appendix 6 – spectra relevant to chapter 5...
TRANSCRIPT
Appendix 6 – Spectra Relevant to Chapter 5 400
APPENDIX 6
Spectra Relevant to Chapter 5
Appendix 6 – Spectra Relevant to Chapter 5 401
Figu
re A
6.1
1 H N
MR
(500
MH
z, C
DC
l 3) o
f com
poun
d 140a
.
OO
OEt
O
OH
140a
Appendix 6 – Spectra Relevant to Chapter 5 402
Figure A6.3 13C NMR (126 MHz, CDCl3) of compound 140a.
Figure A6.2 Infrared spectrum (Thin Film, NaCl) of compound 140a.
Appendix 6 – Spectra Relevant to Chapter 5 403
Figu
re A
6.4
1 H N
MR
(500
MH
z, C
DC
l 3) o
f com
poun
d 152.
O
OMe
O
152
Appendix 6 – Spectra Relevant to Chapter 5 404
Figure A6.6 13C NMR (126 MHz, CDCl3) of compound 152.
Figure A6.5 Infrared spectrum (Thin Film, NaCl) of compound 152.
Appendix 6 – Spectra Relevant to Chapter 5 405
Figu
re A
6.7
1 H N
MR
(500
MH
z, C
DC
l 3) o
f com
poun
d 140b
.
O
OH
O
140b
Appendix 6 – Spectra Relevant to Chapter 5 406
Figure A6.9 13C NMR (126 MHz, CDCl3) of compound 140b.
Figure A6.8 Infrared spectrum (Thin Film, NaCl) of compound 140b.
Appendix 6 – Spectra Relevant to Chapter 5 407
Figu
re A
6.10
1 H N
MR
(500
MH
z, C
DC
l 3) o
f com
poun
d 140c
.
O
OH
O
140c
Appendix 6 – Spectra Relevant to Chapter 5 408
Figure A6.12 13C NMR (126 MHz, CDCl3) of compound 140c.
Figure A6.11 Infrared spectrum (Thin Film, NaCl) of compound 140c.
Appendix 6 – Spectra Relevant to Chapter 5 409
Figu
re A
6.13
1 H N
MR
(500
MH
z, C
DC
l 3) o
f com
poun
d 140d
.
O
OH
O
140d
Appendix 6 – Spectra Relevant to Chapter 5 410
Figure A6.15 13C NMR (126 MHz, CDCl3) of compound 140d.
Figure A6.14 Infrared spectrum (Thin Film, NaCl) of compound 140d.
Appendix 6 – Spectra Relevant to Chapter 5 411
Figu
re A
6.16
1 H N
MR
(500
MH
z, C
DC
l 3) o
f com
poun
d 156.
OO
O CO2Me
156
Appendix 6 – Spectra Relevant to Chapter 5 412
Figure A6.18 13C NMR (126 MHz, CDCl3) of compound 156.
Figure A6.17 Infrared spectrum (Thin Film, NaCl) of compound 156.
Appendix 6 – Spectra Relevant to Chapter 5 413
Figu
re A
6.19
1 H N
MR
(500
MH
z, C
DC
l 3) o
f com
poun
d 157.
O
OMe
O
157
Appendix 6 – Spectra Relevant to Chapter 5 414
Figure A6.21 13C NMR (126 MHz, CDCl3) of compound 157.
Figure A6.20 Infrared spectrum (Thin Film, NaCl) of compound 157.
Appendix 6 – Spectra Relevant to Chapter 5 415
Figu
re A
6.22
1 H N
MR
(500
MH
z, C
DC
l 3) o
f com
poun
d 140e
.
O
OH
O
140e
Appendix 6 – Spectra Relevant to Chapter 5 416
Figure A6.24 13C NMR (126 MHz, CDCl3) of compound 140e.
Figure A6.23 Infrared spectrum (Thin Film, NaCl) of compound 140e.
Appendix 6 – Spectra Relevant to Chapter 5 417
Figu
re A
6.25
1 H N
MR
(400
MH
z, C
DC
l 3) o
f com
poun
d 140f
.
O
OH
O
140f
Appendix 6 – Spectra Relevant to Chapter 5 418
Figure A6.27 13C NMR (101 MHz, CDCl3) of compound 140f.
Figure A6.26 Infrared spectrum (Thin Film, NaCl) of compound 140f.
Appendix 6 – Spectra Relevant to Chapter 5 419
Figu
re A
6.28
1 H N
MR
(500
MH
z, C
DC
l 3) o
f com
poun
d 140g
.
On-Bu
O
CO2H
140g
Appendix 6 – Spectra Relevant to Chapter 5 420
Figure A6.30 13C NMR (126 MHz, CDCl3) of compound 140g.
Figure A6.29 Infrared spectrum (Thin Film, NaCl) of compound 140g.
Appendix 6 – Spectra Relevant to Chapter 5 421
Figu
re A
6.31
1 H N
MR
(500
MH
z, C
DC
l 3) o
f com
poun
d 140h
.
H
O
CO2H
140h
Appendix 6 – Spectra Relevant to Chapter 5 422
Figure A6.33 13C NMR (126 MHz, CDCl3) of compound 140h.
Figure A6.32 Infrared spectrum (Thin Film, NaCl) of compound 140h.
Appendix 6 – Spectra Relevant to Chapter 5 423
Figu
re A
6.34
1 H N
MR
(500
MH
z, C
DC
l 3) o
f com
poun
d 140i
.
H
HH
OAc
HO
O
O140i
Appendix 6 – Spectra Relevant to Chapter 5 424
Figure A6.36 13C NMR (126 MHz, CDCl3) of compound 140i.
Figure A6.35 Infrared spectrum (Thin Film, NaCl) of compound 140i.
Appendix 6 – Spectra Relevant to Chapter 5 425
Figu
re A
6.37
1 H N
MR
(500
MH
z, C
DC
l 3) o
f com
poun
d 141a
.
OO
OEt
141a
Appendix 6 – Spectra Relevant to Chapter 5 426
Figure A6.39 13C NMR (126 MHz, CDCl3) of compound 141a.
Figure A6.38 Infrared spectrum (Thin Film, NaCl) of compound 141a.
Appendix 6 – Spectra Relevant to Chapter 5 427
Figu
re A
6.40
1 H N
MR
(500
MH
z, C
DC
l 3) o
f com
poun
d 142.
O
O
OEt
O142
Appendix 6 – Spectra Relevant to Chapter 5 428
Figure A6.42 13C NMR (126 MHz, CDCl3) of compound 142.
Figure A6.41 Infrared spectrum (Thin Film, NaCl) of compound 142.
Appendix 6 – Spectra Relevant to Chapter 5 429
Figu
re A
6.43
1 H N
MR
(500
MH
z, C
DC
l 3) o
f com
poun
d 139.
O ent-139
Appendix 6 – Spectra Relevant to Chapter 5 430
Figure A6.45 13C NMR (126 MHz, CDCl3) of compound 139.
Figure A6.44 Infrared spectrum (Thin Film, NaCl) of compound 139.
Appendix 6 – Spectra Relevant to Chapter 5 431
Figu
re A
6.46
1 H N
MR
(500
MH
z, C
DC
l 3) o
f com
poun
d 141c
.
O 141c
Appendix 6 – Spectra Relevant to Chapter 5 432
Figure A6.48 13C NMR (126 MHz, CDCl3) of compound 141c.
Figure A6.47 Infrared spectrum (Thin Film, NaCl) of compound 141c.
Appendix 6 – Spectra Relevant to Chapter 5 433
Figu
re A
6.49
1 H N
MR
(500
MH
z, C
DC
l 3) o
f com
poun
d 141d
.
O 141d
Appendix 6 – Spectra Relevant to Chapter 5 434
Figure A6.51 13C NMR (126 MHz, CDCl3) of compound 141d.
Figure A6.50 Infrared spectrum (Thin Film, NaCl) of compound 141d.
Appendix 6 – Spectra Relevant to Chapter 5 435
Figu
re A
6.52
1 H N
MR
(500
MH
z, C
DC
l 3) o
f com
poun
d 141e
.
O 141e
Appendix 6 – Spectra Relevant to Chapter 5 436
Figure A6.54 13C NMR (126 MHz, CDCl3) of compound 141e.
Figure A6.53 Infrared spectrum (Thin Film, NaCl) of compound 141e.
Appendix 6 – Spectra Relevant to Chapter 5 437
Figu
re A
6.55
1 H N
MR
(500
MH
z, C
DC
l 3) o
f com
poun
d 141f
.
O
141f
Appendix 6 – Spectra Relevant to Chapter 5 438
Figure A6.57 13C NMR (126 MHz, CDCl3) of compound 141f.
Figure A6.56 Infrared spectrum (Thin Film, NaCl) of compound 141f.
Appendix 6 – Spectra Relevant to Chapter 5 439
Figu
re A
6.58
1 H N
MR
(500
MH
z, C
DC
l 3) o
f com
poun
d 141g
.
On-Bu
O
141g
Appendix 6 – Spectra Relevant to Chapter 5 440
Figure A6.60 13C NMR (126 MHz, CDCl3) of compound 141g.
Figure A6.59 Infrared spectrum (Thin Film, NaCl) of compound 141g.
Appendix 6 – Spectra Relevant to Chapter 5 441
Figu
re A
6.61
1 H N
MR
(500
MH
z, C
DC
l 3) o
f com
poun
d 141h
.
H
O
141h
Appendix 6 – Spectra Relevant to Chapter 5 442
Figure A6.63 13C NMR (126 MHz, CDCl3) of compound 141h.
Figure A6.62 Infrared spectrum (Thin Film, NaCl) of compound 141h.
Appendix 6 – Spectra Relevant to Chapter 5 443
Figu
re A
6.64
1 H N
MR
(500
MH
z, C
DC
l 3) o
f com
poun
d 141i
.
H
HH
OAc
O141i
Appendix 6 – Spectra Relevant to Chapter 5 444
Figure A6.66 13C NMR (126 MHz, CDCl3) of compound 141i.
Figure A6.65 Infrared spectrum (Thin Film, NaCl) of compound 141i.
Appendix 6 – Spectra Relevant to Chapter 5 445
Figu
re A
6.67
1 H N
MR
(500
MH
z, C
DC
l 3) o
f com
poun
d 162.
OMe
162
CO2Et
Appendix 6 – Spectra Relevant to Chapter 5 446
Figure A6.69 13C NMR (126 MHz, CDCl3) of compound 162.
Figure A6.68 Infrared spectrum (Thin Film, NaCl) of compound 162.
Appendix 6 – Spectra Relevant to Chapter 5 447
Figu
re A
6.70
1 H N
MR
(500
MH
z, C
DC
l 3) o
f com
poun
d 147.
OMe
147
CO2Et
Appendix 6 – Spectra Relevant to Chapter 5 448
Figure A6.72 13C NMR (126 MHz, CDCl3) of compound 147.
Figure A6.71 Infrared spectrum (Thin Film, NaCl) of compound 147.
Appendix 6 – Spectra Relevant to Chapter 5 449
Figu
re A
6.73
1 H N
MR
(500
MH
z, C
DC
l 3) o
f com
poun
d 145.
OMe
145
O
Appendix 6 – Spectra Relevant to Chapter 5 450
Figure A6.75 13C NMR (126 MHz, CDCl3) of compound 145.
Figure A6.74 Infrared spectrum (Thin Film, NaCl) of compound 145.
Appendix 6 – Spectra Relevant to Chapter 5 451
Figu
re A
6.76
1 H N
MR
(500
MH
z, C
DC
l 3) o
f com
poun
d 148.
OMe
148
OO
O
Appendix 6 – Spectra Relevant to Chapter 5 452
Figure A6.78 13C NMR (126 MHz, CDCl3) of compound 148.
Figure A6.77 Infrared spectrum (Thin Film, NaCl) of compound 148.
Appendix 6 – Spectra Relevant to Chapter 5 453
Figu
re A
6.79
1 H N
MR
(500
MH
z, C
DC
l 3) o
f com
poun
d 144.
OMeO
144
Appendix 6 – Spectra Relevant to Chapter 5 454
Figure A6.81 13C NMR (126 MHz, CDCl3) of compound 144.
Figure A6.80 Infrared spectrum (Thin Film, NaCl) of compound 144.
Appendix 6 – Spectra Relevant to Chapter 5 455
Figu
re A
6.82
1 H N
MR
(500
MH
z, C
DC
l 3) o
f com
poun
d 143.
OMe
143
O
OH
O
Appendix 6 – Spectra Relevant to Chapter 5 456
Figure A6.84 13C NMR (126 MHz, CDCl3) of compound 143.
Figure A6.83 Infrared spectrum (Thin Film, NaCl) of compound 143.
Appendix 6 – Spectra Relevant to Chapter 5 457
Figu
re A
6.85
1 H N
MR
(500
MH
z, C
DC
l 3) o
f com
poun
d 149.
OMe
149
O
Appendix 6 – Spectra Relevant to Chapter 5 458
Figure A6.87 13C NMR (126 MHz, CDCl3) of compound 149.
Figure A6.86 Infrared spectrum (Thin Film, NaCl) of compound 149.
Appendix 6 – Spectra Relevant to Chapter 5 459
Figu
re A
6.88
1 H N
MR
(500
MH
z, C
DC
l 3) o
f com
poun
d 133.
OHO
(–)-A
spew
entin
B (1
33)
Appendix 6 – Spectra Relevant to Chapter 5 460
Figure A6.90 13C NMR (126 MHz, CDCl3) of compound 133.
Figure A6.89 Infrared spectrum (Thin Film, NaCl) of compound 133.
Appendix 6 – Spectra Relevant to Chapter 5 461
Figu
re A
6.91
1 H N
MR
(500
MH
z, C
DC
l 3) o
f com
poun
d 133A
.
OH
(–)-A
spew
entin
B (1
33A
)
Appendix 6 – Spectra Relevant to Chapter 5 462
Figure A6.93 13C NMR (126 MHz, CDCl3) of compound 133A.
Figure A6.92 Infrared spectrum (Thin Film, NaCl) of compound 133A.
Appendix 6 – Spectra Relevant to Chapter 5 463
Figu
re A
6.94
1 H N
MR
(500
MH
z, C
DC
l 3) o
f com
poun
d 163.
OHO
163
Appendix 6 – Spectra Relevant to Chapter 5 464
Figure A6.96 13C NMR (126 MHz, CDCl3) of compound 163.
Figure A6.95 Infrared spectrum (Thin Film, NaCl) of compound 163.
Appendix 6 – Spectra Relevant to Chapter 5 465
Figu
re A
6.97
1 H N
MR
(500
MH
z, C
DC
l 3) o
f com
poun
d 164.
OMe
164
O
Appendix 6 – Spectra Relevant to Chapter 5 466
Figure A6.99 13C NMR (126 MHz, CDCl3) of compound 164.
Figure A6.98 Infrared spectrum (Thin Film, NaCl) of compound 164.
Appendix 6 – Spectra Relevant to Chapter 5 467
Figu
re A
6.10
0 1 H
NM
R (5
00 M
Hz,
CD
Cl 3)
of c
ompo
und 165.
OHO
165
Appendix 6 – Spectra Relevant to Chapter 5 468
Figure A6.102 13C NMR (126 MHz, CDCl3) of compound 165.
Figure A6.101 Infrared spectrum (Thin Film, NaCl) of compound 165.