minutes of technical committee meeting held on 06/10/2016 · in next batch. so there is no w/w...
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Minutes of Technical Committee Meeting held on 06/10/2016
A meeting of Technical Committee (TCM) of the Board was held on 06/10/2016 at 11:00 hrs in
the chairmanship of Hon’ble chairman, GPCB at the Committee Room of Gujarat pollution
control Board, Gandhinagar. List of the members, officials and participants who remained
present in the meeting is annexed herewith as Annexure A.
Following agenda regarding change in product mix were discussed in the meeting:
1. M/s. Hem Paints Pvt Limited, VIll. Hasanpar, Ta. Wankaner, Dist..
The unit has applied for CTE change in product mix. It is a Paints & Alkyd Resin manufacturing unit. The unit has proposed to regroup existing paint products into two groups viz. Water based paints & Solvent based Paints as under:
Existing Proposed
Sr. No.
NAME OF PRUDCTS
CAPACITY (MT/M)
NAME OF PRUDCTS CAPACITY(MT/M)
1 Alkyd Resin 300.00 Alkyd Resin 300.00
2 Primer 600.00 Solvent Based Paint (Primer and/or Enamel Paint )
825.00 3 Enamel Paint 225.00
4 Distemper 2000.00 Water Based Paint (Distemper and/or Cement Paint)
2125.00 5 Cement Paint 125.00
Total 3250.00 Total 3250.00
Unit presented data of raw material for worst case scenario as decided in Last meeting. Unit has also presented that waste water mainly generates from washing of vessels in Distemper & Cement Paint mfg. Plant. Which is treated in ETP & used for Plantation. In Primer & Enamel paint mfg. plant, washing of vessels done with Solvent which is reused in next batch. So there is no w/w generation from this Plant.
After detailed deliberations, committee unanimously decided to permit regrouping of existing products into propose products as mentioned in above table with following conditions:
1. There should not be increase in production quantity 2. There should not be increase in pollution load.
3. There should not be addition of any new plant & machinery.
Committee has granted this agenda with above recommendation
2. M/s Bharat Rasayan Ltd, (PCB ID-33612), Plot No. 42/4, GIDC Estate Dahej, Dist- Bharuch.
The unit had applied for CTE change in product mix. It is pesticide technical manufacturing unit. The unit has proposed to discontinue existing some products, changing production capacity of remaining some existing products and proposed to add new products with same production capacity i.e. 12300 MT/Annum. List of proposed change product mix is as under as per Table O.
There is no any change in water consumption and waste water generation. There will not be change in fuel or flue gas or process gas stack-emission. Hazardous waste ( By-product) generation is decreased by 4 MT/year. Existing solvent recovery system shall be used.
This case was discussed in last TCM dated 26-04-2016 & unit was asked to submit the detail. Unit has submitted the required following detailsAA.
(a) To make groups of products (b) Majority of by products will be covered in hazardous waste (c) Certificate from Agricultural department to be submitted. (d) Production detail of last five years to be submitted
Table O PROPOSED PRODUCT LIST AFTER PROPOSED CHANGE IN PRODUCT MIX
Sr. No.
Product Name Production Capacity in MT/Annum Remarks
Existing Consented Capacity (Group-1)
Existing Consented Capacity (Group-2)
Proposed change in
Product mix (Group-3)
1. Acetamipride Technical 140 250 100 Change in existing capacity
2. Alpha Cypermethrin Technical
200 200 100 Change in existing capacity
3. AMBAD (N) 0 0 25 New Product
4. Bifenthrin Technical 100 100 100 No change
5. Buprofezin Technical 240 240 140 Change in existing capacity
6. Butachlor Technical 100 100 0 Discontinued
7. Chlorpyrifos Technical 2810 1910 910 Change in existing capacity
8. Chlorpyrifos Methyl Technical
240 240 100 Change in existing capacity
9. ClodinafopPropargyl Technical
100 200 250 Change in existing capacity
10. Cypermethrin Technical 510 250 400 Change in existing capacity
11. Chlorimuron Ethyl Technical 95%
0 0 10 New Product
12. Cartap Hydrochloride Technical
260 60 0 Discontinued
13. Diafenthiuron Technical 0 250 300 Change in existing capacity
14. Propanil Technical 0 10 50 Change in existing capacity
15. Dichlorvas Technical 600 600 150 Change in existing capacity
16. Diuron Technical 900 900 900 No change
17. Difenconazole Technical 0 0 50 New Product
18. DCAP (N) 0 0 25 New Product
19. Ethion Technical 550 550 700 Change in existing capacity
20. Fenvalerate Technical 400 200 200 No change
21. Fipronil Technical 60 60 60 No change
22. Fenpyroximate Technical 0 15 15 No change
23. Glyphosate Technical 50 50 50 No change
24. Hexaconazole Technical 0 75 150 Change in existing capacity
25. Isoprothiolin Technical 96% 0 0 100 New Product
26. Imidachloprid Technical 100 500 250 Change in existing capacity
27. Indoxacarb Technical 60 60 20 Change in existing capacity
28. Isoproturon Technical 100 25 0 Discontinued
29. Imazethapyr Technical 97% 0 0 50 New Product
30. Lambda Cyhalothrin Technical
300 600 600 No change
31. MetaphenoxyBenzaldehyde 1500 1500 2200 Change in existing capacity
32. Metaphenoxy Benzyl Alcohol
200 200 400 Change in existing capacity
33. Metsulphuron Methyl Technical
20 20 20 No change
34. Metribuzine Technical 300 300 300 No change
35. Myclobutanil Technical 0 15 15 No change
36. Novaluron Technical 0 10 10 No change
37. Propargite Technical 0 25 25 No change
38. Paraquat Technical 100 100 43 Change in
existing capacity
39. Prallethrin Technical 0 25 25 No change
40. Profenofos Technical 0 200 200 No change
41. Pendimethalin Technical 450 150 600 Change in existing capacity
42. Phenthoate Technical 400 400 400 No change
43. Permethrin Technical 250 250 250 No change
44. Pretilachlor Technical 600 100 100 No change
45. Propiconazole Technical 0 150 150 No change
46. Pyrazosulfuron Ethyl Technical 97%
0 0 25 New Product
47. CloquintocetMexyl Technical (Safener Technical)
50 50 50 No change
48. Sulfosulfuron Technical 10 20 20 No change
49. Tricyclazole Technical 0 200 200 No change
50. Transfluthrin Technical 0 50 60 Change in existing capacity
51. Triazophos Technical 0 300 100 Change in existing capacity
52. Temephos Technical 100 100 50 Change in existing capacity
53. Thiamethoxam Technical 260 450 600 Change in existing capacity
54. Triclopyr Technical 240 240 50 Change in existing capacity
55. Tebuconzole Technical 93%
0 0 100 New Product
56. TSBN 0 0 50 New Product
57. Flumethrin Technical 0 0 15 New Product
58. Imiprothrin Technical 0 0 8 New Product
59. Metofluthrin Technical 0 0 4 New Product
60. Amitraz Technical 0 0 60 New Product
61. Flumethic Acid 0 0 15 New Product
62. Bromobenzene 0 0 250 New Product
63. Propoxy Ethyl Chloride 0 0 100 New Product
Total 12300 12300 12300
Formulation Products
1. Pesticides Formulation (Solid)
6000 6000 No change
2. Pesticides Formulation (Liquid)
6000 6000 No change
By-Product List:
Sr. No.
Type of Waste Category (As per
Schedule-I)
Generation MT/year Mode of Treatment & Disposal Existing Total after
change in product mix
1. Spent acid, Dilute sulfuric Acid and Hydrochloric Acid
D-2 12287 8207 Collection, Storage, Transportation, disposal by selling to Actual end user.
2. Ammonium Sulphate solution
C-1 254 330 Collection, Storage, Transportation, disposal by selling to Actual end user.
3. Benzyl Alcohol C-8 19 6 Collection, Storage, Transportation, disposal by selling to Actual end user.
4. Potassium Chloride Solution
B-30 5307 6536 Collection, Storage, Transportation, disposal by selling to Actual end user.
5. Potassium Chloride Solids
600
6. Aq. Alum (Aqueous Aluminum Chloride Solution)
B-30 5744 11001 Collection, Storage, Transportation, disposal by selling to Actual end user.
7. Sodium Bromide Solution
B-30 2431 2620 Collection, Storage, Transportation, disposal by selling to Actual end user.
8. Potassium Bromide Solution
B-30 2895 1582 Collection, Storage, Transportation, disposal by selling to Actual end user.
9. Sodium Sulfite Solution B-30 7393 2807 Collection, Storage, Transportation, disposal by selling to Actual end user.
10. Sodium Sulfite Solids 706
11. Sodium bi sulfide (Sodium Hydrogen Sulfide) Solution
C-13 167 1018 Collection, Storage, Transportation, disposal by selling to Actual end user.
12. Methyl Chloride B-11 137 35 Collection, Storage, Transportation, disposal by selling to Actual end user.
13. 3-Chloro Propino Nitrile B-11 547 177 Collection, Storage, Transportation, disposal
by selling to Actual end user.
14. Ortho Nitro Cumene + Meta Nitro Cumene
B-14 94 0 Collection, Storage, Transportation, disposal by selling to Actual end user.
15. Mix solvents and formaline
20.2 53 593 Collection, Storage, Transportation, disposal by selling to Actual end user.
16. Di-methyl amine (DMA)Solution 40%
B-17 193 196 Collection, Storage, Transportation, disposal by selling to Actual end user.
17. Hydrobromic Acid D-2 0 847 Collection, Storage, Transportation, disposal by selling to Actual end user.
18. Acetic Acid D-6 0 7 Collection, Storage, Transportation, disposal by selling to Actual end user.
19. Methane Sulphonic Acid
D-6 0 22 Collection, Storage, Transportation, disposal by selling to Actual end user.
20. ST Cypermethric Acid (STCMA)
D-6 0 59 Collection, Storage, Transportation, disposal by selling to Actual end user.
21. Used Catalyst 35.2 0 1.1 Collection, Storage, Transportation, disposal by selling to Actual end user.
22. Dibromobenzene C-8 0 7.2 Collection, Storage, Transportation, disposal by selling to Actual end user.
23. Phosphorous Salt (NaH2PO4)
C-5 0 129.5 Collection, Storage, Transportation, disposal by selling to Actual end user.
24. Methyl Amine solution 40%
B-17 0 30.0 Collection, Storage, Transportation, disposal by selling to Actual end user.
Total 37517
The CTE case was discussed in meeting. After detailed discussion the committee unanimously decided to recommend to grant the CTE – change in product mix proposal with the condition of no increase in pollution load & with following conditions
(1) Unit shall follow spent solvent management guideline framed by board and shall make MoU with offside distillation units. Also submit the prescribed forms as per guideline.
(2) Unit shall not discharge their domestic sewage into soak pit. (3) The by products mentioned in the application if falls as the hazardous waste under
the Hazardous and other waste Rules-2016, the unit shall apply for the amendment of the same to the Board.
3. M/s Hikal Ltd. (PCB ID 15177) Plot No.629/630, GIDC Estate Panoli, Dist- Bharuch –
393002. The unit had applied for CTE change in product mix. It is Pharmaceutical & Pesticide technical manufacturing unit. The unit has proposed to add five new products along with decreasing production capacity of three existing products and discontinuing two existing products with same overall production capacity. There shall be no change in formulation products. List of proposed change product mix is as under as per Table A. There is no any change in water consumption & waste water generation quantity. Unit is member of FETP. Existing utilities will be used. There will not be change in fuel consumption or flue gas stack-emission. There will not be change in process gas stack-emission. There is no change in hazardous waste quantity. There will not be any new plant & machinery installed due to proposed change in product mix. This case was discussed in earlier TCM dated 12-7-2016 & unit was asked to submit the detail. Unit has submitted the required following detailsAA. 1. Each product wise reaction. 2. List of Raw material with quantity, mass balance, water balance for each product. 3. Pollution load for each product. 4. Chemical name of product/ raw material. 5. Instead of codeword, CAS number etc shall be given. 6. Measures to be taken for HCl & NH3 handling.
Table: A PROPOSED PRODUCT LIST AFTER PROPOSED CHANGE IN PRODUCT MIX
Sr. No.
Name of products Total production quantity in MT/Annum Remarks
Existing After Proposed Change in
Product mix
Total
01. QUINLPHOS (TECH) 100 - 100 No change
OR/AND
ETHION (TECH) 100 -50 50 Existing Product
OR/AND
TRIZOPHOS 100 -50 50 Existing Product
OR/AND
KARPHOS 100 - 100 No change
OR/AND
TEMPHOS 200 - 200 No change
OR/AND
3-5 DFA (Di fluro Aniline)
200 -100 100 Existing Product
OR/AND
AF -02 (6-tert-butyl-8-fluoro-2,3-dimethylquinolin-4(1H)-
0 +100 100 Proposed Product
one)
OR/AND
2- Hydroxy Quinoxalin (2-HQ)
0 +100 100 Proposed Product
02. GEMESTER 100 - 100 No change
03. BUP-HCL 100 - 100 No change
04. LACTUM (Buproprion HCl)
1800 - 1800 No change
05. HPP-529 (Ethyl 2-oxo pyro butanoate)
150 - 150 No change
06. HPP-453 (Decoquinate) 150 - 150 No change
07. HPP-799 (Ethyl2-oxo pyro acetate)
60 - 60 No change
08. HPP-913 (CBZ Amide) 100 -100 0 Existing Product
09. LEAVI (Leavetiracatam)
100 -100 0 Existing Product
10. PBA HCL (Phenyl benzyloxy Aniniline.HCl)
50 - 50 No change
11. GABAPENTIN 300 - 300 No change
12. HBS (Hydroxy benzne sulphonamide)
0 +50 50 Proposed Product
13. Diketon 0 +50 50 Proposed Product
14. Pregabalin 0 +100 100 Proposed Product
TOTAL PRODUCTION 3710 3710
SR. N0.
NAME OF PRODUCTS QUANTITY (MT/ANNUM)
EXISTING Granted NOC TOTAL
FORMULATION
1 EKALUX 20 AF 4800 0 4800
EKALUX 25 EC 4800 0 4800
QUINALPHOS 70 ZP 840 0 840
MARVIK 25 EC 360 0 360
POLYTRIN C-44 EC, POLYTRIN 25 C,POLYSTRIN 10 EC
4800 0 4800
CURACRON 50 EC 3000 0 3000
TILT 25 EC 240 0 240
TOPAS 10 EC 180 0 180
RIFIT 50 EC 600 0 600
DUAL 50 EC 1200 0 1200
NUVAN 76 EC 1596 0 1596
FENCRON 20 EC 1128 0 1128
CYMBUSH (25% EC & 10% W/V FOR EXPORT)
1200 0 1200
KARATE (5% EC & 25% W/V EXPORT) 1200 0 1200
KUNGFU 2.5 % EC 1200 0 1200
GRAMAXONE 24% 1800 0 1800
THIOVIT (REPACKING ONLY) 300 0 300
BLUE COPPER (REPACKING ONLY) 300 0 300
TOPIK 15 WP (REPACKING ONLY) 360 0 360
TOTAL FORMULATION 29904 0 29904
The unit submitted the details asked in the last meeting and the presentation was made by the project proponent on the issues raised in the last meeting. The presentation included the details of solvent management also. After detailed discussion the committee unanimously decided to recommend to grant the CTE – change in product mix proposal with the condition of no increase in pollution load & with following conditions (1) Unit shall follow spent solvent management guideline framed by board and shall make
MoU with offside distillation units. Also submit the prescribed forms as per guideline. (2) Domestic waste water shall not be discharged in to soak pit(under ground strata)
4. M/s Pranami Drugs Pvt. Ltd, (PCB ID 15498), Plot No.7209, GIDC Estate Ankaleshwar,
Dist- Bharuch – 393002.
The unit had applied for CTE change in product mix. It is pharma intermediate manufacturing unit. The unit has proposed to add three new products along with discontinue of both existing products with same overall production capacity i.e. 7 MT/M. List of proposed change product mix is as under as per Table B.
There will be no change in water consumption & waste water generation. Existing utilities will be used. There will not be change in fuel or flue gas stack-emission. There will not be change in process gas stack-emission. There is no change in hazardous waste quantity. There will not be any new plant & machinery installed due to proposed change in product mix.
Table B PROPOSED PRODUCT LIST AFTER PROPOSED CHANGE IN PRODUCT MIX
Sr. No.
Consented Product Profile(to be deleted) Proposed new Product Profile
Product Name Qty. (T/Month) Product Name Qty. (T/Month)
1. Lamotrigine Acetate 2 Miconazole Nitrate And/OR
7
2. Ketoconazole Acetate 5 Ondansetron HCl And/OR
3. BromhexineHCl
Total (Maximum) 7 TOTAL (MAXIMUM) 7
The CTE case was discussed in meeting. The project proponent represented the details of the worst case scenario i.e. if the each of the product is manufactured to the tune of maximum quantity i.e.7 Mt/Month. The unit is a member of the ETL-CETP and it sends its effluent there through tankers. After change in product mix there will not be any change in the quantum of the wastewater discharge and COD load. Though the project proponent submitted the Schedule I auditor certificate showing no increase in pollution load, the certificate was not having the details of the worst case scenario there in, after detailed discussion the committee unanimously decided to recommend to grant the CTE – change in product mix proposal subject to submission of the modified certificate of the Schedule I auditor showing the details of the worst case scenario which would be verified by the Unit Head and with the condition of no increase in pollution load & with following conditions (1) Unit shall follow spent solvent management guideline framed by board and shall
make MoU with offsite distillation units. (2) Unit shall not discharge their domestic sewage into soak pit(underground starta).
5. M/s Efkam Organics, (PCB ID 15071), Plot No.4801/A/ 10 & 11, GIDC Estate Ankaleshwar, Dist- Bharuch – 393002.
The unit had applied for CTE change in product mix. It is bulk drug intermediate manufacturing unit. The unit has proposed to add nine new products along with existing four products with same overall production capacity i.e. 48.8 MT/M. List of proposed change product mix is as under as per Table C.
There will be no change in water consumption & waste water generation. Unit is at present ZLD & shall maintain ZLD after change in product mix also. Existing utilities will be used. There will not be change in fuel or flue gas stack-emission. There will not be change in process gas stack-emission. There is no change in hazardous waste quantity. There will not be any new plant & machinery installed due to proposed change in product mix.
Table C PROPOSED PRODUCT LIST AFTER PROPOSED CHANGE IN PRODUCT MIX
Sr.No.
NAME OF PRODUCTS QUANTITY (MT/MONTH)
EXISTING PROPOSED TOTAL
EXISTING PRODUCTS
1. Ammonium Formate 20 20.0 20.0
2. Hexa Methyl Disilazane
3. Para Toluene Sulphonyl Chloride
4. Sodium 2. Ethyl Hexonate
PROPOSED PRODUCTS
1. Methyl 3 – Amino Crotonate -
2. Ethyl Formate
3. 3,5-dimethyl 2,6 dimethyl-4(2-nitrophenyl)-1,4 di hydropyridine-3-5 di carboxylate
4. 2,6-dimethyl-4-(3-nitrophenyl)-1,4-dihydropyridine-3,5-dicarboxylic acid mono
5. 4-Methyl -6(-1-methyl Benzimidazol-2-H)2-n-propyl 1H – Benzimidazole
6. 2 – cyno 4 – bromomethyl biphenyl
7. Ammonium Propionate
8. 1 Chloro Methyl Naphthalene
9 Various new product developed by in house R & D
0.0 0.0
10 Ammonium chloride 13.5 - 13.5
11 Mixer of sodium sulphate, sodium chloride & sulphuric acid
15.3 - 15.3
Total 48.8 - 48.8
The CTE case was discussed in meeting. During discussion, it was revealed that the unit has not given the worst case scenario details along with the certificate of the Schedule I auditor indicating the same. The project proponent was asked to submit the following details: 1. No increase in pollution load certificate with incorporating worst case scenario. 2. List of all raw material with quantity & COD load for existing/proposed scenario. 3. Pollution load for each product (Worst case scenario). 4. Products under R&D head applied are not considered by the committee & instead
its quantum is to be amalgamated with the product mix Quantity.
5. Solvent management details: Existing and proposed solvent details. Whether addition of the new solvent will result in to the increase in the pollution load or refractory COD.
6. Management of the concentrated stream of wastewater. 7. Applicability of new haz/w rules-2016 for the by products.
The case will be discussed in next TCM after successful submission of the
details. 6. M/s Feather Colors Industries, (PCB ID 15818), Plot No.3456, GIDC Estate
Ankaleshwar, Dist- Bharuch – 393002.
The unit had applied for CTE change in product mix. It is dyes intermediate manufacturing unit. The unit has proposed to add eleven new products with discontinuing both existing product with same overall production capacity i.e. 3.4 MT/M. List of proposed change product mix is as under as per Table D.
There will be no change in water consumption & waste water generation. Existing utilities will be used. There will not be change in fuel or flue gas stack-emission. There will not be change in process gas stack-emission. There is reduction in Iron sludge quantity in hazardous waste. There will not be any new plant & machinery installed due to proposed change in product mix.
Table D PROPOSED PRODUCT LIST AFTER PROPOSED CHANGE IN PRODUCT MIX
Sr. No.
NAME OF PRODUCTS QUANTITY (MT/MONTH)
EXISTING PROPOSED TOTAL
EXISTING
1 Meta PhenyleneDiamine (MPD) 3.0 -3.0 0
2 Rhoduline Acid(Red 12 B) 0.4 -0.4
PROPOSED
1 PY-74 (Pigment Yellow-74) 0
+3.4
3.4
2 PY-83 (Pigment Yellow-83)
3 PY-191 (Pigment Yellow-191)
4 PY-12 (Pigment Yellow-12)
5 PY-13 (Pigment Yellow-13)
6 PY-14 (Pigment Yellow-14)
7 PY-17 (Pigment Yellow-17)
8 PY-1 (Pigment Yellow-1)
9 PY-3 (Pigment Yellow-3)
10 PY-65 (Pigment Yellow-65)
11 PY-139 (Pigment Yellow-139)
Total 3.4 0 3.4
The CTE case was discussed in meeting. At present the unit is manufacturing the dyes intermediates. Now, the unit has proposed to manufacture the dyes. This will reduce in the pollution load and the handling of the hazardous chemicals. After detailed discussion the committee unanimously decided to recommend to grant the CTE – change in product mix proposal with the condition of no increase in pollution load & with following conditions. (1) Unit shall follow spent solvent management guideline framed by board and shall make
MoU with offside distillation units. Also submit the prescribed forms as per guideline. (2) Unit shall not discharge their domestic sewage into soak pit.
7. M/s Vaikunth Chemicals, (PCB ID 15838), Plot No.408/4 & 5, GIDC Estate Panoli, Dist-
Bharuch – 393002.
The unit had applied for CTE change in product mix. It is bulk drug manufacturing unit. The unit has proposed to add four new products along with reduction of existing both product with reducing overall production capacity i.e. from 15 MT/M to 12 MT/M. List of proposed change product mix is as under as per Table E.
There will be no change in water consumption. There shall be reduction in waste water generation i.e. from 7.2 KLD to 7.195 KLD. Existing utilities will be used. There will not be change in fuel or flue gas stack-emission. Only NG shall be used as a fuel there will not be change in process gas stack-emission. There is no change in hazardous waste quantity. There will not be any new plant & machinery installed due to proposed change in product mix.
Table E PROPOSED PRODUCT LIST AFTER PROPOSED CHANGE IN PRODUCT MIX
Sr. No
Product Existing MT/month
Proposed additions MT/month
Total after proposed change
MT/month
1 Sodium Citrate 10 0 0
2 Micro Crystalline Cellulose Powder 5 0 0
3 Metoclopramide Hydrochloride 0 (Sr. No:3 to
6)
+ 5 (Sr. No:3 to 6)
5 (Sr. No: 3 to 6)
4 Cetirizine Hydrochloride
5 Ondansetron Hydrochloride
6 Trifluoperazine Hydrochloride
Total 15 -10 5
The CTE case was discussed in meeting. The unit intends to stop the manufacturing the existing products as there is no market for the same and reduction in the proposed production is to match with the existing pollution load. The project proponent requested the committee to reserve their right to retain total 15 Mt/Month of the products for the future if they intend to manufacture low pollution load products in future. The details of the worst case scenario were explained. After detailed discussion the committee unanimously decided to recommend to grant the CTE – change in product mix proposal with the condition of no increase in pollution load & with following conditions (1) Unit shall follow spent solvent management guideline framed by board and shall make
MoU with offside distillation units. (2)Unit shall not discharge their domestic sewage into soak pit.
8. M/s Shivnath Industries, (PCB ID 15640), Plot No.1815, GIDC Estate Panoli, Dist-
Bharuch – 393002.
The unit has applied for CTE change in product mix. It is dyes/dyes intermediate manufacturing unit. The unit has proposed to add five new products along with reduction of two existing product with reducing overall production capacity i.e. from 84 MT/M to 70 MT/M. Unit has bifurcated products in three groups. List of proposed change product mix is as under as per Table F.
There will be no change in water consumption & waste water generation. Existing utilities will be used. There will not be change in fuel or flue gas stack-emission. There will not be change in process gas stack-emission. There is no change in hazardous waste quantity. There will not be any new plant & machinery installed due to proposed change in product mix.
Table F PROPOSED PRODUCT LIST AFTER PROPOSED CHANGE IN PRODUCT MIX
SR NO. NAME OF PRODUCTS QUANTITY (MT/MONTH)
EXISTING PROPOSED TOTAL
1 4-AMINO DIPHENYL SULPHONIC ACID 24 -9 15
4-CAP 0 +10 10
OR
BRONNER'S ACID 0 +21 21
2 G SALT 40 -30 10
SCHAEFFER ACID 0 +15 15
OR
OPSAMIDE 0 +10 10
MIX CLEVE'S ACID 0 +5 5
3 R SALT 20 - 20
TOTAL 84 -14 70
The CTE case was discussed in meeting. The unit is a member of the PETL CETP and send their effluent to the PETL through tanker. After detailed discussion the committee unanimously decided to recommend to grant the CTE – change in product mix proposal with the condition of no increase in pollution load & with following conditions (1) Unit shall not discharge their domestic sewage into soak pit. (2) The unit will segregate the concentrated stream based on COD and TDS parameter
and treat it separately with either own MEE or Common MEE. (3) In no case, the unit will send its concentrated effluent to the PETL. (4) Spent acid shall be given to units having valid permission as per rule-9 (5) Unit shall submit the Schedule-I auditor’s Certificate indicating that in the waste case
scenario there is no increase in pollution load.
9. M/s D.N. Chemicals, (PCB ID 14831), Plot No.6007, GIDC Estate Ankaleshwar, Dist-
Bharuch – 393002.
The unit had applied for CTE change in product mix. It is dyes intermediate manufacturing unit. The unit has proposed to add five new products along with discontinuing seven existing product with reducing overall production capacity i.e. from 540 MT/M to 460 MT/M. List of proposed change product mix is as under as per Table G.
There will be no change in water consumption & waste water generation. Existing utilities will be used. There will not be change in fuel or flue gas stack-emission. There will not be change in process gas stack-emission. There is no change in hazardous waste quantity. There will not be any new plant & machinery installed due to proposed change in product mix.
Table G PROPOSED PRODUCT LIST AFTER PROPOSED CHANGE IN PRODUCT MIX
Sr. No.
NAME OF PRODUCTS QUANTITY (MT/MONTH) Remarks
EXISTING
PROPOSED
TOTAL
1. a).2 Chloro 4-Amino Phenol
(2CAP)
0 40
40
Proposed
product
b).4 Chloro 2-Amino Phenol
(4CAP)
Proposed
product
c).2-Chloro 4-Nitro Phenol
(2CNP)
Proposed
product
d).4-Chloro-2-Nitro Phenol
(4CNP)
Proposed
product
e). 5-Chloro-8-Hydroxyquinoline Proposed
product
f).Ortho Toludine (OT) 80 (-) 80 0 To stop
production
g).Para Toludine (PT) To stop
production
h).2:5 Di Chloro Aniline (2:5
DCA)
To stop
production
i).3:5 Di Chloro Aniline (3:5
DCA)
To stop
production
j).Ortho Chloro Aniline (OCA) To stop
production
k).Meta Chloro Aniline (MCA) To stop
production
2. Alpha Nitro Naphthalene 40 (-)40 0 To stop
production
3. 3:5 Di Chloro Nitrobenzene (3:5
DCNB)
70 - 70 No Change
4. 2:5 Di Chloro Phenol (2:5 DCP) 70 - 70 No Change
5. Meta Nitro Aniline (MNA) 40 - 40 No Change
6. Phenyl Alpha Napthalamine
(PANA)
40 - 40 No Change
7. 2:5 DCNB or 3:4 DCNB or 2:4:5
TCNB or 2:4 DCNB or 2:3
DCNB
200 - 200 No Change
TOTAL 540 (-)80 460
The CTE case was discussed in meeting. The project proponent presented that segregation of the concentrated stream based on the TDS and COD load will be carried out and the concentrated stream will be sent to the CMEE of the BEIL. After detailed discussion the committee unanimously decided to recommend to grant the CTE – change in product mix proposal with the condition of no increase in pollution load & with following conditions (1) Unit will segregate its concentrated stream at source based on COD and TDS and will
treat it through CMEE. In no case the concentrated stream shall be sent to the ETL for the treatment. There shall not be any discharge of industrial effluent in to the underground drainage of the GIDC directly.
(2) Unit shall not discharge their domestic sewage into soak pit.
(3) Separate record shall be maintained for the generation/disposal of high COD & low COD effluent.
10. M/s Suyog Dye Chemie Pvt Ltd (Unit- I), (PCB ID 15789), Plot No.6716-17, GIDC Estate
Ankaleshwar, Dist- Bharuch – 393002.
The unit had applied for CTE change in product mix. It is dyes/dyes intermediate manufacturing unit. The unit has proposed to manufacture anyone of the existing product with same overall production capacity i.e. 29 MT/M or 28 MT/M. So there shall be neither addition of any new product nor delete any exiting product. List of proposed change product mix is as under as per Table H.
There shall be reduction in water consumption from 13.2 KLD to 9.65 KLD, subsequently wastewater generation shall be reduced from 9.5 KLD to 6.23 KLD. Existing utilities will be used. There will not be change in fuel or flue gas stack-emission. There will not be change in process gas stack-emission. There is no change in hazardous waste quantity. There will not be any new plant & machinery installed due to proposed change in product mix.
Table H PROPOSED PRODUCT LIST AFTER PROPOSED CHANGE IN PRODUCT MIX
Sr. No.
Name of Products QUANTITY (MT/MONTH)
EXISTING PROPOSED
1 Reactive Turquoise Blue G (Reactive Blue 21) 20 29 OR
2 Reactive Turquoise Blue H5G (Reactive Blue 25) 5 28 OR
3 Reactive Green 6 (Reactive Blue 38) 3 29 OR
4 Direct Turquoise Blue FBL (Direct Blue 199) 1 28
Total 29 29 (MAX.)
The CTE case was discussed in meeting. It was presented that the product mix consists of the single family existing product. There will not be addition of the new product only the quantum will be changed. The worst case scenario details were presented to the committee. After detailed discussion the committee unanimously decided to recommend to grant the CTE – change in product mix proposal with the condition of no increase in pollution load & with following conditions (1) Unit shall follow spent solvent management guideline framed by board and shall make
MoU with offside distillation units. Also submit the prescribed forms as per guideline. (2) Unit shall not discharge their domestic sewage into soak pit.
11. M/s Jay Overseas, (PCB ID 15243), Plot No. A-2/4002, GIDC Estate Ankaleshwar, Dist-
Bharuch – 393002.
The unit had applied for CTE change in product mix. It is chemical manufacturing unit. The unit has proposed to add new product along with reduction of three existing product with reducing overall production capacity i.e. from 12.5 MT/M to 12.38 MT/M. List of proposed change product mix is as under as per Table I.
There will be no change in water consumption & wastewater generation. Existing utilities will be used. There will not be change in fuel or flue gas stack-emission. There will not be change in process gas stack-emission. There is no change in hazardous waste quantity. There will not be any new plant & machinery installed due to proposed change in product mix.
Table I PROPOSED PRODUCT LIST AFTER PROPOSED CHANGE IN PRODUCT MIX
SR. NO
NAME OF PRODUCTS QUANTITY (MT/MONTH)
EXISTING PROPOSED TOTAL
1 Tri Ethyl Benzyl Ammonium Chloride 10 0 10 2 Glycine (1-Amino Acetic Acid)
3 Tetra Butyl Ammonium Bromide(new product) 0 +10
5 Ammonia (Aqueous) 2.5 -0.12 2.38
Total 12.50 -0.12 12.38
The CTE case was discussed in meeting. The request for the inclusion of R & D product was not considered by the committee. After detailed discussion the committee unanimously decided to recommend to grant the CTE – change in product mix proposal with the condition of no increase in pollution load & with following conditions (1) Unit shall follow spent solvent management guideline framed by board and shall make
MoU with offside distillation units. Also submit the prescribed forms as per guideline. Recovered solvent shall be in house reused in next batch
(2) Unit shall not discharge their domestic sewage into soak pit. (3) Products under R&D head applied are not considered by the committee & instead its
quantum is to be amalgamated with the product mix Quantity.
12. M/s Prayosha Health Care Pvt Ltd, (PCB ID 15502), Plot No. 6209, GIDC Estate
Ankaleshwar, Dist- Bharuch – 393002.
The unit had applied for CTE change in product mix. It is pharma intermediate manufacturing unit. The unit has proposed to add nine new products along with reduction in quantity of one existing product with same production capacity i.e. 348 MT/M. List of proposed change product mix is as under as per Table J.
There will be no change in water consumption & waste water generation. Existing utilities will be used. There will not be change in fuel or flue gas stack-emission. There will not be change in process gas stack-emission. There is no change in hazardous waste quantity. There will not be any new plant & machinery installed due to proposed change in product mix.
Table J PROPOSED PRODUCT LIST AFTER PROPOSED CHANGE IN PRODUCT MIX
Sr. No.
NAME OF PRODUCTS QUANTITY (MT/MONTH)
EXISTING PROPOSED TOTAL
1 Methyl Paraben 15 -12 3
2 Propyl Paraben 5 0 5
3 Sodium Methyl Paraben 7 0 7
4 Sodium Propyl Paraben 3 0 3
5 Ethyl Paraben 1 0 1
6 Butyl Paraben 1 0 1
7 ISO Propyl Paraben 0.5 0 0.5
8 Sodium Butyl Paraben 0.5 0 0.5
9 Sodium Citrate 50 0 50
10 Di Sodium Citrate 20 0 20
11 Mono Sodium Citrate 5 0 5
12 Potassium Citrate 64 0 64
13 Citric Acid ( Mono ) 50 0 50
14 Citric Acid ( Anhydrous ) 50 0 50
15 Sodium Benzoate 29 0 29
16 Tri Sodium Phosphate 10 0 10
17 Di Sodium Phosphate 20 0 20
18 Di Potassium Phosphate 2 0 2
19 MonoSodium Phosphate 1 0 1
20 Levosulpiride or Cilnidipine or Iron ( III ) Hydroxide Poly Maltose complex
14 0 14
21 L-Methyl Folate Propyl Gallate Silodosin or Amisulpiride or Lornoxicam or Benidipine or Teneligliptin or 2-(Aminomethyl)-1-ethylpyrrolidine or Benfothiamine
0 12 12
Total 348 0 348
The CTE case was discussed in meeting. The request of the project proponent for R & D products was not considered by the committee. After detailed discussion the committee unanimously decided to recommend to grant the CTE – change in product mix proposal with the condition of no increase in pollution load & with following conditions (1) Unit shall follow spent solvent management guideline framed by board and shall make
MoU with offside distillation units. Also submit the prescribed forms as per guideline. (2) Fresh solvent will be used directly as a raw material in product; There shall not be any
solvent distillation/recovery system. Two stage condensers shall be installed. If required, the condenser with chilled brine shall be provided for the better solvent recovery and prevention of solvent losses. In no case the solvent recovery shall be less than 90%.
(3) Unit shall not discharge their domestic sewage into soak pit. (4) Products under R&D head applied are not considered by the committee & instead its
quantum is to be amalgamated with the product mix Quantity. 13. M/s SAJJAN INDIA LIMITED, (PCB ID- 15600), Plot No. 6102, 6103, 6117-6119, GIDC
Estate Ankaleshwar, Dist- Bharuch – 393002.
The unit had applied for CTE change in product mix. It is agrochemical, pharma and dyes manufacturing unit. The unit has proposed to increase /decrease existing production with addition of new products and maintaining same total production capacity as 19284 MT/Annum & with deleting two by products & addition of one by product NaBR2. List of proposed change product mix is as under as per Table K.
There will not be any change in water consumption, waste water generation & discharge. Existing utilities will be used. There will not be change in fuel or flue gas stack-emission. There will not be change in process gas stack-emission. There is no change in hazardous waste quantity. There will not be any new plant & machinery installed due to proposed change in product mix.
Table K PROPOSED PRODUCT LIST AFTER PROPOSED CHANGE IN PRODUCT MIX
Existing & Proposed product Products (MT)
Sr.No.
Product Name Existing capacity (MT/A)
Proposed Changes (MT/A)
Proposed capacity
after changes (MT/A)
Proposed capacity
of the product group (MT/A)
1 Benzene Derivatives 5771
N-{2-[(phenylcarbamoyl)amino]phenyl}benzenesulfonamide
840 0 840
2,4,6-Trimethy Benzoyl Chloride 480 0 480
4-Nitro-2-sulphobenzoic Acid Potassium salt 480 (-)100 380
2-Bromo-4-fluoro acetanilide 500 0 500
4[[(2Methoxybenzoyl)amino]sulfonyl] benzoyl chloride
1440 0 1440
Tris (4-Aminophenyl) methane 60 0 60
2,4,6 Trimethyl Pheneyl Acetyl Chloride 120 0 120
2,5-Dimethyl phenyl acetyl chloride 240 0 240
Ortho chloroaniline-5-Carboxylic Acid 80 0 80
3-(trifluoromethyl) acetophenone 480 0 480
2-Methoxyethyl a-cyano-a-[4-(1,1-dimethylethyl)phenyl]-B-oxo-2-(trifluoromethyl)benzene propanoate
240 (-)115 125
4-Chloro-2,6-dimethyl bromobenzene 240 (-)140 100
2- bis (2- Aminophenoxy) ethane 180 0 180
2-Trilfuoromethyl benzamide 240 0 240
5-Amino-2,4-di-tert-butylphenol 36 0 36
Polymeric Yellow 2012 240 (-)90 150
5-chloro-2-methoxy-4-methyl nicotinic acid & 3,4,5-Trimethoxy-toluene
120 0 120
AOX-D 150 0 150
4-Acetyl-2-methylbenzamide (Ambad) 0 50 50
Total 6166 (-)395 5771
2 Benzene Nitro Derivatives 84
2 – Hydroxy – 4 – nitro Benzene Amine 24 0 24
2-Hydroxy-5-Nitro Benzene Amine 36 0 36
4-Amino-3-Nitro Phenyl Ethyl sulphone 24 0 24
Total 84 0 84
3 Benzidines and Alkyl aromatics 1600
3,3'-DImethylbenzidine 300 0 300
3,3’ Dichloro-4,4’ Diamino Diphenyl 480 0 480
3,3’,4,4’-Tetra amino biphenyl 120 0 120
N PROPYL BENZENE 700 0 700
Total 1600 0 1600
4 CPW 940
Chlorinated Paraffin Wax 940 0 940
Total 940 0 940
5 Hetrocyclic Derivatives 2756
3-[1-(3,5-dichlorophenyl)-1-methylethyl]-2,3-dihydro-6-methyl-5-phenyl-4H-1,3-oxazin-4-one and its intermediates
180 0 180
2-Benzyl-2-(Dimethylamino)-4-Morpholino-Butyrophenone and its intermediates
840 (-)140 700
1,3-Dimethyl-5-pyrazolone 120 0 120
1,3-Dimethyl-5-chloropyrazol carbonyl chloride 120 0 120
1,3-Dimethyl-5-fluoropyrazol carbonyl fluoride 96 0 96
2-(4-methylbenzyl)-2-(dimethylamino) -1-(4-morpholinophenyl)butan-1-one
120 0 120
2,6-Dimethyl-,2,3-dihydro-1H-inden-1-one 300 (-)150 150
N-[1,1-dimethyl-2-(4-isopropoxy-o-tolyl)-2-oxoethyl]-3-methylthiophene-2-carboxamide
180 0 180
2,3-Dihydro-3,3-dimethyl-5-benzofuryl ethanesulphonate
120 0 120
3-Amino-2-(1,3-dimethylbutyl)thiophene 120 0 120
1-{1-ethyl-4-{4-mesyl-3-(2-methoxy ethoxy)-o-toluoyl}-1H-pyrazol-5-yloxy}ethyl methyl carbonate
100 0 100
S-sec-Butyl O-ethyl 2-oxo-3-thiazolidinyl phosphonothioate
0 300 300
4-methyl-N-phenyl-6-(1-propynyl)-2-pyrimidinamine
0 50 50
Ethyl (2R)-2-[4(6-chloroquinoxalin-2-yloxy)phenoxy]propionate & (RS)-tetrahydrofurfuryl (R)-2-[4-(6-chloroquinoxalin-2-yloxy)phenoxy]propionate
0 400 400
Total 2296 460 2756
6 Electrolyte 480
Bis(fluorosulfonyl)amide
480 0 480
Total 480 0 480
7 Naphthalene based Dye intermediates 312
4 – Benzoylamino - 5 – Napthol – 2 – 7 Disulphonic Acid
96 0 96
4 – Benzoylamino - 5 – Napthol – 1 – 7 Disulphonic Acid
60 0 60
4 – Hydoxy N – (3 – Sulfophenyl – 2 – Napthylamine – 6- Sulphonic Acid
36 0 36
1 – Napthalene Sulfonic Acid 2 – Amino – 5 – Aminomethyl
72 0 72
Dichloro Phenoxy Acetyl K Acid 48 0 48
Total 312 0 312
8 para quinone derivative 60
Ethyl Trichloro Benzoquinone 60 0 60
Total 60 0 60
9 Pyridine Derivatives 1040
(E)-1,1-dimethylethyl 4-[[[[(1,3dimethyl-5-phenoxy-1H pyrazol-4-yl)methylene]amino]oxy]methyl]benzoate and its intermediates.
120 0 120.0
(3-Ethylsulfonyl)-2-pyridinesulfonamide and its intermediates./2-Ethylsulfonyl-imidazo{1,2-a}pyridine 3-sulfonamide and its intermediates.
120 0 120
3-Chloro-5-trifluoromethylpyridine-2-acetonitrile/5-chloro-2-methoxy-4-methyl nicotinic acid
800 0 800
Total 1040 0 1040
10 Pyrimidine Chloro Derivatives 1560
Trichloro 1,3-Diazabenzene 600 0 600
Tetrachloro 1,3-Diazabenzene 300 0 300
Dichloro-1,3 diazabenzene 240 0 240
Dichloro-Mehtoxy-1,3-diazabenzene 120 0 120
Diamino Chloro 1,3 diazabenzene 300 0 300
Total 1560 0 1560
11 Pyrimidine Derivatives 1124
Amino-Dimethoxy-1,3 Diazabenzene 360 (-)160 200
Dimethoxy-(Phenoxy Carbonyl) Amino)-1,3 diazabenzene
360 0 360
2-Amino-4,6-dimethylpyrimidine 84 0 84
2-Amino-5,8-dimethoxy(1,2,4)triazolo(1,5-C) pyrimidine
60 0 60
5-(1,3-Dioxan-2-yl)-4-(4-trilfuoromethylbenzyloxy)pyrimidine
240 0 240
3-(4-Chloro-2-fluoro-5-mercapto-phenyl)-1-methyl-6-trifluoromethyl-1H-pyrimidine-2,4-dione
180 0 180
0
Total 1284 (-)160 1124
12 Pyrimidine-pyridine Derivatives 640
1-(4,6-dimethoxypyrimidin-2-yl)-3-(3-trifluoromethyl-2-pyridylsulfonyl)urea and its intermediates.
240 0 240
aryl fused pyrimidinedione 400 0 400
Total 640 0 640
13 Quinoxaline Derivatives 21
2 – 3 Dihydroxy Quixoline – 6 – Carboxylic Acid 21 0 21
Total 21 0 21
14 Triazine derivative 180
2-(2,4-dihydroxyphenyl)-4,6-bis(4-biphenyl)-1,3,5-triazine
80 0 80
2-Chloro-4,6-Dimethoxy, 1,3,5 Triazine (CDMT/DTC)
0 100 100
Total 80 100 180
15 Other agro and pharma intermediates
2,5-Dimethoxypyrimidin-4-amine 180 (-)120 60 2715
(1E)-[2-[[6-(2-chlorophenoxy)-5-fluoro-4-pyrimidinyl] oxy]phenyl] and its intermediates.
300 (-)150 150
2-{[(4,6-Dimethoxy-2-pyrimidinyl)carbamoyl]sulfamoyl}-4-formamido-N,N-dimethylbenzamide and its intermediates
240 0 240
3',4'-difluoro-2-aminobiphenyl 180 (-)120 60
isopropyl 2-(4-methoxybiphenyl-3-yl)hydrazinoformate 1-methylethyl 2-(4-methoxy[1,1′-biphenyl]-3-yl)hydrazinecarboxylate and its intermediates
180 (-)120 60
Napthols & bases 240 (-)194 46
O-(2,4-dichlorophenyl)o-ethyl 5-propyl phosphoro dithioate
200 0 200
POCL34 1200 0 1200
2,3 Dimethly-1-Nitroisourea (MNO)
0 250 250
Diethyl Disulfide (DEDS) 0 100 100
4-Methoxycyclohexanone (MOCHON) 0 200 200
1,1 -Carbonyl diazepan -2-One Code: (CBC) 0 149 149
Total 2720 (-)5 2715
19284
BY-PRODUCTS:
Sr. No.
Name of BY-Products Quantity mode of Disposal
Existing MT/Y
Proposed changes
MT/Y
Total after proposed changes
MT/Y
A Captive
1 Xylene 1776.96 0 1776.96 Captive consumption
2 Dichloromethane 8672.53 0 8672.53 Captive consumption
3 Hexane 4341.1 0 4341.1 Captive consumption
4 Methanol 1165.51 0 1165.51 Captive consumption
5 Toluene 11046.56 0 11046.56 Captive consumption
6 Pthalic anhydride 111.96 0 111.96 Captive consumption
7 Chloro benzene 1097.28 0 1097.28 Captive consumption
8 Isopar-G 521.28 0 521.28 Captive consumption
9 2-Bromopropane 241.56 0 241.56 Captive consumption
10 N,N-Dimethylacetamide
2802.6 0 2802.6 Captive consumption
11 DMF 1628.16 0 1628.16 Captive consumption
12 Orthodichlorobenzene 1609.74 0 1609.74 Captive consumption
13 Spent raney nickel 30.6 0 30.6 Captive consumption
14 EDC 2042.88 0 2042.88 Captive consumption
B CAPTIVE/SELL
15 Isopropyl alcohol 5190.36 0 5190.36 Captive consumption/ Sell out to GPCB approved actual users
16 HCL (30%) 2992.45 0 2992.45 Captive consumption/ Sell out to GPCB approved actual users
17 Formic acid 826.8 0 826.8 Captive consumption/ Sell out to GPCB approved actual users
18 Butylacetate 3108.96 0 3108.96 Captive consumption/ Sell out to GPCB approved actual users
19 Inorganic Salt 2620.84 (-)1500 1120.84 Captive consumption/ Sell out to GPCB approved actual users
C SELL
20 Mix Solvent 906 0 906 Sell out to GPCB approved actual users
21 HBr in acetic acid 52.39 0 52.39 Sell out to GPCB approved actual users
22 NaHSO3 5152.74 (-)4000 1152.74 Sell out to GPCB approved actual users
23 Liquid ammonia 388 0 388 Sell out to GPCB approved actual users
23 NaBr Solution 0 5500 5500 Sell out to GPCB approved actual users
The CTE case was discussed in meeting. After detailed discussion the committee unanimously decided to recommend granting the CTE – change in product mix proposal with the condition of no increase in pollution load & with following conditions (1) Unit shall follow spent solvent management guideline framed by board and shall make
MoU with offside distillation units. Also submit the prescribed forms as per guideline. (2) Unit shall not discharge their domestic sewage into soak pit. (3) By products covered under Hazardous and Other Wastes (Management and
Transboundary Movement) Rules, 2016 shall be considered as Hazardous wastes. (4) The unit should strive for the attaining Zero Liquid Discharge and feasibility report and
action plan shall be submitted to the Board. 14. M/s Atul Ltd, (PCB ID 14942), Plot No.297, GIDC Estate Ankleshwar, Dist- Bharuch –
393002.
The unit had applied for CTE change in product mix. It is chemical manufacturing unit. The unit has proposed to merge their two products. There will not be any change in existing/proposed products. No any new product is proposed and no any existing product will be deleted. Hence their total production capacity – 8137.07 MT/M & By products-2000 MT/M will remain same. List of proposed change product mix is as under as per Table M.
There is no any change in water consumption. Unit is at present ZLD & shall maintain ZLD after change in product mix also. Existing utilities will be used. There will not be change in fuel or flue gas stack-emission. There will not be change in process gas stack-emission. There is no change in hazardous waste quantity. There will not be any new plant & machinery installed due to proposed change in product mix.
Table M PROPOSED PRODUCT LIST AFTER PROPOSED CHANGE IN PRODUCT MIX
SR. NO.
NAME OF PRODUCTS PRODUCTION (MT/MONTH)
CONSENTED
PROPOSED
TOTAL
GROUP-1 PRODUCTS
1. CRESOLS- LIQUID AND/OR PARA TOLUENE SULPHONIC ACID-SOLID
1500 2100
2100
600
2. PARA ANISALDEHYDE-LIQUID 700 0 700
3. PARA ANISYL ALCOHOL-LIQUID 200 0 200
4. PARA CRESIDINE-SOLID 50 0 50
5. PARA ANISIC ACID (FROM PARA ANISALDYHYDE PLANT)- SOLID
15 0 15
6. ANISOL (METHOXY BENZENE)-LIQUID 35 0 35
7. ANISYL ACETATE-LIQUID 10 0 10
8. MANGANESE SULPHATE (FROM PARA ANISALDEHYDE PLANT)-SOLID
1100 0 1100
B
MANGANESE SULPHATE (FROM PARA ANISALDEHYDE PLANT)- LIQUID
2000 0 2000
9. 4-METHOXY ACETOPHENON (4-MAP)- LIQUID 50 0 50
10. SODIUM SULPHITE (FROM CRESOL PLANT)-SOLID)
1500 0 1500
GROUP-2 PRODUCTS
11. PARA TOLUENE SULPHONIC ACID-SOLID - - -
12. OCTYL METHOXY CINNAMATE-LIQUID 250 0 250
13. PARA CRESYL ACETATE-LIQUID 1.66 0 1.66
14. PARA CRESYL PHENYL ACETATE-SOLID 3 0 3
15. PARA ANISYL PROPANOL-LIQUID 4 0 4
16. 4-METHOXY PHENYL ACITONITRILE-LIQUID 25 0 25
17. PARA CRESYL CAPRYLATE-LIQUID 1 0 1
18. PARA CRESYL ISOBUTYRATE-LIQUID 1 0 1
19. PARA CRESYL FORMATE-LIQUID 1 0 1
20. PARA ANISYL FORMATE-LIQUID 1.25 0 1.25
21. PARA ANISYL PHENYL ACITATE-LIQUID 1.66 0 1.66
22. 4-METHOXY PHENYL ACETICACID-SOLID 3 0 3
23. 4-METHOXY PHENYL ETHYL AMINE-LIQUID 5.5 0 5.5
24. PERFUMERY INGREDIENTS-LIQUID 15 0 15
25. ETHANOL (FROM OMC PLANT)-LIQUID 16 0 16
26. HCL (FROM NITRILE PLANT)-LIQUID 48 0 48
TOTAL 8137.07 8137.07
BY PRODUCT
1. 99 % SODIUM SULPHATE –SOLID 2000 0 2000
TOTAL 2000 2000
The CTE case was discussed in meeting. After detailed discussion the committee unanimously decided to recommend to grant the CTE – change in product mix proposal with the condition of no increase in pollution load to maintain ZLD & with following conditions (1) Odour management plan shall be submitted to the Board. (2) Unit shall not discharge their domestic sewage into soak pit.
15. M/s UPL LIMITED (UNIT NO. 5), (PCB ID-25353), Plot No. 750 & 746, GIDC Estate
JHAGADIA, Dist- Bharuch – 393002.
The unit had applied for CTE change in product mix. It is Pesticide/Pesticide intermediate/ chlore alkali manufacturing unit. The unit has proposed to increase /decrease existing production with addition of new products and maintaining same total production capacity. There will be decrease in pesticide intermediate by products. List of proposed change product mix is as under as per Table L.
Water consumption will decrease from 777.27 KL/d to 722.384 kl/d. Total effluent load will decrease from 204.165 KL/d to 195.77 Kl/d. Existing utilities will be used. There will not be change in fuel or flue gas stack-emission. There will not be change in process gas stack-emission. There is no change in hazardous waste quantity. There will not be any new plant & machinery installed due to proposed change in product mix.
Table L PROPOSED PRODUCT LIST AFTER PROPOSED CHANGE IN PRODUCT MIX
COMPREHENSIVE LIST OF PRODUCTS
Sr No
Product Quantity – MT / Month By-Product
Quantity – MT / Month
Existing Additional
Total after
product mix
change
Existing
Additional
Total after product mix
change
01 PCL3 Plant
Phosphorus Tri Chloride
2550 500 3050 -- -- -- --
02 156 TPD Caustic Chlorine Plant
Caustic Soda Lye 48 % (on 100 % basis)
4680 -- 4680 Sodium Hypochlorite
225 -- 225
Chlorine Gas 3972 -- 3972 Dilute Sulphuric Acid (78 %)
155 -- 155
Hydrogen Gas 225 -- 225
Hydrochloric Acid (30 %)
1200 -- 1200
03 50 MW Power Plant (NG base)
Electric Power 50 MW / HR
-- 50 MW / HR
Steam 30 MT / HR
-- 30 MT / HR
04 Phosphorus 900 (-)600 300 Ferrous Phosphorus
150 (-)105 45
Calcium Silicate
6000 (-)3690 2310
05 PCL5 Plant
Phosphorus Penta Chloride (PCL5)
200 50 375 (Combine Capacity)
HCl (30 %) --
17.33 -- 17.33 --
COMPREHENSIVE LIST OF PRODUCTS
Sr No
Product Quantity – MT / Month By-Product
Quantity – MT / Month
Existing Additional
Total after
product mix
change
Existing
Additional
Total after product mix
change
06 Phosphorus Oxychloride OR Phosphorus Thiochloride
125 OR 100
--
07 Mancozeb / Antracol (combined capacity)
4000 -- 4000 Sodium Sulphate 96 % / Sodium Sulphate Solution
4092 / 15680
-- 4092 / 15680
Manganese Hydroxide
236 -- 236
Zinc Hydroxide
39 -- 39
NASH 1276 --- 1276
08 Pendimethylene OR Fipronil OR Buprofezin
400 OR NIL OR NIL
NIL OR 400 OR 400
400 (Combine Capacity)
Spent HCL Acid
200 -- 200
Spent H2SO4 Acid Nitric Acid
600 & NIL
NIL & 136
600 & 136
09 Glyphosate OR Gluphosinate (combined capacity)
550 -- 550 Ammonium Sulphate Solution
3600 -- 3600
Ammonium Sulphate Solid
750 -- 750
Magnesium Chloride Solution
2070 -- 2070
Ammonium Chloride(Solid)
950 - 950
10 CS2 (Carbon Di Sulphide)
3000 -- 3000 NaHS Solution
600 -- 600
COMPREHENSIVE LIST OF PRODUCTS
Sr No
Product Quantity – MT / Month By-Product
Quantity – MT / Month
Existing Additional
Total after
product mix
change
Existing
Additional
Total after product mix
change
11 37.5 MW POWER PLANT (Coal Fired )
37.5 MW/H
- 37.5 MW/H
Steam 30 MTH
- 30 MTH
12 Phenyl Di IsoDecylPhosphite OR Tri DecylPhosphite (TDP) OR Tris Tri DecylPhosphite (TTD)
50 - 50 -- -- -- --
13 Di Phenyl Methyl Phosphonate (DPMP) OR Tri Phenyl Phosphate (TPPA) OR Bisphenol Di Phosphate (BDP)
15 OR 15 OR 3.75
- -
15 OR 15 OR 3.75
HCl (30%) HCl (30%) HCl (30%) TPPA
56.6 17.08 6.64 5.1
- - - -
56.6 17.08 6.64 5.1
14 Tri Phenyl Phosphite (TPPI)
150 110 260 ( Combine Capacity) OR 140
HCl (30 %) 266 354 620
15 Tri Butyl Phosphite (TBP) OR Tri Iso Butyl Phosphite (TIBP) OR Phosphorus Acid
60 200 OR 200 OR 80
16 Di Methyl 600 - 600 HCl (30 %) 998 - 998
COMPREHENSIVE LIST OF PRODUCTS
Sr No
Product Quantity – MT / Month By-Product
Quantity – MT / Month
Existing Additional
Total after
product mix
change
Existing
Additional
Total after product mix
change
PhosphoroAmidoThioate (DMPAT) OR Myristyl amine(MO) (Combine Capacity) OR Phosphonate Diethyl P – Toluene Sulfonyloxy Methyl Phosphonate (DESMP)
OR NIL OR NIL
OR 600 (Combine Capacity) OR 300
Ammonium Chloride (NH4Cl)
211 - 211
17 Fosthiazate (IKI-1145) OR Cyproconazole OR Atrazine (Combine Capacity) OR 2,4 D Technical (2, 4 DiChloroPhenoxy Acetic Acid)
250 OR NIL OR NIL OR 125
NIL OR 250 OR 250 OR NIL
250 OR 250 OR 250 (Combine Capacity) OR 125
Ethylene Chloride
44.5 -- 44.5
Ammonium Chloride
84.25 -- 84.25
Ammonium Hydroxide (20 %) Sodium Hypochlorite (IKI – 1145)
116.75 NIL
-- 130
116.75 130
18 Dichloro Vinyl Acid Chloride (DVACL)/Acrolein/ TriethylPhosphite (Combine capacity)
300/NIL/NIL
- 300/300/300 Combine capacity
Spent Sulphuric Acid
900 - 900
POCl3 400 - 400
HCl (28%) 490 - 490
Sodium Sulphite
1200 - 1200
COMPREHENSIVE LIST OF PRODUCTS
Sr No
Product Quantity – MT / Month By-Product
Quantity – MT / Month
Existing Additional
Total after
product mix
change
Existing
Additional
Total after product mix
change
19 N Alkylated XyledeneOR HRT Ketone OR 2 Ethyl 6 Methyl N N Aniline OR MPBAL OR UPDT (Saponified Poly acrylonitrile Starch Graft Polymer)
300 OR 200 OR 300 OR 300 OR nil
- 300 OR 200 OR 300 OR 300 OR 300
20 PESTICIDE FORMULATION PRODUCTS
Existing Qty –MT/M
After Product Mix Change Qty –MT/M
Mancozeb 6700 Mancozeb 6700
Antracol Antracol
Glufosinate Glufosinate
Pendimethelen Pendimethelen
S-Metalachlor S-Metalachlor
Flonicamide (IKI220) Flonicamide (IKI220)
Clomazone Clomazone
Acephate (Combine capacity) Acephate (Combine capacity)
TOTAL MAXIMUM B (FORMULATION)
6700 TOTAL MAX (FORMULATION)
6700
TOTAL LIST OF BY-PRODUCTS AS ALLREADY MENTIONED ABOVE
Sr No
Name Existing Quantity
TPM
Additional Quantity
TPM
Total quantity
TPM
Source
01 Sodium Hypochlorite
TOTAL
225 -- 225 Caustic Chlorine Plant
02 -- 130 130 Fosthiazate
03 225 130 355
04 Dilute Sulphuric Acid 78 % 155 -- 155 Caustic Chlorine Plant
05 Steam
TOTAL
30 TPH -- 30 TPH Power Plant 50 MW
06 30 TPH -- 30 TPH Power Plant CFB
07 60 TPH -- 60 TPH
08 Ferrous Phosphorus 150 -(105) 45 Phosphorus Plant
TOTAL LIST OF BY-PRODUCTS AS ALLREADY MENTIONED ABOVE
Sr No
Name Existing Quantity
TPM
Additional Quantity
TPM
Total quantity
TPM
Source
09 Calcium Silicate 6000 -(3690) 2310 Phosphorus Plant
10 HCL 30 %
TOTAL
17.33 -- 17.33 PCL5 Plant
11 56.6 -- 56.6 DPMP
12 17.08 -- 17.08 TPPA
13 6.64 -- 6.64 BDP
14 266 354 620 TPPI Plant
15 998 -- 998 DMPAT
16 1361.65 354 1715.65
17 Sodium Sulphate 96 % / Sodium Sulphate Solution
4092 / 15680
-- 4092 / 15680
Mancozeb / Antracol Plant
18 Manganese Hydroxide 236 -- 236 Mancozeb / Antracol Plant
19 Zinc Hydroxide 39 -- 39 Mancozeb / Antracol Plant
20 NASH / NA2S
TOTAL
1276 / NIL
NIL / 1276
1276 combined capacity
Mancozeb / Antracol Plant
21 600 / NIL
NIL / 600 600 combined capacity
CS2 Plant
22 1876 / NIL
NIL / 1876
1876 combined capacity
23 Spent HCL 200 -- 200 Pendimethylene Plant
24 Spent Sulphuric Acid
TOTAL
600 -- 600 Pendimethylene Plant
25 900 -- 900 DVACL / Acrolein / TEP
26 1500 -- 1500
27 Nitric Acid -- 136 136 Pendimethylene Plant
28 Ammonium Sulphate Solution 3600 -- 3600 Glufosinate Plant
29 Ammonium Sulphate Solid 750 -- 750 Glufosinate Plant
30 Magnesium Chloride Solution 2070 -- 2070 Glufosinate Plant
31 Ammonium Chloride Solid 950 -- 950 Glufosinate Plant
32 Ammonium Chloride
TOTAL
211 -- 211 DMPAT
33 84.25 -- 84.25 Fosthiazate / Cyproconazol / Atrazine / 2-4D
34
35 296.25 296.25
36 TPPA (Tri Phenyl Phosphate) 5.1 -- 5.1 BDP
37 Ethylene Chloride 44.5 -- 44.5 Fosthiazate / Cyproconazol / Atrazine / 2-4D
TOTAL LIST OF BY-PRODUCTS AS ALLREADY MENTIONED ABOVE
Sr No
Name Existing Quantity
TPM
Additional Quantity
TPM
Total quantity
TPM
Source
38 Ammonium Hydroxide 20 % 116.75 -- 116.75 Fosthiazate / Cyproconazol / Atrazine / 2-4D
39 POCL3 400 -- 400 DVACL
40 HCL 28 % 490 -- 490 DVACL / Acrolein / TEP
41 Sodium Sulphite 1200 -- 1200 DVACL / Acrolein / TEP
The CTE case was discussed in meeting. After detailed discussion the committee unanimously decided to recommend to grant the CTE – change in product mix proposal with the condition of no increase in pollution load & with following conditions (1) Odour management plan shall be submitted to the Board . (2) Unit shall not discharge their domestic sewage into soak pit.
16. M/s Asian Paint Ltd, (PCB ID-14934), Plot No. 2702, GIDC Estate Ankaleshwar, Dist-
Bharuch – 393002.
The unit had applied for CTE change in product mix. It is paints, Varnishes, Pigment manufacturing unit. The unit has proposed to add one new product with deleting existing all three products with same overall production capacity i.e. 35016 MT/Annum. List of proposed change product mix is as under as per Table N.
There is no any change in water consumption and waste water generation. There will not be change in fuel or flue gas stack-emission. Existing two process gas stacks will be eliminated. There is decrease in hazardous waste category/quantity.
Table N PROPOSED PRODUCT LIST AFTER PROPOSED CHANGE IN PRODUCT MIX
Sr. No. Product Existing (TPA / KLPA)
Additional quantity (TPA/ KLPA)
Total after expansion (TPA / KLPA)
1. Phthalic Anhydride 29796 TPA 0 0
2. Light and Heavy ends of Phthalic Anhydride
360 TPA 0 0
3. Maleic Acid Solution 4860 TPA 0 0
5. Synthetic Resins and Emulsions (TSR)
0 35016 TPA 35016 TPA
The CTE case was discussed in meeting. After detailed discussion the committee unanimously decided to recommend to grant the CTE – change in product mix proposal with the condition of no increase in pollution load & with following conditions (1) Unit shall follow spent solvent management guideline framed by board and shall make
MoU with offside distillation units. Also submit the prescribed forms as per guideline. (2) Unit shall not discharge their domestic sewage into soak pit.
17. M/s. Baroda Intermediate Pvt Ltd, Plot No.C1/B-128/27, GIDC: Nandesari Dist:
Vadodara.
Unit has applied for CTE- change in product mix without increasing total product quantity and pollution load. Unit engaged in manufacturing of 4-NAP. They have applied for product mix for the same production capacity as under:
Sr. No.
Name of Product Existing quantity
Proposed quantity
Total Quantity
1 4-Nitro 2 Amino Phenol (4-NAP) OR
14MT/Month 0 14MT/Month
2 4-Chloro 2 Amino Phenol (4-CAP)
0 14MT/Month
The project proponent and his representative made a detailed presentation and represented for no increase in overall hazardous waste generation.
But the Committee felt that industry has not disclosed the actual quantity of Iron waste generation & also auditor M/s. Darshan Institute of Engineering & Technology has endorsed on wrong details of iron waste submitted by unit. The committee has decided to refer the case in TCM meeting whenever industry shall submit actual details of Iron waste generation & also the new adequacy certificate endorsing actual quantity of Hazardous wastes.
18. Deepak Nitrite Limited, Plot no. 4-12, GIDC Nandesari, Dist: Vadodara
Unit has applied for CTE- change in product mix without increasing total product quantity and pollution load. Unit engaged in manufacturing Nitrite section and Nitro Aromatics products. They have applied for product mix for the following products as under:
Sr. No.
Name of Product Existing quantity
Proposed addition quantity
Total Quantity
1 Para Nitro Toluene Sulphonic acid (PNToSA) OR Lubricity Improver
400MT/Month 0 400MT/Month
2 Toluidine/Xyledene/Cumedene OR Dichloro Aniline
1000MT/Month 0 1000MT/Month
The project proponent and his representative made a detailed presentation. There is no additional water consumption or industrial wastewater generation after proposed change in product mix. There is no change in flue gas emission or process gas emission.
After detailed deliberation, the committee unanimously decided to recommend the case
for the grant of CTE-change in product mix with following conditions.
1. Domestic wastewater shall be treated in STP and discharge into NIA-CETP.
2. Applicant shall ensure that Real Time Online Monitoring System shall be
operated, maintained & calibrated time to time for major parameters of Air
Pollution & Water Pollution being discharged.
19. M/s. Solaris Chemfood Ltd, Vill: Karakhadi, Ta: Padra, Dist: Vadodara.
Unit has applied for CTE- change in product mix without increasing total product quantity and pollution load. Unit engaged in manufacturing Chemicals (Bromine Derivatives) products. Unit’s product attached as annexure-I.
The project proponent and his representative made a detailed presentation. There is no additional water consumption or industrial wastewater generation after proposed change in product mix. There is no change in flue gas emission or process gas emission.
After detailed deliberation, the committee unanimously decided to recommend the case for the grant of CTE-change in product mix with following conditions:
1. Hazardous waste HBr shall be completely reused within factory premises. Hence, production shall be synchronized with the generation of HBr.
20. M/s. S.Kant Health Care Ltd, Plot No- 1802, 1805, Phase-II, GIDC Estate, Vapi-369195, Tal - Pardi, Dist -Valsad
Unit had applied Consent to Establish for change of product mix. The unit has proposed to manufacture their existing Bulk Drugs and its intermediate products by reducing some of their existing products quantity and addition of new products of same group as per annexure A.
After proposed production existing total capacity of organic product 260 MT/Month reduced by 257.32 MT/Month.
In the meeting representative from the industry has made presentation with technical details of proposed products with quantity of effluent generation, air emissions, and hazardous waste management to the technical committee members. There is reduction in waste water generation 96 KLD to 93.10 KLD. No additional stack for flue gas as well as process emission. No increase in HW generation, quantity of ETP waste is decreased. The unit has submitted adequacy certificate for no increase in pollution load.
Thereafter due discussions, the committee recommended for granting CTE to the unit with condition:
• There shall be no increase in existing pollution load • The unit shall apply as per provision rule 9 of HW 2016 for their by products • The unit shall comply the guideline made by GPCB for spent solvent management and
handling. • The unit shall not dispose domestic waste water through soak pit, instead of it overflow
of septic shall be diverted to ETP of the unit.
21. M/s. Kroma Industries, Plot No- 1404, 1405, Phase-III, GIDC Estate, Vapi-369195, Tal - Pardi, Dist -Valsad
Unit had applied Consent to Establish for change of product mix. The unit has proposed to manufacture their existing organic products by reducing production capacity for three products and addition of two new products of the same group as per bellow. Unit will also discontinue their two existing inorganic products:
Sr
No.
Organic Pigment
Existing
MT/Month
Proposed
MT/Month
Total
MT/Month
1 Organic Red Pigment 30.00 -10.00 20.00
2 Organic Yellow Pigment 40.00 -10.00 30.00
3 Organic Orange Pigment 20.oo -10.00 10.00
4 Organic Violet Pigment 00 20.00 20.00
5 Organic Blue Pigment 00 05.00 05.00
Total 90.00 05.00 85.00
After proposed production existing total capacity of organic product 90 MT/Month reduced by 5 MT/Month and final total is 85 Mt/Month capacity
In the meeting representative from the industry has made presentation with technical details of proposed products with quantity of effluent generation, air emissions, and hazardous waste management to the technical committee members. There is reduction in water consumption as well as waste water generation. No additional stack for flue gas as well as process emission. No increase in HW generation. The unit has submitted adequacy certificate for no increase in pollution load.
Thereafter due discussions, the committee recommended for granting CTE to the unit with condition:
• No increase in existing pollution load • The unit shall not dispose domestic waste water through soak pit, instead of it overflow
of septic shall be diverted to ETP of the unit.
22. M/s. Creative Textile Mills Pvt. Ltd., Plot No- 157, 158, Phase-II, GIDC Estate, Vapi- 369195, Tal - Pardi, Dist -Valsad
Unit had applied for CTE –amendment for modernisation of their plant with expansion of production capacity and proposed to use CETP and its conveyance system for disposal of their treated waste water after achieving outlet norms of CETP,Vapi.
This is the case pertain to CPCB’s directions issued to GPCB, vide letter no B-22013/ PCI-III/ CETP/ 2008 dated 02/09/2008; under section 18(1) (b) of the Water (Prevention and Control of Pollution) Act 1974, in the matter of CETP and its subsequent modification of the said direction on 31.03.2016.
In meeting representative of the unit has made brief about the project, however, Chairman GPCB has suggested that to decide policy as soon as early for such matter and then keep such CTE in the next meeting.
24. M/s. United Phosphorous Ltd., Plot No- 3-11, Phase-I, GIDC Estate, Vapi-369195, Tal - Pardi, Dist -Valsad
Unit had applied Consent to Establish for change of product mix. The unit has proposed to manufacture their existing Pesticide products by either or combination without increase in existing production capacity of pesticide for only following products as per bellow. The unit is having permission to manufacture other products also as per existing CCA.
Sr. No.
Existing Products Capacity MT/M
Proposed Products Capacity MT/M
Pesticide Products- Technical Grade
1.
Alpha Cypermethrin 30
OR
30
OR
30
Alpha Cypermethrin 30
OR
30
OR
30
OR
30
OR OR
Beta Cypermethrin Beta Cypermethrin
OR OR
Imidacloprid
Imidacloprid
OR
Azoxystrobin
2. Denatonium Benzoate 1
Denatonium Benzoate (DB)
1
ASAM 2 ASAM 2
OR
Denatonium Benzoate 2
Total 33 Total 33
After proposed production existing total capacity remain 33 MT/Month for the above mentioned products.
In the meeting representative from the industry has made presentation with technical details of proposed products with quantity of effluent generation, air emissions, and hazardous waste management to the technical committee members. There is no increase in waste water generation. No additional stack for flue gas as well as process emission. No increase in HW generation. The unit has submitted adequacy certificate for no increase in pollution load.
Thereafter due discussions, the committee recommended for granting CTE to the unit with conditions:
• No increase in existing pollution load • The unit shall apply as per provision rule 9 of HW 2016 for their by products • The unit shall comply the guideline made for spent solvent management and handling. • The unit shall not dispose domestic waste water through soak pit, instead of it overflow
of septic shall be diverted to ETP of the unit.
Annexure A
Sr. No.
NAME OF PRODUCT QUANTITY
EXISTING ADDITIONAL TOTAL
A. FORMULATION
1 Tablets 2,500 Lacs/Month 0 2,500 Lacs/Month
2 Liquid Syrup/ Suspension 9,00,000 Lit/Month 0 9,00,000 Lit/Month
3 Dry Syrup/Suspension 4,00,000 Lit/Month 0 4,00,000 Lit/Month
4 Capsules 1000 Lacs/Month 0 1,000 Lacs/Month
5 Ointment/Oleum 60,000 Kg/Month 0 60,000 Kg/Month
B. BULK DRUGS (MT/Month)
1 Isox Suprine Hydrochloride 0.250 -0.100 0.150
2 Chlorzoxazone 0.150 -0.150 0.000
3 Calcium Levilinate 0.250 -0.250 0.000
4 Artesunate 1.000 -0.400 0.600
5 Artemether 1.870 0.000 1.870
6 ABA Artether 0.500 -0.300 0.200
7 Dihydroartomisin (DHAM) 1.000 -0.400 0.600
8 Silver Sulphadiazine 0.000 0.350 0.350
9 Methylcobalamine 0.000 0.150 0.150
10 Praziquantel 0.000 1.000 1.000
TOTAL 5.020 -0.100 4.920
C. INTERMEDIATES (MT/Month)
1 Bromo compounds 0.425 -0.425 0.000
2 PIP Amine 0.250 -0.250 0.000
3 Normal Amino Ketone Hydrochloride
1.375 -1.375 0.000
4 Lumefantrine 4.000 0.000 4.000
5 Dichloro Dibutylamino 0.000 2.000 2.000
Fluoren Ethanol (DDFE)
TOTAL 6.050 -0.050 6.000
D. STEARATES (MT/Month)
1 Magnesium Stearates 34.000 0.000 34.000
2 Zinc Stearates 7.000 -1.000 6.000
3 Calcium Stearates 8.000 -2.000 6.000
TOTAL 49.000 -3.000 46.000
E. IODIDE SALTS (MT/Month)
1 Potassium Iodide (Salt) 100.000 0.000 100.000
2 Sodium Iodide (Salt) 100.000 0.000 100.000
TOTAL 200.000 0.000 200.000
F. BY PRODUCT FROM BULK DRUGS (MT/Month)
1 Benzoic Acid 0.000 0.400 0.400
TOTAL 0.000 0.400 0.400
OVERALL TOTAL (B+C+D+E+F) 260.070 -2.750 257.320
LIST OF RAW MATERIALS
S.
NO.
RAW MATERIALS
QUANTITY (KG/MONTH)
EXISTING PROPOSED TOTAL
1 Charcoal 926.68 - 0.99 925.69
2 Artemisinine 1052.63 - 421.05 631.58
3 DihydroArtemisinine 3243.88 - 616.29 2627.59
4 Methanol 34534.50 - 3038.79 31495.71
5 Acetone 4702.61 - 442.38 4260.23
6 Tri Methyl Ortho Acetate 1870.00 0.00 1870.00
7 Acetyl Chloride Cat -I 51.94 0.00 51.94
8 Boron tri flouride Cat -II 157.34 - 94.40 62.94
9 n-hexane 217.60 - 217.60 0.00
10 Ab.Alcohol 1174.82 - 704.89 469.93
11 Sodium Bicarbonate 19.47 0.01 19.48
12 Sodium Acetate 1468.53 - 881.12 587.41
13 Dichloro methane 5316.22 - 3094.00 2222.22
14 para chlorobenzaldehyde 1266.67 0.00 1266.67
15 Caustic 27950.84 - 43.86 27906.98
16 DDFE 1333.33 0.00 1333.33
17 Stearic Acid 44071.64 - 2734.33 41337.31
18 Magnesium Hydroxide 4567.16 0.00 4567.16
19 Calcium Hydroxide 1261.49 - 365.97 895.52
20 Zinc Oxide 1072.63 - 153.23 919.40
21 Tri Ethyl Amine 290.32 - 116.13 174.19
22 Siccinic Anhydried 564.52 - 225.81 338.71
23 Sodium Borohydried 168.42 - 67.37 101.05
24 Levulinic Acid 208.33 - 208.33 0.00
25 Iodine 163634.00 0.04 163634.04
26 Formic Acid 35105.20 0.00 35105.20
27 Pottesium Carbonate 42639.75 - 332.06 42307.69
28 Acetic Acid 461.16 - 184.47 276.70
29 Bromine 175.10 - 175.10 0.00
30 Mono chloro Benzene 1118.82 - 1118.82 0.00
31 4ChloroAmino Phenol 150.00 - 150.00 0.00
32 Urea 75.00 - 75.00 0.00
33 NAK HCl 380.00 - 152.00 228.00
34 Pallaium Charcoal 5.00 - 2.00 3.00
35 hydrogen Gas M3 133.55 - 81.05 52.50
36 Amonia M3 151.32 - 151.32 0.00
37 Nikle 43.86 - 43.86 0.00
38 Toluene 1354.76 - 1354.76 0.00
39 Sulphuric Acid 183.10 - 183.10 0.00
40 Benzylpropiophenone 258.40 - 258.40 0.00
41 Aluminium chloride 425.00 - 425.00 0.00
42 Phenol 248.94 -701.06 950.00
43 P-hydroxypropiophenol 170.00 170.00 0.00
44 Benzyl chloride 153.00 - 153.00 0.00
45 Sodi.Iodide 13.60 - 13.60 0.00
46 MEA 34.00 - 34.00 0.00
47 chlorine 130.48 - 130.48 0.00
48 Monochloroacetone 208.33 - 208.33 0.00
49 Calcium Carbonate 98.68 - 98.68 0.00
50 Calcium Chloride 53.73 - 53.73 0.00
51 NAOH 2199.97 - 562.40 1637.58
52 MEK 15391.93 - 14562.43 829.50
53 PTSA 985.85 - 985.85 0.00
54 AAK HCl 1731.72 - 1731.72 0.00
55 HCL 329.50 - 268.00 61.50
56 Propionyl chloride 139.40 - 139.40 0.00
57 HNO3 1.70 - 1.70 0.00
58 Sulfadaizine 0.00 255.47 255.47
59 AgNO3 0.00 153.28 153.28
60 Cynocobalamine 0.00 166.67 166.67
61 CH3I 0.00 133.33 133.33
62 Choloroform 0.00 10016.31 10016.31
63 Compound – 1 0.00 2127.66 2127.66
64 H3PO4 0.00 3191.49 3191.49
65 NH3 0.00 1489.36 1489.36
66 MDC 0.00 319.15 319.15
67 CHCC 0.00 638.30 638.30
68 Soda Ash 0.00 531.91 531.91
69 Oxirane 0.00 1515.15 1515.15
70 n-Butanol 0.00 3636.36 3636.36
71 DBA 0.00 787.88 787.88
TOTAL 405676.44 - 11563.33 394113.10
25. M/s . Shital Chemical Ind. (GPCB ID No:17625), Plot No.:194/1,SOKHADA - -388620’DIST : Anand, TAL : Khambhat
The unit had applied for CTE change in product mix. It is Chemical manufacturing unit.
Product profile of the unit can be classified in to sets broadly as under:
1) Bulk drugs-10 numbers of product-10 MT/Month(Total products).
2) Organic derivatives(Chlorine and Acid Chloride)-62 products & 625 MT/Month(Including
Existing and Proposed)
Unit does not intend to change in Bulk Drug Production and that products & production
quantity List of proposed change product mix is given in Table A.
There is no any change in water consumption & waste water generation quantity after this
change. Unit is at present member of EICL and their discharge to EICL is 25 KLD. Existing
utilities will be used. There will not be change in fuel consumption or flue gas stack-
emission. There will not be change in process gas stack-emission. There is no change in
hazardous waste quantity. There will not be any new plant & machinery installed due to
proposed change in product mix. Distillation residue shall be sent for co-processing in
cement industry.
Table: A PROPOSED PRODUCT LIST AFTER PROPOSED CHANGE IN PRODUCT MIX
Sr.
No.
Name of Product Existing Quantity
(MT/Month)
Proposed
Quantity*
(MT/Month)
Campaign
Basis Max.
Production
(MT/Month)
1. Benzotrichloride 250 463 625
2. Benzyl Chloride 625
3. 2,4-Dichlorobenzyl
chloride 625
4. 4-Fluorobenzoyl chloride 297
5. N – Chlorosuccinimide 5
6. 2-Chloro-6-fluoro
benzaldehyde 250
7. 2,6-Dichloro
benzaldehyde
8. 4-fluoro benzaldehyde
9. 2-Chloro 4-Fluoro
Benzotrichloride
-
589
10. Methoxyethyl chloride - 176
11. Propoxyethyl chloride - 231
12. Isobutyl chloride - 176
13. n-Pentyl chloride - 203
14. n-Hexyl chloride - 225
15. n-Heptyl chloride - 251
16. n-Octyl chloride - 278
17. Isooctyl (2-Ethylhexyl)
chloride
-
278
18. Decyl Chloride - 330
19. Dodecyl chloride - 383
20. Dimethylaminoethyl
chloride hydrochloride
-
268
21. Diethylaminoethyl
chloride hydrochloride
-
321
22. Benzoyl chloride 375 625
23. Trimethylacetyl chloride 289
24. Acetyl chloride 355
25. 4-Chlorobutyryl Chloride 264
26. 2,4-Dichloro
acetophenone 40
27. Chloroacetyl chloride 279
28. Isobutyryl chloride 269
29. N – Valeryl chloride 288
30. Isovaleryl chloride 288
31. Isopthaloyl chloride 190
32. Propionyl chloride 248
33. Propiophenone 10
34. 4 – Fluorobenzyl chloride 625
35. N – Butyryl Chloride 269
36. 2,2-Dimethyl butyryl
chloride 306
37. 3-Chloropropionyl chloride 238
38. m-Chlorobenzoyl chloride 328
39. P – Chlorobenzoyl
chloride 328
40. p-Toluoyl chloride 291
41. 4-Methoxybenzoyl
Chloride 319
42. 2-Ethylhexanoyl Chloride - 304
43. 4-Chloromethyl Benzoyl
chloride
-
354
44. o-Toluoyl chloride - 291
45. Trifluoroacetyl chloride - 303
46. Cyclopropanecarbonyl
chloride
-
266
47. Methoxyacetyl chloride - 251
48. Heptanoyl Chloride - 278
49. Octanoyl chloride - 304
50. Cyclohexanoyl chloride - 274
51. 1,4-
Cyclohexanedicarbonyl
chloride
-
202
52. Neodecanoyl chloride - 356
53. Isononanoyl Chloride - 330
54. Undecanoyl Chloride - 383
55. Dodecanoyl (Lauroyl)
Chloride
-
409
56. 2-Furoyl chloride - 225
57. 2-Thiophenecarbonyl
chloride
-
255
58. 3,5-Dichlorobenzoyl
chloride
-
422
59. Terephthaloyl chloride - 188
60. Isobutyramide - 5
61. Trimethylacetic acid 99% - 50
62. 3-Amino Propane Sulfonic
Acid
- 10
BULK DRUGS (No Change)
63. Aripiprazole 10 - 10
64. Cilostozole
65. Doxazocine
66. Fexofenadine
67. Irbesartan
68. Lisinopril
69. Lumefentrine
70. Metoprolol
71. Nibivolol
72. Pantoprazole
73. Pioglitazone
74. Telmisartan
75. Zonisamide
The project proponent made a detailed presentation in this regard. The committee discussed the case in detailed &. After detailed discussion the committee unanimously decided to recommend to grant the CTE – change in product mix proposal with the condition of no increase in pollution load & with following conditions.
(1) Unit shall follow spent solvent management guideline framed by board and shall make MOU with offsite distillation units. Also submit the prescribed forms as per guideline.
(2) Unit shall send their Aqueous layer for Co – Processing. (3) The by product mentioned in the application shall be treated as hazardous wastes
considering the Hazardous and other waste (Management and Transboundry) Rules -2016 and the unit shall apply for amendment in the authorization.
(4) Online CEMS for the process gas shall be provided & its data shall be hooked up with GPCB web site.
(5) Alkaline scrubbing media tank shall be provided with online pH sensor with hooter device to maintain the alkalinity of the scrubbing media continuously.
(6) Standby pump shall be provided with all process stack scrubbing media tanks & all efforts shall be made to have instrumentation and control of the Air pollution control measures and ins linkage with main plant.
26. M/s . Cambay Organics P Ltd. (GPCB ID No: 17361), PLOT NO: 194/1,SOKHADA –
388620, DIST : Anand, TAL : Khambhat.
The unit had applied for CTE change in product mix. It is Chemical manufacturing unit.
Product profile of the unit can be classified in to sets broadly as under:
3) Organic derivatives(Chlorine and Acid Chloride)-56 products & 400
MT/Month(Including Existing and Proposed)
List of proposed change product mix is given in Table A.
There is no any change in water consumption & waste water generation quantity after this
change. Unit is at present member of EICL and their discharge to EICL is 10 KLD. Existing
utilities will be used. There will not be change in fuel consumption or flue gas stack-
emission. There will not be change in process gas stack-emission. There is no change in
hazardous waste quantity. There will not be any new plant & machinery installed due to
proposed change in product mix. Distillation residue shall be sent for co-processing in
cement industry.
Table: A PROPOSED PRODUCT LIST AFTER PROPOSED CHANGE IN PRODUCT MIX
SR. NO.
NAME OF PRODUCTS QUANTITY (MT/MONTH)
EXISTING PROPOSED * CAMPAIGN BASIS MAX. PRODCTION
1. Benzotri Chloride 175 272 400
2. 2,3 Dichloro Benzotri Chloride 367
3. m- Chloro Benzyl Chloride 400
4. p- Chloro Benzyl Chloride 400
5. o- Chloro Benzyl Chloride 400
6. m-Fluorobenzotri Chloride 297
7. p-Fluorobenzotri Chloride 297
8. o-Fluorobenzotri Chloride 297
9. m-Fluorobenzyl Chloride 400
10. p-Fluorobenzyl Chloride 400
11. o-Fluorobenzyl Chloride 400
12. O - Chlorobenzotri Chloride - 297
13. m -Chlorobenzotri Chloride - 297
14. p- Chlorobenzotri Chloride - 297
15. 4 Chloro 2 Fluoro Benzotri Chloride
- 344
16. 2 Chloro 4 Fluorobenzotri Chloride - 344
17. Benzyl chloride - 400
18. 2 Chloro 6 Fluoro Benzyl Chloride - 400
19. Benzoyl Chloride 110 400
20. Acetyl Chloride 65 211
21. Chloro Acetyl Chloride 50 179
22. Iso Valeryl Chloride 185
23. 2,3 Dichloro Benzoyl Chloride 291
24. Trimethyl Acetyl Chloride 185
25. N-Valeryl Chloride 185
26. 2- Chloro Propionyl Chloride 190
27. m- Chloro Benzoyl Chloride 102
28. p- Chloro Benzoyl Chloride 102
29. o- Chloro Benzoyl Chloride 102
30. m-Fluorobenzoyl Chloride 93
31. p-Fluorobenzoyl Chloride 93
32. o-Fluorobenzoyl Chloride 93
33. Propionyl Chloride 159
34. N- Butyryl Chloride 173
35. Iso Butyryl Choride 173
36. 2-Furoyl Chloride 76
37. 2 Bromo Benzoyl chloride - 128
38. 2,4 Dichloro Benzoyl chloride - 122
39. 3,4 Dichloro Benzoyl Chloride - 122
40. 4 Chloro 2 Fluoro Benzoyl Chloride
- 113
41. 2 Chloro 4 Fluoro Benzoyl Chloride
- 113
42. 3 Methoxy Benzoyl Chloride - 100
43. 2 methoxy Benoyl Chloride - 100
44. 4 methoxy Benoyl Chloride - 100
45. 3-Bromo Benzoyl chloride - 128
46. 4 Bromo Benzoyl Chloride - 128
47. Isophthoyl Chloride - 59
48. phenyl acetyl Chloride - 90
49. propoxy Ethyl Chloride - 72
50. 2 - Ethyl hexanoyl Chloride - 95
51. 4 - Chloro Butyryl Chloride - 82
52. P-Toluoyl Chloride - 90
53. Benzophenone - 180
54. Propiophenone - 120
55. 2,4-Dichloroacetophenone 180
56. 2’-Chloro-2-Amino-5-
- 272
nitrobenzophenone
TOTAL 400 - 400
The project proponent made a detailed presentation in this regard. The committee discussed the case in detailed &. After detailed discussion the committee unanimously decided to recommend to grant the CTE – change in product mix proposal with the condition of no increase in pollution load & with following conditions. (7) Unit shall follow spent solvent management guideline framed by board and shall make
MoU with offsite distillation units. Also submit the prescribed forms as per guideline. (8) Unit shall send their Aqueous layer for Co – Processing. (9) The by product mentioned in the application shall be treated as hazardous wastes
considering the Hazardous and other waste (Management and Transboundry) Rules -2016 and the unit shall apply for amendment in the authorization .
(10) Online CEMS for the process gas shall be provided & its data shall be hooked up with GPCB web site.
(11) Alkaline scrubbing media tank shall be provided with online pH sensor with hooter device to maintain the alkalinity of the scrubbing media continuously .
(12) Standby pump shall be provided with all process stack scrubbing media tanks & all efforts shall be made to have instrumentation and control of the Air pollution control measures and ins linkage with main plant.
27 M/s. Ambuja Intermediates Pvt. Ltd. Plot No.: 41, Phase – II, GIDC Estate,Vatva, Ahmedabad. The unit had applied for CTE change in product mix. It is dyes manufacturing unit. The unit has proposed additional Reactive/Acid/Mono Azo/ Disazo dyes with existing reactive dyes as shown below with same production capacity i.e. 30 MT/month. There will be no increase in pollution load due to proposed change in product mix. There will not be any new plant & machinery installed.
Sr No
Existing Products
Existing Quantity (MT/mont
h)
Sr no
Proposed Products Proposed Quantity
(MT/month)
1 REACTIVE BLACKN150/
30
1 REACTIVE BLACK-N150
30
2 REACTIVE BLACKHFGR/ 2
/REACTIVE BLACK-HFGR/
3 ACID BROWN-14 / 3 ACID BROWN-14/
4 ACID BROWN-214 / 4 ACID BROWN-214 /
5 ACID BLACK -172 / 5 ACID BLACK -172 /
6 ACID BLACK -194 / 6 ACID BLACK -194 /
7 ACID BLACK -234 / 7 ACID BLACK -234 /
8 ACID BLACK -210 / 8 ACID BLACK -210 /
9 DIRECT BLACK-80 9 DIRECT BLACK-80/
10 NOVACRON YELLOW NC[Ambuja Yellow H-14]
12 MONOAZO TZ 3948 [Ambuja Monoazo H-10]
13 MONOAZO TZ 2688 [Ambuja Monoazo H-19]
14 MONOAZO SR 4420 [Ambuja Monoazo H-8]
15 DISAZO ROE 888 [Ambuja Disazo H-15]
16 MONOAZO AE 3978 [Ambuja monoazo H-6 ]
There will not be any change in water consumption & waste water generation as well as disposal mode in existing as well as proposed change of product. There will be no change in flue gas/ process stacks as well as fuel consumption and hazardous waste quantity due to proposed change in product mix.
The CTE case was discussed in meeting. After detailed discussion the committee
unanimously decided and recommended to grant the CTE – change in product mix
proposal with the conditions (1) There shall be no increase in pollution load. (2) Unit
shall treat its domestic waste water along with industrial waste water or treat it
separately in a STP instead of its discharge into Septic tank/ Soak pit.
28. M/s. Continental Chemicals, Plot No. 632, Phase VI, GIDC Naroda, Ahmedabad ‐
382330. The unit has applied for CTE change in product mix. It is Dye Intermediate manufacturing unit. The unit has proposed to discontinue existing intermediate and proposed to manufacture reactive and acid dyes with same production capacity i.e. 20 MT/month. There will be no increase in pollution load due to proposed change in product mix. There will not be any new plant & machinery installed.
Sr. No.
Product type
Products
Existing Quantity
(MT/month)
Proposed Product Change Mix(MT/month)
Total Quantity (MT/month)
1 Dyes
Intermediate DASA 20.0 -19.0 1.0
2
Reactive Dyes
Reactive Blue 222
0.0 19.0 19.0
3 Reactive Blue 21
4 Reactive Blue 198
5 Reactive Blue 221
6 Reactive Orange ME2RL
7 Acid Dyes Acid Blue 324
TOTAL 20.0 0.0 20.0
The table below shows the total water consumption as well as waste water generation
scenario after change in product mix.
Sr.
No.
Category Water Consumption
(L/d)
Waste Water generation
(L/d)
EXISTING PROPOSED TOTAL EXISTING PROPOSED TOTAL
1. Domestic 2000 0 2000 1000 0 1000
2. Industrial
Process & Washing 12850 ‐450 12400
14050 ‐350 13700
Boiler 1800 0 1800
0 0 0
Cooling 1350 0 1350 950 0 950
Total Industrial 18000 ‐450 17550
15000 ‐350 14650
Grand Total 18000 ‐450 17550 16000 ‐350 15650
Industrial wastewater will be separated in to dilute effluent & concentrated effluent. Dilute effluent will be treated in ETP plant of the unit & then it will be sent to CETP, NEPL. Concentrated stream separately stored will be sent to common MEE of NEPL.
There are no changes in flue gas and process stack details. Unit proposes to switch over
from LDO (2 kL/month) and Agro waste (9.0 MT/month) to Natural gas (112.95 mm
BTU/month). Diesel (for D. G. Set- 6 L/h) remains same.
The table below shows the total Hazardous waste scenario after change in product mix.
Sr. No.
Waste Exisiting Proposed Total Management
1
ETP Sludge
(a)Gypsum
(b)ETP
140 MT/month
0.5
MT/ month
-133 MT/ month
‐0.3
MT/ month
7 MT/ month
0.2
MT month
Collection, Storage, Transportation, Disposal by selling to M/s. Gujarat Ambuja Cement Ltd and/or at TSDF by NEPL.
2 Used Oil 125 L/y - 125 L/y
Collection, Storage, Transportation, Disposal by selling to Registered rerefiners.
3 Discarded Containers
70 nos./y -50 nos./y 20 nos./y Collection, Storage, Transportation, Disposal by
& Bags
selling to authorized recycler.
4 Process Waste
70 MT/month
-65 MT/month 5
MT/month
Collection, Storage, Transportation, Disposal by selling to M/s. Gujarat Ambuja Cement Ltd. and M/s. Gujarat Sidhee Cement Lts. And/or at TSDF by NEPL
5 Inorganic
Acid(Spent Acid)
15 MT/d -14.2 MT/d 0.8 MT/d
Collection, Storage, Treatment, Transportation, Disposal at TSDF by NEPL and/or by selling to actual and user
The CTE case was discussed in meeting. After detailed discussion the committee
unanimously decided and recommended to grant the CTE – change in product mix proposal
with following conditions: (1) There shall be no increase in pollution load. (2) Unit shall submit
the worst case scenario for the most polluting product obtained from Schedule-I auditor. (3)
Unit shall treat its domestic waste water along with industrial waste water or treat it
separately in a STP instead of its discharge into Septic tank/ Soak pit.
29. M/s. Advance Adhesive Ltd. (Old name: Kairav Chemical Ltd.) located at Block no. 2221,
Plot No. 5 & 6, Vill. Santej, Ta. Kalol, Dist. Gandhinagar has applied for the CTE –
Amendment under the head of product mix.
Earlier unit was manufacturing Bulk Drug under the category of 5(f) of EIA Notification –
2006. Now unit has approached for manufacturing of Adhesive Chemicals under the
category of 5(f) of EIA Notification – 2006.
Manufacturing of Diclofenac Sodium and other products were stopped in 2014 for which
they had CCA up to 2014. Then industry switched over to other products which are not
attracting EIA Notification – 2006.
The details of old products and proposed products are mentioned below;
Sr. No.
Name of Product Production Capacity (MT Per Month)
Existing Proposed Total
EXISTING PRODUCTS
1 Diclofenac Sodium 20 -20 Nil
2 Diclofenac Potassium 2 -2 Nil
3 Diclofenac Diethyl Ammonium Salt 2 -2 Nil
4 Diclofenac Free Acid 1 -1 Nil
5 2: 6 Dichloro Phenol 20 -20 Nil
6 Nimesulide 10 -10 Nil
7 Chlorzoxazone 5 -5 Nil
8 Methanol (Recovered as by product) 10 -10 Nil
9 Spent Acid(Recovered as by product) 5 -5 Nil
TOTAL 75 -75 Nil
Sr. No.
Name of Product Production Capacity (MT Per Month)
Existing Proposed Total
PROPOSED PRODUCTS
1 Epoxy Hardener Nil 25 25
2 Poly Vinyl Alcohol (PVA) / Acrylic Emulsions and Adhesives Solution
Nil 10 10
3 Construction chemicals & Adhesives Nil 10 10
4 Epoxy Adhesives and Modified products Nil 25 25
TOTAL Nil 70 70
Industry has made the presentation before the Technical Committee and copy of the same is
also enclosed here. During detail deliberation it was mentioned that overall waste water
generation quantity and pollution load in terms of COD will be reduced. At the same time the
emission of flue gas will also reduced as in compare to fuel as a wood and LDO, now they will
use Natural Gas. In addition to this during production of proposed product there will be no
process gas emission and whatever process emissions were in old products, will be totally
eliminated. L.D. College of Engineering Chemical Department has submitted the adequacy
certificate.
After detail discussion it is recommended to grant the CTE – Amendment with the following
conditions;
1. Certificate from chartered engineers shall be submitted within 15 days.
2. Distance certificate and self certification that industrial plant is not covered under Eco
Sensitive Zone Notification.
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