an experimental optimization study on a tube-in-shell latent heat storage
TRANSCRIPT
![Page 1: An experimental optimization study on a tube-in-shell latent heat storage](https://reader031.vdocuments.us/reader031/viewer/2022020402/575004701a28ab11489ec261/html5/thumbnails/1.jpg)
INTERNATIONAL JOURNAL OF ENERGY RESEARCHInt. J. Energy Res. 2007; 31:274–287Published online 9 August 2006 in Wiley InterScience(www.interscience.wiley.com) DOI: 10.1002/er.1249
An experimental optimization study on a tube-in-shell latentheat storage
Orhan Aydın1,*,y, Mithat Akgun1 and Kamil Kaygusuz2
1Department of Mechanical Engineering, Karadeniz Technical University, 61080 Trabzon, Turkey2Department of Chemistry, Karadeniz Technical University, 61080 Trabzon, Turkey
SUMMARY
Thermal energy storage (TES) using phase change materials (PCMs) has recently received considerableattention in the literature, due to its high storage capacity and isothermal behaviour during the storage(melting or charging) and removal (discharging or solidification). In this study, a novel modification on atube-in-shell-type storage geometry is suggested. In the proposed geometry, the outer surface of the shell isinclined and it is the objective of this study to determine the optimum range for the inclination angle of theshell surface. Paraffin with a melting temperature of 58.068C, which is supplied by the Merck Company, isused as the PCM. The PCM is stored in the vertical annular space between an inner tube through which theheat transfer fluid (HTF), hot water, is flowing and a concentrically placed outer shell. At first, thethermophysical properties of this paraffin are determined through the differential scanning calorimeter(DSC) analysis. Temporal behaviour of the PCM undergoing a non-isothermal solid–liquid phase changeduring its melting or charging by the HTF are determined for different values of the inlet temperature andthe mass flow rate of the HTF. The new geometry is shown to respond well with the melting characteristicsof the PCM and to enhance heat transfer inside the PCM for a specific range of the shell inclination angle.Copyright # 2006 John Wiley & Sons, Ltd.
KEY WORDS: PCM; paraffin; thermal energy storage; melting; charging; tube-in-shell geometry
1. INTRODUCTION
Thermal energy storage (TES) has recently become popular as an energy saving method toconserve available energy and to improve its utilization overcoming the imbalance betweenenergy supply or availability and demand through the implementation of a proper energystorage system. Of various thermal energy storage methods, the latent heat thermal energy
*Correspondence to: Orhan Aydın, Department of Mechanical Engineering, Karadeniz Technical University, 61080Trabzon, Turkey.yE-mail: [email protected]
Contract/grant sponsor: Karadeniz Technical University Research Fund; contract/grant numbers: 2001.112.3.2,2002.111.002.4
Received 25 March 2006Revised 20 June 2006Accepted 2 July 2006Copyright # 2006 John Wiley & Sons, Ltd.
![Page 2: An experimental optimization study on a tube-in-shell latent heat storage](https://reader031.vdocuments.us/reader031/viewer/2022020402/575004701a28ab11489ec261/html5/thumbnails/2.jpg)
storage (LHTES) employing phase change material (PCM) has been widely noticed as aneffective way due to its advantages of high energy storage density (i.e. low volume/energy ratio)and its isothermal operating characteristics (i.e. charging/discharging heat at a nearly constanttemperature) during solidification and melting processes, which is desirable for efficientoperation of thermal systems. In a latent heat storage system, energy is stored during meltingand recovered during solidification of a PCM. The use of the latent heat of a PCM as a thermalenergy storage medium has gained considerable attention recently by finding applications inconservation of energy and natural resources, recovery and use of waste industrial energy, spacecraft, refrigeration and air conditioning systems, solar energy systems, heating and cooling ofbuildings, etc. However, practical difficulties usually arise in applying the latent heat methoddue to the low thermal conductivity, density change, stability of properties under extendedcycling, and sometimes phase segregation and subcooling of the PCMs. During the last 20 years,PCM for storing energy have developed rapidly. Their thermal and physical properties such aslong-term stability and durability have been improved a lot.
A number of studies have been performed to examine the overall thermal behaviour andperformance of various LHTES systems in recent years. These studies focused on the melting/freezing problem of the PCM and on the convective heat transfer problem of the heat transferfluid (HTF) used to store (melting) and/or retrieve energy (solidification) from the unit. Readersare referred to see the excellent reference books by Lane (1983), Garg et al. (1985), and Dincerand Rosen (2002) on the topic to have a better view on the studies existing in the literature. Also,some of the review articles are mentioned in the following: Abhat (1983) and Hasnain (1998)presented a review on sustainable thermal energy storage technologies in terms of heat storagematerials and techniques. Faith (1998) assessed solar thermal energy storage technologies. Zalbaet al. (2003) presented a review of the history of thermal energy storage with solid–liquid phasechange focusing on three aspects; materials, heat transfer and applications. Ettouney et al.(2004) studied heat transfer enhancement by use of metal screens/spheres placed inside the PCMin double pipe energy storage system. A paraffin wax is used as the PCM. Farid et al. (2004)reviewed previous work on latent heat storage and provided an insight to recent efforts todevelop new classes of PCMs for use in energy storage focusing his review on PCM materials,encapsulation and applications. Recently, Sharma and Sagara (2005) presented a detailed reviewon latent heat storage materials and systems.
Paraffin wax is an attractive material for heat storage applications. High latent heat storagecapacities over a narrow temperature range can be obtained and these PCM’s are ecologicallyharmless and non-toxic. Paraffin waxes are cheap and have moderate thermal energy storagedensity but low thermal conductivity and, hence, require large surface area. The normalparaffins of type CnH2nþ2 are a family of saturated hydrocarbons with very similar properties.Paraffins between C5 and C15 are liquids, and the rest are waxy solids. Paraffin wax is the most-used commercial organic heat storage PCM (Garg et al., 1985). It consists of mainly straightchain hydrocarbons that have melting temperatures ranging from 23 to 678C (Abhat, 1983).Commercial-grade paraffin wax is obtained from petroleum distillation and is not a puresubstance, but a combination of different hydrocarbons. In general, the longer the averagelength of the hydrocarbon chain, the higher the melting temperature and heat of fusion (Himranet al., 1994). Paraffins are easily available from many manufacturers and are usually lessexpensive than some salt hydrates. Recently, several works have been carried out in order tostudy the thermal characteristics of paraffins during solidification and melting processes (Banuet al., 1998; Velraj et al., 1999; Cho and Choi, 2000; Hong and Xin-Shi, 2000; Enibe, 2002;
TUBE-IN-SHELL LATENT HEAT STORAGE 275
Copyright # 2006 John Wiley & Sons, Ltd. Int. J. Energy Res. 2007; 31:274–287
DOI: 10.1002/er
![Page 3: An experimental optimization study on a tube-in-shell latent heat storage](https://reader031.vdocuments.us/reader031/viewer/2022020402/575004701a28ab11489ec261/html5/thumbnails/3.jpg)
He and Setterwall, 2002; Sharma et al., 2002; Sarı, 2004; Trp, 2005). Their studies show thatcommercial-grade paraffin wax and other pure paraffins have stable properties after 1000–2000cycles. Paraffin wax did not show regular degradation in thermal properties after repeatedmelting/freezing cycles. Paraffin waxes are safe and non-reactive. They are compatible with allmetal containers and easily incorporated into heat storage systems. Care should be taken whenusing plastic containers as paraffins have a tendency to infiltrate and soften some plastics.
In this study, we aimed at experimentally investigating a novel tube-in-shell-type storagegeometry for PCMs. The storage geometry is constructed as the annular space between a tubethrough which the HTF (water) is flowing and a conical shell. Both the tube and the shell areplaced concentrically. The surface of the shell, conical, is motivated by the structure of themelting behaviour of the PCM in the annular space between a tube and an outer concentricallyplaced shell. Optimum angle of the shell is defined following the determination of the thermalperformance of the PCM during the melting process for each angle.
2. EXPERIMENTAL STUDY
2.1. Heat storage material
In the present study, paraffin (P1, C26H54) supplied from the Merck Company is used as a latentheat energy storage material. Paraffin is an attractive, chemically stable and non-toxic materialwithout regular degradation and it has high latent heat storage capacities over a narrowtemperature range. In terms of the thermal energy storage capacity, the latent heat storagecapacity, the melting point temperature and the density are the important parameters, whosevalues are shown to be 250 kJ kg�1, 58.068C and 880 kgm�3, respectively, by a differentialscanning calorimeter (DSC) technique for the PCM under study.
2.2. Experimental apparatus and procedure
A general view of the experimental set-up designed is shown in Figure 1. It mainly consists of aconstant-temperature water bath, a circulation pump, the PCM storage container, HTF tube,T-type thermocouples wiring, data acquisition unit, and a PC for data analysis. Water is used asthe HTF. The PCM is kept in the annular space between an inner tube and a concentricallyplaced outer shell. The tube is made of the copper while the outer shell is made of the stainlesssteel. Five different values for the inclination angles of the shell are examined in the study:f ¼ 08; 58, 108, 158 and 208. The PCM container is filled with paraffin. As it is shown, the hotwater flows from the constant-temperature bath to the HTF tube. The hot water releases itssensible heat to the PCM. The cooler water is routed back to the water bath. The constant-temperature water bath controlling the inlet temperature of the HTF has a temperature range of20–1708C with accuracy of � 0.18C. The unit can deliver up to 0.5 kg s�1 of hot water.A detailed view of the test section with the locations where the thermocouples are inserted isshown in Figure 2. Thermocouple wires are used to measure the temperature field in the PCM.All the thermocouples are calibrated before use and they are observed to have a measuringrange of �10 to 2008C and an accuracy of � 0.28C. A number of thermocouples are distributedin an order in the PCM (see Figure 2). The placement of the thermocouples for eachmeasurement has been tabulated in Table I. Other temperature measurements include the inlet/outlet HTF temperatures and the ambient temperature. A 32-channel data logger is used to
O. AYDIN, M. AKGUN AND K. KAYGUSUZ276
Copyright # 2006 John Wiley & Sons, Ltd. Int. J. Energy Res. 2007; 31:274–287
DOI: 10.1002/er
![Page 4: An experimental optimization study on a tube-in-shell latent heat storage](https://reader031.vdocuments.us/reader031/viewer/2022020402/575004701a28ab11489ec261/html5/thumbnails/4.jpg)
collect the temperature measurements. It stores the entire temperature set once every minute.The experimental data are simultaneously transferred to a PC. The flow rate is measured by arotameter with a degree of calibration within � 1% accuracy. The charging process is startedby flowing the hot water through the HTF tube. This process is assumed to finish when all thetemperature recordings in the PCM region present higher values than the melting temperatureof the PCM. No sooner does the charging process end than the stored energy is extracted bypassing the cold water. The charging and discharging processes are run for different mass flowrates and the inlet temperatures of the water. For the charging or melting experiments, the inlettemperatures of the water are prescribed at values higher than the melting temperature of thePCM, while setting them to lower temperatures for discharging or solidification processes.
3. RESULTS AND DISCUSSION
Charging (i.e. melting) and discharging (i.e. freezing) characteristics of the paraffin are examinedby conducting the experiments described above. Experiments are repeated for the five differentvalues of the inclination angle of the shell, which are: f ¼ 08; 58, 108, 158 and 208. Theexperiments are performed for different inlet temperatures and mass flow rates of the HTF,water. For brevity, only the results of the charging experiments are included. Four differentvalues for the inlet temperature of the water have been tested, which are all set to be above themelting temperature of the paraffin under consideration: Tg ¼ 70; 75, 80 and 858C. Threedifferent values of the flow rate of water are examined: ’m ¼ 4; 6 and 8 kgmin�1.
118
109
7
6
5
4
3
2
1
Cold water inlet
a
b
c
i
f
j
keh
dg
Figure 1. Schematic representation of the experimental set-up.
TUBE-IN-SHELL LATENT HEAT STORAGE 277
Copyright # 2006 John Wiley & Sons, Ltd. Int. J. Energy Res. 2007; 31:274–287
DOI: 10.1002/er
![Page 5: An experimental optimization study on a tube-in-shell latent heat storage](https://reader031.vdocuments.us/reader031/viewer/2022020402/575004701a28ab11489ec261/html5/thumbnails/5.jpg)
At all times, the temperature field presented a symmetric shape around the HTF tube. Figure 3shows typical transients of the temperatures at different points given in Figure 2 for Tg ¼ 858Cand ’m ¼ 8 kgmin�1 for each value of the shell inclination angle. The other values of Tg and ’msuggest similar results. As inferred from the changes of the temperature at different points bytime, melting starts in the below region close to the inner wall and, in the following, moltenPCM ascends to the top part of the PCM container as a result of natural convection boundarylayers existing near the tube wall. Then, two regions coexist during the charging processes,which are the melted PCM region in the liquid phase and the non-melted PCM region in thesolid phase. In the solid region, the conduction inside the solid matrix of the PCM is responsiblefor the heat transfer process inside and this region receives heat from the melted part byconvection. When the solid melts or in the melt region, convection mechanism of the heattransfer drives the recirculation inside the melted the PCM, which is due to the buoyancy forces
rmax
rmax
Ø
Ø28
PCM container
PCMs
PCMI
Tir
z
Tr,z
Tr,z
Tr,z
14
14 14 14 14
Z5
Z4
Z3
Z2
Z1
2
3
4
5
1
0
Zm
ax
To
copper HTF pipe
inlet HTF (hot water)
Figure 2. Temperature measurements points inside the PCM.
O. AYDIN, M. AKGUN AND K. KAYGUSUZ278
Copyright # 2006 John Wiley & Sons, Ltd. Int. J. Energy Res. 2007; 31:274–287
DOI: 10.1002/er
![Page 6: An experimental optimization study on a tube-in-shell latent heat storage](https://reader031.vdocuments.us/reader031/viewer/2022020402/575004701a28ab11489ec261/html5/thumbnails/6.jpg)
TableI.
Theplacementofthethermocouples.
1r m
ax
r min¼
r 0r 1
r 2r 3
r 4r 5
ZmaxZ1
Z2
Z3
Z4
Z5
08
47,3
47,3
47,3
47,3
47,3
47,3
47,3
Tr,z
T14,0,T28,0,T14,100,T28,100,T14,200,T28,200,T14,300,T28,300,
T14,400,T28,400,
T14,421,T28,421,
T42,0,T46,0
T42,100,T46,100
T42,200,T46,200
T42,300,T46,300
T42,400,T46,400
T42,421,T46,421
465
100200300400421
58
66,7
28
36,7
45,5
54,2
63
67T14,445,T28,445,
T14,200,T28,200,T14,300,T28,300,
T14,400,T28,400,
T42,445,T56,445,
Tr,z
T14,0,T28,0
T14,100,T28,100,
T36,100
T42,200
T42,300,T53,300
T42,400,T56,400,T62,445T65,445
465
100200300400445
10888,3
28
45,6
63,3
80,9
T14,200,T28,200,T14,300,T28,300,
T42,300,
Tr,z
T14,0,T28,0
T14,100,T28,100,
T42,100
T42,200,T61,200
T56,300,T70,300,
T77,300
325
100200300
15896,1
28
54,8
81,6
89,6
T14,100,T28,100,T14,200,T28,200,T14,230,T28,230,T42,230,
Tr,z
T14,0,T28,0
T42,100,T50,100
T42,200,T77,200
T56,230,T70,230,T84,230
254
100200230
208104
28
64,4
100,8
T14,200,T28,200,
T42,200,
T14,100,T28,100,
T42,100,
T56,100,T70,200,
T84,200,
Tr,z
T14,0,T28,0
T56,100,T61,100
T98,200
210
100200
TUBE-IN-SHELL LATENT HEAT STORAGE 279
Copyright # 2006 John Wiley & Sons, Ltd. Int. J. Energy Res. 2007; 31:274–287
DOI: 10.1002/er
![Page 7: An experimental optimization study on a tube-in-shell latent heat storage](https://reader031.vdocuments.us/reader031/viewer/2022020402/575004701a28ab11489ec261/html5/thumbnails/7.jpg)
30
40
50
60
70
80
0 60 120 180
Time, t (min)
0 60 120 180
Time, t (min)
0 60 120 180
Time, t (min)
0 60 120 180
Time, t (min)
0 60 120 180
Time, t (min)
0 60 120 180
Time, t (min)
Tem
per
ature
, T
(°C
)T
emper
ature
, T
(°C
)
20
30
40
50
60
70
80T14,100
T28,100
T36,100
z = 100 mm
Tem
per
ature
, T
(°C
)
T14,0
T28,0
z = 0 mm
20
30
40
50
60
70
80
90
Tem
per
ature
, T
(°C
)
20
30
40
50
60
70
80
90
Tem
per
ature
, T
(°C
)
20
30
40
50
60
70
80
90
Tem
per
ature
, T
(°C
)
20
30
40
50
60
70
80
90T14,200
T28,200
T42,200
z = 200 mm
T14,300
T28,300
T42,300
T53,300
z = 300 mm
T14,400
T28,400,T42,400,T56,400,T62,400
z = 400 mm
T14,445
T28,445,T42,445, T56,445, T65,445
z = 445 mm
(a)
Figure 3. Temporal variations of temperature during melting at some typical points for different values ofthe shell inclination angle: (a) f=08; (b) f=58; (c) f=108; (d) f=158; and (e) f=208.
O. AYDIN, M. AKGUN AND K. KAYGUSUZ280
Copyright # 2006 John Wiley & Sons, Ltd. Int. J. Energy Res. 2007; 31:274–287
DOI: 10.1002/er
![Page 8: An experimental optimization study on a tube-in-shell latent heat storage](https://reader031.vdocuments.us/reader031/viewer/2022020402/575004701a28ab11489ec261/html5/thumbnails/8.jpg)
induced by the density gradients as a result of temperature differences. This recirculation insideenhances mixing and heat transfer within the molten PCM, which can be explained by the factthat the points near the upper part reach higher temperatures than the lower points. Note that
20
30
40
50
60
70
80T14,100
T28,100
T36,100
z = 100 mm
30
40
50
60
70
80
0 60 120 180
Time, t (min)
0 60 120 180
Time, t (min)
0 60 120 180
Time, t (min)
0 60 120 180
Time, t (min)
0 60 120 180
Time, t (min)
0 60 120 180
Time, t (min)
T14,0
T28,0
z = 0 mm
20
30
40
50
60
70
80
90T14,200
T28,200
T42,200
z = 200 mm
T14,300
T28,300
T42,300
T53,300
z = 300 mm
T14,400
T28,400,T42,400,T56,400,T62,400
z = 400 mm
T14,445
T28,445,T42,445, T56,445, T65,445
z = 445 mm
Tem
per
ature
, T
(°C
)T
emper
ature
, T
(°C
)
20
30
40
50
60
70
80
90
Tem
per
ature
, T
(°C
)
20
30
40
50
60
70
80
90
Tem
per
ature
, T
(°C
)
20
30
40
50
60
70
80
90
Tem
per
ature
, T
(°C
)T
emper
ature
, T
(°C
)
(b)
Figure 3. Continued.
TUBE-IN-SHELL LATENT HEAT STORAGE 281
Copyright # 2006 John Wiley & Sons, Ltd. Int. J. Energy Res. 2007; 31:274–287
DOI: 10.1002/er
![Page 9: An experimental optimization study on a tube-in-shell latent heat storage](https://reader031.vdocuments.us/reader031/viewer/2022020402/575004701a28ab11489ec261/html5/thumbnails/9.jpg)
the density of the molten PCM is lower than that in the PCM in the solid phase. At largeroperating times, the region of the molten PCM extends to cover larger regions of the PCMcontainer. The PCM located near the lower/outer regions of the PCM tube remains solid, evenfor large operating times. This is because the amount of input energy at these conditions is notsufficient to achieve complete melting of the PCM. As can be seen from the figure, the storagegeometry with a 5o of the shell inclination angle suggested the lowest melting times. However, atthis point, we should remember the energy balance between the HTF and PCM at the tube wall,which is
Q
t¼ hADTlm
where Q and t represent the amount of heat stored by the PCM and the time, respectively, h isthe convective heat transfer coefficient of the HTF, A is the inner surface area of the HTF tubeand DTlm is the logarithmic mean temperature. From this energy balance, we see that
Melting time � 1=ðHeat transfer areaÞ
20
30
40
50
60
70
80
0 60 120 180
Time, t (min)
0 60 120 180
Time, t (min)
0 60 120 180
Time, t (min)
0 60 120 180
Time, t (min)
z = 0 mm
T14,0
T28,0
z =100 mm
T14,100
T28,100
T42,100
20
30
40
50
60
70
80
90T14,200
T28,200
T42,200,T61,200
z =200 mm
T14,300
T28,300,T42,300,T56,300
T70,300,T77,300
z =300 mm
Tem
per
ature
, T
(°C
)T
emper
ature
, T
(°C
)
20
30
40
50
60
70
80
90
Tem
per
ature
, T
(°C
)
20
30
40
50
60
70
80
Tem
per
ature
, T
(°C
)
(c)
Figure 3. Continued.
O. AYDIN, M. AKGUN AND K. KAYGUSUZ282
Copyright # 2006 John Wiley & Sons, Ltd. Int. J. Energy Res. 2007; 31:274–287
DOI: 10.1002/er
![Page 10: An experimental optimization study on a tube-in-shell latent heat storage](https://reader031.vdocuments.us/reader031/viewer/2022020402/575004701a28ab11489ec261/html5/thumbnails/10.jpg)
or in notational form
t�1
2pr0L
For a constant value of r0; the above correlation states that
t�1
Lð1Þ
As seen, the melting time is inversely proportional to the height of the PCM storage container.Here, it should be emphasized again, we keep the PCM mass and the radius of the HTF tubeconstant for each experiment using a different shell inclination angle. For the shell inclinationangles of 08 and 58, we use the same value of L, L¼ 465 mm: When we compare the meltingtimes for these two angles, we see that 08 requires higher times than 58 does. For example, fromthe T28,0�t variation for these two angles (see Figures 3(a) and (b)), we see that melting time is240min for 08, while it is 140min for 58. This indicates that the storage geometry with the shellinclination angle of 08 is superior to that of 58, suggesting about a 40% decrease in the total
20
30
40
50
60
70
80
0 60 120 180 240Time, t (min)
0 60 120 180 240Time, t (min)
0 60 120 180 240Time, t (min)
0 60 120 180 240Time, t (min)
T14,0
T28,0
z = 0 mm
10
20
30
40
50
60
70
80
T28,100, T42,100, T50,100
T14,100
z =100 mm
10
20
30
40
50
60
70
80
90T14,200
T28,200, T42, 200, T77,200
z = 200 mm
T14,230
T28,230,T42,230,T56,200,T70,230,T84,230
z = 230 mm
Tem
per
ature
, T
(°C
)T
emper
ature
, T
(°C
)
10
20
30
40
50
60
70
80
90
Tem
per
ature
, T
(°C
)T
emper
ature
, T
(°C
)
(d)
Figure 3. Continued.
TUBE-IN-SHELL LATENT HEAT STORAGE 283
Copyright # 2006 John Wiley & Sons, Ltd. Int. J. Energy Res. 2007; 31:274–287
DOI: 10.1002/er
![Page 11: An experimental optimization study on a tube-in-shell latent heat storage](https://reader031.vdocuments.us/reader031/viewer/2022020402/575004701a28ab11489ec261/html5/thumbnails/11.jpg)
melting time. Note such an enhancement is obtained without any extra costs (the same values ofthe total mass of the PCM, the storage volume, the convective heat transfer coefficient of theHTF, the inlet temperature and mass of the HTF). For the other values of the shell inclinationangle, the height of the geometry is different to that given for of 08 and 58. Since the height of thestorage geometry is different (see Table I), the melting times for 108, 158 and 208 cannot becompared with those for 08 and 58. However, assigning a proportionality constant for therelation given in Equation (1) using the values of 58, we can predict the melting times for theother shell inclination angles, 108, 158 and 208. As a result, we predict the melting times as 215,274 and 332min for 108, 158 and 208, respectively. For 108 and 158, these extrapolation valuesare consistent with those obtained (see Figures 3(c) and (d)). But for 208, the extrapolation valueunderestimates the measured value. From these results, we can conclude that lower meltingtimes or better performance are obtained in the range of 5–158 of the shell inclination angle thanthat either for 08 or for 208.
With an increase in Tg, the solidification will require smaller times at any point considered.The higher the inlet temperature is, the higher the heat transfer rates are as a result of increasing
20
30
40
50
60
70
80
0 60 120 180 240 300 360 420 480
Time, t (min)
0 60 120 180 240 300 360 420 480
Time, t (min)
Time, t (min)
Tem
pera
ture
, T (
˚C)
Tem
pera
ture
, T (
˚C)
20
30
40
50
60
70
80
Tem
pera
ture
, T (
˚C)
T14,0
T28,0
0 60 120 180 240 300 360 420 480
T 14,100
T28,100,T42,100,T56,100,T64,100
z = 100 mm
20
30
40
50
60
70
T14,200,T28,200,T42,200,T56,200, T70,200,T84,200,T98,200
z = 200 mm
(e)
Figure 3. Continued.
O. AYDIN, M. AKGUN AND K. KAYGUSUZ284
Copyright # 2006 John Wiley & Sons, Ltd. Int. J. Energy Res. 2007; 31:274–287
DOI: 10.1002/er
![Page 12: An experimental optimization study on a tube-in-shell latent heat storage](https://reader031.vdocuments.us/reader031/viewer/2022020402/575004701a28ab11489ec261/html5/thumbnails/12.jpg)
temperature differences between the inner wall of the storage container and the bulk of theflowing HTF, water. The effect of the inlet temperature of the water on the time variation of thetemperature of the PCM at some representative points for the inclination angle of 108 isillustrated in Figure 4 at ’m ¼ 8 kg min�1: At each point, increasing inlet temperatures of theHTF lead to smaller melting times and gives more enthalpy flow from the HTF into the PCM.As observed, an increase in the HTF inlet temperature results in higher temperature gradientnear the HTF tube. This gradient diminishes by the increasing melting time.
Figure 5 shows the effect of the mass flow rate of the HTF on the temporal variation oftemperature for the inclination angle of 108 at Tg¼ 858C: As seen from the figure, the influenceof the mass flow rate of the HTF on the melting time at that point is negligible. The fact thathigher mass flow rates require higher pumping powers will result in choosing the lower valuesfor an energy-efficient thermal energy storage process.
4. CONCLUSIONS
In this experimental study, a novel modification on a tube-in-shell-type storage geometry hasbeen proposed in which the outer surface of the shell is inclined. Temporal behaviour of thePCM, paraffin, undergoing a non-isothermal solid–liquid phase change during its melting orcharging by the HTF, hot water, has been determined for different values of the inlettemperature and the mass flow rate of the HTF. The new geometry has been shown to respondwell with the melting characteristics of the PCM and to enhance heat transfer inside the PCM
20
30
40
50
60
70
0 60 120 180 240 300 360 420 480 540 600Time, t(min)
0 60 120 180 240 300 360 420 480 540 600Time, t(min)
Tem
pera
ture
,T (
˚C)
Tem
pera
ture
,T (
˚C)
Tem
pera
ture
,T (
˚C)
Ti = 85˚C, 80˚C, 75˚C, 70˚C
Ti = 85˚C, 80˚C, 75˚C, 70˚C
T28,0T42, 100
Ti = 85˚C, 80˚C, 75˚C, 70˚C
T70, 300
20
30
40
50
60
70
80
20
30
40
50
60
70
80
0 60 120 180 240 300 360 420Time, t (min)
Figure 4. Effect of the inlet temperature of HTF on the temporal variations of temperaturefor f ¼ 108 and ’m ¼ 8 kgmin�1:
TUBE-IN-SHELL LATENT HEAT STORAGE 285
Copyright # 2006 John Wiley & Sons, Ltd. Int. J. Energy Res. 2007; 31:274–287
DOI: 10.1002/er
![Page 13: An experimental optimization study on a tube-in-shell latent heat storage](https://reader031.vdocuments.us/reader031/viewer/2022020402/575004701a28ab11489ec261/html5/thumbnails/13.jpg)
for a specific range of the shell inclination angle. From these results, it has been concluded thatlower melting times or better performance could be obtained in the range of 5–158 of the shellinclination angle than that either for 08 or for 208.
ACKNOWLEDGEMENTS
The authors greatly acknowledge the financial support of this work by the Karadeniz Technical UniversityResearch Fund under Grant No. 2001.112.3.2 and 2002.111.002.4.
REFERENCES
Abhat A. 1983. Low temperature latent heat thermal energy storage: heat storage materials. Solar Energy 30:313–332.Banu D, Feldman D, Hawes D. 1998. Evaluation of thermal storage as latent heat in phase change material wallboard
by differential scanning calorimeter and large scale thermal testing. Thermochica Acta 317:39–45.Cho K, Choi SH. 2000. Thermal characteristics of paraffin in a spherical capsule during freezing and melting processes.
International Journal of Heat and Mass Transfer 43:3183–3196.Dincer I, Rosen MA. 2002. Thermal Energy Storage, Systems and Applications. Wiley: New York.Enibe SO. 2002. Performance of a natural circulation solar air heating system with phase change material energy storage.
Renewable Energy 27:69–86.
10
20
30
40
50
60
70
80
0 60 120 180 240 300
Time, t(min) Time, t(min)
Tem
per
ature
, T
(°C
)
Tem
per
ature
, T
(°C
)
8 kg/min, 6 kg/min, 4 kg/min
8 kg/min, 6 kg/min, 4 kg/min
8 kg/min, 6 kg/min, 4 kg/min
T50,100 T77,200
T84,230
20
30
40
50
60
70
80
Tem
per
ature
, T
(°C
)
20
30
40
50
60
70
80
0 60 120 180 240
Time, t(min)
0 60 120 180 240
Figure 5. Effect of the inlet mass flow rate of HTF on the temporal variations of temperaturefor f ¼ 108 and Tg¼ 858C:
O. AYDIN, M. AKGUN AND K. KAYGUSUZ286
Copyright # 2006 John Wiley & Sons, Ltd. Int. J. Energy Res. 2007; 31:274–287
DOI: 10.1002/er
![Page 14: An experimental optimization study on a tube-in-shell latent heat storage](https://reader031.vdocuments.us/reader031/viewer/2022020402/575004701a28ab11489ec261/html5/thumbnails/14.jpg)
Ettouney HM, Alatigi I, Al-Sahali M, Al-Ali SA. 2004. Heat transfer enhancement by metal screens and metal spheres inphase change energy storage systems. Renewable Energy 29:841–860.
Faith HE. 1998. Technical assessment of solar thermal energy storage technologies. Renewable Energy 14:35–40.Farid MM, Khudhair AM, Razack SAK, Al-Hallaj A. 2004. A review on phase change energy storage materials and
applications. Energy Conversation and Management 45:1597–1615.Garg HP, Mullick SC, Bhargava AK. 1985. Solar Thermal Energy Storage. D. Reidel Publishing Company: Dordrecht.Hasnain SM. 1998. Review on sustainable thermal energy storage technologies. Part I: heat storage materials and
techniques. Energy Conversion Management 39:1127–1138.He B, Setterwall F. 2002. Technical grade paraffin waxes as phase change materials for cool thermal storage and cool
storage systems capital cost estimation. Energy Conversion and Management 43:1709–1723.Himran S, Suwono A, Mansori GA. 1994. Characterization of alkanes and paraffin waxes for application as phase
change energy storage medium. Energy Sources 16:117–128.Hong Y, Xin-Shi G. 2000. Preparation of polyethylene-paraffin compound as a form-stable solid–liquid phase change
material. Solar Energy Materials and Solar Cells 64:37–44.Lane GA. 1983. Solar Heat Storage: Latent Heat Materials, vol. I. CRC Press: Boca Raton.Sarı A. 2004. Form-stable paraffin/high density polyethylene composites as solid–liquid phase change material for
thermal energy storage: preparation and thermal properties. Energy Conversion and Management 45:2033–2042.Sharma SD, Sagara K. 2005. Latent heat storage materials and systems: a review, International Journal of Green Energy
2:1–56.Sharma A, Sharma SD, Buddhi D. 2002. Accelerated thermal cycle test of acetamide, stearic acid and paraffin wax for
solar thermal latent heat storage applications. Energy Conversion and Management 43:1923–1930.Trp A. 2005. An experimental and numerical investigation of heat transfer during technical grade paraffin melting and
solidification in a shell-and-tube latent thermal energy storage unit. Solar Energy 79:648–660.Velraj R, Seeniraj RV, Hafner B, Faber C, Schwarzer K. 1999. Heat transfer enhancement in a latent heat storage
system. Solar Energy 65:171–180.Zalba B, Marin JM, Cabeza LF, Mehling H. 2003. Review on thermal energy storage with phase change: materials, heat
transfer analysis and applications. Applied Thermal Engineering 23:251–283.
TUBE-IN-SHELL LATENT HEAT STORAGE 287
Copyright # 2006 John Wiley & Sons, Ltd. Int. J. Energy Res. 2007; 31:274–287
DOI: 10.1002/er