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r j r i d ' j . l p : - . NJ 0 7 o 6 9 :: :) r.
• • . y ^ ^ ^ g f n
N.J DEP C e r t i f i e d D r i n k i n s Ua t e r / U a e t c^j j t e r ^
L a t o r a t c i r y I D ! 1 1 1 1 a : ' / .
US EPf t C o n t r a c t L a b o r a t o r y _ _ ; V'
SDMS Document
68215
t ANALYTICAL CATA REPORT PACKAGE FOR.' •y^r*^'.-•^^•^*-*:•*•|y*•i^•fr•^r*-fr•^!-k•k•**•fr-A * * * * * * * * • ^ • * - k * - k * * * * * * * * * * * * * * * * * * - f , - k * * * * * * * * * * * * * - ' t - A * - k * * - ^ - i , - » r 4 r *
EARTH TtrCHNOLOGY CORf'ORATION
Stapling Machine
August 1. 1989 I
h J r • * • • ^ - ^ - l f • * : • ^ : • ^ • k • l r * * • ^ • • ^ - ^ * * • • ^ * * * * * • * * * * * * • J r * * * • ^ * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * - ) t * * - i ^
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_._Ji'i.6.!:.,£.... QE. ...C.QP(I£NI.S..„..
£.aae_*. O.-jti M;3n33c->Tri£nt Sarrinsiry i Lab/Client ID Cross Reference 2 Q'? 1 i V»? r. i b 1 c s C h e c; k i i'-, t 3 Field Chain-of-Custody 4 - 5 LjbOiVjtory Cha i n--of-Castod ie-s 6 - 15 Laboratory Chronicles 16 No nco nf or:T:3nce Summary 23 - 25 Methodology Summaries 26 - 29 S3n;plf? Results: SMC-MU-1-2 Lab #103438 30 SMC-MU-2-2 Lab #103439 46 SMC-MU-3-2 Lab #103440 54 SMC-MU-4-2 Lab #103441 64 SMC-MU-5-2 Lab #103442 74 SMC-F8-2 Lab #103443 34 SMC-TB-2 Lab #103444 94
Q'jality Assurance Oata; Volatiles Aqueous 9 7 - 1 1 2
Quality Assurance 03ta: Semivolatiles Aqueous 113 - 124
Quality Assurance Data; Petroleum Hydrocarbons Aqueous 125 - 126
Quality Assurance Data: General Analytical Aqueous 53
I i o \ O !
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INDUSTRIAL CORROSION MANAGEMENT INCORPORATED
t t S t m n E N k M N O U K I K W X I H E T e r t M 10«-«M41N
DATA SUMMARY REPORT; E^TH TECHNOLOGY CORPORATION - STAPLING MACHINE
The following sutniarises those parameters and their corresponding concentrations found in the aamples submitted.
SAMPLE ID
PARAMETERS i WLWItES: 'dt0-yi^ 1,1-Dlchloroethene (ppb) '*'* f V;
•• .''-H y ' i / i . .
Trlchloroethene (ppb) '•
Bencene (ppb) • ' • .y,- ' \ 'g^A
Toluene (ppb)
Chlorobentene (ppb)
pH (standard units)
t m TOO iMH
' S H C -MM-1-2
22
19
15
2.1
16
13
7.27
SMC-MW-2-2
6.51
SMC-MW-3-2
6.42
SMC-MW-4-2
7.35
'.'.f.-.i
SMC-MW-5-2
6.85
•^4Hy
Srtt-FB-2
6.74
SMfc-TB-2
NA
B-Analyte found in blank J*Identtfled at value 1 than detection limit; value is estimated
. •. • »
•• •' i -^f^^ 'n , • • • j - . i^yy. •..: v - M *
1 i ; :i >• g u 113 1 0
Pando l(r!> , NJ 07869 .::-M-'53-1-v?:?0 AMGUSr 1, 1989
•M^mp NJ OEP Certifie.i Drink in<J Ua t er/U ast r-.-j t,--Laboratory ID* i'l U 6 3 US EPA Contrii.it Laboratorv
AK'ALVriCA-L '.'ATA REPORT PACKAGE FGHi
C 1 i i - r . t :
•? i::t.;> 1 >? ':; ;) U T'C e
I'^ciirif ] c d \ i y :
EARTH T E C H K ' O L O G Y CORPORATION
STAPLING nACHIN!-;: CUSTOMIf.R
SAMPLE. ID:
SMC-MU-1-2 SMC-?';U!-2-2 SMC-KU-3-2 Si'(C-KU~4-2 SMC-MU-^.-2 SMC-F.'5-2 SMC-TB-:>
MATRIX
U-^TER UATER UATER WATER UATER UATER UATER
LAB NUMBER
103438 103439 103440 103441 103442 103443 103444
DATE *. TIME
COLLECTED
06/23/89 0 6 / 2 3 / 3 9 06/23/89 06/23/99 06/23/89 06/23/99 06/23/89
13: 14 12; 14 15i 12i
; 10 •y30
;45 ;50 !l0 ;30
AT LAS DATE
06/23/89 06/23/89 06/23/S9 06/23/39 06/23/39 06/23/S? 06/23/89
S u p e r v i s o r / M a n a g e r S i g n a t u r e :
C o p y r i g h t ICM, I r i c , 19S6. A l l r i s h t s r e s e r v e d . TS
.1 O O
00
,' • ' ^ ' ' • ^ . " • ' ' • ^ • T ^ ' ^ ^ ^ - ^
INDUSTRIAL CORROSION NANACENENT 1152 Route 10 Randolpii, New Jersey 07869 210-584-0330
The Earth Technology Corporation 53 Haddonfield Road. Suite 316 Cherry Hill, Nev Jersey 08002
Re: Stapling Machine - Base/Neutral Surrogate Recovery
To Whoa it Nay Concern:
Two of the Three BN surrogates added to SHC-MW 5-2 saaple (our lab • 103442) for the Base/Neutral analysis did not recover to within QC liaits. The recoveries were as follows:
Nitrohenxene-ds 2 33 - 141 2-Piuorobiphenyl 25 43 - 116
As the saaple appeared to have only ainiaal aatrix interference, it iSf suspected that the poor surrogate recoveries are due to laboratory |. error. Possible causes are technician error in adding the surrogates^' or error when concentrating the extract.
I hope that this error will not cause yon any difficulties. If you have any further questions, please do not hesitate to call.
Sincere ly , ICM Laboratories
Edwina B. Cariat i Quali ty Assurance Supervisor
EBC/ks
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LABORATORY DELIVERABLES
THIS FORM MUST BE COMPLETED BY THE LABORATORY OR ENVIRONMENTAL CONSULTANT AND ACCOMPANY ALL DATA SUBMISSIONS
The following laboratory deliverables shall be included in the data submission. All'deviations from the accepted methodology and procedures, or performance values outside acceptable ranges shall be summarized in - the Non-Conformance Summary. Attachment 2 of the Draft ECRA Sampling Plan Guide (ESPG) provides further details to be followed. The document shall be bound and paginated, contain a table of contents, and all pages shall be legible. Incomplete packages will be returned or held without review until the data package is completed.
Check if Complete
I.
II.
III.
IV.
V.
VI.
VII.
VIII.
IX.
X.
Cover Page, Format, and Laboratory Certlflcatiea (Include Cross Reference Table cf Field I.D. # and Laboratory I.D. #)
Chain of Custody
Summary Sheets Listing Analytical Results Including QA Data Information (see Attached Fora and ESPG Attachment 2.B.2.C.)
Laboratory Chronicle and Hethodolofy
Suonary including Sampling Holding Tiae Check
Initlal Calibration and Continuing Calibration
Tuna Suanary (MS)
Blanks (Mathod, Fiald. Trip)
SurrogAt* Kacovazy Suaaazy
Chroaatofra^w Laballad/Coopound Identification
(flidiiai Oiti^t^ Liaits (Lower thaa Action Level If CifiBtiZdiM:<8iiiipl« - and consistent vith aethod l iidUiiliUiM)'.", ,....
X
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Nm-Coiifonaiica Suaaary
or Environaental Consultant'4 Signatuze
Date iX
W
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I PROJECT NAME
I COLLECTED BY
IheearthUBehnologu tHV Capomtion Qhain of Custody Record
SriETYPE SITE 10 PROJECT NO
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D TER I V T I E R II a NO(4-TIER
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SAMPUNO POINT « SAMPLING METHOD DESCRIPTION
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SAMPLE MATERIAL
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ORQANIZATION DATE A TIME
RECEIVED BY (•Ignatur*) ORGANIZATION
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Sampling Equtpment Custody Record
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Client: "ETy^CrK Vexz-\\r\ n
Address:
n-Pro jec t Manager: l , p ^ r \ v^
iPro jec t ID : < ;A - ^ ^ V y \ ( X J > V ;
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City/State: _Zip:
Phone#: { )
£ia. >^,£^
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Soil Water
Parameter Bottle Order
Field Blank: . vt*,;'^"*-'
Parameter
BXT
Trip Blank; J^^TT
Sample Bottles were: ¥'1 |.V<^ 'Delivered by ICM
U ^ M I P'cked-up by client
I I Shipped UPS/ Fed. Express
Bottle Order
.^ j42e£LA sMt-
Sample Containers i i A Sample Containers Relinquished by ICM: >-*^i^ye>io la.eJuU-> Received by
Date: U f - u ^ l ^ ^ T l m : ^ ' . 3 ^
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SIGNATURE IDENTIFICATIOM FOB IM-HOOSE CHAIN-OF-CDSTODIEg
WtJiS.
Abbaye, Daniel
Baron, Mary
Bek
B
SICWATVRE UIIIIAI.&
ekuretsion, Cubssa pUet^jLtR,^.*^*.. yM .ji./1_
erberiaa, Barbara / ifej U S.o /^^^a^K-y^.
fVffOUAtA ,' Bijowski, Malgorsata Ko/^
Blank, Robert
Cariati, Edwins CcLuyvit^- O . L^^r\JL»XX.
Cowell, KristlB _
Crotty, Michael l u h c ^ A M J . ^
Eberly, Daniel
Gbebreyesus, Habteab
Harvey, Sarab
Heller, Sbaron
Hof, Philip
Holt, Sodica
Jercsyaski, Hallns
Kadakla. Geeta
Koleno, Paals
Kusterer, Jeaaac
Lao, Snyi'
Mancnso, Thoass
Nartinei, Jose
McElbenny, Colleea
Mebari, Sebhatu ^r^^jtrrrwT^o^
z \ ^ ^
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H 6
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/UC
< s ^ ȣ. -to ^
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SICNATOBE IDENTIFICATIOM FOB IM-HOUSB CHATM-OF-COSTODIES
(CQNTIHygB)
^vvv»caw.\A^ i e c in ska , Ell«ah«th Qri.(Ay^^i./vw»geL
t. Oebra <kjb<lfth-
NAME
Morsch, Cathie
Norton, Kiaberly
Peters, Catbsrine
Pies, Sangeeta
Poai
Pos
Price, Elizabeth
Bei, Aaabela
Biccio, Mark
Bicbardsoa, Snsaa
Bldlngs, Audrey
Biagwelski, Eva
Boberts, S. David
Santana, Illnaiaada
Sarsony, Kenneth
Strojnovska, Isshella
Thorp, Carla
Wachal, Btati
Oboh* Aaroit-w V
Selengut t' Jeffrey
SICNATOBE
• ^ ^ . ^ ^
- ^
CQiAft AnKft^p
Shields-Baker, Celeste
Norman, Dorothy
Drinka, Anna
SC
JL ea
l£s
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CXt>- l i . o o
14
SIGNATURE IDENTIFICATION FOR IN-HOUSE CHAIN-OF-CUSTODIES
(CONTINUED)
NAME ^ SIGNATURE INITIALS
Maedel, Lynne > A ^ 1 U U L / ( - J y C M ^ ^ ' ^ ry^fgC---
Tesfaghiorghls, Teoane_
Otey, Margo Mann. Dudley ^ ^ ^ ^ " T h ^ Q ^/^
Rollerson, Wlla
1 5
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ON
:tii'i NJ DEP Certified Drinking Wacer/WasCftwater ""Pr^i^
• y ».'i Wji •"..,a.*«i
Laboratory 1D# 14116
LABORATORY CHRONICLE
DATE RECEIPT/REFRIGERATION
DATE SAMPLED
" m i^/;?-^/y\
GC/MS:
Extractions: Acids
Base/Neutrals taj.xn ^ \
Analysis Volatiles
Acids
Base/Neutrals "1 ( I 3^[<^
GC: Extractions:
Pesticide>PCB Analysis:
Pesticide/PCB
Volatiles
rETROLEDM HYDROCARBONS;
Extractions: L,! M l ^
Analysis: j » h^
ATOMIC ABSORPTION:
Metals:
Mercury: ____
GENERAL ANALYTICAL;!'-'
Cyanide:
Phenol:
OTHER ANALYSIS:
fit^ •'''hh
LAB # io'a.«43>y
PRESERVATIVE U^a^j^j^fiflliiiii^ SO*f
Section Supervisor Review & Approval:
(Signature)
1 Section Supervisor Review & i^proval:
(Signature)
Section Supervisor Review & Approval:
(Signature) ''^Oi^.
Section Supervisor Review & Approval:
(Signature)
Section Supervisor Review & Approval:
w
o o
O l
(Signature)
F ina l Approval: CJjuLJUf^ J S . ^U>vautL
Quality Assurance Coordinator 1 6
Si'i "yiMjiM
NJ DEP Certified Drinking Water/Wastewater •"t^* Laboratory ID# 14116
DATE RECEIPT/REFRIGERATION
DATE SAMPLED
LABORATORY CHRONICLE
^Hh LAB #__L0ii3l. PRI-SERVATIVE i^^Y^jt^o^j^,^! f>l^\Ci^
GC/MS:
Extractions; Acids
Base/Neutrals .l alsL Analysis: . .
Volatiles U)(X^/^
Acids
Base/Neutrals ll |->-(^
GC:
Section Supervisor Review &
Extractions: Pesticlde7PCB
Analysis: Pesticide/PCB
Volatiles
PETROLEUM HYDROCARBONS:
Extractions: Loi 1 !
Analysis: (//
ATOMIC ABSORPTION:
Metals:
Mercury:
' $ • - • •
GENERAL ANALYTICAL: : -
Cyanide:
Phenol:
OTHER ANALYSIS:
r/ri ^/ft
Section Supervisor Review & Approval:
Section Supervisor Review & Approval: _
Section Supervisor Review & Approval: _
Section Supervisor Review & Approval: _
Final Approval: ^ ^
1 7 Quel:
(Signature)
(Signature)
(Signature)
(Signature)
Lty Assurance Co
'4
i .
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— >-»
»-• ilk
•
ordinatoi
Sl'i NJ DEP C e r t i f i e d Dr ink ing Water/Wastewater L a b o r a t o r y ID# 14116
LABORATORY CHRONICLE
DATE RECEIPT/REFRIGERATION
DATE SAMPLED
'/>3/gA LAB # lO^'tO
GC/MS:
/ ^ / p - ^ / r l PRESERVATIVE J t f ^ ^ i a ^ j g w i i i S o ^
Extractions; Acids
Base/Neutrals U [--l [^
Analysis: Volatiles
Acids
Base/Neutrals "7 ( /^/S^ Section Supervisor Review & Approval
^'SigiSure") GC:
Extractions: Pesticide7PCB
Analysis: Pesticide/PCB
Volatiles
PETROLEUM HYDROCARBONS:
Extractions:
Analysis:
ATOMIC ABSORPTION:
Metals:
Mercury:
Jj^rfet J^i l^
' / • • - •
Section Supervisor Review & Approval:
Section Supervisor Review & Approval: __
(Signature)
(Signature) ""•
UV..
Section Supervisor Review & Approval:
(Signature)
GENERAL ANALYTICAL:'
Cyanide:
Phenol: Section Supervisor Review & Approval:
50
O o
Ul
(Signature)
OTHER ANALYSIS:
H-V^l^^l^
18
Final Approval: Fj^ucn^Mi^ J^_ Gc-iIlX^
Quality Aasurance Coordinator
:^i ' i NJ DEP Certified Drinking Water/Wastewater " 9 1 Laboratory ID# 14116 •'':!;'
DATE RECEIPT/REFRIGERATION
DATE SAMPLED
LABORATORY CHRONICLE
U l ^ - ^ l ^ L.\B # <^/>^/A
\C>3i«^l
GC/MS:
Extractions: Acids
Base/Neutrals la 1 > n [ ^
Analysis: Volatiles Acids
U>(d^fa?l*S^
Base/Neutrals "{ |i " ^ j ^
GC: Extractions:
Pestlcide7PCB Analysis:
Pesticide/PCB
Volatiles
PETROLEUM HYDROCARBONS;
Extractions: L/|a<{|S^
Analysis: U |j.V[Vt
ATOMIC ABSORPTION:
Metals:
Mercury: .
GENERAL ANALYTlOa.?
C y a n i d e :
P h e n o l ;
OTHER ANALYSIS:
PRZSERVATIVE _0±^ i iS - - s>u i£<J jW^^^^
Section Supervisor Review & Approval
(Signature)
Section Supervisor Review & Approval:
Section Supervisor Review & Approval:
(Signature)
^ ' t ^ < ^ (Signature)
Section Supervisor Review & Approval:
(Signature)
Section Supervisor Review & Approval:
o o
1 9
(Signature)
Quality Assurance Coordinator
u NJ DEP C e r t i f i e d Dr inking Water /Wastewate i L a b o r a t o r y ID# 14116
DATE RECEIPT/REFRIGERATION
DATE SAMPLED
LABORATORY CHRONICLE
U [ > 1 [<-^ LAB i
;:.!i
Ib t**
^ | » - * ) | ^
GC/MS;
Extractions: Acids
Base/Neutrals
Analys i s : V o l a t i l e s
J alM •l^ui-ISft
Acids
Base/Neutrals -aU^H
GC; Extractions:
PesticideyPCB Analysis:
Pesticide/PCB
Volatiles
PETROLEUM HYDROCARBONS;
Extractions:
Analysis:
uUt^ J J ^
k. < 4 ^ Y ( < ^
ATOMIC ABSORPTION:
Metals:
Mercury:
GENERAL ANALYTICAL:
Cyanide:
Phenol:
OTHER ANALYSIS: .
PRESERVATIVE ^ ^ ^ O t f ' \ J - t J fJ S0«
Section Supervisor Review & Approval:
(Slgnaturfe)
Section Supervisor Review & Approval:
(Signature)
(Signature)
Section Supervisor Review & Approval;
(Signature) C3 O
Section Supervisor Review & Approval:
•1^
20
(Signature 1
(^lallcy Aaauranee Coordinator:
M :iii'j
NJ DEP C e r t i f i e d Dr ink ing Water/Wastewater L a b o r a t o r y ID# 14116
LABORATORY CHRONICLE
DATE RECEIPT/REFRIGERATION
DATE SAMPLED
M [ T>M
LAB #__iVbHH3^ PRESERVATIVE
GC/MS:
Extractions; Acids
Base/Neutrals Vj\x.'llV\
Analysis: Volatiles
Acids
Base/Neutrals IHJE
GC: Extractions:
Pcsticide7PCB Analysis:
Pesticide/PCB
Volatiles
PETROLEUM HYDROCARBONS:
Extractions;
Analysis:
"u^Mlja Mu
ATOMIC ABSORPTION:
Metals:
Mercury:
GENERAL ANALYTICAL;
Cyanide:
Phenol:
OTHER ANALYSIS:
Section Supervisor Review & Approval:
Section Supervisor Review & Approval:
\*,iA^tf^^r<l. , (J^^OY
(Signature)
Section Supervisor Review & Approval: _
Section Supervisor Review & Approval: _
Section Supervisor Review & Approval:
(Signature) ^ ^
(Signature)
(Signature)
1 o o
CO
2 1
Final Approval: c j^JL^niULJD, C^^^tcaA
Quality Assurance Coordinator
• ' S f i . •!
^Si
'Mi NJ DEP Certified Drinking Water/Waste^/ater"" Laboratory ID#, 14116 "-^'y^
LABORATORY CHRONICLE
DATE RECEIPT/REFftlGERAIION
DATE SAMPLED
u( 3,:> fa u I ^ m
LAB / /b'S« < *<'
PRESERVATIVE
GC/MS:
Extractions: Acids
Base/Neutrals
Analysis: Volatiles «Ul^ Acids
Base/Neutrals
GC: Extractions:
Pestlcide>PCB Analysis:
Pesticide/PCB
Volatiles
PETROLEUM HYDROCARBONS;
Extractions:
Analysis:
AT(»aC ABSORPTION:
Section Supervisor Review & Approval
Section Supervisor Review & Approval:
Section Supervisor Review & Approval:
Metals:
Mercury: -.;
fPT0^y-
GENERAL AHALYTiCAl^^
Cyanide:
1
1
Phenol:
OTHER ANALYSIS:
• . . . . . . '
]
22
Section Supervisor Review & Approval:
Section Supervisor Review & Approval:
£ t< Vy N «»a*4xJi,
(Signature gnature)
•3} y y S
(Signature)
(Signature)
(Signature)
(Signature)
Final Approval: Odt^tiViL A . Q u ^ '
Quality Aasurance Coordlnatoi
^ y ^ ! ^
11S2 Boute 10 NJ DEP Certified Drinking Hater/ ^ ^ . # ^ Randoipb, NJ 07869 Wastewater Laboratory I0I14116 201-584-0330 USEPA Contract Laboratory
NOWCOWPQRMANCE SUMMARY CHECKLIST
Lab Nu.h«r., lO^H-b^ - (&!>^^H
Volatile Organics: Anaiyied -y Not Analysed
A H tunes were run in required frequency. Yes -^ No
Ail tune a/x ratios aet criteria. Yes -^ No
Ail iaitial and/or continuing calibrations were run in required frequency. Yes j^ No
All calibration SPCCs and CCCs aet criteria. Yes No
Surrogate recoveries aet QC criteria. Yes -^ No
All aethod blanks aet contaaination criteria. Yes N o _
All saaples were analysed witbin the required holding tiaes, Yes / No
Other nonconforsanccs.
Coaaents!
Seal-volatile Organics: Analysed J Not Analysed
All tunes were run in required frequency. Yes ^ No
All tune a/i ratios aet criteria. Yes ^ No »
All initial and/or continuing calibrations were run in required
frcgaoncy. Yes / No o o
A U c a l l b r i t i O B SPCCs and CCCs aet c r i t e r i a . Yes y No
Saritogate recover ies aet QC c r i t e r i a . Yes No_/
All •ethdd'^blanks net contaainat ion c r i t e r i a . Yes • No.
-J o
All saaples wece extracted and analysed within the required holding tiaes. Yes No
Other nonconf oraances. AlXM^^-^Ly^^^^-eig « w A J ^ - f l h U 7 i ^ - ( n ^ C f ^
Coaaents:
_ 2 ^
1152 Route 10 NJ DEP Certified Drinking Water'/ 1 1 - ^ ^ 3 Randolph, NJ 07869 Wastewater Laboratory IDtl4H6 ti. ii 201-584-0330 USEPA Contract Laboratory #S/I
NONCONFORMANCE SUMMARY CHECKLIST
Lab Nunbers: I lii^^H 3 ^ - / 0 1 ^ 4 ^
Pesticides/PCBs: Analysed Not Analysed ^
All aetbod blanks aet contaaination criteria. Yes No
All saaples were extracted and analysed within the required bolding tiaes. Yes No
Other nonconforaances.
Coaaents:
Metals: Analysed Not Analysed ^
All aethod blanks net contaaination criteria. Yes No_
All saaples were analysed within the required holding tiaes. Yes No
Other nonconforaances..
Coaaentsi
Petroleaa Hydrocarbons: Analysed_^^ Not Analysed
All saaales were analysed within the required holding tiaes,
Othe^r^aoneoaf oraances.
y-i.
w
o Coaaents: o
24
fl. , — 1152 Route 10 NJ DEP Certified Drinking Water/ -'IrfS ife' >; ." Randolph, NJ 07869 Wastewater Laboratory IDtl4116 - - •">
201-584-0330 USEPA Contract Laboratory
NONCONFORMANCE SUMMARY CHECKLIST
Lab- M a . h c r s : ( D ^ ^ 1>^ ~ ( 0 :^ H <4 ^
General Chcaistry: Analysed Not Analysed
All saaples were analysed within the required holding tiaes. Yes_ji_ No
Other nonconforaances..
Coaaents:.
General:
All saaples were properly preserved in the field, ^ e s j , No.
Coaaents:
Additional Coaaents;
<\
^ -
25
. ^ • ;
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^^^-yr-^-y-
Puracablcs (CC/MS)
MATRIX: Water
y i i
METHOD REFERENCE: Code of Federal Regulations 40, Part 136, Appendix A, Metbod 624.
METHOD SUMMARY: Heliun is bubbled through a S nl water saaple contained in specially designed purging chanber for 11 nin. at aabient teaperature. The purgeables are transferred froa the aqueous to the vapor phase and passed through a 3 coaponent trap (OV-1, Tenax and silica gel) where they are absorbed. After purging is conplete, the trap is heated and backflushed with heliua to desorb the purgeables onto a gas chroaato-graphic coluan. The chroaatograph is teaperature prograaaed (3 ain. at 4S degrees C, then ranp to 220 degrees C at 8 degreos/ain.; final hold 12ain.) to separate the purgeables which are then detected with the aass spectroaeter. The aass spectroaeter data I systea (RTE-6) identifies target coapounds that aeet the criteria of retention tiae (-*30 s e c ) , relative abundance of characteristic aasses (-*20X), and aaxiaisation of characteristic aasses within 1 scan of each other. Other coapounds detected can be searched by the data systea in its EPA/NIH library of 42000* coapounds.
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26
:• .-•. ' i iy- i^
33je_Ncmr.U jmJ Aciii^
MATRIX: Wjtct
METHOD REFERENCE: Code of Federal Regulations 40, Method 625.
Pjrt 136, Appendix A,
METHOD SUMMARY: A Bcasured voluae of saaple, approxiaatel is serially extracted with acthylene chlo pH greater than 11 and again at pH less t a separatory funnel. The nethylene chlor is dried, concentrated to a voluae of 1.0 analysed by CC/MS. The gas chroaatograph SPB-5 capillary coluan, is prograaaed at C (1 Bin.) to 60 degrees C at 30 degrees then to 300 degrees C at 8 degrees C/ain, final hold of 24 ain. The aass spectroae systea (RTE-6) identifies target coapound the criteria of retention tiae (-•30 sec. abundance of 3 characteristic aasses (-•2 standard spectra), and aaxiaisation of characteristic aasses within 1 scan of ea Other coapounds detected can be searched systcB in its EPA/NIH library of 42000* c Quantitative analysis is perforaed using internal standard techniques with a singl characteristic a/s.
y 1 liter, ride at a ban 2 using ide extract al and with 30 a .
30 degrees C / a i n . ,
with a , :, t e rvda tac ;., s t ha t , a e e t ) ,_ r e l a t ^ e v ; OX - - o t y •••.•Wi'^''pi
• J ? < , t -
ch otheriif?\^ by the data oapounds.
•-.mr-
' '-•yy[^^..\y^'}^^- •:-•-fyy.-.' ; .
• i - ; ' , ^ .T ' ' ( ' x y ^ ^ ' ' : ^ - & ••'it-• - I ' ^ y y , ..-y^ •..;. •,,.?!;
• : » i
o ; . 0 :
27
PETROLEUM HYDROCARBON
MATRIX: Water
'mm '•ysyi
METHOD REFERENCE: U.S. EPA Methods for cheaical Analysis of Water and Wastes, 1983 Spectropbotoaetric Infrared Method 418.1
METHOD SUMMARY: The saaple bottle is aarked at the water aeniscus for later deteraination of voluae. The saaple is poured into a 2000 al separatory funnel. The saaple bottle is rinsed with 30 al of fluorocarbon-113 which is then added to the saaple in the separatory funnel. The funnel is shaken for 10 ainutes and the solvent layer filtered through a funnel containing solvent-aoistened filter paper into a 100 al voluaetric flask. The saaple is' extracted twice aore with 30 al of fresh solvent coabin-ing all extracts in the voluaetric flask. The extract is diluted to 100 Bl. 3 g. of silica gel is added and stirred for S ninutes. Quantitation is perforaed using an infrared, spectrophotoaeter. Appropriate dilutions are aade if the extract concentration is greater than 4ag/100al.
W
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28
tK
MATRIX: Water
METHOD REFERENCE: Standard Methods 16th Edition, Method 423
• - ^ l • • • > ^ i r
ym
METHOD SUMMARY: Following standardisation of the pH neter, the electrode is rinsed with deionised water and blotted dry. Saaples are brought to rooa teaperature, the electrode is iaaersed in the solution, and when equilibriua is established, the pH is read.
o o
28
11 "5 2 R c u t e 10 R a n d ) I p h , NJ C78A9 : C - l - ' ? : 3 4 - 0 3 3 0 AMGUST ] , 1 9 8 9
N.J D£P C e r t i f i i ^ d D r i n k i n g L a b o r a t o r y ID l 1411.6 US EPA C o n t r a c t L a b o r a t o r y
U a t e r / U a r, t €' u a t e^^ • '•y-' ' j5,i
LFiBGPATQRY ANAL'r'.S I S - - V O L A T I L E PCLLUTANT-S N o t e ; D i c h lo ro b e n i i-?ne(i a n a l y z e d a s s e i r i i - v o l a t .i I F
GC/MS VOLATILES - TIEf? I I DEL IVfrABLES
l.<.>b ^ . ' l ; ^ l h e ^ : CI L.:- r» t : S;?>:iple i i o u r c e : S i 11: P 11? I D : S3»riF> ] e d a t e ; £an;p l a i by ; A t l a b d a t e ; M a t r i x :
103^38 EARTH TECHMOLO-Gr STAPLING MACHINE SMC-H(J-l--:2 06/23/8' CUSTOMER 06/23/89 UATER
CQRFGRATICN
Par am«?ter Result ug/1
Chl Bro Win Chl Met 1 ,1 1 . 1 tot Chl 1 ,2 1 ,1 Ccir Bro 1 ,2 t-1 Tri Dib 1 , 1 Ben c-1 2-C Bro Tet 1 ,1 Tol Chl Eth Tot
0 r
yl 0 r hy -C -D al o r -D ,1 b'j rio -0 ,3 ch ro
• t
z e , 3 hi mo ra '>
t *-
ue yl al
omc rR»?t Ch
0 »?t len i<:h ich --1 , of 0 i r. !i --Tr •n T die ich -Di lor mo c -Tr ne -Oi 0 ro f o r chl / »-ne ob<? ben Xy
thane hane loride hane e Chlor ide lo roethylene loroethane 2-Oichloroethene
lore cv thane ichlo ro ethane etrachlo ride hlo romethane loropropane chlo ropropene 0 ethiy lene hlo romethane ichloroethane
19
chlo ropropene ethylvinyl Ether m 0 roethylene Tetrachloroethane
nzeno z ene lenes
16 13
U U U U U
U U U u u u u u u
u u
u u u J u
u u
UJ/I micrograms/liter or ppb
Method Slank ug/1
Min imum Detect io n Limit ug/1
U U U U U U U U U U U U U U U U U U U U U U U U U U U
u
S
5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5
ll: Indicates a compound uas analyzed for but not detected. Ji [ndicate-s an e<>timated value. It is utilized when a reported value
meets the identification criteria but the result is less than ihe -ipecified detection limit but greater than zero.
B: Indicates that the analyte was found in the blank as well as the sample. It indicates possible/probable blank contamination.
Copyright ICM, I-nc. ;'1986. All rights reserved, TS
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PAGE * 30
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I'J rile: bOOHL : sSL licleJ GtNEK'HL lOFILE FOR INSTRUHENT t Last Lalibrat^oris 890628 OBsf-O
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Data Files .G0326ssGl Quant Output File* *G0826ssQT Names UOA ON G, SAMPLE Miscs 103433, QU0672, 5 , L, 6'X2mrri I'/. SP 1000 ON CARBOPKB Cuant Times 890628 lls42 Quant 10 Files GUOALssSC Injected ats 890628 llsOl Last Calibrations 890628 09s50
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Last Calibrations 890628 08s50
I
Ccrnpound Nos 26 Compound Names Benzene Scan Numbers 461 Retention Times 18.73 min. Quant Ions 78.0 Areas 75300 Concentrations 15.40 UG/L q-ualues 91
I
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35
1 i-:i2 Riu t.e 10 Piindjlph, N.J 07S69 2 0 1 -•:•>• A - 0 3 3 0 AUGUST J, 1989
' " ' ' ' ' • - • ' ^^^ f /M NJ DEP C e r t i f i e d O r i n k i n s Uater /Uartet jJ j i^ t L a b o r a t o r y I D * 14116 ' ^ 0 US EPA C o n t r a c t L a b o r a t o r y
LAEOPATORY ANALYSIS A ] ] r e s u l t t i a r e r e p o r t e d i n m g / l (ppm) u n l e s ' i o t h e r y i s e s t a t e d
C l i e n t ! Soiirpli? Soa;~ce: ;;>3t!ipic ID! S.jii!pl'? Dale; Sampled By: At Lab Date!
103A'iO EAtUH TECHNOLOGY CORPORATION STAPLING MACHINE SMC-MU-3-2 06/23/9? CUSTOMER 06/23/S9
.PARAMETER TESTED RESULT DUPLICATE SPIKE
RECOVERY X
pH (units) 6.42
<- Less than >= Grea t f? r t h a n
INDUSTRIAL CORROSION MANAGEMENT, I n c , R i c h a r d L e v i n e , P r e s i d e n t
C o p y r i g h t ICM, I n c , TS
1986 . A l l r i g h t s r e s e r v e d ,
PAGE * 63
5
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Randolph, NJ 07869 NJ DEP Certified Drinking Uater . 201-••}:? 4-0330 Laboratory ID* 14116 • ' • ' " M ^ ! ^ AUGUST ] , 1989 US EPA Contract Laboratory ' ;it^
LAPOKATORr ANALYSIS — '.'OLATILE POLLUTANTS Note: Oich lo ro benz ene'i- analv:jed as semi-vo lati les.
GC/r»3 '.'0LATILE3 - TIER II OELIVERASLES
LvJb Number: 103441 Clt.:-.Tt; EARTH TECHNOLOGY CORPOPAT-'GN Sair.Dle source: STAPLIW(5 MACHINE 3::i:i:pli7 ID: SMC-«'J-4-2 Siample date: 06/23/89 Sampl.id by: CUSTOMER At lab date: 06/23/89 M.atrix; UATER
Min imum Method Detection
Parjm>?>.er Result Slank Limit ug/1 ug/1 ug/1
Chloromethane U U BrcT.c:nethane U U
5 Vinyl Chloride U U 5 Chloroethane U U Methylene Chloride U U 1 , l-Oi.::hlo roethy lene U U 1,1-Dichloroethane U U
5 5 5
total-1,2-Oichloroethene U U 5 5 5 5
Chloroform U U 1,2-0ichloroethare U U 1,1,1-Trichloroethane U U Carboi Tetrachloride U U 5 Bromodichloromethane U U 5 i 1 ,2-Oich lo ropropane U U 5 |J t-1 ,3-0 ich loro pro pene U U 5 .|-Trichloroethylene U U 5 ^ D ibromochloromethane U U 5 i / • . 1,1,2-Trichloroethane U U 5 Benz€?ne U U 5 c-1,3-Oichloropropene U U 5 2-ChloroethyIviny1 Ether U U 5 Bromoform U U 5 Tetrachloroethylene U U 5 1,1,2,2-Tetrachloroethane U U 5 Toluene U U 5 Chlorobenzene U LJ 5 Ethylbenzene U U 5 Total Xylenes U U 5
ug/1 " microsrams/liter or ppb
U: Indicates a compound uas analyzed for but not detected. J: Indicates an estimated value. It is utilized when a reported v-iluc
meets the identification criteria but the result is less than the specified detection limit but greater than zero.
B: Indicates that the analyte uas found in the blank as uell as the sample, .sl't. indicates possible/probable blank contamination.
''tB:.y ••;»••:
Copyright l C H , l i i . n c . , 1986. All rights reserved
»
PAGE • 64 o o
4^ 00 lu
T i i r o L r o N fHPOMflro'=i»f lM I r • I • i i i-)T«a -<K . 0 - 2 6 0 ."^ I B . . . '.'OJ i lN i ; , SAMPLE 1 0 ' 5 4 4 1 , f ( V 0 6 7 £ , iTT '•
• - • - • - - " T I C «;0 100 150 iO<3 250 3 0 0 250 4 0 0 450
l lOOOOH"
1 1-11't n,-% . T J
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£ '
Id Flles GUOALS:SC Titles GENERAL IDFILE FOR INSTRUMENT G Last Calibrations 890626 13s25
Operator IDs SP5680 Quant Time* 890626 18*54 Injected ats 890626 IS'IB
TIC page 1 of 2
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Data Files G0798>>G1 Quant Output Files *G07985sQT Names UOA ON G, SAMPLE Miscs 103441, QU0672, L, 5, 6'X2mm I^CSPIOOO ON CBPK B
Id Files GUOALs sSC Titles GENERAL IDFILE FOR INSTRUMENT G Last Calibrations 890626 13»25
Operator IDs SP5680 Quant Times 890626 18*54 Injected at* 890626 18*18
TIC page 2 of 2
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11 ;!• J R-o:ite 10 R.3ndolph, NJ 07869 2Cl-r3'1-0330 AUGUST 1, 1989
NJ DEP Certified Drinking Laboratory 10* 14116 US EPA Contract Laboratory
li' a t e> >U a%ffi^a;^]
LAEORAT^r-RY ANALYSIS-GC/MS BA-SE/NEUTRALS -
-PRIORITY POLLUTANT BASE/NEUTRALS TIER II DELIVERABLES PLUS 15 PEAKS
Lab Nirr Client! S.3)1: pi.? Syini.»] e
Samp led At 1 ? IJ Matrix:
Paramot
b (3 r:
• our ID: date by;
d a t e
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' j.r-CG'.
103441 EARTH TECHNOLOGY CORPORATION STAFLIrIG MACHINE SMC-MU-4-2 0.*/23/'3? CUSTOMER 0.^/23/3? UATER
W>
Acenaphthene Acen-ajihthy lene Anthracene Benzidine Benzo(a)anthracene Benzo( i> pyrene Benzo<b)fluoranthcn2-Benz 0 < gh i > perylene Benzo(k)fluoranthene 8 i i ( 2~ <: h 10 r 0 e t hy 0 xy ) me t h a n e B i s ( 2 - ch 10 r 0 e t hy 1) e t h e r 8 i s ( 2 - c h l o r o i s o p r o p y 1 ) e t h e r B i s ( 2 - e t h y l h e x y l ) p h t h a l a t e 4-BrorD0?heny 1 p h e n y l e t h e r B u t y l b e n z y l p h t h a l a t e 2 - C h l o r o n a p h t h a l e n e 4 - C h l o r o p h e n y 1 pheny l e t h e r C h r y s « n e Dib.enz<a,h)anthracene 1 ,2-Di':hlorobenzene 1,3-Dichlorobenzene 1,4-Oichlorobenzene 3,3-Dichlorobenzidine Diethyl phthalate Dimethyl phthalate Oi-n-butyl phthalate 2,4-Dinitrotoluene 2,6-Oinitrotoluene Di-n-octyl phthalate 1,2-DiphonyIhydrazine Fl^io rarthene FlJO rene Hexachlorobenzene Hexachlorobutadiene Hexachlorocyclopentadiene Hexachloroethane Indeno(1,2,3-cd)pyrene, Isophorone Naphthalene ..i .,., -^yriiS^i' ' Nitrob»?nze. i ie •,IJCM?:f\ . m-N - N i t r 0 so d ime.tl1ly4iamine^.^-^'^It N - N i t r 0 so d i - n-R.roIp'yiami ne-s P ' N - N i t r 0 so d iphenyj'lamine.'^''^^*',» Phc.13 nthrene i'-* Mg^<^y' f-^'-t'''^'' . Pyrene 'Z »-^'4'^i'>f:~>^'^s^- 1 , 2 , 4 - T r i c h l o r ' b b e n z"en'et; - •» y
Result u g / 1
U U U U U U U U U U U U U U U U U U U U U U U U U U u u u u u u u u u u u u u u u u u u u u
M e t h o d Slank u g / 1
u U U U U U U U U U U U U U U U u u u u u u u u u u u u u u u u u u u u u u u u u u u u u u
M i n i m u m D e t e c t i o n L i m i t u g / 1
5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5
• " . »
O-'
o
00
U9/1 micrograms/liter or ppb
U: Indicates a compound uas analyzed for but not detected. ^___i J: Indicates an estimated value. It is utilized uhen a reported value
meets the identification criteria but the result is less than the spt»cified detection limit but greater than zero. . •• '
B: Indicates that the analyte uas found in the.blank as uell as the sample.
j /
C o p y r i g h t TS
ICM, I n c . , 1986 . A l l r i g h t s r e s e r v e d ,
.1 m
PAGE t 67
I t ?
X i J i r 0 t t ' : e i •-'
Pando I p h . NJ 07869 2 0 1 - : i 3 A ~ 0 3 3 0 7 ' 1 9 / 8 9
NJ DEP C e r t i f i e d D r i n k i n g U a t e r / U a s t p u a t , t 3 Li ibo r.3to ry I D * 1411.s / - f i l
LIBRARY SEARCH RESULTS OF NONTARGETED PEAKS U I I H ESTIMATED CONCENTf'ATIGN OF Tt.NTATl'.'ELY I DENTIFI tO COhPUUNUS
D a t y f i l e n a m e : L :•:'.•) .n.'irnber; F r a c t i o n :
>C3831 1034-11 Ba!ie./Neu t r a l
b c a r K';i;t:bi?r
'349
CAS No Rete-n t ion
Time Compo u nd h'-.aiDe
2 8 . i: Unk nown
Mo lecuIar U e i g h t
Est imated C 0 n c e n t r a t i 'J n
u g / 1
77 B
A: Indicates that the compound is an acetone based aldol-type condensation produi:t formed by concentrating the extraction solvent (1:1 acetone/methylene chloride).
3: Indicates that the analyte tjas found in the blank as well as the sample. It. furthsr indicate'.* possible/probable blank contamination,
Copyright ICM, Inc., 1996. All rights reserved.
• '•.?•*•« i,''
• • ' •• i i ' j ih^/yAy' . -Ty, .,•;•"
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6 8 00 00
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TOTAL ION CHROnATOSRAn F i l « >C3ddl 39.a-5ee.a M U . INST 59703,SAtlPLE I5544l f f7SCl5 l27r331
TIC 4ee
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I • I ' I ' I • I ' 18 12 14
' I ' I • I ' 16 10
I ' l * 28 22
Data F i l e : > C 3 8 8 1 : : C 1 Name: INST 59703,SAMPLE M i s c : 1 0 3 4 4 1 B , Q C 1 2 1 2 , L , 9 8 0 , I , 3 0 M SPB- f CAP COLUMN
I d F i l e : ABNC::SC Title: CLP BNA IDFILE Last Calibration: 890712 17:56
Quant Q i j t p u t F i l e : ^ C 3 8 8 1 : : Q T
BTL#13
Operator ID: MB1874 Quant Times 890713 01:55 Injected at: 890713 01:11
TIC page 1 of 2
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TOTAL ION CMROnHTOSRAfl F i l * >C36ai 39 .8 -588 .a M U . INST 89783,SAIIFLE 13344157^151171755?
1888880:
988888^
888880:
7888e»
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588880^
48888^
388889:
288880:
188880^
20.00 , • - • • -- ' - '
TIC 24.88 2880 3288
J9
J • I ' I ' I ' J ' I ' I ' I ' I ' I ' I ' I ' J ' I ' I ' I • I ' I ' r' 22 24 26 28 38 32 34 36 38 48
m.
Data File: >C3881::C1 Name: INST 59703,SAMPLE Misc: 103441B,QC1212,L,980,1,30M SPB-5 CAP COLUMN
Id File: ABNC::SC Title: CLP BNA IDFILE Last Calibration; 890712 17:56
Quant Output File: ^03881::QT
BTL#13
•' M • ? ^ ^
Operator ID: MB1874 Quant Time: 890713 01:59 Injected at: 890713 OtMl
TIC page 2 of 2
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2 6 1 26-ii [ 2
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I I I* J I I I . > • I I I I I . I 1 1 I I I 11* Q
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/ / X ,if., jitprt-ff< ^ f •»»• ,^4 I t e 2 9 1 2 1 6 ^ ^ * 2?S
*y<^ . i y < i - > | FT , ; s > ' r | I T . f ' l . ^ 1 ,< i^ ^ P I , r | ' . ••» [ » f • I . I I I i • • I • • » I
aa i sa i^a znv 24a s-zta 32a 3^0
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Unknown t , l J i r c a • 52769 00 T e n t a t i v e C o n c e n t r a t i o n i s J ^ ^
1. lH-Pyrrole-2>5-dionc, I-£4-(2-benzoxasoly1iphenylJ-tyci)
2. Pndrosterone (801)
230 C1VH10N203
2y0 C1'^H3U02
Sarriplc f i l e : >P3aa i > , S p e c t r a r n • : S e a r c h spaed'M^:;lS^%.v-'f".^M!t'ing o p t i o n : N
-• • :'f.r:?fe?¥:«w'feHi':^.'.54::% Prob . J | 2$ i l ^Sg i&^ ' JebN t
• y i m y > ^ ? > y ^ ^ : . . ' ^ ' • ' • • • ^ m m B f i ^ - P ^ - y.. - • - -
1 . ^ 2 0 * JU65^tiC?M8;..>3S974 53418 3 2 3 t 2
ROOT
2349 No. oi- i o n r a n g e s s e a r c h e d : 4'.,
"BIGDB 23 •'Bir.-JB 1-4
DK IFLG TIi.T tl CON r.-_I « _ !
68 SS
3 3
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11 53 11 61 -
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44
KdndolF!--. NJ 078.69 NJ DEP Cert i f i e J Drink in>3 Ua t er/Uostef i^^l ;:':i-5;i'1--0330 L a b o r a t o r y ID# 14J. Is '¥<^4 Ai.iGUST 1, 1989 US EPA Contra;:t Laboratory 'vsj ij
' "•";??#•-
LAEORATORY AKftLYSIS-PETRGLEUM HYDRDCAReONS "§1
Client: EARTH TECHNOLOGY CORPORATION S-ainpl.? •:curc:e.' STAPLING MACHINE Samp liny Date: 06/23/89 SjinplC'i by: CUSTOMER At Lai) t^te: 06/23/89
MINIMUM LA8 DUPL. DETECTION METHOD SPIKE NO. ID. RESULT RESULT RPD LIMIT BLANK RECO'VER
';U3t«>r matrix) m- /1 mg/l mg/l X
1C34'11 SMC-!«U-4-2 U 0.99 U
U== Not detected NC= N':i n-calcu lable RPO due to valueCs) less than the detection limit
INDUSTRIAL CORROSION MANAGEMENT,•Inc, Richard Levine, President f
Copyright ICM, Inc., 1986. All ri'Shts reserved. TS
yisa^-.ai •'-. -,A?*fei,-.
• - ' ^ [ y . : " ^ y ^ y ^ i ^ /
y^ylh'ry^^^-'."^ ''l
PAGE #72 3 1
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i" ' ' Randolph 11.•52 R-3:ite 1'3
NJ 07869 201-?i:-3'1-0330 AUOUST 1, 1989
• • ' ^ m ^ ' i NJ DEP Certified Drinking Uater/Uasteilia'ee*! Laboratory rO# 14116 "^-y^""'' US EPA Contract Laboratory
LABORATORY ANALYSIS Al] results are reported in my/1 <ppm) unless otheruiise stated.
L:ib N'lffiil'C-T ; C l i e n t : Sjinpl*? So'Jree: Samp 1e ID; Samp I*? Date: Sampled By: At Lab Date:
103441 EARTH TECHNOLOGY CORPORATION STAPLING MACHINE SHC-MU-4-2 06/23/89 CUSTOMER 06/23/89
*. PARAMETER TESTED RESULT DUPLICATE SPIKE
RECOVERY
pH (units) 7.3;
4
•~ L e a s t h a n ' = G r e a t e r t h a n
I N D U S T R I A L CORROSION MANAGEMENT ,^Vi;n:^ff:f-R i c h a r d L e v i n e , P r e s i d e n t " ' ' ' ' " ' • - y ^ ' ^
C o p y r i g h t ICM, I n c , TS
1 9 8 6 . A l l r i g h t s r e s e r v e d .
it y s . y
PAGE 0 7 3
5
1 „-o.-
-- -.- -- '•'•y^^SW Randolph, NJ 07869 NJ DEP Certified Orinl<ing Uater/UasteiJa;t'er ;:01-'J.^M-0330 Lafcor-atory ID# 14116 =-,<?£§! AUGUST 1, 1989 US EPA Contract Laboratory - ;%?2
LABORArnftr ANALYSIS—VOLATILE POLLUTANTS i Note: Dich 1 0 robi?nz enes analyzed as sem i-vo 1 at i le'i .
C-C/M3 VOLATILES - TIER II DELIVERABLES
L;.>b Number: " 103442 C l i e n t : EARTH TECHK'OLOGY CORPCRATrON S;?iTip]e r.ource; STAPLING MACHINE S jinp 1 e ID: E.^iC-hU-.5-2 Sn^iple d a t e : 06/23/89 S.!ii,pl.;"i by: CUSTOMER At lab date: 06/23/89 .'i.dtrix: UATER
Min imum Method Detection
Param»?t«:'r Result Slank Limit ug/1 ug/1 ug/1
Chloromethane U U 5 Bron;oin«?thane U U 5 Vinyl Chloride U U 5 Chloroethane U U b Methylene Chloride U U 5 1 , l-Dichloroethylene U U 5 1 ,1-Dichloroethane U U 5 total--l ,2-Dichloroethene U U 5 Chloroform U U 5 1 ,2-D ii:h lo roethane , U U 5 1,1,1-Trichloroethane U U ;3rbon Tetrachloride U U 5 Bromodichloromethane U U 5 l,2-Di<:hloroprcp3ne U U 5 t-1,3-Dichloropropene U - U 5 Trichloroethylene U U 5 Dibromochloromethane U U 5 i,1,2-Trichloroethane U U 5 Benzene U U 5 c-1,3-0ichloroprapene U U 5 2-ChloroethyIvinyl Ether U U 5 Bromoform U U 5 Tetrachloroethylene U U 5 1 , 1 ,2,2-Tetrachloroeth3ne U U 5 Toluene U U 5 Chlorobenzene U U 5 Ethylbenzene U U 5 Total .Xylenes U U 5
ug/1 - micrograms/liter or ppb
U; Indicates a compound uas analyzed for but not detected. J: Indicates an estimated value. It is utilized when a reported value
neets the identification criteria but the result is less than the sp<?cified detection limit but greater than zero,
6: Indicates that the analyte was found in the blank as uell as the sample. It,., indicates possible/probable blank contamination.
Copyright ICM, Inc., •1986. All rights reserved, TO • ! • : • -
o o M
PAGE * 74 1
T.ITCL ION :HRQMaTQi5(iCiri r i l e >ftOS3? ' • 5 . 0 - 2 ( > 0 . 0 » i j i . VQO ON l i , Si i r lPLE 1 0 3 4 4 2 . a V 0 6 7 2 . 5 . L
T I C 100 200 ?C0 400 500
' I . . . . 1 . . . 1 . . . . 1 . . . . I . . . . I .
i4000(>-
12000CH
'10000'>
oCCOO"
bOuOO-
40000-1
•t'ffftl^^.f^yM
-•; y . ) i
D a t a F i l e ' > G 0 8 2 5 « « G 1 Q u a n t O u t p u t F i l e * * G 0 8 2 5 ! ! Q T Names UOA ON G, SAMPLE M i s c « 1 0 5 4 4 2 , Q V 0 6 7 2 , 5 , L , 6'X2mrr. IX SP 1 0 0 0 ON CARBOPKB
I d F i l e ! GyOALs sSC T i t l e ' GENERAL I D F I L E FOR INSTRUMENT G L a s t C a l i b r a t i o n ' 8 9 0 6 2 8 0 8 > 5 0
O p e r a t o r I D ' SP5680 Q u a n t T i m e ' 8 9 0 6 2 8 1 0 « 5 7 I n j e c t e d a t < 8 9 0 6 2 8 1 0 ( 1 6
T I C p a g e 1 o f 2
59
o o
75 VD VJ1
5'fj
TOTAL ION CHROMOTOGROM F i l « f-0325 ?5.0-2<J0.
1 i
500 bOO 1 , . . . , . . . . 1 .
1 1
1 J
i 1 ; i- ' :-:- j '>i 2 1
1 1 1 •• ; r i i - i l1 i -»-
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i II II « n II )i I 1 1 1
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1 . 1 . .
' I ' l £3
800
u u
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11 \
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' 1 ' 1 ' 1 • 1
30 32
103442 , dvO^T-S. S. L
?00 1000 . 1 . . . . * \ .
, • 1 • 1 • 1 • 1 • 1 ' 1 • 1
34 i i 33 40
Data F i l e s >G0825««G1 Quant O u t p u t F i l e ' * G 0 8 2 5 ! ' Q T Name' UOA ON G, SAMPLE M i s c 1 0 3 4 4 2 , QU0672, 5 , L, 6'X2mm IX SP 1000 ON CARBOPKB 0-Id File' GUOALs'SC litle' GENERAL IDFILE FOR INSTR^UMENT G Last Calibration' 890628 08'50*
Operator I0« SP5680 Uuant Time' 890628 10'57 Injected at' 890628 10*16
IC page 2 o f 2
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115? Route 1'3 Rando Iph , NJ 0736? 2.-. 1 -•=,; .1 -03 30 AUOUSf 1 , 1989
N.J DEP Certified Drin!<ing Laboratory ID# 14116 US EPA Contract Laboratory
LAEC'!?A7GRY Al^^ALYSIS-GC/HS e.'^.Se/NEUTRALS -
•-PRIGRITY POLLUTANT BASE/NEUTRALS TIER II DELIVERABLES PLUS 15 PEAKS
U a t e r / U a s t;eua:'%e;tJ
-yy?
• : , .%?:
ijk^
L.^ib N'.;rr;ber : C I : i e n t : 3;.--.I-;-•!»? ' - o a r c e : S: . . i ; ip le I D : •Sir:i;f>l>? ' J a t e : Si imp l e d by : A t l a b d 2 t e ! M a t r i x :
103442 EARTH TECHNOLOGI' STAPLING MACHINE SMC-MIJ-5-2 06/23/39 CUSTOMER 0 6 / 2 3 / 3 9 UATER
CORPORATION
P3r-3w.f.;*er Re- i iu l t u g / 1
A.r en aph t h e n e U Aoi'T^aph t h y 1 t r i e U A n t h r a c e n e U B e .1;: i d i r! e U B e n z o ( a ) a n t h r a c e n e U S e n ^ 0 ( i ) p y r e n e U B e n z o ( b > f l u o r a n t h e n e U 9 e n z 0 < j h i > p e r y l e n e U B<£>iTi 0 ( k ) f l u o r a n t h e n e U B i i i < 2 - ( : h l o r o e t h y 0 xy) methane U Bir i< 2 - c h l o r o e t h y 1) e t h e r U S i i , ( 2 - f : h l o r 0 i i ' . t p r o p y l ) e t h e r U B i s < 2 - e t h y l h e x y l ) p h t h a l a t e U 1 -S ro :eopheny 1 p h e n y l et.her U B u t y l b e n z y l p h t h a l a t e U 2 - C h l o r o n a p h t h a l e n e U " ^ - C h l o r o p h e n y l p h e n y l e t h e r U ChrysGrna U D i b e n z ( a , h ) a n t h r a c e n e U 1 , 2 - D i c h l o r o b e n z e n e U 1 . 3 - D i c h l o r o b S ' n z e n e U 1 . 4 - 0 i i : h l o r obenzene U 3 , 3 - D i c h l o r o b e n z i d i n e U O i . ? t h y l p h t h a l a t e U O in / / ? t hy l p h t h a l a t e U D i - n - b u t y l p h t h a l a t e U 2 , - 4 - D i n i t r o t o l u e n e U 2 , 6 - O i n i t r o t o l i i e n e U D i - n - o c t y l p h t h a l a t e U 1 . 2 - O i p h e n y I h y d r a z i n e U F l u o r a n t h e n e U F l x o r t i n f i U H e x a c h l o r o b e n z e n e U H e x a c h l o r o b u t a d i e n e U H e x a c h l o r o c y c l o p e n t a d i e n e U H e x . a c h l o r o e t h a n e U I n d e n o < 1 , 2 , 3 - c d ) p y r e n e U I s o p h o r o n e U N a p h t h a l e n e U N i t r o b e . i z e n e . -.^ , U N - N i t r o s o d i m e t h y l a m i ' n e U N - N i t r o s o d i - n - p r . o ? y , l a i n i n 8 U N - N i t r o s o d i p h e n y ' l a m i n © U Phen.-anthrfene v f * , ( - . ^ U P y r e n e — v-t^C"-.4^' - -' , U 1 , 2 , ' 4 - T r i c h l o r o b e n z e n e - U
•d-^/l - m i c r c s r a m s / l i t e r o r ppb
U: I n d i c a t e s a compound uas a n a l y z e d f o r J : I ' u l i c a t e s an e s t i m a t e d v a l u e . I t i s u
Method Blank u g / 1
U U U U U U U U U U U U U U U U u u u U u u u u u U u U u u u U u u u u u u u u u u u u u u
b u t n o t d e t t i l i z e d uhen
Min imum D e t e c t i o n L i m i t u g / 1
5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5
e c t e d .
' t . 1 ^
'€••
S-
a r e p o r t e d v a l u e
RWY
1 o i 2- !
^ !
i • meets the identification criteria but the result is less than __ . the -ipecified detection limit but greater than zero. Indicates that the analyte uas found in the blank as uell as the sample.
Copyright TS
ICM, Inc., 1986, All rights reserved.
PAGE # 77
... i - - r. y u L e I '-' PcMtfJo ] ph . NJ 07869 2'"1 - ' v34 - : ' 330 7 / 1 9 / 8 9
;. ^•i^<^C?.5s'^:.,'",,-,
MJ DEP Certified Drinking Uater/Uaste<^^at'y Laboratory lOt 14116 <yn
•yi^y
LIBRARY SEARCH RESULTS OF NOWTARGETED PEAKS UITH ESTIMATED CGNCENTRATION OF TENTATIVELY IDENTIFIED CUMPOUNL»S,
D;rt;i f i l e n a m e : i.. .30 n^trnbcr; F r a c t i o n :
>C3882 1 0 3 4 4 2 Ba l i e / N e u t r a l
S c a n • u ;r! b >2 r CAS No
2357
R e t e n t i o n T i m e
Compo und N.3me
28.09 Unk no un
MolecuIar Ueight
Est imated Concentration
ug/1
120 B
A: I n d i c a t e s t h a t t h e c o m p o u n d i s an a c e t o n e b a s e d a l d o l - t y p e c o n d e n s a t i o n p r o d u c t f o r m e d by co n c e n t r a t i : :g t h e e x t r a c t i o n s o l v e n t ( 1 : 1 a c e t o n e / m e t h y l e n e c h l o r i d e ) .
B: I r ^ l i c a t e s t h a t t h e a n a l y t e was f o u n d i n t h e b l a n k a s u e l l a s t h e s a m p l e , I t . f u r t h e r i n d i c a t e s p o s s i b l e / p r o b a b l e b l a n k c o n t a m i n a t i o n .
C o p y r i g h t ICM, I n c . , 1 9 8 6 , A l l r i g h t s r e s e r v e d .
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vo 00
78
TOTWI. ION CHROflBTOeRWn __ F i l a >C3e8£ 3 5 . 8 - 9 6 8 . 6 u u . IMST 59793,Sf inPLE 1834428 ,001212 ,L ,98<
780888-
fiseeee'
680888-
558880-
580880-
450000-
400000-
380000-
3O000»
250000-
200000'
190009-
100000-
50000-
0 7
. 400 I - r ' * ' • ' ' • '
TIC 880 1200
* - - • ' •
«
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1600 ' - '
o 5
Oata File: >C3882::C1 Name: INST 59703,SAMPLE Miac: 103442B,QC1212,L,980,1,30M SPB-5 CAP COLUMN
Id File: ABNC::SC Title: CLP BNA IDFILE Last Calibration: 890712 17:56
Quant Output File: ^C3882::QT
BTL*14
Operator ID: MB1874 Quant Time: 890713 02:48 Injected at: 690713 02:04
TIC page 1 of 2
'•'^^wyyy-.-'
5d
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79
TOTAL ION CHROnnTOORnn Til. >C3882
7eo0e»'
650ee»
688800-
558000-
500000-
450000-
400000-
350880-
380888-
250000-
200000-
150000-
100000'
50000-
1 .
2^-^
39.0-500.0 « u . iH i l S*r63,irtn^Lt
2OO0- 2400 . 2000 ,
i
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It
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i iU4&b,&ti i i i ,L,^i i
^ .' ^ .
•3'6'' "s'o' " V o " '
Data File: >C3882::C1 Quant Output File: ^C?eS2::QT Name: INST 59703,SAMPLE Misc: 103442B,QC1212,L,980,1,30M SPB-5 CAP COLUMN BTL*14
Id File: ABNC::SC Title: CLP BNA IDFILE Last Calibration: 890712 17:56
Operator ID: MB1874 Quant Time: 890713 02:48 Injected at: 890713 02:04
TIC page 2 of 2
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i . ' ^ l i . i . - C S m I N i r Sy,'i9J .SMflFut I t i » 4 i = . u C l i i i .L. . ' J s o . 1 . i O r . SP i c a r . 2 3 ; : r.f. w ot. cOo.'iifc SUR 000 OVC £ b . 0 9 n i n ,
^ :^9
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9 1
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l i V IfcM Z t V 241*
269 «^t!:
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1
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B i n .
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•• • •• .-••• -.f V . ? { ' : ! H
•^'•;:3l
1. l , b - H e p t a d i v r i e ISCI9C1) 2 . Ber .zer te , (phenoxymethtyi ) - l 9 C i )
92 C7H3 184 CI -:H11' i
Sample file: >C38'i'2 Spectrum •: Search speed: 1- - . Til-tinq option: N
•-. ;iv-•5%^.'' •-•'' • ' - - y y • •:-
..'. >y^?^;. ---?s ...
Prob.-^^|si^av-i,.o:%Qrt t
t U * "^ ;;»2 39 bb^iiev'J • 76 b 3 6U 94630b 7638
R(.-.OT
"Blc:!JS "BIGDB
23b7 No. of ion ranges searched
Vb 3 3
- 1 :
Dl'v I rwG TILT % C'..N C _ i R _ i y
7 1 • J O
0 l l i : j : 4 3 0 I -0 lOM 14 3U -y-y.
50
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8 1 Ul
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I
.1 . . . . . . •_!.;•., n t ,-.,.. O l . . ' : - . - . - •_ , i ' . ' - . •:. , . j , ; . , ; L . , ; I , .. ., u . . . ^.iy^Tyn'^Z'^
1 1 3 2 R o u t . 3 l O ' "'^IC^jVisf.' F i u i J o l p h , NJ 0 7 3 6 9 NJ DEP C e r t i f i ( ? d D r i n k i n g U a t e r / U a s t e u d . t e i : 201-'^3A-0330 L 3 b o ^ a t ( ) r ^ y I D * 1 4 1 1 6 r-iUGUsiir 1 , 1 9 8 9 US EPA Con t r. i c t L a b o r a t o r y
I.APQRrtTORY ANALYSIS-PETROLEUM HYOPOCARBQNS
C l i r n t ! EARTH TECHNOLOGY CORPORATION' S::urpl'.y Sour- ' -*?; .STAPLING MACHINE .5r:iiriplin<.:: D a t e ; 0< :^ /23 /89 S.?>;i:pls?tJ b y : CUSTOMER A t L a b D a t e ; 0 6 / 2 3 / 8 9
MINIMUM LA.S DUPL. DETECTION METHOD SP IKE NO. I D . RESULT RESULT RPD L I M I T BLANK RECOVERY
(W3 t (? r r n s t r i x ) m g / l m g / l m g / l %
1 Q 3 A A 2 S M C - M U - 5 - 2 U 0 . 3 9 U
U:= Not i i f i t e c t e d K'C- No n-calcu Isblc RPD due to V3lue'(s) less than the detection limit,
INCUSTi?IAL CORROSION MANAGEMENT, Inc, Richard Levine, President £•
C'.-,':?yr isht ICM, Ire,, 19SA. All rights reserved, TS
PAGE * 82
o
.. .. .i <. r . J u '- t? J. 'w'
F d n d o l F h . NJ 078A9 2 0 1 - ; ; ; J ' 1 - J 3 . 3 0 AUGUST 1 , 1989
NJ DEP C e r t i f i e d D r i n k i n g U a t e r / U a 5t eua't'e.; L ; 2 b o r a t o r y I D * 1411.6 ' ^ ^ ' US EPA C o n t r a c t L a b o r a t o r y p*;;
LABORATORY ANALYSIS A I ] r e s u l t s a r e rci--o r t c d i n m g / l (ppm) u n l e s s o t h e r w i s e s t a t e d .
L.v;b N'Jniter! C l i e n t : S.-y.nplo S o u r c e : S;3niple I D : Sani!:jl»? D a t e : Samp led Ey: A(. Lab O a t c !
103442 EARTH TECHNOLOGY CORPORATION STAPLING MACHINE SMC-MU-5-2 0 6 / 2 3 / 3 9 CUSTOMER 0 6 / 2 3 / 8 9
PARAMETER TESTED
pH (units)
•= Les^ than " G r e 3 t e r thiin
RESULT DUPLICATE SPIKE
RECO'.;ERY X
6.&1
INDUSTRIAL CORROSION MANAGEMENT, Inc, Richard Levine, President
Capyriijht ICM, Inc., 19S4. All rights reserved, TS
PAGE * 83
!d
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o
Randolph, N i 07969 201-:v3 4—:'3 30 AUGUST ] . 1939
NJ DEP Certified Drinking Uater/Uastruatt Laboratory ID* 1411A -US EPA Contract Laboratory
LAeOPATQRY ANALYSI3--V0LATTLE POLLUTANTS Note; Dichlo robenz enes an3lY.ied as 'j.emi-vo lat i les .
L-C/M3 '.'0LATILE3 - TIER II DELIVERABLES
L i.>l> Number : C I i -3 -i * : Sa.rip ] G so ij r c e ; S - J ) l : p l > 7 I D ; S a Triple d a t e : c a in ;:> I'? d b y : At lab date: d 3 t r i X !
1034^3 EARTH TECHNOLOGY STAPLING MACHINE SMC-FS-2 06/23/89 CUSTOMER 06/23/89 UATER
COrPORAriCN
P a r . a m a t e r Re?<>ult u g / 1
Method Slank ug/1
Minimum Detectio n Limit ug/1
h lo r ." 0 m w-iny 1 hlo r ethy ,1-0 ,1-D ctal h 1 o r .2-0 , 1 .. 1 arbo r 0 mo .2-0 -1 ,3 rich ibr 0 1 ''
enz c -1,3 -Chl romo etra .1.2 clue h lo r thyl otal
0 metha jnethan Chlor
0 G t l a n lene C i c /T 10 r i c h 10 r -1,2-0 0 f 0 rifi i': h 10 r - T r i c: h r. T o t r d i c h 10 i c h 10 r - D i c h 1 1 0 r 0 e t mo chlo - T r i c h ne - 0 i c h 1 0 r0 eth f o r m c h l o r o ... 1 c; %.
ne c b e n z e benz en Xy len
ne e ide e h 10 r i d e oethylene 0 e t h a n e i c h l o r o e l h e n e
0 e t !•( 3 n e loro ethane •jchlori-de romethane opropane 0 ropropene hylene romethane loroethane
0 ropropene ylvinyl Ether
ethylene rachlo roethane
ne e es
U U U U U U U U U U u u u u u u u u u u u u u u u u u u
u g / 1 " m i c r o g r i i T s / l i t e r or ppb
U U U U U U U U U U U u u u u u u u u u u u u u u u u u
5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5
U t
a compound u a s a n a l y z e d f o r b u t n o t d e t e c t e d , n e s t i m a t e d v a l u e . I t i s u t i l i z e d uhen a r e p o r t e d v a l u e
Indicates Indicates an e&iimaiea vaxue. i x I'S uiixizea unen a reporiea meets the identification criteria but the result is less than
as the
niF.-tTL:? Liiif A U i f n L . i i j i . d L J . u i i u i J L f c - i J d u u L \ . n a r e ^ u j i J 5 j e s s i r t h e 'Specified d e t e c t i o n l i m i t b u t g r e a t e r t h a n z e r o . I n d i c a t e s t h a t t h e a n a l y t e u a s f o u n d in t h e b l a n k a s u e l l ; s a m p l e . It i n d i c a t e s p o s s i b l e / p r o b a b l e b l a n k c o n t a m i n a t i o n ,
Copyright ICM, Inc., 1986. All rights reserved, TC
55
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PAGE * 84
o iCk
TOTOL t r iN CHPnMOTf,i;?Qn r , \ . r . n s i O !"•. . O - i ' ^ O . 0 i o u . V0i3 l lN S . S O n f L r 1 0 ' S 4 4 3 . .1V0672 . ? , <:
T I C : jw i U U i ' j ' j ••00 500
- • . ' . • t J - .
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i 1 j e.'.'WV'>
i i 7C00'^ i i . • I iz-'JU'J'J-
i : I 50000;
I 4 0 0 0 >
' 30000-
iOOOO;
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,£ 4 i 3 10 1£ 14 li 18 cO
D a t a Files >G0810'«G1 Qudr.t Output F i l e ' *G0810ssQT Names UOA ON G, SftMPLE M i s c 1 0 5 4 4 3 , Q 0 0 6 7 2 . 5, S, 6->.Zmfr. IV. p lOOO ON CftRBOPKB
Id riles GUOftLs sSC Tit l e s GtHERftL IDFILE FOR INSTRUHENT G Last Calibrations 8 9 0 6 2 7 13«22
O p e r a t o r ID» SP5680 G u a n t T i m e * 890627 16'25 In j s c t e d at» 890627 15s41
TIC p a g e 1 of 2
o o
85 Ul o u»
T O T M I . I O N CHR-|MMTO(;RPn
I T I C I 5 0 0 ijOO TOO 300 900
• • ' — . . ; . . . , : I 1 . . i . . , . : . , . • • • . . . : . . . . I
1 0 3 4 4 3 . a v O B 7 i . 5 . J I
1 JOO
i .-tCd ( - l i e s . b O t s l O s s & i Q u a n t O u t p u t F i l e s ' G O a i O s : ; i l Haines v b H ON b , SutlPLE i - l i f . cs iO>-+'+.^, QU06/ "2 , :-•, S, 6 X2riif.. IX P I'JOO ON CrtRBOFKB
«
I d F i l e : L. ;-i U H L s : b t t i t l e s Gc;,SEf<ftL I D F I L E FOR INSTRUHENT G L a s t C a l i b r a t i o n s 8 9 0 6 2 7 1 3 « 2 2
O p e r a t o r I D s S P 5 6 8 0 I j u a n t T i m e s 8 9 0 6 2 7 168 25 I n j e c t e d a t « 8 9 0 6 2 7 16i»41
T I C p a g e 2 o f 2
- » ' ..---^:;
' ^ ^ y ^ : ^ y .':'
86 O O H4
U l O
R a n d o l p h , NJ 07869 NJ DEP C e r t i f i e d D r i n k i n g Uater/UWst%^iiiijt*€ 201- : i3 '1 -0330 L a b o r a t o r y 10* 14116 -".; *^?>a AUGUST 1 . 1989 US EPA C o n t r a c t L a b o r a t o r y ' ' "^^
LASOPATriRY A N A L Y S I S — P R I O R I T Y POLLUTANT KASE/NEUTPALS '-'.': GC/M? BA.'SE/NEUTRALS - T I E R I I DELIVERABLES PLUS 15 PEAKS
Lab N;ic!ber: 103443 Client! • EARTH TECHNOLOGY CORPORATION SD;'.i:>le source: STAPLING MACHINE Sirnii 'le ID; SMC-FB-2 Gain?. I,? date; 06/23/89 Sampled by: CUSTOMER At Lib 'iate; 06/23/39 Matrix: UATER
P-ar ameter ResuIt ug/1
U U U U U U U U U U U U U U U U U U U U U U U U U U U u u u u u u u u u u u u u u u u u u u
Method Blank ug/1
U U U U U U U U U U U U U U U U U U U u u u u u u u u u u u u u u u u u u u u u u u u u u u
Minimum Detection Limit ug/1
5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5
Acenaphthene Acenaphthylene Anthracene Benz idine B e n z o ( a ) a n t h r a c e n e B e n . : o ( a > p y r e n o B e n ; o ( b ) f l u o r a n t h e n e Be:TZ 3 ( sh i ) p e r y l e n e B e n z o < k ) f l u o r a n t h e n e B i i ' ' 2-(:h lo r 0 e t h y 0 xy ) i i e t h a n e B i s ( 2 - c h l o r o e t h y l ) e t h e r B i i > ( 2 ~ i : h l o r o i s c p r 3 p y l ) e t h e r B i 5 ( 2 - e t h y l h e x y l ) p h t h a l a t e 4 - 3 r o re o p h e n y l p h e n y l e t h e r B u t y l b e n z y l p h t h a l a t e 2 - C h l o r-3 n .aphtha l e n e 4- (Jh lo ro p h e n y l pheny l e t h e r C h r y s e n o Dibenz(3,h)anthracene 1 ,2-Oic,'iiorobenzene 1,3-Dichlorobenzene 1,4-Oichlorcbenzene 3,3-Dichlorobenzidine Oiothyl phthalate Dimethyl phthalate Di-n-butyl phthalate 2,'4-Oinitrotoluene 2,6-Dinitrotoluene Di-n-octyl phthalate 1,2-0iphenylhydra2ine Fluoranthene Fluorene Hexachlorobenzene Hexachlorobutadiene Hexachlorocyclopentadiene U U 5 ^ Hexachloroethane ~ Indeno(l,2,3-cd)pyrene Isopho rone N a p h t h a l e n e U U 5 ^ N i t r o b e n z e n e U U 5 o N - N i t r o s o d i m e t h y l a m i n e N-Ni t r o ' i o d i - n - p r o p ' y l a a i i n e N-Ni t r o sod iphenylvaminer. U U 5 ^ Fhe.'Ian t h r o n e •yi. ;'*-' • .• - U U 5 oi P y r e n e i , r " v ' U U 5 o 1 , 2 , 4 - T r i ch lo - rdbenzene» - U U 5 -J
._.„__ _ inTcf r^ i^ rams/ l i t e r or~p^"b
U: I n d i c a t e s a compound u a s a n a l y z e d f o r b u t no t d e t e c t e d . J ; I n d i c a t e s an e s t i n a t e d v a l u e . I t i s u t i l i z e d when a r e p o r t e d v a l u e
m e e t s t h e i d e n t i f i c a t i o n c r i t e r i a b u t t h e r e s u l t i s l e s s t h a n t h e - i p t j c i f i e d d e t e c t i o n l i m i t b u t g r e a t e r t h a n z e r o .
B: I n d i c a t e ' . ^ t h a t t h e a n a l y t e u a s f o u n d in t h e b l a n k a s u e l l a s t h e sample
C o p y r i g h t ICM, I n c . , 1986 . A l l r i g h t s r e s e r v e d . TS
PAGE * 87
1
. - • . - . • . , , n .1.1-11- ^ _ w . ' n i , ' ^ . ' J . i . ' i* ( u - i i v t - j i j ' : . n i r . f V I y i T>C . '^M$yM
l l ' ! ; 2 R o u t e 10 'SgUi| R a n d o l p h , NJ 0 7 8 6 9 NJ DEP C e r t i f i e d D r i n k i n g U a t e r / U a s t e u S t i | > 2 0 1 - r : ' 3 4 - 0 3 3 0 L a b o r a t o r y I D * 14116 y'' ' 7 / 1 9 / 8 9 i ^
• LIBRARY SEARCH RESULTS OF NONTARGETED PEAKS U I T H ESTIMATED CONCENTRATION OF TENTAT IVELY I D t : W T I F I E D COMPOUNDS.
D a t a f i l e name: >C3883 L a b Ti'^rBber; 1 0 3 4 4 3 F r a c t i o n : Ba !ie./N eu t r a 1
3 c i ? r R e t e n t i o n Compound M o l e c u l a r E s t i m a t e d N u m b e r CAS No, T ime Name U e i g h t C o n c e n t r a t i o n
u g / 1
>357 2 8 . 0 8 U n k n o u n 5 7 B
A: I n d i c a t e s t h a t t h e c o m p o u n d i s an a c e t o n e b a s e d a l d o l - t y p e c o n d e n s a t i o n p r o d u c t f o r m e d by c o n c e n t r a t i n g t h e e x t r a c t i o n s o l v e n t ( 1 : 1 a c e t o n e / m e t h y l e n e c h l o r i d e ) ,
B; I n d i c a t e - 3 t h a t t h e a n a l y t e was f o u n d i n t h e b l a n k a s u e l l a s t h e s a m p l e , I t , f u r t h e r i n d i c a t e s p o s s i b l e / p r o b a b l e b l a n k c o n t a m i n a t i o n .
i
Copyri'jht ICM, Inc., 1996. All rights reserved.
O O
Ul
88 S
TOTAL ION CHROnATOGRRn n i * >c3ee3 39.a-5ee.a M U . INST 59793,snnPLE i A U 4 i b . { i t i i i i , L , i 7 i
70eee9-
5eeee»
4eeee»
2eeee»
i8eee»
4ee see i • - ' I . . . I . . - I . . . I . . . I . . .
izee
I
1680
o
f
'*/yxmm^M
•ysM' >~-^f^y , * • • - . is
Quant O u t p u t F i l e : ^C3883:sQT
8TL#15
Data File: >C3883::C1 Name: INST 59703,SAMPLE Misc: 103443B,QC1212,L,970,1,30M SPB-5 CAP COLUMN
Id File: ABNC::SC Title: CLP BNA IDFILE Last Calibration: 890712 17:56
Operator ID: M61874 Quant Time: 990713 03:41 Injected at: 890713 02:57
TIC page 1 of 2
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89 Ul o vo
TOTAL ION CHROMATOeRRn Fil* >C3ee3 35.e-5ee.e M U . INST s^res.snnPLC 1034438,001212,L,97(
TIC 2098" 2488 28,88 3288
780088-
600808-
588088-
488888-
308888-
208888-
188888-
22 24 26 1 ' I ' 1 ' I ' I • I ' I ' I '
38 32 34 36 •! ' 1 ' T ' 1 '• I
38 48
Quant Output File: ^C3883::QT
BTLtl5
Data File: >C3883::C1 Name: INST 59703,SAMPLE Misc: 1Q3443B,QC1212,L,970,1,30M SPB-5 CAP COLUMN
Id File: ABNC::SC Title: CLP BNA IDFILE Last Calibration: 890712 17:56
Operator ID: MB1874 Quant Time: 890713 03:41 Injected at: 890713 02:57
TIC page 2 of 2
w
o o
Ul M o
90
r ' i i e - 'C i . iSJ If i iT S j i ' i j i .ii'<f:.*-£ l o - - » 4 3 c . u C - i i i .L . r r e . 1 , j j i i i P S c a n H i ' S p i flb 3 5 " , : i SI 10 flOn OVC 2 C . 0 S m i n .
I -I
.1-" l e i 115 141 171 181 19? 223 248 *" I I I ' I ; . , I ; , , , 1
IGC I ' I : ' I ' ' ' !"
2<>e f
I^r c c i Unknown t ^ 1 35;'co/.iJ T e n t a t i v e C o n c e n t r a t i o n i s '-.•7,0:
Sample f i l e : >crjS3'3 Spectrum I : ^ . J - J /^
9 1
' •?&*•
Mo d-ita base e n t r i e s u e r e r e t r i e v e d .
- • : • • • . ' • • : • ' " , « ; , ;
%
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U l
?iir:do I p h , NJ 07S69 ; 0 1 - ' v 3 4 - ; ' 3 3 0 •iMOusr 1 , i9 'a9
istet<b#e:t NJ DEP Certified Drinking Uater/Uas Laboratory ID# 14116 '- ' US EPA Contract Laboratory .-"
LABORATORY ANALYSIS-PETROLEUM HYOROCAReONS
C :i icnt : 3 •:i;'i ?' 11? S o 11 r c e : Siiirip l i n y D a t e : S.7i:i;p I •;-i.l b y :
At Lab Date:
EARTH TECHNOLOGY CORPORATION STAPLING MACHINE 06/23/89 CUSTOMER 06/23/89
LAS DUPL. NO, ID, RESULT RESULT
CUate.'" matrix) ms/l mg/l
1031'13 SMC-F3-2 U
RPD
MINIMUM DETECTION
LIMIT mg/l
METHOD BLANK
0 . 3 3 U
SPIKE RECOVERS
U-- N o t d e t e c t e d NC ~ N o n - c a l c u l a b l e RPO d u e t o v a l u e ( s ) l e s s t h a n t h e d e t e c t i o n l i m i t
I N D U S T R I A L CORROSION MANAGEMENT, I n c R i c h a r d L e v i n e , P r e s i d e n t I
L'j py;
TS yht ICM, Inc., 1936, All rights reserved.
•vi'" .,-"7" ••.. .jp^i^j-
PAGE * 92 ^
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to
J. . - ^ p. J l l I. e i V
F s i i d o l p h , NJ 0 7 8 6 9 201- ' v :3<1-0330 AUGUST 1 , 1 9 3 9
NJ DEP Certified Drinking UatE' /Uas-.tCp'ObSle Laboratory ID* 14116 US EPA Contract Laboratory
LAPOPATORY ANALYSIS All reriults are reported in mg.''l (ppm) unless otheruise sts'.ed.
L^b .'v'lrnber : C1 tent ; Swir-pl*? Source Sample ID: 3i:i:ple ijate: SaTiipled By; At Lab Date:
103443 EARTH TECHNOLOGY CORPORATION STAPLING MACHINE SMC-FB-2 06/23/S9 CUSTOMER 06/23/39
.•PARAMETER TESTED RESULT DUPLICATE S P I K E
RECOUERY X
K- H ( u n i t s ) 6 . 7 4
< •-'• L e s s thicui .'•- Greater than
INDUSTRIAL CORROSION MANAGEMENT, Inc Richard Levine, Frs'Siident
Co.--yri3ht ICM, Inc., 1996. All rights reserved, TS
PAGE # 93
• . • y : y ? - S . } / y •';.•.
a
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1. i. o .L-. K 0 'i t e I '-• Randolph, NJ 07369 201 -•-" .3-1-03 30 AUGUST 1, 1989
Note
t 'iAyy,t!j^2 m N J DEP C e r t i f i e d Drinking Water/Uasteua";t''erf Laboratory ID* 14116 .-•%iiil US EPA JDortract Laboratory ;i|3&!
.ABOPATORY ANALY.SIS—".'OLATILE POLLUTANTS Dichlorobenz fncjs analy:zed a^ i=emi-vo 1 at i le-o , GC/MS VOLATILES - TIER II OELIVEf-ASLES
'¥
l . i i ib NunibC'?r :
S : j m p l e s o u r c e : 5.;,;i^;.le I D ; S a m p l e d a t e : b . j ; n p A t l a b .M 31 r i X
(?d by da t<
P a r -iJrKjter
hlo r romo iny 1 hlor ethy ,1-0 ,1-D otal hlor ,2-D ,1,1 arbo romo ,2-D -1 .3 rich ibro 1 ''
enz e -1 ,3 -Chl romo etra 1 "
o lue hlor thyl otal
omet meth Chl
oeth lene ichl ichl -1,2 of or ichl -Tri 1 Te dich i.:hl -Die loro mo ch -Tri ne -Die 0 ro e form chlo ,2-T ne oben benz Xyl
hane ane 0 r ide ane Chlor i
0 roethy oroetha -Dichlo m 0 raetha chlo roe trach lo lo romet 0 roprop hlo r0 pr ethyilen lo romet chlo ro e
h 10 r 0 p r thy 1vin
roethyl etrachl
zene ene enes
de lene ne roethene
ne thane ride hane ane opene e hane thane
opene yl Ether
ene oroethane
103444 EARTH TECH." STAPLING H,' SMC-T3-2 06/23/39 CUSTOMER 06/23/89 UATER
Result ug/1
U U U U U U U U u u u u u u u u u u u u u u u u u u u u
'GLOGY CORP ^CHINE
Method Slank ug/1
U U U U U U U u u u u u u u u u u u u u u u u u u u u u
OPATI
M D L
CN
in imum etect io n imit
ug/1
5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5
ug/1 •- micrograms/liter or ppb
U: Indicates a compound was analyzed for but not detected. J: Iniiicates an estimated value. It is utilized uhen a reported value
meets the identification criteria but the result is less than the •jp<?cified detection limit but greater than zero.
B: IndicateS'that the analyte was found in the blank as well as the sample. '.Ife'vindic'atfta possible/probable blank contamination.
• & y i / i ' ' "• "
C o p y r i g h t ICM ,^!T»k't ,V4^86fv- A-11 r i g h t s r e s e r v e d .
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PAGE t 94
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• . ' • • \ - . . ^
TOTOL ION CMROflQTOGRQtl V i W eoe2«> 3 5 . 0 - 2 1 5 0 . 0 a « u . VOfl OM S , S&nPLE
TIC 100 200 300
*—^ 1 - 1 - - A fl i ^ 1 I 1 . • ; 1 . 1 . 1 t . • 1 1 - i - . 1 - j _ - i 1 . • . . 1
103444 , a v o t r a , 5 . L
14CCC'>|
i ' n r» < A J
T i -. ,; i ion(vi i -I I i i ' ioocH
1
I annn iv I 4 i 7 0 0 0 > I I ijuOuO-1 I ouuOv-
[ «'3C00-
I •>nnr>ru I i 20000-
10000-
0-
400 ' ' • f I I
5C0 • I I
I • I ' I ' - 7 - ' 10 12 14
' I ' l 16 13 20
Data File' >G0829«sGl Quant Output File» *G0829i:QT Name« UOA ON G, SAMPLE ni5c« 103444, QU0672, 5, L, 6'X2mm DC SP 1000 ON CftRBOPKB
Id File". GUOAL'sSC Title* GENERAL IDFILE FOR INSTRUMENT G Last Calibration' 890628 08«50
Operator ID« SP5680 Quant Timet 890628 14«52 Injected at' 890628 la»ll
TIC page 1 of 2
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Data File: >G0329««G1 Quant Output File« *G0829!sQT Names U O H ON G, SAMPLE liisc: 103444, QU0672, 5, L, 6-X2mni IV. SP 1000 ON CARBOPKB
Id h I le= GUUAL!sSC litle: GENERAL lOFILE FOR INSTRUMENT G Last Calibrations 890628 08:50
Operator ID: SP5680 U'jant rime: 890«>28 l4s5>2 Injected at: 890628 1-4:11
j i L page 2 or .::
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:. I. j y K -3 u t C 10 F^>;d;i ] p h , N J 0 7'86'. - y i - - y 3 ^ - 0 2 2 0 AUGUST 1 , 1 9 3 9
^-^'•y?m NJ OEP C<?v f i f iec! D r i n k i n g U a t e r / U a ? . t e u a ' l % L.abo r I ' . ' j ; y I'D* 1-4116 US EPA Cor i t r ib i r t L a b o r a t o r y
SURFjrGATE RflCO'.-E KY SUf^r'rARi' A •} 0 (? o u s V ii 1 a 11 1 e S 'a T• r : ci vi t e 'y
T '1 ri;l;'er 0V0.572
.''. R e c o v e r y 2-D i c h lo r o e t b a n e - d 4
% Reco'.'ery Toluere-dS
% Recovery Bromofluorobenzene
• Outside QC Limit-3
BLANK 103441 1034 4 0 •034.39 BLANK 103443 BLANK 103412 J 034 39 1034123 1034 42SD
lO'i 114 114 112 104 105 104 104 103 105 lOS
.
101 101 100 100 107 107 103 103 107 110 106
99 101 104 101 103 106
9 7 101
9 9 1 0 0 1 0 4
0 0 0 0 0 0 0 0 0 0 0
QC L i i i i i t y ; 1 , 2 - D i c h l o r o e t h a n e - d 4 To I ' l e n e - d S Bromofluorobenzene
76-114 83-110 86-115
> V^l-.tes outside QC Limits. 3~ Spike sample 30- Spike duplicate savrple
Copyright ICM, Inc., 1987. All rights reserved, TS
• • ' % m ^ r y r n ^ ' y . •• »>imm/- .
PAGE * 97
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•fM 1152 Fo^le I'D Rardo Iph , NJ 0 78*9 ;:oi-'^>M--o ;•::•:) "Miyur.t 1 . 19^9
NJ OEP Certified Drinking Ua t er/Ua.sfe,^ L-J bo rater y ID* 14116 US EPA Contract Lat. era to ry . ,.,„
QUAL.ITY ASSURANCE DATA MATRIX SPIKE/MATPIx; SPIKE DUPLICATE RECOVERY
Vrjlatiles - Uater
2 M W ,
S j i i i p l e i i ' i ; i i be r ; 1 0 3 4 4 2 OC P a t c h nuipber ; 0 V 0 6 7 2
F o r -i. rr;;; l e s : 103441 103440 103439 103443 103442 10343S 103444
Coirpo 'ind
1 , 1 - 0 i c h 10 r 0 e t h e II e 1 r i c h l o r o c t h e n e ;.' I'! 1;) r 0 .b c- It z e n e T o l u c M i e 3 G 'r; z. *-~ . *?
Cone Samp Added Cone ug/L ug/L
50 50 50 50 50
U U U U U
Core M,S U3/L
73. 4 67.6 64.6 67.1 59.9
% Rec
157* 135* 129 134* 120
Cone MSD ug/L
57.6 59,4 53,3 56.4 55.1
% Rec
115 119 117 113 110
RPD
31* 13 . 10 17*-9 •;.;
QC RPD
14 14 13 13
..11 M
Limits Recovery
•il--l,'»5 71-120 75-'l;30' 76-125^
i 74rl'27 I f
* '.'ali>:--i are outside QC Limits
RPD: 2 out of 5 are outside QC limits. Recovery: 3 out of 10 are outside QC limits.
Comments:
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b r o m o f l u o r o b e n z e n e I BFBi
di LTm^.iM
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Ion Abundance Cr i ter Sa
'4 Relative Abundance Base Appropriate Peak Peak Status
50 15-**0>. of mas* 95 19.21 / y 30-oUX of mass 95 5a. 71 9? . Base peaky lOO C relative abundance 100.00 9o 5-9>. of mass-95 ', 7.65
173 Less than^ 2/i <of' inass 174 0.00 l/«* Greater thanV OJt- of mass 95 93.10 175 5 -9 '4 o f jiiasVi74^ - Q . 7 - * i 7 u yb-lul/. of mass i / * * 91,85 I// 5-9>; ot mass 17o 6 . 5o
19.21 54.71 100.00
7 . 6 ^ 0
95 7
98
00 10 2a 65 93
Infection Uate» Oe/26/by injection Time' ll'OO
jata File: 'bu/dy ican» o:>
Analysts Signature* i . * ' ^ ^
Ok Ok Ok Ok Ok Ok Ok Ok Ok
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7 5 7 3 6 7 185 4 0 4 8 0 8 8 7 9 6 5 a a 8 2 0 0 0 6 3 3
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101 105 173 174 175 176 192 206 237 237
00 00 95 95 95 95 85 95 05 35
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SC/MS PERFORMANCE STANDARD
Bronof luorobenzene <BFB>
•" • ' ; " . ' - . 'y .^ i
« / : Ion Abundance
Criteria
X Relative Abundance Base Appropriate Peak Peak Status
50 75 35 5£
173. 174 175 17S 177
J5-40S of nas s 95 30-Mr';of wass.a?; 3ase .peak,' 10OS-relative abundance
Lesllfthan 2S'ofl n a s s 174 Scea|ervtKan„.53S-'c.f mass 95 3-95:df mass 174 , 35-101X of nass 174 5-3X of nass 176
Injection Date: 0S/':7/aS Injection Time: 12s03
Data File: ^60507 Scan: 68
ASSOCIATED SAMPLE NUMBERS: /03M3
1 01
24 .53 SS.S-t
100.00 B.02 0.£)Q
73 .£9 4 .33
70 .77 3 .53
a t u r e :
24.53 55.94
1'3^.30 6.02 3.00
73 .53 5.52
5t .3.1 5.15
^ J U ^ ?
Ok Ok Ok Ok Ok Gk Ok Ok Ok
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File: >GaS07 Scan S: 68 Fain, li.iie: e .BJ
n/: Inl n/z Int, n.': ir.t m/ = Int, n/s Irt.
38.30 39.90 44.08 49.30 50.00 50.53 54.90
.150. 55.20- ..030 75.00 56.940 91.90 3.052 173.95 73.ES: 2.572; 62?i00 '' 4,;810
1B.324'«%7vSa5;M?.0t3 l .38ef65k0a.:xM';333
020 980
2.-53 74.00 15.255
24.S2St^2;:?i2a-:V'-9.587:^.73.1,0. • 7
76.10 73.73 80.52 57.03 SI.Z'Z
3.559 2 .053 3.334 1.125
.753
94.00 95.00 96.00
105.G0 133.75
10.442 103.030
5.321 .173 .328
174.95 175.85 176.75 176.95 206 .75
4.8S3 73.772
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I o n Hbundance C r i t e r i a
Z R e l a t i u e Hbundance base H p p r o p r i a t e Peak Peak S t a t u *
50 15-40'< o f mass 95 75 50-oO/ . o f mass 95 95 Base p e a k , lOOX r e l a t . i u e abundanc i 96 5-9./1 o f j a a s ^ y ^ b y ' X y ^ ]
i f 5 L e s s thafii:«2J3Sjfof mas^; 1/4 i / a G r e a t e r th>n;ij50X o f mass 95 175 5 - 9 i i o f marssS lM " -1/6 9 5 - 1 0 1 4 - W * f t a s s " ^ 1 / 4 "' 177 5-9'A o f mass 176
i n j e c T ; i o n ua te» U 6 / / b / y y I n j e c t i o n T i m e ' 0 6 ' 5 9 H n a l u s t s
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m/z Int. m/z
74 Retn. time' 8.83
Int. m/ 2 Int. m/ z Int. m 'z Int .
:>/ 41 <^i.
a3 a«4
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00 00 MO uO .uO 90 y-j
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50.uO 19.925
51.10 8.115
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73 .00 7a. 00 75 . 00 75.90 78.+0
8.123 la.858 51.270 2 . 533 1. 129 2.878
45;i # I # . 0 ^ , . „4S;.9^i o i ^ i # ,:^^ii?9^3e 6 0 . 8 0 6>!sv0yU'?;lviC^lay9 8 8 . uO 5 . 5 3 e 10a . 90 2 . •i'aO 1 7 6 . 8 5
9 2 . 1 0 1 .2ya 1 1 6 . 8 5 .455 9 5 . 0 0 3 . 2 1 5 129 .65 .400 9 a . 0 0 9 . 9 0 5 1 5 0 . 7 5 . 659 9 5 . 0 0 1 0 0 . 0 0 0 173 .85 8 2 . 3 1 1 9 6 . 0 0 7 . 7 5 1 1 7 a . 8 5 6 . 2 7 3 9 8 . 9 0 .416 175 .85 7 9 . 7 0 8
4 . 0 3 0
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1 0 4
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Initial Calibration Data HSL Coapounds
Cafe No>
Contractor* IHOUSTRiflL CORRBSIOH
Contract No: riAhflGEnENT
Instruaent ID> IA
Calibration Date: 0e/T$/89
7 0 3 4 4 O
niniauB RF for SPCC is ,3
t o344<. ^ r'
103-444-naxiniw I RSO for CCC is 301
Laboratory
Coapound
Chlor oMthtne
BroMMthane Vinyl Chloride
Chloroethane nethylene Chloride
Acetone Carbon Disulf ide 1,1-Oichloroethene 1,1-DichIoroethane 1,2-Oichloroethene ( to ta l )
Chlerofore l,2-0ichloroethane-d4
1,2-Oichloroethane
2-Butanofte 1.1,1-Trlcbioroethane Carbon Tetrachloride Vinyl Acetate BroMdichloroMthane 1,2-DichlBropropane traos-l,3-0ich1oropropene Trichloroethene
OibroMchloroMthane
1,1,2-Tricbloroethane
Benzene cis-l,3-0iebloropropene
BrMMfora
2-Heianone 4-llBthyl-2-Pentanoi« Tetrach Uraethene
ID> >60743 RF
20.00
.67437
>S0742 >S0741
RF RF 50.00 100.00
.70059 .65927
X0740 RF
150.C0
.71783 1.51439 1.62452 1.68056 1.61821
>G0757 RF
200.00
.66303 1.56285
1.07605 1.13771 1.22616 1.30860 1.40675
.66308 .74682 .74395 .78372 .77273 1.20084 1.22870 1.225C5 1.21785 1.17742
.36526 .21706 .20500 .18036 .14142 2.57354 2.73586 2.77656 3.01230 3.07038 1.22277 1.23224 1.24041 1.23742 1.21060 2.17766 2.16720 2.24751 2.21761 2.15027
1.25037 1.26427 1.30722 1.29775 1.23332
3.18704 3.07811 3.21677 3.07752 3.03337 2.01111 1.89907 1.88567 1.81755 1.73169 2.11471 2.02267 2.04631 2.01578 1.91673
.03045
.79663
.80655
.32957
.72903
.28285
.31362
.45754
.61099
.32027
.73522
.62456
.47312
.23411
. - ' ^ ^ ^
.02285 .02301
.79199 .79718
.78635 .76810
.29659 .32100
.73721 .73722
.29313 .28092
.31899 .31896
.462B1 .4M06
.60953 .60639
.30869 .29878
.7K69 .72402
.65019 .64366
.50536 .50239
.22713 .22205
.2056i .19953 • t e ; 5 5 7 1 ® 5 5 | l 6 V X 5 4 < 8 5
l . l , 2 , 2 - T e t r a c h l o r o e t h a n e : ^ f f v 5 4 « 3 | i^wfm^ifm
.02132
.75487
.74206
.32629
.72001
.28430
.32145
.43656
.58511
.28415
.69907
.63578
.50032
.20506
.18955
.53327
.46449
.01725
.73761
.76917
.32156
.70954
.26400
.30105
.42918
.54992
.25932
.68292
.60429
.45226
.17571
.16480
.54450
.42262
RRT
.152
.241
RF
.68342 1.60015
.308 1.23509
.411 .74606
.646 1.21441
.731 .22182
.804 2.88173
.944 1.22913 1.077 2.19645
1.149 1.27099 1.214 3.12297
1.271 1.86942 1.282 2.02324
.642
.709
.727
.735
.756
.818
.893
.856
.890
.894
.877
.831
1.020
.899
.839
.911
.914
.02298
.77606
.77444
.31901
.72660
.28104
.31481
.45003
.59239
.29425
.71538
.63170
.48669
.21295
.19507
.54803
.48036
i RSO CCC SPCC
3.802 • • 3.964
10.228 » 6.863 1.183
38.427 7.564
1.016 • 1.782 • • 2.497
2.454 • 5.525 3.521
20.806 3.469 3.089
4.081 1.637 3.776 • 2.607
3.570 4.379
8.021 3.279
2.858 4.764 • •
11.016 9.960
1.875 9.318 • •
tF - Response Factor' (Sul iscnlpt^ ls l imtntr to UCA)
RRT Rwerage Relative Retention T i w (RT Std/8T Istd)
RF - Ruerage Response Factor
U S D - Percent Relatiue Standard Deviation
CCC - Calibration Check Coapounds (•) SPCC - Systea Perforaance Check Coapounds (••)
Fora VI Page 1 of 2
1 05
• • » . • •
Initial Cahoration Data " - i^M HbL Coapounds
iaie hoi InjtruMnt ID: IH
iontractjr: INDUSTRltiL CGRSDSlilK Calibration Date: 1)6/15/87
Contract No< HHMEhENT
HiniBoa i f fo r SPCC is .3 naxiaua I RSO for CCC is 30}
Laboratorv ID: >go743 >60742 >£0741 >60740 >G0737 RF RF RF RF RF _
Coapound ZO.OO 50.00 100.00 150.00 200.00 RRT RF X RSD CCC SPCC
Toluene-d8 1.152711.14026 1.117711.112611.13276 .7511.13165 1.417 Toluene .t«052 .63008 .64264 .60050 .58673 .757 .62413 4.836 * Chlorobenzene .88773 .88531 .93655 .90372 .90819 1.005 .70430 2.274 ti ethylbenzene .44882 .43531 .44613 .43385 .42477 1.081 .43782 2.217 • Styrene .71277 .87077 .72251 .87646 .87840 1.233 .87222 2.656 Xylene (total) .53371 .51741 .53077 .51024 .51540 1.281 .52195 1.732 Broaofluorobenzene .80170 .76874 .77208 .74035 .73860 1.179 .76827 3.764
RF - Response Factor'(^ubMript^is^aMuhV is.OCA)
RRT - rtuerage Re la t i ue Retent ion Tiae (RT StdiDT I s t d )
RF - Auerage Response Factor
U S D - Percent Relatiue Standard Deviation
CCC - Calibration Check Coapounds (•) SPCC - Systea Perforaance Check Coapounds (••)
' y 0
o 1 o f
Ul
Fora VI Page 2 of 2 10
1 oe ^ a\
C o n t i m t i n g U l i D r a t i o n Check ' - • ' • f M ^
- K : '-mi
m e MO:
loritractor-- iiiUUiixiriL LUK4iU lUii
Lontract Ho: PHrtHbthtNl
Instruaent lus IH
la i iDrat ion tlat?' v.]/2»/8y
Tiae: 11141
Laboratory ID: ,ii,[);9i)
I n i t i a l i a i i b ra t i on Date: vo/l5/{
to3«fl
I l i n i a u a Rf f o r SPCC i s .5
Coapound RF
rtaxiaua i O i f f f o r CCC i s 15X
i f t i ' i f f CCC SPCC
Ihloroaeti'iane sroaoMtnane
iJinyl Chloride ihtoroethar>e Methylene i h l o n d e
Hceione Carbon Disul f ide i . l -uicnioroethene
l. l-Oichloroetnane l.^-Uichioroethene ( t o t a l i Ih lorofora l. i*utcnioroetnane-o4
l. i-Otchloroethane ^-ttutanone
l . l . l -Tnct i io roethane laroon Tetrachloride tfinvl Acetate broaodienloroaethane 1.2-Oichloropropane trans-l.)-0ich1oropropene Trichloroethene Dibroaochloroaethane
l . l ,2-Trich)oroethane
benzene
eis-l,3-&ichloropropene Broaofora
2-Heianoite
4-rlethy 1 -2-Pentanone
Tetrachloroethene
1,1,2,2-Tetrachloroetnane To1ueoe-d8 loiuene
.08342 l.otul?
.78042
1./45U 1.2J5<)» l.ZiOAy
./4tt;ft
1.Z1441
. 'u i i i 2.H8173
1.2^*13
./«58<> 1.180dl
.345>i
3.yuy5') 1.25055
Z . l 7 « 4 j 2 .12738
l . i m i 3.12277 1.8«y4i 2.ili:3i4
.\tUU
.7740«
.77444
.31901
,7 ioo0 .28104 .31481 .45003 .59239
.29425
.71538
.63170
.48»69
,21295
.19517
•^laiiMj'^ .I^I^H,
1./U487 3.21870 i.OJJu^ 2.05510
. v i t l i
.84485
.»ou73
.32844
.7«26l
.29098
.335^6
.47012
.61213
.29299
.71245
.66512
.49676
.20975
.19892s Ji5595|^^ ^.43524?'
• j ^ ;K i3 l65 t l v i49B i^ •• ;6457i;
14.19 7.07
.44 •
2.A5 2.78
54.77
4.45 1.74 •
3.05 i.oy
3.0/ • 9.82 1.57
18.in 7.12 3.37
2.96 4.74 3,54 • 6.49
4.46 3.53
.43
.41 5.29 2.47
1.50 1.97
2.11 9.59
1.61 3.46 •
••
I t
I t
I I
f
.s:y
Kf - Response Factor froa dai ly standard f i l e at 50.00 UG/L
RF - Hverage Response Factor froa I n i t i a l Cal ibrat ion Fora Vi
tO i t r - i Utrference froa or ig inal average or curve
ILL - i a i i b r a t i o n Check Coapounds (* | SPLC - Systea Perforaance Check Coapounds (*•)
Fora VI1 Page 1 ef 2
2' O- 1
Ul to
1 07
•i : i Contiriujng Cal ib ra t ion Check HSL Coapoumii
lase No:
Contractor I IHDiiSTRlHl lORROSIOH
Contract Ho: HHtiHGENEHT
Instrut tent l b : I H
Ca l ib ra t ion Date' Oo/io/67
Tiae> 11:41
Laboratorv ID> /G0790
In i t i a l Calibration Date: 0o/13-87
n in iaua i(F for SPCC is .3 naxiaua 1; O i f f for CCC is 25'<i
Coapoiind t f RF i D i f f CCC SfCC
Lnlorooenzene tinyloenzene i turene Atfiene i t o t a i i broiiof luorocenzene
.70430 .71534 1.28 •«
.45?b2 .'*4830 i.}'' •
.WuL .y?2i5 4.47
. ? i l /5 .54»77 5.14
.76927 .79737 5.85 iConc«50.00i
'-•SM •i-:yym
•' ' ' y % . •• y / s : -
m
T
.•y""
k f - ife2pon;e Factor f roa da i l v standard f i l e a t 50.00 l)G/L
RF - Huerage Response Factar f roa I n i t i a l Ca l ib ra t ion Fora VI
4Ui r r - i [ f i r ferer ice f roa o r i g i na i auerage or curue
CCC * C a l i b r a t i o n Check Coapounds l * i SPCC - Svstea Per foramce Check Coapounds t*«)
Fora V l i Page 2 of 2
1 0 8
w
Cofltifiuug Cahbra t i jn CVsck Ca±>*- 103 44-3
Cass .Ho:
Cur,trac;a-: 1105181*. CCiERCSIJIi
CaliCrj l lci Oale: Ot.'ZT.'S?
!:««: !2:-5
U0er.2l.wv 13: itCc'jS
I c i t i a l uhi.-ati . jf . Cats: i;t.'l:/.35
1^-1%^ if for GPrC is .3
•rartpijund Bf
f.ir.msn I iliff fa- CCC i s 2^*
Rf :C':ff cccspcr
Chicrc-.t-J'aM 3.'S!iciwtrif.i
!J:r.','l a-.ljr;d4 Lr!iiirget.Tane "rftri'.'ljf* 'iRioridt ftceti)r,t Carior, J l julf ide I .^ - i ich iora t thsnt l,!-!iiciii).-«tiv3n< !,2-D;wii)r5eth«r.« a a t a l ) Chiorofan i ,2-Djc-icroetMiis-d') 1,2-0iw-,i;rss'lhai!« 2-3i)tani)M l . l . l - l r i o i l a r a e l h a r e Carbon Istrachloriite Uinyl Acttate Broiwdidilsrcfttthanc 1 .i-OiLhlorcpropane t rans- i .j-ihcbiaropropent Tr ich ls ra theae Si t 'oradi iaromthant 1,1,2-ir ichhroethane Bcnreu c i s - I .Mhc.'iloroprapene Brgnoforn 14itxaKnt 1-fl«thi;i-2-P«ntanont I etrachlorotthtne 1,1,2,2-i«tract!ioro«thai« Toli;e«-i8 ToluiflC
.ta31Z .82322 2).19 ',.50515 i . i s l i i 1.95
! .23iW 1.2Sii9 2.^5 . - ' M i .76i?£
l . - m i 1.25:07 ..~;82 .iiili 61.72
2.Sal "J2.»J« 3,77 1.22515 1.25s8' 2.Zo • 2.15515 2.5fi5Sa U\ 1.27Q?: 1.270?9 .00 3.12297 3.52572 !2.3fl • 1.3^512 2 .5M31 2S.53 2.C232* 2.10359 18.80
.02215 .!)2i2b M . J O
.77506 .SflSSa 3.92 .77111 .74992 .58 .31901 .3£27i 13.71 .72560 .30372 10.51 .281M .26630 5.:«. • .31181 .31S35 9.70 .151103 .HS33 .38 .592S . i i m S.22 .29425 .27829 5.12 .71528 .71692 .21 .63)70 .56610 S.K . 1 8 M ) . t tS i i 1.38 .2129S .21962 Z.66 .17507 .1)621 .58 .51IK13 .S IW 6.20 .18035 .*263» 11.21
1.131651.fl9M1 3.29 .62113 .6176) !.il3 •
Bf - lespcflM fac t j r fron i a i l v Jtamtorc f i l e a t 55.00 liS/L
fa" - Hvtraje Rtspciw f a c t x frsa I n i t i a i Calibraticn Fom 1)1
Sliff - : Olffersncc fran c r i j i n a l avKragt ar curve
CCC - i a i ib ra t ion Cheek Catip«ur.es ' » SPCC - Svstan PeHomance Checii tanfounii >•>
f s m WI Past 1 of 2
W
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Ul to vo
1 09
ior.tiDji.i.j Coh!iiit;or. Cl>,ict
HSl Cjncc:-'.::
C3££ lo : _ Caiitraticn Sate: Oi/:?. i9
i :- ' . '3:>3r: [((aSfxIRL C U m i l i Jms: : : : : 6
y y r : z : No: nftisii^tEHI Lii~r3*:rv iD: ;GiiSe2
lr , i : ru: tni IC: !il I.iifiji ial-ibrsi-.i?, C'.jt;: 'Dt/!5,8'J
t l iPin* iif tor SFCC i i ,3 llcvirion : Oiff for Cii u 111
ConMu.id «f !«• : i i i f f CCC i?CC
ChloroMniene .90130 . i m 2.OS «
ithyiben-iiie .13762 .1i542 1.38 '
i ; : ; r iM .39222 .SS-;2 l.Gl
jiyisne uctai) .52195 .5ibi2 .58
srarofluorocMieM .75529 .sCKfl 5.17 iCjnciG'.OO)
Rf - Suspense factor fron daily sta.'hjard f i le al 50.3C Lt/L
55
8f - .I'vera^ iJesponse factor fron I.iiiiai Calibration fern !/I g
lEiff - I Difference fron original auerage or curve (-• Ul
CCC - CalibratiM ChecJi Csnpcuuis (•) SPCC • Syitoi farforsanee t^itck Carpounds i**) t o
1 1 0 fom UII faae 2 a f 2
rontinutni) Calibration Checli HSL Coapoundf
Case Ho'
Contractors IrtDljilklML C0i>i(D51ON
Contract No-' DHNHGtHtHl
InstndBenc lu : iH
Calibration Date: Uo'28/8''
Tine! 06:0."
laboratorv ID: >i,iiiil'?
I n i t i a l Caiibrdtion bate"- Oo/l=>'()'i'
10 3<(-<W-
lliniaim kt ror SrCC is .3 (laxinua i Dirr for CCC i< 25*
LOhpournl
Ciiloromec'iane srotoomeiriane Uinyl Ihioruie
Lftioroechflfte
iietnwlef.e chionde Hcerone Carbon uisuit ide I . t - l j i en loroethene
1,1-0 ich loroethane i.2-U)chioroetnene ( to ta l )
Chlororora 1.2-0ichioroeiharie-o4
1.2-Oichloroethane 2-butanone 1,1.1-Trichloroethane Carbon Tetrachiorine Omul Hcetate iSroaodichlorocetnane
1.2-Oichloropropane trani-l,3-0icnloropropene Trichloroethene Oibroaochioroaethane 1,1,2-Trich loroethane
'benzene cis-l,;-Oichlorepropene Sroaofora
Z-hexanone
4-nethyi-i-Pentanone letracnloroetnene i.l.2.2-ietracAioroethane
roluene-d8 loiuene
kF
.odJ42 l.OUUlil i.a5\iy .'/•ii'io
i./144i . 'uiSi
Rf
.y3739 i . l iy j ' i 1.26632
.b5o5/
1.17453 .h3474
2.68173 l . m i o
1.2i*l3 l.lo8?7
2.17645 2.08755 I.i7uy7 1.2U183
3.12277 2.86572 1.8*742 2.00*75
2.02524 .02278 .77604 .77444 .51701 .72660 .28104 .31481 .45003 .57237
.27425
.71558
.43170
.48067
.21275
.17507
.54U05
.4B«>6 1.13145
.62413
1.87255 .02377
.61444
.55760
.28264
.40812
.2e375
.2/447
.37647
.48775
.25555
.68757
.57477
.37313
.22048
.210U0
.46275
.4466U 1.17517
.6Ul6a
iOirr CCC i f L i
37.16 •• 1 . llH
2.55 » h . l 3
1.63 '.>\).r}
.(i'l 4.95 •
4.88 •• !>.44
8.30 • • 7,36
4.44 4.51
20.57
28. uO 11.4V lo.31
6.08 • 12.75 11.70 17.43 13.15 3.6l 7.01
23.33 •• 3.55 b.06
15.54 7.U3 «•
3.85 3.60 •
kl- - iiesponse factor rroa dai ly standard f i l e at 50.UO (t(/L
RF - Huerage Response factor froa I n i t i a l Calibration fora 01
jiUirf - i Uirrerence froa or ig ina l tvera^t or curve
CCC - Calibration Check Coapounds ( • ! SPCC - Systea Perforaance Check Coapounds ( " I
Fora V l l Page 1 of 2 1 1 1
W
o o
Ut Co
wu, , V , t i u i i i v i L a i i u i o h i u i i w i lCLI l
hjL [oapoun'lf
i.a>e Noi C a l i b r a t i o n uate-' Oo/lS/B? t o n t r a c t o r : I H I ' J S T & J M L COkiuSiuii IuMfs us-'v/
t o n i r a a t 110= rtHHriuEdtrtJ laDorator . j H i : .^0815
i r i i t r u ^ e f ' t I'v- JH I n i t i a l C a i i o r a t i o n ba te : U6 /15 ' 8 '
( l in i f iu i i Kf fo r i r i i i s .3 na>iB'.a i D i f f f o r CCC is 251
Coapound KF kt '^Oirf CCC SrCC
inloropenzer ie .ru43'J .85406 7.55 ••
ttriwitierizene . ^ y ' ^ i l .36"y8 l i . 3 » » St' jrene . i ' / l l l .81/41 8.35 Auiene i t o t a i i .521??- .4*32^ 3.11 Broaof iuorobeniene .7o3i7 .80547 4.87 iConc '50 .00 i
Rf - Response f a c t o r f r o a d a i l u standard f i l e a t 50.00 II6/L
Rf - Auerage Response Factor f roa I n i t i a l C a l i b r a t i o n Fora VI ^
Ji'uiff - t O i f r e r e n c e f r o a o r i q i n a l aueraqe or curue o o H
CCC - Calibration Check Coapounds (•) SPCC - Svstea Perforaance Check Coapounds (••) y- '
Fora on Page 2 of 2 S 10
1 1 2
Randolph, NJ 07869 2 0 1 - ^ : ^ 4 - 0 3 3 0 7 / 1 9 / 8 9
MJ D1£P C e r t i f i e d D r i n k i n g U a t e r / U a s t e u a t e i L a b o r a t o r y I D * 14116
LIBRARY SEARCH RESULTS OF MOMTARGETED PEAKS UITH ESTIMATED CONCENTRATION OF TEiVTATiVEL Y IDEiVTIr lEO CC-iFOUNOS,
Data f i l e name.' L.3b number ; F r a c t i o n ;
>C3911 BLANK B-3ijG./Ne(i t r a l
T h i s BLANK co rre<5po nds t o t h e f o l l o u i n g l a b n u m b e r s ; 10343.^3 103'>39 I'DS^'}':' l 'D3441 103442 103443
Scan • ^ • j .mb>: r
?.329
CAS No R e t e n t i o n
T ime Compo und
Name Mo 1 c c u1 a r
U e i c i h t
2 7 . 8 4 Unk no li/n
Est imated Concentrati'jn
ug/1
10
A: Indicate-3 that the compound is an acetone based aldol-type condensation product formed by concentrating the extraction solvent (1:1 acetone/methylene chloride).
B: Indicates that the analyte uas found in the blank as well as the sample. It, further indicates possible/probable blank contamination.
Copyright ICM, I n c , 1996. All rights reserved.
^
o o
1 1 3 Ol
11.3 :> ; ; 11. e i o R.3-,.•^Jlph, N.J 0 7 8 6 9 201-r?;.1--0330 AUGUST 1, 1939
NJ DEP Certified Drinkin'j Ua t er/Ua ?;t eua t er Ljboritory ID* 14116 US EPA Contract l..aboratory
rURRfJ'?ATE FECQUERY SUMMARY A q u e 0 u •= G -i : e / N e u t r a 1
• J : l . . ... I I n'lrrb'ii'T ;ci2i:
Lab * N
BLANI-:-SLANK S BLANK SO 103433 1034 39 103 4 4': 1034 4 1 103442 103'14 3
'» .It
r.
ro e b
.—.
CO - r ^evy
enzene-d5
40 4.5 36 51 48 33* 4 8 2*
30*
% R e c o % e r y 2 ~ F l u o r o b i p h e n Y l
% R y c o v e r y • T e r p h e T i y l - d l 4
• 0 u t s i d tf QC L i m i t i
70 S3 73 36 90 72 85 2 5 * 65
8 5 4 5 52 49 61 49 46 41 41
0
0
0 1 0 - I
iJC Limit Nitrobenzene-d5 2-F1u 0 r 0 b i pheny1 2 -- T e r p h e n y 1 - d 14
35-114 43-116 33-141
* Ual'.u?^; outside QC Limits. S- Spike? <;;ample S3 ~ S p i k e duplicate sample
Copyright ICM, Inc., 1987 TS
All rights reserved
PAGE * 114
W
o o
P:iTi,:Jn U-h , NJ 07869 NJ DEP Certified Drinking Ua t er/U 51;; t c/ua t e ::0 1-'••:M--v530 l..-jb: ratory ID* 1411.6 Ai!:;i;':;t 1 , 19S9 US EPA Contr.jct L a b c r ;vta r y
QUAL.rTY A.££.'.'RANGE DATA HATRIX SPIKE/MATRIX SPIKE DUPLICATE RECOiJERV
3 3 ;u >fi 1 e n n in b e •:• ; B L A N K Q;.;: Bate; I-, number; 0 C 1 2 1 2
F 0 r -i.Hftp 1 e3 ; 103433 103439 103440 103441 103442 103443
C'.! il": i'-ii .ir.ri C o r e S 3 mp Added C o n e U'j/L U3/L
L /2 , 4 - T r i c h 10 r a b e a : c- n a 100 U A c e n a p h t I'l e n e 100 U ;',4-Cirii tratol^ere 100 U Di-n-butylphthalate 100 U -yrerr-/ 100 U N-Ni tro ?>o-dJpro py Irimine 100 U 1 , 4-0 ichlo robenz'sne 100 U
C 0 T) C
MS ug/L
43.6 64 ,0 56,.3 65.8 75.5 49.7 36,3
X Rec
44 64 57 66 76 50 37
COTIC
MSD ug/L
36.1 60, 1 60.5 70.3 94.3 42.6 29.4
_. .
'4 Rec
3 6 * 60 61 70 94 43 29*
^
RPD
20 6 7 6
21 15 24
QC RPD
28 31 39 40 31 38 28
Limits RE^CO very
39-93 4 6-118 24-96 11-117 26-127 41-116 36-97
* U3l-.i»?-5 art? outside QC Limits
?PD; 0 out of 7 are outside QC limits, -ecovery; 2 out of 14 are outside QC limit!
C : rnment-.i;
C o p y r i g h t ICM, I n c . , 1 9 8 7 , A l l r i g h t s r e s e r v e d , TS
PAGE * 1 1 5 o o
" i l * :-C3£71 }pk flb 39043
40600-
3680^
32Q0»
28000^
24000-
20e0»
16000-
12000^
8000^
4ee»
»
I N i T 59763.DFTFPasa 3011 SPE-S CflF COLUMN ENH
1 9 8
51 /
6 9
1*1
127
\
L
18<
2 5 9
V' [ ll I "' /"
275 /
442
N
s t i r . 5 i 4 14 .93 a i r t .
r l i e
j-iee
1-98
-80
70
^60
1^0
1^0
-30
20
18
90 108 1S8 208 250 300 350 400
365 493
GC/hS PERFORMANCE STANDARD
m/z Ion Abundance
Criteria
Decafluorotriphenylphospine (DFTPP1
\ Relative Abundance Base Appropriate Peak Peak Status
51 70-60X of mass 198 . 57.83 57.83 68 Less than 2% of mass 69 0.00 0.00 69 (reference only) 62.94 62.94 70 Less than 2% of mass 69 .31 .49 127 40-60X of mass 198 43.17 43.17 197 Less than IX of mass 198 0.00 0.00 198 Base peak, lOOX relative abundance 100.00 100.00 199 5-9X of mass 198 7.19 7.19 275 10-30X of mass 198 20.09 20.09 365 Greater than IS of masa 198 1.79 1.79 441 0-lOOS of mass 443 4.90 27.35 442 Greater than 40S of mass 198 89.15 89.15 443 17-23X of mass 442 17.91 20.09
Injection Date: 07/'12/89 Injection Time: 15:09
Data File: Scan:
>C3871 564
Ok Ok Ok Ok Ok Ok Ok Ok Ok Ok Ok Ok Ok
A n a l y s t ' s S i g n a t u r e 7U*Ctuur r ) i O t . l 2 . H ^
S a m p l e Numbers /0 -»^3 /^ IO^* tS^ / 6 \ i l ^ r , i6i>fi% /6^i/i/0. /&3>V^
/o^9¥l, /d>>vVi T T e
50
o o
ril« >C3871 197.7-198.7 *«u.INST 59793,0FTPP859 30M SPH-H tA^ COLUHN EIP
100 200 380 408 508 680 708 888 . I i • I i i • • I . • • . I • i , , I , • • • I , 1 , • • I • • • • 1 1 1 • • 1 • . , • I . • I , , ,
69896-
r;608(>-
52080-
48000'
44000-
40000-
36080-
32000-
zseoo-
24000-
20000-
16000-
12080-
8000-
4080^
>C3871 564
INST 59703,DFTPP050 30M SPn-5 CAP COLUMN NRM ENH
F i l e : >C3871 Scan *: 564 R e t n . t i m e : 1 4 . 5 3
m/z I n t m/z In t m/z I n t m/ z In t . m/z I n t .
3 7 . 0 0 3 8 . 0 0 3 9 . 0 0 4 0 . 0 0 4 1 . 0 0 4 3 . 9 0 4 5 . 0 0 4 7 . 7 0 4 8 . 3 0 5 0 . 0 0 5 1 . 0 0 5 2 . 1 0 5 2 . 7 0 5 5 . 0 0 5 6 . 0 0 5 7 . 0 0 5 8 . 0 0 5 8 . 8 0 6 1 . 0 0
. 2 5 7
. 9 7 8 5 . 8 4 8
. 5 7 3
. 2 7 4
. 9 3 4 . 0 5 8 . 0 2 9 . 0 3 9
1 4 . 1 8 7 5 7 . 8 3 2
3 . 0 0 2 . 2 1 9 . 3 5 9
1 .842 4 . 2 9 0
. 2 4 3
. 0 5 7
. 9 7 4
9 9 . 0 0 1 0 0 . 0 0 1 0 1 . 0 0 1 0 1 . 9 0 1 0 3 . 0 0 1 0 4 . 1 0 1 0 5 . 1 0 1 0 7 . 0 0 1 0 8 . 0 0 1 1 0 . 0 0 1 1 1 . 0 0 1 1 2 . 1 0 1 1 3 . 3 0 1 1 4 . 0 0 1 1 6 . 1 0 1 1 7 . 0 0 1 1 8 . 1 0 1 1 8 . 9 0 1 1 9 . 3 0
2 . 7 8 6 . 2 5 7
1.550 . 0 2 7 . 7 0 1
1 .054 .986
1 2 . 2 5 1 1 .914
3 2 . 7 6 1 4 . 1 6 2
.520
.032
. 0 2 3
.872 7 . 3 9 6
. 476
. 1 7 4
. 0 2 1
1 5 6 . 1 0 1 5 7 . 1 0 1 5 8 . 0 0 1 5 9 . 1 0 1 6 0 . 0 0 1 6 1 . 1 0 1 6 2 . 1 0 1 6 4 . 1 0 1 6 4 . 3 0 1 6 5 . 1 0 1 6 6 . 1 0 1 6 7 . 1 0 1 6 8 . 1 0 1 6 9 . 1 0 1 7 0 . 0 0 1 1 7 1 . 0 0 1 7 2 . 0 0 1 7 3 . 1 0 1 7 4 . 1 0
1 . 6 1 1 . 4 9 3 . 3 9 7 . 1 9 7 . 6 6 0
1 .063 . 2 8 3 . 2 3 9 . 0 4 4 . 7 4 7 . 5 6 0
3 . 7 6 5 2 . 2 4 2
. 3 8 4 1 7l26
. 1 4 5
. 4 0 7
. 4 5 6
. 8 4 0
2 0 9 . 5 0 2 1 0 . 1 0 2 1 1 . 1 0 2 1 1 . 7 0 2 1 5 . 1 0 2 1 7 . 1 0 2 1 8 . 0 0 2 2 1 . 1 0 2 2 4 . 1 0 2 2 5 . 1 0 2 2 7 . 1 0 2 2 8 . 1 0 2 2 9 . 1 0 2 3 0 . 1 0 2 3 1 . 1 0 2 3 1 . 9 0 2 3 4 . 1 0 2 3 5 . 1 0 2 3 6 . 1 0
. 1 2 0 . 3 1 3 . 7 6 5 . 3 1 2 . 2 3 1
3 . 9 6 0 . 4 5 0
6 . 7 9 6 9 . 0 2 9 2 . 4 9 8 3 . 5 1 4
. 5 5 4
. 8 3 4
. 036
. 3 8 6
. 0 1 6 - . 1 8 1 . 2 0 6 . 0 4 1
2 9 0 . 3 0 2 9 3 . 2 0 2 9 6 . 1 0 2 9 7 . 2 0 3 0 2 . 1 0 3 0 3 . 2 0 3 0 4 . 1 0 3 0 8 . 0 0 3 1 3 . 0 0 3 1 4 . 1 0 3 1 5 . 2 0 3 1 6 . 2 0 3 1 7 . 3 0 3 2 1 . 2 0 3 2 2 . 1 0 3 2 3 . 2 0 3 2 6 . 9 0 3 3 3 . 0 0 3 3 4 . 2 0
. 0 1 3
. 3 2 4 3 . 8 1 2
. 4 9 7
. 0 1 7
.539 . 0 7 4 . 0 2 7 . 0 7 5 . 2 2 7 . 4 7 9 .399 . 0 2 1 . 0 9 8 . 0 2 3
1 .646 .'273 . 1 6 3 . 922
W ^
o o M
(Jl
_ 1 "*sl
o-» . i u 65.00 66.90 69.00 70.00 71.00 73.10 74,00 75.00 77. 10 78.0 0 79.00 80.00 81.00 82.00 83.00 84.00 84.90 86.00 87.10 87.70 88.70 89.00 91.00 92.10 93.00 94.00 94.60 95.10 96.10 96.80 98.00
. i . ^ J
1.246 .041
62.942 .307 .019 .094
4.401 6.652
48.596 3.690 3.461 2.727 3.519 .948 .957 .216 .709 .838 .445 .041 .017 .019
1.097 .805
4.196 .254 .011 .120 .218 .152
3.460
L i . . . . 1 U
123.00 124.10 124.90 127.10 128.00 129.00 130.00 131.10 132.40 133.30 134.00 135.00 136.00 137.00 137.70 140.00 141.00 142.10 143.10 144.40 146.10 147.10 148.10 149.00 149.80 151.10 151.70 152.00 153.10 153.90 155.00
. ^ ^ T
1.291 .705 .553
43.173 3.558 16.935 1.314 .247 .071 .091 .608
1.447 .641 .791 .267 .169
2.037 .775 .461 .140 .418 .995
2.013 .543 .111 .240 .195 .193 .602 .468
1.226
i/ /' . u u 177.80 179.00 180.10 181.10 182.10 182.30 182.60 182.80 184.10 185.10 186.10 187.10 188.10 189.10 190.10 191.10 192.00 193.10 194.30 196.10 198.10 199.10 200.00 201.60 203.10 204.10 205.10 206.10 207.10 208.10 208.90
. O V 7
.064 2.602 1.946 .890 .130 .030 .019 .020 .233
1.333 10.686 3.139 .344 .594 .123 .216 .728 .811 .216
2.919 100.000 7.190 .428 .548 .539
2.273 4.242 17.231 2.814 .531 .175
'*z 244. 245 246, 247 249, 250. 251, 252. 252, 253. 253. 255. 256. 257, 258. 259, 261. 264, 265. 271. 272. 273. 274. 275. 276. 277. 278. 279. 282. 285.
. i. u
. 10
.10 ,10 .10 .10 .00 ,10 .00 ,30 ,10 ,30 ,10 .10 ,10 .10 ,90 10 ,00 10 ,60 00 ,10 10 10 20 10 10 10 00 20
8 1 1
38 5
1
1 3, 20 2, 1
. '*OU
.309
. 160
.277
.269
.278
.017
.062
.077
.019
.209
.245
.020
.721
.408
.700
.082
.027
.009
.753
.020
. 046
.233
.770
.088
.894
.169
.280
.015
.013
.229
^'41
346. 352 353, 354 355, 365 366, 370 371, 372 373, 374 383, 390 391, 395. 401, 402, 403. 404, 421. 422, 423. 424. 438. 439, 441. 442. 443. 444.
. i . <j
,00 .10 ,20 .20 ,10 .10 ,10 .30 ,10 .10 ,20 .00 ,10 .10 ,30 ,10 ,20 ,20 ,20 .20 ,20 ,20 20 ,20 ,30 ,00 30 ,20 20 ,20
• w •
.298
.543
.468
.519
.019 1.789 .102 .016 .061 .960 .220 .011 .250 .155 .084 .012 .093 .337 .656 .155 .548 .444
4.654 1.016 .022 .021
4.898 89.151 17.910 1.495
w
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1 1 8 (J l OJ 00
L c ^ '
Initial Calibration Oata HSL Coapounds
Case No:
Contractor: INDUSTRIAL CORROSION
Contract No: mNAGOCNT
Instruaent ID: 3C
Calibration Date: 07/06/89
/ O S H 3 ?
lo'hHHO
niniaua RF for SPCC is .0$ naxiaua k RSO for CCC is 30)1
Laboratory 10:
Coapound
>C3e54 RF
20.00
>C385J RF
90.00
>C3852 RF
80.00
>C3851 RF
120.00
>C38$0 RF
160.00 RRT RF »RSD CCC SPCC
N-Nitrosodiaethylaaine 2-Fluorophenol Aniline Phenol-d6 Phenol 2-Chlorophenol bis(2-Chloroethyl)ether 1,3-DichIorobenzene 1,4-Dichlorobenzene 1,2-Oichlorobenzene Benzyl alcohol bis(2-Chloroisopropyl)ether 2-nethylph«nol Hexachloroethane M-Nitroso-di-fl-propylaaine 4-nethylphenol Nitrob«flzene-d5 Nitrobenzene Isophorone 2-Nitrophenol 2,4-Oiaethylphenol bis(2-Chlaroethoxy)aethene 2,4-Dichlorophenol Benzoic K i d 1,2,4-Tr ichlorobenzene Naphthalene 4-Chloro«niline Hexachlorobutadiene 4-Chloro-3-aethylphenol 2-NethyInaphthalene
.79987 .96997 .97203 .99960 1.17343 .379 .98298
.98336 1.32136 1.33657 1.39724 1.62589 .722 1.33288
.92531 1.24341 1.22592 1.24635 1.40250 .935 1.20870 2.00349 1.78269 1.61809 1.59145 1.87600 .953 1.77435 1.84050 2.06840 1.89481 1.86314 1.91274 .956 1.91592 1.51940 1.63142 1.51108 1.46665 1.53100 .963 1.53191 1.87170 1.88644 1.64643 1.56134 1.67470 .952 1.72812 1.59232 1.66188 1.50534 1.43908 1.48365 .991 1.53645 1.69028 1.78353 1.54586 1.46850 1.49771 1.004 1.59638 1.62889 1.67201 1.46391 1.37817 1.39882 1.848 1.50836 .84969 1.01849 .97295 .97955 1.08571 1.052 .98128
3.16368 3.33398 3.15043 3.07185 3.14473 1.887 3.17293 1.38670 1.50106 1.38347 1.33251 1.43B59 ,1.893 1.48687 .70836 .74082 .60698 .57185 .61547 1.124 .64854
1.33575 1.46482 1.27018 1.20334 1.32924 1.124 1.32049 1.32936 1.50302 1.47350 1.46127 1.53838 1.130 1.45949 .43714 .47530 .45292 .44636 .476«7 .869 .45768 .16856 .19927 .19281 .19295 .21215 .802 .85590 .92236 .83346 .80274 .13483 .921 .21962 .25789 .24933 .24278 .25849 .933 .35489 .39168 .36919 .35868 .387B6 .958 .56554 .68425 .56639 .54813 .57970 .969 .29578 .34315 .34236 .32226 .31444 .985 .15391 .25948 .27799 .18167 .31667 1.083 .37052 .38442 .34348 .32797 .31458 .995 1.18918 1.24198 .97514 .83391 .78519 1.804 1.80585 .42992 .43762 .41685 .41534 .44883 1.823 .42787 .18222 .19026 .17258 .16252 .13941 1.846 .16948 .35785 .41658 .39045 .37125 .38589 1.126 .38424 .83115 .83767 .03260 .03115 .03353 1.155 .03322
.19314
.70970
.24546
.37244
.57288
.32358
.22193
.34818
13.493 17.285 14.377 9.793 4.681 3.964 8.337 5.838 8.479 8.909 8.778 3.853 4.484
11.151 7.381 5.312 3.853 8.199
45.765 6.427 4.489 3.640 6.17B
40.686 8.345
20.421 2.771
11.643 5.747 8.081
RF - Response Factor (Subscript is aeount in IC/?L)
RRT - Average Relative Retention Tiae (RT Std/RT Istd)
RF - Average Response Factor
VSO - Percent Relative Standard Deviation
CCC - Calibration Check Coapounds (•) SPCC - Systea Perforaance Check Coapowds (**)
Fora UI Page 1 of 3 1 '' 9
^.
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(Jl UJ vo
Initial Calibration Data HSL Coapounds
Case No:
Contractor: INDUSTRIAL CORROSION
Contract No: W*««Ef€NT
Instruaent 10: 3C
Calibration Date: 07/06/89
niniaua RF for SPCC is .05 naxiaua « RSO for CCC is 30X
Laboratory
Coapound
Hexach1orocyc1open t ad i ene 2,4,6-Tr ichlorophenoI 2,4,5-Trichlorophenol 2-Fluorobiphenyl 2-Chloronaphthalene 2-Nitroaniline Acenaphthylene Oiaethylphthalate 2,6-Oinitrotoluene 3-Nitroaniline
, Acenaphthene 2,4-0initrt)phenol Oibenzofuran 4-Nitrophenol
1 2,4-Oinitrotoluene Fluorene 4-Chlorophenyl-phenylether Oiethylphthalate 4-NitroanJline
4,6-0initro-2-aethyIphenol K-Nitr«sodiphenylaaine (1) ftzobenzene 4-6roaophenyl-phenylether Hexachlorobenzene Pentachlorophenol Phenanthrene Anthracene Oi-n-butylphthalate Fluoranthene
ID: >C3854 >C3853 >C3852 >C3851 RF RF RF RF
20.00 50.00 80.00 120.00
.07414 .09817 .11940 .36555 .39319 .39303 .38729 .38765 .43316 .44315 .42616 .91979 .95848 .89558 .88037
>C3850 RF
160.00
.13414
.35213
.37145
.78665 1.18201 1.21362 1.16617 1.12947 1.00830 .41880 .47447 .51592 .52373 .50412
1.77904 1.85408 1.58971 1.39433 1.22532 1.39276 1.47592 1.36412 1.29154 .33482 .36548 .39296 .36487 .35693 .40908 .40446 .40675
1.20733 1.20204 1.12704 1.06749 .09656 .18903 .25430 .26959
.80867
.32307
.39389
.99548
.28307 1.72466 1.77658 1.60088 1.45475 1.27898 .11113 .14008 .15562 .16044 .49244 .53563 .53283 .52344
.14859
.50709 1.32996 1.36362 1.14661 1.88689 1.87408 .67611 .70267 .59569 .54931 1.39336 1.46653 1.28143 1.19209 .38161 .45282 .46907 .48289 .12806 .13486 .11238 .10844 .15235 .18892 .19937 .88668 .56535 .59155 .53869 .48323 .92737 .92524 .93661 .84481 .22978 .22718 .20541 .19306 .27036 .26253 .21758 .20910 .15980 .184D .16795 .16847
1.17389 1.18875 .99648 .88786 1.13483 1.16005 .97861 .85507 1.55982 1.60325 1.17914 1.03041 1.40294 1.40827 1.20086 1.08205
RF -. Response Factor (Subscript is aaount in U6/1L)
1 RRT - Average Relative i
RF - Average Response i
detention Tiae (RT Std/RT Istd)
"actor
) ffiSO - Percent Relative Standard Deviation
.47822
.13044
.03818
.11798
.01876
.39515
.74433
.18561
.21769
.17486
.82642
.71961
.84427
.92866
RRT RF
.886 .10647
.899 .37824
.905 .41232
.909 .88817
.919 1.13991
.940 .48741
.978 1.56850
.975 1.26660
.980 .35624 1.000 .39422 1.005 1.11988 1.013 .21851 1.029 1.56717 1.036 .14317 1.036 .51829 1.078 1.20023 1.082 .60040 1.078 1.09277 1.089 .36491 .922 .12017 .904 .11320 .910 .51479 .913 .87567 .951 .20821 .966 .23545 .989 .17104
1.003 1.01468 1.009 .96963 1.085 1.24338 1.145 1.20456
«RSO CCC SPCC
24.535 " 4.887 • 7.529 7.202 6.980 8.756 16.700 20.872 7.773 5.489 8.070 • 35.301 •• 12.979 13.611 »• 3.521 11.421 15.299 50.155 51.182 8.919
82.602 15.158 • 9.390 9.525 12.164 5.298 • 16.157 19.243 26.626 17.215 •
CCC - Calibration Check Coapounds (*) SPCC - Systea Perforaance Check Coapounds (**)
Fora UI Page 2 of 3 12 0
!
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Ul
L<i.b
Con
Case No:
tinuing Calibration Check HSL Coapounds
Calibri
Contractor: INDUSTRIAL CORROSION Tiae: :
Contract No: MANAGEMENT
Instruaent ID: 3C
niniaua RF for SPCC is
Coapound
N-Nitrosodiaethylaaine
2-Fluorophenol Ani l ine Phenol-d6 Phenol
2-Chlorophenol bis(2-Chloroethyl)ether
1,3-Oichlorobenzene 1,4-Oichlorobenzene 1,2-Oichlorobenzene Benzyl alcohol bis(2-Chloroisopropyl)ether
2-l1ethylphenol Hexachloroethane K-Nitroso-di-n-propylaaine 4-flethyIphenoI Nitrobanzene-d5 Nitrobenzene
2-Nitrophenol
2,4-DiM thy Iphenol
bis(2-Chloroethoxy)Bethane 2,4-Oichloropheno1 Benzoic acid 1,2,4-Tr ichlorobenzene Naphthalene
4-Chloroanil ine Hexachlorobutadiene 4-Chloro-3-aethylphenol
2-nethyInaphthaiene Hexachlorocyclopentadiene
2,4,6-Trichlorophenol
Laboral
I n i t i a l
.05 naxiai
^ RF
.98298 1.07713 1.33288 1.46853
1.20870 1.05901 1.77435 2.09731 1.91592 2.10775
1.53191 1.62313 1.72812 1.98553 1.53645 1.67947
1.59638 1.74128 1.50836 1.70110
.98128 .90205 3.17293 3.92289 1.40687 1.50940 .64854 .78328
1.32049 1.47048 1.45949 1.45846
.«768 .49597
.19314 .17693
.70970 .92727
.24546 .23714
.37244 .37652
.57280 .60595
.32358 .29288 .22193 .17167
.34818 .35212 1.00505 1.23434
.42787 .28894
.16940 .17731
.38424 .33225
.03322 .03710
.10647 .11242
.37824 .34626
RF - Response Factor froa dai ly standard f i !
I t ion Da
15:36
tory ID:
1 Cal ibr,
ja % Dif
W i f f 1
9.58 10.18 12.38 18.20
10.01 5.95
14.90 9.31 9.08
12.78 8.87
23.64
7.29 20.78 11.35
.07 8.37 8.39
30.66 3.39
1.09 5.79
9.49 22.64
1.13
22.81 32.47 4.67
13.53 11.67
5.59
8.46
le at '
te : 07/12/89
>C3872
i t ion Date: 07/06/89
f for CCC is 25»
CCCSWX
f
•
ff«
t
•
t
t
t l
•
50.00 UG/lt
RF - Average Response Factor froa I n i t i a l Cal ibrat ion Fora UI
ttiff - X Difference froa or ig inal average or i
CCC - Cal ibrat ion Check Coi
curve
opouids (•) SPCC - Sy stea Perforaance Check Co
?0
o o
(Jl
Fora UII Page 1 of 3 - ? 2
Continuing Calibration Check HSL Coapounds
Case No: Calibration Date: 07/12/89
Contractor: INDUSTRIAL CORROSION Tiae:
Contract No: fWNAGEf€NT
Instruaent ID: 3C
niniaua RF for SPCC is
Coapound
2,4,5-Tr ichlorophenoI 2-Fluorobiphenyl 2-ChIoronaphthalene 2-NitroaniIine Acenaphthylene Oiaethylphthalate 2,6-Oinitrotoluene 3-Nitroaniline Acenaphthene 2,4-OinitrophenoI Oibenzofuran 4-Nitrophenol 2,4-Oinitrotoluene Fluorene 4-Chtorophenyl-phenylether Oiethylphthalate 4-Hitroaniline 2,4,6-Tr ibroaopheno1 4,6-0initro-2-aethyIphenol N-Nitrosodiphenylaaine (1) Azobenzen« 4-6roBophenyl-phenyIether Hexachlorobenzene Pentachlorophanol Phenanthrene Anthracene Oi-n-butylphthalate Fluoranthene Benzidine Pyrene Terphenyl-dl4 Butylbenzylphthalate
15:36
Laboratory 10: >C?8.''2
Initial Calibration Date: 07/06.^9
.05 naxiaua % Diff for U X is 25%
RF RF
.41232 .34302
.88817 1.02201 1.13991 1.23999 .48741 .38677 1.56850 1.83989 1.26660 1.28964 .35624 .30427 .39422 .16319 1.11988 1.22850 .21851 .07712 1.56717 1.57306 .14317 .08535 .51829 .34026
1.20023 1.18013 .60040 .58118
1.09277 1.14924 .36491 .07885 .12017 .16711 .11320 .15439 .51479 .56692 .87567 1.25955 .20821 .27814 .23545 .33348 .17104 .14971 1.01468 1.21454 .96963 1.15888 1.24338 1.44964 1.28456 l.mOI .00801 .00581
1.43285 2.00195 .96534 1,18151 .90207 .89082
\Diff CCC SPCC
16.81 15.07 8.78
20.65 17.30 1.82 14.59 58.60 9.70 •
64.71 " .38
52.30 •• 34.35 1.67 3.21 5.17 . 78.39 39.86 36.39 9.55 • 43.84 29.74 41.64 12.47 • 19.70 19.52 16.59 7.77 • 27.48 39.72 22.39 1.25
RF - Response Factor froa daily standard f i l e at 50.00 UG/ll
RF - Average Response Factor froa In i t ia l Calibration Fora Ut
ttiff - X Difference froa original average or curve
CCC - Calibration Check Coapounds (*) SPCC - Systea Perforaance Check CoqMxmds (••)
Fora UII Page 2 of 3 1 2 3
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(Jl •Co
Continuing Calibration Check HSL Coapounds
Case No:
Contractor: IWXJSTRIAL CORROSION
Contract No: MAW^nENT
Instruaent ID: 3C
Calibration Date: 07/12/89
Tiae: 15:36
Laboratory ID: >C3872
Initial Calibration Date: 07/06/89
niniaua RF for SPCC is .05 naxiaua % Diff for CCC is 25«
Coapound
Senzo(a)anthracene 3,3'-OichIorobenzidine Chrysene bis(2-Ethylhexyl)phthaIate Oi-n-octylphthalate Benzo(b)fluoranthene 8enzo(k)fluoranthene Benzo(a)pyrene Indenod,2,3-cd )pyrene Dibenz(a,h)anthracene Benzo(g,h,i)perylene
RF RF
1.32516 1.29184 .43549 .25511
1.16247 1.26203 1.19107 1.21479 2.46779 2.83390 1.96578 1.60351 1.47693 1.60351 1.47733 1.51778
.88323 1.19545
.90015 1.08384
.83663 1.21859
»Dif f CCC SPCC
2.51 41.42
8.56 1.99
14.84 • 18.43 8.57 2.74 •
35.35 20.41 45.65
RF - Response Factor froa daily standard file at 50.00 UG/HL
RF - Average Response Factor froa Initial Calibration Fora UI
ttiff - I Difference froa original average or curve
CCC - Calibration Check Coapounds (*) SPCC - Systea Perforaance Check Coapounds (**)
Fora UII Page 3 of 3
1 24
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•i . l 'J2 P .y . i t c - LO R;.. li(J:; Ip l - i , N-.i O?'*?,!
2 0 1 - 2 3 4 - 0 2 3 0 A u M U - t 1 , 1 9 S 9
NJ CEP CI-:-,- t. i f i e d D r i n k ;in<3 Ua t t r / U r i r t €=ua t e r L i b c r n i - y y I D * I ' V l l i y (J S E P A C o n t r ;3, : t L 31) o i- ;3 t. o T- y •
QUALITY ASSURANCE DATA - SPIKE rECQ'-'EiR lE'S
F o f • i . ; i i i l i : . - l . ; ;S i
.L03-13S 1 0 3 - 4 3 9 103-44'0 103-44.1 1 0 3 - 4 4 2 1 0 3 4 , 1 3
M a t r i x t y p e : WATER
P a r a m e t e r L a b
N u m b e r R e ^ i u l t
P.v,tr-o l e u m H y d r o c a r b o TI BLK S P U
Amount AcJded mg/ 1
C o n e , M 3 1 1 > i X
S p i k e m g / l
% S p i k e
R e c ,
QC L i m i t % Spik, ; / Rf->co v e r y
1 0 iO 1 0 0 % 7 5 - i ; 5
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C ( . ' p y r i 9 h t I C M , I n c . , 1 9 8 7 . A l l r i g h t s r e s e r v e d ,
PAGE * 125
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Sl^X^lSSS^ Chain of Custody Record PELIVERABLE PACKAGE
a TIER I 2 ) TIER il D NON-TIER.
8PL NO.
DATE SPLD
TIME 8PL0
SAMPUNQ POINT « SAMPUNG METHOD DESCRIPTION SAMPLE MATERIAL ANALYSIS REMARKS
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ORQANIZATION DATE & TIME
RECEIVED BY (Signature) ORQANIZATION DATE &
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kuretslon, Gubssa ^U!,j .^^Li.rt^f<>ii . jLi\yLja-^*^
rberlan, Barbara /^wb^^-^c^X«=>/^a^A><JL/»^^—
Abba/e, Oanial
Baron, Nary
Bek
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Bijowski, Nalgoriata
Blank, Robert
Cariati, Edwina
Cowell, Kristin
Crotty, Michael
Eberly, Daniel
Gbebreyesus, Habteab
Harvey, Sarab
Heller, Sbaron
Hof. Philip
Holt, Sodica
Jercsynski, Hallna
Kadakla, Geeta
Koleno, Panla
Kusterer, Jeanat
Luo, Snyl
Mancuso, Thoaas
Martines, Jose
McElbenny, Colleea
Mebari, Sebhatu
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SIGNATURE
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;t, Debra ^LjA^ft' \ -
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Norscb, Cathie
Norton, Kiaberly
Peters, Catherine
Pies, Sangeeta
Poai
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Price, Elisabeth
Rel, Anabela
Riccio, Mark
Richardson, Susan
Ridings, Audrey
Rlngwelski, Ewa
Roberts, S. David
Santana, Illnaiaada
Sarsoay, Keaneth
Strojnowska, Isabtlli
Thorp, Carla
Wachal, Best!
Obohi Aaron
Selengut, Jeffrey
Shields-Baker, Cglaate (^^^^f^^'^JfJ.^ȣ^ ^f^aJ)Uu>.^
Norman, Dorothy ^^r<^^;6(^^-"V!?<!T'*'»*--ews^
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NAME
Maedel, Lynne
Tesfaghiorghls . Yemane^ Vg-AQ^^o^ 9 ^ 4 f k ^ - J
Otey, Margo vt)a\QO O ^ g J U
INITIALS
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m NJ DEP Certified Drinking Water/Wastewater Laboratory ID# U116
LABORATORY CHRONICLE
DATE RECEIPT/REFRIGERATION ?>\\^W*=\
DATE SAMPLED aWSN*^*^
LAB # Q ^ / ^
GC/MS:
Ex t r ac t i ons : Acids
Base/Neutrals 3 > \ n \ ^ * ^
Analys i s : Vo la t i l e s a»V^\HS
Acids
Base/Neutrals ? , \ ^ \ \ ^ * ^
GC: Extractions:
Pesticide/PCB Analysis:
Pesticide/PCB
Volatiles
PETROLEUM HYDROCARBONS:
Extractions: f ^ \ n H ^
Analysis: ^V^^N^Ot
PRESERVATIVE j I r t j i , A . , i ^ r / h / ^ ^ ^ . ^
Section Supervisor Review & Approval
(Signature) 25253^sigw3L-
Section Supervisor Review & Approval:
(Signature)
ATOMIC ABSORPTION:
Metals:
Mercury:
GENERAL ANALYTICAL:
Cyanide:
Phenol:
OTHER ANALYSIS:
V>Vl ?>\N?SW 1 3
Section Supervisor ~^. -Review & Approval: *U«<Jt^<£^
(Signature) "*"
Section Supervisor Review & Approval:
(Signature)
_
Section Supervisor Review & Approval:
(Signature)
j r \ -
Final Approval: (y(/YvnQ tfSi.
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:«i'i • - m ^
NJ DEP C e r t i f i e d Dr inking Water /Wastewater L a b o r a t o r y IDl 14116
LABORATORY CHRONICLE
DATE RECEIPT/REFRIGERATION ^^\c^\^C\
DATE SAMPLED ?>\\fe.N\<H .
GC/MS:
Extractions: Acids
Base/Neutrals 3|v^\^<\
Analysis: Volatiles
Acids
'^h>\*i^
B a s e / N e u t r a l s 3»\'?>>\US
GC: Extractions:
Pesticide/PCB Analysis:
Pesticide/PCB
Volatiles
PETROLEUM HYDROCARBONS:
Extractions:
Analysis:
3\'n\ *^ ^\a^\^*^
ATOMIC ABSORPTION;
Metals:
Mercury;
GENERAL ANALYTICAL:
Cyanide:
Phenol:
OTHER ANALYSIS:
LAB # 99iv^i
PRESERVATIVE l i r t ^ i l o y ^ O l i ^ H ^ H,<7\^
Section Supervisor Review & Approval: 2te&
Section Supervisor Review & Approval:
(Signature)
Section Supervisor Review & Approval:
(Signature) '^^
Section Supervisor Review & Approval:
(Signature)
Section Supervisor Review & Approval:
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(Signature)
1 4 Final Approval : ' ' ^ ^ r y n \Jf*'
Quality Assurance Coordinator
•
E NJ DEP Certified Drinking Water/Wastewater Laboratory ID# IA116
LABORATORY CHRONICLE
DATE RECEIPT/REFRIGERATION ?v\\S\*^*^ LAB # ^ Q i 3 ^ 0
DATE SAMPLED
GC/MS:
Extractions: Acids
?^\^\^^
Base/Neutrals ?>\n\%«^
Analys is : Vo la t i l e s 3\a\WQ>
Acids
Base/Neutrals TsyXvV'?.*
GC:
PRESERVATIVE (^ntjia^Q/iyr/H-^V>.^
Section Supervisor Review & Approval
(Sisdaturi (Sigdature)
Extractions: Pesticide/PCB
Analysis: Pesticide/PCB
Volatiles
PETROLEUM HYDROCARBONS:
Extractions: ?N\nNflL<H
Analysis:
ATOMIC ABSORPTION:
Metals:
Mercury:
GENERAL ANALYTICAL:
Cyanide:
Phenol:
OTHER ANALYSIS:
'X\;^a>S^^
Section Supervisor Review & Approval:
Section Supervisor Review & Approval:
Section Supervisor Review & Approval:
Section Supervisor Review & Approval:
Final Approval: (
^ 5 Qua]
(Signature)
(Signature)
(Signature)
(Signature)
7 f? .lty Assurance Coordinj
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:«i'i NJ DEP Cer t i f i ed Drinking Water/Wastewater Laboratory ID# U I I 6 "
LABORATORY CHRONICLE
DATE RECEIPT/REFRIGERATION >>\\'r>\9>^
DATE SAMPLED ?^\\«h\'^^
GC/MS:
GC: Extractions:
Pestlcide/PCB Analysis:
Pesticide/PCB
Volatiles
GENERAL ANALYTICAL:
LAB # qsi53>
:
Extractions: Acids
Base/Neutrals
Analysis: Volatiles
Acids
Base/Neutrals ?.\'^^^^^
PRESERVATIVE :UJ^M-£lfli=»JCd^^SC
Section Supervisor Review & Approval:
^ XsT^Jtuxk)
PETROLEUM HYDROCARBONS:
Extractions:
Analysis:
ATOMIC ABSORPTION:
Metals:
Mercury:
?S\\"l\?kS ?.\^^N\°i
Section Supervisor Review & Approval:
Section Supervisor Review & Approval:
(Signature)
B2i (Signatu: i tufe)
Section Supervisor Review & Approval:
(Signature)
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Cyanide:
Phenol:
OTHER ANALYSIS:
Section Supervisor Review & Approval:
(Signature)
- g ^in*l Approval: (^A/TVnO i l O ^
(Quality Assurance Coor
N3
dinato
u Jj NJ DEP Certified Drinking Water/Wastewater Laboratory ID# 14116
LABORATORY CHRONICLE
DATE RECEIPT/REFRIGERATION I^Nyg^VRq
DATE SAMPLED •?k\\c->\\.<=K
GC/MS:
Extractions: Acids
Base/Neutrals ?^\r)\^°\
Analysis: Volatiles
Acids ?>^^'!^q
Base/Neutrals "?.^?>>\%t^
GC: Extractions:
Pesticide/PCB Analysis:
Pesticide/PCB
Volatiles
PETROLEUM HYDROCARBONS:
Extractions:
Analysis:
.JbiD^Sl '>>\Ba\VH
ATOMIC ABSORPTION;
Metals:
Mercury:
GENERAL ANALYTICAL:
Cyanide:
Phenol:
OTHER ANALYSIS:
LAB # ^ ^ \ ? S ^
PRESERVATIVE I. UX^ i D C ^ i v f A ^y\^^
Section Supervisor Review & Approval:
(Sign^tur^)
Section Supervisor Review & Approval:
(Signature)
Section Supervisor Review & Approval: eAn^tA
(Signature)
1 7
Section Supervisor Review & Approval:
Section Supervisor Review & Approval:
Final Approval: ( /
(Signature)
(Signature)
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Quality Assurance Coordinator
m NJ DEP Certified Drinking Water/Wastewater Laboratory IDl 14116
LABORATORY CHRONICLE
DATE RECEIPT/REFRIGERATION \\<;\<Kgi
DATE SAMPLED :^\\S\7k9
LAB # Q^<\\?iS
GC/MS:
Extractions: Acids
Base/Neutrals ?>\n\<r<^
Analysis:
Volatiles ^bvN^"'
Acids
Base/Neutrals '3>\'X\\' g)
GC: Extractions:
Pesticlde/PCB Analysis:
Pesticide/PCB
Volatiles
PETROLEUM HYDROCARBONS:
PRESERVATIVE U , ^ t . o AQ JULt-a _ H iXsLi
Section Supervisor Review & Approval
(SignatiAre)
Section Supervisor Review & Approval:
(Signature)
Extractions: _
Analysis:
ATWaC ABSORPTION:
Metals:
Mercury:
GENERAL ANALYTICAL:
Cyanide:
Phenol:
OTHER ANALYSIS:
9>rs >.\V^^<^<\
Section Supervisor Review & Approval:
Section Supervisor Review & Approval:
Section Supervisor Review & Approval:
Final Approval: (
(Signature)
1 o
(Signature) °
M (Jl ON
(Signature)
..J/h/naU«-' w Quality Assurance Coordinator
% r NJ DEP C e r t i f i e d Dr ink ing Water/Wastewater Labora to ry IDl 14116
LABORATORY CHRONICLE
DATE RECEIPT/REFRIGERATION 3 \ S S V & S
DATE SAMPLED ? ) ^ ^ S \ ^ ^
GC/MS:
E x t r a c t i o n s : Acids
Base/Neutrals
Ana lys i s : Vo la t i l e s ;^V^^\^°|
Acids
Base/Neutrals
GC: Extractions:
Pestlcide/PCB Analysis:
Pesticide/PCB
Volatiles
PETROLEUM HYDROCARBONS:
Extractions:
Analysis:
ATOMIC ABSORPTION:
Metals:
Mercury:
GENERAL ANALYTICAL:
Cyanide:
Phenol:
OTHER ANALYSIS:
LAB I 9S^^\o PRESERVATIVE
Section Supervisor Review & Approval
Section Supervisor Review & Approval:
Section Supervisor Review & Approval:
Section Supervisor Review & Approval:
Section Supervisor Review & Approval:
V w r t ^ i o ^ f ^ . t > f p ^
(Signature)
(Signature)
(Signature) »
(Signature)
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Final Approval
(Signature)
1 9 Quality Assurance Coordinator
i i . u u j i n m i - v ^ u n n u J i U . - l n n N f l O t f l t N T , I N C .
n S 2 Route 10 NJ DEP Certified Drinking Water/ Randolph, NJ 07869 Wastewater Laboratory l O t U l U 201-584-0330 USEPA Contract Laboratory
NONCONFORMANCE SUMMARY CHECKLIST
-Lab Nuabers: Q Q \ ? f V C^Q\>vi>.
Volatile Organics: Anaiyied j^ Not Analyzed
All tunes were run in required frequency. YesJ^ No
All tunc a/t ratios aet criteria. YesJ( No
All initial and/or continuing calibrations were run in required frequency. YesJ|[ No
All calibration SPCCs and CCCs act criteria. Yes A No
Surrogate recoveries act QC criteria. Yes ^ No
All aethod blanks aet contaaination criteria. Yes No
Ail saaples were analyzed within the required holding tiaes. Yes X No
Other nonconforaances.
Coaaents:
Seal-volatlIc Organics: Analyzed X Not Analyzed
All tuoes were run in required frequency. Yes X No.
All tune a/x ratios aet criteria. Yes y No
All initial and/or continuing calibrations were run in required frequency. Yes •^ No
All calibration SPCCs and CCCs aet criteria. Yes V No
Surrogate recoveries aet QC criteria. Yesji|![__ No
All aetbod blanks act contaaination criteria. Yes X No 15
All saaples were extracted and analyzed within the required holding tiaes. Yes JC No ^
o Other nonconforaances.
^ _ _ _ Ul
— — ^ Coaaents:
xo-
115.2 Route 10 Randolph, NJ 07869 201-S84-0330
NJ DEP Certified Drinking Water/ Wastewater Laboratory IDai*116 USEPA Contract Laboratory
NONCONFORMANCE SUMMARY CHECKLIST
Lab Nuabors : _ 9 9 - L 3 Q : L 9 ^ i 3 k
Pesticides/PCBs: Analyzed. Not Analyzed
All aetbod blanks set contaaination criteria. Yes No
All saaples were extracted and analyzed within the required holding tiaes. Yes No.
Other nonconforaances.
Coaaents:
Metals: Analyzed. Not Analyzed_iL
All aethod blanks aet contaaination criteria. Yes. No
All saaples were analyzed within the required holding tiaes. Yes No
Other nonconforaances.
Coaaents:
Petroleua Hydrocarbons: Analyzed. Not Analyzed.
All saaples were analysed within the required holding tiaes. Yes t . No
Other nonconforaances.
Coaaen ts : 50
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•y.y^-y~jmii 113^ Koucc iQ NJ OEP C e r t i f i e d D r i n k i n g W a t e r / i ? t i S ^ R a n d o l p h , NJ 07369 W a s t e w a l o r L a b o r a t o r y I D t l 4 l l 6 v|? 2 0 1 - 5 8 4 - 0 3 3 0 USEPA C o n t r a c t L a b o r a t o r y **
NONCONFORMANCE SUMMARY CHECKLIST
^ab N u a b c r s : _ ^ V 2 Q z a ^ a 2 i A ^
General Cheaistry: Analyzed X Not Analyzed
All saaples were analyzed within the required holding tiaes. Yes )C No
Other nonconforaances.
Coaaents;
Genera 1:
All saaples were properly preserved in the field. Yes y No.
Coaaents:.
A d d i t i o n a l C o a a e n t s ;
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MATRIX: Water
METHOD REFERENCE: Code of Federal Regulations 40, Part 136, Appendix A, Method 624.
METHOD SUMMARY: Heliua Is bubbled through a S al water saaple contained in specially designed purging chaaber for 11 Bla. at aabient teaperature. The purgeables are transferred froa the aqueous to the vapor phase and passed through a 3 coaponeat trap (OV-1, Tenax and silica gel) where they are absorbed. After purging is coaplete, the trap is heated and backflushed with heliua to desorb the purgeables onto a gss chroaato-graphic coluan. The chroaatograph is teaperature prograaaed (3 ain. at 4S degrees C, then raap to 220 degrees C at 8 degrees/ain.; final hold 12ala.) to separate the purgeables which are thea detected with the aass spectroaeter. The aass spectroaeter dtjta systea (RTE-6) identifies target coapouads thatlaeflt the criteria of reteatloa tiae (-•SO sec), relative abundance of characteristic aasses (-*20X), and' aazlaisation of characteristic aasses wlthla 1 scan of each other. Other coapouads detected can be searched by the data systea ia its EPA/NIH library of 42000« coapoaads.
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Basc/Meutcal and ftcids
HATRIX: Hater
HETHOO REFSSEMCE: Code of Federal Regulations '^O, Part 136, Appeodis A, Hethod 62S.
METHOD SUHMSY: A Deasured voluQe of saeple, approziaately 1 litsr, is serially estractsd v;ith setbylene chloride at a pH greater than 11 and again at pH less than 3 asiag a ssparatory funnel. The oethylene chloride estract is drisd, concentrated to a voluEie of 1.0 al and analysed by CC/HS. The gas chroaatograph t ith 30 n . SPB-S capillary coluan, is prograaaed at 30 degrees C (1 Qia.) to 60 degrees C at 30 degrees C/@ia., then to 300 degrees C at & degrees C/iin, uith a final bold of 24 Qia. The Q S S S spectroaeter data systeQ (BTE-6) identifies target coapouads that oest the criteria of retention tioe (-«30 s e c ) , relative abundance of 3 characteristic Basses (-*20S,of u standard spectra), aad QasiQisation of , i. characteristic Basses uithin 1 scan of each'^othspT ; Other conpounds detected can b® searched ^y, tbe'da^ta systeo ia its BPA/t4!H library of 42000« coopouads.-Quantitative analysis is perforaed osiag intersai standard tecbaigues trith a single characteristic n/s.
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HATRIX: Water
METHOD REFERENCE: U.S. EPA Methods for cheaical Analysis of ^ater and Hastes, 1983 Spectrophotooetric Infrared Hethod 418.1
NETHOO SUnnASY: The saaple bottle is oarbed at the uater aeniscus for later detoraination of voluae. The saaple is poured in a 2000 Ql separatory funnel. The saople bottl@ is rins tilth 30 ol of fluorocarbon-113 uhich is thea addsd to the saople in the separatory funnel.- The faasQl is shaben for 10 ainutes and the solvoat lays? filtered through a funnel containing solveat-ooistenod fliter "-paper into a 100 ol voluaetric flasCi. The saople is estracted tuice oors uith 30 ol of fresh solvent cpobia ing all extracts ia the voluaetric flasb. ¥h@ extract diluted to 100 ol. 3 g. of silica gel is added andr stirred for S ainutes. Quaatitatioa is perforaed esisg aa infrared spectrophotoaeter. Appropriate dilutioao are aade if tha estract eoaceatratioa is greater thaa 4Qg/100ol.
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« ™ D REFERENCE: Standard Method, u t h Editiun. Methud 423
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B r o m o f l u o r o b e n z e n e (EFB)
Ion Abundance C r i t e r i a
% R«lati<,>e Abundance Base A p p r o p r i a t e Psak Peak S t a t u s
50 75 95 96
173 174 175 176 177
l?5^-4d|t?-of-;i:»^iii? 95
' '""""""'"'^'^^^QQ% r e l a t i v e -Basis' a b u n d a n c e
95
•'5s^S»^:*.o;f'?.m4»«,.;"?5 - t ^ ^ y i t i i i r y 2 % ; t 2 o f mass 174 G r e a t e r tHan "30% of m-^ss 5 - 9 * of mass 174 95-101% of mass 174 5-9% of mass 176
Injection Date Injection Time
Data File Scan
Analyst's Signature
23.65 58.26 100.00 5.39 0.00
91.17 7.77 87.56 4.93
03/ '21 /89 1 6 : 2 1 >B6010 11
2 3 . 6 5 5 8 . 2 6
1 0 0 . 0 0 5 . ? 9 0 0 0
9 1 . 1 7 8 . 5 2
9 6 . 0 4 5 . 6 3
s ^
o
M OV-W 00
Ok Ok Ok Ok Ok : Ok - Ok ; Ok -Ok-^i
'2'yi f • ' \y
1 • -,-ii;
< . iiuJi^SCkJb^ Sample Numbers = ^ / ^ S " qQl?L,^ 9*?/3^^ < ? ^ / 3 /
9 4 99/^0 9^/^^ "fhy-.^ff^^-
- 0
T i i « >e6aie 94.7-95.7 aau. voA <JN §.H-JML t^K S6 u4 6r*6 SUL !MJ,*»kg.. EIP
68 ed 1V)0 120 148 • • • • ' ' ' • • ' • • ' ' ' I , . . . I . . . I . . . . I
980-
880;
78»;
608-
380;
2e»
180;
0 8 . 5 9 . 8
An^TAc<y\^^i^.l^O•lll/^/ , . . . . , . . . . , I jA . rTAA^ 9 . 5 1 8 . 8 1 8 . 8 11 .e 1 1 . S I S . 8
-*4i,'j5'S:.«
'.-a^ . 1
.-'K.
>B6010 UOA ON B,MSCAL CHK 50 NG BFB 2uL IM7,6'X2mm 1% SPIOOO ON CB
110 SUB NRM Eh«
File: >B6010 Scan ff :
m/z Int. m/z
110 Retn. time: 10.42
Int. m/z Int. m/z I n t m/s I n t .
37 38 39 42 50 5 1
00 10 00 10 05 05
6.200v 2.590 5; 6 05 4. 034
23;36S2? 7r55'8-
56.05 68.00 69.10 72.00 74. I t i .
' 7 5 . 1 0
4 11 14
1 19 58
.119 635
.692 614
.236 259
76 79 87 8S 92 3 i
.00 00 05 95 05 05
1.699 9 4 . 0 5 12.272 162.25 2 123 9 5 . 0 5 100.000 174.00 4.331 9 6 . 0 5 5.393 175.00 3 142 105.10 1.529 176.00 4.544 138.00 .934 177.00 4.841
.892 91.168
7 .771 87.553
4.92f5
o o
9 5 o> vo
l r . i U i i Ci i- .snhsr. fe*.
Cijt Hs:
Cintrattof: 4211.v.
In3».r-jw,l ; i : 2J
iailferatic.'' 2aic: 03.'2L'.'S9
!!;,-.iw i?r far SPCC is .2) toiftwt J JfC- for CCC is 30:
Labisratsry 10: )fl598j >8597? ;«=5-3 .>K5J1 >8S982
Ca^otmij
Chicrawthane
BroBCBettene
9iRVl O i iw i te
ChJsrsetJra
ncthvifi'.i Chlorxiie Bcstijfit
Carbsa SiSiilfide
l.t-DicfclwMtheM
l.l-flidvlB-Bethant
l5tai-t,2-Si:li lersetJane
ChlOTBfom
1.2-3isJdi!r8»thjn«
1,!-Bic)ilcrMtiiane-tH
2-Bytangiffi
l , ' .,1-Inchl8rMthafi£
Carbon Ictrachlorii l t
Uinyl Acetate Bratc^chloraiethsw
1,2-9iuilsroprspane
Irans-!.Z-Oicfeiarsprapine
Tr lch2sr»t l»%
ihbrcnschisnntirait
1.1.2-lnchl(ir«than«
6er.:»w
ci3-'>,3-Sidlsn)|)r3{itne
2-Ctttrsethvlvirr; l8t lw
ft-swfvn
<-fl8ttiyl-2-fH>t3n«»
2-HeuMM
htrad- i loret t l iBK. ,* " . - ' i t ' "- .
«• 8f Iif «• 8f
28.80 58.00 IOi:.i;-0 !S8.()C 2t}0.8C
I.981K 2.)J9e3 i . M s r !.8ete2 i . tacj?
.9i2i31 .9i2B2 .;5;19 .a7^6 .31396
1.28S55 2,28295 Z. iK^t 2.957.3 l.iK1385
!.27Sn M 5 ) 3 : \ . W M 1.0*083 .95^70
7.06632 2.5728E 3.35138 ISXJH 2.fl^S9
1.20850 .80287 .e?-:5J .71731 .59789
5.18335 S.33C59 t6JIH31.8M)8 1.26896
1.J216S 3.85865 3.5i513 3.158S3 3.0G178
3.95K6 3.69333 5.2S»72 3.31612 3.80803
).37231 1.78238 1.615811.S3129 1.1)111
5.88669 1.192821.39?^ 1.892S3 h i i m
5.11295 1.21571 l . ^ ' ' l 3.9K91 3.2913S
1.60916 3,65590 3.17957 3.38115 3.06361
.863« .31158 .SrW .03978 .01021
.98691 .96851 .85733 .86569 .78110
,98301 .916Si .35755 .36916 .77730 ,69511 ,55821 ,53398 .SHIS .50728
.92868 .77785 ,71231 .77218 .72395
,11762 .38193 .iSi97 .27178 .5121
.87261 .81308 .77»7: .78610 .TT/t t
,56721 .15162 .12521 .1IW3 .37329
,68689 ,53699 ,5!S1* .53118 .52111
.36761 ,28929 ,::»!? .28185 .262%
1,26221 1.M281 l.«7211.06921 I,a2$j7
.13928 . W 5 7 .11713 .12M8 .18638
.19878 .15281 . ! « » : . ! « » .13317
.61187 .1380 ,13^7 .17102 .11536
. S e S .3K99 .7.611 , i 3 e 6 ,30631
. m a .28286 .2663 .2nS6 ,21326 : . % m .19871 .1^553 .11651 ,3713
W l 8?
,220 1.91813 .327 .57575
.105 2.89736
.523 1.09768
.725 3.67811
,888 .88133
.867 1.92751
.972 3,58291
1.079 3.15721
l . m 1.66265
1.1831.29826 1.250 1,39011
1.211 3.57851
.515 .01522
.727 .98115
.711 . m i l
.7SS .56788
.761 .78710
.827 .38569
.836 ,fl)12S
.862 .15281
.881 .55988
.891 .2961?
.S89».'1113
.89: .12713
. m .15569
1.882 .17983
. m .3K39
.901 ,31157
.y i2 ,«251
IliSS
8.431
5.156
8.691
51.951
52.138
29.589
9.318 11.711
18.SS
13.652
12.318
16.552
17.281 28.118
8.815
3.687
12.968 9.871
9.136
5.572
15.135
12.373 13.911
8.325
3.686
16.211
15.68t
31.256 23.116
55.591
CCt Sri::
8f - ixs^m:fkiJar . i ixbiaif i if aneont in p;?-
i r - Averaj! i t l i i i v t it\aii<m I im (Vl Stii '?! Uii)
tf - Dvtrage h ^ s a i factar
UtSS - 7«rc«r.t JtldtiM 5iatard 8a<.natia)
CCC - Calibration Cktck Ca«Nn6s (») SPK - Syi tw Perfornance Chtci; Canpooids <» )
f m n H Tage 1 8f 2
9 6
I o
y * O l
h i t i a l 'Cahlif3:.i» D-a'a HSl Catpcvr.^
CaxD::
Coniracta-: "fSI I.-iC.
ContriKt DP:
I s s t rwwt 18: 2
r - , ' ; K r i t i . , IV..,. r.I.Tfi.«q
'.'•--bi Z -y, 'y ' '1 .
•-z.yryii
ryytf?.
r . v n t m Sr fw SPCC i s .30 !!ar.n.jn I i!S8 for CCC i s JS2
Laboratory 10: >85«3 >85579 )K980 )8S981 >853S2 ff if Rf Rf 8f _ _
CwjHJWiiJ 20.08 58.88 100.38 158.88 286.!KJ MT 8f : K 2 CCC S?:C
1 . ! .2 .2 - I« t rach ior» lhan« .68501 .11633 .12707 .13881 .12663 .987 .18177 22.551 loiuene-dS 1.613351.£0887 1.37875 5,31155 1.13583 .956 5.11287 12,375 Io l«M .91238 ,86122 ,77877 .77213 .69528 .962 .85181 51.9:3 •
'ChlsrofcaszKW 5.15153 !.18851 1.31523 .53321 .31861 l.»11.31813 11.SK *» CthvlfceniHt 2,35211 2,11695 2,18565 1,93621 1.75319 1.889 2.K889 11.569 » Styrant 1.39587 1.28139 1,13031 1,10616 1,81708 1,263 1.17676 11.159 lotal Xylenes 2.28372 1.98831 1.88219 1.75618 1.56503 1.J15 1.871S5 i;.»7S Br-awfliBrobfc-erie 1.11122 .95726 .90573 .81681 .79681 1.1S3 .52157 13.163 Scroleis . . . . . . . . feryljRitrile . . . . . . . . iHhthlc-ratecaw - - -9«p-3lcl>l5ri)benia)*s . . . . . . . .
(Csnc*28C. (t8K<88, 8.S
j ^
•"ays', -• -- .,..,
-my^y- ' •• yy?'-•^X'lzy'. 'fi - ^T... ' -
W - !««sn»-racti)ri<Stii)Kriptisaneasi inppb)
• ':y -yi \ _ ->. ;
m - 3v«rase Relat ive Retffltim h n t iV. St<S/R? I s td )
Rf - !!vera;e Respsise f ae t t r
1858 - Pe r : s i t Relat ive Stacdvd e » i a t i s s
CCC - Caiicrat ioa Chetk Conpeiadi (•) 5KC - Syiien Ferforaance Check
farn.VI h g t 2 ol 2 9 7
{ « ;
CauKs:
Coritnottr: ICR I-.c.
btf.'tL, O b i nw.
T _ . l . , ^ „ . Tn. Vt
Cahintisfi fete: 33.-'2!/«9
Tir*: 16:18
.li.-.jiwRf forSPCCis.}! inXlnun « i/tn i5r L*. i J 4j«
Cjn^sund
C,M3rsn«t!',3i» Srononetiwie Vinyl CMsriiie CMcTGetl-A-te Itethylaw CMwiiie 8ceia» Carbcr, Oisuifiiie l,1-0ichloroether,e l . l -Dic.ysTMt' iafa Toial-1,2-03cMorsei'iem CMwofom Lr-Oiehla-oetJane
1 . :-3;r i t lcrMiiaf ie-d1 2 - ia ia imt l.l.l-Tnchlsraeti'ans Carbor, TetratUsrliie Uinyl Dcitate SroiwiicbloraiitthaAe 1,2-Bichlcr8|»'tpa>')e Trai»-1,3-8icfcIorapr3peia Ir:cj)li)r»th«M SisronscMcraKthaH
l.l.Z-InchisrsetlaM 8in»J»
tii-1,3-8j:hlori>pr:(inc 2-Chli>r9«it)ylvi»yletl»r Sronsfsn
1-fl»ti)vl-2-F»tffl«t- ,
Z-SaxanoBe • • • V - . ' ' " • '
Ie t ra th l i r« t t^ i f ; t -«?^- -I j .2 .2-T8i i ; i^^ ia»k; ' \ o l m H S . . ^ . ^ f y C y ,
Rf Rf
!,95313 2,28861 . r f t f t 1.18532
2,39726 2.35985 5.S9768 1.21S)5 3.67815 2.S1238 .»)138 .32319
1.92751 1.71899 3.58291 1.81369 3.157:^ 2.6316:
1.66:^ 1.51985 1.29826 1.85181 1.5%}1 5.85886 3.57851 1.52218 .31523 .81851 .58115 5.31823 .88887 1.31776 .567n .53817 .78718 .52111 . ^ 9 .28881 .«I125 .85(37 .15281 .19055
.55508 .62669 .2«17 .3817?.
l . n i C 1.12992
.irm .««
.15569 .19671 ,17!S .57155 iSSBi .12857
. • J « 7 " . i C 1 9
: y m .51321 :i'^1«?7 .f7396
f.i lST 1.17360
:D-.ff cccspcc
IS.88 ** 26.18 1,21 •
13.13 23.51 2.28 1.23
12.19 • 6.37 «
8,59 13.39 » 23,66 26.11 7.25
12,55 15,51 3.95
17.37 .81 •
6.53 3.33
12.11 2.85 1.3?
8.7E
22.51 19.71 *•
16.21
8.58 i : . i :
2.23 « 1.26
(Co«->50,08)
«'. .' 4 "•
(C(mc<'53.80)
Rf - Response factor frtn oaily standard file at 58.1)8 ppb
Rf - Rveraje Re^KKse factsr frtn Liitial Cdliaratlsn f im ill
Shff - ! ihffs-ence frait onjiaiS K t r ^ ^ or carve
CCC - Calitratis-. Check Cai^tsndi <>! SKI - Systen Pa-fsmanct Qtacii Ca^owds ( « )
fom lai taj! U f 2
98
I O i o
o
I
VV,.^...S,*,ll^ VU..1WI . ] , . < , ' , (.,,ffCll
KSi. Cunpu'.T.-ii
Cass He: Caiiisrat-.on 5at j : •32.'25.''85
Cwt r j c ta - : IC!IJnc. I i w : ! i :18
C;,-,t,-sc'. Its: CatoratDry ID: >Btti5
Ir.5t7ijia.-,t IS: 28 I n i t i a l CaiitratiiW Sate: 32/20/85
!5:r,iri»i « for SPCC is , 2 I1a««« I Siff for CCC js 25)1
Conpsui-id Rf Rf lO l f f CCCSPCC
Toluer,8 ,35185 .75151 2.33 • a i j r s b e r u H a 5.01813 1.82313 1.50 » Ct.".vlta.i:tr* 2.06385 2.23328 15,53 » Styrene 1.17676 1.25651 6.81 Total Xylenes !.87555 2,17561 55.75
B r a w f l u c r s i w j e M .52157 5.01837 53.36 <Corf--53.B0)
Iteroleia - - - <Cone»5SB.80>
Bc -v l cn i t r i l e - - - (Consul 008. OO.i ii-3ic''.lorsbei«er<e . . . <C5nt'508,aO) c«p-3icMerofcenjsne3 - - - (Cone-100. W )
Rf - Res CRse factsr f r a i da l ly standard f i l e at 58,33 ppb
y - ^ z : ^ z m
ry-.i
i Rf - Rverafe Respcnse factar fron I n i t i a l Cali i iration f o m 81 o I o
SStff - I Siffs-encs f ron s r i s ina ! average or n r v e
CCC - Calibration Check Conftounds («) SPC£ * Systen Perfomance Check Ca^ounds (*•>
f o r n V I I Pase 2 o f 2
99
0^ i l »
^ • i inds Iph . MJ 0 7-369 -.>l-3.= -1-;-33'D / A / 8 9 ''
NJ DCP Certified Drinking U a t e r / U a s t e u a ^ ^ Labor 3lor-y I D * .14114 "' ^
l.JBRARir SEARCH RESULTS OF NONTARGETED PEAKS UITH ESrr,'^A7£.P CCi.'^CEWT^AriClN OF TENTATIVELY IDENTIFIES COMPOUNDS,
• ' yy
a t a f i l e ncime: >iC3137
T a c t i o n ; B a s e / N e u t r a l
,-130 T h j i BLANK c o r r e s p o n d s to t h e f o l l o u i n g l a b nu:r>bers:
>913i 99132 99133 99134 99135
* » ; •
Scan \'iiirber CAS No
ftetentio n Time
Compound Name
MolecuIar Ueisht
Est imated Co ncentra t io n
ug/1
None Found
Indic:at5s that the compound is an acetone based aldol-type condensation produc fsrxijd by CO ncentrat iJ!3 t, e extraction- solvent (li 1 aceto ne/inethylene._chip ridt Indicates that th© analyte was found in the blank as uell as t_hei.,same;ie..jvllt farthfjr indicates possible/probsble blank contamination. 1-ft s^.yy
'Wf ' -'s^tf.-y.y
• cpyright ICH, I n c , 1986. All rights reserved.
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GC/TIS PERFOPnoNCE STANDARD DecaK l i j o r c t r j p h e n y J p h o s p m e tD ; -TPP)
m / z Ion A b u n d a n c e
Cr 1 t e r \ a
H R e l a t i v e P b u n d a n - e B a s e ftppro.or l a t f l Peak P i fsu Sr.-Hti.!*.
5 1
6 9 7U
1 2 7 1 9 7 1 9 8 V?9 '2 75 3 6 5 4 4 1 44-;>
A 4 3
30-6CH< o f rr.a^s 198 Leas than ?K of masa 69 t r e f e - ' e r . c e o n l y ) L a s s t h a n 2*J o f m a > s ' 6 9 4 0 - 6 U X o f mass I V S L e a s t h a n JL!i o f ^ j m a a a l^iS B a s e p a a J c ' j i ^ i ' U O X l r e l a t i v e 5 - 9 H 'ei-¥/fma^i,, iviji ff.' 10-3 0 Ji|Jo'^^fea'«^> l!5 i8V Graat;e;h-?'th *h*;*I»t-ftO'f, ma.^s I 9 ' i C-10'0J«^r^^S"/443^- . Greater than 4 0 % of ma'^a 17-23X cf w .'.a 442
I n j e c t lo r . D a t e : 0 ? > ' 3 1 / 8 9 I n j a c t i o n T-, ma: U 9 : 3 1
anui -Tiance
9 ' i
I'^H
D a t a
43 . ^ 4 o .nn
^ 6 . '•II IJ. 01)
4 9 , - 6 0 . 0 0
• o n . n o 7.J?S
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)H*^4m Q m ^
Ol-OJ-
Ok 0:-OV Ot. Ot-01 Oi. O;: OV 1;!.
Analyst'.s S i g n a t u r e
Sample Numbers *Wl3C,«Wft/^ t t . 7 ^ <>^/33, T/^«f/y/aX"^ f/-^V^^T/^^^
o o
o\
5T/5 7
103
*'(
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rood-'
1
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i e f l»
1 3 . 2 I I M t i i | i i < i r
14 .S 1 5 . 2
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t
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I N S T 5 9 7 0 3 , O F T P P 0 5 0 5 0 N G I C M C A L S T O , 3 0 r i S P S - 5 Cf tH C O L U O M
F i l e ; > C ? 1 3 ' ? S c a n * : 441 P a t n . t i m e : 1 3 . 8 7
m/z In t . m y z I r . t m*'z I n t . m-'z I r . t . r » / r i n t -
39.3 0 5 0. Ou 93 .IJO 92.00 54.20 56.00 57.00 62.0 J 63.no 6 5 . 6 9 . 7 4 . 7 9 . 7 6 . 7 7 .
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1 0 0 0 OiJ f lO 1 0 110
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611 002 970
2.970 3.642 1 . 2 1 4
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I r . i t i i ! C^tifcrattor C^ta ftl CoFf ounds
Case No:
C o n t r a c t o r : iNCOSTRJflL C.-^CSiOH
Cantracf Nc: tWW^rtMT
Initrunent IP: 3C
Catibration Date: O'/tJ-'S?
- ' I C
ainiBUB Rf far £KX is .CS r^-visu* X RSO for CCC IS JfiS
Labor.itory 10:
Coepound
N-NttrosodiMV,yl«aine 2-Flucropher.ot A r . i l iM Pherjol-<14 PhenoS 2-Chtoraph9nol bis(2-Chloroethyl)ether 1,3-Oichlorobenzene 1,4-Ojchlorobenierie 1,2-Cichlorobenzene Benzyl alcohol bis(2-Chloroisopropyl)ether 2-nethylpheflol Hexecti loroethane H-ri J t roso-d 1 -n-propy! am i ne 4-netttylphenol Nitrobenzene-dS Nl trobenzene Isophorone 2 - N i t r o ^ n o l 2,4-0iaethylph8nol bis(2-CMoroethQiry)Mth9ne 2,4-UicMorophenoi Benzoic t c i d 1,2,4-Trichloroben?sne
Naphthalene 4-Chloroan:l ine H»xacM orobut a l 1 ene
4-0»loro-J-«thylphenol 2-nethy lMphthalena/v>V . ;v;;
i >C2?S1 >C79/7 >C?V78 » Rf Rf
23.011 50.eo ao.oo
.S(27«8 .82.-71 .ir.'43»
>C2'*?9 Rf
12fl.ua
.8249?
>i:29t!u Rf
160.UII
.80271 1.J2177 1,J695-' l . J : m 1.32446 1.296'!4
1.^6018 1.5(1729 1.44S9J 1.6961? l . t59?i ' 1.83294 1.8909i 1.79fc78 l..'3'J28 1.54766 1.80298 1.72846 1.56526 l . ' f l l95 1.36259 1.53922 1.49044 1.JW05 1.2?':3U i.Odais 1.40963 1.50729 1.57114 1.69617 1.65972 1.74243 1.67885 1.57846 1.52^46 1.45715
1.75606 1.66232 1.54,->97 1.498W 1.39660
1.77J51 1.65583 1.55352 1.52718 1.43514 1.00459 .98251 .96540 1.31905 ,94866 2.16153 1.90669 2.03822 2.13517 2.07877 1.32792 1.27792 1.17713 1.173«8 1.1!.^38
.75317 .76576 .70374 .68154
1.28681 1.23895 1.12310 1.24428 1.44819 1.39038 1.27758 .44066 .43192 .43176
.23763 .22535 .21581
.88513 .84852 .&i844
.26484 .25470 .25488
.36133 .372-rt .56r/4
.52442 .49394 .48879
.59*63 .36541 .'6247
.25610 .29420 .2e926
.43U8 .41105 .594V4
1.1SH72 1.07678 l . t U t i .50.^6 .47647 .464!-:< .24288 .22614 .21412 .42.MI .48AA8 .!yp>»
•^<i7»29 .73349 .68109
'''--'.'.-; -,' -'' 9f ' Reapnnse Fac^tirJlSi|i icnpt^ri> aaount tn Usvn.)
,63883 ,75198
1.23180 1.14459 .43457
.20264
.iM7'/8
.26371
.*85W
.48957
.35y?6
.32^59
.:8886
.91357
.4.'124
.•M}i f
.^97/6
.64765
RRT - A-.-erage Pelat iyefPl t ln t ion: T i ie (KT SXtAll Istd)
.41110
.19537
.802*-5 ,24360 .36531 .45847
.54366
.30794
.?6?"2
.91692
.426-44
.18771
.5 5 7 !
.63540
W l «tF
.316 ,821"»2
.674 1.32668
.943 1.57446
.951 1.75973
.954 1.59219
.9'<5 1.32634
.VJ2 1.56879
.99y 1.59567 1.0115 1,57239 1.054 1.58901) l.'J64 .938>4
l . l «5 2.S5768 1.707 1.207:5
l.l.'*5 .70861 1.149 i . r m 3
1.152 1.29H49 .864 ,43031)
.821 ,21488
.922 .H4480
.952 .25617
.958 .37008
.975 .4894C
.984 ,36583
1.015 ,29462 .994 .;"»9«7
1.005 1.03443 l.BJfl . i«9:6 1.047 ,21487 1,13« .39788
1.147 ,69756
% Pb.) Cl t
1.5)5 1.997
6.551
7.507 11.-^s? •
14.297 7.58n
7.191 8.921 •
8.162 2.54^
4.998 a.Btr
7.359 19.4i')» 9.387 2,596
8.195 5.47t
3.3*3 * 2.26? 4.876 4.9»2 ^ 8.756
5.!«2 l8.9i!!J 4,19V
9.816 • 4.5*1 •
18.459
SPir
#•
fif - ftverage Response F«»or
tfSO - Percent Kel«ti</e Star^rd £'<uiaticn
CCC - Calibration Clecit Csipnwids (*^ SMI - S<jst«a Ptrfiirrance Check Caa aun.1s ('*)
Fora Vl Page I of ' 1 ft ft
y f a ' y
u o» OI o
In i t ia l Calibration Ota HS. fonpouncs
CaM No:
Contractor: !t«(J£TRl«. C'lRRiBlUi
•.:antract fte: n f t ' * ! ^ N f
Instruaent 10: 3C
CalibreMon aue: 0.'/24/8''
r * •
.. % ^
- V
» * , r^
' 4 t
v^
^ ^ ^ ^ p ^ ^ r,-,
- , " k^^
^ ^, t . - - '
» P» .
^ . ?
rmiaja Rf f,-.r:?,SPCC- is .05 ra-'isu» X KSU for CX is 3ii?l
i Laboratory 11): >L29S1 >U'2977 >L7* '8 >C297«» >C,;98I! M
Coixpound
Heyachlorocyclopentadiene ' 2,4,6-Tr icMorophenol
2,4,5-Trichlaropher.ol 2-Fluorobiphenyl
' 2-Chloronaphthalene 2-Ni t roani l in« Acenaphthylene
Oiaethylphthalate 2,6-UinitrotDluene 3-NitroaniItne flcenaphthar«
2,4-Oinitrophenol Oibenzofuran
J 4-Nitrophano: [j 2,4-0ini t rotaluen«
4-'iIhlorophenyl-pnfnylat.^«r
1 ^ Oiethylphthalate B 4-Ni t roani l ine ^ ^ 2,4,6-Tr Ibroaopheno I
4,6--Oinitro-2-nethy:phenil N-Nitrosedip»enytaistne (1)
ftzobenrene 4-8roaaphenyl-phenu|ether
Heiaehlornbenzerie Pentachlorophenol (^^nanthrene
Anthracene Ui-n-tuitylpNthalate
Fluoranthar^ . ^ <.:;><>
Bf Rf Rf Rf Rf 20.00 50,08 30.!!8 IV!!. 80 160. nO
.15515 .26712 .26B11 .2«9tt2 .26592
.48628 .46500 .45027 .4505? .41194
.53425 .50907 .«9V)4 ,-6944 .4 l l ' '4
1.35178 .98795 ,93390 .91785 .84059 1.37465 1.2V562 1.2!!l39 \ . \ n - f i I.f59'i8
.46985 .46651 .46159 .45785 .44693 2.84761 1.96555 l.84«fl9 l . ; 5 f i : i 1.57406
1.78122 1.68931 1.63505 1.57271 1.47^64 .42506 .45265 .42078 .419^3 .39106 .44,'96 .41882 .37850 .57576 .55813
1.36454 1.21510 1.0V863 1.85267 .96365
.24028 .29318 .51583 .33215 .31666 1.94848 1.80862 1,70686 1.68228 1.5549/
.26038 .27848 .25793 .24682 .23488
.62785 .62717 .60912 .6!?:04 .56452
1.56736 1.47987 1.37734 1.33574 1.22128 .73687 .67676 .63541 .422al .5,''443
1.84226 1.68144 1,55475 1.58474 1.41W8 .46561 .47286 .46884 .44573 .572'.8 .15264 ,14113 ,15893 ,14563 .14203 ,21644 .23499 .25517 .21567 .17528 .6399a ,59158 ,51250 .4=843 ,40290
1.52716 .97584 .9!y81 .24518 .73438 .25426 .23596 .23265 .23735 .23829 .29946 .28536 .2*778 .-JaiV) .2/^619 .20.'45 .21601 .205IW .21537 .21526
1.36911 1.23'>51 1.18/60 l . lV j ^ v 1,15'2S7 l.)?88« 1.29824 1.20223 1.1*722 l . l ? r . 2 1.9S9S2 V.W95 1,64559 l . ^ l t f t } l .J^87l
,4.«288J41§56854 1.43553 1.46530 1,31467
m yf
.878 .24866
.893 .45243
.897 .43341
.906 .946-25 ,915 l.r.U19
.942 .46030
.977 1.8J7IW
.980 1.62979 ,9(J8 .4177*
1.006 .39584 l.e:i6 1.15892
1.021 .29962 1.050 \ .?Ain i 1.041 .25554 1.845 .ia65!'
1.882 1.3'»632 1.387 ,64878 I.W9 1.6C841 I . I M .445fiS .919 .14437 .907 .21511 .939 .52CK4 .911 .9«BC?
,950 .23918 .964 ,28175
,988 .21198 1.503 1.227*4 1.839 1.22194
1,693 1,66)66
1.150 1.46.?37
% s^v CiC spcr;
21.5y7 »• 5.957 • 9.{:J6
8.3:7 9.725 1.936
10.!599
7.158 5.784 9.257
1J.6<7 *
12.005 • •> 8.467 < 6.4P9 ' • *
4.220 9.535 9.439
10,326 9,44Ji
3.723 11.171
18.418 • 12.7^2 3.969 4 . l e ;
2.314 t 6.974
4.38^ 14.168 7,542 •
'-Z''M:^^yyy •'
• -^^iij'--^-^y:y:=%,^Z^. •' -'^y'-v 'Zzye^SfJ:, ^^ i^Mm^M- '•
'Zs'-M-yM''.''^'- •
-.•-! i * * - )
BF
Kfti
• Resp< . '"'%s-iz y2- ' y y 0 m i y
nnse F^actor .tSubacriptf is^anunt in •. .r^S^-i f t fe.e,, .^5(iS>•.. . , I• i ,WJ.-r ' ' . -K.-:-S'^w' ' ,
utm)
ftw«rage vl*»iliii««ilSitin<icniTiaek(»^ I'
fr-frage Pfsponse factor
9RS0 - Percent Re'.atjve stan.lard !!<!viattnn
tdl
CCC - Calibration Ciecii Ccapoimds (») SHIl - Stiatea Perforaance Check Coapouni s t**)
far* VI Pane 2 of 3
'•or
S^^ 'm y ^ a y . . y t i :m: y> ' z.:. .-;.-;o.'-%..
m fl..:'-0)c?;.-?tit.J
i*^* ..-''.c'yit-^ .v-' ,-.. <v--,'c.'
, - • ' 1 ^ 5 - 4
r J ^ • m ,:;,-, «A,
'Zyr y ^ ; ' ^ i ^ r ^ U l . . ! ' -y.A y^yr*- ' • 'rr^i
, • • • • • , • - . • . - . ? > }
• p - •.. ' - ' ' ' 'A ' 'y.yyyy-z-^ • ' • • - • : ' - - i ? ^
• \ ' v ^ '
• / y
1
|r,-,t-.al Cal id.-ar icn Oata HSL Corrcun.ls
Case No:
Contractor: iNftJSfPIflL C-WJSICM
Contract Mo! : ' = M w i T t N f •: .
Instrunent 10: 3i:
Calibration Date: O.V'^4/8''
fliniiiwia Rf for ;SHCt: IS ,C'"' r,Ji'i\M» % SSD f.ir DC IS 3li!J
L^tjoratory
Coopounrt
>C29M1
2fl.3!l
>C2V77
Rf
50 . Oil
>C2979 RF
80.110
>C^ '9 ;N
Rf 120.RB
>C':v8!i Rf
160.^0 K«T ( f % m.\ DT !-Hcr
Benzidine .01476 .31390 .31294 .ni2fcy .01219 l.2'i4 .1)1330 7.7:6 P-yrena 1.88059 1.80207 1.73638 1.75o73 1.,'3474 ,825 1.78218 3.445 Terphar.yl-dl4 1.15827 1.12!!a5 1. ! !B418 1.0!?2!4 I.u5-'y2 .986 1.II9631 3.60-.' Butylbenrylpnthaiata 1.08237 1.08598 1.81138 1.00417 .98357 .960 1.03349 4.i.?4 Benzoia)anthr»ceae 1.66415 1.602116 1.577.'a 1.57^54 1.566^4 .999 1.59.'11 2.48'' 3,3*-0ichl3robenzidir.8 .59137 .578:'8 .56856 .53200 .43391 1,082 .55ia7 7.892 Chrysene 1.494^3 1.46H08 l . }9 i43 1.344l'# 1.-/65'9 1.083 l.?9314 6.67« bist2-Ethylhe-<y:)phth3late 1.58515 1.55B83 1.42499 1.38'-"23 1.32'»91 1.019 1.45482 7.452 Di-n-octylphthalate 5.1B!I51 5.17650 2.88556 2."0712 2,92119 .949 2.99774 4.399
eanrolb)fluoranthene 1.8935? 1.78683 1.95763 2.55256 2.72881 .9*3 2.18228 19.4.')5 tonzotklflucranthene 1.76410 1.74471 1.54735 1.15436 ?.,^ft81 .965 l..->8626 ^2.305 eenzotalpyrene 1.62880 1.60020 1.58646 1.637711.61194 .995 1.61382 1.299 lrdenotl,2,3-cdlpyrene 1.33910 1.35156 1.24442 ,65750 1.4165" 1.144 1.19783 26.649
Oir4nz(a,h)anthracene 1.25105 1,27507 1.28243 1.21613 1.16120 1,151 1.22118 3.609 benzo(g,h,i)perylene 1.28V05 1.5eSrt2 1.16428 l.r,'»l69 l.:i542*i 1.1«7 1.18746 8.954
T
" * . £ / * - , ' ' ^
y I ' - ' ^ . . . ' "-t. * i
Rf Responi'a Farter,, (Suhwript.tV^OBnunt in %.Tt.)
Ai-eraoe Relattve'ReteiitionTiae^ ( K >»td.1?r Isti!)
C'.-eraga Respcnse factor
Percent Stel.it!'* Staniarj Ueviatis.-\
Cal'.brafion Check l>.af,««il« (•) SW - S-^ten Perfor»snce O'-eck C-^coads (•*)
fora ')[ Pv n 3 r-f ) 1 0 fl
'IvZfimijrY^ryr;.
m
.C»5'
Continuing Catibratior. D-'ecii K>L Compounds
Ca^e tio:
Ccntracto.-: ItOlSTRIW. Cl»*iBia)
Contract Nn: R«l«iEfl£NT
Instrusant IC: 3C
CahbraMon C«l«: 0?'5;/^9
Tiae: l ' i : lA
Laboratory IC: >C51'6
I n i t i a l Cal i t raf ior , Cste: 05.'24,'8"?
riiniBUffl Rf for S W is .05
Coapaunrt Rf
RaxiHua !t Oiff for C X is 25S
RF ttiff O X SPCC
N-Nitrosodiaethylaaine 2-fluorophenol
A r i l i ne PhenoI-d6 P^.enol 2-Chlorophenol bis(2-Chloroethyl)ether
1,3-Oichlorobenzene 1,4-Oichtorobenzene 1,2-Dichlorobenzene Benzyl alcohol bi9(2-ChloroisRpropyl lether 2-nethylphenol Hexechloroethane N-Nitroso-di-n-propylaaine
Nitrobenzene-d5 Nitrobenzene Isophorone 2-Nitrophenol
2,4-Oiaathylphenol bis(2-Chloroathoxylaethane 2,4-Oichlorophenol
Benzoic acid 1,2,4-Trichlorobenzene
Naphthalene 4-Chloroanil ine
He«achIorobutadiene 4-Chloro-3-aethylph«nol
2-nethylnaphthalene . ' ; i i j ^ . ; ' Hexach lorocyc lopentaditimii l^.;
.82192 .25718 1.52668 1.52CS6 1.57446 1.43095 1.75975 l.,-^165 1.59219 1.67239
1.J2634 1.42514 1.56879 ,90234
1.59567 1,67829 1.57239 1,66613 1.589'JO 1.67508
.98804 ,81081 2.85768 1.55674 1.2072* 1,17955 ,78861 .76704
1.12903 1.09019 1.29849 1.26635
,43000 .42157 .21480 .23717
.84480 .81550
.2561? .23391
.37808 .35868
.48948 .47615
.36503 .34606
.29462 .13827
.39907 .48116 1.93440 1.12134
.46916 .36988
.21487 .22491
.39789 .3M92
yw7i f^7Am •«v24e66ft.l2M0
2,4,6-Tr ich lorophenoi^ | i ;^#- ;5^452/WS-- i^^
- . • y 7 f i ; ^ y z ^ ^ ' y y ; ^ i } y » . . yy$MM'i^- '< i^-y^ ' -^ -••- • -
RF - itesponse Factorjfr«M'.•tallyiitanCard f i l
68.71 .46
5.94 .46
5.84 •
7.45 42.48 5,18 5.96 • 5.42
18.02 24,34
2.29 8.25 3.44 • *
2.-48 1,96
19.42 3.47 8.69 •
3.98 2.71 5.19 •
53.97
.52 8.41
21.18 4.67 «
7.99 •
6.58 49.9'/ • * 2.99 •
le at 59.30 U6.
RF - A^'erage Response Factor froa Initial Caliwration Fora V!
Oiff • X Oiffer5nr.e frca anginal average or curve
CCC - Calibration Check Diapowds (*i SPCC - S^«tea Perforaance Oieck Coopnunds (**)
Fora UIl Pa.:;a 1 ef 5 1 0 8
•O'
o
Ol Ol
Continuing Calibration D^eck HS. Coapounds
'Ja-ie tio:
Contractor: DOJSTPIAL CIKFOSION
Contract Ho: .rnNAttftNT
InjtfuMnl ID: iC
Calibration Cate: O.VJl.'Oy
Tiee: 10:16
Laboratory IC: )Cn?6
I n i t i a l Cj!:br-iHo.r Date: 0'/24/8V
"' z/'f'yy.
tliniiTJia Rf fcr SPCC is .05
Ca-apound Kf
ItiYiaua S Oiff for ClX is 2f*
Rf iCiff CCC s p a
2,4,5-Trichiorophenol 2-FluorobiphV7! 2-C')lor3naphtha!er.e 2-»iJro8r,ilir.e Acanaphthylere Oiaethylphthalate 2,6-Oinitretoluene 3-Nitroaniline Acenaphthene 2,4-Oinitrophenol Oibenzofuran 4-Nitrophenol 2,4-Oinitrotoluene Fluorene 4-Chlorophenyl-pnenylether Oiethylphthalate 4-Nitrcanitine 2,4,6-TribroacphensI 4,6-0initro-2-«ethyIphenol M-Nitroaodiphenylaair.e (!) Azobenzene 4-8roaophenyl-phenylether HexachIorcbenzene Pentachlorop^«nol Phena-tthrene Anthracene Di-n-butylpMhalats Fluoranthene &nzidine Pyrene Te.'phanyl -dl4 fiuty!ben:ylphthalate :f4f'y •'
zy%: -''
.48341 .44834 3.12
.94625 .96025 1.4« 1.22419 1.27927 4.50
.46850 .57583 ?9.52 1.83709 1.91707 4.35 1.62979 1.54171 5.4u
.4177/ .36681 12.20 .39584 .54539 12.74
1.13892 1,22521 7,58 ,29962 .14150 52.77
1.74024 1.68427 3.22 .25554 .26722 4.5? .68658 .52473 15.4y
1.39652 1,40823 ,8S .64878 .65098 .34
1.61941 1,66265 3.89 .44505 .30954 58.49 .1440? .15661 5.18 .21511 .19158 10.94 .52894 .5775! 18.84 .90007 1.00157 11.28 .2!810 .23206 2.54 .28173 .28834 .49 .21198 .20272 4.37
1.22/64 1.27889 3.46 1.K194 1.24944 2,25 1.64366 1.83621 18.37 1.4e.'571.52124 5.67
.91339 .91919 14.22 vj l.?K!19 1.64944 7.67 'Siif?*)! Ii8«93 9.51
•^l-:»?i^:;i;?W75 4.81
RF - Response Factortf ro r daily: stMdard file et '-'9.!)3 iG/nL
Rf - A-Jersga Response factor froa Initial Calibfetion Frra VI
"SOiff - % Difference froa original av-erage or curve
CCC - Calibratiai Cieck CAcptwnds (*) SK£, - Syateo Parforaancs D'-ack Ciapnunds (**)
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Continuing Caiibrati j. ' i Ciiect: ({9. Cospounfls
Case t:o:
Contractor: iMOlTilRIAL CUTPObilCN
Cnntract Nn: r p m s O t l T
Instrunent ID: 3C
Calibration Date: 0-/31/8':'
Tiae: 1-J:14
Laboratory IC: >C51.'6
I n i t i a l C i l i t r a t i o r , O.-ite: fl5/24/SV
tliniBua RF f,-r SPCC is .C5 RaxiHja % Oif f fc? OX is T-A
Coapeunri
BenzoleJanthracane 3,5'-Oichlorab«nzid;ne
Chrysene bis(2-EthyIhexyl)phthalate Oi-n-or.tylphthalate Ger.zolblflucranthens 8enzo(k)fluoranthene
8e,tzo(a)pyrene Indenoll,2,5-cd)pyrene Oibenz(a,h)anthracene 8enzo(g,h,i)psry!ene
Rf Rf
1.59713 1.55532 .55087 .31025
1.39514 1.41879
1.45482 1.45l-.'8 2.99774 2.73424
2.18228 1.84721 1.78626 1.84720
1.41502 1.57436 1.19783 1.61383 1.22118 1.44544 1.18746 l.6'284S
!B)iff i x i : SP-X
2.74 4?.6H 1.84 .25
8.79 » 15.55 3.41 2.48 •
34.73 18.36 37.13
:'^*SfS^3
- y y
'1;.
•» ' - . , f
Rf - Sespcnse Factor" froB d u l y s tvdard f : ! e at 5!:.03 LN'TS
Sf - A-.'erag!> kespnnsa Factar froa I n i t i a l CalitraMa.". F-.ra 'Jl
VQiff - % Difference f rca o r : g i m l a«.-Kre^e nr curt-e
CCC - Cal ibrat ion Check Coapounds (*) SPCC - Syatea Perforaance O-iack C-apounda (>•)
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