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The Periodic Table
The Periodic TableElements
Why is the Periodic Table important to me?
• The periodic table is the most useful tool to a chemist.
• You get to use it on every test.
• It organizes lots of information about all the known elements.
Pre-Periodic Table Chemistry …
• …was a mess!!!• No organization of
elements.• Imagine going to a grocery
store with no organization!!• Difficult to find information.• Chemistry didn’t make
sense.
Discovery of Elements
• Science has come along way since Aristotle’s theory of Air, Water, Fire, and Earth.
• Scientists have identified 90 naturally occurring elements, and created about 28 others.
The most abundant element in the earth’s crust is oxygen.
Dmitri Mendeleev: Father of the Table
HOW HIS WORKED…• Put elements in rows by
increasing atomic weight.• Put elements in columns
by the way they reacted.
SOME PROBLEMS…• He left blank spaces for
what he said were undiscovered elements. (Turned out he was right!)
• He broke the pattern of increasing atomic weight to keep similar reacting elements together.
The Current Periodic Table• Mendeleev wasn’t too far off.
•Now the elements are put in rows by increasing
ATOMIC NUMBER!!• The horizontal rows are called periods and are
labeled from 1 to 7.• The vertical columns are called (families) groups are
labeled from 1 to 18.
Families • Columns of elements are called groups or families. • Elements in each family have similar but not identical
properties.• For example, lithium (Li), sodium (Na), potassium (K),
and other members of family IA are all soft, white, shiny metals.
• All elements in a family have the same number of valence electrons.
Periods
• Each horizontal row of elements is called a period.• The elements in a period are not alike in properties.• In fact, the properties change greatly across even given
row.• The first element in a period is always an extremely
active solid. The last element in a period, is always an inactive gas.
Groups…Here’s Where the Periodic Table Gets Useful!!• Elements in the
same group have similar chemical and physical properties!!
• (Mendeleev did that on purpose.)
Why??• They have the same
number of valence electrons.
• They will form the same kinds of ions.
Families on the Periodic Table
• Columns are groups of families.
• Families may be one column, or several columns put together.
• Families have names rather than numbers. (Just like your family has a common last name.)
Vocabulary used to explain metals.Malleable = can be pounded into thin sheets
Ductile = can be drawn out into a thin wire
Lustrous: Shiny Brittle: hard but easy to break.
Hydrogen • Hydrogen belongs to a family of its own.
• Hydrogen is a diatomic, reactive gas.• Hydrogen was involved in the
explosion of the Hindenberg.• Hydrogen is promising as an
alternative fuel source for automobiles• Hydrogen bomb
Alkali Metals
• 1st column on the periodic table (Group 1) not including hydrogen.
• Most reactive metals, always combined with something else in nature (like in salt).
• Soft enough to cut with a butter knife
• They react violently with water.
What does it mean to be reactive?– An incomplete valence electron level.– All atoms (except hydrogen) want to
have 8 electrons in their very outermost energy level (This is
called the rule of octet.)– Atoms bond until this level is
complete. Atoms with few valence electrons lose them during bonding. Atoms with 6, 7, or 8 valence electrons gain electrons during bonding.
Alkaline Earth Metals
• Second column on the periodic table. (Group 2)
• Reactive metals that are always combined with nonmetals in nature.
• Several of these elements are important mineral nutrients (such as Mg and Ca
Transition Metals
• Elements in groups 3-12• Less reactive harder metals• Includes metals used in jewelry and
construction.• Metals used “as metal.”
Metalloids “The Ladder”Properties between metals and nonmetals
Sometimes lose and sometimes gain electrons
Ex: Si appears lustrous, is brittle, not malleable or ductile. Poorer conductor of heat and electricity than metals.
Useful in the semiconductor industry.
Gases• Boron Family• Carbon Family• Nitrogen Family• Oxygen Family• Halogens• Noble Gases
Boron Family
• Elements in group 13• Aluminum metal was once
rare and expensive, not a “disposable metal.”
Carbon Family• Elements in group 14• Contains elements important to life
and computers.• Carbon is the basis for an entire
branch of chemistry.• Silicon and Germanium are
important semiconductors.
Nitrogen Family• Elements in group 15• Nitrogen makes up over ¾
of the atmosphere.• Nitrogen and phosphorus
are both important in living things.
• Most of the world’s nitrogen is not available to living things.
• The red stuff on the tip of matches is phosphorus.
Oxygen Family or Chalcogens• Elements in group 16• Oxygen is necessary for
respiration and combustion.• Many things that stink, contain
sulfur (rotten eggs, garlic, skunks,etc.)
Halogens
• Elements in group 17• Very reactive, volatile,
diatomic, nonmetals• Always found combined
with other element in nature .
• Used as disinfectants and to strengthen teeth.
The Noble Gases
• Elements in group 18• VERY unreactive,
monatomic gases• Used in lighted “neon”
signs• Used in blimps to fix the
Hindenberg problem.• Have a full valence
shell.
Lanthanide and Actinide series.• The 30 rare earth
elements are composed of the lanthanide and actinide series.
• One element of the lanthanide series and most of the elements in the actinide series are called trans-uranium, which means synthetic or man-made.
Periodic Trends
• Atomic Radii• Electronegativity• Ionization Energy• Electron Affinity
Atomic Radii(Radius)Increase
down group
Decrease across period
ElectronegativityType of Measure
Ability of an atom to attract electrons– Dec. down
group (electron shielding)
– Inc. across period
Ionization Energy
Amount of energy needed to remove an electron– Inc. across
period– Dec. down group
(electron shielding)
Electron Affinity
Amount of energy released when an electron is added to a neutral atom.
Periodic Trends1. Rank the following elements by increasing atomic radius:
C, Al, O, K.2. Rank the following elements by increasing electronegativity:
S, O, Ne, Al.3. What is the difference between electron affinity and ionization
energy?
4. Why does fluorine have a higher ionization energy than iodine?
5. Why do elements in the same family generally have similar
properties?
O, C, Al, K
Al, S,O,Ne
EA. Ability to attract electrons and I.E.energy to remove electron
Fluorine is located above the Iodine in the column.
They have identical number of electrons in their outermost shell.
Matter
• All matter is composed of atoms and groups of atoms bonded together, called molecules.– Substances that are made from one type of atom only are
called pure substances. Can not be separated chemically or physically.
– Substances that are made from more than one or more than one type of atom bonded together are called compounds. Can be separated by chemical means only.
– Compounds that are combined physically, but not chemically, are called mixtures. Can be separated.
Elements, Compounds, Mixtures
• Sodium(Na+) an element.• Chlorine (Cl-) is an element.• When sodium and chlorine bond they make the
compound sodium chloride(NaCl), commonly known as table salt.
Salt is a compound.
Ocean is a mixture
Elements, compounds, and mixtures
• Mixtures can be separated by physical means.• Compounds can only be separated by chemical
means.• Elements are pure substances. When the
subatomic particles of an element are separated from its atom, it no longer retains the properties of that element.
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