supporting information fore-mail: camilla.parmeggiani@lens.unifi.it b dipartimento di chimica “ugo...

Supporting Information for

First Thiol-yne Click Chemistry approach for Liquid Crystalline Elastomer preparation

D. Martella,a,b,c C. Parmeggiani,*a,d D. S. Wiersma,a M. Piñolb and L. Oriol*b

aEuropean Laboratory for Non-Linear Spectroscopy (LENS), University of Florence, Via Nello Carrara 1, 50019 Sesto Fiorentino, Italy. E-mail: camilla.parmeggiani@lens.unifi.itbDipartimento di Chimica “Ugo Schiff”, University of Florence, via della Lastruccia 3-13, 50019 Sesto Fiorentino, Italy.cInstituto de Ciencia de Materiales de Aragón (ICMA), Departamento de Química Orgánica, Facultad de Ciencias, CSIC-Universidad de Zaragoza, C./Pedro Cerbuna 12, 50009 Zaragoza, Spain.E-mail: loriol@unizar.esdIstituto Nazionale di Ottica (CNR-INO), U.O.S. Sesto Fiorentino, Via Nello Carrara 1, 50019 Sesto Fiorentino, Italy.

Electronic Supplementary Material (ESI) for Journal of Materials Chemistry C.This journal is © The Royal Society of Chemistry 2015

S2

Summary

Figure S1. 1H-NMR spectrum (400 MHz, CDCl3) of compound M1. S3

Figure S2. 13C-NMR spectrum (100 MHz, CDCl3) of compound M1. S3

Figure S3. 1H-NMR spectrum (400 MHz, CDCl3) of compound M2. S4

Figure S4. 13C-NMR spectrum (100 MHz, CDCl3) of compound M2. S4

Figure S5. DSC traces on heating and on cooling of M1, 7 and M2. S5

Figure S6. FTIR spectra of the monomers. S6

Figure S7. FTIR spectra of the LCE films. S7

Figure S8. POM images and XDR trace for E-CL120 film. S7

Figure S9. DSC traces corresponding on heating and on cooling of LCE films. S8

Figure S10. POM images of E-CL120 film at different temperatures. S9

Figure S11. TGA traces of LCE films. S9

Figure S12. Stress-strain curves for E-CL120 film. S10

S3

O O

OOC4H9C4H9O

O

OO

OM1

Figure S1. 1H-NMR spectrum (400 MHz, CDCl3) of compound M1.

Figure S2. 13C-NMR spectrum (100 MHz, CDCl3) of compound M1.

S4

O SHOHSO

O

O

O

M2

66

Figure S3. 1H-NMR spectrum (400 MHz, CDCl3) of compound M2.

Figure S4. 13C-NMR spectrum (100 MHz, CDCl3) of compound M2.

S5

Figure S5. DSC traces (10 °C/min) corresponding to the second cycle of heating and cooling of M1, 7 and M2.

M1

M2

7

S6

Figure S6. FTIR spectra of the monomers.

M1 M2

CL1 CL2

CL3

M1 M2

CL1

S7

Figure S7. FTIR spectra of the LCE films.

Figure S8. POM images and XDR trace for E-CL120 film. a) POM image of the film (20); b) same image rotates of 45° in respect of the analyzer. c) XRD pattern, the arrow indicates the alignment direction

E-CL120 E-CL110

E-CL220 E-CL320

a

b

c

S8

Figure S9. DSC traces (10 °C/min) corresponding to the second cycle of heating and cooling of LCE films.

E-CL110E-CL120

E-CL220 E-CL320

Figure S10. POM images of E-CL120 film at different temperatures. Images registered at 90 ºC, 120 ºC and 160 ºC (up to down) while rotating the sample 0, 45 and 90º in relation to the preferential alignment direction (left to right).

Figure S11. TGA traces of the LCE films.

E-CL110

E-CL220 E-CL320

E-CL120

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0 0.2 0.4 0.6 0.8 1 1.20

1

2

3

4

5

6

Strain (%)

Stre

ss (M

Pa)

Figure S12. Stress-strain curves for E-CL120 at room temperature.