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SRNMC Regulation-2016 Syllabus
SRI S.RAMASAMY NAIDU MEMORIAL COLLEGE
SATTUR- 626 203 (An Autonomous institution affiliated to the Madurai Kamaraj University, Madurai)
(Re-Accredited with Grade ‘A’ by NAAC)
M.Sc. DEGREE COURSE
IN
CHEMISTRY
SYLLABUS AND REGULATIONS
UNDER
CHOICE BASED CREDIT SYSTEM (CBCS)
(Those who joined in 2016-2017 and after)
SRNMC Regulation-2016 Syllabus
Objectives
To enable the students
1. To gain knowledge on the basic and advanced level aspects in the different
disciplines of chemistry.
2. To get an exposure to the basics in Nano chemistry and biochemistry.
3. To gain knowledge on the basic and advanced level experimental techniques.
4. To get an exposure on some current trends in chemistry.
Eligibility for Admission
B.Sc. degree with chemistry as the core subject and physics as one of the allied
subjects; the other allied subject may be any one of the following: Mathematics, Botany and
Zoology.
Duration of the Course
The duration of the course shall be two academic years comprising four semesters
with two semesters in each academic year.
Courses of Study
1. Core subjects
2. Major elective subjects
3. Non major electives
.
Credits
The term ‗credit‘ refers to the weightage given to the course, usually in relation to the
instructional hours assigned to it. The total credits required for completing Master of Science
in Chemistry is 90. The particulars of the credits for individual components and courses are
placed on Table-1.
SRNMC Regulation-2016 Syllabus
Extra Credits Paper:
1. This paper is optional. Students may or may not select this paper. If he/she selects
this paper and if he/she passes the paper, then 3 extra credits will be added in his/her
total credit to the degree, even otherwise, it won‘t affect the completion of degree.
2. Though this paper is common to all PG programmes, the syllabus varies according to
the subject selected by the department.
3. The title of this paper is ―Model Paper for NET Examinations‖
4. Examination for this paper will be held at the end of the 4th
semester examinations.
5. There is no internal examination and only external examination for this paper.
6. Maximum marks for this paper is 100.
Scheme of Examination
It is presented on Table-2
Pattern of the Question Paper
Theory
Part A
Ten questions (Multiple choice) 10 x 1 = 10 marks
Two questions from each Unit
Part B
Five questions (either or type) 5 x 7 = 35 marks
One question from each Unit
Part C
Three questions (out of five) 3 x 10 = 30 marks
One question from each unit
---------------
Total 75 Marks
---------------
Evaluation:
The performance of the student is evaluated in terms of percentage of marks with a
provision for conversion to grade points. Evaluation for each course shall be done by a
continuous internal assessment by the concerned course teacher as well as by an end semester
examination which will be written type examination of 3 hours duration and will be
SRNMC Regulation-2016 Syllabus
consolidated at the end of the course. The ratio of marks to be allotted to continuous internal
assessment and to end semester examination is 25:75 (i.e. Internal 25 Marks and external 75
Marks)
The components of continuous internal assessment are:
Two tests and their average 15 Marks
Seminar/Group Discussion 5 Marks
Assignment 5 Marks
Total 25 Marks
Passing Minimum
A) Theory
1. 50% of the aggregate (External+ Internal)
2. No separate pass minimum for Internal
3. 34 Marks out of 75 is the pass minimum for the External.
B) Practical
1. 50% of the aggregate (External+ Internal)
2. No separate pass minimum for Internal
3. 27 Marks out of 60 is the pass minimum for the External.
C) Project
1. 50% of the aggregate (Project Evaluation + Viva Voce+ Internal)
2. No separate pass minimum for internal.
3. 27 marks out of 60 is the pass minimum for the External.
SRNMC Regulation-2016 Syllabus
M.Sc (CHEMISTRY)
Table -1: Course pattern
(With effect from the academic year 2016 – 2017)
Extra Credits Papers: 3 Credits
Grand Total : 93
S.No
Semester
I
II
III
IV
V
Total
Hours
Total
Credits
No. of
Courses
1
I
Core
6(5)
Core
6(5)
Core
6(4)
Elective
6(4)
Practical
6(4)
30
22
5
2
II
Core
6(5)
Core
6(4)
Core
6(5)
Elective
6(4)
Practical
6(4)
30
22
5
3
III
Core
6(5)
Core
6(5)
Core
6(5)
Elective
6(4)
Practical
6(4)
30
23
5
4
IV
Core
6(5)
Core
6(5)
Core
6(5)
Elective
6(4)
Project
6(4)
30
23
5
TOTAL
120
90
20
SRNMC Regulation-2016 Syllabus
M.Sc (CHEMISTRY)
Table -2: Course details and scheme of examinations
(With effect from the academic year 2016 – 2017)
Semester Title of the Paper
Subject
Code
Hr
s
/we
ek
Credit
Exam
hrs.
Marks Total
Marks Int Ext
I
Organic chemistry - I
Stereochemistry and
reaction
mechanism -I
P16CHC11
6 5 3 25 75 100
Inorganic
Chemistry I –
Atomic properties,
coordination and solid
state
chemistry I
P16CHC12
6 5 3 25 75 100
Physical
Chemistry I –
Thermodynamics and
electrochemistry
P16CHC13
6 4 3 25 75 100
Major elective:
a)Environmental
Chemistry
b) Biochemistry
P16CHE11
P16CHE12
6
4
3
25
75
100
Practical I Inorganic
Chemistry
P16CHC1P1
6
4
6
40
60
100
II
Organic Chemistry II -
Natural products,
conformational analysis
and reaction
mechanism – II
P16CHC21
6 5 3 25 75 100
Inorganic Chemistry II -
Bioinorganic and solid
state
chemistry II
P16CHC22
6 4 3 25 75 100
Physical
Chemistry II -
Quantum, catalysis and
molecular spectroscopy
P16CHC23
6 5 3 25 75 100
SRNMC Regulation-2016 Syllabus
Major Elective
a)Analytical Chemistry
b)Industrial Chemistry
P16CHE21
P16CHE22
6 4 3 25 75 100
Practical – II
Organic Chemistry
P16CHC2P1
6 4 6 40 60 100
III
Organic Chemistry III -
Reactions , reagents and
Spectroscopy
P16CHC31 6 5 3 25 75 100
Inorganic Chemistry III -
Inorganic Spectroscopy and
Nano Chemistry
P16CHC32
6 5 3 25 75 100
Physical Chemistry III -
Group theory and
nanochemistry
P16CHC33 6 5 3 25 75 100
Major elective: (Any one)
a) Computer Applications
b) Pharmaceutical
chemistry
P16CHE31
P16CHE32 6 4
3
25
75
100
Practical III
Physical chemistry
P16CHC3P1
6 4
6
40
60
100
IV
Organic chemistry -IV
Molecular rearrangements
and synthetic methods
P16CHC41 6 5 3 25 75 100
Inorganic Chemistry IV -
Nuclear and
Organometallic Chemistry.
P16CHC42 6 5 3 25 75 100
Physical Chemistry IV -
Chemical Kinetics ,
Surface, Biophysical and
Photo Chemistry
P16CHC43
6 5 3 25 75 100
Major Elective: (Any one)
a) Introduction to Nano
Science
b) Polymer Chemistry
P16CHE41
P16CHE42
6 4 3 25 75 100
1) Project
2) Review of recent aspects
of Chemistry
Viva Voce
P16CHPT41
6 4 6 40
40
20 100
Extra Credit Paper
Model Paper for NET /SET
Examination P16CHX41
3 3 100
SRNMC Regulation-2016 Syllabus
SRI S.RAMASAMY NAIDU MEMORIAL COLLEGE (An Autonomous Institution Re-accredited with ‗A‘ Grade by NAAC)
SATTUR-626 203.
Department of Chemistry
(For those who joining in 2016-2017 and after)
Programme : M.Sc. Chemistry Subject Code : P16CHC11
Semester : I No.of Hours allotted : 6 / week
Subject : Core Paper I No of Credits : 5
Title of the Paper : ORGANIC CHEMISTRY - I
STEREOCHEMISTRY AND REACTION MECHANISM- I
Objectives
To enable the learners
To learn the basic concepts of organic chemistry
To know about the basic concept of stereochemistry in detail
To understand the aromatic character of organic compounds.
To learn the fundamentals of reaction mechanism.
Unit-I Electron displacement and structure-reactivity correlation
Inductive and field effects – bond distances - bond energies – delocalised
bonds - cross conjugation – rules of resonance effect - steric inhibition of resonance
– hyper conjugation - hydrogen bonding – addition compounds – EDA complexes -
inclusion compounds.
Quantitative treatment of the effect of structure on reactivity – The
Hammett relationship - significance of reaction and substituent‘s constants -
application of the Hammett equation in reaction mechanism – limitations and
deviation.
Unit II Stereochemistry –I
Symmetry elements - Concept of chirality , necessary and sufficient conditions
for chirality – Relationship between substrate symmetry and chirality - Projection
formulae – Wedge, Fischer, Sawhorse and Newmann - Optical isomerism due to
centre of chirality - Molecules with one stereogenic centre (chiral centre) and
molecules with more than one chiral centre – properties of enantiomers and
diastereoisomers – erythro and threo nomenclature – Cahn, Ingold and Prelog
system of designation of configuration .
SRNMC Regulation-2016 Syllabus
Geometrical isomerism: E-Z nomenclature- determination of configuration
of geometrical isomers using physical and chemical methods – stereoisomerism in
monocyclic compounds (upto six membered ring).
Unit III Stereochemistry II
Prochirality and prosteroisomerism, enantiotopic and diastereotopic ligands
and faces and their nomenclature - pro-R and pro-S and Re and Si faces -
Stereospecfic and stereoselective reactions - Asymmetric synthesis; Cram and
Prelog rule - Optical isomerism due to axial chirality - biphenyl, Allenes and
spiranes - Molecules with planar chirality – paracyclophanes, trans-cyclooctene and
ansa compounds.
Unit –IV Aromatic Character
Aromatic character in benzene, six membered rings, five, seven and eight
membered rings – other systems with aromatic sextets – Huckel‘s rule – Craigs rule
– concept of homoaromaticity and antiaromaticity - systems with 2,4,8 and 10
electrons – systems with more than10 electrons – Alternant and nonalternant
hydrocarbons - Chemistry of cyclopentadienyl anion – Fulvene, Azulene,
Tropolones, Sydnones and Annulenes .
Novel ring system: Nomenclature of bicyclic and tricyclic systems -
chemistry of adamantane, diamantane (congressane), cubane and catenanes.
Unit –V Introduction to Reaction Mechanism
Reaction intermediates – free radicals, carbenes, nitrenes, carbanions,
carbocations – formation and stability of reaction intermediates – methods of
determination of reaction mechanism - kinetic and thermodynamic control of
chemical reaction - Kinetic and non kinetic methods for determining organic
reaction mechanism –principle of microscopic reversibility – Hammond postulate.
Partial rate factors - ortho/para ratio - Quantitative treatment of
reactivity of the electrophile (the selectivity relation).
Text books:
Text book-1
Title of the book : Reaction mechanism and reagents in organic chemistry
Names of the Author : G.R. Chatwal
Publisher : Himalaya publishing house,
Edition/Year : 5/2012
SRNMC Regulation-2016 Syllabus
Text book-2
Title of the book : Stereochemistry of Organic compounds, Principles and
Application,
Name of the Author : D.Nasipuri
Publisher : Wiley eastern Ltd
Edition/Year : 2 /2006
Text book-3
Title of the book : Stereochemistry conformation and Mechanism
Name of the Author : P.S.Kalsi
Publisher : New age international publishers
Edition/Year : 1/1990
Text book-4
Title of the book : Organic chemistry Vol-II
Name of the Author : I.L.Finar
Publisher : ELBS Longmann
Edition/Year : 5 /1975
Text book-5
Title of the book : Organic reaction mechanism
Name of the Author : V.K Ahluwalia
Publisher : Narosa publishing House New Delhi
Edition/Year : 3 /2007
Unit –I (From text book 1)
Chapter –2 (Page No.2.1- 2.46)
Unit –II (From text book –2) Chapter – 2 (Page No.15-20)
Chapter – 3 (PageNo.27-36)
Chapter – 5 (Page No. 43-67)
(From text book –4) Chapter – 4 (Page No.170-200)
Unit –III (From text book –3)
Chapter – 1 (Page No.84-130)
Unit –IV (From text book –1)
Chapter –13 (Page No.13.1-13.37)
Unit –V (From text book –5) Chapter –2 (Page No.78-118)
Reference books
Reference Book-1
Title of the book : Guide book to Mechanism in Organic chemistry
Name of the Author : Peter Sykes
Publisher : Orient longmann Ltd., New Delhi,1998,
Edition/Year : 6 / 1984
SRNMC Regulation-2016 Syllabus
Reference Book-2
Title of the book : Organic chemistry,
Name of the Author : R.T.Morrison and R.N. Boyd,
Publisher : Prentice, Hall,
Edition/Year : 6/ 1995,
Reference Book-3
Title of the book : Mechanism and Structure of Organic Chemistry,
Name of the Author : E.S. Gould,
Publisher : Holt, Rinehart and Winston Inc, New York,
Edition/Year : 2 /2006
Reference Book-4
Title of the book : Stereo chemistry of carbon compounds,
Name of the Author : E.l.Eliel
Publisher : Mc Graw Hill
Edition/Year : Reprint 2008 Edition / 1975
Reference Book- 5
Title of the book : Advanced Organic Chemistry,
Name of the Author : Jerry March,
Publisher : John Wiley and Sons,
Edition/Year : 4/ 2004.
Prepared by :
Signature :
SRNMC Regulation-2016 Syllabus
SRI S.RAMASAMY NAIDU MEMORIAL COLLEGE (An Autonomous Institution Re-accredited with ‗A‘ Grade by NAAC)
SATTUR-626 203.
Department of Chemistry
(For those who joining in 2016-2017 and after)
SYLLABUS
Programme : M.Sc Chemistry Subject Code : P16CHC12
Semester : I No. of Hours allotted: 6 / week
Subject : Core - Paper II No. of Credits : 5
Title of the Paper : INORGANIC CHEMISTRY – I
ATOMIC PROPERTIES, COORDINATION AND SOLID STATE
CHEMISTRY -I
Objectives
To enable the learners to
Apply molecular orbital theory to the poly atomic molecules
Know about bond properties , Ionic bonding and the concepts of solid chemistry
Interrelate the structure of inorganic cage, chain and poly-acids.
Unit I : Nature of chemical bonds:
Covalent bond: Hybridisation – Calculation of S and P characters – Bent‘s rule –
VSEPR theory - M.O.theory; LCAO approximation – application of MOT to heteronuclear
diatomic molecules like NO, CO and triatomic molecule BeH2 –Structure and bonding of
electron deficient molecules like diborane.
Unit II : Atomic Properties
Ionic radii - covalent radii – Vander Waals Radius – bond length, bond order,
bond energy, bond polarity – partial ionic character of covalent bonds – electro negativity
– electron affinity –Lattice energy-Born-Lande equation-Born Haber cycle - Covalent
character in ionic compounds - different types of electrostatic interactions - hydrogen
bonding.
Unit III: Co-ordination chemistry I
Basics of co-ordination compounds- IUPAC nomenclature of co-ordination
compounds – isomerism in co-ordination compounds – types of ligands – monodentate,
ambidentate and macrocyclic ligands – chelate and its applications – detection of complex
SRNMC Regulation-2016 Syllabus
formation in solution – factors affecting stability constant in solution – determination of
stability constant by spectrophotometric, polorographic and potentiometric and Job‘s method.
Unit IV : Solid state chemistry – I
Elements of crystallography-space lattice - Unit cell-Crystal system - X ray
diffraction - Bragg‘s equation-Bragg‘s method-Rotation crystal method and powder method
of x-ray diffraction - Evaluation of unit cell dimensions - Structure of typical lattice
such Cesium chloride, Zinc blende, Wurzite, Rutile, Fluorite, antifluorite, perovskite,
covalent crystal as diamond and graphite.
Unit V : Inorganic chains, rings and cages
Polyacids – classification – isopoly acids like polymolybdate, polyvanadate and
polytungstate – their structures – heteropolyacids 12A, 12B, 9 and 6 heteropolyacids –
Preparation and structure: Silicates - Silicones- Phosphazenes and their polymers – S4N4 –
polymeric sulphur nitride (polythiazyl) cage compound- Boranes – nomenclature of boranes
and carboranes –Wade‘ rules – Styx number – preparation and structures of B4H10 and
C2B10H12 – borazine.
Text books
Text Book- 1
Title of the book : Selected Topics in Inorganic Chemistry
Name of the Author : Wahid U.Malik
Publisher : S.Chand and Company Ltd.
Edition/Year : 7/2007
Text Book- 2
Title of the book : Principles of Inorganic Chemistry
Name of the Author : B.R.Puri and L.R.Sharma and K.C.Kalia
Publisher : Milestone Publishers,New Delhi 2008.
Edition/Year : 30/2008
Unit-I (From Text Book-1)
Chapter – 5 (Page No 154 to 196)
Unit II to V (From Text Book-2)
Chapter – 2 (Page No 64 to 79)
Chapter – 4 (Page No 131 to 135 , 179 to 183)
Chapter-26 (Page No 729-734, 738 to 764)
Chapter – 6 (Page No 222 to 231, 244 to 246)
Chapter – 16 (Page No 466 to 472)
Chapter – 15 (Page No 417 to 429)
Appendix I(Page No1114 to1126)
SRNMC Regulation-2016 Syllabus
Reference Books
Reference Book-1
Title of the book : Inorganic Chemistry.
Name of the Author : James E. Huheey , Ellen A. Keitler and Richard L. Keitler,
Publisher : Harper Collins College Publishers
Edition/Year : 4 /2006
Reference Book-2
Title of the book : An Introduction to Inorganic Chemistry
Name of the Author : K.F.Purcell and J.C Koltz
Publisher : W.B. Saunders Company, Philadelphia,
Edition/Year : 1 /1980
Reference Book-3
Title of the book : Introduction to solids
Name of the Author : L.V.Azaroff
Publisher : Tata Mc Graw Hill Publishing House
Edition/Year : 1/2007
Prepared by :
Signature :
SRNMC Regulation-2016 Syllabus
SRI S.RAMASAMY NAIDU MEMORIAL COLLEGE
(An Autonomous Institution Re-accredited with ‗A‘ Grade by NAAC)
SATTUR-626 203.
Department of Chemistry
(For those who joining in 2016-2017 and after)
SYLLABUS
Programme : M.Sc .Chemistry Subject Code : P16CHC13
Semester : I No. of Hours allotted : 6 / week
Subject : Core - Paper III No. of Credits : 4
Title of the Paper : PHYSICAL CHEMISTRY – I
THERMODYNAMICS AND ELECTROCHEMISTRY
Objectives
To enable the students
To understand the importance and significance of thermodynamics and the principle
of chemical equilibrium.
To acquire an insight into phase rule.
To understand the principles of quantum chemistry.
To know about the importance and significance of electrochemistry and its
applications.
UNIT-I Chemical Thermodynamics
Second law of thermodynamics, concept of entropy. Gibbs-Helmholtz equation,
Maxwell relations and thermodynamic equation of state. Partial molar quantities - Chemical
potential, its variation with temperature and pressure, Gibbs Duhem equation. Experimental
determinations of fugacity of real gases (Graphical, from state equation, approximate and
generalized methods).Third law of thermodynamics – Nernst theorem, absolute entropies,
determinations of absolute entropies, exception to third law and unattainability of absolute
zero.
UNIT-II Chemical and Phase Equilibria
Spontaneous reactions, free energy of a spontaneous reaction, role of temperature,
standard free energy change of a reaction. Thermodynamic derivation for the law of
chemical equilibrium, Van‘t Hoff‘s reaction isotherm. Temperature dependence of
equilibrium constant, Integrated form of the Van‘t Hoff equation. Relation between Kp and
Kc. De Donder‘s concept of degree of advancement of a reaction.
SRNMC Regulation-2016 Syllabus
Gibbs phase rule - its thermodynamic derivation. Application of phase rule to
three component systems - systems composed of two solids and a liquid ( crystallization of
pure components only, hydrate and double salt formation ). Formation of one pair, two pairs
and three pairs of partially miscible liquids.
UNIT – III Basic Principles of Quantum Mechanics
Planck‘s explanation about black- body radiation, de-Broglie‘s concept of matter
waves ( Experimental technique and verification), Compton effect, Heisenberg‘s uncertainty
principle, Postulates of quantum mechanics, Operators (addition, subtraction, multiplication,
commutator, Hermitian, Hamiltonian and linear operators), Rules for setting up the following
quantum mechanical operators - position, momentum, kinetic energy, potential energy, total
energy, angular momentum, raising and lowering of spin angular momentum. Orthogonality
and normalization of wave functions.
Problems on evaluation of commutators and find expressions of some
operators. Simple problems based on to find out the eigen values and eigen functions.
UNIT-IV Electrochemistry - I
Theory of electrolytic conductance – inter ionic attraction , ionic atmosphere ,
thickness of ionic atmosphere. Debye Huckel - Onsager conductance equation – its derivation
and experimental verification, deviations and modifications-Debye Falkenhagen and Wein
effects. Mean ionic activity and activity coefficients of strong electrolytes. Liquid junction
potential and membrane potential. Construction and working of metal-metal ion electrode,
hydrogen electrode, calomel electrode and oxidation-reduction electrode.
Types of cells - Electrochemical cells – primary cells, secondary cells and fuel cells.
Experimental determination of EMF of cells. Nernst equation. Applications of EMF
measurements- determination of equilibrium constant, pH and solubility product.
UNIT-V Electrochemistry - II
The electrical double layer and zeta potential. Perrin, Gouy-Chapmen and Stern
models. Butler-Volmer equation - Tafel equation. Over voltage, Hydrogen over voltage.
current-potential curves.
Potentiometric titrations – principles and types (acid- base, redox and precipitation).
Conductometric titrations – principles and types ( acid – base and precipitation )
SRNMC Regulation-2016 Syllabus
Text books
Text book-1
Title of the book : Principles of Physical chemistry
Name of the Author : B.R.Puri, L.R.Sharma,M.S.Pathania
Publication : Vishal publishing Co,New Delhi.
Edition/ year : 45 /2012
Text Book- 2
Title of the book : Advanced Physical chemistry
Name of the Author : Gurdeep Raj
Publisher : Goel Publishing Co.Meerut.
Edition/Year : 30 /2004
Text Book- 3
Title of the book : Quantum chemistry
Name of the Author : R.K Prasad
Publisher : New Age International publishers
Edition/Year : 3 /2008
Text Book- 4
Title of the book : An Introduction to Electrochemistry
Name of the Author : S.Glasstone
Publisher : East West Press (P) Ltd.
Edition/Year : 10 /1942
Unit-I (From Text Book-1)
Chapter – 14 (Page No.517-541,546-549)
Unit-II (From Text Book-1)
Chapter – 16 (Page No.564-573,581-582)
(From Text Book-2)
Chapter – 18 (Page No.1050-1052, 1054-1056, 1079-1083, 1085-1088)
Unit- III (From Text Book-1)
Chapter -1(Page No.23-25, 32-39, 43, 44)
(From Text Book-3)
Chapter -2(Page No.32, 33)
Chapter -3(Page No. 34-55)
Unit-IV (From Text Book-1)
Chapter – 22 (Page No.770-829,845-850,867-887)
(From Text Book-4)
Chapter – 3 (Page No.79-105)
Unit-V (From Text Book-1) Chapter – 24 (Page No.845-851,867-873)
SRNMC Regulation-2016 Syllabus
Reference Books
Reference Book-1
Title of the book : Thermodynamics for chemists
Name of the Author : S.Glasstone
Publisher : East West Press (P) Ltd,New Delhi.
Edition/Year : 3 /1947
Reference Book-2
Title of the book : Thermodynamics
Name of the Author : J.Rajaram and J.C. Kuriakose
Publisher : Shoban Lal Nagin, Chand & Co, New Delhi.
Edition/Year : 3 /1999
Reference Book-3
Title of the book : Advanced Physical chemistry
Name of the Author : D.N. Bajpai
Publisher : S.Chand &Company Ltd, New Delhi.
Edition/Year : 1 /1992
Reference Book-4
Title of the book : Electrochemistry
Name of the Author : B.K. Sharma
Publisher : Goel Publishing House,Meerut.
Edition/Year : 5 /1998
Prepared by :
Signature :
SRNMC Regulation-2016 Syllabus
SRI S.RAMASAMY NAIDU MEMORIAL COLLEGE
(An Autonomous Institution Re-accredited with ‗A‘ Grade by NAAC)
SATTUR-626 203.
Department of Chemistry
(For those who joining in 2016-2017 and after)
SYLLABUS
Programme : M.Sc., Chemistry Subject Code : P16CHE11
Semester : I No. of Hours allotted : 6 / week
Subject : Paper IV Major Elective I- (a) No. of Credits : 4
Title of the Paper : ENVIRONMENTAL CHEMISTRY
Objectives:
To learn about pollutions and its types.
To know the sources and control measures of various pollution.
UNIT: I Introduction and Classification of Pollution
Introduction, definitions – Environment, Environmental Science,Environmental
education. Types of environment and its components. Definitions-Ecology,Ecosystem.Types
and components of Ecosystem.Cycling of minerals, elements and gases –Phosphate
cycle,Carbon cycle, Nitrogen Cycle, Hydrological cycle. Pollution and its types: Air
pollution, water pollution, soil pollution, radioactive pollution, thermal pollution, noise
pollution, marine pollution. Discuss its sources, effects and control measures.
UNIT: II Analysis of Pollutant
Neutron Activation Analysis-Anodic Stripping Voltametry-Atomic Absorption
Spectrophotometry-X-Ray Florescence-non-dispersive Infrared spectrometry-Fourier
transform Infrared spectroscopy- chemiluminescence-gas chromatography-High performance
Liquid chromatography-Ion selective Electrode.
SRNMC Regulation-2016 Syllabus
UNIT: III Air Pollution
Introduction – sources of air pollution – air pollutants – classification and effects of
air pollutants – oxides of nitrogen,sulphur and carbon- acid rain-effects and control-hydrogen
sulphide – effects and control- carbon mono oxide – effects and control- photochemical smog
– effects and control – fly ash – effects and control – green house effect – global warming –
effects and control – ozone layer – ozone depletion – cholorofluoro carbons – effects and
control.
UNIT : IV Soil Pollution
Introduction, types of soil on the basis of its texture, sources of soil pollution-
fertilizers and pesticides, radioactive pollutants, soil sediments as pollutant. Soil erosion –
types,harmful effects,causes and its control measures. Solid waste management-types,
sources and effect of improper solid wastes. Process of solid waste management, disposal
methods- sanitary land filling , incineration and composting methods. Control measures of
soil pollution.
UNIT : V Industrial Pollution & Chemical Toxicology
Introduction-causes of industrial pollution–thermal power plants-nuclear power
reactors-fertilizers and chemical industry-pulp and paper industries – agro based industries-
cement industry.
Toxic chemicals in the environment – biochemical effects of arsenic, cadmium,
lead, mercury and cyanide- bio-ware agents.
Text books
Text Book- 1
Title of the book : Environmental Chemistry,
Name of the Author : A.K De,
Publisher : Wiley Eastern Ltd, Meerut.
Edition/Year : 6 /1994
Text Book- 2
Title of the book : Environmental chemistry
Name of the Author : B.K.Sharma
Publisher : Goel Publishing House
Edition/Year : 11 /2007
SRNMC Regulation-2016 Syllabus
Unit-I (From Text Book-1)
Chapter 1(Page No 1 to 15)
Unit II (From Text book -1)
Chapter 11(Page No 268 to 289)
Unit III (From Text book -2) Chapter 4 &5 (Page No 69-129)
Unit- IV (From Text Book-2)
Chapter -1(Page No. 33-34)
Chapter -2(Page No 47-55,62-64)
Chapter-3(Page No 75-80)
Unit V (From text book -1) Chapter 6(Page No 84 to 91,97 to 103)
Reference Books
Reference Book-1
Title of the book : Environmental Chemistry,
Name of the Author : B.K Sharma and H.Kaur,
Publisher : Krishna Prakashan, Meerut
Edition/Year : 1/1997
Prepared by :
Signature :
SRNMC Regulation-2016 Syllabus
SRI S.RAMASAMY NAIDU MEMORIAL COLLEGE
(An Autonomous Institution Re-accredited with ‗A‘ Grade by NAAC)
SATTUR-626 203.
Department of Chemistry
(For those who joining in 2016-2017 and after )
SYLLABUS
Programme : M.Sc ., Chemistry Subject Code : P16CHE12
Semester : I No. of Hours allotted: 6 / week
Subject : Paper V- Major Elective – I (b) No. of Credits : 4
Title of the Paper : BIOCHEMISTRY
Objectives:
To enable the students
To understand the biological role of enzymes in living organisms
To get a knowledge about the metabolism and genetic information.
Unit-I Enzymes
Classifications, nomenclature,properties of enzymes, some features of active sites of
enzymes, enzyme kinetics-Michaelis-Menton model-significance of Km and VMax Values,
Enzyme inhibition-competitive and non-competitive.Allosteric interaction-Mechanism of
enzyme action .Lysozyme and carboxypeptidase.
Unit-II Generation and storage of Metabolic energy
Metabolism-basic concepts and design: glycolysis-citric acid cycle-oxidative
phosphorylation-pentose pathway and gluoneogenesis.
Glycogen and disaccharide metabolism, fatty acid metabolism –amino acid degradation
and urea cycle-photosynthesis.
Unit-III Information. Storage, transmission, expression of genetic information
DNA-Genetic role structure and replication: messenger RNA and transcription
genetic code and gene protein relationship-protein synthesis, control of gene expression -
Eukaryotic chromosomes, Recombinant DNA technology and viruses.
SRNMC Regulation-2016 Syllabus
Unit-IV Bio-inorganic chemistry
Metalloproteins and enzymes-Blue copper proteins-copper proteins as
oxidases/reductases-Nickel containing enzymes-structure of DNA-types of nucleic acid
interactions-coordination, intercalation and hydrogen bonding-interactions of metal ions with
nucleic acid-redox chemistry. Hydrolytic chemistry-monitoring the DNA binding by UV, IR,
NMR and CV spectral techniques.
Unit-V Biophysical aspects
Electron transport and oxidative phosphorylation - Thermodynamic and kinetic
aspects -Photosynthesis - An overview - Photo system II-The light harvesting
chlorophyll - protein complexes of photo system II-Role of carotenoids in photosynthesis-
The primary electron donor of photo system II, P680 - The stable primary electron
acceptor QA and the secondary electron acceptor QB –The transient intermediate electron
acceptor of photo system II,pheophytin - Oxygen evolution-The role of manganese - The
electron donor to P680+ - Charge recombination in photo system II-Photo system I-Light-
harvesting chlorophyll - protein complexes of photo system I - The primary electron donor
of photo system I ,P700- The primary electron acceptor Ao of photo system I- The
intermediate electron acceptor A1 of photo system I- Mobile electron carriers plastocynanin
and ferredoxin NADP+ - reductase.
Text books
Text Book- 1
Title of the book : Fundamentals of Biochemistry
Name of the Author : J.L Jain
Publisher : S.Chand & company Limited
Edition/Year : 5/2001
Text Book- 2
Title of the book : Bioinorganic Chemistry
Name of the Author : I.Bertini, H.B.Gray S.J.Leppard and J.S Valentine
Publisher : Viva Books Pvt Ltd..
Edition/Year : 1 /2007
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Text Book- 3
Title of the book : Biochemistry
Name of the Author : A.L.Lehninger,
Publisher : CBS publishers
Edition/Year : 1/1990
Text Book -4 Title of the book : An Introduction to Inorganic Chemistry
Name of the Author : K.F. Purcell and J.C. Koltz,
Publisher : W.B. Saunders Company, Philadelpha 1980
Edition/Year : 1/1980
Unit-I (From Text Book-1)
Chapter 16 (Page No. 277-286,309-331)
Unit-II (From Text Book-1)
Chapter 21(Page No 367-412,420-422)
Unit-III (From Text Book-3 )
Chapter 4 (Page No 791-913)
Unit IV (From Text Book -2)
Chapter 6 (page No 315-346)
Unit-V Study materials will be provided
Reference Books
Reference Book-1
Title of the book : Biochemistry
Name of the Author : B.D.Hames and N.M.Hooper
Publisher : Viva Books Ltd
Edition/Year : 1/2003
Reference Book-2
Title of the book :.Bioinorganic Chemistry,
Name of the Author : G.R. Chatwal and A.K.Bhagi
Publisher : Himalaya Publishing House
Edition/Year :
Reference Book-3
Title of the book : Biochemistry,
Name of the Author : J.M. Berg, J.L.Tymoczko and L.Stryer,
Publisher : W.H.Freeman and company, New York
Edition/Year : 5/2002
Prepared by :
Signature :
SRNMC Regulation-2016 Syllabus
SRI S.RAMASAMY NAIDU MEMORIAL COLLEGE
(An Autonomous Institution Re-accredited with ‗A‘ Grade by NAAC)
SATTUR-626 203.
Department of Chemistry
(For those who joining in 2016-2017 and after)
SYLLABUS
Programme : M.Sc ., Chemistry Subject Code : P16CHC1P1
Semester : I No. of Hours allotted: 6 / week
Subject : Paper V Practical - I No. of Credits : 4
Title of the Paper : Inorganic Chemistry Practical
Objectives
To enable the learners
To understand the principle for the estimation of binary mixture.
To apply the principle in the semi-micro analysis of an inorganic salt mixture.
To prepare the inorganic complexes
1. Semi-micro qualitative analysis: Analysis of mixtures containing one familiar and
one less familiar cations from the following W, Pb, Se, Mo, Cu, Cd, V, Mn, Ni, Co,
Zn, Ca, Ba, Sr, Li, Mg (insoluble and interfering an ion may be avoided).
2. Inorganic preparations: preparation of at least 5 inorganic complexes.
3. Quantitative analysis: separation and estimation of mixtures by volumetric and
gravimetric methods: some recommended mixtures are
i) Cu and Ni
ii) Fe and Ni
iii) Ca and Ba
iv) Cu and Zn
v) Fe and Cu
References
Reference Book-1
Title of the book : Vogel’s Text Book of Quantitative Chemical Analysis
Name of the Author : J. Bassett et al
Publisher : ELBS, Longmann, U.K
Edition/Year : 5 / 1989
SRNMC Regulation-2016 Syllabus
Reference Book-2
Title of the book : Inorganic Semi micro Qualitative Analysis
Name of the Author : V.V. Ramanujam
Publisher : The National Publishing Co, Chennai
Edition/Year : 3/2008
Prepared by :
Signature :
SRNMC Regulation-2016 Syllabus
SRI S.RAMASAMY NAIDU MEMORIAL COLLEGE (An Autonomous Institution Re-accredited with ‗A‘ Grade by NAAC)
SATTUR-626 203.
Department of Chemistry
(For those who joining in 2016-2017 and after)
Programme : M.Sc ., Chemistry Subject Code : P16CHC21
Semester : II No. of Hours alloted : 6 / week
Subject : Core Paper VI No of Credits : 5
Title of the Paper : ORGANIC CHEMISTRY – II
NATURAL PRODUCTS, CONFORMATIONAL ANALYSIS AND REACTION
MECHANISM – II
Objectives
To enable the learners
To know the concept of aliphatic nucleophilic and electrophilic substitution and
elimination.
To learn the concept of addition to multiple bonds.
To understand the principle of UV, IR and Mass spectroscopy and their application in
organic chemistry.
To know about the chemistry of carbohydrates and terpenoids.
To understand the concept of conformational analysis.
Unit I Aliphatic Nucleophilic Substitution
Nucleophilicity and basicity – SN1and SN2 mechanisms – Effect of substrate structure
- Effect of the attacking nucleophile – Effect of the leaving group – Effect of the reaction
medium – ambident nucleophiles – ambident substrates – neighbouring group participation
by n, π and σ bonds – SNi mechanism –– nucleophilic substitution at an allylic and a vinylic
carbon.
Aliphatic electrophilic substitution: Electrophilic substitution at saturated carbon –
SE1,SE2 and SEi mechanism.
Elimination: Elimination - E1, E2 and E1CB mechanism – stereochemistry of Elimination
– orientation of the double bond– Effect of changes in the substrates base, leaving group and
medium on E1, E2, and E1CB reactions – elimination Vs substitution – pyrolytic cis
eliminations – Bredts rule .
SRNMC Regulation-2016 Syllabus
Unit II Addition to multiple bonds
Electrophilic, nucleophilic and free radical additions - addition to conjugated systems
– orientation of the addendum - stereochemical factors in reactions like addition of hydrogen,
halogens, hydrogen halides and hypohalous acids, hydroboration and hydroxylation -
epoxidation.
Addition to carbonyl groups – mechanism - Aldol condensation – Perkin reaction -
Knoevenagel reaction - Mannich reaction - Cannizaro reaction – Benzoin condensation -
Claisen ester condensation –Darzen‘s reaction - Reformatsky reaction - Wittig reaction –
Grignard reactions.
Addition to α,β -Unsaturated carbonyl groups : Addition of Grignard reagents to
α,β-unsaturated carbonyl compounds – Michael addition – Diels-Alder reaction .
Unit III Spectroscopy I
UV Spectroscopy: Principle - absorption spectra of conjugated dienes – α,β -
unsaturated carbonyl compounds – Woodward- Fieser rules - Scott‘s rules for aromatic
carbonyls.
IR Spectroscopy: Molecular vibrations – vibrational frequency - factors influencing
group frequencies – quantitative studies.
Mass Spectrometry: Principle – type of ions – base peak – parent ion, meta stable
and isotopic peaks – nitrogen rule – fragmentation - general rules - pattern of fragmentation
for compounds such as hydrocarbons, amines, alcohols, ketones, acids, phenols and nitro
compounds – McLafferty rearrangement – Retro Diels-Alder reaction.
UNIT IV Carbohydrates, Amino Acids, Proteins and terpenoids:
Carbohydrates: Methods used for determination of ring size – structure
elucidation of maltose, lactose and cellobiose - a brief study of starch and cellulose (structure
only).
Amino acids and Proteins: Amino acids - Peptides - Classification of proteins –
denaturation – structure of (primary, secondary, tertiary and quaternary) peptides - structural
elucidation of glutathione and oxytocin
Terpenoids: Classification of terpenoids – structural elucidation of α-pinene,
zingiberene and squalene.
SRNMC Regulation-2016 Syllabus
Unit V Conformational analysis
Configuration and Conformation – Conformation of ethane, 1,2-dicholoro ethane and
n- butane - conformational analysis – stereoelectronic and steric factors - conformation of
simple acyclic compounds -conformation of monosubtituted and disubstituted cyclohexanes –
conformation of acyclic and cyclic systems with their physical and chemical properties –
conformational free energy – Curtin- Hammett principle - Quantitative treatment of Mobile
system - Eliel-Ro equation – conformations and reactivity of cyclohexanones.
Text books
Text book-1
Title of the book : Reaction mechanism and reagents in organic chemistry
Names of the Author : G.R. Chatwal
Publisher : Himalaya publishing house,
Edition/Year : 5/2012
Text book-2
Title of the book : Organic reaction mechanism
Name of the Author : V.K Ahluwalia
Publisher : Narosa publishing House New Delhi
Edition/Year : 3 /2007
Text Book- 3
Title of the book : Reactions, Rearrangements and Reagents
Name of the Author : Somorendra Nath Sanyal
Publisher : Bharati Bhawan Publishers
Edition/Year : 4 / 2003
Text Book- 4
Title of the book : Elementary organic spectroscopy principles and chemical
applications
Name of the Author : Y.R.Sharma
Publisher : S.Chand and company Ltd, New Delhi
Edition/Year : Reprint /2012
Text book-5
Title of the book : Stereochemistry conformation and Mechanism
Name of the Author : P.S.Kalsi
Publisher : New age international publishers
Edition/Year : 1/1990
SRNMC Regulation-2016 Syllabus
Text book-6
Title of the book : Organic chemistry of natural products
Names of the Author : G.R. Chatwal
Publisher : Himalaya publishing house,
Edition/Year : 4/2007
Unit-I (From Text Book-2)
Chapter-1(page No 12-33, 50-59)
Unit-II (From Text Book-1)
Chapter -7 (Page No 7.1-7.61)
(From Text Book-3)
Chapter -2 (Page No 77-83, 97-107, 117-121,141-146,148-152,154-158,161-164,182-
185)
Unit-III (From Text Book-4)
Chapter-2 (Page No.9-12, 15-33, 34-42, 44-54)
Chapter-3 (Page No.69-82, 89-140)
Chapter-7 (Page No.280-328)
Unit-IV (From Text Book-6)
Chapter-1 (Page No.1.46-53, 1.115-123, 1.132-144)
Chapter-2 (Page No.2.62-93, 2.98-101)
Unit-V (From Text Book-5)
Chapter-4 (Page No.217-252)
Reference Books
Reference Book-1
Title of the book : Stereochemistry of Organic Compounds, Principles and
Applications
Name of the Author : D.Nasipuri,
Publisher : New Age International (P) Ltd.,
Edition/Year : 2 / 1994.
SRNMC Regulation-2016 Syllabus
Reference Book-2
Title of the book : Mechanism and Structure in Organic Chemistry,
Name of the Author : E.S. Gould,
Publisher : Henry Holt& Co.,New York ,
Edition/Year : 1 / 1959
Reference Book-3
Title of the book : Organic Spectroscopy,
Name of the Author : William Kemp,
Publisher : ELBS,
Edition/Year : 3 / 1991
Reference Book-4
Title of the book : Spectrometric Identification of Organic Compounds,
Name of the Author : Robert M.Silverstein, Francis X. Webster,
Publisher : John Wiley and Sons Inc.,
Edition/Year : 6 / 2010.
Reference Book-5
Title of the book : Spectroscopy of Organic Compounds,
Name of the Author : P.S.Kalsi,
Publisher : New Age International Publishers,
Edition/Year : 6 / 2009.
Reference Book-6
Title of the book : Advanced Organic Chemistry,
Name of the Author : Jerry March,
Publisher : John Wiley and Sons,
Edition/Year : 4 / 2004.
Reference Book-7
Title of the book : Stereo chemistry of carbon compounds,
Name of the Author : E.l.Eliel
Publisher : Mc Graw Hill
Edition/Year : Reprint 2008 /1975
Prepared by :
Signature :
SRNMC Regulation-2016 Syllabus
SRI S.RAMASAMY NAIDU MEMORIAL COLLEGE (An Autonomous Institution Re-accredited with ‗A‘ Grade by NAAC)
SATTUR-626 203.
Department of Chemistry
(For those who joining in 2016-2017 and after)
SYLLABUS
Programme : M.Sc., Chemistry Subject Code : P16CHC22
Semester : II No. of Hours allotted : 6 / week
Subject : Core Paper VII No. of Credits : 4
Title of the Paper : INORGANIC CHEMISTRY – II
BIOINORGANIC AND SOILD STATE CHEMISTRY- II
Objectives
To have an insight into study of coordination compounds and their reactions
To have an understanding of role of inorganic metal complexes in living systems
Unit I: Co-ordination Chemistry II
Theories of bonding - Werner theory –VB theory and CFT theory – splitting of d-
orbitals in Oh, Td, square planar and tetragonal distortion –Jahn-Teller distortions – CFSE
calculation in terms of Dq – factors affecting crystal field splitting – spectrochemical series –
applications of CFSE – MOT diagram of octahedral, Td and square planar complexes – effect
of π-donor and π-acceptor ligands – magnetic properties of transition metal complexes –
calculation of spin-only magnetic moments –orbital contribution to the magnetic moment –
spin orbit coupling.
Unit – II Bio – Inorganic Chemistry – I
Porphyrin ring system – metalloporphyrins – hemogolobin and myoglobin structures and
work functions – synthetic oxygen carries – cytochromes and its types – structure and work
functions in respiration – chlorophyll – structure – photosynthetic sequence – iron sulphur
proteins [ non – heme iron protein] – copper containing proteins – classification – blue
copper proteins – structure of blue copper electron transferases, copper proteins as Oxidases .
Unit – III Bio – Inorganic Chemistry – II
: Structure and function of Carboxypeptidase A –carbonic anhydrase – Inhibition and
poisoning – Corin ring system – Vitamin B12 and B12 Coenzymes – in – vivo and in – vitro
nitrogen fixation – essential and trace elements in biological systems- metal ion toxicity. -
Sodium and potassium ions pumps – chelate therapy – cis platin
SRNMC Regulation-2016 Syllabus
Unit IV Acid – base systems and non aqueous solvents : Acid –base definition: Bronsted
– Lowry- Lux – flood- Solvent system – Lewis Usanovich – generalized acid – base concept
– steric effect on the strength of acids and bases – HSAB concept – Symbiosis.
Non Aqueous Solvents: Classification of solvents- A general study of typical reactions in
non aqueous media like liquid NH3, liquid HF, liquid N2O4 and liquid SO2 .
Unit V : Solid state chemistry II
Dislocation in solids- crystal defects-stoichiometric and non stoichiometric defects-
colour centers – Free electron and band theories – Types of solids – super conductivity –
High temperature super conductors – Types of semiconductors – Thermo electric power and
Hall effect - Photo voltaic effect – solar cell..
Text books
Text Book- 1
Title of the book : Principles of Inorganic Chemistry
Name of the Author : B.R.Puri and L.R.Sharma and K.C. Kalia
Publisher : Milestone Publishers, New Delhi
Edition/Year : 30/2008
Text Book- 2
Title of the book : Selected Topics in Inorganic Chemistry
Name of the Author : Wahid U.Malik et al
Publisher : S.Chand and Company Ltd.
Edition/Year : 7/2007
Text Book- 3
Title of the book : Concise Co-ordination Chemistry,
Name of the Author : R.Gopalan and V.Ramalingam,
Publisher : Vikas Publishing House PVT Ltd
Edition/Year : 1 /2009
Unit-I (From Text Book-1)
764 to 780, )
Unit II (From Text Book 2)
Chapter 15, 16 and 17(Page No 510 to 550)
Unit III and IV ( From Text Book 3)
Chapter 14(Page No 313 to 328)
Unit IV Chapter 7 (Page No 260 to 274)
Unit V (From Text Book I)
Chapter 6(Page No 253 to 256)
SRNMC Regulation-2016 Syllabus
Reference Books
Reference Book-1
Title of the book : An Introduction to Inorganic Chemistry
Name of the Author : K.F. Purcell and J.C. Koltz,
Publisher : W.B. Saunders Company, Philadelpha 1980
Edition/Year : 1 /1980
Reference Book-2
Title of the book : Inorganic Chemistry.
Name of the Author : James E. Huheey , Ellen A. Keitler and Richard L. Keitler,
Publisher : Harper Collins College Publishers
Edition/Year : 4/2006
Reference Book-3
Title of the book : Introduction to solids
Name of the Author : L.V.Azaroff
Publisher : Tata Mc Graw Hill Publishing House
Edition/Year : 1/2007
Prepared by :
Signature :
SRNMC Regulation-2016 Syllabus
SRI S.RAMASAMY NAIDU MEMORIAL COLLEGE
(An Autonomous Institution Re-accredited with ‗A‘ Grade by NAAC)
SATTUR-626 203.
Department of Chemistry
(For those who joining in 2016-2017 and after)
SYLLABUS
Programme : M.Sc. Chemistry Subject Code : P16CHC23
Semester : II No. of Hours allotted: 6 / week
Subject : Core Paper VIII No. of Credits : 5
Title of the Paper : PHYSICAL CHEMISTRY - II
QUANTUM, CATALYSIS AND MOLECULAR SPECTROSCOPY
Objectives:
To apply the principles of quantum chemistry to simple systems, atomic and
molecular systems and to obtain their energies.
To understand the theory and applications of catalysis.
To get an insight into the principles of molecular spectroscopy
UNIT: I Application of Quantum Mechanics to Simple Systems
Derivation of Schrodinger wave equation (SWE). Application of SWE to simple
systems - particle moving in one dimensional box, particle moving in a 3-D box- degeneracy
– distortion, particle moving in a ring, rigid rotator, simple harmonic oscillator. Radial
wave function and radial probability distribution function. Shapes of various atomic orbitals.
UNIT : II Approximation Methods in Quantum Mechanics
Need for approximation methods (variation and Perturbation methods). Perturbation
corrections-first order correction. Schrodinger equation for He atom. Variation theorem-
application to hydrogen and He atoms. Hartee - Fock Self Consistent Field (HFSCF) theory-
application to He atom, HFSCF method of many electron system. Electron spin and Pauli
principle, anti symmetric nature of the wave functions, Slater rules and Born-Oppenheimer
approximation.
UNIT-III Statistical Thermodynamics
Aims of statistical thermodynamics, definitions of state of a system, ensembles
(micro, macro and grand canonical). Derivation of Boltzmann distribution law, Boltzmann-
SRNMC Regulation-2016 Syllabus
Planck equation. Partition functions-thermodynamic properties from partition functions,
partition function and equilibrium constant. Quantum statistics –Fermi-Dirac and Bose-
Einstein statistics. Population inversion. Einstein‘s and Debye‘s theories of heat capacities of
solids. Nuclear spin statistics- ortho- and para- nuclear states-calculation of residual entropy
of H2 at 0 K in terms of ortho- and para- ratio.
UNIT:IV Catalysis
Catalysis - Types, characteristics and theory of catalysis. Heterogeneous catalysis-
kinetics, retardation and effect of temperature. Classification of catalysis. Enzyme catalysis –
characteristics, factors governing the rate of enzyme reaction. Mechanism of enzyme
catalysis (Michaelis Menten equation), Line weaver and Burk plot and Eadie‘s plot
Acid–Base catalysis –Mechanism and its kinetics. Hammett and Bronsted equation,
Acidity function. Langmuir – Heinshelwood and Langmuir – Rideal- mechanism. ARRT of
surface reactions – NH3 synthesis, cracking of hydrocarbons.
UNIT-V Molecular Spectroscopy-I
Electromagnetic spectrum. Types of molecular energies. Absorption and emission of
radiation. Einstein‘s coefficient-induced emission and absorption. Rotational spectra of rigid
diatomic molecules-isotope effect in rotational spectra. Microwave spectrometer.
Informations derived from rotational spectra.
Infrared spectroscopy. Vibrational energy of diatomic molecule-infrared selection
rules-diatomic vibrating rotator. Vibrations of polyatomic molecules - overtone, combination
and hot bands. Concept of group frequencies - coupling interaction. Fermi resonance-
Fourier transform infrared spectroscopy.
Text books
Text Book- 1
Title of the book : Introductory Quantum chemistry
Name of the Author : A.K.Chandra
Publisher : Tata McGraw –Hill Publishing Company Limited,New Delhi.
Edition/Year : 4 /2002
Text book-2
Title of the book : Principles of Physical chemistry
Name of the Author : B.R.Puri, L.R.Sharma,M.S.Pathania
Publication : Vishal publishing Co,New Delhi.
Edition/ year : 45 /2012
SRNMC Regulation-2016 Syllabus
Text Book- 3
Title of the book : Advanced Physical chemistry
Name of the Author : Gurdeep Raj
Publisher : Goel Publishing Co,Meerut.
Edition/Year : 30 /2004
Text Book- 4
Title of the book : Fundamentals of molecular spectroscopy
Name of the Author : Colin N. Banwell and Elaine M.McCash
Publisher : Tata McGraw- Hill Publishing Company Limited
Edition/Year : 4/2003
Unit- I & II (From Text Book-1)
Chapter -3(Page No.39-55)
Chapter -4(Page No.82-101)
Chapter -5(Page No.109-120)
Chapter -6(Page No.142-148)
Chapter -7(Page No.183-209)
Unit-III (From Text Book-2) Chapter – 25 (Page No.892-910,919-923)
Unit -IV (From text book 3)
Chapter-15(Page No.841-872)
Unit- V (From Text book-4) Chapter-2&3(Page No. 31-98)
Chapter-4(Page No. 100-126)
Reference Books
Reference Book-1
Title of the book : Quantum chemistry
Name of the Author : R.K.Prasad
Publisher : New Age International Publishers, New Delhi
Edition/Year : 3 /2006
Reference Book-2
Title of the book : Molecular structure and spectroscopy
Name of the Author : G.Aruldhas
Publisher : PHI Learning (P) Limited, New Delhi
Edition/Year : 2 /2009
Prepared by :
Signature :
SRNMC Regulation-2016 Syllabus
SRI S.RAMASAMY NAIDU MEMORIAL COLLEGE (An Autonomous Institution Re-accredited with ‗A‘ Grade by NAAC)
SATTUR-626 203.
Department of Chemistry
(For those who joining in 2016-2017 and after)
SYLLABUS
Programme : M.Sc ., Chemistry Subject Code : P16CHE21
Semester : II No. of Hours allotted: 6/ week
Subject : Paper IX Major Elective –II (a) No. of Credits : 4
Title of the Paper : ANALYTICAL CHEMISTRY
Objectives:
To enable the students
To learn the principle of electro analytical methods & spectroanalytical methods.
To gain knowledge on the basic concepts of error analysis
Unit-I: Precipitation Techniques
Introduction-properties of precipitates and precipitating reagents –colloidal
precipitates, Co-precipitation-post precipitation –precipitates from homogeneous solution –
surface adsorption –drying and ignition of precipitates –application of gravimetric methods
Unit-II: Error Analysis
Error analysis: Classification of errors-accuracy and precision-minimization of errors-
significant figures-significant figures in computation-statistical treatment of data: mean,
median, standard deviations, variance, relative standard deviation –spread, errors-standard
deviation of computed results-Student‘s t-test-F-test-comparison of the means of two
samples-correlation and regression: linear regression (least square analysis).
Unit-III Electro analytical methods
Electro analytical techniques: Electrogravimetry, theory of eletrogravimetric analysis-
electrolytic separation and determination of metal ions.Coulometry: Electrolytic cell-working
electrodes-auxiliary electrode and reference electrode- coulometric titrations Voltammetry:
Cyclic Voltammetry - stripping, voltammetry - chronopoteniometry. Amperometry:
Amperometric titrations.
SRNMC Regulation-2016 Syllabus
Unit-IV: Thermoanalytical Methods
Thermal analysis, theory and principles of DTA and TGA- factors affecting the
position of DT and TG traces-application of DTA and TGA to the thermal behavior of the
following compounds-crystalline coppersulphate, calcium oxalate monohydrate, calcium
acetate monohydrate, zinc hexafluosilicate-complementary nature of DTA and TGA-
principle and application of DSC-determination of degree of conversion of high alumina
cement-purity determination-phase transition study –in forensic laboratory.
Unit-V: Spectroanalytical Methods
Colorimetry: Beer and Lambert‘s law-terminology-condition for a satisfactory
colorimetric analysis-method of colour measurement or comparison-principles of
colorimetric determinations of NH3, Cr, Cu, Fe, Mn-simultaneous spectrophotometer
determination of Cr and Mn.
Nephelometry and turbidimetry:principle-determination of sulphate and phosphate-
fluorimetry:principle-application of fluorimetry in the determination of Cd,Ca,and Zn and
determination of codeine and morphine in a mixture-flame spectrometry: theory-
interferences-AAS-applications in the determination of Mg+2
and Ca+2
in tap water ,V in
lubricating oil, trace lead in a ferrous alloy and trace elements in contaminated soil.
Text books
Text Book- 1
Title of the book : Elements of analytical chemistry
Name of the Author : R.Gopalan
Publisher : Sultan Chand & sons
Edition/Year : 3/2003
Text Book- 2
Title of the book : Instrumental method of chemical analysis
Name of the Author : Gurdeep chatwal
Publisher : Himalaya publishing House
Edition/Year : 5/2012
Unit-I (From Text Book-1)
Chapter 9(Page No 121 to134)
Unit-II (From Text Book-1)
Chapter 4(Page No 28 to 37)
Unit-III (From Text Book-1)
Chapter 10(Page No 139 to 145,148 to 150)
(From Text Book-2)
SRNMC Regulation-2016 Syllabus
Chapter 28(Page No 2.541 to 2.545)
Unit-IV (From Text Book-2)
Chapter 41(Page No 2.701 to 2.759)
Unit-V (From Text Book-2)
Chapter 5(Page No 2.107 to 2.112)
Chapter 13 to 16(Page No 2.389 to 2.398 , 2.349 to 2.416, 2.367)
Reference Books
Reference Book-1,
Title of the book : Fundamentals of Analytical Chemistry,
Name of the Author : D.A.Skoog, D.M.West and F.J.Hollar
Publisher : Harcourt College Publishers,1
Edition/Year : 7/1996
Reference Book-2
Title of the book : Instrumental Methods of Analysis
Name of the Author : H.H.Williard,L.L.Merritt and J.A.Dean
Publisher : East-West press New Delhi
Edition/Year : 1/1988
Prepared by :
Signature :
SRNMC Regulation-2016 Syllabus
SRI S.RAMASAMY NAIDU MEMORIAL COLLEGE (An Autonomous Institution Re-accredited with ‗A‘ Grade by NAAC)
SATTUR-626 203.
Department of Chemistry
(For those who joining in 2016 -2017 and after)
SYLLABUS
Programme : M.Sc ., Chemistry Subject Code : P16CHE22
Semester : II No. of Hours allotted: 6 / week
Subject : Paper IX-Major Elective –II (b) No. of Credits : 4
Title of the Paper : INDUSTRIAL CHEMISTRY
Objectives:
To enable the students
To understand the principle and importance of chemical technology
To utilize the raw materials in chemical industry
To get the awareness about the pollution and its control
Unit-I: Principles and Importance of chemical process industry
Introduction – importance of chemical industry – new developments in chemical
technology – classification of technologies processes – unit process and unit operation –
batch and continuous process – Indian chemical industry today – basic principles of
homogeneous and heterogeneous processes.
Unit-II: Raw Materials and Energy for Chemical Industry
Raw materials-Characteristics of raw materials and their resources- methods of raw
material concentration –integral utilization of raw materials
Energy for chemical industry-power and fuels-classification of fuels-coal-fuel gases
and liquid fuels-petroleum-cracking-chemical corrosion-types of corrosion and preventive
measures
Unit-III: Water Pollution and Its Control
Introduction – types of water –soft and hard water-softening of water– water
pollution – sources of water pollution – water pollutants – classification – physical, chemical
and biological – inorganic pollutants and toxic metals – organic pollutants – -pesticides and
fertilizers – suspended particles – water quality – ill effects of water pollutants – water
SRNMC Regulation-2016 Syllabus
pollution control – water treatment – primary, secondary and tertiary treatment – desalination
– reverse osmosis – sewage and industrial waste water treatment.
Unit-IV: Small Scale Chemical Industries
Electro-thermal and electro-chemical industries:
Electric furnace - classification - manufacture of calcium carbide - Electrolytic
manufacturing and refining of aluminium - process and theory of electroplating.
oils, fats and waxes:
Manufacturing of soyabean oil-Analysis of oils,fats and waxes- manufacture of soap
by batch process - detergent (cationic ,anionic and non-ionic) –preparation, properties and
uses of potassium chlorate . .
Unit-V: Large Scale Chemical Industries
Manufacturing process - raw materials - composition and uses of products in Portland
cement – ceramics - plastics(Polyethylene, PVC) -- synthetic fibres (Nylon66, Nylon 6,
Terylene) - natural Rubber- Refining of crude rubber - Vulcanization of rubber and Synthetic
rubbers (BunaS, Neoprene) - fertilizers(Nitrogen and phosphate) Organic insecticides
(DDT,BHC)
Text Book- 1
Title of the book : ChemicalTechnology,Vol.1.
Name of the Author: 1.Mukhlyonov(ed.),
Publisher : Mir publication, Moscow
Edition/Year : 3/1979
Text Book- 2
Title of the book : Enviromental Chemistry
Name of the Author : A.K.De
Publisher : New age International (P) Limited
Edition/Year : 6/2006
Text book-3
Title of the book : Industrial chemistry
Name of the Author : B.K Sharma -
Publisher : Goel publishing house.
Edition/Year : 13 /2008
Text book-4
Title of the book : Outlines of Chemical Technology
Name of the Author : M.Gopala Rao Drydens
Publisher : East-West Press
Edition/Year : 3/2001
SRNMC Regulation-2016 Syllabus
Text Book- 5
Title of the book : Polymer Science
Name of the Author : V.R.Gowarikar, N.V.Viswanathan and Jayadev Sreedher, ―
Publisher : Wiley Eastern Ltd., New Delhi
Edition/Year : 4 /1986
Unit-I (From Text Book-1)
Chapter 2( Page No 20-25,68-89)
Chapter 3( Page No90-118)
Chapter 4( Page No 136-158)
Chapter 5( Page No159-230)
(From textbook -4)
Chapter 1(Page No.)
Unit-II(From Text Book-1)
Chapter 7(page no.287-307,316-320)
(From Text Book-2)
Chapter 12(page no292-295)
Unit-III (From Text Book-2) Chapter -9 &10 (Page No. 170-267)
Unit-IV (From Text Book-3) Chapter -40 (Page No. 1153-1155, 1169-1171, 1176-1178, 1184-1186, 1296-1298,
1305-1306)
Chapter-48 (Page No.1340-1343)
Unit-V (From Text Book- 5)
Chapter 9 (Page No 215 to 220
Reference Books
Reference Book-1
Title of the book : Industrial chemistry
Name of the Author : B.K Sharma
Publisher : Goel publishing house.
Edition/Year : 1/
Reference Book-2
Title of the book : Chemical process industries
Name of the Author : R.Norris shreve & J.A.Brink
Publisher : McGraw Hill
Edition/Year : 4/1977
Prepared by:
Signature :
SRNMC Regulation-2016 Syllabus
SRI S.RAMASAMY NAIDU MEMORIAL COLLEGE
(An Autonomous Institution Re-accredited with ‗A‘ Grade by NAAC)
SATTUR-626 203.
Department of Chemistry
(For those who joining in 2016-2017 and after)
SYLLABUS
Programme : M.Sc ., Chemistry Subject Code :P16CHC2P1
Semester : II No. of Hours allotted : 6 / week
Subject : Paper X Practical - II No. of Credits : 4
Title of the Paper : ORGANIC CHEMISTRY PRACTICAL
Objectives
To enable the students
To estimate the organic compounds quantitatively
To prepare organic compounds by two stage preparation
To separate and analyse the given organic mixture into two different components
Separation and analysis of two component mixtures. Identification of the
components and preparation of solid derivative.
Quantitative analysis:
a. Estimation of glucose by Lane and Eynon method and Bertrand method
b. Estimation of glycine.
c. Estimation of formaldehyde.
d. Estimation of ethylmethyl ketone
Organic preparations: (only for class work)
About 5 (five) two stage preparations:
a. p-Nitroaniline from acetanilide
b. Anthranilic acid from phthalimide
c. m-Nitrobenzoic acid from methyl benzoate
d. Benzanilide from benzophenone.
e. Acetylsalicylic acid from salicylic acid
SRNMC Regulation-2016 Syllabus
Reference book-1:
Title of the book : Small Scale Preparations
Name of the Author : A.I. Vogel
Publisher : ELSB
Edition/Year : 2/1966
Reference book -2
Title of the book : Basic principles of practical Chemistry
Name of the Author : V. Venkateswaran, R.Veerasamy, A.R Kulandaivelu
Publisher : Sultan chand & sons Publishers, New Delhi
Edition/Year : 1/1995
Reference book -3
Title of the book : A Laboratory Manual of Organic Chemistry
Name of the Author : S. Murugan
Publisher : Bharathi Press
Edition/Year : 3/ 1988
Prepared by:
Signature :
SRNMC Regulation-2016 Syllabus
SRI S.RAMASAMY NAIDU MEMORIAL COLLEGE (An Autonomous Institution Re-accredited with ‗A‘ Grade by NAAC)
SATTUR-626 203.
Department of Chemistry
(For those who joining in 2016-2017 and after)
Programme : M.Sc ., Chemistry Subject Code :P16CHC31
Semester : III No.of Hours allotted: 6 / week
Subject : Core Paper No of Credits :5
Title of the Paper : ORGANIC CHEMISTRY - III
REACTIONS, REAGENTS AND SPECTROSCOPY
Objectives
To understand the concept of Oxidation and reduction
To know the application of reagents in organic synthesis
To apply 1H NMR and
13C NMR methods in elucidating the structure and
identification of organic molecules.
To apply the principle of ORD and CD in elucidating the structure of organic
molecules.
To know the chemistry of vitamins.
UNIT: I Oxidation and reduction
Elimination of hydrogen and aromatization reactions – catalytic dehydrogenation –
mechanism and application of stereochemical aspect of the following oxidation – reduction
reactions : Oxidation reaction involving CrO3, SeO2, OsO4, lead tetra acetate, periodic acid,
N- bromosuccinimide, H2O2 - Oppenauer oxidation.
Catalytic hydrogenation – reaction involving lithium aluminium hydride, tri
isobutoxy aluminium hydride - DIBAL and sodium borohydride - Birch reduction –
Meerwein-Pondorf-Verley reduction – Wolff-Kishner reduction — Hydroboration.
UNIT :II Reagents in organic synthesis and Free radicals :
Gilman‘s reagent (lithium dimethylcuprate), lithium diisopropylamide(LDA),
Dicyclohexylcarbodiimide, 1,3-dithiane,Woodward and Prevost hydroxylation, Merrifield
resin, phase transfer catalysts, Peterson‘s synthesis and Baker‘s yeast.
Free radicals: Free radical reactions – halogenations, addition, oxidation, reduction
and rearrangement reactions – Barton, Sandmeyer, Gomberg, Bachmann, Ullmann, Pschorr
and Hundsdiecker reactions.
SRNMC Regulation-2016 Syllabus
UNIT : III 1H NMR Spectroscopy :
1H NMR spectroscopy: Origin of NMR spectra – chemical shift, chemical shift
parameters – internal standards – factors affecting chemical shift, anisotropic effect, – NMR
concept of aromaticity – spin-spin coupling – coupling constant – first and second order
spectra– influence of stereochemical factors on chemical shift of protons – simplification of
complex spectra – deuterium substitution – spin decoupling and spin tickling – double
resonance – shift reagents – lanthanide shift reagents, chiral resolving reagents – Nuclear
Overhauser effect – CIDNP.
UNIT : IV 13
C NMR spectroscopy:
Natural abundance – H decoupling - Off-resonance decoupling – line intensities –
chemical shift equivalence - elementary study of alpha, beta and gamma effects -
hybridization of carbon - calculation of chemical shifts for aromatic and aliphatic
compounds , DEPT 13
C spectra - 13
C correlation spectroscopy - COSY, HETCOR, NOESY
and Inadequate.
Application: Application of spectral studies to characterize the organic compounds
Unit: V Chiro- optical and Analytical techniques and vitamins:
ORD and CD – principle - Cotton effect - type of ORD curves - α-haloketone rule -
octant rule - applications to determine the configuration and conformation of simple
monocyclic and bicyclic ketones-comparison of ORD and CD.
Vitamins : Introduction, classification, Structural elucidation of vitamins A, B1, B2,
B6, C, D2 and H
Text Books
Text book-1
Title of the book : Reaction mechanism and reagents in organic chemistry
Names of the Author : G.R.Chatwal
Publisher : Himalaya publishing house,
Edition/Year : 5 / 2012
Text Book- 2
Title of the book : Reactions, Rearrangements and Reagents
Name of the Author : Somorendra Nath Sanyal
Publisher : Bharati Bhawan Publishers
Edition/Year : 3 reprint / 2000
SRNMC Regulation-2016 Syllabus
Text Book- 3
Title of the book : Elementary organic spectroscopy principles and chemical
applications
Name of the Author : Y.R.Sharma
Publisher : S.Chand and company Ltd, New Delhi
Edition/Year : Reprint / 2012
Text Book- 4
Title of the book : Organic spectroscopy – principles and applications,
Name of the Author : Jag Mohan,
Publisher : Narosa Publishing House,
Edition/Year : 2/ 2003.
Unit-I (From Text Book-1)
Chapter-17 (Page No.17.12-17, 27-48,56-70,91)
(From Text Book-2)
Chapter-2 (Page No.96-97, 146-148, 152-154)
Chapter-3 (Page No.199-202, 210-234, 237-246).
Unit-II (From Text Book-1)
Chapter-17 (Page No.17.23-26)
(From Text Book-2)
Chapter-2 (Page No.91-94, 167-170, 177-180)
Chapter-3 (Page No.206-209)
Unit-III (From Text Book-3)
Chapter-5 (Page No.182-221,230-233)
(From Text Book-4)
Chapter-4 (Page No.187-197,203-256,269-288,296-306)
Unit-IV (From Text Book-4)
Chapter-4 (Page No.307-326)
Unit-V (From Text Book-4)
Chapter-5 (Page No.440-445,457-460)
Chapter-6 (Page No.473-481)
SRNMC Regulation-2016 Syllabus
Reference books:
Reference book1
Title of the book : Organic reaction mechanism
Name of the Author : V.K Ahluwalia
Publisher : Narosa publishing House New Delhi
Edition/Year : 3 /2007
Reference Book-2
Title of the book : Organic Spectroscopy,
Name of the Author : William Kemp,
Publisher : ELBS,
Edition/Year : 3 / 2008,
Reference Book-3
Title of the book : Spectrometric Identification of Organic Compounds,
Name of the Author : Robert M.Silverstein, Francis X. Webster,
Publisher : John Wiley and Sons Inc.,
Edition/Year : 6 / 2010.
Reference Book-4
Title of the book : Spectroscopy of Organic Compounds,
Name of the Author : P.S.Kalsi,
Publisher : New Age International Publishers,
Edition/Year : 6 / 2009.
Reference Book-5
Title of the book : Organic Chemistry of Natural Products volume I ,
Name of the Author : Gurdeep R. Chatwal,
Publisher : Himalaya PublishingHouse.
Edition/Year : 1 / 2007
SRNMC Regulation-2016 Syllabus
Reference Book-6
Title of the book : Organic Chemistry of Natural Products volume II,
Name of the Author : Gurdeep R. Chatwal
Publisher : Himalaya PublishingHouse.
Edition/Year : 4 /2007
Reference Book-7
Title of the book : ORD and CD in Chemistry and Biochemistry
Name of the Author : P. Crabbe
Publisher : Academic Press,
Edition/Year : 2 / 1972
Prepared by :
Signature :
SRNMC Regulation-2016 Syllabus
SRI S.RAMASAMY NAIDU MEMORIAL COLLEGE
(An Autonomous Institution Re-accredited with ‗A‘ Grade by NAAC)
SATTUR-626 203.
Department of Chemistry
(For those who joining in 2016-2017 and after)
SYLLABUS
Programme : M.Sc ., Chemistry Subject Code : P16CHC32
Semester : III No. of Hours allotted: 6 / week
Subject : Core -Paper - XII No. of Credits : 5
Title of the Paper : INORGANIC CHEMISTRY III
INORGANIC SPECTROSCOPY AND NANO CHEMISTRY
Objectives:
To enable the students
to have an indepth study of spectral applications to the structural elucidation of
inorganic compounds.
to have an exposure to the nano technology
to understand the concept of molecular rearrangements reaction in coordination
complexes.
Unit : I Electronic Spectra of Transition Metal Complexes and Photochemistry:
d-d transition- charge transfer transition.- L-S coupling- Microstates –Term
symbol-selection rules – mechanism of breakdown of selection rules- bandwidths and shapes-
Jahn Teller effect –Orgel diagram --Tanabo-sugano diagram- Racah parameter- evaluation of
10Dq and Nephelauxetic ratio( β) for octahedral and tetrahedral complexes of d2,d
3,d
7 and d
8
configurations-photochemistry –photo redox and substitution reactions in Co(III) and Cr(III)
complexes.
Unit : II Application of Spectroscopy to the Study of Inorganic Compounds:
Mossbauer Spectroscopy:
Mossbauer effect- resonance absorption-Doppler effect- Doppler velocity –isomer
shift-magnetic hyperfine splitting-application of Mossbauer spectroscopy in the study of iron
and tin complexes.
NMR Spectroscopy: 31
P,19
F and 15
N – NMR – introduction –application in structural
problem-evaluation of rate constants –NMR of fluxional molecules –NMR of paramagnetic
molecules- contact shifts and shift reagents.
SRNMC Regulation-2016 Syllabus
ESR Spectroscopy: Principle –presentation of the spectrum –hyperfine splitting- evaluation
of g values –factors affecting the magnitude of g –values-Zero field splitting –Kramer's
degeneracy---application of ESR in the study of transition of metal complex
UNIT : III Nanochemistry
Basic idea of nanoscience–Dimensional in nano structures-,0D,1D,2D and 3D ,
synthesis of nano materials -chemical method, sol gel , Chemical vapour deposition- Ball
milling-plasma Arcing- electrodeposition- Thermolysis
Carbon nanotubes: Types of carbon nano tubes- Structure, properties and applications of
single walled carbon nano tubes.
Nano Shells: Introduction-types- properties and applications (Ion slective film gold
nanoshell for Blood Immunoassay and cancer Detection and therapy.)
Nano polymers: Conductive polymer and Block copolymer.
Applications of nano materials- Insulation material-machine tools-high power magnets-
motor vehicle and Aircrafts.
Unit – IV Reaction Mechanism of Coordination compounds
Substitution reactions of octahedral complexes- Factors affecting reactivity octahedral of
complexes – – labile – inert complexes – Mechanism of acid hydrolysis, base hydrolysis and
anation reactions Substitution reactions of square planar complexes – Factors affecting
reactivity of square planar complexes – The trans- effect and its applications– Electron
transfer reactions – outer sphere and inner sphere electron transfer mechanisms-
complementary and non complementary reactions.
UNIT :V Molecular Rearrangements and Reaction of Coordinated Ligands:
Molecular rearrangement of four coordinated complex- six coordinated
complexes-reaction at coordinated ligands- reaction due to metal ion polarization of
coordinated ligands-hydrolysis of amino acid ester, amides and of peptides- Aldol
condensation-imine formation, hydrolysis and substituent exchange – the template effect and
macro cyclic ligands.
SRNMC Regulation-2016 Syllabus
Text books
Text Book- 1
Title of the book : Principles of Inorganic Chemistry
Name of the Author : B.R.Puri and L.R.Sharma and K.C.Kalia
Publisher : Milestone Publishers , New Delhi
Edition/Year : 30/2008
Text Book- 2
Title of the book : Introduction to Nanotechnology
Name of the Author : Charles P.Poolee Jr. and Franck Owens,
Publisher : John-Wiley and Sons
Edition/Year : 1/2006
Text Book- 3
Title of the book : Nano: the Essentials
Name of the Author : T.Pradeep
Publisher : Mc Graw-Hill Education,Delhi.
Edition/Year : 1 /2008
Text Book- 4
Title of the book : NanoTechnology
Name of the Author : Mick Wilson
Publisher : Overseas Press India Private Limited
Edition/Year : 1/2008
Text Book-5
Title of the book : An Introduction to Inorganic Chemistry.
Name of the Author : K.F. Purcell and J.C Koltz ,
Publisher : W.B Saunders company,
Edition/Year : /1980
Text Book-6
Title of the book : .Spectroscopy
Name of the Author : B.K Sharma
Publisher : Geol Publishing House,Meerut
Edition/Year : 17/2005
Text Book-7
Title of the book : .Slected topics in Inorganic Chemistry
Name of the Author : Wahid U.Malik ,G.D Tuli and R.D Madan
Publisher : S.Chand & company Ltd
Edition/Year : 1/2007
SRNMC Regulation-2016 Syllabus
Unit-I (From Text Book-1)
Chapter 29 (Page No 822 to 838,872 to 876)
Unit-II (From Text Book-6)
Chapter 14 (Page No 737 to760)
Unit-III (From Text Book-4)
Chapter 3 (Page No 59 to 81)
Unit IV (From Text Book -7)
Chapter 15 and 16(page No 510-542) )
Unit V (From Text Book -5) Chapter (Page No 757 to 791)
Reference Books
Reference Book-1
Title of the book : Inorganic Chemistry.
Name of the Author : James E. Huheey , Ellen A. Keitler and Richard L. Keitler,
Publisher : Harper Collins College Publishers
Edition/Year : 4/1993
Reference Book-2
Title of the book : Physical Methods in Chemistry
Name of the Author : R.S.Drago
Publisher : W.B.Saunder company, London
Edition/Year : 1/1977
Prepared by :
Signature :
SRNMC Regulation-2016 Syllabus
SRI S.RAMASAMY NAIDU MEMORIAL COLLEGE
(An Autonomous Institution Re-accredited with ‗A‘ Grade by NAAC)
SATTUR-626 203.
Department of Chemistry
(For those who joining in 2016-2017 and after )
SYLLABUS
Programme : M.Sc. Chemistry Subject Code : P16CHC33
Semester : III No. of Hours allotted: 6 / week
Subject : Core Paper VIII No. of Credits : 5
Title of the Paper : PHYSICAL CHEMISTRY – III
GROUP THEORY AND NANO CHEMISTRY
Objectives
To enable the learners to
To have an idea of symmetries of molecules and their fundamental concepts.
To apply the group theory to spectroscopy and molecular problems.
To know about the principles and instrumentation of nano chemistry.
To get a clear idea about various spectroscopic technique and their applications.
UNIT-I Group Theory
Molecular symmetry elements and symmetry operations. Matrix algebra- types of
matrices, matrix representation for symmetry operations (E,Cn,Sn,i, σ) and transformatuon
matrices. Group-definition and properties of a group, subgroup, isomorphic group and
classes. Group multiplication table for C2Vand C3V point groups. Representation of a group
- reducible and irreducible representations.
Great Orthogonality theorem. Construction of a character tables- C2V, C3V, C2h and
D2d. Standard reduction formula. Direct product – definition and its applications.
UNIT-II Application of Group Theory to Spectroscopy and Molecular Problems
Definition of molecular vibration, symmetry of normal mode analysis to water,
formaldehyde, ammonia, trans-N2F2 and ethylene molecule. Selection rules for IR and Raman
spectra. Selection rules for electronic transition in simple molecules like ethylene,
formaldehyde and benzene.
SRNMC Regulation-2016 Syllabus
Group theory applied to hybridization (BCl3, PCl5, XeF4, SF6 and CH4). Simplication
for molecular orbital calculation- SALC procedure - HMO theory and delocalization energy
for cyclopropenyl ,butadiene and benzene systems.
UNIT-III Molecular Spectroscopy-II
Raman spectroscopy: Theories of Raman scattering, Rotational and vibrational
Raman spectra. Mutual exclusion principle- Laser Raman spectra. Electronic spectra of
diatomic and polyatomic molecules. Intensity of vibrational electronic spectra - Franck
Condon principle -rotational fine structure of electronic vibrational spectra. Fortrat parabola.
Dissociation and predissociation spectra.
NQR : Principles and applications –quadruple moment and electrical field, nuclear
quadruple resonance, nuclear quadruple coupling in atoms and molecules. Identification of
ionic character and hybridization.
UNIT-IV Spin Resonance Spectroscopy
NMR : Magnetic properties of nuclei, resonance condition, NMR instrumentation.
Chemical shift, spin-spin splitting, relaxation processes, line shape and line width. Double
resonance technique, ENDOR, Nuclear Overhauser effect, FT-NMR spectroscopy and
lanthanide shift reagents.
Photo electron spectroscopy – principle, XPS of elements, chemical shift, Koopman‘s
theorem, XPS of O2 molecule, valence electron photoelectron spectroscopy. UPS spectrum
of N2 and O2 molecule. Application of photoelectron spectroscopy.
UNIT : V Instrumentation in Nanochemistry:
Microscopic techniques for the characterization of nanomaterials – UV-Visible and
fluorescence spectroscopy AFM, SEM, TEM. X-ray diffraction and microanalysis.
Text books
Text Book- 1
Title of the book : Symmetry and spectroscopy of molecules
Name of the Author : K. Veera Reeddy
Publisher : New Age International Publishers
Edition/Year : 1 /2007
SRNMC Regulation-2016 Syllabus
Text Book- 2
Title of the book : Group Theory in Chemistry
Name of the Author : V.Ramakrishnan and M.S. Gopinathan
Publisher : Vishal Publications
Edition/Year : 2/1996
Text Book- 3
Title of the book : Fundamentals of molecular spectroscopy
Name of the Author : Colin N. Banwell and Elaine M.McCash
Publisher : Tata McGraw- Hill Publishing Company Limited
Edition/Year : 4/2003
Text book-4
Title of the book : Principles of Physical chemistry
Name of the Author : B.R.Puri, L.R.Sharma,M.S.Pathania
Publication : Vishal publishing Co,New Delhi.
Edition/ year : 45 /2012
Text Book- 5
Title of the book : Instrumental methods of chemical analysis
Name of the Author : Gurdeep R. Chatwal
Publisher : Himalaya Publishing House
Edition/Year : 5 / 2007
Text Book- 6
Title of the book : Nano technology, basic science and emerging technologies
Name of the Author : Mick Wilson
Publisher : Overseas Press India Private Limited,New Delhi.
Edition/Year : 1 /2008
Unit I (From Text book 1)
Chapter-2(Page No. 21-47)
Chapter-4(Page No. 127-143)
Chapter-5(Page No. 144-172)
Chapter-6(Page No. 185-211)
Unit II (From Text book 1)
Chapter-7(Page No. 212-225)
(From Text book 2)
Chapter-5(Page No. 62-98)
Unit III (From Text book 4)
Chapter-4(Page No. 2.83-2.99)
Unit IV (From Text book 3)
Chapter-7 (Page No. 199-219)
(From Text book-4)
Chapter-7 (page No. 416-420)
(From Text book 4)
Chapter-7(Page No. 2.185-2.210)
Chapter-10(Page No. 2.245-2.267)
Unit- V (From text book 5)
Chapter-2(Page No. 30-40)
SRNMC Regulation-2016 Syllabus
Reference Books
Reference Book-1
Title of the book : Group Theory and its applications to chemistry
Name of the Author : K.V.Raman
Publisher : Tata McGraw- Hill Publishing company limited
Edition/Year : 1 /1990
Reference Book-2
Title of the book : Chemical applications of Group Theory
Name of the Author : F.A. Cotton
Publisher : John Wiley & Sons,New york
Edition/Year : 3 /1999
Reference Book-3
Title of the book : A Simple approach to group theory in chemistry
Name of the Author : S. Swarnalakshmi,T. Saroja,R.M.Ezhilarasi
Publisher : Universities Press Private Ltd
Edition/Year : 1 /2008
Reference Book-4
Title of the book : Molecular structure and spectroscopy
Name of the Author : G.Aruldhas
Publisher : PHI Learning (P) Limited, New Delhi
Edition/Year : 2 /2009
Reference Book-5
Title of the book : Introduction to Nanotechnology
Name of the Author : Charles P.Poolee Jr. and Franck Owens,
Publisher : John-Wiley and Sons
Edition/Year : 1 /2006
Reference Book-6
Title of the book : Nano: the Essentials
Name of the Author : T.Pradeep
Publisher : Mc Graw-Hill Education, Delhi.
Edition/Year : 1 /2008
Prepared by :
Signature :
SRNMC Regulation-2016 Syllabus
SRI S.RAMASAMY NAIDU MEMORIAL COLLEGE (An Autonomous Institution Re-accredited with ‗A‘ Grade by NAAC)
SATTUR-626 203.
Department of Chemistry
(For those who joining in 2016-2017 and after)
SYLLABUS
Programme : M.Sc ., Chemistry Subject Code :P16CHE31
Semester : III No. of Hours allotted: 6 / week
Subject : Paper XIV - Major Elective III (a) No. of Credits : 4
Title of the Paper : COMPUTER APPLICATIONS
Objectives:
To study the basic concepts of VB and its application in chemistry.
To know about basic concepts of internet.
UNIT:1 Basic Concept of VB
Introduction to visual basic-the integrated development environment-the menu bar,tool
bar,the project explorer,the tool box,the properties of window,the form designer,the form lay
out,the immediate window,the elements of the interface-programming an application
common properties,common methods and common events-customising the environment.
Working with Forms: The appearance of form – the start up form – loading,
showing and hiding forms – elementary concepts of drag and drop operations.
Basic active X controls : Elementary concepts of Text Box control, the List Box and
ComboBox controls.
Variables – declaring variables – variable types – strings, numeric and data variables-
scope and life forms of variables – constants.
UNIT: II The Language Forms And Basic Active Controls
Control flow statements: If… Then and If… Then…Else. Loop statements : DO…
Loop,For…Next and While – Wend – nested control statement – the Exit statement.
Arrays : Declaring arrays – specifying arrays – multi dimensional arrays.
Procedures: Subroutines, functions, calling procedures – arrangements – arguments passing
mechanism – using optional arguments – functions returning arrays.
SRNMC Regulation-2016 Syllabus
UNIT:III Applications of VB in Chemistry
Writing Simple programs in Chemistry :
1. Calculation of molecular weight of organic compound,
2. Ionic strength of an electrolyte,
3. Different velocities of a gas,
4. NMR frequency values of nuclei,
5. Average rate constant,
6. Unit cell dimensions,
7. Thermodynamic parameters,
8. Reduced mass,
9. Empirical formula of an organic compound containing C,H and O,
10. Normality, molality and molarity of a solution,
11. Half life period of a radioactive material,
12. Surface tension and
13. Temperature in Kelvin scale into Celsius and vice-versa.
Practical : (Class work only)
Construcion of programs in VB language, compiling, debugging and making
executive files, printing the output.
Running Simple VB programs in Chemistry to calculate/ determine the above
problems.
UNIT :IV Basic Concepts Of Communications Systems
Communication systems : Satellites – RADAR – optical fibers – advantages
and disadvantages – ISDN – distributed systems – advantages and disadvantages.
Telecommunications: analog and digital signals – types and needs of modulations –
MODEMS – Telecommunication software.
Computer networks : An overview – communication processors – protocols
– network architecture.
Practicals (Class work only)
1. Salient features of Windows and MS Word for typing texts and equations in Chemistry
– tabular columns – advanced concepts.
2. Basic concept of creating and accessing databases using MS Access.
3. Significance of Chemdraw – drawing chemical structures and pasting them in the text.
SRNMC Regulation-2016 Syllabus
UNIT : V Basic Concepts of Internet and Applications in Chemistry
Internet: History of internet – the working way of internet – getting connected to internet
,internet protocols – internet addressing –domain names- internet services.
www : Web Pages–homepages –web browsers –search engines –internet chat – chatting on
web.
E-mail : Introduction – working way – mailing basics – e-mail ethics – advantages and
disadvantages – creating e-mail – receiving and sending e-mails.
Internet : characterisation – advantages – drawbacks – need for internet – extranet.
Applications of internet in Chemistry : Websites in Literature survey in chemistry –
popular websites in chemistry – data bases in chemistry - URLS – WAIS – downloading the
attachment / PDF files – opening ,browsing and searching a website literature searching
online.
Practicals (Class work only) :
1. Creating e-mail id,sending and receiving e- mail, attachment files, PDF files.Opening,
browsing and searching a website – down loading– literature survey in chemistry –
online searching.
Unit I To V Study material will be provided
Reference Book-1
Title of the book : Mastering Visual Basic 6
Name of the Author : Evangelos Petroutsos
Publisher : BPB Publication
Edition/Year : 1/1998
Reference Book-2
Title of the book : Visual Basic 6 Super Bible
Name of the Author : David Jung, Pierre Boutqukin, John D. Conley III, Loren Eidahl
Publisher : First Indian Edition, Techmedia, New Delhi, 1999.
Edition/Year : 1/1999
Reference Book-3
Title of the book : Visual Basic 6.
Name of the Author : Gary Cornell,
Publisher : Tata-McGraw Hill, New Delhi
Edition/Year : 1/1998
Prepared by :
Signature :
SRNMC Regulation-2016 Syllabus
SRI S.RAMASAMY NAIDU MEMORIAL COLLEGE (An Autonomous Institution Re-accredited with ‗A‘ Grade by NAAC)
SATTUR-626 203.
Department of Chemistry
(For those who joining in 2016-2017 and after )
SYLLABUS
Programme : M.Sc ., Chemistry Subject Code :P16CHE32
Semester : III No. of Hours allotted: 6 / week
Subject : Paper XIV Major Elective – III (b) No. of Credits : 4
Title of the Paper : PHARMACEUTICAL CHEMISTRY
Objectives
To enable the learners to
1. Know the fundamentals of Medicinal Chemistry.
2. Learn uses of antibiotics and steroids.
3. Understand the concept of chemotherapy and its agents.
Unit-I Fundamentals of Medicinal chemistry
Definitions of Medicinal Chemistry, Pharmacology and molecular pharmacology,
pharmacodynamics, pharmacophore, pharmacodynamics agents - Structure Activity
Relationship (QSAR) – Hansch approach – account of physiological effects by hydroxyl,
aldehyde, ketone, acidic, nitro, nitrite, nitrile groups and unsaturation - drug receptors ,
mechanism of drug action on enzymes, gene function, biological membranes.
Unit-II Medicinally useful antibiotics and antimalarials
Classification of antibiotics - Structural features and SAR of the following
antibiotics - penicillin G, cephalosphorin and their semisynthetic analogs (β-lactam),
streptomycin (amino glycoside), terramycin (tetracycline), erythromycin(macrolide) ,
chloramphenicol and Rifamycin.
Unit-III Chemotherapeutic agents
Antineoplastic agents: Classification, synthesis and uses of Cyclophosphamide,
Clorambucil, Busulfan, Decarbazine, Methotrexate, 6-Mercaptopurine, 5-fluorouracil and
cisplatin,
Antitubercular drugs: Classification, synthesis and uses of Isoniazid, Rifampicin,
Pyrazinamine, Ethambutol and Ethionamide.
SRNMC Regulation-2016 Syllabus
Anti malarial drugs: Classification, synthesis and uses of Chloroquin, Primaquine,
Amaodiaquine.
Diuretics: Classification, synthesis and uses of Fursemide, Acetazolamide,
Chlorothiazide.
Unit-IV Synthesis and Therapeutic action of certain drugs
Antihypertensive drugs: Nifedipine, Captopril, Sodiumnitroprusside, clonidine,
methyldopa and guanothidine.
Antihistamines: H1-Antagonists: Pheniramine, Mepyramine, Promethazine,
H2- Antagonists: Cimetidine, Ranitidine and fomotidine.
Unit- V
Anti-inflammatory drugs: Antipyratics & Non-narcotic analgesics: Aspirin, sodium
salicylate, paracetamol, phenylbutazone, oxyphenylbutazone, ibuprofen, Mephenamicacid,
Diclofenac sodium (preparation,structure and therapeutic uses only).
CNS Stimulant drugs: Amphetamine, Caffeine, Theobromine, Theophylline (structure and
therapeutic uses only).
CNS Depressent drugs: Phenelazine, Imipramine, Amitriptyline, Desipramine (structure and
therapeutic uses only).
Text books
Text Book- 1
Title of the book : Pharmaceutical chemistry-organic
Name of the Author : G.R.Chatwal
Publisher : Himalaya Publishing House
Edition/Year : 3/2007
Text Book- 2
Title of the book : A Textbook of Pharmaceutical Chemistry
Name of the Author : Jayashree Ghosh
Publisher : S.Chand& Company Ltd
Edition/Year : 2/1996
Text Book- 3
Title of the book : Medicinal chemistry
Name of the Author : G.R.Chatwal
Publisher : Himalaya Publishing House
Edition/Year : 2/2006
SRNMC Regulation-2016 Syllabus
Text Book- 4
Title of the book : Text book of Pharmaceutical Organic chemistry
Name of the Author : Mohammad Ali
Publisher : CBS Publichers & distributors
Edition/Year : 1 /2006
Unit-I (From Text Book-1)
Chapter – 1 (Page No. 5-7)
Chapter – 3 (Page No. 41-45, 50-56, 62,63)
Chapter – 5 (Page No. 94-97)
Unit-II (From Text Book-2)
Chapter – 23 (Page No.242-265)
Unit-III (From Text Book- 3 )
Chapter – 31 (Page No 316-333, 283 to291, 264 to271)
Unit-IV (From Text Book- 3 )
Chapter – 19 (Page No 214 to224)
Unit-V (From Text Book-3)
Chapter – 13 (Page No.175-179)
(From Text Book-4)
Chapter – 16 (Page No.174-176)
Reference Books
Reference Book-1
Title of the book : Medicinal Chemistry
Name of the Author : Sriram.D,Yogeeswari
Publisher : PESL
Edition/Year :2/2010
Reference Book-2
Title of the book : Medicinal Chemistry
Name of the Author : Kar.Ashutosh
Publisher : New age International Publishing House
Edition/Year : 5/2010
Reference Book-3
Title of the book : Introductory Medicinal Chemistry..
Name of the Author : J.B Taylor and P.D Kennewell
Publisher : Ellisworth publishers
Edition/Year : 1/1985
Prepared by :
Signature :
SRNMC Regulation-2016 Syllabus
SRI S.RAMASAMY NAIDU MEMORIAL COLLEGE
(An Autonomous Institution Re-accredited with ‗A‘ Grade by NAAC)
SATTUR-626 203.
Department of Chemistry
(For those who joining in 2016--2017 and after )
SYLLABUS
Programme : M.Sc ., Chemistry Subject Code :P16CHC3P1
Semester : III No. of Hours allotted: 6 / week
Subject : Paper XV PRACTICAL III No. of Credits :4
Title of the Paper : PHYSICAL CHEMISTRY PRACTICAL
Objectives:
To know about the practical applications of conductometry.
To appreciate the application of potentiometric technique in the quantitative analysis.
To understand the concepts of adsorption and Chemical kinetics by carrying out
experiments.
I. Conductometric Experiments
i. Double displacement & acid base titrations
a) NH4Cl-NaOH-Mixture of CH3COOH &HCl.
b) NH4Cl- NaOH- Mixture of NH4Cl &HCl.
ii. Precipitation titration
a) Na2CO3-Pb(NO3)2 – Na2CO3
b) b) K2SO4 – BaCl2 – K2SO4.
iii. Determination of dissociation constant of weak acids.
II Adsorption Experiments
Adsorption of oxalic acid/ Acetic acid on charcoal.
III Kinetic Experiments
i. Perdisulphate and iodide ion reaction: Study of primary salt effect and
determination of concentration of given KNO3.
IV Potentiometric methods
i. Precipitation titration : Ag vs. halide mixture
ii. Redox titrations : a) permanganate vs iodide ion
b) ceric ammonium sulphate vs. ferrous ion
SRNMC Regulation-2016 Syllabus
iii. Determination of dissociation constant of weak acids and pH of
buffer solutions
iii. Determination of solubility product of sparingly soluble salts.
References:
Reference Book-1
Title of the book : Advanced Practical Physical Chemistry
Name of the Author : J.B. Yadav
Publisher : Goel Publications, Meerut
Edition/Year : 6/1986
Reference Book-2
Title of the book : Practical physical Chemistry
Name of the Author : B.Viswanathan
Publisher : Vivas Book private limited
Edition/Year : 1/2005
SRNMC Regulation-2016 Syllabus
SRI S.RAMASAMY NAIDU MEMORIAL COLLEGE (An Autonomous Institution Re-accredited with ‗A‘ Grade by NAAC)
SATTUR-626 203.
Department of Chemistry
(For those who joining in 2016-2017 and after)
Programme : M.Sc . Chemistry Subject Code :P16CHC41
Semester : IV No.of Hours allotted: 6 / week
Subject : Paper XVI -Core Paper No of Credits : 5
ORGANIC CHEMISTRY -IV
MOLECULAR REARRANGEMENTS AND SYNTHETIC METHODS
Objectives:
To know about the various types of molecular rearrangements.
To understanding the fundamental concept of photochemistry and free radicals.
To know about alkaloids and steroids.
To get insight into the principle of green chemistry.
To know the synthetic utility of reagents.
UNIT :I Molecular Rearrangements
Mechanism of the following rearrangement reactions: Wagner – Meerwein, Pinacol-
pinacolone, Demjanov, Beckmann, Hofmann, Curtius, Wolff, Baeyer-Villeger, Stevens,
Sommelet-Hauser, Favorskii, Benzil-benzilic acid, Claisen, Cope, Fries, Dienone-phenol and
Benzidine rearrangement – photo Fries rearrangements.
UNIT :II Photochemistry and Pericyclic Reactions
Basic principles of photochemistry - Jablonskii diagram – Norrish- I and Norrish-II
type reactions – Paternò–Büchi reaction – photochemistry of olefins and dienes – cis, trans
isomerisation - photosensitization - photoreduction .
Pericyclic reactions:
Conservation of orbital symmetry – electrocyclic reactions – cyclo addition
reactions and sigmatropic rearrangements –applications of correlation diagram approach
(butadiene and hexatriene), Frontier molecular approach, Huckel-Mobius approach to the
above reactions.
SRNMC Regulation-2016 Syllabus
UNIT III: Steroids,Harmones and Alkaloids
Steroids and Harmones: Classification – structural elucidation of cholesterol,– male
sex harmones – androsterone and testosterone – female sex harmones – oestrone, equilenin
and progesterone
Alkaloids: General methods of structural determination – Hofmann, Emde and Von
Braun degradations. structural elucidation of quinine, reserpine, morphine (synthesis not
required) and lysergic acid
UNIT : IV Green Chemistry
Twelve basic principles of green chemistry, green starting materials, green catalyst
(zeolites as solid acid catalyst) and reagents (molecular oxygen ,tetrabutylammonium
tribromide), green solvents – applications of supercritical fluids, ionic liquids and water –
solvent free techniques.
Non-conventional microwave heating - interaction of microwave radiation with the
material-difference between conventional heating and microwave heating. Dielectric
polarization-dipolar polarization-applications and advantages of microwave heating over
conventional heating.
UNIT: V - Synthetic Methods
Planning a synthesis - molecular history - starting materials - Relay approach and
convergent approach to total synthesis - Retro synthetic analysis of simple organic
compounds - functional group inter conversions -use of activating and blocking groups in
synthesis - stereo selective problems of geometrical and optical isomerism - steric crowding
– Regioselectivity – Diastereoselectivity – Enantioselectivity - Umpolung synthesis -
Robinson annelation – A schematic analysis of the total synthesis of the following
compounds:, trans-9-methyl -1-decalone and 2,4-dimethyl-2-hydroxy pentanoic acid,
Isonootkatone.
Text books
Text book-1
Title of the book : Organic reaction mechanism
Name of the Author : V.K Ahluwalia
Publisher : Narosa publishing House New Delhi
Edition/Year : 3 /2007
SRNMC Regulation-2016 Syllabus
Text Book- 2
Title of the book : Reactions, Rearrangements and Reagents
Name of the Author : Somorendra Nath Sanyal
Publisher : Bharati Bhawan Publishers
Edition/Year : 3 / 2000
Text Book- 3
Title of the book : Photochemistry and Pericyclic Reactions
Name of the Author : Jagdamba Singh and Jayasingh
Publisher : New age international (p) limited, New Delhi.
Edition/Year : 3 / 2012
Text Book- 4
Title of the book : New trends in Green chemistry
Name of the Author : V.K Ahluwalia and Kidwai ,
Publisher : Anamaya publishing house, New Delhi.
Edition/Year : 1 / 2004
Text Book- 5
Title of the book : Organic Synthesis,.
Name of the Author : R.E. Ireland,
Publisher : prentice-Hall of India Pvt. Ltd ,
Edition/Year : 2 reprint /1998
Text book-6
Title of the book : Organic chemistry of natural products Vol-I&vol-II
Name of the Author : G.R.Chatwal,
Publisher : Himalaya publishing House New Delhi,
Edition/Year : 4 & 5 /2007, 2009
Unit-I (From Text Book-1)
Chapter 6 (Page No.398-413, 415-424, 434-440,454-460)
(From Text Book-2)
Chapter 2 (Page No.89-94, 107-109,121-133, 172-174, 180-187)
Unit-II (From Text Book-3)
Chapter 6 (Page No.160-183)
Chapter 7 (Page No.184-212, 218-223)
SRNMC Regulation-2016 Syllabus
Chapter 8 (Page No.251-257)
Chapter 9 (Page No.262-264)
Chapter 10 (Page No.270-282)
Chapter 1 (Page No.1-16)
Chapter 2 (Page No.17-34)
Chapter 3 (Page No.58-87)
Unit-III (From Text Book-6)
Chapter 4 (Page No.4.1-4.25,4.59-4.68,4.76-4.82,4.90-4.92,4.95-4.96)
Chapter 3 (Page No.3.6-3.19, 3.66-76, 3.109-117, 3.123-137, )
Unit-IV (From Text Book-4)
Chapter 1&2 (Page No.1-4)
Chapter 3 (Page No.5-14)
Chapter 6 (Page No.22-26)
Chapter 7(Page No.27-28)
Chapter 8 (Page No.39-50)
Chapter 9 (Page No.59-71)
Unit-V (From Text Book-5)
Chapter 2(Page No.17-52)
Chapter 3 (Page No.55-56,81-87)
Reference Books
Reference Book-1
Title of the book : Organic Chemistry,Vol II ,
Name of the Author : I.L.Finar
Publisher : ELBS Longmann
Edition/Year : 5 / 1975
Reference Book-2
Title of the book : Advanced Organic Chemistry,.
Name of the Author : Jerry March
Publisher : John Wiley and Sons,
Edition/Year : 4 / 2000
SRNMC Regulation-2016 Syllabus
Reference Book-3
Title of the book : Green chemistry (Environmental Benign Reactions)
Name of the Autho : V.K Ahluwalia ,
Publisher : Aru Books India. New Delhi.
Edition/Year : 1 /2006
Reference Book-4
Title of the book : Green Chemistry (Environmental Friendly Alternatives)
Name of the Author : R.Sanghi and M.M. Srivastava,
Publisher : Narosa publishing House, New Delhi.
Edition/Year : 1 /2006
Reference Book-5
Title of the book : Reaction Mechanism in Organic Chemistry,
Name of the Author : S.M .Mukherji and Singh
Publisher : Macmillan India Ltd
Edition/Year : Reprint / 2007
Reference Book-6
Title of the book : Pericyclic Reactions,
Name of the Author : Sankarraman ,
Publisher : Wiley VCH.
Edition/Year : 2/2005
Reference Book-8
Title of the book : Organic Chemistry of Natural Products volume II,
Name of the Author : Gurdeep R. Chatwal
Publisher : Himalaya PublishingHouse.
Edition/Year : 4/2007
SRNMC Regulation-2016 Syllabus
Reference Book-9
Title of the book : The Chemistry of Steroids,
Name of the Author : W.Klyne
Publisher : Reinhold
Edition/Year : 1 / 1957
Prepared by :
Signature :
SRNMC Regulation-2016 Syllabus
SRI S.RAMASAMY NAIDU MEMORIAL COLLEGE (An Autonomous Institution Re-accredited with ‗A‘ Grade by NAAC)
SATTUR-626 203.
Department of Chemistry
(For those who joining in 2016-2017 and after )
SYLLABUS
Programme : M.Sc ., Chemistry Subject Code :P16CHC42
Semester : IV No. of hours allotted: 6 / week
Subject : Core Paper XVII No. of Credits : 5
Title of the Paper : INORGANIC CHEMISTRY -IV
NUCLEAR AND ORGANOMETALLIC CHEMISTRY
Objectives : To enable the students
to have a complete study of f-block elements.
to have an idea about various analytical techniques.
to learn principles and applications in nuclear chemistry.
Unit : I Structure of Nucleus and Radioactive Decay
Composition of the nucleus –nuclear Size, shape and density-Principle, radial
and magnetic quantum numbers n/p ratio- stability of nucleus packing fraction--mass defect
and binding energy.
Radioactive decay: Group displacement law – decay series – rate of disintegration -half life
period -average life period – secular and transient equilibria - theories of alpha decay, beta
decay, gamma emission, internal conversion and electron capture - Auger effect.
Unit : II Nuclear Fission and Fusion and Application of Radioactive Isotopes:
Bethe's notation of nuclear process - nuclear reaction energies (Q-values) – fission
-energy release in nuclear fission-mass distribution of fission products-theory of nuclear
fission -fissile and fertile isotopes – energy from nuclear fusion-thermonuclear reaction in
stars - Nuclear reactor--breeder reactor- waste disposal management.
Applications of radioactive isotopes: - chemical investigations-age determination-medical
field-agriculture and analytical techniques.
SRNMC Regulation-2016 Syllabus
Unit :III Actinides and Lanthanides: Chemistry of Lanthanides and Actinides;
Position of lanthanides and actinides in periodic table – occurrence, extraction of
lanthanides from monazite sand -ion exchange and solvent extraction method. -Electronic
configuration-properties of lanthanides-oxidation state-lanthanide contraction and its
consequences-color of lanthanides ions- magnetic properties of lanthanides.
Actinides: separation of actinide elements-separation of Pu from fission products-electronic
configuration- oxidation state-comparison of lanthanides and actinides.
Unit: IV Electro Analytical and SpectroAnalytical Methods:
Electro analytical Techniques:
Electrogravimetry: Theory of electro gravimetric analysis - electrolytic separation
and determination of metal ions. Coulometry - coulometric titrations. Voltametry: cyclic
voltammetry-Amperometry: Amperometric titrations.
Thermo analytical Methods: Principle and applications of TGA and DTA
Spectro analytical Method: principle and applications of – Fluorimetry - nepheometry and
turbidimetry - flame photometry and atomic absorptions spectroscopy .
Unit – V
Complexes of п- acceptor ligands:
Synthesis, structure and bonding in metal carbonyls and nitrosyls – Application of
EAN rule. Synthesis, properties, structure and bonding in ferrocene- olefin and acetylene
complexes.
Catalysis using organometallic compounds
Oxidative addition – reductive elimination – insertion reaction Catalytic mechanism in
the following Reactions: hydrogenation of olefins (Wilkinson catalyst) - hydroformylation
(Oxoprocess) – acetic acid from methanol – oxidation of alkenes to aldehydes and Ketones
(Wacker process) – olefin polymerization (Ziegler – Natta) – Cyclo oligomerisation of
acetylenes (Reppe‘s or Wilke‘s catalysts).
SRNMC Regulation-2016 Syllabus
Text books
Text Book- 1
Title of the book : Essential of Nuclear Chemistry
Name of the Author : H.I .Arnikar
Publisher : Wiley Eastern Ltd.,New Delhi
Edition/Year : 3/1987
Text Book- 2
Title of the book : Nuclear Chemistry
Name of the Author : U.N.Dash
Publisher : Sultan Chand and Sons, New Delhi
Edition/Year : 1/1991
Text Book- 3
Title of the book : Selected Topics in Inorganic Chemistry
Name of the Author : Wahid U.Malik ,Tuli, Madan
Publisher : S.Chand and Company Ltd.
Edition/Year : 7/2007
Text Book- 4
Title of the book : Instrumental Methods of chemical Analysis
Name of the Author : Gurdeep R.Chatwal
Publisher : Himalaya Publishing House
Edition/Year : 5/2012
Text Book- 5
Title of the book : Advanced Inorganic Chemistry Vol II
Name of the Author : Satya Prakash
Publisher : S.Chand & Company LTD
Edition/Year : 17/2000
Text Book- 6
Title of the book : Concise Co-ordination Chemistry,
Name of the Author : R.Gopalan and V.Ramalingam,
Publisher : Vikas Publishing House PVT Ltd
Edition/Year : 1/2009
Unit I (From Text book-2)
Chapter - 1 ( section 1.5 to 1.6.4, 1.8.1, 1.8.2)
Chapter - 3 (section 3.2 to3.3, 3.6.1, 3.6.2,)
Chapter - 5 (Page no 195 to 201, 214 to 227)
Unit II (From Text book -1)
Chapter 5(section 5.1 to 5.2.6, 5.7 to 5.7.3, 5.9 ,5.10)
Chapter 6 (section6.2 ,6.3 6.9)
Chapter 7 (section 7.8.1 ,7.11)
Chapter 10 (section 10.7.1.10.7.3 to 10.7.6)
SRNMC Regulation-2016 Syllabus
Unit-III (From Text Book-3)
Chapter 9 and 10 (274 to 331)
Unit IV (From Text Book -4)
Chapter 26 to29 (Page No 2.523 to 2.549)
Chapter 41 (Page No 2.701 ,2.719 to 2.738)
Chapter 13 to 16(Page No 2.340 to 2.415)
Unit-V (From Text Book-5)
Chapter 13(Page No 370 to 405)
(From Text Book-6)
Chapter 13(Page No 285 to 309)
Reference Books
Reference Book-1
Title of the book : Source Book on Atomic Energy
Name of the Author : S.Glasstone,
Publisher : Van Nostrand Reinhold Company, New York
Edition/Year : 3/1967
Reference Book-2
Title of the book : Fundamentals of Analytical Chemistry,
Name of the Author : D.A .Skoog and D.M. Weat
Publisher : Saunders college Puplishing co Philadelphia
Edition/Year : 1/1982
Reference Book-2
Title of the book : Instrumental Methods of Analysis
Name of the Author : H.H..Willard, LL.Merritt and J.A.Dean,
Publisher : East- West press., New Delhi
Edition/Year : 1 /1988
Prepared by :
Signature :
SRNMC Regulation-2016 Syllabus
SRI S.RAMASAMY NAIDU MEMORIAL COLLEGE
(An Autonomous Institution Re-accredited with ‗A‘ Grade by NAAC)
SATTUR-626 203.
Department of Chemistry
(For those who joining in 2016-2017 and after)
SYLLABUS
Programme : M.Sc ., Chemistry Subject Code:P16CHC43
Semester : IV No. of Hours allotted: 6 /week
Subject : Core Paper XVIII No. of Credits : 5
Title of the Paper : PHYSICAL CHEMISTRY -IV
CHEMICAL KINETICS, SURFACE, BIOPHYSICAL AND
PHOTOCHEMISTRY
Objectives:
To get themselves exposed to kinetics and mechanism.
To derive advance knowledge on solids and surface phenomena.
To learn concepts of non-equilibrium thermodynamics and bio-energetic.
To understand the fundamental concepts of photochemistry.
UNIT - I Chemical Kinetics I:
Chain reactions and its general characteristics. Study of kinetics of chain reactions
like H2-Br2 reaction, decomposition of acetaldehyde and N2O5. Study of H2-O2 explosive
reactions.
Unimolecular reaction rate theories – the simple Lindemann treatment,
Hishelwood‘s theory, Rice, Ramsperger and Kassel(RRK) theory, Marcus theory or Rice,
Ramsperger, Kassel and Marcus (RRKM) theory and Slater‘s theory. Principle of
microscopic reversibility and detailed balancing, Kinetic isotope effect. Reactions in solution
– influence of solvent dielectric constant, ionic strength (Bronsted- Bjerrum equation –
primary and secondary salt effects).
UNIT- II Chemical Kinetics II
Fast reactions techniques – chemical relaxation methods, temperature and pressure
jump methods, ultrasonic absorption technique, reactions in flow system, continuous and
stopped flow, shock wave tube methods; chemical kinetics in crossed molecular beams and
Flash photolysis.
SRNMC Regulation-2016 Syllabus
UNIT - III Surface Chemistry
Introduction- adsorption of gases on solids- physisorption and chemisorptions –
adsorption isotherms- Freundlich-Langmuir, BET and Temkin adsorption isotherms – surface
tension-Gibbs adsorption isotherm-surface area determination–monolayer-preparation of LB
films – micelles - critical micellar concentration (CMC)-structure- reverse micelles-micro
emulsion.
UNIT - IV Biophysical Chemistry
Basic concept of non-equilibrium thermodynamics, Onsager reciprocal relationship
– Its application to biological systems. High energy metabolites – ATP and its role in
bioenergetics, transfer of potential and coupled reaction. Biological energy conversion in
catabolism and anabolism – Biophysical applications of Mossbauer Effect, NMR imaging.
Applications of spin labeling in membrane research – Molecular recognition.
UNIT - V Photo- and Radiation Chemistry :
Physical properties of the electronically excited molecules – excited state dipole
moments, pKa and redox potentials –photo physical processes in electronically excited
molecules – Fluorescence, phosphorescence and other deactivating processes. Stern - Volmer
equation and its applications – electronic energy transfer mechanisms – photosensitization
and chemiluminescence, Experimental techniques in photochemistry – light sources –
chemical actinometry – elementary aspects of photosynthesis, photochemical conversion and
storage of solar energy. Radiation chemistry – source of high energy – interaction of high
energy radiation with matter – radiolysis of water. Experimental techniques of radiation
chemistry- Dosimeter .
Text Book- 1
Title of the book : Chemical Kinetics
Name of the Author : K.J.Laidler
Publisher : Pearson Education Private Ltd, Delhi
Edition/Year : 3 /2004
SRNMC Regulation-2016 Syllabus
Text Book- 2
Title of the book : Fast Reactions
Name of the Author : J.N.Bradley
Publisher : Clarendon Press Oxford
Edition/Year : 1975
Text Book- 3
Title of the book : Advanced Physical chemistry
Name of the Author : Gurdeep Raj
Publisher : Goel Publishing Co,Meerut.
Edition/Year : 30 /2004
Text Book- 4
Title of the book : Fundamentals of Biochemistry
Name of the Author : J.N.Jain
Publisher : S.Chand & Company Ltd, New Delhi
Edition/year : 6 / 2005
Text Book- 5
Title of the book : Fundamentals of Photochemisty
Name of the Author : K.K. Rohatgi Mukherjee
Publisher : New age International (P) Limited
Edition/Year : 2 /2006
Text Book- 6
Title of the book : Essential of Nuclear chemistry
Name of the Author : H.J.Arnikar
Publisher : New Age International Publishers
Edition/Year : 4 /2005
Unit-I (From Text Book-1)
Chapter-3(Page No.59-61)
Chapter-4(Page No.129-131)
Chapter-5(Page No.150-167)
Chapter-6(Page No.191-201)
Unit-II (From Text book-2)
Chapter-4(Page No.33-36)
Chapter-5(Page No.47-52)
Chapter-8(Page No.79-85)
Chapter-9(Page No.89-90)
Chapter-11(Page No.112-115)
Unit-III (From Text book-3)
Chapter-16(Page No. 873-880, 882-894. 905-909)
Chapter-17(Page No. 952-954, 1017-1021, 1028-1030)
Unit-IV (From Text book-4)
Chapter-20(Page No. 348-366)
Unit- V (From text book -5)
Chapter - 4 (Section 4.7 to 4.9)
SRNMC Regulation-2016 Syllabus
Chapter - 5 (section 5.1)
Chapter - 9 (section 9.5)
Chapter -10 (section 10.1)
(From text book -6)
Chapter -11 (section 11.1 to 11.7.5)
Reference Book-1
Title of the book : Advanced Physical chemistry
Name of the Author : D.N. Bajpai
Publisher : S.Chand &Company Ltd, New Delhi.
Edition/Year : 1 /1992
Reference Book-2
Title of the book : Principles of Physical chemistry
Name of the Author : B.R.Puri, L.R.Sharma,M.S.Pathania
Publication : Vishal publishing Co,New Delhi.
Edition/ year : 45 /2012
Reference Book-3
Title of the book : Physical chemistry on Surfaces
Name of the Author : A.W.Adamson
Publisher : John Wiley &Sons, New York
Edition/Year : 5 /1990
Reference Book-4
Title of the book : Principles of Biochemistry
Name of the Author : A.L.Lehninger
Publisher : CBS Publication,New Delhi
Edition/year : 1/1984
Reference Book-5
Title of the book : Advanced Physical chemistry
Name of the Author : D.N. Bajpai
Publisher : S.Chand &Company Ltd, New Delhi.
Edition/Year : 1 /1992
Prepared by :
Signature :
SRNMC Regulation-2016 Syllabus
SRI S.RAMASAMY NAIDU MEMORIAL COLLEGE
(An Autonomous Institution Re-accredited with ‗A‘ Grade by NAAC)
SATTUR-626 203.
Department of Chemistry
(For those who joining in 2016-2017 and after)
SYLLABUS
Programme : M.Sc ., Chemistry Subject Code :P16CHE41
Semester : IV No. of Hours allotted : 6 / week
Subject : paper XIX Major Elective IV (a) No. of Credits : 4
Title of the Paper : INTRODUCTION TO NANOSCIENCE
Objectives :
To understand the basic concept of nano science.
To study the synthesis and applications of nano chemistry.
To know about the characterization of nano materials.
UNIT : I General Introduction
Forms of Matter – Crystal structures –electronic properties of atoms and solids –
surface energy and surface tension – defining nanodimensional materials – 0D, 1D and 2D
nanostructures – size dependence of properties – special properties resulting from
nanodimensionality – potential use of nanomaterials.
UNIT : II Synthesis of nanomaterials
General approaches – nucleation process – sizes of the crystal – influence of
nucleation rate on the size of the crystal – chemical methods – Sol-gel techniques – control of
grain size – Co- precipitation - hydrolysis – sonochemical method – colloidal precipitation –
bottom up and top down approaches – kinetically confined synthesis of nanoparticles.
UNIT :III Principle and Instrumentation
Spectrophotometry, XRD, EXAFS, XPS, SEM, TEM, AFM – application to
nanomaterials characterization.
SRNMC Regulation-2016 Syllabus
UNIT : IV Optical properties of nanomaterials:
UV-Vis, IR absorption – photoluminescence and stimulated emission – nonlinear
optical mixing – photo conductivity Magnetic properties: concepts of dia-, para-, and ferro-
magnetism – exchange correlation – exchange interaction. Electrical properties: electrical
conductivity – Hall effect – charge carrier density – activation energy; electronic properties –
field emission properties.
UNIT: V Biological nanomaterials:
Sizes of building blocks – proteins – DNA double nanowire – enzymes – protein
synthesis – Micelles and vesicles – Biomimetic nanostructures – Worm micelles and Vesicles
from block copolymers.
Text books
Text Book- 1
Title of the book : Introduction to Nanotechnology
Name of the Author : C.P. Poole
Publisher : John Wiley & Sons, INC.
Edition/Year : 1 /2012
Text Book- 2
Title of the book : Nano: the Essentials
Name of the Author : T. Pradeep
Publisher : Mc Grow-Hill Education, Delhi.
Edition/Year : 1 /2008
Text Book- 3
Title of the book : Nanotechnology
Name of the Author : Mick Wilson
Publisher : Oversaes India pvt Ltd
Edition/Year : 1/2008
SRNMC Regulation-2016 Syllabus
Unit-I (From Text Book-1)
Chapter – 2 (Page No. 8-21)
Unit-II (From Text Book-3)
Chapter – 3 (Page No.56-70)
Unit-III (From Text Book-2)
Chapter – 2 (Page No. 15-75)
Unit-IV&V (From Text Book-1)
Chapter – 4 ( Page No.80-93)
Chapter – 12 ( Page No.310-329)
Reference Book
Title of the book : The Chemistry of Nano Materials
Name of the Author : C.N.R.Rao
Publisher : Wiley-VCH –Verlag Gmoh and co
Edition/Year : volumes 1and 2 /1980
Reference Book
Title of the book : NanoTechnology
Name of the Author :S.Shanmugam
Publisher : NJP Publisher
Edition/Year : 1/2011
Prepared by :
Signature :
SRNMC Regulation-2016 Syllabus
SRI S.RAMASAMY NAIDU MEMORIAL COLLEGE
(An Autonomous Institution Re-accredited with ‗A‘ Grade by NAAC)
SATTUR-626 203.
Department of Chemistry
(For those who joining in 2016-2017 and after)
SYLLABUS
Programme : M.Sc ., Chemistry Subject Code :P16CHE42
Semester : IV No. of Hours allotted : 6 / week
Subject : paper XIX Major Elective IV (b) No. of Credits : 4
Title of the Paper : POLYMER CHEMISTRY
Objectives:
To understand the chemistry of polymerization.
To study about the utility of polymers in various field.
To know about the processing of polymers.
UNIT I : Classification of Polymers and Chemistry of Polymerisation
Classification of polymers: linear polymers, non-linear or branched polymers,
cross - linked polymers, homo chain hetero chain, homopolymers co-polymers block
polymers and graft polymers.
Chemistry of polymerisation: Types of polymerization – mechanism – chain,
growth, free radical, ionic, co-ordination, ring opening, metathetical, group transfer,
polyaddition and polycondensation polymerizations.
UNIT II : Individual Polymers
Individual polymers: Monomers required general methods of preparation, repeat
units and uses of the following polymers and resins - polyethylene, polystyrene,
polyacryloniltrile, polymethylmethacrylate, PVC, polytetra - fluoroethylene, polybutadienes
and polychloroprene, polyesters, polycarbonates, polyimides, polyamides (Kevlar),
polyurethanes, polyethylene, glycols, phenol - formaldehyde, urea- formaldehyde, melamine
– formaldehyde and epoxy resins.
UNIT III: Properties of Polymers
Intrinsic properties – processing properties – basic idea of isomerism of polymers –
configuration of polymer chain – geometrical structure - syndiotatic, isotatic and atatic
polymers.
SRNMC Regulation-2016 Syllabus
Glass transition temperature: Definition – factors affecting glass transition
temperature – relationships between glass transition temperature and (a) molecular weight,
(b) melting point and (c) plasticizer – importance of glass transition temperature –
heat distortion temperature.
Molecular weight and size of polymers : Number average, weight average,
sedimentation and viscosity average molecular weights – molecular weights and degree of
polymerisation– poly dispersity – molecular weight distribution in polymers – size of
polymer molecules – kinetics of polymerization.
UNIT IV: Polymerisation Techniques Degradation and Uses of Polymers
Polymerisation Techniques: Bulk, solution, suspension, emulsion, melt
condensation and interfacial polycondensation polymerizations. Degradation: Types of
degradation – thermal, mechanical, ultrasonic and photodegradation – photo stabilizers –
oxidative degradation – antioxidants – hydrolytic degradation. Uses of polymers in
electronics and biomedicine.
UNIT V : Polymer Processing
Polymer processing: plastics (thermo and thermosetting), elastomers, fibres,
compounding, plasticizers, colorants, flame retardants. Compression and injection mouldings
– film extrusion and calendaring – die casting and rotational casting- thermofoaming –
reinforcing.
Text books
Text Book- 1
Title of the book : Polymer Science
Name of the Author : V.R.Gowarikar, N.V.Viswanathan and Jayadev Sreedher, ―
Publisher : Wiley Eastern Ltd., New Delhi
Edition/Year : 4 /1986
Text Book- 2
Title of the book : Principles of Polymer science
Name of the Author : N.V.Sastry
Publisher : Narosa Publishing House
Edition/Year : 2 / 2005
SRNMC Regulation-2016 Syllabus
Unit-I (From Text Book - 1)
Chapter – 1 (Page No 12-14)
Chapter – 2 (Page No 15-71)
Unit-II (From Text Book-1)
Chapter – 4 (Page No 105-121)
Unit-III (From Text Book-1)
Chapter – 3 (Page no 86 to 97)
Chapter – 6 (Page No150 to172)
Unit-IV (From Text Book-1)
Chapter – 2 (Page no: 71-85)
Chapter – 10 (Page no: 264-289)
Unit-V (From Text Book -1)
Chapter – (Page No.206-219)
Reference Books
Reference Book-1
Title of the book : Text book of polymer science
Name of the Author : F.W.Billmeyer
Publisher : JohnWiley and sons,New York
Edition/Year : 3/1984
Reference Book-2
Title of the book : Text book of polymer chemistry
Name of the Author : B.K.Sharma
Publisher : Goel pub,House, Meerut.
Edition/Year : 1/1989
Reference Book-3
Title of the book : Text book of Introductory polymer chemistry
Name of the Author : G.S.Mistra
Publisher : New Age International pub , New Delhi
Edition/Year : 1/2005
Prepared by :
Signature :
SRNMC Regulation-2016 Syllabus
SRI S.RAMASAMY NAIDU MEMORIAL COLLEGE
(An Autonomous Institution Re-accredited with ‗A‘ Grade by NAAC)
SATTUR-626 203.
Department of Chemistry
(For those who joining in 2016-2017 and after)
SYLLABUS
Programme : M.Sc .,Chemistry Subject Code :P16CHPT41
Semester : IV No. of Hours allotted : 6 / week
Subject : Paper XX No. of Credits : 4
Title of the Paper : Project Work and Viva-Voce
Objectives
To develop the ability of the students to prepare a project.
To get clear idea about the new concepts in our field apart from the syllabus.
Regulations for the Project Report
Evaluation method for project:
Max. Marks Credits
Internal External
Project Evaluation 40 40
Viva Voce 20
Total 100 4
1. 50% of the aggregate (Project Evaluation + Viva Voce+ Internal)
2. No separate pass minimum for internal.
3. 27 marks out of 60 is the pass minimum for the External.
Internal examiners are the respective supervisors.
Viva voce examination to be evaluated by the external examiner.
The report of the project must be in the prescribed form. It should be typed neatly in
MS word with the equation editor or using Latex. The font size of the letter should be
13 or points with double space.
SRNMC Regulation-2016 Syllabus
The format of the project should have the following components.
First page should contain:
Title of the project report.
Name of the candidate
Register number.
Name of the supervisor.
Address of the institution
Month and year of submission.
1. Contents.
2. Declaration by candidate
3. Certificate by supervisor
4. Acknowledgement
5. Preface
6. Chapter 1 – Preliminaries.
7. Other chapters
8. References
The number of pages in the project may be 40 to 50
Each page should contain atleast 18 lines.
Four copies of the project report with spiral binding should be submitted.
Prepared by :
Signature :
SRI S.RAMASAMY NAIDU MEMORIAL COLLEGE
SRNMC Regulation-2016 Syllabus
(An Autonomous Institution Re-accredited with ‗A‘ Grade by NAAC)
SATTUR-626 203.
Department of Chemistry
(For those who joining in 2016-2017 and after)
SYLLABUS
Programme : M.Sc .,Chemistry Subject Code :P16CHX41
Semester : IV No. of Hours allotted : 6 / week
Subject : Paper XX No. of Credits : 4
Title of the Paper : Extra credit Paper
Objectives:
To create an awareness of the NET/SET Examination
To make the students prepared for NET / SET Examinations
Unit I
i) Periodic properties – Atomic radius – ionic radius, ionization potential, electron
affinity and electronegativity – Their significance in chemical bonding.
ii) VB theory, MO theory – applications – Comparision of VB and MO theories –
VSEPR theory –Bond order – Bond energy – Bond length Bond polarity – Partial
ionic character of bonds – The conceptof multi-centre bond – Electron deficient
compounds – Hydrogen bond – Its influences.
iii) Non aqueous solvents – A general study of typical reactions in non aqueous
media – comparison with reactions in aqueous media.
iv) Nuclear – chemistry – Nuclear structure – Nuclear forces –Nuclear stability –
Nuclear modes – Modes of Radioactivity decay. Nuclear Reaction- fission and
fusion
v) Orgnometallic compounds – Metallecences – Arene complexes – Non aromatic
olefins and acetylenes complexes – catalysis by organometallic compounds
Wilkinson‘s catalyst – Oxoprocess –wacker process – Ziegler – Natta catalysis.
Unit II
i) Optical activity and concept of chirality – Different kinds of optically active
compounds – Absolute configuration - R and S Notations– Methods with more
than one chiral center – Asymmetric synthesis.
ii) Geometrical isomerism resulting from double bonds – The E.Z. system of
nomenclature –Geometrical isomerism of monocyclic compounds and fused ring
systems – Stereospecific and stereo selective reactions with examples.
SRNMC Regulation-2016 Syllabus
iii) Organic reaction mechanisms – Aliphatic nucleophilic substituion SN1 and SN2
– stereo chemistry of nucleophilic reaction –Elimination reactions E1, E2, E1cB
Mechanism – dehydration of alcohols – dehydro halogenation – cope
elemination.
iv) Reagents in organic synthesis - DCC, DDQ ,selenium dioxide ,phase transfer
catalyst, LDA – Rearrangements:- Lossen, Schmitts, Baeyer – Villiger, Pinacol –
Pinacolene, Benzoil –Benzilic acid, Benzidine, Favorski and fries rearrangements
– sigmatropic rearragements – claisen and cope rearragements. Pericyclic
reactions, selection rules – orbital symmetry – Electrocyclic reactions – cyclic
additions - sigmatropic reactions.
Unit III
i) The old quantum theory – black body radiation – Photo electric effect –
Hydrogen spectrum – Compton effect- de Broglie equation – Heisenberg‘s
uncertainty principle – Postulates of quantum mechanics – Schrödinger
equation – Operator algebra – Linear and Hermitian operators –Eigen
functions and Eigen values – Hamiltonian operators – Angular momentum.
ii) Symmetry elements and symmetry operations – Point groups – reducible and
irreducible representations, characters tables – Orthogonality theorem and its
consequences. Symmetry selection rule for IR and Raman spectra -
symmetries of normal modes of vibration – symmetry applied to MO theory
and orbital hybridization.
iii) Thermodynamic equations of state – closed and open systems – partial molar
quantities –chemical potential with temperature and pressure – third law of
thermodynamics. Fugacity – methods of determination – activity and activity
co-efficient – Maxwell‘s distribution of molecular velocities – derivation of
expression for average, most probable and root mean square velocities –
Microstates Macro states – partial functions – Sacker tetrode equation.
iv) Hammett acidity function –Acid base catalysis Bronsted relation- Enzyme
catalysis – Michaelis Menton Law – influence of PH and temperature. Surface
phenomenon – Heterogeneous catalysis – Adsorption isotherms.
v) Electrolytic conductance – applications – solubility product – Inter ionic
attraction theory – Debye- Huckel – Onsager equation – equivalent
SRNMC Regulation-2016 Syllabus
conductivity of electrolytes. Electrode potentials – Electrochemical cells –
electrode – electrolyte interface – electrical double layer electro capillary
phenomena – electro kinetic Phenomena – Membrane potential – Polarisation
–Butler-Volmer equation.
Unit-IV
i) UV Spectroscopy: Principle - absorption spectra of conjugated dienes – α,β -
unsaturated carbonyl compounds – Woodward- Fieser rules - Scott‘s rules for
aromatic carbonyls.
ii) IR Spectroscopy: Molecular vibrations – vibrational frequency - factors
influencing group frequencies – quantitative studies.
iii) 1H NMR spectroscopy: Theory of NMR – chemical shift- factors affecting
chemical shift, spin-spin coupling – coupling constant – spin-spin splitting –
simplification of complex spectra –double resonance – lanthanide shift reagents,
chiral resolving reagents – nuclear overhauser effect – NMR concept of
aromaticity.
iv) Mossbauer Spectroscopy: Mossbauer effect- resonance absorption-Doppler effect-
Doppler velocity –isomer shift-magnetic hyperfine splitting-application of
Mossbauer spectroscopy in the study of iron and tin complexes.
v) ESR Spectroscopy: Principle –presentation of the spectrum –hyperfine splitting-
evaluation of g values –factors affecting the magnitude of g –values-Zero field
splitting –Kramer's degeneracy---application of ESR in the study of transition of
metal complex
Unit V
SRNMC Regulation-2016 Syllabus
i) Basic idea of nanoscience–Dimensional control in nano structures-,1D,2D and 3D
nano structures , synthesis of nano materials -chemical method, sol gel -Chemical
vapour deposition- Ball milling-plasma Arcing- electrodeposition- Thermolysis
ii) Carbon nanotubes: structure and characterization of single walled carbon nano
tubes-properties and applications of nano tubes.
iii) Nano polymers:Conductive polymer and Block copolymer.
iv) Twelve basic principles of green chemistry, green starting materials, green catalyst
and reagents -green solvents –applications of supercritical fluids, ionic liquids and
water – solvent free techniques- Non-conventional microwave heating - interaction
of microwave radiation with the material-difference between conventional heating
and microwave heating.
Text Books:
Text Book:1
Title of the book : Inorganic Chemistry.
Name of the Author : James E. Huheey , Ellen A. Keitler and Richard L. Keitler,
Publisher : Harper Collins College Publishers
Edition/Year : 4/2006
Text book-2
Title of the book : Principles of Physical chemistry
Name of the Author : B.R.Puri, L.R.Sharma,M.S.Pathania
Publication : Vishal publishing Co,New Delhi.
Edition/ year : 45 /2012
Text book-3
Title of the book : Reaction mechanism and reagents in organic chemistry
Name of the Author : G.R.Chatwal
Publisher : Himalaya publishing house,
Edition/Year : 5 / 2012
Text Book- 4
Title of the book : Elementary organic spectroscopy principles and
chemical applications Name of the Author : Y.R.Sharma
Publisher : S.Chand and company Ltd, New Delhi
Edition/Year : Reprint / 2012
Reference Book:1
SRNMC Regulation-2016 Syllabus
CSIR-UGC NET/JRF/SET Chemical sciences - Hemant Kulshrestha, Ajay Taneja,
2010,Upkar‘s Publication.
Reference Book:2
CSIR-UGC NET/JRF/SET Chemical sciences - Helder, Trueman‘s Specific series(2012)
Prepared by:
Signature :
CHAIRMAN DEAN
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