

wcr

ysta

lline

solid

will)

a

char

acte

ristic

odo

r [N

ote

Ofte

n sh

ippe

d m

olte

n ]

Ora

nge-

yello

w c

ryst

alline

so

lid w

ith d

cha

ract

eris

ticod

or

[Not

e

Ofte

n sh

ippc

m

olte

n J

t

3 ci

HS

I G

eoT

ra

1 pound ^ E a S ii

i


gt gt J2 11C3 U

o H-5 bullo j ^ ^ u



5-T

nchl

orop

h i -^shy


46

-Tnch

loro

ph


_

a s= S ~ SO a s ggt

2 S = n bullpound c


sect ijj C 30 tft







bull2 1 u


s

U d

la

tA w


)JE

CT

WR

GA

t rO

NU

( V bull3


mdash a

o jj

e


a _g 00 c^ ^ c

10) u c Q bullM


^

1 2-

Dic

hlor

oben

zi

1 3-D

ichlo

robenz

4-D

ichlo

rophen

4-D

imet

hylp

her

2-C

hlor

onap

htha

l

2-C

hlor

ophe

nol

2-M

eth

ylnaphth

al

WR

G

RA

CE

26

-Din

itroto

luemi s

1

1 4-

Dic

hlor

oben

z

12

4-T

nchl

orob

e

22

-Oxy

bis

(l-c

hl

O



i rpound ampO gt

i t^ U_ a pound

2

1

1

9 e o c 1^ J



-gt vi 13 U U

Oat o



O ol u sl 5 Q^ ^1

I Iu

|


S ^ 5^ q 3 1 ^



Q

tmdash

u


V)

2 c pound

C3


o V) S


3 C


e

1o




c

2



pound E i bull 2


u


a

Ski

n S

ensi

tizat

ion

Der

mat

itis

Hea

dach

e

Diz

zine

ss

caus

tic b

urns

fre

quen

t ur

inat

ion

dy

suria

H

emat

una

Gas

troin

test

inal

ups

et

uppe

r R

espi

rato

ry i

nfec

tion

Car

cino

gen

Sens

e of

wel

l be

ing

Hea

dach

e f

ever

I

assi

tude

pr

ofus

e S

wea

ting

exc

ess

thirs

t Ta

chyc

ardi

a h

ypei

pnea

co

ugh

Sho

rtnes

s B

reat

hing

com

a

Irrit

atio

n e

yes

ski

n m

ucou

s m

embr

ane

Cen

tral

Ner

vous

Sys

tem

effe

cts

Con

fusi

on

Dep

ress

antD

epre

ssio

n R

espi

rato

ry 1

ailu

re

Dys

pnea

Irr

egul

arIr

regu

larit

ies

rapi

dR

espi

rato

ry

Wea

knes

s pu

lse

eye

ski

n bu

rns

Der

mat

itis

lung

liv

er

kidn

ey

panc

reas

Irrit

atio

n no

se

thro

at

Cya

nosi

s a

taxi

a

Tach

ycar

dia

tac

hypn

ea

Dys

pnea

Ir

rita

bili

ty

Vom

iting

D

iarr

hea

C

onvu

lsio

ns

Res

pira

tory

arr

est

anem

ia

Met

hem

oglo

bmem

ia j

aund

ice

2

laquo P

hys

ical D

esc

riptio

n

solid

C

onst

ituen

t in

coa

l tar

pi

tch

vola

tlles

C

oal t

ar is

a

blac

k or

dar

k-br

own

amor

phou

s re

sidu

e

whi

te t

o ye

llow

cry

stal

s w

ithbl

uish

or

viol

et fl

uore

scen

cean

d a

wea

k ar

omat

ic o

dor

Con

stitu

ent

in c

oal t

ar p

itch

vo

latil

es

Coa

l ta

r is

a b

lack

or

dar

k-br

own

amor

phou

s re

sidu

e

colo

rless

leaf

lets

or p

late

s w

ith a

gre

enis

h-ye

llow

fluor

esce

nce

Con

stitu

ent

in

coal

tar

pitc

h v

olat

iles

C

oal

tar

is a

bla

ck o

r da

rk-b

row

n

amor

phou

s re

sidu

e

odor

less

ye

llow

cry

stal

s

Con

stitu

ent

in c

oal t

ar p

itch

vo

latil

es

Coa

l tar

is a

bla

ck

or d

ark-

brow

n am

orph

ous

resi

due

solid

C

onst

ituen

t in

coa

l tar

pi

tch

vola

tiles

C

oal

tar

is a

bl

ack

or d

ark-

brow

nam

orph

ous

resi

due

solid

C

onst

ituen

t in

coa

l tar

pi

tch

vola

tiles

C

oal

tar

is a

bl

ack

or d

ark-

brow

nam

orph

ous

resi

due

solid

C

onst

ituen

t in

coa

l tar

pi

tch

vola

tlles

C

oal

tar

is a

bl

ack

or d

ark-

brow

nam

orph

ous

resi

due

O H-1

CD

1

iV

c a o ogt u cs

I H

c -^ 15 ao w c - 3

c mdash

bulllaquo C U

o ^ i 2 amp B

sectbullbullsect -^

cpound 2 ltJ

u T3

c -^ 3 00 gt C

E=

|l|

S u e ^bull^ ^2

oi 35 ^J

S T3

c - gpound

laquo S


O ~^ trade

2 S i-l5 _laquo

S T3

c - 5 gjj

s M gti

lyen |J| a S $t

tgt c

TJ

cf bull

bull5 ^

c 5_

tS gtraquo VI C 0gt


ci S

u cbullo

=bull ~z degdeg


2 u e 5-3 JZ 13 s

otf S =laquo

u c

T3



c c c E c c c

V)

o

U)o c

laquo o

u 00 o c u

u

o c 5

0

amp o c 3

0

00 O

)mdash

0

o

j-3

U

oo

s J-]

o | Q

pound en

ltgt mdash 1 c

wf bullS o c o

i o

bull~ _

o o

claquo

^

C o

(X1

S

c o

vT c o


J

E

S2

ec

^

S =

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ho

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on

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in

dic

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s e

xpo

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feas

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n E oen JS

(U

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CN

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ab

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1 E a a

lt I ID

I

C








Da

D

(A3)

3 (A3)

D(A4)

a D

aa

nn nnnnnaanannanan



VOC

Isophorone


Nitrobenzene

Phenol


11-DichIoroethene

12-Dichloroethane

12-Dichloropropane

Benzene

Bromoform

Bromomethane

4 ppm

LFC

1 ppm [skin]

5 ppm

1 ppm

LFC (Ippm

1 ppm

LFC (75ppm)

0 1 ppm

0 5 ppm [skin]

LFC(lppm[skm])

3 (A3)

D(A3) D(A4)

a (A3) a(A4)

3 (A4)



Chloroform 2 ppm

D




Notes

a






























VOC



ATTACHMENT B



DEFINITIONS







health effects



































employers attention


GeoTrans










HSI GeoTrans







AIR MONITORING













DECONTAMINATION











































all employees





consultation
















(2) EKG


(4) urinalysis

(5) blood profile







taken











SITE CONTROL


following
















































Accidents







Chemical Exposure













Cold Stress
























Heat Stress































(5) Acclimation

First Aid




































fatality


WATER SAFETY





















































confined space



ATTACHMENT C

















Emergency Overview


I o f 8 10199 1208 PM









2 of 8 10199 1208 PM










3 of 8 10199 1208 PM








4 of 8 10199 1208 PM












5 of 8 10199 1208 PM






Domestic (Land DOT)






6 of 8 10199 1208 PM
















7 of8 101991208 PM






8 of 8 10199 1208 PM




General Information








I o f 4 10199 212 PM











Health Hazard Data


2 of 4 10199 2 12 PM






Control Measures


Transportation Data


3 of 4 10199 212 PM




Disposal Data

Label Data


4 of4 10199 212 PM
















Emergency Overview


I o f 8 10199 12 17PM








2 of 8 10199 1217 PM











3 of 8 10199 1217PM







4 of 8 10199 1217 PM












5 of 8 10199 1217 PM






Domestic (Land DOT)








(7647-01-0) YesYes

Yes Yes

Yes Yes

Yes Yes


Ingredient

- Part 2shy

Korea--C



(7647-01-0) YesYes

Yes Yes

No No

Yes Yes



6 of 8 10199 12 17PM



Federal

Ingredient


CERCLA

shy Part 2 -RCRAshy

26133 -TSCAshy 8 (d )


(7647-01-0 ) 5000 No

No No

No No






7of8 10199 1217 PM




8 of 8 10199 1217PM




General Information






I o f 5 10199 1212 PM










2 of 5 10199 1212 PM










Reactivity Data


Health Hazard Data


3 of 5 10199 1212PM





Control Measures


Transportation Data


4 of 5 10199 1212 PM




Disposal Data

Label Data


5 of 5 10199 1212 PM


mdash



General Information








I o f 3 10199 1213PM

_ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _


Reactivity Data


Health Hazard Data




Control Measures


Transportation Data

= = == ====== = ==ss = == = = =

Disposal Data

2 of 3 10199 1213 PM


Label Data



3of3 10199 12 13PM




General Information









I o f 4 10199 1229PM



Reactivity Data


Health Hazard Data




Control Measures


2 of 4 10199 1229 PM



Transportation Data


Disposal Data = = = = = = = = 5= = = = ==

= = == = ===== = S3SSpound

Label Data



3of4 10199 12 29PM




4 of 4 10199 1229 PM




General Information








I o f 3 10199 207 PM



Reactivity Data


Health Hazard Data





Control Measures


2 of3 10199 207 PM



Transportation Data

Disposal Data = ===== = == = S5== ==

===============

Label Data


3 of 3 10199 207 PM

ATTACHMENT D

FIELD FORMS


TETRA TECH INC




E-mail


Name Office


Marital status




Street address


County






Witness(es)

Name

Address

Telephone








D None

Telephone No








Injured Employee











FormAR-l Page 2 of3

TETRA TECH INC



FormAR-1 of3

b O

U1

c

CQ

t3

C ltu s pound o O

I O

C3 0)

_i w S j mdashshy

c u

O O

O Z 2

Q

CC o o

(U

03ltu

O

i i U

pound ab

is

sr a

Q U

degshy s a


s OH t4_ o

u

a 9 deg

o

gt^ -4mdashraquo

bull5

3 T3 C

3

I|

OS c 2

pi ^3 laquow y 1)

ll -4-

O

O -4mdashraquo

2 _bull -

oa ltu CD

3ltu H bulla

TETRA TECH INC







Chemical hazards

Physical hazards


Equipment hazards


Other






Attendees



Name Title

Signature


TETRA TECH INC


Project Name

Field Location

Project Manager

General Items


Project No

Completed by














Emergency Planning







Air Monitoring





In Compliance

Yes No NA

1






1 Splash suit



4 Gloves

5 Overboots

6 Hard hat

7 Dust mask


9 Respirator

Instrumentation


11 Oxygen meter


Supplies








Date


ft a u S |

Bar

omet

ric

Pre

ssur

e(u

nits

)

00 o

u -4mdash

ltu

-4mdashoo C

S 8 H mdash

B1) E T 1 i bullo

bull5 2

bullB L

bullo e

S 3 u

C

w

=

2

tJ

j-

C

^

a

k

iduc

tivi

ty

a X gC

E c bull3 X T3








CompanyOffice Date

Date



Site Information

Project Name Date


Project No


Space Preparation





Result


Oxygen-nun gt195

Oxygen-max lt235


HS lt10 ppm

Cl lt05 ppm

CO lt35 ppm

SO lt2 ppm

Heat degFdegC

Toxic (specify)

Other

Tester Initials


Signature of Tester

Notes




TETRA TECH INC


PROTECTIVE CLOTHING

Before use



- Imperfect seams


- Tears










bull Tears

bull Punctures



GLOVES

Before use


- Imperfect seams

Tears and abrasions





TETRA TECH INC


FOOTWEAR


bull Holes and cuts



bull Cracks in sole


EYEWEAR


bull Cracks

Fogginess

bull Scratches



HEADGEAR


Cracks or gouges



Page 2 of 2

TETRA TECH INC




Site name

Site address

City state and zip











Reviewed by Date




Proiec Name Task No




Site Descnotion











G Stream Y - N z G













ATTACHMENT E




Acton Massachusetts


















barcode 43196


TABLE OF CONTENTS

PAGE










LIST OF ATTACHMENTS







LIST OF TABLES

PAGE









LIST OF FIGURES

PAGE




ACGIH




1 INTRODUCTION


















Section 2-7)







their own employees






















Non-Hazardous Site

Characterization









Site Office

Ambulance

Hospital


Fire Department

Poison Control

Nearest Phone



Client Contact

Project Coordinator






NameLocation Number







Fire Emergency 911








Donald Hanson MADEP

Workcare Inc

(800)424-8426










Figure 1-1)






map Figure 1-1)






apply)



and outer

hard hats


covers



TYVEK)


escape air pack

safety glasses


washable coveralls




first aid kit

fire extinguisher


FireExplosion











Hazardous Spill










(4) a shovel

















the situation






















Radiation






that exceed 1 mRhr



HAZARD

RAILROAD TRACKS

SURFACE WATER

(RIVER BROOK PONDS)

WETLANDSSWAMPS


SPIDERS TICKS


TEMPERATURE








the tracks














vegetation areas





Attachment B




Low Unknown














constructed in 1951














demolished


















































































bull _c 0






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AL

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AC

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IS (

2-E

TH

YL

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XY

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(2-

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L) E

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cf g1


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HL

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TH

YL

PHE

NO

4-D

IME

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YL

PHE

NO

L

ME

TH

YL

PHE

NO

LM

ETH

YLP

HEN

OL

bull

fN

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RA

CT

AB

LE

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OL

^j

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IC A

CIDbullo


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CH

LOR

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ENO

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DIC

HL

OR

OPH

EN

OL

NIT

RO

PHEN

OL

bull 45-

TRIC

HLO

RO

PHEN

OL

NIT

RO

PHEN

OL

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ICH

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4-D

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APH

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TE


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inue

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AC

ET

ON

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NE

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ICH

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LE

NE

(T

OT

AL)

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11 2

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TR

AC

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11

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F

TR

ICH

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RO

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OR

OM

ET

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N

CH

LOR

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EN

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NE

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BR

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AN

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TH

E

BR

OM

OD

ICH

LOR

OM

ET

HA

NE

CA

RB

ON

TE

TR

AC

HLO

RID

E

cis-

1 3

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HLO

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PR

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EN

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p-X

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cls

WR

GA

clon

Ucc

ess9

7N

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D m

dbshy

Tab

le 1

-1 (c

ontin

ued)

Com

pound


Cbull

H CO


S 2 oE bull bullo V



c _o i



eji

lt C o igt

ciU fi u c


o T3 C

6 V cs

bull ^ c]Z bull0U



^ rjr laquoQ^ jE DC


trt

6 0flj 3 T3

U CZ U 0 O

5 H 1 0gt

^Jlt2J 6JD c S ltuc

W

utJ3 v-




C e 3

Z gtltu E

a- 5TlkJ

Com

poun

d de

tect

ed a s

om

pound

trans-

l3-D

ICH

LO

RO

PR

O

1U

_c -raquo

o o

ltuf raquo U

_3 a

00

ltU D

c 9gt V

CO U 1 oco

1



SVOC

VOC

14-Dichloro benzene

4-Methylphenol


Nitrobenzene

Phenol


11-Dichloroethene

12-Dichloroethane

12-Dichloropropane

Benzene

Carbon disulfide

Chloroform

Chloromethane

Methylene chloride

Vinyl chloride

LFC(lOppm)

2 3 ppm

5 ppm

1 ppm [skin]

5 ppm

1 ppm

LFC( lppm)

1 ppm

LFC (75ppm)

0 1 ppm

1 ppm

2 ppm

LFC (50ppm)

LFC (25ppm)

LFC (1 ppm)

0 (A3)

n

3 (A3)

V) (A4)

S(A4)

n a (A3) 3 (A4)

g (A3) VI ( A l )






O O

a

d O

rgta

0 O

o tt

_o cL o

pound=i O)



SECONDARY LAGOON


SLOWDOWN PIT

EMERGENCY LAGOON

PRIMARY LAGOON


NORTH LAGOON

TANK CAR AREA


AHAKT2



HSI



h-s_SCH-smdwg















STATION PROTOCOL





Disposal Procedures




















methane in air


air


Confined Space


10ppm~H2S 28 ppm CO






Instrument

Action Level

Protocol

PPE

Action Level

Protocol

PPE

Action Level

Protocol

PPE

OVA andor HNu

Background


Level D



Level D



Level D






PPE Level D



PPE Level D





















Protective gloves



Dosimeter Type

Hard hat



Hearing protection


Other















Protective gloves



Dosimeter Type

Hard hat



Hearing protection


Other












STATION PROTOCOL






Disposal Procedures















methane in air


air






Instrument

Action Level

Protocol

PPE

Action Level

Protocol

PPE

Action Level

Protocol

PPE

OVA andor HNu

Background


Level D



Level D



Level D























_ Protective gloves



Dosimeter Type

Hard hat



Hearing protection


Other















Protective gloves



Dosimeter Type

Hard hat



Hearing protection


Other













STATION PROTOCOL





Disposal Procedures


















methane in air


air








PPE Level D




PPE Level D



PPE Level D




















Protective gloves



Dosimeter Type

Hard hat



Hearing protection


Other Life Vest















Protective gloves



Dosimeter Type

Hard hat

_bull_



Hearing protection


Other Life Vest



Compound

1 4-dichlorobenzene

4-methylphenol


nitrobenzene

phenol


tetrachloroethane

11 -dichloroethene

1 2-dichloroethane

1 2-dichloropropane

benzene

carbon disulfide

chloroform

chloromethane

methylene chloride

vinyl chloride

NA Not Available

HNul 02 eV Lamp1

119

NA

NA

NA

NA

NA

64

NA

02

10

49

NA

NA

014

32

Response Factor

Foxboro OVAshy108

NA

no response

2212

1641

1638

164

273

NA

149

056

3387

206

197

167

203

Foxboro OVAshy128

NA

no response

251

1652

4489

169

297

NA

148

054

5306

238

238

172

211



ATTACHMENT A










Table 1-1)



















































compounds




required


i bull U e

1 i bullltH

bullo I n cn

V


i S I0gt



Irrit

atio

n e

yes

ski

n

Res

pira

tory

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u

J mdash o CO


bullsect


t^ 0

bull y)lt1 gt U

lcer

atio

n of

nas

al s

eptu

m

Der

mat

iti


Oas

trom

test

mal

dis

turb

ance

s P

crip

he



00Ily

perp

igm

enta

tion

of s

kin

Car

cmog

i 1 E pound U

3c





chills

Mus

cle

ach

es

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sea

Vom

itn


c S

1 H w


Wea

knes

s L

assi

tude

In

som

nia

tac

ia

pallo

r a

nore

xia

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ght

loss

Mal

nuti

anem

ia

gmgi

val

lead

lin

e t

rem

or P

a

Sen

sitiz

atio

n D

erm

atiti

s a

llerg

ic a

sth

c ~ =

Ber

ylllo

sis

(chr

onic

exp

osur

e) a

nore

gt W

eigh

t lo

ss

Wea

knes

s c

hest

pai

n u

cl

ubbi

ng o

t fin

gers

C

yano

sis

Pul

moi

in

suffi

cien

cy

irrita

tion

eye

s d

erm

atll

carc

inog

en

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mon

ary

edem

a D

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ea

coug

h c

Dia

rrhe

a a

nosm

ia E

mph

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aP

rote

mur

ia m

ild a

nem

ia C

arci

noge

n

Irrit

atio

n e

yes

ski

n lu

ng T

ibro

sis

rfll

ct^l

trade^

Irrit

atio

n egt

es

nose

ph

aryn

x n

asal

si

Per

fora

tion

met

allic

tas

te D

erm

atiti

s an

imal

s lu

ng

liver

ki

dney

dam

age

lt

wris

t an

kles

en

ceph

alop

athy

kid

ney

dise

ase

Irr

itatio

n e

yes

hyp

oten

sion

Tig

htne

ss

Sub

ster

nal p

ain

Hea

dach

e

Con

stip

atio

n a

bdom

inal

pai

n c

olic

neur

opat

hy

Res

pira

tory

Irr

itatio

n

dete

cted

com

poun

ds

amp S o

Pne

umom

tis

Car

cino

gen lt-n

a o

1 iC3

Cu

o


Sshyn

c

i O o C2ltu

T3

-


SI bullS

1 3 C ^

a T3

s =g- su f

n a G S1

S s a s s a |

bullS 3 ~

CO co

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-raquo

S~

SG ^|

lt

SJOrtH

e o 85^5 c

j gj

i

w c 2 1 r g

9S

ff O G shy

| lt

a

j 5

IS

1

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imdash

1o

1

S

I C

ll u

i

s

i l

8 o

jU1

i

as

I

S

u -^2Z

G

i

u = N

i

ag^

js 1

5 lt

K 3 CJ U

LLJ I

^ sect4raquo U


c

i U _c

u c M ic T3

Phys

ical D

esc

riptio

Col

orle

ss liq

uid

or

crys

tal

solid

(be

low

63

degh)

with

ai

arom

atic

odo

r

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orle

ss t

o pa

le-y

ello

w

liquid

wit

h a p

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ic o

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de

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liq

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ss o

r w

hite

cry

stal

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lid w

ith a

moth

bdll-

like

odor

[in

sect

icid

e]

Yel

low

to

red

need

les

or

yello

w l

iquid

with

a s

llghl

odor

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nge-

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wcr

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lline

solid

will)

a

char

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ristic

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r [N

ote

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ippe

d m

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n ]

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e

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n J

t

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ra

1 pound ^ E a S ii

i


gt gt J2 11C3 U

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5-T

nchl

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ph


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a s= S ~ SO a s ggt

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sect ijj C 30 tft







bull2 1 u


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la

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^

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imet

hylp

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htha

l

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ophe

nol

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eth

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al

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RA

CE

26

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itroto

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12

4-T

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bis

(l-c

hl

O



i rpound ampO gt

i t^ U_ a pound

2

1

1

9 e o c 1^ J



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Q

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u


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2 c pound

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3 C


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c

2



pound E i bull 2


u


a

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n S

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tizat

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mat

itis

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dach

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ss

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tic b

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fre

quen

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ion

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una

Gas

troin

test

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ups

et

uppe

r R

espi

rato

ry i

nfec

tion

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gen

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e of

wel

l be

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dach

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ever

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pr

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e S

wea

ting

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ess

thirs

t Ta

chyc

ardi

a h

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pnea

co

ugh

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rtnes

s B

reat

hing

com

a

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atio

n e

yes

ski

n m

ucou

s m

embr

ane

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tral

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vous

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tem

effe

cts

Con

fusi

on

Dep

ress

antD

epre

ssio

n R

espi

rato

ry 1

ailu

re

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pnea

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egul

arIr

regu

larit

ies

rapi

dR

espi

rato

ry

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knes

s pu

lse

eye

ski

n bu

rns

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mat

itis

lung

liv

er

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ey

panc

reas

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n no

se

thro

at

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nosi

s a

taxi

a

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ycar

dia

tac

hypn

ea

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pnea

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rita

bili

ty

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iting

D

iarr

hea

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onvu

lsio

ns

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pira

tory

arr

est

anem

ia

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hem

oglo

bmem

ia j

aund

ice

2

laquo P

hys

ical D

esc

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solid

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coa

l tar

pi

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exc

eede

d d

Icrs

a s

ubst

ance

lo

Ag

en

ts A

CG

IH

uu C ~c

min

ute

TW

A e

xpos

ure

caus

e de

ath o

r im

medi

IDLII

Imm

edia

tely

D

Carc

inogenic

ity =

Ann

LE

L

low

er

exp

losi

ve 1

UE

L u

pper

exp

losi

ve1

mgm

3

mill

igra

ms

per

carc

inogen A

3 =

Conf

Ceiling

MA

X

Ceiling

Co

mp

ou

nd

s w

ith

IP

gr

Ch

em

ica

l S

ubst

ance

s a0gt

and

oth

er

appro

priate

PID

P

ho

to-i

on

iza

tion

NA

in

dic

ate

s e

xpo

sure

feas

ible

co

nce

ntr

atio

n E oen JS

(U

pound2

O O

CN

G

ab

0cs u 3

gC

1 E a a

lt I ID

I

C








Da

D

(A3)

3 (A3)

D(A4)

a D

aa

nn nnnnnaanannanan



VOC

Isophorone


Nitrobenzene

Phenol


11-DichIoroethene

12-Dichloroethane

12-Dichloropropane

Benzene

Bromoform

Bromomethane

4 ppm

LFC

1 ppm [skin]

5 ppm

1 ppm

LFC (Ippm

1 ppm

LFC (75ppm)

0 1 ppm

0 5 ppm [skin]

LFC(lppm[skm])

3 (A3)

D(A3) D(A4)

a (A3) a(A4)

3 (A4)



Chloroform 2 ppm

D




Notes

a






























VOC



ATTACHMENT B



DEFINITIONS







health effects



































employers attention


GeoTrans










HSI GeoTrans







AIR MONITORING













DECONTAMINATION











































all employees





consultation
















(2) EKG


(4) urinalysis

(5) blood profile







taken











SITE CONTROL


following
















































Accidents







Chemical Exposure













Cold Stress
























Heat Stress































(5) Acclimation

First Aid




































fatality


WATER SAFETY





















































confined space



ATTACHMENT C

















Emergency Overview


I o f 8 10199 1208 PM









2 of 8 10199 1208 PM










3 of 8 10199 1208 PM








4 of 8 10199 1208 PM












5 of 8 10199 1208 PM






Domestic (Land DOT)






6 of 8 10199 1208 PM
















7 of8 101991208 PM






8 of 8 10199 1208 PM




General Information








I o f 4 10199 212 PM











Health Hazard Data


2 of 4 10199 2 12 PM






Control Measures


Transportation Data


3 of 4 10199 212 PM




Disposal Data

Label Data


4 of4 10199 212 PM
















Emergency Overview


I o f 8 10199 12 17PM








2 of 8 10199 1217 PM











3 of 8 10199 1217PM







4 of 8 10199 1217 PM












5 of 8 10199 1217 PM






Domestic (Land DOT)








(7647-01-0) YesYes

Yes Yes

Yes Yes

Yes Yes


Ingredient

- Part 2shy

Korea--C



(7647-01-0) YesYes

Yes Yes

No No

Yes Yes



6 of 8 10199 12 17PM



Federal

Ingredient


CERCLA

shy Part 2 -RCRAshy

26133 -TSCAshy 8 (d )


(7647-01-0 ) 5000 No

No No

No No






7of8 10199 1217 PM




8 of 8 10199 1217PM




General Information






I o f 5 10199 1212 PM










2 of 5 10199 1212 PM










Reactivity Data


Health Hazard Data


3 of 5 10199 1212PM





Control Measures


Transportation Data


4 of 5 10199 1212 PM




Disposal Data

Label Data


5 of 5 10199 1212 PM


mdash



General Information








I o f 3 10199 1213PM

_ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _


Reactivity Data


Health Hazard Data




Control Measures


Transportation Data

= = == ====== = ==ss = == = = =

Disposal Data

2 of 3 10199 1213 PM


Label Data



3of3 10199 12 13PM




General Information









I o f 4 10199 1229PM



Reactivity Data


Health Hazard Data




Control Measures


2 of 4 10199 1229 PM



Transportation Data


Disposal Data = = = = = = = = 5= = = = ==

= = == = ===== = S3SSpound

Label Data



3of4 10199 12 29PM




4 of 4 10199 1229 PM




General Information








I o f 3 10199 207 PM



Reactivity Data


Health Hazard Data





Control Measures


2 of3 10199 207 PM



Transportation Data

Disposal Data = ===== = == = S5== ==

===============

Label Data


3 of 3 10199 207 PM

ATTACHMENT D

FIELD FORMS


TETRA TECH INC




E-mail


Name Office


Marital status




Street address


County






Witness(es)

Name

Address

Telephone








D None

Telephone No








Injured Employee











FormAR-l Page 2 of3

TETRA TECH INC



FormAR-1 Page 3 of3

b O

U1

c

CQ

t3

C ltu s pound o O

I O

C3 0)

_i w S j mdashshy

c u

O O

O Z 2

Q

CC o o

(U

03ltu

O

i i U

pound ab

is

sr a

Q U

degshy s a


s OH t4_ o

u

a 9 deg

o

gt^ -4mdashraquo

bull5

3 T3 C

3

I|

OS c 2

pi ^3 laquow y 1)

ll -4-

O

O -4mdashraquo

2 _bull -

oa ltu CD

3ltu H bulla

TETRA TECH INC







Chemical hazards

Physical hazards


Equipment hazards


Other






Attendees



Name Title

Signature


TETRA TECH INC


Project Name

Field Location

Project Manager

General Items


Project No

Completed by














Emergency Planning







Air Monitoring





In Compliance

Yes No NA

1






1 Splash suit



4 Gloves

5 Overboots

6 Hard hat

7 Dust mask


9 Respirator

Instrumentation


11 Oxygen meter


Supplies








Date


ft a u S |

Bar

omet

ric

Pre

ssur

e(u

nits

)

00 o

u -4mdash

ltu

-4mdashoo C

S 8 H mdash

B1) E T 1 i bullo

bull5 2

bullB L

bullo e

S 3 u

C

w

=

2

tJ

j-

C

^

a

k

iduc

tivi

ty

a X gC

E c bull3 X T3








CompanyOffice Date

Date



Site Information

Project Name Date


Project No


Space Preparation





Result


Oxygen-nun gt195

Oxygen-max lt235


HS lt10 ppm

Cl lt05 ppm

CO lt35 ppm

SO lt2 ppm

Heat degFdegC

Toxic (specify)

Other

Tester Initials


Signature of Tester

Notes




TETRA TECH INC


PROTECTIVE CLOTHING

Before use



- Imperfect seams


- Tears










bull Tears

bull Punctures



GLOVES

Before use


- Imperfect seams

Tears and abrasions





TETRA TECH INC


FOOTWEAR


bull Holes and cuts



bull Cracks in sole


EYEWEAR


bull Cracks

Fogginess

bull Scratches



HEADGEAR


Cracks or gouges



Page 2 of 2

TETRA TECH INC




Site name

Site address

City state and zip











Reviewed by Date




Proiec Name Task No




Site Descnotion











G Stream Y - N z G













ATTACHMENT E




Acton Massachusetts


















barcode 43196


LIST OF ATTACHMENTS







LIST OF TABLES

PAGE









LIST OF FIGURES

PAGE




ACGIH




1 INTRODUCTION


















Section 2-7)







their own employees






















Non-Hazardous Site

Characterization









Site Office

Ambulance

Hospital


Fire Department

Poison Control

Nearest Phone



Client Contact

Project Coordinator






NameLocation Number







Fire Emergency 911








Donald Hanson MADEP

Workcare Inc

(800)424-8426










Figure 1-1)






map Figure 1-1)






apply)



and outer

hard hats


covers



TYVEK)


escape air pack

safety glasses


washable coveralls




first aid kit

fire extinguisher


FireExplosion











Hazardous Spill










(4) a shovel

















the situation






















Radiation






that exceed 1 mRhr



HAZARD

RAILROAD TRACKS

SURFACE WATER

(RIVER BROOK PONDS)

WETLANDSSWAMPS


SPIDERS TICKS


TEMPERATURE








the tracks














vegetation areas





Attachment B




Low Unknown














constructed in 1951














demolished


















































































bull _c 0






Ml^ w^^ C -u

O 0 U Q


gt o o 03 Z S 3 c

5E N

EU

TR

AL

EX

TR

AC

T

C03

- mdash5 3

IS (

2-E

TH

YL

HE

XY

L)

PHTH

Al

O _c 0 IS

(2-

CH

LOR

OET

HY

L) E

THEI

~~~ u



u C tflME ~T X


bull ^ ^^

S ^^ L ^^ C3 z 5 oSO o

T3 C S laquo


WR

GR

AC



cls

WR

GA

clon

Acc

ess9

7N

099B

D m

db

2O b ^ ^bull t3 00 =

cf g1


o

S3

E 3

00

_Q 6-D

INIT

RO

-2-M

ETH

YLP

HEN

-CH

LOR

OPH

ENO

LC

HL

OR

O-3

-ME

TH

YL

PHE

NO

4-D

IME

TH

YL

PHE

NO

L

ME

TH

YL

PHE

NO

LM

ETH

YLP

HEN

OL

bull

fN

ID E

XT

RA

CT

AB

LE

HEN

OL

^j

ENZO

IC A

CIDbullo


ENTA

CH

LOR

OPH

ENO

L4-

DIC

HL

OR

OPH

EN

OL

NIT

RO

PHEN

OL

bull 45-

TRIC

HLO

RO

PHEN

OL

NIT

RO

PHEN

OL

46

-TR

ICH

LOR

OPH

ENO

L

4-D

INIT

RO

PHEN

OL

APH

THA

LEN

E I-

n-B

UTY

LPH

THA

LATE

ITR

OB

ENZE

NE

4-D

lCH

LOR

OB

ENZE

NE

2-D

ICH

LOR

OB

ENZE

NE

I-n-

OC

TY

LPm

HA

LA

TE

CE

NA

PHT

HE

NE

UTY

LBEN

ZYLP

I ITH

ALA

TE

LUO

RA

NIH

ENE

IbTH

YLP

HTH

ALA

TE


shyCO H u

e ^ c -2 M 1 g3

ill 58 4gt w

S sect |

U Q

e poundbull 2 5D





^ s i O U uo


fl

SB

A g H


S BB 8 8 5 0


o w e Z y S

a) H

ej)pm


ltN

S _3 ^

| gt 3 C0

tU

U jB



sectO bulla

c s

l o


LU ^trade

Z gt EM S C tlJ

w ^ Z o z ^ 1 ^


rs

O lt = gtdeg O sect

uT 2 ^

^

O 2 ^

S z sect J

C ^ - - 1 - ^ ^ 1 ^ 2 ^ ^ ^ ^ sect


U

U JG

C

H2

O

C^^3 K

W~l

3 (N U

^

rlt o 5

g

J |

0 J3

1

Q 03

S f

RG

RA

CE

RC

Aclo

nA

ccraquos9

sect1

ai ^ 2O JLL a

_C

w C 5 Hllf

oIs- o o




u a

So 7s gv lt


^ rraquo

c +z u c

Cfl


bull



m

_ bull

M H 12

-DIC

HLO

RO

PR

OP


QJ CQ r- s

3

C5 1 Q Z |

UJ tO C c f

lt 1O QU aj a


cont

inue

BE

NZ

EN

E

11

-DIC

HLO

RO

ET

HE

VIN

YL C

HLO

RID

E

ET

HY

LB

EN

ZE

NE

AC

ET

ON

E

CH

LO

RO

ET

HA

NE

11 -D

ICH

LO

RO

ET

HA

XY

LE

NE

(T

OT

AL)

FO

R W

RG

RA

CE

H H

rojtc

tsW

RG

Act

oMA

cccs

s97t


TJ - s s s o G

12

-DIC

HLO

RO

ET

HA

D S D 2 W LU S

AR

SE

NIC

I S_U

UJ


gt

J

e s- C reg Si fl

raquo raquo

S bullpound 3

3 g ~ S

sect a 2 d V



U C E

c o O gv



0 raquo u c

CA

laquobullB


_^ ^ mdash 1

O U Z bullpound

O

5 j elaquo

^ 4gt 00 C5


S gtbull -5 bull C5


O U R

Z laquo S 1

11 2

-TE

TR

AC

l ILO

RO

ET

l IA

N^ r



0 S -bull3u ^

C3 j

1

a UJ Uj UJ

z0 Z X


11

2-T

RIC

HLO

RO

ET

IIAN

F

TR

ICH

LO

RO

I-LU

OR

OM

ET

HA

N

CH

LOR

OB

EN

ZE

NE

CH

LOR

OFO

RM

BR

OM

OM

ETH

AN

E

n-P

RO

PY

LBE

NZ

EN

E

BR

OM

OF

OR

M

2-C

HLO

RO

ET

HY

LV

INY

L E

TH

E

BR

OM

OD

ICH

LOR

OM

ET

HA

NE

CA

RB

ON

TE

TR

AC

HLO

RID

E

cis-

1 3

-DIC

HLO

RO

PR

OP

EN

E

p-X

YLE

NE

FO

R W

RG

RA

CE

P P

roje

cls

WR

GA

clon

Ucc

ess9

7N

099B

D m

dbshy

Tab

le 1

-1 (c

ontin

ued)

Com

pound


Cbull

H CO


S 2 oE bull bullo V



c _o i



eji

lt C o igt

ciU fi u c


o T3 C

6 V cs

bull ^ c]Z bull0U



^ rjr laquoQ^ jE DC


trt

6 0flj 3 T3

U CZ U 0 O

5 H 1 0gt

^Jlt2J 6JD c S ltuc

W

utJ3 v-




C e 3

Z gtltu E

a- 5TlkJ

Com

poun

d de

tect

ed a s

om

pound

trans-

l3-D

ICH

LO

RO

PR

O

1U

_c -raquo

o o

ltuf raquo U

_3 a

00

ltU D

c 9gt V

CO U 1 oco

1



SVOC

VOC

14-Dichloro benzene

4-Methylphenol


Nitrobenzene

Phenol


11-Dichloroethene

12-Dichloroethane

12-Dichloropropane

Benzene

Carbon disulfide

Chloroform

Chloromethane

Methylene chloride

Vinyl chloride

LFC(lOppm)

2 3 ppm

5 ppm

1 ppm [skin]

5 ppm

1 ppm

LFC( lppm)

1 ppm

LFC (75ppm)

0 1 ppm

1 ppm

2 ppm

LFC (50ppm)

LFC (25ppm)

LFC (1 ppm)

0 (A3)

n

3 (A3)

V) (A4)

S(A4)

n a (A3) 3 (A4)

g (A3) VI ( A l )






O O

a

d O

rgta

0 O

o tt

_o cL o

pound=i O)



SECONDARY LAGOON


SLOWDOWN PIT

EMERGENCY LAGOON

PRIMARY LAGOON


NORTH LAGOON

TANK CAR AREA


AHAKT2



HSI



h-s_SCH-smdwg















STATION PROTOCOL





Disposal Procedures




















methane in air


air


Confined Space


10ppm~H2S 28 ppm CO






Instrument

Action Level

Protocol

PPE

Action Level

Protocol

PPE

Action Level

Protocol

PPE

OVA andor HNu

Background


Level D



Level D



Level D






PPE Level D



PPE Level D





















Protective gloves



Dosimeter Type

Hard hat



Hearing protection


Other















Protective gloves



Dosimeter Type

Hard hat



Hearing protection


Other












STATION PROTOCOL






Disposal Procedures















methane in air


air






Instrument

Action Level

Protocol

PPE

Action Level

Protocol

PPE

Action Level

Protocol

PPE

OVA andor HNu

Background


Level D



Level D



Level D























_ Protective gloves



Dosimeter Type

Hard hat



Hearing protection


Other















Protective gloves



Dosimeter Type

Hard hat



Hearing protection


Other













STATION PROTOCOL





Disposal Procedures


















methane in air


air








PPE Level D




PPE Level D



PPE Level D




















Protective gloves



Dosimeter Type

Hard hat



Hearing protection


Other Life Vest















Protective gloves



Dosimeter Type

Hard hat

_bull_



Hearing protection


Other Life Vest



Compound

1 4-dichlorobenzene

4-methylphenol


nitrobenzene

phenol


tetrachloroethane

11 -dichloroethene

1 2-dichloroethane

1 2-dichloropropane

benzene

carbon disulfide

chloroform

chloromethane

methylene chloride

vinyl chloride

NA Not Available

HNul 02 eV Lamp1

119

NA

NA

NA

NA

NA

64

NA

02

10

49

NA

NA

014

32

Response Factor

Foxboro OVAshy108

NA

no response

2212

1641

1638

164

273

NA

149

056

3387

206

197

167

203

Foxboro OVAshy128

NA

no response

251

1652

4489

169

297

NA

148

054

5306

238

238

172

211



ATTACHMENT A










Table 1-1)



















































compounds




required


i bull U e

1 i bullltH

bullo I n cn

V


i S I0gt



Irrit

atio

n e

yes

ski

n

Res

pira

tory

Sys

u

J mdash o CO


bullsect


t^ 0

bull y)lt1 gt U

lcer

atio

n of

nas

al s

eptu

m

Der

mat

iti


Oas

trom

test

mal

dis

turb

ance

s P

crip

he



00Ily

perp

igm

enta

tion

of s

kin

Car

cmog

i 1 E pound U

3c





chills

Mus

cle

ach

es

Nau

sea

Vom

itn


c S

1 H w


Wea

knes

s L

assi

tude

In

som

nia

tac

ia

pallo

r a

nore

xia

Wei

ght

loss

Mal

nuti

anem

ia

gmgi

val

lead

lin

e t

rem

or P

a

Sen

sitiz

atio

n D

erm

atiti

s a

llerg

ic a

sth

c ~ =

Ber

ylllo

sis

(chr

onic

exp

osur

e) a

nore

gt W

eigh

t lo

ss

Wea

knes

s c

hest

pai

n u

cl

ubbi

ng o

t fin

gers

C

yano

sis

Pul

moi

in

suffi

cien

cy

irrita

tion

eye

s d

erm

atll

carc

inog

en

Pul

mon

ary

edem

a D

yspn

ea

coug

h c

Dia

rrhe

a a

nosm

ia E

mph

ysem

aP

rote

mur

ia m

ild a

nem

ia C

arci

noge

n

Irrit

atio

n e

yes

ski

n lu

ng T

ibro

sis

rfll

ct^l

trade^

Irrit

atio

n egt

es

nose

ph

aryn

x n

asal

si

Per

fora

tion

met

allic

tas

te D

erm

atiti

s an

imal

s lu

ng

liver

ki

dney

dam

age

lt

wris

t an

kles

en

ceph

alop

athy

kid

ney

dise

ase

Irr

itatio

n e

yes

hyp

oten

sion

Tig

htne

ss

Sub

ster

nal p

ain

Hea

dach

e

Con

stip

atio

n a

bdom

inal

pai

n c

olic

neur

opat

hy

Res

pira

tory

Irr

itatio

n

dete

cted

com

poun

ds

amp S o

Pne

umom

tis

Car

cino

gen lt-n

a o

1 iC3

Cu

o


Sshyn

c

i O o C2ltu

T3

-


SI bullS

1 3 C ^

a T3

s =g- su f

n a G S1

S s a s s a |

bullS 3 ~

CO co

1N laquo _c jC

-raquo

S~

SG ^|

lt

SJOrtH

e o 85^5 c

j gj

i

w c 2 1 r g

9S

ff O G shy

| lt

a

j 5

IS

1

u ca

S

imdash

1o

1

S

I C

ll u

i

s

i l

8 o

jU1

i

as

I

S

u -^2Z

G

i

u = N

i

ag^

js 1

5 lt

K 3 CJ U

LLJ I

^ sect4raquo U


c

i U _c

u c M ic T3

Phys

ical D

esc

riptio

Col

orle

ss liq

uid

or

crys

tal

solid

(be

low

63

degh)

with

ai

arom

atic

odo

r

Col

orle

ss t

o pa

le-y

ello

w

liquid

wit

h a p

leds

diit

dr

omat

ic o

dor

[her

bici

de

colo

rless

liq

uid

Col

orle

ss o

r w

hite

cry

stal

lso

lid w

ith a

moth

bdll-

like

odor

[in

sect

icid

e]

Yel

low

to

red

need

les

or

yello

w l

iquid

with

a s

llghl

odor

Ora

nge-

yello

wcr

ysta

lline

solid

will)

a

char

acte

ristic

odo

r [N

ote

Ofte

n sh

ippe

d m

olte

n ]

Ora

nge-

yello

w c

ryst

alline

so

lid w

ith d

cha

ract

eris

ticod

or

[Not

e

Ofte

n sh

ippc

m

olte

n J

t

3 ci

HS

I G

eoT

ra

1 pound ^ E a S ii

i


gt gt J2 11C3 U

o H-5 bullo j ^ ^ u



5-T

nchl

orop

h i -^shy


46

-Tnch

loro

ph


_

a s= S ~ SO a s ggt

2 S = n bullpound c


sect ijj C 30 tft







bull2 1 u


s

U d

la

tA w


)JE

CT

WR

GA

t rO

NU

( V bull3


mdash a

o jj

e


a _g 00 c^ ^ c

10) u c Q bullM


^

1 2-

Dic

hlor

oben

zi

1 3-D

ichlo

robenz

4-D

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M

aine

iKiii

alio

n

prev

ente

d a

s ne

cess

ary

thro

ug

h th

eus

e

even

t es

cape

fro

m s

uch

an

env

i ronm

ent

Iccl

ron

ic N

IOS

H P

ocke

t G

uid

e to

Che

m

hum

ans

A4

= n

ot c

lass

ifia

ble

a

Ad

min

istr

atio

n (

OS

IIA

) 19

89

RE

L tim

e-w

eig

hte

d a

vera

ge

(1

inal

carc

ino

ge

n

and

th

ere

is

ni

bullHA

PE

L o

r A

CG

IH

1 LV

in p

a


lt poundiI

~ stU S û ] u uS 2 O -5

cons

ider

s su

bsta

nce

to b

e p

ote

N

IOS

H r

eco

mm

en

de

d e

xpo

sur

O

B bull

55 nI S 2 bullmdash

o

ure

Lim

it (

ST

EL)

or

the A

CG

I

ists

(A

CG

IH)

carc

ino

ge

nic

ity degs

0 S Vgt

1 es s laquo en C

(H

gtgt R

|

X_J a

I 0gt u

I1

ii

i a -1


3 55 2deg poundM U

J= U2 a

is

a co

nef

fect

s i

iu 2=5 k 5 bull= _

Xi deg 3 = pound a

)ot

enlia

oin

incn

mdash ^ gti


^-s S M_1 gt = = =


B |


9S = mdashM C8

S pound S a

9 S

ho


|laquo^S


^ _

CA

in

dic

ate

s N

IOS

II(

mos

t p

rote

ctiv

e r

espi

rn

eren

ce o

f G

ove

rnm

al

carc

ino

ge

n w

ith

Per

Day

TW

A

The

me

Industr

ial

Hyg

ieni

sts

(

resh

old

Lim

it V

alu

w

ork

da

y (

RE

L) I

fNI

con

cen

tra

tion

(LF

C)

1

unds

are

not

ed w

ill

ed p

erm

anent

adve

|skln

| In

dic

ate

s th

e p

ot

om

po

un

ds

who

se i

17

can

no

t be

det

ci

ot a

vaila

ble

in

Qui

lt1 r^r O r_


n ^3



= =oo^S i u Vo en

û3 u u

rm

al abso

rptio

ns

istit

ute

for

Occ

up

al

Life

or

Health

con

se s

ubst

ance

s at

co

tof e

ithe

r O

ccu

pa

ti

it of

cith

er

OS

HA

1

1 no

t be

exc

eede

d d

Icrs

a s

ubst

ance

lo

Ag

en

ts A

CG

IH

uu C ~c

min

ute

TW

A e

xpos

ure

caus

e de

ath o

r im

medi

IDLII

Imm

edia

tely

D

Carc

inogenic

ity =

Ann

LE

L

low

er

exp

losi

ve 1

UE

L u

pper

exp

losi

ve1

mgm

3

mill

igra

ms

per

carc

inogen A

3 =

Conf

Ceiling

MA

X

Ceiling

Co

mp

ou

nd

s w

ith

IP

gr

Ch

em

ica

l S

ubst

ance

s a0gt

and

oth

er

appro

priate

PID

P

ho

to-i

on

iza

tion

NA

in

dic

ate

s e

xpo

sure

feas

ible

co

nce

ntr

atio

n E oen JS

(U

pound2

O O

CN

G

ab

0cs u 3

gC

1 E a a

lt I ID

I

C








Da

D

(A3)

3 (A3)

D(A4)

a D

aa

nn nnnnnaanannanan



VOC

Isophorone


Nitrobenzene

Phenol


11-DichIoroethene

12-Dichloroethane

12-Dichloropropane

Benzene

Bromoform

Bromomethane

4 ppm

LFC

1 ppm [skin]

5 ppm

1 ppm

LFC (Ippm

1 ppm

LFC (75ppm)

0 1 ppm

0 5 ppm [skin]

LFC(lppm[skm])

3 (A3)

D(A3) D(A4)

a (A3) a(A4)

3 (A4)



Chloroform 2 ppm

D




Notes

a






























VOC



ATTACHMENT B



DEFINITIONS







health effects



































employers attention


GeoTrans










HSI GeoTrans







AIR MONITORING













DECONTAMINATION











































all employees





consultation
















(2) EKG


(4) urinalysis

(5) blood profile







taken











SITE CONTROL


following
















































Accidents







Chemical Exposure













Cold Stress
























Heat Stress































(5) Acclimation

First Aid




































fatality


WATER SAFETY





















































confined space



ATTACHMENT C

















Emergency Overview


I o f 8 10199 1208 PM









2 of 8 10199 1208 PM










3 of 8 10199 1208 PM








4 of 8 10199 1208 PM












5 of 8 10199 1208 PM






Domestic (Land DOT)






6 of 8 10199 1208 PM
















7 of8 101991208 PM






8 of 8 10199 1208 PM




General Information








I o f 4 10199 212 PM











Health Hazard Data


2 of 4 10199 2 12 PM






Control Measures


Transportation Data


3 of 4 10199 212 PM




Disposal Data

Label Data


4 of4 10199 212 PM
















Emergency Overview


I o f 8 10199 12 17PM








2 of 8 10199 1217 PM











3 of 8 10199 1217PM







4 of 8 10199 1217 PM












5 of 8 10199 1217 PM






Domestic (Land DOT)








(7647-01-0) YesYes

Yes Yes

Yes Yes

Yes Yes


Ingredient

- Part 2shy

Korea--C



(7647-01-0) YesYes

Yes Yes

No No

Yes Yes



6 of 8 10199 12 17PM



Federal

Ingredient


CERCLA

shy Part 2 -RCRAshy

26133 -TSCAshy 8 (d )


(7647-01-0 ) 5000 No

No No

No No






7of8 10199 1217 PM




8 of 8 10199 1217PM




General Information






I o f 5 10199 1212 PM










2 of 5 10199 1212 PM










Reactivity Data


Health Hazard Data


3 of 5 10199 1212PM





Control Measures


Transportation Data


4 of 5 10199 1212 PM




Disposal Data

Label Data


5 of 5 10199 1212 PM


mdash



General Information








I o f 3 10199 1213PM

_ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _


Reactivity Data


Health Hazard Data




Control Measures


Transportation Data

= = == ====== = ==ss = == = = =

Disposal Data

2 of 3 10199 1213 PM


Label Data



3of3 10199 12 13PM




General Information









I o f 4 10199 1229PM



Reactivity Data


Health Hazard Data




Control Measures


2 of 4 10199 1229 PM



Transportation Data


Disposal Data = = = = = = = = 5= = = = ==

= = == = ===== = S3SSpound

Label Data



3of4 10199 12 29PM




4 of 4 10199 1229 PM




General Information








I o f 3 10199 207 PM



Reactivity Data


Health Hazard Data





Control Measures


2 of3 10199 207 PM



Transportation Data

Disposal Data = ===== = == = S5== ==

===============

Label Data


3 of 3 10199 207 PM

ATTACHMENT D

FIELD FORMS


TETRA TECH INC




E-mail


Name Office


Marital status




Street address


County






Witness(es)

Name

Address

Telephone








D None

Telephone No








Injured Employee











FormAR-l Page 2 of3

TETRA TECH INC



FormAR-1 Page 3 of3

b O

U1

c

CQ

t3

C ltu s pound o O

I O

C3 0)

_i w S j mdashshy

c u

O O

O Z 2

Q

CC o o

(U

03ltu

O

i i U

pound ab

is

sr a

Q U

degshy s a


s OH t4_ o

u

a 9 deg

o

gt^ -4mdashraquo

bull5

3 T3 C

3

I|

OS c 2

pi ^3 laquow y 1)

ll -4-

O

O -4mdashraquo

2 _bull -

oa ltu CD

3ltu H bulla

TETRA TECH INC







Chemical hazards

Physical hazards


Equipment hazards


Other






Attendees



Name Title

Signature


TETRA TECH INC


Project Name

Field Location

Project Manager

General Items


Project No

Completed by














Emergency Planning







Air Monitoring





In Compliance

Yes No NA

1






1 Splash suit



4 Gloves

5 Overboots

6 Hard hat

7 Dust mask


9 Respirator

Instrumentation


11 Oxygen meter


Supplies








Date


ft a u S |

Bar

omet

ric

Pre

ssur

e(u

nits

)

00 o

u -4mdash

ltu

-4mdashoo C

S 8 H mdash

B1) E T 1 i bullo

bull5 2

bullB L

bullo e

S 3 u

C

w

=

2

tJ

j-

C

^

a

k

iduc

tivi

ty

a X gC

E c bull3 X T3








CompanyOffice Date

Date



Site Information

Project Name Date


Project No


Space Preparation





Result


Oxygen-nun gt195

Oxygen-max lt235


HS lt10 ppm

Cl lt05 ppm

CO lt35 ppm

SO lt2 ppm

Heat degFdegC

Toxic (specify)

Other

Tester Initials


Signature of Tester

Notes




TETRA TECH INC


PROTECTIVE CLOTHING

Before use



- Imperfect seams


- Tears










bull Tears

bull Punctures



GLOVES

Before use


- Imperfect seams

Tears and abrasions





TETRA TECH INC


FOOTWEAR


bull Holes and cuts



bull Cracks in sole


EYEWEAR


bull Cracks

Fogginess

bull Scratches



HEADGEAR


Cracks or gouges



Page 2 of 2

TETRA TECH INC




Site name

Site address

City state and zip











Reviewed by Date




Proiec Name Task No




Site Descnotion











G Stream Y - N z G













ATTACHMENT E




Acton Massachusetts


















barcode 43196


LIST OF TABLES

PAGE









LIST OF FIGURES

PAGE




ACGIH




1 INTRODUCTION


















Section 2-7)







their own employees






















Non-Hazardous Site

Characterization









Site Office

Ambulance

Hospital


Fire Department

Poison Control

Nearest Phone



Client Contact

Project Coordinator






NameLocation Number







Fire Emergency 911








Donald Hanson MADEP

Workcare Inc

(800)424-8426










Figure 1-1)






map Figure 1-1)






apply)



and outer

hard hats


covers



TYVEK)


escape air pack

safety glasses


washable coveralls




first aid kit

fire extinguisher


FireExplosion











Hazardous Spill










(4) a shovel

















the situation






















Radiation






that exceed 1 mRhr



HAZARD

RAILROAD TRACKS

SURFACE WATER

(RIVER BROOK PONDS)

WETLANDSSWAMPS


SPIDERS TICKS


TEMPERATURE








the tracks














vegetation areas





Attachment B




Low Unknown














constructed in 1951














demolished


















































































bull _c 0






Ml^ w^^ C -u

O 0 U Q


gt o o 03 Z S 3 c

5E N

EU

TR

AL

EX

TR

AC

T

C03

- mdash5 3

IS (

2-E

TH

YL

HE

XY

L)

PHTH

Al

O _c 0 IS

(2-

CH

LOR

OET

HY

L) E

THEI

~~~ u



u C tflME ~T X


bull ^ ^^

S ^^ L ^^ C3 z 5 oSO o

T3 C S laquo


WR

GR

AC



cls

WR

GA

clon

Acc

ess9

7N

099B

D m

db

2O b ^ ^bull t3 00 =

cf g1


o

S3

E 3

00

_Q 6-D

INIT

RO

-2-M

ETH

YLP

HEN

-CH

LOR

OPH

ENO

LC

HL

OR

O-3

-ME

TH

YL

PHE

NO

4-D

IME

TH

YL

PHE

NO

L

ME

TH

YL

PHE

NO

LM

ETH

YLP

HEN

OL

bull

fN

ID E

XT

RA

CT

AB

LE

HEN

OL

^j

ENZO

IC A

CIDbullo


ENTA

CH

LOR

OPH

ENO

L4-

DIC

HL

OR

OPH

EN

OL

NIT

RO

PHEN

OL

bull 45-

TRIC

HLO

RO

PHEN

OL

NIT

RO

PHEN

OL

46

-TR

ICH

LOR

OPH

ENO

L

4-D

INIT

RO

PHEN

OL

APH

THA

LEN

E I-

n-B

UTY

LPH

THA

LATE

ITR

OB

ENZE

NE

4-D

lCH

LOR

OB

ENZE

NE

2-D

ICH

LOR

OB

ENZE

NE

I-n-

OC

TY

LPm

HA

LA

TE

CE

NA

PHT

HE

NE

UTY

LBEN

ZYLP

I ITH

ALA

TE

LUO

RA

NIH

ENE

IbTH

YLP

HTH

ALA

TE


shyCO H u

e ^ c -2 M 1 g3

ill 58 4gt w

S sect |

U Q

e poundbull 2 5D





^ s i O U uo


fl

SB

A g H


S BB 8 8 5 0


o w e Z y S

a) H

ej)pm


ltN

S _3 ^

| gt 3 C0

tU

U jB



sectO bulla

c s

l o


LU ^trade

Z gt EM S C tlJ

w ^ Z o z ^ 1 ^


rs

O lt = gtdeg O sect

uT 2 ^

^

O 2 ^

S z sect J

C ^ - - 1 - ^ ^ 1 ^ 2 ^ ^ ^ ^ sect


U

U JG

C

H2

O

C^^3 K

W~l

3 (N U

^

rlt o 5

g

J |

0 J3

1

Q 03

S f

RG

RA

CE

RC

Aclo

nA

ccraquos9

sect1

ai ^ 2O JLL a

_C

w C 5 Hllf

oIs- o o




u a

So 7s gv lt


^ rraquo

c +z u c

Cfl


bull



m

_ bull

M H 12

-DIC

HLO

RO

PR

OP


QJ CQ r- s

3

C5 1 Q Z |

UJ tO C c f

lt 1O QU aj a


cont

inue

BE

NZ

EN

E

11

-DIC

HLO

RO

ET

HE

VIN

YL C

HLO

RID

E

ET

HY

LB

EN

ZE

NE

AC

ET

ON

E

CH

LO

RO

ET

HA

NE

11 -D

ICH

LO

RO

ET

HA

XY

LE

NE

(T

OT

AL)

FO

R W

RG

RA

CE

H H

rojtc

tsW

RG

Act

oMA

cccs

s97t


TJ - s s s o G

12

-DIC

HLO

RO

ET

HA

D S D 2 W LU S

AR

SE

NIC

I S_U

UJ


gt

J

e s- C reg Si fl

raquo raquo

S bullpound 3

3 g ~ S

sect a 2 d V



U C E

c o O gv



0 raquo u c

CA

laquobullB


_^ ^ mdash 1

O U Z bullpound

O

5 j elaquo

^ 4gt 00 C5


S gtbull -5 bull C5


O U R

Z laquo S 1

11 2

-TE

TR

AC

l ILO

RO

ET

l IA

N^ r



0 S -bull3u ^

C3 j

1

a UJ Uj UJ

z0 Z X


11

2-T

RIC

HLO

RO

ET

IIAN

F

TR

ICH

LO

RO

I-LU

OR

OM

ET

HA

N

CH

LOR

OB

EN

ZE

NE

CH

LOR

OFO

RM

BR

OM

OM

ETH

AN

E

n-P

RO

PY

LBE

NZ

EN

E

BR

OM

OF

OR

M

2-C

HLO

RO

ET

HY

LV

INY

L E

TH

E

BR

OM

OD

ICH

LOR

OM

ET

HA

NE

CA

RB

ON

TE

TR

AC

HLO

RID

E

cis-

1 3

-DIC

HLO

RO

PR

OP

EN

E

p-X

YLE

NE

FO

R W

RG

RA

CE

P P

roje

cls

WR

GA

clon

Ucc

ess9

7N

099B

D m

dbshy

Tab

le 1

-1 (c

ontin

ued)

Com

pound


Cbull

H CO


S 2 oE bull bullo V



c _o i



eji

lt C o igt

ciU fi u c


o T3 C

6 V cs

bull ^ c]Z bull0U



^ rjr laquoQ^ jE DC


trt

6 0flj 3 T3

U CZ U 0 O

5 H 1 0gt

^Jlt2J 6JD c S ltuc

W

utJ3 v-




C e 3

Z gtltu E

a- 5TlkJ

Com

poun

d de

tect

ed a s

om

pound

trans-

l3-D

ICH

LO

RO

PR

O

1U

_c -raquo

o o

ltuf raquo U

_3 a

00

ltU D

c 9gt V

CO U 1 oco

1



SVOC

VOC

14-Dichloro benzene

4-Methylphenol


Nitrobenzene

Phenol


11-Dichloroethene

12-Dichloroethane

12-Dichloropropane

Benzene

Carbon disulfide

Chloroform

Chloromethane

Methylene chloride

Vinyl chloride

LFC(lOppm)

2 3 ppm

5 ppm

1 ppm [skin]

5 ppm

1 ppm

LFC( lppm)

1 ppm

LFC (75ppm)

0 1 ppm

1 ppm

2 ppm

LFC (50ppm)

LFC (25ppm)

LFC (1 ppm)

0 (A3)

n

3 (A3)

V) (A4)

S(A4)

n a (A3) 3 (A4)

g (A3) VI ( A l )






O O

a

d O

rgta

0 O

o tt

_o cL o

pound=i O)



SECONDARY LAGOON


SLOWDOWN PIT

EMERGENCY LAGOON

PRIMARY LAGOON


NORTH LAGOON

TANK CAR AREA


AHAKT2



HSI



h-s_SCH-smdwg















STATION PROTOCOL





Disposal Procedures




















methane in air


air


Confined Space


10ppm~H2S 28 ppm CO






Instrument

Action Level

Protocol

PPE

Action Level

Protocol

PPE

Action Level

Protocol

PPE

OVA andor HNu

Background


Level D



Level D



Level D






PPE Level D



PPE Level D





















Protective gloves



Dosimeter Type

Hard hat



Hearing protection


Other















Protective gloves



Dosimeter Type

Hard hat



Hearing protection


Other












STATION PROTOCOL






Disposal Procedures















methane in air


air






Instrument

Action Level

Protocol

PPE

Action Level

Protocol

PPE

Action Level

Protocol

PPE

OVA andor HNu

Background


Level D



Level D



Level D























_ Protective gloves



Dosimeter Type

Hard hat



Hearing protection


Other















Protective gloves



Dosimeter Type

Hard hat



Hearing protection


Other













STATION PROTOCOL





Disposal Procedures


















methane in air


air








PPE Level D




PPE Level D



PPE Level D




















Protective gloves



Dosimeter Type

Hard hat



Hearing protection


Other Life Vest















Protective gloves



Dosimeter Type

Hard hat

_bull_



Hearing protection


Other Life Vest



Compound

1 4-dichlorobenzene

4-methylphenol


nitrobenzene

phenol


tetrachloroethane

11 -dichloroethene

1 2-dichloroethane

1 2-dichloropropane

benzene

carbon disulfide

chloroform

chloromethane

methylene chloride

vinyl chloride

NA Not Available

HNul 02 eV Lamp1

119

NA

NA

NA

NA

NA

64

NA

02

10

49

NA

NA

014

32

Response Factor

Foxboro OVAshy108

NA

no response

2212

1641

1638

164

273

NA

149

056

3387

206

197

167

203

Foxboro OVAshy128

NA

no response

251

1652

4489

169

297

NA

148

054

5306

238

238

172

211



ATTACHMENT A










Table 1-1)



















































compounds




required


i bull U e

1 i bullltH

bullo I n cn

V


i S I0gt



Irrit

atio

n e

yes

ski

n

Res

pira

tory

Sys

u

J mdash o CO


bullsect


t^ 0

bull y)lt1 gt U

lcer

atio

n of

nas

al s

eptu

m

Der

mat

iti


Oas

trom

test

mal

dis

turb

ance

s P

crip

he



00Ily

perp

igm

enta

tion

of s

kin

Car

cmog

i 1 E pound U

3c





chills

Mus

cle

ach

es

Nau

sea

Vom

itn


c S

1 H w


Wea

knes

s L

assi

tude

In

som

nia

tac

ia

pallo

r a

nore

xia

Wei

ght

loss

Mal

nuti

anem

ia

gmgi

val

lead

lin

e t

rem

or P

a

Sen

sitiz

atio

n D

erm

atiti

s a

llerg

ic a

sth

c ~ =

Ber

ylllo

sis

(chr

onic

exp

osur

e) a

nore

gt W

eigh

t lo

ss

Wea

knes

s c

hest

pai

n u

cl

ubbi

ng o

t fin

gers

C

yano

sis

Pul

moi

in

suffi

cien

cy

irrita

tion

eye

s d

erm

atll

carc

inog

en

Pul

mon

ary

edem

a D

yspn

ea

coug

h c

Dia

rrhe

a a

nosm

ia E

mph

ysem

aP

rote

mur

ia m

ild a

nem

ia C

arci

noge

n

Irrit

atio

n e

yes

ski

n lu

ng T

ibro

sis

rfll

ct^l

trade^

Irrit

atio

n egt

es

nose

ph

aryn

x n

asal

si

Per

fora

tion

met

allic

tas

te D

erm

atiti

s an

imal

s lu

ng

liver

ki

dney

dam

age

lt

wris

t an

kles

en

ceph

alop

athy

kid

ney

dise

ase

Irr

itatio

n e

yes

hyp

oten

sion

Tig

htne

ss

Sub

ster

nal p

ain

Hea

dach

e

Con

stip

atio

n a

bdom

inal

pai

n c

olic

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low

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ai

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icid

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effe

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fusi

on

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ssio

n R

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re

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ry

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knes

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lse

eye

ski

n bu

rns

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mat

itis

lung

liv

er

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se

thro

at

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hem

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hys

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n

solid

C

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coa

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pi

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tlles

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phou

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uish

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et fl

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k ar

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Con

stitu

ent

in c

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latil

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l ta

r is

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k-br

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phou

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enis

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nce

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stitu

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in

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n

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phou

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less

ye

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mon

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a

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solid

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6degF

] ki

dney

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k or

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cr

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ever

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tain

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mat

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mat

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hem

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mix

ing

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orph

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ch

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dor




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a 05= S l Q i Q

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pound

gt 1

gt

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u oo oo o

s s oo -ltr ^ Vl

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0

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u I-shyo

gt u r-

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VO

g

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pound

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gt

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gt

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oo

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eft

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bull shy

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mdash mdash mdash

mdash mdash pound

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0 60

ppm

s a

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pound CL CL e CL a

CL CL CL CL g CL



|1 c

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a CLCL

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ter

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n (

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inal

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ni

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ider

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nce

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ity degs

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fect

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incn

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TW

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me

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resh

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ork

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cen

tra

tion

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C)

1

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are

not

ed w

ill

ed p

erm

anent

adve

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ate

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ds

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se i

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can

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ble

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n ^3



= =oo^S i u Vo en

û3 u u

rm

al abso

rptio

ns

istit

ute

for

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up

al

Life

or

Health

con

se s

ubst

ance

s at

co

tof e

ithe

r O

ccu

pa

ti

it of

cith

er

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HA

1

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t be

exc

eede

d d

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a s

ubst

ance

lo

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en

ts A

CG

IH

uu C ~c

min

ute

TW

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xpos

ure

caus

e de

ath o

r im

medi

IDLII

Imm

edia

tely

D

Carc

inogenic

ity =

Ann

LE

L

low

er

exp

losi

ve 1

UE

L u

pper

exp

losi

ve1

mgm

3

mill

igra

ms

per

carc

inogen A

3 =

Conf

Ceiling

MA

X

Ceiling

Co

mp

ou

nd

s w

ith

IP

gr

Ch

em

ica

l S

ubst

ance

s a0gt

and

oth

er

appro

priate

PID

P

ho

to-i

on

iza

tion

NA

in

dic

ate

s e

xpo

sure

feas

ible

co

nce

ntr

atio

n E oen JS

(U

pound2

O O

CN

G

ab

0cs u 3

gC

1 E a a

lt I ID

I

C








Da

D

(A3)

3 (A3)

D(A4)

a D

aa

nn nnnnnaanannanan



VOC

Isophorone


Nitrobenzene

Phenol


11-DichIoroethene

12-Dichloroethane

12-Dichloropropane

Benzene

Bromoform

Bromomethane

4 ppm

LFC

1 ppm [skin]

5 ppm

1 ppm

LFC (Ippm

1 ppm

LFC (75ppm)

0 1 ppm

0 5 ppm [skin]

LFC(lppm[skm])

3 (A3)

D(A3) D(A4)

a (A3) a(A4)

3 (A4)



Chloroform 2 ppm

D




Notes

a






























VOC



ATTACHMENT B



DEFINITIONS







health effects



































employers attention


GeoTrans










HSI GeoTrans







AIR MONITORING













DECONTAMINATION











































all employees





consultation
















(2) EKG


(4) urinalysis

(5) blood profile







taken











SITE CONTROL


following
















































Accidents







Chemical Exposure













Cold Stress
























Heat Stress































(5) Acclimation

First Aid




































fatality


WATER SAFETY





















































confined space



ATTACHMENT C

















Emergency Overview


I o f 8 10199 1208 PM









2 of 8 10199 1208 PM










3 of 8 10199 1208 PM








4 of 8 10199 1208 PM












5 of 8 10199 1208 PM






Domestic (Land DOT)






6 of 8 10199 1208 PM
















7 of8 101991208 PM






8 of 8 10199 1208 PM




General Information








I o f 4 10199 212 PM











Health Hazard Data


2 of 4 10199 2 12 PM






Control Measures


Transportation Data


3 of 4 10199 212 PM




Disposal Data

Label Data


4 of4 10199 212 PM
















Emergency Overview


I o f 8 10199 12 17PM








2 of 8 10199 1217 PM











3 of 8 10199 1217PM







4 of 8 10199 1217 PM












5 of 8 10199 1217 PM






Domestic (Land DOT)








(7647-01-0) YesYes

Yes Yes

Yes Yes

Yes Yes


Ingredient

- Part 2shy

Korea--C



(7647-01-0) YesYes

Yes Yes

No No

Yes Yes



6 of 8 10199 12 17PM



Federal

Ingredient


CERCLA

shy Part 2 -RCRAshy

26133 -TSCAshy 8 (d )


(7647-01-0 ) 5000 No

No No

No No






7of8 10199 1217 PM




8 of 8 10199 1217PM




General Information






I o f 5 10199 1212 PM










2 of 5 10199 1212 PM










Reactivity Data


Health Hazard Data


3 of 5 10199 1212PM





Control Measures


Transportation Data


4 of 5 10199 1212 PM




Disposal Data

Label Data


5 of 5 10199 1212 PM


mdash



General Information








I o f 3 10199 1213PM

_ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _


Reactivity Data


Health Hazard Data




Control Measures


Transportation Data

= = == ====== = ==ss = == = = =

Disposal Data

2 of 3 10199 1213 PM


Label Data



3of3 10199 12 13PM




General Information









I o f 4 10199 1229PM



Reactivity Data


Health Hazard Data




Control Measures


2 of 4 10199 1229 PM



Transportation Data


Disposal Data = = = = = = = = 5= = = = ==

= = == = ===== = S3SSpound

Label Data



3of4 10199 12 29PM




4 of 4 10199 1229 PM




General Information








I o f 3 10199 207 PM



Reactivity Data


Health Hazard Data





Control Measures


2 of3 10199 207 PM



Transportation Data

Disposal Data = ===== = == = S5== ==

===============

Label Data


3 of 3 10199 207 PM

ATTACHMENT D

FIELD FORMS


TETRA TECH INC




E-mail


Name Office


Marital status




Street address


County






Witness(es)

Name

Address

Telephone








D None

Telephone No








Injured Employee











FormAR-l Page 2 of3

TETRA TECH INC



FormAR-1 Page 3 of3

b O

U1

c

CQ

t3

C ltu s pound o O

I O

C3 0)

_i w S j mdashshy

c u

O O

O Z 2

Q

CC o o

(U

03ltu

O

i i U

pound ab

is

sr a

Q U

degshy s a


s OH t4_ o

u

a 9 deg

o

gt^ -4mdashraquo

bull5

3 T3 C

3

I|

OS c 2

pi ^3 laquow y 1)

ll -4-

O

O -4mdashraquo

2 _bull -

oa ltu CD

3ltu H bulla

TETRA TECH INC







Chemical hazards

Physical hazards


Equipment hazards


Other






Attendees



Name Title

Signature


TETRA TECH INC


Project Name

Field Location

Project Manager

General Items


Project No

Completed by














Emergency Planning







Air Monitoring





In Compliance

Yes No NA

1






1 Splash suit



4 Gloves

5 Overboots

6 Hard hat

7 Dust mask


9 Respirator

Instrumentation


11 Oxygen meter


Supplies








Date


ft a u S |

Bar

omet

ric

Pre

ssur

e(u

nits

)

00 o

u -4mdash

ltu

-4mdashoo C

S 8 H mdash

B1) E T 1 i bullo

bull5 2

bullB L

bullo e

S 3 u

C

w

=

2

tJ

j-

C

^

a

k

iduc

tivi

ty

a X gC

E c bull3 X T3








CompanyOffice Date

Date



Site Information

Project Name Date


Project No


Space Preparation





Result


Oxygen-nun gt195

Oxygen-max lt235


HS lt10 ppm

Cl lt05 ppm

CO lt35 ppm

SO lt2 ppm

Heat degFdegC

Toxic (specify)

Other

Tester Initials


Signature of Tester

Notes




TETRA TECH INC


PROTECTIVE CLOTHING

Before use



- Imperfect seams


- Tears










bull Tears

bull Punctures



GLOVES

Before use


- Imperfect seams

Tears and abrasions





TETRA TECH INC


FOOTWEAR


bull Holes and cuts



bull Cracks in sole


EYEWEAR


bull Cracks

Fogginess

bull Scratches



HEADGEAR


Cracks or gouges



Page 2 of 2

TETRA TECH INC




Site name

Site address

City state and zip











Reviewed by Date




Proiec Name Task No




Site Descnotion











G Stream Y - N z G













ATTACHMENT E




Acton Massachusetts


















barcode 43196


LIST OF FIGURES

PAGE




ACGIH




1 INTRODUCTION


















Section 2-7)







their own employees






















Non-Hazardous Site

Characterization









Site Office

Ambulance

Hospital


Fire Department

Poison Control

Nearest Phone



Client Contact

Project Coordinator






NameLocation Number







Fire Emergency 911








Donald Hanson MADEP

Workcare Inc

(800)424-8426










Figure 1-1)






map Figure 1-1)






apply)



and outer

hard hats


covers



TYVEK)


escape air pack

safety glasses


washable coveralls




first aid kit

fire extinguisher


FireExplosion











Hazardous Spill










(4) a shovel

















the situation






















Radiation






that exceed 1 mRhr



HAZARD

RAILROAD TRACKS

SURFACE WATER

(RIVER BROOK PONDS)

WETLANDSSWAMPS


SPIDERS TICKS


TEMPERATURE








the tracks














vegetation areas





Attachment B




Low Unknown














constructed in 1951














demolished


















































































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bull 45-

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AC

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le 1

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ontin

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Com

pound


Cbull

H CO


S 2 oE bull bullo V



c _o i



eji

lt C o igt

ciU fi u c


o T3 C

6 V cs

bull ^ c]Z bull0U



^ rjr laquoQ^ jE DC


trt

6 0flj 3 T3

U CZ U 0 O

5 H 1 0gt

^Jlt2J 6JD c S ltuc

W

utJ3 v-




C e 3

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a- 5TlkJ

Com

poun

d de

tect

ed a s

om

pound

trans-

l3-D

ICH

LO

RO

PR

O

1U

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o o

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00

ltU D

c 9gt V

CO U 1 oco

1



SVOC

VOC

14-Dichloro benzene

4-Methylphenol


Nitrobenzene

Phenol


11-Dichloroethene

12-Dichloroethane

12-Dichloropropane

Benzene

Carbon disulfide

Chloroform

Chloromethane

Methylene chloride

Vinyl chloride

LFC(lOppm)

2 3 ppm

5 ppm

1 ppm [skin]

5 ppm

1 ppm

LFC( lppm)

1 ppm

LFC (75ppm)

0 1 ppm

1 ppm

2 ppm

LFC (50ppm)

LFC (25ppm)

LFC (1 ppm)

0 (A3)

n

3 (A3)

V) (A4)

S(A4)

n a (A3) 3 (A4)

g (A3) VI ( A l )






O O

a

d O

rgta

0 O

o tt

_o cL o

pound=i O)



SECONDARY LAGOON


SLOWDOWN PIT

EMERGENCY LAGOON

PRIMARY LAGOON


NORTH LAGOON

TANK CAR AREA


AHAKT2



HSI



h-s_SCH-smdwg















STATION PROTOCOL





Disposal Procedures




















methane in air


air


Confined Space


10ppm~H2S 28 ppm CO






Instrument

Action Level

Protocol

PPE

Action Level

Protocol

PPE

Action Level

Protocol

PPE

OVA andor HNu

Background


Level D



Level D



Level D






PPE Level D



PPE Level D





















Protective gloves



Dosimeter Type

Hard hat



Hearing protection


Other















Protective gloves



Dosimeter Type

Hard hat



Hearing protection


Other












STATION PROTOCOL






Disposal Procedures















methane in air


air






Instrument

Action Level

Protocol

PPE

Action Level

Protocol

PPE

Action Level

Protocol

PPE

OVA andor HNu

Background


Level D



Level D



Level D























_ Protective gloves



Dosimeter Type

Hard hat



Hearing protection


Other















Protective gloves



Dosimeter Type

Hard hat



Hearing protection


Other













STATION PROTOCOL





Disposal Procedures


















methane in air


air








PPE Level D




PPE Level D



PPE Level D




















Protective gloves



Dosimeter Type

Hard hat



Hearing protection


Other Life Vest















Protective gloves



Dosimeter Type

Hard hat

_bull_



Hearing protection


Other Life Vest



Compound

1 4-dichlorobenzene

4-methylphenol


nitrobenzene

phenol


tetrachloroethane

11 -dichloroethene

1 2-dichloroethane

1 2-dichloropropane

benzene

carbon disulfide

chloroform

chloromethane

methylene chloride

vinyl chloride

NA Not Available

HNul 02 eV Lamp1

119

NA

NA

NA

NA

NA

64

NA

02

10

49

NA

NA

014

32

Response Factor

Foxboro OVAshy108

NA

no response

2212

1641

1638

164

273

NA

149

056

3387

206

197

167

203

Foxboro OVAshy128

NA

no response

251

1652

4489

169

297

NA

148

054

5306

238

238

172

211



ATTACHMENT A










Table 1-1)



















































compounds




required


i bull U e

1 i bullltH

bullo I n cn

V


i S I0gt



Irrit

atio

n e

yes

ski

n

Res

pira

tory

Sys

u

J mdash o CO


bullsect


t^ 0

bull y)lt1 gt U

lcer

atio

n of

nas

al s

eptu

m

Der

mat

iti


Oas

trom

test

mal

dis

turb

ance

s P

crip

he



00Ily

perp

igm

enta

tion

of s

kin

Car

cmog

i 1 E pound U

3c





chills

Mus

cle

ach

es

Nau

sea

Vom

itn


c S

1 H w


Wea

knes

s L

assi

tude

In

som

nia

tac

ia

pallo

r a

nore

xia

Wei

ght

loss

Mal

nuti

anem

ia

gmgi

val

lead

lin

e t

rem

or P

a

Sen

sitiz

atio

n D

erm

atiti

s a

llerg

ic a

sth

c ~ =

Ber

ylllo

sis

(chr

onic

exp

osur

e) a

nore

gt W

eigh

t lo

ss

Wea

knes

s c

hest

pai

n u

cl

ubbi

ng o

t fin

gers

C

yano

sis

Pul

moi

in

suffi

cien

cy

irrita

tion

eye

s d

erm

atll

carc

inog

en

Pul

mon

ary

edem

a D

yspn

ea

coug

h c

Dia

rrhe

a a

nosm

ia E

mph

ysem

aP

rote

mur

ia m

ild a

nem

ia C

arci

noge

n

Irrit

atio

n e

yes

ski

n lu

ng T

ibro

sis

rfll

ct^l

trade^

Irrit

atio

n egt

es

nose

ph

aryn

x n

asal

si

Per

fora

tion

met

allic

tas

te D

erm

atiti

s an

imal

s lu

ng

liver

ki

dney

dam

age

lt

wris

t an

kles

en

ceph

alop

athy

kid

ney

dise

ase

Irr

itatio

n e

yes

hyp

oten

sion

Tig

htne

ss

Sub

ster

nal p

ain

Hea

dach

e

Con

stip

atio

n a

bdom

inal

pai

n c

olic

neur

opat

hy

Res

pira

tory

Irr

itatio

n

dete

cted

com

poun

ds

amp S o

Pne

umom

tis

Car

cino

gen lt-n

a o

1 iC3

Cu

o


Sshyn

c

i O o C2ltu

T3

-


SI bullS

1 3 C ^

a T3

s =g- su f

n a G S1

S s a s s a |

bullS 3 ~

CO co

1N laquo _c jC

-raquo

S~

SG ^|

lt

SJOrtH

e o 85^5 c

j gj

i

w c 2 1 r g

9S

ff O G shy

| lt

a

j 5

IS

1

u ca

S

imdash

1o

1

S

I C

ll u

i

s

i l

8 o

jU1

i

as

I

S

u -^2Z

G

i

u = N

i

ag^

js 1

5 lt

K 3 CJ U

LLJ I

^ sect4raquo U


c

i U _c

u c M ic T3

Phys

ical D

esc

riptio

Col

orle

ss liq

uid

or

crys

tal

solid

(be

low

63

degh)

with

ai

arom

atic

odo

r

Col

orle

ss t

o pa

le-y

ello

w

liquid

wit

h a p

leds

diit

dr

omat

ic o

dor

[her

bici

de

colo

rless

liq

uid

Col

orle

ss o

r w

hite

cry

stal

lso

lid w

ith a

moth

bdll-

like

odor

[in

sect

icid

e]

Yel

low

to

red

need

les

or

yello

w l

iquid

with

a s

llghl

odor

Ora

nge-

yello

wcr

ysta

lline

solid

will)

a

char

acte

ristic

odo

r [N

ote

Ofte

n sh

ippe

d m

olte

n ]

Ora

nge-

yello

w c

ryst

alline

so

lid w

ith d

cha

ract

eris

ticod

or

[Not

e

Ofte

n sh

ippc

m

olte

n J

t

3 ci

HS

I G

eoT

ra

1 pound ^ E a S ii

i


gt gt J2 11C3 U

o H-5 bullo j ^ ^ u



5-T

nchl

orop

h i -^shy


46

-Tnch

loro

ph


_

a s= S ~ SO a s ggt

2 S = n bullpound c


sect ijj C 30 tft







bull2 1 u


s

U d

la

tA w


)JE

CT

WR

GA

t rO

NU

( V bull3


mdash a

o jj

e


a _g 00 c^ ^ c

10) u c Q bullM


^

1 2-

Dic

hlor

oben

zi

1 3-D

ichlo

robenz

4-D

ichlo

rophen

4-D

imet

hylp

her

2-C

hlor

onap

htha

l

2-C

hlor

ophe

nol

2-M

eth

ylnaphth

al

WR

G

RA

CE

26

-Din

itroto

luemi s

1

1 4-

Dic

hlor

oben

z

12

4-T

nchl

orob

e

22

-Oxy

bis

(l-c

hl

O



i rpound ampO gt

i t^ U_ a pound

2

1

1

9 e o c 1^ J



-gt vi 13 U U

Oat o



O ol u sl 5 Q^ ^1

I Iu

|


S ^ 5^ q 3 1 ^



Q

tmdash

u


V)

2 c pound

C3


o V) S


3 C


e

1o




c

2



pound E i bull 2


u


a

Ski

n S

ensi

tizat

ion

Der

mat

itis

Hea

dach

e

Diz

zine

ss

caus

tic b

urns

fre

quen

t ur

inat

ion

dy

suria

H

emat

una

Gas

troin

test

inal

ups

et

uppe

r R

espi

rato

ry i

nfec

tion

Car

cino

gen

Sens

e of

wel

l be

ing

Hea

dach

e f

ever

I

assi

tude

pr

ofus

e S

wea

ting

exc

ess

thirs

t Ta

chyc

ardi

a h

ypei

pnea

co

ugh

Sho

rtnes

s B

reat

hing

com

a

Irrit

atio

n e

yes

ski

n m

ucou

s m

embr

ane

Cen

tral

Ner

vous

Sys

tem

effe

cts

Con

fusi

on

Dep

ress

antD

epre

ssio

n R

espi

rato

ry 1

ailu

re

Dys

pnea

Irr

egul

arIr

regu

larit

ies

rapi

dR

espi

rato

ry

Wea

knes

s pu

lse

eye

ski

n bu

rns

Der

mat

itis

lung

liv

er

kidn

ey

panc

reas

Irrit

atio

n no

se

thro

at

Cya

nosi

s a

taxi

a

Tach

ycar

dia

tac

hypn

ea

Dys

pnea

Ir

rita

bili

ty

Vom

iting

D

iarr

hea

C

onvu

lsio

ns

Res

pira

tory

arr

est

anem

ia

Met

hem

oglo

bmem

ia j

aund

ice

2

laquo P

hys

ical D

esc

riptio

n

solid

C

onst

ituen

t in

coa

l tar

pi

tch

vola

tlles

C

oal t

ar is

a

blac

k or

dar

k-br

own

amor

phou

s re

sidu

e

whi

te t

o ye

llow

cry

stal

s w

ithbl

uish

or

viol

et fl

uore

scen

cean

d a

wea

k ar

omat

ic o

dor

Con

stitu

ent

in c

oal t

ar p

itch

vo

latil

es

Coa

l ta

r is

a b

lack

or

dar

k-br

own

amor

phou

s re

sidu

e

colo

rless

leaf

lets

or p

late

s w

ith a

gre

enis

h-ye

llow

fluor

esce

nce

Con

stitu

ent

in

coal

tar

pitc

h v

olat

iles

C

oal

tar

is a

bla

ck o

r da

rk-b

row

n

amor

phou

s re

sidu

e

odor

less

ye

llow

cry

stal

s

Con

stitu

ent

in c

oal t

ar p

itch

vo

latil

es

Coa

l tar

is a

bla

ck

or d

ark-

brow

n am

orph

ous

resi

due

solid

C

onst

ituen

t in

coa

l tar

pi

tch

vola

tiles

C

oal

tar

is a

bl

ack

or d

ark-

brow

nam

orph

ous

resi

due

solid

C

onst

ituen

t in

coa

l tar

pi

tch

vola

tiles

C

oal

tar

is a

bl

ack

or d

ark-

brow

nam

orph

ous

resi

due

solid

C

onst

ituen

t in

coa

l tar

pi

tch

vola

tlles

C

oal

tar

is a

bl

ack

or d

ark-

brow

nam

orph

ous

resi

due

O H-1

CD

1

iV

c a o ogt u cs

I H

c -^ 15 ao w c - 3

c mdash

bulllaquo C U

o ^ i 2 amp B

sectbullbullsect -^

cpound 2 ltJ

u T3

c -^ 3 00 gt C

E=

|l|

S u e ^bull^ ^2

oi 35 ^J

S T3

c - gpound

laquo S


O ~^ trade

2 S i-l5 _laquo

S T3

c - 5 gjj

s M gti

lyen |J| a S $t

tgt c

TJ

cf bull

bull5 ^

c 5_

tS gtraquo VI C 0gt


ci S

u cbullo

=bull ~z degdeg


2 u e 5-3 JZ 13 s

otf S =laquo

u c

T3



c c c E c c c

V)

o

U)o c

laquo o

u 00 o c u

u

o c 5

0

amp o c 3

0

00 O

)mdash

0

o

j-3

U

oo

s J-]

o | Q

pound en

ltgt mdash 1 c

wf bullS o c o

i o

bull~ _

o o

claquo

^

C o

(X1

S

c o

vT c o


J

E

S2

ec

^

S =

S3

i C

amp

= a c

^

Wl

I C

amp

wf

fl S

1


c _o 4gt C

D n a D D n D ||

U 3 B

o -^


s o


ltU 3 C

+2

u c o

u c u

c

C O

1 1

u

=Hjj1

s C CO C

lt

u g

n

lt

u

bulls c 1

IV

03

u jgt graquo -5

t a

i o 3

2 N

U 03

u c bullmdashbdquo

00

ca

^

o 3

2

N

U CQ

H

C bull1

1

Phy

sica

l D

esc

riptio

n

colo

rless

to

whi

te n

eedl

es

scal

es

or p

owde

r w

ith a

fai

nt

benz

oin

or

ben

alde

hyde

-like

odor

Col

orle

ss li

quid

with

ach

lorin

ated

so

lve

nt-

like

odor

Col

orle

ss

oily

liq

uid

with

a

slig

ht

odor




HS

I G

eoT

rans

| 5 c c






E pound i otil s


0 o 0c H n

1 2 V) 2 - mdash -o o


0 vT 0^ cf _- Z 13 3 0 S 5

~






1 |

s o VI ~


i3 S


w _f J~

a c


^ ~ lt w ~ i


VJ



1

tfR

GR

AC

EC

TW

RG

AC

TO

NY

laquo eg ^ O

S J iO 3 _O Q 2


is(2

-Chl

oroe

th

uty

l be

nzyl

phi

ffl

|Clt3 o U- a H 1


1jU

rs rs 1 _

Q 15 S1gt a 1 0 a03 C Q gt S

pound 2

1

0

1

i

HS

I G

eoT

rans

inc

Colo

rless

to

wate

r-w

hite

oily

liquid

with

a v

ery

slig

ht

aro

matic

odo

r [p

est

icid

e]

Colo

rless

oily

liq

uid

with a




ar

colo

rless

liq

uid

with

a

mild

tu

rpentin

e-lik

e o

dor

Pa

le-y

ello

w t

o a

mber-

colo

red

liquid

with

a p

ungent

Colo

rless

cry

sta

ls w

ith

a

cam

phor-

like odor

Sol

id

Con

stitu

ent in

coa

l tar

pi

tch

vola

tiles

C

oal t

ar is

a

Gast

roin

test

inal tr

act

slig

ht

aro

matic

odo

r [N

ote

A

solid

belo

w 4

2degF

J

Physic

al D

escription

ea

Saliv

atio

n

Pul

mon

ary

unple

asa

nt

odor

[N

ote

A

a

Vom

iting

Dia

rrhea

in

solid

belo

w I

6degF

] ki

dney

Inju

ry

amp s

kin c

ance

r]

blac

k or

dar

k-br

own

amor

phou

s re

sidu

e

sk

in

nose

th

roat

Hea

dac

Eye

s s

kin

Resp

irato

Centr

al

Nerv

ous

Sys

tP

erip

hera

l nerv

ous

sy

ss

Wea

knes

s s

pasm

s in

ar

R

ep

rod

uct

ive

eff

ect


adde

r ki

dney

s [lu

n



bla

dder

kid

neys

[lu

n

-C P tlaquo S c

natio

n e

yes

ski

n

Resp

irati

Eye

s s

kin

Re

spir

ato

i y

dam

age C

arc

inogen

kid

ne

ys [

in a

nim

als

1

sk

in

muco

us

mem

bra

ne i

Re

spir

ato

ry s

yste

ms

bla

dder

kid

ne

ys |lu


up

per

Re

spir

ato

ry S

yste

m

Eye

s R

esp

irato

ry s

ys

bullonc

hltis

Car

cino

gen

Res

pira

tory

sys

tem

s

amp s

kin

canc

er]

onch

ltis

Carc

inogen

Resp

irato

ry s

yste

m s

Re

pro

du

ctiv

e s

yste

m o o

a 33 ^2 Cfl


H

i 1 o

s

S E i= (n =

amp s

kin

cance

r]

c E J 2 gt -^

tum

ors

UJ

usca

Lacr

unatio

n p

oss

ible

ski

n

Re

spir

ato

ry S

yste

m

ly

vest

lbula

r D

ysfu

nct

ion

s 1

acn

matio

n S

neezi

ng

y d

am

age C

arc

inogen

onch

ltis

Carc

inogen

fn Cb O

c3 iHin

dis


5 a 2 2 bullo








GA

CT

ON

UI



IO

a a a a D a a a a ^

curaquo 11

bullo e c c

ltX

g 351 c V)


HV CL

o 0gt Js 1 1 1|

5R

AC

EOc5

_0 2 2 1 _O 0 _o 1

S 1V


11 ~x 5 -g g


bullo ^ 63

Iltu I Ko 5 i

U a H










c 0


pound 1 i2 gtgt O f


C u c y




Sym

ptom

s Ph

ysic

al D

escr

iptio

nIr

rita

tion

eyes

no

se t

hroa

t H

eada

che

C

olor

less

to

whi

te li

quid

with

N

ause

a D

izzi

ness

Fat

igue

Mal

aise

a

pepp

erm

int-

likeo

dor

Nar

cosi

s D

erm

atiti

s in

ani

mal

s ki

dney

liv

er d

amag

e

Irri

tatio

n ey

es s

kin

muc

ous

mem

bran

e

Col

orle

ss l

iqui

d w

ith a

sha

rp

Der

mat

itis

Hea

dach

e N

arco

sis

com

a pe

netr

atin

g a

rom

atic

odo

r

Nau

sea

Vom

itin

g D

iarr

hea

abd

omin

alY

ello

w o

ily l

iqui

d w

ith a

cr

amps

Hea

dach

e l

ever

enl

arge

d liv

er

tain

t ch

arac

teri

stic

odo

rJa

undi

ce D

ecre

ased

liv

erk

idne

y

Pulm

onar

y Fu

nctio

n C

arci

noge

n

gree

n pl

aty

crys

tals

or

dark

bl

ue c

ryst

als

Irri

tatio

n ey

es

Hea

dach

e C

onfu

sion

C

olor

less

to b

row

n so

lid w

ith

exci

tem

ent

Mal

aise

Nau

sea

Vom

iting

an

odo

r of

mot

hbal

ls

[Not

e ab

dom

inal

pai

n I

rrita

tion

blad

der

prof

use

Ship

ped

as a

mol

ten

solid

]

Swea

ting

Jau

ndic

e H

emat

una

H

emog

lobm

una

ren

al s

hutd

own

Der

mat

itis

opt

ical

neu

riti

s C

orne

al d

amag

e

Irri

tatio

n ey

es s

kin

ano

xia

Der

mat

itis

Yel

low

oily

liq

uid

wit

h a

anem

ia

Met

hem

oglo

bmem

ia i

n an

imal

s pu

ngen

t odo

r lik

e pa

ste

shoe

liv

er k

idne

y da

mag

e te

stic

ular

eff

ects

po

lish

[Not

e A

sol

id b

elow

42

F

Irri

tatio

n ey

es n

ose

thr

oat

Snee

zing

C

olor

less

to

whi

te c

ryst

allin

eco

ugh

Wea

knes

s a

nore

xia

Wei

ght

loss

so

lid w

ith a

ben

zene

-lik

eSw

eatin

g H

eada

che

Diz

zine

ss N

ause

aod

or

[fun

gici

de]

Vom

iting

D

yspn

ea c

hest

pai

n h

igh

feve

r D

erm

atiti

s

Der

mat

itis

Bro

nchi

tisC

arci

noge

n co

lorle

ss

mon

oclm

ic

crys

tals

C

onst

ituen

t in

coal

ta

r pi

tch

vola

tlles

C

oal

tar

is a

blac

k or

dar

k-br

own

amor

phou

s re

sidu

e

on C5C_

08

O 0) u HC3 ffi

V

9) a a a a 5 a a O

c o


3 C i SCL



-C 13

_C

-mdash

O

E

1 CL

u gtv

CL r ^^

O

Cnbull5g1su7H

1

laquogt 1 8 1

5 pound raquo

cbullj^

i s

^J rp

JH

o c CO

1 bullC

n

-shy

a J o Q

S

I sect e g So sLL o

en E c o i

Irrita

tion

eye

s n

ose

thro

at

lt W

eigh

t lo

ss

Wea

knes

s M

u-

dark

urin

e

Cya

nosi

s l

ive

r k

sk

in b

urns

D

erm

atit

is

oct

m

Convu

lsio

ns

I

witc

hin

g

S 5 u c 3 -1


VI CS srj J S





c

0 - 00 i~shyS S -a - 3 u O 81 1 shy


Phy

sica

l Des

crip

tion

Col

orle

ss t

o li

ght-

pin

kcr

ysta

lline

solid

with

a s

wee

t acr

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exp

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mill

igra

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carc

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nd

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Da

D

(A3)

3 (A3)

D(A4)

a D

aa

nn nnnnnaanannanan



VOC

Isophorone


Nitrobenzene

Phenol


11-DichIoroethene

12-Dichloroethane

12-Dichloropropane

Benzene

Bromoform

Bromomethane

4 ppm

LFC

1 ppm [skin]

5 ppm

1 ppm

LFC (Ippm

1 ppm

LFC (75ppm)

0 1 ppm

0 5 ppm [skin]

LFC(lppm[skm])

3 (A3)

D(A3) D(A4)

a (A3) a(A4)

3 (A4)



Chloroform 2 ppm

D




Notes

a






























VOC



ATTACHMENT B



DEFINITIONS







health effects



































employers attention


GeoTrans










HSI GeoTrans







AIR MONITORING













DECONTAMINATION











































all employees





consultation
















(2) EKG


(4) urinalysis

(5) blood profile







taken











SITE CONTROL


following
















































Accidents







Chemical Exposure













Cold Stress
























Heat Stress































(5) Acclimation

First Aid




































fatality


WATER SAFETY





















































confined space



ATTACHMENT C

















Emergency Overview


I o f 8 10199 1208 PM









2 of 8 10199 1208 PM










3 of 8 10199 1208 PM








4 of 8 10199 1208 PM












5 of 8 10199 1208 PM






Domestic (Land DOT)






6 of 8 10199 1208 PM
















7 of8 101991208 PM






8 of 8 10199 1208 PM




General Information








I o f 4 10199 212 PM











Health Hazard Data


2 of 4 10199 2 12 PM






Control Measures


Transportation Data


3 of 4 10199 212 PM




Disposal Data

Label Data


4 of4 10199 212 PM
















Emergency Overview


I o f 8 10199 12 17PM








2 of 8 10199 1217 PM











3 of 8 10199 1217PM







4 of 8 10199 1217 PM












5 of 8 10199 1217 PM






Domestic (Land DOT)








(7647-01-0) YesYes

Yes Yes

Yes Yes

Yes Yes


Ingredient

- Part 2shy

Korea--C



(7647-01-0) YesYes

Yes Yes

No No

Yes Yes



6 of 8 10199 12 17PM



Federal

Ingredient


CERCLA

shy Part 2 -RCRAshy

26133 -TSCAshy 8 (d )


(7647-01-0 ) 5000 No

No No

No No






7of8 10199 1217 PM




8 of 8 10199 1217PM




General Information






I o f 5 10199 1212 PM










2 of 5 10199 1212 PM










Reactivity Data


Health Hazard Data


3 of 5 10199 1212PM





Control Measures


Transportation Data


4 of 5 10199 1212 PM




Disposal Data

Label Data


5 of 5 10199 1212 PM


mdash



General Information








I o f 3 10199 1213PM

_ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _


Reactivity Data


Health Hazard Data




Control Measures


Transportation Data

= = == ====== = ==ss = == = = =

Disposal Data

2 of 3 10199 1213 PM


Label Data



3of3 10199 12 13PM




General Information









I o f 4 10199 1229PM



Reactivity Data


Health Hazard Data




Control Measures


2 of 4 10199 1229 PM



Transportation Data


Disposal Data = = = = = = = = 5= = = = ==

= = == = ===== = S3SSpound

Label Data



3of4 10199 12 29PM




4 of 4 10199 1229 PM




General Information








I o f 3 10199 207 PM



Reactivity Data


Health Hazard Data





Control Measures


2 of3 10199 207 PM



Transportation Data

Disposal Data = ===== = == = S5== ==

===============

Label Data


3 of 3 10199 207 PM

ATTACHMENT D

FIELD FORMS


TETRA TECH INC




E-mail


Name Office


Marital status




Street address


County






Witness(es)

Name

Address

Telephone








D None

Telephone No








Injured Employee











FormAR-l Page 2 of3

TETRA TECH INC



FormAR-1 Page 3 of3

b O

U1

c

CQ

t3

C ltu s pound o O

I O

C3 0)

_i w S j mdashshy

c u

O O

O Z 2

Q

CC o o

(U

03ltu

O

i i U

pound ab

is

sr a

Q U

degshy s a


s OH t4_ o

u

a 9 deg

o

gt^ -4mdashraquo

bull5

3 T3 C

3

I|

OS c 2

pi ^3 laquow y 1)

ll -4-

O

O -4mdashraquo

2 _bull -

oa ltu CD

3ltu H bulla

TETRA TECH INC







Chemical hazards

Physical hazards


Equipment hazards


Other






Attendees



Name Title

Signature


TETRA TECH INC


Project Name

Field Location

Project Manager

General Items


Project No

Completed by














Emergency Planning







Air Monitoring





In Compliance

Yes No NA

1






1 Splash suit



4 Gloves

5 Overboots

6 Hard hat

7 Dust mask


9 Respirator

Instrumentation


11 Oxygen meter


Supplies








Date


ft a u S |

Bar

omet

ric

Pre

ssur

e(u

nits

)

00 o

u -4mdash

ltu

-4mdashoo C

S 8 H mdash

B1) E T 1 i bullo

bull5 2

bullB L

bullo e

S 3 u

C

w

=

2

tJ

j-

C

^

a

k

iduc

tivi

ty

a X gC

E c bull3 X T3








CompanyOffice Date

Date



Site Information

Project Name Date


Project No


Space Preparation





Result


Oxygen-nun gt195

Oxygen-max lt235


HS lt10 ppm

Cl lt05 ppm

CO lt35 ppm

SO lt2 ppm

Heat degFdegC

Toxic (specify)

Other

Tester Initials


Signature of Tester

Notes




TETRA TECH INC


PROTECTIVE CLOTHING

Before use



- Imperfect seams


- Tears










bull Tears

bull Punctures



GLOVES

Before use


- Imperfect seams

Tears and abrasions





TETRA TECH INC


FOOTWEAR


bull Holes and cuts



bull Cracks in sole


EYEWEAR


bull Cracks

Fogginess

bull Scratches



HEADGEAR


Cracks or gouges



Page 2 of 2

TETRA TECH INC




Site name

Site address

City state and zip











Reviewed by Date




Proiec Name Task No




Site Descnotion











G Stream Y - N z G













ATTACHMENT E




Acton Massachusetts


















barcode 43196


appendix d health and safety plan w.r. grac ...2.2.3 task preparation/sop aps d2-12 p 2.2.4 ai...

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