appendix d - amazon simple storage...

Appendix D Task 1 and 2 Gas Composition and Methane Isotope Laboratory Analytical Reports

Task 1 Laboratory Analytical Results

®ISOTECH

i!1Sk- I

Isotech Laboratories, Inc. 1308 Parkland Court Champaign, IL 61821-1826 Telephone 217/398-3490 FAX 217/398-3493

August 23, 2007

Bryan GrigsbySS Papadolpulos & Associates1877 Broadway, Suite 703Boulder, CO 80303

Dear Bryan:

Enclosed are the analysis reports for the dissolved gas samples recently submitted from your project1101-M31ll Creek. These s31llples were assigned to Isotechjob numbers 8602 & 8636. These are thesame data that were emailed to you earlier. If you have any questions, or ifthere is anything else wecan do for you, please do not hesitate to contact us.

Thank you for choosing Isotech for your 311alysis needs, we appreciate your business.

Sincerely,

Steven R. PelphreyLaboratory Manager

Enclosure

SRP:cw

Gb'070823.doc

ANALYSIS REPORTJob #: 8636

Co. Lab#:

Lab #: 120768

Sample Name: 703866

Company: SS Papadopulos

Date Sampled: 7/12/2007

Container: Dissolved Gas Bottle

FieldlSite Name: Project 101 - Mamm Creek

Location: Garfield Colorado

Formation/Depth:

Sampling Point:

Date Received: 7/20/2007 Date Reported: 8/13/2007

Component

Carbon Monoxide -----------.

Hydrogen Sulfide ------------.

Helium -------------------------.

Hydrogen ----------------------

Argon ---------------------------

Oxygen ------------------------

Nitrogen -----------------------.

Carbon Dioxide --------------.

Methane -----------------------.

Ethane -------------------------.

Ethylene -----------------------.Propane u

Iso-butane --------------------N-butane ----------------------.

Iso-pentane -------------------.N-pentane --------------------

Hexanes + --------------------.

Chemical

mol. %

ndnd

nd

nd

1.57

4.84

82.31

11.22

0.0603

nd

ndnd

nd

nd

nd

nd

nd

Delta 13C

per mil

Delta 0

per mil

Delta 15N

per mil

Total BTU/cu.ft. dry @ 60deg F & 14.7psia, calculated:

Specific gravity, calculated: 1.042

Remarks: Analysis is of gas extracted from water by headspace equilibration. Analysis has been corrected forhelium added to create headspace. Helium dilution factor = 0.73

nd =not detected. na =not analyzed. Isotopic composition of carbon is relative to VPDB. Isotopiccomposition of hydrogen is relative to VSMOW. Calculations for BTU and specific gravity per ASTM03588. Chemical compositions are normalized to 100%. Mol. % is approximately equal to vol. %.Chemical analysis based on standards accurate to within 2%

(A) ISOTEC Laboratories, Inc. 1308 Parkland Ct. Champaign, IL 61821 217/398-3490

A ALYS S R PORTJob #: 8602

Co. Lab#:

Lab #: 119886

Sample Name: 703983




Field/Site Name: 1101 - Mam Creek

Location: Garfield County CO

Formation/Depth:

Sampling Point:


Component

Carbon Monoxide -----------


Helium -------------------------

Hydrogen ----------------------

Argon ---------------------------Oxygen n

Nitrogen -----------------------


Methane -----------------------.

Ethane -------------------------.

Ethylene -----------------------.Propane n

Iso-butane ---------------------N-butane n

Iso-pentane -------------------.

N-pentane --------------------

Hexanes + ---------------------

Chemical

mol. %

nd

nd

0.0613

nd

0.581

0.285

35.39

0.36

63.30

0.0211

nd

nd

nd

nd

nd

nd

nd

Delta 13C

per mil

-64.91

Delta D

per mil

-236.5

Delta 15N

per mil

Total BTU/cu.ft. dry @ 60deg F & 14.7psia, calculated:. 642


nd =not detected. na =not analyzed. Isotopic composition of carbon is relative to VPDB. Isotopiccomposition of hydrogen is relative to VSMOW. Calculations for BTU and specific gravity per ASTMD3588. Chemical compositions are normalized to 100%. Mol. % is approximately equal to vol. %.Chemical analysis based on standards accurate to within 2%

(A) ISOTEC Laboratories, Inc. 1308 Parkland Ct. Champaign, IL 61821 217/398-3490


Co. Lab#:

Lab #: 120767

Sample Name: 703996




Field/Site Name: Project 101 - Mamm Creek


Formation/Depth:

Sampling Point:


Component



Helium -------------------------

Hydrogen ----------------------

Argon ---------------------------

Oxygen ------------------------

Nitrogen -----------------------.


Methane -----------------------.

Ethane -------------------------

Ethylene -----------------------.

Propane -----------------------.

Iso-butane --------------------

N-butane ----------------------.

Iso-pentane -------------------.

N-pentane --------------------

Hexanes + ---------------------

Chemical

mol. %

nd

nd

nd

nd

0.686

0.0182

54.12

1.7243.10

0.348

nd

0.0014

0.0024

nd

nd

nd

nd

Delta 13C

per mil

-41.69

Delta D

per mil

-176.3

Delta 15N

per mil

Total BTU/cu.ft. dry @ 60deg F & 14.7psia, calculated: 443


Remarks: Analysis is of gas extracted from water by headspace equilibration. Analysis has been corrected forhelium added to create headspace. Helium dilution factor =0.29

nd =not detected. na =not analyzed. Isotopic composition of carbon is relative to VPDB. Isotopicc<," composition of hydrogen is relative to VSMOW. Calculations for BTU and specific gravity per ASTM

D3588. Chemical compositions are normalized to 100%. Mol. % is approximately equal to vol. %.Chemical analysis based on standards accurate to within 2%

(A] ISOTECH Laboratories, Inc. 1308 Parkland Ct. Champaign, IL 61821 217/398-3490

A ALYSIS E oJob #: 8602

Co. Lab#:

Lab #: 119889

Sample Name: 704023






Formation/Depth:

Sampling Point:


Component



Hel ium -------------------------

Hydrogen ----------------------

Argon ---------------------------

Oxygen ------------------------

Nitrogen -----------------------

Carbon Dioxide --------------

Methane -----------------------.

Ethane -------------------------

Ethylene -----------------------

Propane -----------------------

Iso-butane --------------------

N-butane ----------------------

Iso-pentane -------------------.

N-pentane --------------------

Hexanes + ---------------------

Chemical

mol. %

nd

nd

0.0164

nd

0.977

0.721

84.25

1.42

12.27

0.342

nd

0.0055

nd

nd

nd

nd

nd

Delta 13C

per mil

-36.97

Delta D

per mil

-119.6

Delta 15N

per mil



nd = not detected. na = not analyzed. Isotopic composition of carbon is relative to VPDB. Isotopiccomposition of hydrogen is relative to VSMOW. Calculations for BTU and specific gravity per ASTMD3588. Chemical compositions are normalized to 100%. Mol. % is approximately equal to vol. %.Chemical analysis based on standards accurate to within 2%

(A) ISOTECH Laboratories, Inc. 1308 Parkland Ct. Champaign,IL61821 217/398-3490

A A YS S RE oJob #: 8602

Co. Lab#:

Component

Lab #: 119885

Sample Name: 704050






Formation/Depth:

Sampling Point:

Date Received: 7/10/2007

Chemical

mol. %

Carbon Monoxide -----------. nd

Hydrogen Sulfide ------------. nd

Helium -------------------------. nd

Hydrogen ---------------------- nd

Argon --------------------------- 1.55

Oxygen ------------------------- 6.51

Nitrogen -----------------------. 78.02

Carbon Dioxide --------------. 12.40

Methane -----------------------. 1.52

Ethane -------------------------. nd

Ethylene -----------------------. ndPropane n nd

Iso-butane -----------7--------- nd

N-butane ----------------------- nd

Iso-pentane -------------------. nd

N-pentane --------------------- nd

Hexanes + --------------------. nd

Delta 13C

per mil

Date Reported:

Delta 0

per mil

8/13/2007

Delta 15N

per mil



Remarks: Analysis is of gas extracted from water by headspace equilibration. Analysis has been corrected forhelium added to create headspace. He dilution factor =0.65



ANALYSIS EPOJob #: 8602

Co. Lab#:

Lab #: 119891

Sample Name: 704073






Formation/Depth:

Sampling Point:


Component



Hel ium -------------------------Hydrogen ----------------------

Argon ---------------------------

Oxygen ------------------------

Nitrogen -----------------------


Methane -----------------------.

Ethane -------------------------.

Ethylene -----------------------.Propane n

Iso-butane ---------------------N-butane n

Iso-pentane -------------------.

N-pentane --------------------

Hexanes + ---------------------

Chemical

mol. %

0.065

nd

nd

nd

1.33

12.70

64.40

5.49

16.01

0.0085

nd

nd

nd

nd

nd

nd

nd

Delta 13C

per mil

-60.68

Delta D

per mil

-126.1

Delta 15N

per mil






A ALYSIS RE o TJob #: 8636

Co. Lab#:

Lab #: 120769

Sample Name: 704074




Field/Site Name: Project 101 - Mamm Creek


Formation/Depth:

Sampling Point:


Component Chemical

mol. %

Carbon Monoxide -----------. nd

Hydrogen Sulfide ------------. nd

Helium -------------------------- nd

Hydrogen ---------------------- nd

Argon --------------------------- 1.37

Oxygen ------------------------- 17.08

Nitrogen ------------------------ 73.80

Carbon Dioxide --------------. 7.75

Methane -----------------------. nd

Ethane -------------------------. nd

Ethylene -----------------------. nd

Propane ------------------------ nd

Iso-butane --------------------- nd

N-butane ----------------------- nd

Iso-pentane -------------------. nd

N-pentane --------------------- nd

Hexanes + --------------------- nd

Delta 13C

per mil

Delta D

per mil

Delta 15N

per mil







Co. Lab#:

Lab #: 120771

Sample Name: 704076




Field/Sit.e Name: Project 101 - Mamm Creek


Formation/Depth:

Sampling Point:


Component



Hel ium -------------------------Hydrogen ----------------------

Argon ---------------------------

Oxygen ------------------------

Nitrogen -----------------------


Methane -----------------------.

Ethane -------------------------

Ethylene -----------------------.

Propane -----------------------

Iso-butane --------------------

N-butane ----------------------

Iso-pentane -------------------.N-pentane --------------------

Hexanes + ---------------------

Chemical

mol. %

ndnd

nd

nd

1.19

7.29

68.90

2.94

19.68

nd

nd

nd

nd

nd

ndnd

nd

Delta 13C

per mil

-39.27

Delta D

per mil

-167.8

Delta 15N

per mil





(A] ISOTECH Laboratories, Inc. 1308 Parkland Ct. Champaign,IL61821 217/398-3490


Co. Lab#:

Lab #: 119890

Sample Name: 704151




FieldlSite Name: 1101 - Mam Creek


FormationlDepth:

Sampling Point:


Component

Carbon Monoxide m·

Hydrogen Sulfide m •

Hel ium m _

Hydrogen ----------------------

Argon ---------------------------Oxygen m n

Nitrogen -----------------------Carbon Dioxide --------------.Methane m m_.

Ethane m_.

Ethylene m m •

Propane n

Iso-butane ---------------------N-butane m _

Iso-pentane m •

N-pentane m _

Hexanes + m _

Chemical

mol. %

ndnd

0.0064

nd

0.525

0.673

31.92

1.07

65.80

0.0087

ndnd

nd

nd

ndnd

nd

Delta 13C

per mil

-40.99

Delta D

per mil

-182.6

Delta 15N

per mil




(A) ISOTECH Laboratories, Inc. 1308 Parkland Ct. Champaign, IL 61821 217/398-3490


Co. Lab#:

Lab #: 119888

Sample Name: 704330






Formation/Depth:

Sampling Point:


Component



Helium -------------------------

Hydrogen ----------------------

Argon ---------------------------Oxygen m

Nitrogen -----------------------


Methane -----------------------.

Ethane --------------------------Ethylene m.

Propane -----------------------

Iso-butane --------------------

N-butane ----------------------

Iso-pentane -------------------,

N-pentane --------------------

Hexanes + ---------------------

Chemical

mol. %

ndnd

0.0046

nd

0.0936

0.749

5.13

0.66

93.31

0.0483

nd

nd

nd

nd

nd

nd

nd

Delta 13C

per mil

-44.68

Delta 0

per mil

-203.5

Delta 15N

per mil




(A) ISOTECH Laboratories, Inc. 1308 Parkland Ct. Champaign,IL61821 217/398-3490

A A YS S RE ORJob #: 8602

Co. Lab#:

Lab #: 119887

Sample Name: 704332






Formation/Depth:

Sampling Point:


Component



Helium -------------------------

Hydrogen ----------------------

Argon ---------------------------

Oxygen ------------------------

Nitrogen -----------------------


Methane -----------------------.

Ethane -------------------------.

Ethylene -----------------------.

Propane -----------------------

Iso-butane --------------------

N-butane ----------------------

Iso-pentane -------------------.

N-pentane --------------------

Hexanes + ---------------------

Chemical

mol. %

0.063nd

nd

nd

1.57

5.46

83.73

9.18

nd

nd

nd

nd

nd

nd

nd

nd

nd

Delta 13C

per mil

Delta D

per mil

Delta 15N

per mil






ANALYSIS REPORT

Sample Name: 704534






Formation/Depth:

Sampling Point:

Date Received: 7/10/2007

Job #: 8602

Co. Lab#:

Lab#:

Component

119892

Chemical

mol. %

Delta 13C

per mil

Date Reported:

Delta D

per mil

8/13/2007

Delta 15N

per mil


Helium -------------------------- na

Hydrogen ---------------------- na

Argon --------------------------- na

Oxygen + Argon -------------.

Nitrogen -----------------------


Methane -----------------------.

Ethane -------------------------.

Ethylene -----------------------. na

Propane -----------------------

Iso-butane --------------------

N-butane -----------------------

Iso-pentane -------------------,

N-pentane --------------------

Hexanes + ---------------------

Total BTU/cu.ft. dry @ 60deg F & 14.7psia, calculated:

Specific gravity, calculated:

Remarks: sample on hold


(AJ ISOTECH Laboratories, Inc. 1308 Parkland Ct. Champaign, IL 61821 217/398-3490

Task 1 QA/QC

®

ISOTECH [email protected]

Isotech Laboratories, Inc. 1308 Parkland Court Champaign, IL 61821-1826 Telephone 217/398-3490 FAX 217/398-3493

December 12,2007

Bryan GrigsbySS Papadopulos3100 Arapahoe AveSuite 203Boulder CO 80303

J

Dear Bryan,

Enclosed is the hard copy analysis report for the gas sample submitted from project 1101in Garfield County. This sample was assigned to Isotech job number 8821. These are thesame data that were emailed to you earlier: this copy is for your records.

If you have any questions or if there is anything else we can do for you, please do nothesitate to contact us. Thank you for choosing Isotech for your analysis needs, weappreciate your business.

Sincerely,


Enclosure (1)

Gb071212.doc


Co. Lab#:

Lab #: 122946

Sample Name: 703866-A




Field/Site Name: 1101

Location: Garfield Co, CO

Formation/Depth:

Sampling Point:


Component

Carbon Monoxide u •


Helium -------------------------

Hydrogen ----------------------

Argon ---------------------------

Oxygen ------------------------

Nitrogen -----------------------


Methane -----------------------.

Ethane -------------------------

Ethylene -----------------------.

Propane -----------------------

Iso-butane --------------------

N-butane ----------------------

Iso-pentane -------------------.

N-pentane --------------------

Hexanes + ---------------------

Chemical

mol. %

0.028

nd

nd

nd

1.52

1.47

83.94

12.99

0.0508

nd

nd

nd

nd

nd

nd

nd

nd

Delta 13C

per mil

Delta D

per mil

Delta 15N

per mil





lAllSOTECH Laboratories, Inc. 1308 Parkland Ct. Champaign,IL61821 217/398-3490

Task 2 Laboratory Analytical Results

[email protected]

®

ECIsotech Laboratories, Inc. 1308 Parkland Court Champaign, IL 61821-1826 Telephone 217/398-3490 FAX 217/398-3493

January 18, 2008

Bryan GrigsbySS Papadopulos3100 Arapahoe AveSuite 203Boulder CO 80303

Dear Bryan,

Enclosed are the hard copy analysis reports for the gas samples from your proj ect 1101.These samples were assigned to Isotechjob number 9167. These are the same data thatwere emailed to you earlier.

We will hold the samples until 2/11108 in case you would want any additional analysescarried out, and will then dispose of the remaining sample material. If you need us tohold the samples longer, please contact us.

If you have any questions or ifthere is anything else we can do for you, please do nothesitate to contact us. Thank you for choosing Isotech for your analysis needs, weappreciate your business.

Sincerely,


Enclosures (4)

Gb080118.doc

ANALVSIS REPORT

Cylinder: 2037

Job #: 9167

Co. Lab#:

Lab #: 128639

Sample Name: 05-045-07155 (Boulton 10)



Container: 300 ml stainless

Field/Site Name: Project 1101

Location: Garfield County

Formation/Depth:

Sampling Point:


Component

Carbon Monoxide -----------.Hydrogen Sulfide mmmm.

Helium m _

Hydrogen m _

Argon u u

Oxygen mmmmmmumu

Nitrogen mmmummmm_

Carbon Dioxide m m.

Methane m •

Ethane m_m _

Ethylene m •

Propane m mm__ m _

Iso-butane --------------------N-butane ummmmumm_

Iso-pentane m m.

N-pentane mmmmmmm

Hexanes + mm _

Chemical

mol. %

ndnd

0.0053

0.0036

nd

nd

0.11

0.62

83.12

9.52

nd

4.02

0.859

0.890

0.291

0.226

0.331

Delta 13C

per mil

-41.67

Delta 0

per mil

-199.1

Delta 15N

per mil



nd =not detected. na =not analyzed. Isotopic composition of carbon is relative to VPDB. Isotopiccomposition of hydrogen is relative to VSMOW. Calculations for BTU and specific gravity per ASTM03588. Chemical compositions are normalized to 100%. Mol. % is approximately equal to vol. %.m Chemical analysis based on standards accurate to within 2%

l~ ISOTECH Laboratories, Inc. 1308 Parkland Ct. Champaign, IL 61821 217/398-3490

ANALYSIS REPORT

Cylinder: 2769

Job #: 9167

Co. Lab#:

Lab #: 128638

Sample Name: 05-045-09156 (Magnall)






Formation/Depth:

Sampling Point:


Component

Carbon Monoxide m_.


Helium --------------------------Hydrogen m _

Argon ---------------------------Oxygen m m _

Nitrogen m m_

Carbon Dioxide m •

Methane m __ m •

Ethane __mm •

Ethylene m •

Propane m __

Iso-butane ---------------------N-butane _m m_

Iso-pentane m _

N-pentane m m

Hexanes + ---------------------

Chemical

mol. %

ndnd

0.0047

0.0014

nd

0.00590.13

1.62

83.99

8.94

nd

3.43

0.704

0.689

0.197

0.131

0.155

Delta 13C

per mil

-41.80

Delta 0

per mil

-197.7

Delta 15N

per mil





ANALYSIS REPORT

Cylinder: 2006

Job #: 9167

Co. Lab#:

Lab #: 128636

Sample Name: 05-045-09462 (Magic)






Formation/Depth:

Sampling Point:


Component

Carbon Monoxide m •

Hydrogen Sulfide _mm •

HeIium n _

Hydrogen __ m _

Argon n _

Oxygen __ m m n_m__

Nitrogen _m __

Carbon Dioxide --------------.Methane m •

Ethane __ n n_n •

Ethylene m •

Propane -----------------------

Iso-butane ---------------------N-butane __ m _

Iso-pentane m m_.

N-pentane n m_n__

Hexanes + m __m_m_

Chemical

mol. %

ndnd

0.0055

nd

nd

0.0244

0.21

1.43

84.81

8.38

nd

3.00

0.667

0.680

0.237

0.184

0.369

Delta 13C

per mil

-41.49

Delta D

per mil

-195.5

Delta 15N

per mil





ANALYSIS REPORT

Cylinder: 2752

Job #: 9167

Co. Lab#:

Lab #: 128637

Sample Name: 05-045-13527 (Boulton)






Formation/Depth:

Sampling Point:


Component

Carbon Monoxide m •

Hydrogen Sulfide __ m •

Helium m _

Hydrogen __mm _

Argon ---------------------------Oxygen m __

Nitrogen m _

Carbon Dioxide m •

Methane mmm •

Ethane m m •

Ethylene -----------------------.Propane m _

Iso-butane m _

N-butane mmm _

Iso-pentane m •

N-pentane m m _

Hexanes + m mm.

Chemical

mol. %

ndnd

0.0040

0.0010

nd

nd

0.072

3.5084.30

7.22

nd

2.68

0.680

0.701

0.263

0.200

0.383

Delta 13C

per mil

-41.39

Delta 0

per mil

-191.6

Delta 15N

per mil



nd = not detected. na = not analyzed. Isotopic composition of carbon is relative to VPDB. Isotopiccomposition of hydrogen is relative to VSMOW. Calculations for BTU and specific gravity per ASTM03588. Chemical compositions are normalized to 100%. Mol. % is approximately equal to vol. %.Chemical analysis based on standards accurate to within 2%

lA)ISOTECH Laboratories, Inc. 1308 Parkland Ct. Champaign, IL 61821 217/398-3490

appendix d - amazon simple storage...

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